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Iberian Pyrite Belt

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The Iberian Pyrite Belt is a vast geographical area with particular geological features that stretches along much of the south of the Iberian Peninsula , from Portugal to Spain . It is about 250 km long and 30–50 km wide, running northwest to southeast from Alcácer do Sal (Portugal) to Sevilla (Spain). The mining activity in this region goes back thousands of years.

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129-467: The Iberian Pyrite Belt has had more than 2000 million tons of ore removed, and still has more than 400 million left to exploit. It is the largest concentration of massive sulfides in the world. The Iberian Pyrite Belt was formed 350 million years ago in the Devonian Period, connected to active and hydrothermal volcanism that led to the formation of a volcanic-sedimentary complex. Volcanic activity in

258-507: A predatory microorganism invaded a large prokaryote, probably an archaean , but instead of killing its prey, the attacker took up residence and evolved into mitochondria; one of these chimeras later tried to swallow a photosynthesizing cyanobacterium, but the victim survived inside the attacker and the new combination became the ancestor of plants ; and so on. After each endosymbiosis, the partners eventually eliminated unproductive duplication of genetic functions by re-arranging their genomes,

387-555: A Mid-Devonian cooling of around 5 °C (9 °F). The Late Devonian warmed to levels equivalent to the Early Devonian; while there is no corresponding increase in CO 2 concentrations, continental weathering increases (as predicted by warmer temperatures); further, a range of evidence, such as plant distribution, points to a Late Devonian warming. The climate would have affected the dominant organisms in reefs ; microbes would have been

516-446: A compartment for abiogenic processes. A genomic analysis supports this hypothesis as they found 355 genes that likely traced to LUCA upon 6.1 million sequenced prokaryotic genes. They reconstruct LUCA as a thermophilic anaerobe with a Wood-Ljungdahl pathway, implying an origin of life at white smokers. LUCA would also have exhibited other biochemical pathways such as gluconeogenesis , reverse incomplete Krebs cycle , glycolysis , and

645-457: A county in southwestern England, where a controversial argument in the 1830s over the age and structure of the rocks found throughout the county was resolved by adding the Devonian Period to the geological timescale. The Great Devonian Controversy was a lengthy debate between Roderick Murchison , Adam Sedgwick and Henry De la Beche over the naming of the period. Murchison and Sedgwick won

774-399: A different scenario a single last universal ancestor, e.g. a "first cell" or a first individual precursor cell has never existed. Instead, the early biochemical evolution of life led to diversification through the development of a multiphenotypical population of pre-cells from which the precursor cells ( protocells ) of the three domains of life emerged. Thus, the formation of cells was

903-622: A diverse ecosystem of reefs and marine life. Devonian marine deposits are particularly prevalent in the midwestern and northeastern United States. Devonian reefs also extended along the southeast edge of Laurussia, a coastline now corresponding to southern England , Belgium , and other mid-latitude areas of Europe. In the Early and Middle Devonian, the west coast of Laurussia was a passive margin with broad coastal waters, deep silty embayments, river deltas and estuaries, found today in Idaho and Nevada . In

1032-634: A left and a right side that are mirror images of each other, appeared by 555 Ma (million years ago). Ediacara biota appeared during the Ediacaran period, while vertebrates , along with most other modern phyla originated about 525 Ma during the Cambrian explosion . During the Permian period, synapsids , including the ancestors of mammals , dominated the land. The Permian–Triassic extinction event killed most complex species of its time, 252 Ma . During

1161-443: A long way to go, since theoretical and empirical approaches are only beginning to make contact with each other. Even the simplest members of the three modern domains of life use DNA to record their "recipes" and a complex array of RNA and protein molecules to "read" these instructions and use them for growth, maintenance and self-replication. The discovery that some RNA molecules can catalyze both their own replication and

1290-736: A low-latitude archipelago to the north of Gondwana. They were separated from the southern continent by an oceanic basin: the Paleo-Tethys . Although the western Paleo-Tethys Ocean had existed since the Cambrian, the eastern part only began to rift apart as late as the Silurian. This process accelerated in the Devonian. The eastern branch of the Paleo-Tethys was fully opened when South China and Annamia (a terrane equivalent to most of Indochina ), together as

1419-520: A massive extinction event . ( See Late Devonian extinction ). Primitive arthropods co-evolved with this diversified terrestrial vegetation structure. The evolving co-dependence of insects and seed plants that characterized a recognizably modern world had its genesis in the Late Devonian Epoch. The development of soils and plant root systems probably led to changes in the speed and pattern of erosion and sediment deposition. The rapid evolution of

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1548-480: A particular environment rapidly becomes dominant; and they can catalyze the formation of RNA molecules. Although this idea has not become the scientific consensus, it still has active supporters. Research in 2003 reported that montmorillonite could also accelerate the conversion of fatty acids into "bubbles" and that the "bubbles" could encapsulate RNA attached to the clay. These "bubbles" can then grow by absorbing additional lipids and then divide. The formation of

1677-577: A process which sometimes involved transfer of genes between them. Another hypothesis proposes that mitochondria were originally sulfur - or hydrogen -metabolising endosymbionts, and became oxygen-consumers later. On the other hand, mitochondria might have been part of eukaryotes' original equipment. There is a debate about when eukaryotes first appeared: the presence of steranes in Australian shales may indicate eukaryotes at 2.7 Ga; however, an analysis in 2008 concluded that these chemicals infiltrated

1806-409: A successive process. See § Metabolism first: Pre-cells, successive cellularisation , below. Life on Earth is based on carbon and water . Carbon provides stable frameworks for complex chemicals and can be easily extracted from the environment, especially from carbon dioxide . There is no other chemical element whose properties are similar enough to carbon's to be called an analogue; silicon ,

1935-638: A terrestrial ecosystem that contained copious animals opened the way for the first vertebrates to seek terrestrial living. By the end of the Devonian, arthropods were solidly established on the land. The Late Devonian extinction is not a single event, but rather is a series of pulsed extinctions at the Givetian-Frasnian boundary, the Frasnian-Famennian boundary, and the Devonian-Carboniferous boundary. Together, these are considered one of

2064-527: A unified continent, detached from the northeastern sector of Gondwana. Nevertheless, they remained close enough to Gondwana that their Devonian fossils were more closely related to Australian species than to north Asian species. Other Asian terranes remained attached to Gondwana, including Sibumasu (western Indochina), Tibet, and the rest of the Cimmerian blocks. While the South China-Annamia continent

2193-533: A very small percentage of species have been identified: one estimate claims that Earth may have 1 trillion species, because "identifying every microbial species on Earth presents a huge challenge." Only 1.75–1.8 million species have been named and 1.8 million documented in a central database. The currently living species represent less than one percent of all species that have ever lived on Earth. The oldest meteorite fragments found on Earth are about 4.54 billion years old; this, coupled primarily with

2322-582: A volcanically active region during the Devonian, as it continued to assimilate smaller island arcs. The island arcs of the region, such as the Balkhash-West Junggar Arc, exhibited biological endemism as a consequence of their location. Siberia was located just north of the equator as the largest landmass in the Northern Hemisphere. At the beginning of the Devonian, Siberia was inverted (upside down) relative to its modern orientation. Later in

2451-966: Is an excellent solvent and has two other useful properties: the fact that ice floats enables aquatic organisms to survive beneath it in winter; and its molecules have electrically negative and positive ends, which enables it to form a wider range of compounds than other solvents can. Other good solvents, such as ammonia , are liquid only at such low temperatures that chemical reactions may be too slow to sustain life, and lack water's other advantages. Organisms based on alternative biochemistry may, however, be possible on other planets. Research on how life might have emerged from non-living chemicals focuses on three possible starting points: self-replication , an organism's ability to produce offspring that are very similar to itself; metabolism, its ability to feed and repair itself; and external cell membranes , which allow food to enter and waste products to leave, but exclude unwanted substances. Research on abiogenesis still has

2580-667: Is formally broken into Early, Middle and Late subdivisions. The rocks corresponding to those epochs are referred to as belonging to the Lower, Middle and Upper parts of the Devonian System. The Early Devonian lasted from 419.2 to 393.3 Ma. It began with the Lochkovian Stage 419.2 to 410.8 Ma, which was followed by the Pragian from 410.8 to 407.6 Ma and then by the Emsian , which lasted until

2709-592: Is further evidence of possibly the oldest forms of life in the form of fossilized microorganisms in hydrothermal vent precipitates from the Nuvvuagittuq Belt , that may have lived as early as 4.28 billion years ago, not long after the oceans formed 4.4 billion years ago, and after the Earth formed 4.54 billion years ago. These earliest fossils, however, may have originated from non-biological processes. Microbial mats of coexisting bacteria and archaea were

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2838-572: Is good evidence that Rheic oceanic crust experienced intense subduction and metamorphism under Mexico and Central America. The closure of the eastern part of the Rheic Ocean is associated with the assemblage of central and southern Europe. In the early Paleozoic, much of Europe was still attached to Gondwana, including the terranes of Iberia , Armorica (France), Palaeo-Adria (the western Mediterranean area), Bohemia , Franconia , and Saxothuringia . These continental blocks, collectively known as

2967-553: Is now a deserted open-pit pyrite mine in Alentejo , Portugal . Devonian The Devonian ( / d ə ˈ v oʊ n i . ən , d ɛ -/ də- VOH -nee-ən, deh- ) is a geologic period and system of the Paleozoic era during the Phanerozoic eon , spanning 60.3 million years from the end of the preceding Silurian period at 419.2 million years ago ( Ma ), to

3096-430: Is observed in many of those plants. Some of the early land plants such as Drepanophycus likely spread by vegetative growth and spores. The earliest land plants such as Cooksonia consisted of leafless, dichotomous axes with terminal sporangia and were generally very short-statured, and grew hardly more than a few centimetres tall. Fossils of Armoricaphyton chateaupannense , about 400 million years old, represent

3225-446: Is sequestered into calcium carbonate ( calcite ), phosphate concentrations are able to increase to levels necessary for facilitating biomolecule creation. Though carbonate-rich lakes have alkaline chemistry in modern times, models suggest that carbonate lakes had a pH low enough for prebiotic synthesis when placed in the acidifying context of Earth's early carbon dioxide rich atmosphere . Rainwater rich in carbonic acid weathered

3354-477: Is shown in the adjacent figure, where important evolutionary improvements are indicated by numbers. Wet-dry cycles at geothermal springs are shown to solve the problem of hydrolysis and promote the polymerization and vesicle encapsulation of biopolymers. The temperatures of geothermal springs are suitable for biomolecules. Silica minerals and metal sulfides in these environments have photocatalytic properties to catalyze biomolecules. Solar UV exposure also promotes

3483-402: Is solved in carbonate -rich environments. When in the presence of carbonate, calcium readily reacts to form calcium carbonate instead of apatite minerals. With the free calcium ions removed from solution , phosphate ions are no longer precipitated from solution. This is specifically seen in lakes with no inflow, since no new calcium is introduced into the water body. After all of the calcium

3612-453: Is that the Earth and Moon started to coalesce at the same time but the Earth, having a much stronger gravity than the early Moon, attracted almost all the iron particles in the area. Until 2001, the oldest rocks found on Earth were about 3.8 billion years old, leading scientists to estimate that the Earth's surface had been molten until then. Accordingly, they named this part of Earth's history

3741-398: Is water, which is much more plentiful than the geologically produced reducing agents required by the earlier non-oxygenic photosynthesis. From this point onwards life itself produced significantly more of the resources it needed than did geochemical processes. Oxygen became a significant component of Earth's atmosphere about 2.4 Ga. Although eukaryotes may have been present much earlier,

3870-510: The Hadean . However, analysis of zircons formed 4.4 Ga indicates that Earth's crust solidified about 100 million years after the planet's formation and that the planet quickly acquired oceans and an atmosphere , which may have been capable of supporting life. Evidence from the Moon indicates that from 4 to 3.8 Ga it suffered a Late Heavy Bombardment by debris that was left over from the formation of

3999-645: The Hadley cell and the Ferrel cell . In these near-deserts, the Old Red Sandstone sedimentary beds formed, made red by the oxidised iron ( hematite ) characteristic of drought conditions. The abundance of red sandstone on continental land also lends Laurussia the name "the Old Red Continent". For much of the Devonian, the majority of western Laurussia (North America) was covered by subtropical inland seas which hosted

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4128-516: The Ordovician period. Fishes , especially jawed fish , reached substantial diversity during this time, leading the Devonian to often be dubbed the Age of Fishes . The armored placoderms began dominating almost every known aquatic environment. In the oceans, cartilaginous fishes such as primitive sharks became more numerous than in the Silurian and Late Ordovician . Tetrapodomorphs , which include

4257-473: The Paleo-Tethys Ocean and Rheic Ocean . By the early Devonian, the continent Laurussia (also known as Euramerica ) was fully formed through the collision of the continents Laurentia (modern day North America) and Baltica (modern day northern and eastern Europe). The tectonic effects of this collision continued into the Devonian, producing a string of mountain ranges along the southeastern coast of

4386-680: The Solar System , and the Earth should have experienced an even heavier bombardment due to its stronger gravity. While there is no direct evidence of conditions on Earth 4 to 3.8 Ga, there is no reason to think that the Earth was not also affected by this late heavy bombardment. This event may well have stripped away any previous atmosphere and oceans; in this case gases and water from comet impacts may have contributed to their replacement, although outgassing from volcanoes on Earth would have supplied at least half. However, if subsurface microbial life had evolved by this point, it would have survived

4515-423: The cladoxylopsids and progymnosperm Archaeopteris . These tracheophytes were able to grow to large size on dry land because they had evolved the ability to biosynthesize lignin , which gave them physical rigidity and improved the effectiveness of their vascular system while giving them resistance to pathogens and herbivores. In Eifelian age, cladoxylopsid trees formed the first forests in Earth history. By

4644-588: The domain Archea and finally to the domain Eucarya . For the development of cells ( cellularisation ), the pre-cells had to be protected from their surroundings by envelopes (i.e. membranes, walls). For instance, the development of rigid cell walls by the invention of peptidoglycan in bacteria (domain Bacteria) may have been a prerequisite for their successful survival, radiation and colonisation of virtually all habitats of

4773-477: The endosymbiont mitochondria provided a more abundant source of biological energy . Around 1.6 Ga, some eukaryotes gained the ability to photosynthesize via endosymbiosis with cyanobacteria, and gave rise to various algae that eventually overtook cyanobacteria as the dominant primary producers . At around 1.7 Ga, multicellular organisms began to appear, with differentiated cells performing specialised functions. While early organisms reproduced asexually ,

4902-508: The pentose phosphate pathway , including biochemical reactions such as reductive amination and transamination . The Panspermia hypothesis does not explain how life arose originally, but simply examines the possibility of its coming from somewhere other than Earth. The idea that life on Earth was "seeded" from elsewhere in the Universe dates back at least to the Greek philosopher Anaximander in

5031-452: The " Big Five " mass extinctions in Earth's history. The Devonian extinction crisis primarily affected the marine community, and selectively affected shallow warm-water organisms rather than cool-water organisms. The most important group to be affected by this extinction event were the reef-builders of the great Devonian reef systems. Amongst the severely affected marine groups were the brachiopods, trilobites, ammonites, and acritarchs , and

5160-619: The Armorican Terrane Assemblage, split away from Gondwana in the Silurian and drifted towards Laurussia through the Devonian. Their collision with Laurussia leads to the beginning of the Variscan Orogeny , a major mountain-building event which would escalate further in the Late Paleozoic. Franconia and Saxothuringia collided with Laurussia near the end of the Early Devonian, pinching out the easternmost Rheic Ocean. The rest of

5289-524: The Armorican terranes followed, and by the end of the Devonian they were fully connected with Laurussia. This sequence of rifting and collision events led to the successive creation and destruction of several small seaways, including the Rheno-Hercynian, Saxo-Thuringian, and Galicia-Moldanubian oceans. Their sediments were eventually compressed and completely buried as Gondwana fully collided with Laurussia in

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5418-567: The Carboniferous. Sea levels in the Devonian were generally high. Marine faunas continued to be dominated by conodonts, bryozoans , diverse and abundant brachiopods , the enigmatic hederellids , microconchids , and corals . Lily-like crinoids (animals, their resemblance to flowers notwithstanding) were abundant, and trilobites were still fairly common. Bivalves became commonplace in deep water and outer shelf environments. The first ammonites also appeared during or slightly before

5547-595: The Carboniferous. In 19th-century texts the Devonian has been called the "Old Red Age", after the red and brown terrestrial deposits known in the United Kingdom as the Old Red Sandstone in which early fossil discoveries were found. Another common term is "Age of the Fishes", referring to the evolution of several major groups of fish that took place during the period. Older literature on the Anglo-Welsh basin divides it into

5676-476: The Devonian extinction events were caused by an asteroid impact. However, while there were Late Devonian collision events (see the Alamo bolide impact ), little evidence supports the existence of a large enough Devonian crater. History of life#Colonization of land The history of life on Earth traces the processes by which living and extinct organisms evolved, from the earliest emergence of life to

5805-408: The Devonian seas. The first abundant genus of cartilaginous fish, Cladoselache , appeared in the oceans during the Devonian Period. The great diversity of fish around at the time has led to the Devonian being given the name "The Age of Fishes" in popular culture. The Devonian saw significant expansion in the diversity of nektonic marine life driven by the abundance of planktonic microorganisms in

5934-639: The Downtonian, Dittonian, Breconian, and Farlovian stages, the latter three of which are placed in the Devonian. The Devonian has also erroneously been characterised as a "greenhouse age", due to sampling bias : most of the early Devonian-age discoveries came from the strata of western Europe and eastern North America , which at the time straddled the Equator as part of the supercontinent of Euramerica where fossil signatures of widespread reefs indicate tropical climates that were warm and moderately humid. In fact

6063-451: The Early Devonian and the existence of fossils such as Protichnites suggest that amphibious arthropods may have appeared as early as the Cambrian ). By far the largest land organism at the beginning of this period was the enigmatic Prototaxites , which was possibly the fruiting body of an enormous fungus, rolled liverwort mat, or another organism of uncertain affinities that stood more than 8 metres (26 ft) tall, and towered over

6192-551: The Industrial Revolution it intensified again, especially from the late nineteenth century when dozens of mines operated, primarily producing pyrite. Removal of sulfur remained significant until the 1950s because of its application in the chemical industry (production of sulfuric acid ). At present, this mining area is in decline. The economic viability depends on the extraction of copper, zinc, lead and, in some cases, precious metals like gold and silver. The São Domingos Mine

6321-672: The Late Devonian the tectonic situation had relaxed and much of South America was covered by shallow seas. These south polar seas hosted a distinctive brachiopod fauna, the Malvinokaffric Realm, which extended eastward to marginal areas now equivalent to South Africa and Antarctica. Malvinokaffric faunas even managed to approach the South Pole via a tongue of Panthalassa which extended into the Paraná Basin . The northern rim of Gondwana

6450-487: The Late Devonian, an approaching volcanic island arc reached the steep slope of the continental shelf and began to uplift deep water deposits. This minor collision sparked the start of a mountain-building episode called the Antler orogeny , which extended into the Carboniferous. Mountain building could also be found in the far northeastern extent of the continent, as minor tropical island arcs and detached Baltic terranes re-join

6579-652: The Late Devonian. The Altai-Sayan region was shaken by volcanism in the Early and Middle Devonian, while Late Devonian magmatism was magnified further to produce the Vilyuy Traps , flood basalts which may have contributed to the Late Devonian Mass Extinction. The last major round of volcanism, the Yakutsk Large Igneous Province, continued into the Carboniferous to produce extensive kimberlite deposits. Similar volcanic activity also affected

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6708-490: The Middle Devonian began, 393.3 Ma. During this time, the first ammonoids appeared, descending from bactritoid nautiloids . Ammonoids during this time period were simple and differed little from their nautiloid counterparts. These ammonoids belong to the order Agoniatitida , which in later epochs evolved to new ammonoid orders, for example Goniatitida and Clymeniida . This class of cephalopod molluscs would dominate

6837-583: The Portuguese Castro Verde territory. A mining transportation route that existed between the mines of Aljustrel 20 km to the north and the port city of Mértola 40 km to the east, is situated on the Guadiana river . The Sao Domingos Mine and Ríotinto mines accounted for one of the bases of the economy in the area. While in the Middle Ages there was a decline in the mining industry, in

6966-619: The Silurian and Devonian, it decreased across the span of the Devonian, particularly during the Pragian, and that the overall diversity of nektonic taxa did not increase significantly during the Devonian compared to during other geologic periods, and was in fact higher during the intervals spanning from the Wenlock to the Lochkovian and from the Carboniferous to the Permian. The study's authors instead attribute

7095-415: The ability to tolerate and then to use oxygen, possibly via endosymbiosis , where one organism lives inside another and both of them benefit from their association. Cyanobacteria have the most complete biochemical "toolkits" of all the mat-forming organisms. Hence they are the most self-sufficient, well-adapted to strike out on their own both as floating mats and as the first of the phytoplankton , provide

7224-488: The ancestors of all four- limbed vertebrates (i.e. tetrapods ), began diverging from freshwater lobe-finned fish as their more robust and muscled pectoral and pelvic fins gradually evolved into forelimbs and hindlimbs , though they were not fully established for life on land until the Late Carboniferous . The first ammonites , a subclass of cephalopod molluscs , appeared. Trilobites , brachiopods and

7353-538: The area played a significant role in the expansion of Roman metallurgy . During the Roman period, extensive mining and storage of valuable minerals required protective fortifications and mineral warehouses. This physiographic region contains many areas that contain large concentrations of ore and areas of extreme environmental conditions such as the Rio Tinto River . There are remains of more than 20 such small structures in

7482-762: The assembly of vesicles. Exergonic reactions at hydrothermal vents are suggested to have been a source of free energy that promoted chemical reactions, synthesis of organic molecules, and are inducive to chemical gradients. In small rock pore systems, membranous structures between alkaline seawater and the acidic ocean would be conducive to natural proton gradients. Nucleobase synthesis could occur by following universally conserved biochemical pathways by using metal ions as catalysts. RNA molecules of 22 bases can be polymerized in alkaline hydrothermal vent pores. Thin pores are shown to only accumulate long polynucleotides whereas thick pores accumulate both short and long polynucleotides. Small mineral cavities or mineral gels could have been

7611-496: The atmosphere, leading to the Great Oxygenation Event around 2.4 Ga. The earliest evidence of eukaryotes (complex cells with organelles ) dates from 1.85 Ga, likely due to symbiogenesis between anaerobic archaea and aerobic proteobacteria in co-adaptation against the new oxidative stress . While eukaryotes may have been present earlier, their diversification accelerated when aerobic cellular respiration by

7740-428: The basis of most marine food chains. Eukaryotes may have been present long before the oxygenation of the atmosphere, but most modern eukaryotes require oxygen, which is used by their mitochondria to fuel the production of ATP , the internal energy supply of all known cells. In the 1970s, a vigorous debate concluded that eukaryotes emerged as a result of a sequence of endosymbiosis between prokaryotes . For example:

7869-406: The beginning and end of which are marked with extinction events. This lasted until the end of the Devonian, 358.9 Ma. The Devonian was a relatively warm period, although significant glaciers may have existed during the Early and Middle Devonian. The temperature gradient from the equator to the poles was not as large as it is today. The weather was also very arid, mostly along the equator where it

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7998-568: The beginning of the succeeding Carboniferous period at 358.9 Ma. It is the fourth period of both the Paleozoic and the Phanerozoic. It is named after Devon , South West England , where rocks from this period were first studied. The first significant evolutionary radiation of life on land occurred during the Devonian, as free- sporing land plants ( pteridophytes ) began to spread across dry land , forming extensive coal forests which covered

8127-512: The belt. From the eighth century BC, there was mining in the area but it was the Romans who exploited the mines with greater intensity, thanks to its strategic position in the Mediterranean. This southern area of Lusitania , a Roman province for several centuries, was an abundant source of mineral ore which included gold , silver , copper , tin , lead , and iron . Given its mineral riches,

8256-464: The bombardment. The earliest identified organisms were minute and relatively featureless, and their fossils looked like small rods that are very difficult to tell apart from structures that arise through abiotic physical processes. The oldest undisputed evidence of life on Earth, interpreted as fossilized bacteria, dates to 3 Ga. Other finds in rocks dated to about 3.5 Ga have been interpreted as bacteria, with geochemical evidence also seeming to show

8385-427: The bottom layer is oxygen-free and often dominated by hydrogen sulfide emitted by the organisms living there. Oxygen is toxic to organisms that are not adapted to it, but greatly increases the metabolic efficiency of oxygen-adapted organisms; oxygenic photosynthesis by bacteria in mats increased biological productivity by a factor of between 100 and 1,000. The source of hydrogen atoms used by oxygenic photosynthesis

8514-574: The capabilities of individual organisms. Ribozymes remain as the main components of ribosomes , the "protein factories" in modern cells. Evidence suggests the first RNA molecules formed on Earth prior to 4.17 Ga. Although short self-replicating RNA molecules have been artificially produced in laboratories, doubts have been raised about whether natural non-biological synthesis of RNA is possible. The earliest "ribozymes" may have been formed of simpler nucleic acids such as PNA , TNA or GNA , which would have been replaced later by RNA. In 2003, it

8643-466: The climate in the Devonian differed greatly during its epochs and between geographic regions. For example, during the Early Devonian, arid conditions were prevalent through much of the world including Siberia, Australia, North America, and China, but Africa and South America had a warm temperate climate . In the Late Devonian, by contrast, arid conditions were less prevalent across the world and temperate climates were more common. The Devonian Period

8772-534: The construction of proteins led to the hypothesis of earlier life-forms based entirely on RNA. These ribozymes could have formed an RNA world in which there were individuals but no species, as mutations and horizontal gene transfers would have meant that offspring were likely to have different genomes from their parents, and evolution occurred at the level of genes rather than organisms. RNA would later have been replaced by DNA, which can build longer, more stable genomes, strengthening heritability and expanding

8901-515: The continent. Deformed remnants of these mountains can still be found on Ellesmere Island and Svalbard . Many of the Devonian collisions in Laurussia produce both mountain chains and foreland basins , which are frequently fossiliferous. Gondwana was by far the largest continent on the planet. It was completely south of the equator, although the northeastern sector (now Australia) did reach tropical latitudes. The southwestern sector (now South America)

9030-703: The continent. In present-day eastern North America, the Acadian Orogeny continued to raise the Appalachian Mountains . Further east, the collision also extended the rise of the Caledonian Mountains of Great Britain and Scandinavia . As the Caledonian Orogeny wound down in the later part of the period, orogenic collapse facilitated a cluster of granite intrusions in Scotland. Most of Laurussia

9159-657: The continents. By the middle of the Devonian, several groups of vascular plants had evolved leaves and true roots , and by the end of the period the first seed -bearing plants ( pteridospermatophytes ) appeared. This rapid evolution and colonization process, which had begun during the Silurian, is known as the Silurian-Devonian Terrestrial Revolution . The earliest land animals , predominantly arthropods such as myriapods , arachnids and hexapods , also became well-established early in this period, after beginning their colonization of land at least from

9288-624: The continuous exposure to sunlight as well as their cell walls with ion pumps to maintain their intracellular metabolism after they entered the oceans. Catalytic mineral particles and transition metal sulfides at these environments are capable of catalyzing organic compounds. Scientists simulated laboratory conditions that were identical to white smokers and successfully oligomerized RNA, measured to be 4 units long. Long chain fatty acids can be synthesized via Fischer-Tropsch synthesis . Another experiment that replicated conditions also similar white smokers, with long chain fatty acids present resulted in

9417-479: The cytoplasm of modern cells. Fatty acids in acidic or slightly alkaline geothermal springs assemble into vesicles after wet-dry cycles as there is a lower concentration of ionic solutes at geothermal springs since they are freshwater environments, in contrast to seawater which has a higher concentration of ionic solutes. For organic compounds to be present at geothermal springs, they would have likely been transported by carbonaceous meteors. The molecules that fell from

9546-416: The dating of ancient lead deposits, has put the estimated age of Earth at around that time. The Moon has the same composition as Earth's crust but does not contain an iron -rich core like the Earth's. Many scientists think that about 40 million years after the formation of Earth, it collided with a body the size of Mars , throwing crust material into the orbit that formed the Moon. Another hypothesis

9675-653: The debate and named it the Devonian System. While the rock beds that define the start and end of the Devonian Period are well identified, the exact dates are uncertain. According to the International Commission on Stratigraphy , the Devonian extends from the end of the Silurian 419.2 Ma, to the beginning of the Carboniferous 358.9 Ma – in North America , at the beginning of the Mississippian subperiod of

9804-461: The development of a multiphenotypical population of pre-cells , i.e. evolving entities of primordial life with different characteristics and widespread horizontal gene transfer . From this pre-cell population the founder groups A, B, C and then, from them, the precursor cells (here named proto-cells) of the three domains of life arose successively, leading first to the domain Bacteria , then to

9933-404: The dominant form of life in the early Archean eon, and many of the major steps in early evolution are thought to have taken place in this environment. The evolution of photosynthesis by cyanobacteria , around 3.5 Ga, eventually led to a buildup of its waste product, oxygen , in the oceans. After free oxygen saturated all available reductant substances on the Earth's surface , it built up in

10062-694: The earliest terrestrial ecosystems at least 2.7 Ga, the evolution of plants from freshwater green algae dates back to about 1 billion years ago. Microorganisms are thought to have paved the way for the inception of land plants in the Ordovician period. Land plants were so successful that they are thought to have contributed to the Late Devonian extinction event as early tree Archaeopteris drew down CO 2 levels, leading to global cooling and lowered sea levels, while their roots increased rock weathering and nutrient run-offs which may have triggered algal bloom anoxic events . Bilateria , animals having

10191-451: The earliest cells may have been aided by similar processes. A similar hypothesis presents self-replicating iron-rich clays as the progenitors of nucleotides , lipids and amino acids . A series of experiments starting in 1997 showed that early stages in the formation of proteins from inorganic materials including carbon monoxide and hydrogen sulfide could be achieved by using iron sulfide and nickel sulfide as catalysts . Most of

10320-405: The early Devonian Period around 400  Ma. Bactritoids make their first appearance in the Early Devonian as well; their radiation, along with that of ammonoids, has been attributed by some authors to increased environmental stress resulting from decreasing oxygen levels in the deeper parts of the water column. Among vertebrates, jawless armored fish ( ostracoderms ) declined in diversity, while

10449-459: The ecosystems and completed the extinction of all calcite sponge reefs and placoderms. Devonian palaeogeography was dominated by the supercontinent Gondwana to the south, the small continent of Siberia to the north, and the medium-sized continent of Laurussia to the east. Major tectonic events include the closure of the Rheic Ocean , the separation of South China from Gondwana, and

10578-481: The element directly below carbon on the periodic table , does not form very many complex stable molecules, and because most of its compounds are water-insoluble and because silicon dioxide is a hard and abrasive solid in contrast to carbon dioxide at temperatures associated with living things, it would be more difficult for organisms to extract. The elements boron and phosphorus have more complex chemistries but suffer from other limitations relative to carbon. Water

10707-545: The end of the Devonian, the first seed-forming plants had appeared. This rapid appearance of many plant groups and growth forms has been referred to as the Devonian Explosion or the Silurian-Devonian Terrestrial Revolution. The 'greening' of the continents acted as a carbon sink , and atmospheric concentrations of carbon dioxide may have dropped. This may have cooled the climate and led to

10836-470: The environment necessary for certain early fish to develop such essential characteristics as well developed lungs and the ability to crawl out of the water and onto the land for short periods of time. Finally, the Late Devonian started with the Frasnian , 382.7 to 372.2 Ma, during which the first forests took shape on land. The first tetrapods appeared in the fossil record in the ensuing Famennian subdivision,

10965-498: The external membranes of cells may have been an essential first step. Experiments that simulated the conditions of the early Earth have reported the formation of lipids, and these can spontaneously form liposomes , double-walled "bubbles", and then reproduce themselves. Although they are not intrinsically information-carriers as nucleic acids are, they would be subject to natural selection for longevity and reproduction. Nucleic acids such as RNA might then have formed more easily within

11094-481: The free water column as well as high ecological competition in benthic habitats, which were extremely saturated; this diversification has been labeled the Devonian Nekton Revolution by many researchers. However, other researchers have questioned whether this revolution existed at all; a 2018 study found that although the proportion of biodiversity constituted by nekton increased across the boundary between

11223-467: The geosphere and hydrosphere. This scenario may explain the quasi-random distribution of evolutionarily important features among the three domains and, at the same time, the existence of the most basic biochemical features (genetic code, set of protein amino acids etc.) in all three domains (unity of life), as well as the close relationship between the Archaea and the Eucarya. A scheme of the pre-cell scenario

11352-418: The great coral reefs were still common during the Devonian. The Late Devonian extinction , which started about 375 Ma, severely affected marine life, killing off most of the reef systems, most of the jawless fish, half of all placoderms, and nearly all trilobites save for a few species of the order Proetida . The subsequent end-Devonian extinction , which occurred at around 359 Ma, further impacted

11481-744: The increased overall diversity of nekton in the Devonian to a broader, gradual trend of nektonic diversification across the entire Palaeozoic. A now-dry barrier reef, located in present-day Kimberley Basin of northwest Australia , once extended 350 km (220 mi), fringing a Devonian continent. Reefs are generally built by various carbonate -secreting organisms that can erect wave-resistant structures near sea level. Although modern reefs are constructed mainly by corals and calcareous algae , Devonian reefs were either microbial reefs built up mostly by autotrophic cyanobacteria or coral-stromatoporoid reefs built up by coral-like stromatoporoids and tabulate and rugose corals . Microbial reefs dominated under

11610-403: The jawed fish (gnathostomes) simultaneously increased in both the sea and fresh water . Armored placoderms were numerous during the early ages of the Devonian Period and became extinct in the Late Devonian, perhaps because of competition for food against the other fish species. Early cartilaginous ( Chondrichthyes ) and bony fishes ( Osteichthyes ) also become diverse and played a large role within

11739-669: The lake - allowing the first prebiotic syntheses on Earth to occur. Microbial mats are multi-layered, multi-species colonies of bacteria and other organisms that are generally only a few millimeters thick, but still contain a wide range of chemical environments, each of which favors a different set of microorganisms. To some extent each mat forms its own food chain , as the by-products of each group of microorganisms generally serve as "food" for adjacent groups. Stromatolites are stubby pillars built as microorganisms in mats slowly migrate upwards to avoid being smothered by sediment deposited on them by water. There has been vigorous debate about

11868-420: The liposomes than outside. RNA is complex and there are doubts about whether it can be produced non-biologically in the wild. Some clays , notably montmorillonite , have properties that make them plausible accelerators for the emergence of an RNA world: they grow by self-replication of their crystalline pattern; they are subject to an analogue of natural selection, as the clay "species" that grows fastest in

11997-575: The low, carpet-like vegetation during the early part of the Devonian. Also, the first possible fossils of insects appeared around 416  Ma, in the Early Devonian. Evidence for the earliest tetrapods takes the form of trace fossils in shallow lagoon environments within a marine carbonate platform/shelf during the Middle Devonian, although these traces have been questioned and an interpretation as fish feeding traces ( Piscichnus ) has been advanced. Many Early Devonian plants did not have true roots or leaves like extant plants, although vascular tissue

12126-542: The main reef-forming organisms in warm periods, with corals and stromatoporoid sponges taking the dominant role in cooler times. The warming at the end of the Devonian may even have contributed to the extinction of the stromatoporoids. At the terminus of the Devonian, Earth rapidly cooled into an icehouse , marking the beginning of the Late Paleozoic icehouse . The Devonian world involved many continents and ocean basins of various sizes. The largest continent, Gondwana ,

12255-693: The marine fauna until the beginning of the Mesozoic Era. The Middle Devonian comprised two subdivisions: first the Eifelian , which then gave way to the Givetian 387.7 Ma. During this time the jawless agnathan fishes began to decline in diversity in freshwater and marine environments partly due to drastic environmental changes and partly due to the increasing competition, predation, and diversity of jawed fishes . The shallow, warm, oxygen-depleted waters of Devonian inland lakes, surrounded by primitive plants, provided

12384-406: The meteors were then accumulated in geothermal springs. Geothermal springs can accumulate aqueous phosphate in the form of phopshoric acid . Based on lab-run models, these concentrations of phoshate are insufficient to facilitate biosynthesis . As for the evolutionary implications, freshwater heterotrophic cells that depended upon synthesized organic compounds later evolved photosynthesis because of

12513-551: The most credible sources are Mars and Venus ; by alien visitors , possibly as a result of accidental contamination by microorganisms that they brought with them; and from outside the Solar System but by natural means. Experiments in low Earth orbit, such as EXOSTACK , have demonstrated that some microorganism spores can survive the shock of being catapulted into space and some can survive exposure to outer space radiation for at least 5.7 years. Meteorite ALH84001 , which

12642-411: The nearby microcontinent of Amuria (now Manchuria , Mongolia and their vicinities). Though certainly close to Siberia in the Devonian, the precise location of Amuria is uncertain due to contradictory paleomagnetic data. The Rheic Ocean, which separated Laurussia from Gondwana, was wide at the start of the Devonian, having formed after the drift of Avalonia away from Gondwana. It steadily shrunk as

12771-401: The oldest known plants with woody tissue. By the Middle Devonian, shrub-like forests of primitive plants existed: lycophytes , horsetails , ferns , and progymnosperms evolved. Most of these plants had true roots and leaves, and many were quite tall. The earliest-known trees appeared in the Middle Devonian. These included a lineage of lycopods and another arborescent, woody vascular plant,

12900-601: The origin of life since it is a critical component of nucleotides , phospholipids , and adenosine triphosphate . Phosphate is often depleted in natural environments due to its uptake by microbes and its affinity for calcium ions. In a process called ' apatite precipitation', free phosphate ions react with the calcium ions abundant in water to precipitate out of solution as apatite minerals. When attempting to simulate prebiotic phosphorylation , scientists have only found success when using phosphorus levels far above modern day natural concentrations. This problem of low phosphate

13029-522: The origin of life. Similar to the process predicted by geothermal hot spring hypotheses , changing lake levels and wave action deposited phosphorus-rich brine onto dry shore and marginal pools. This drying of the solution promotes polymerization reactions and removes enough water to promote phosphorylation, a process integral to biological energy storage and transfer. When washed away by further precipitation and wave action, researchers concluded these newly formed biomolecules may have washed back into

13158-445: The oxygenation of the atmosphere was a prerequisite for the evolution of the most complex eukaryotic cells, from which all multicellular organisms are built. The boundary between oxygen-rich and oxygen-free layers in microbial mats would have moved upwards when photosynthesis shut down overnight, and then downwards as it resumed on the next day. This would have created selection pressure for organisms in this intermediate zone to acquire

13287-403: The period continued, as the two major continents approached near the equator in the early stages of the assembly of Pangaea . The closure of the Rheic Ocean began in the Devonian and continued into the Carboniferous. As the ocean narrowed, endemic marine faunas of Gondwana and Laurussia combined into a single tropical fauna. The history of the western Rheic Ocean is a subject of debate, but there

13416-466: The period it moved northwards and began to twist clockwise, though it was not near its modern location. Siberia approached the eastern edge of Laurussia as the Devonian progressed, but it was still separated by a seaway, the Ural Ocean . Although Siberia's margins were generally tectonically stable and ecologically productive, rifting and deep mantle plumes impacted the continent with flood basalts during

13545-537: The presence of life 3.8 Ga. However, these analyses were closely scrutinized, and non-biological processes were found which could produce all of the "signatures of life" that had been reported. While this does not prove that the structures found had a non-biological origin, they cannot be taken as clear evidence for the presence of life. Geochemical signatures from rocks deposited 3.4 Ga have been interpreted as evidence for life. Evidence for fossilized microorganisms considered to be 3.77 billion to 4.28 billion years old

13674-680: The present day. Earth formed about 4.5 billion years ago (abbreviated as Ga , for gigaannum ) and evidence suggests that life emerged prior to 3.7 Ga. The similarities among all known present-day species indicate that they have diverged through the process of evolution from a common ancestor . The earliest clear evidence of life comes from biogenic carbon signatures and stromatolite fossils discovered in 3.7 billion-year-old metasedimentary rocks from western Greenland . In 2015, possible "remains of biotic life " were found in 4.1 billion-year-old rocks in Western Australia . There

13803-463: The primary method of reproduction for the vast majority of macroscopic organisms, including almost all eukaryotes (which includes animals and plants ), is sexual reproduction , the fusion of male and female reproductive cells ( gametes ) to create a zygote . The origin and evolution of sexual reproduction remain a puzzle for biologists, though it is thought to have evolved from a single-celled eukaryotic ancestor. While microorganisms formed

13932-575: The recovery from this catastrophe, archosaurs became the most abundant land vertebrates; one archosaur group, the dinosaurs , dominated the Jurassic and Cretaceous periods. After the Cretaceous–Paleogene extinction event 66 Ma killed off the non-avian dinosaurs, mammals increased rapidly in size and diversity . Such mass extinctions may have accelerated evolution by providing opportunities for new groups of organisms to diversify. Only

14061-552: The region led to eight giant volcanogenic massive sulfide ore deposits (VMS) associated with polymetallic massive flanks of volcanic cones in the form of pyrite , and also chalcopyrite , sphalerite , galena and cassiterite . The deposits of the Iberian Pyrite Belt are notable examples of volcanic- and sediment-hosted massive sulfide (VSHMS) deposits, which hybrids between the VMS and SEDEX deposits. Over 250 deposits are known in

14190-512: The resulting expansion of the Paleo-Tethys Ocean . The Devonian experienced several major mountain-building events as Laurussia and Gondwana approached; these include the Acadian Orogeny in North America and the beginning of the Variscan Orogeny in Europe. These early collisions preceded the formation of the single supercontinent Pangaea in the Late Paleozoic. The period is named after Devon ,

14319-417: The rock on the surface of the Earth at rates far greater than today. With high phosphate influx, no phosphate precipitation, and no microbial usage of phosphate at this time, models show phosphate reached concentrations approximately 100 times greater than they are today. Modeled pH and phosphate levels of early Earth carbonate-rich lakes nearly match the conditions used in current laboratory experiments on

14448-438: The rocks less than 2.2 Ga and prove nothing about the origins of eukaryotes. Fossils of the algae Grypania have been reported in 1.85 billion-year-old rocks (originally dated to 2.1 Ga but later revised ), indicating that eukaryotes with organelles had already evolved. A diverse collection of fossil algae were found in rocks dated between 1.5 and 1.4 Ga. The earliest known fossils of fungi date from 1.43 Ga. Plastids ,

14577-437: The sixth century BCE . In the twentieth century it was proposed by the physical chemist Svante Arrhenius , by the astronomers Fred Hoyle and Chandra Wickramasinghe , and by molecular biologist Francis Crick and chemist Leslie Orgel . There are three main versions of the "seeded from elsewhere" hypothesis: from elsewhere in our Solar System via fragments knocked into space by a large meteor impact, in which case

14706-423: The steps required temperatures of about 100 °C (212 °F) and moderate pressures, although one stage required 250 °C (482 °F) and a pressure equivalent to that found under 7 kilometres (4.3 mi) of rock. Hence it was suggested that self-sustaining synthesis of proteins could have occurred near hydrothermal vents. In this scenario, the biochemical evolution of life led to diversification through

14835-415: The superclass of organelles of which chloroplasts are the best-known exemplar, are thought to have originated from endosymbiotic cyanobacteria. The symbiosis evolved around 1.5 Ga and enabled eukaryotes to carry out oxygenic photosynthesis . Three evolutionary lineages of photosynthetic plastids have since emerged: chloroplasts in green algae and plants, rhodoplasts in red algae and cyanelles in

14964-407: The synthesis of biomolecules like RNA nucleotides. An analysis of hydrothermal veins at a 3.5 Gya (giga years ago or 1 billion years) geothermal spring setting were found to have elements required for the origin of life, which are potassium, boron, hydrogen, sulfur, phosphorus, zinc, nitrogen, and oxygen. Mulkidjanian and colleagues find that such environments have identical ionic concentrations to

15093-400: The validity of alleged stromatolite fossils from before 3 Ga, with critics arguing that they could have been formed by non-biological processes. In 2006, another find of stromatolites was reported from the same part of Australia, in rocks dated to 3.5 Ga. In modern underwater mats the top layer often consists of photosynthesizing cyanobacteria which create an oxygen-rich environment, while

15222-521: The warmer conditions of the early and late Devonian, while coral-stromatoporoid reefs dominated during the cooler middle Devonian. By the Devonian Period, life was well underway in its colonization of the land. The moss forests and bacterial and algal mats of the Silurian were joined early in the period by primitive rooted plants that created the first stable soils and harbored arthropods like mites , scorpions , trigonotarbids and myriapods (although arthropods appeared on land much earlier than in

15351-555: The world saw the disappearance of an estimated 96% of vertebrates like conodonts and bony fishes , and all of the ostracoderms and placoderms. Land plants as well as freshwater species, such as our tetrapod ancestors, were relatively unaffected by the Late Devonian extinction event (there is a counterargument that the Devonian extinctions nearly wiped out the tetrapods ). The reasons for the Late Devonian extinctions are still unknown, and all explanations remain speculative. Canadian paleontologist Digby McLaren suggested in 1969 that

15480-471: Was a time of great tectonic activity, as the major continents of Laurussia and Gondwana drew closer together. Sea levels were high worldwide, and much of the land lay under shallow seas, where tropical reef organisms lived. The enormous "world ocean", Panthalassa , occupied much of the Northern Hemisphere as well as wide swathes east of Gondwana and west of Laurussia. Other minor oceans were

15609-547: Was found in the Nuvvuagittuq Greenstone Belt in Quebec, Canada, although the evidence is disputed as inconclusive. Some biologists reason that all living organisms on Earth must share a single last universal ancestor , because it would be virtually impossible that two or more separate lineages could have independently developed the many complex biochemical mechanisms common to all living organisms. According to

15738-585: Was located entirely within the Southern Hemisphere . It corresponds to modern day South America , Africa , Australia , Antarctica , and India , as well as minor components of North America and Asia . The second-largest continent, Laurussia, was northwest of Gondwana, and corresponds to much of modern-day North America and Europe . Various smaller continents, microcontinents , and terranes were present east of Laurussia and north of Gondwana, corresponding to parts of Europe and Asia. The Devonian Period

15867-483: Was located south of the equator, but in the Devonian it moved northwards and began to rotate counterclockwise towards its modern position. While the most northern parts of the continent (such as Greenland and Ellesmere Island ) established tropical conditions, most of the continent was located within the natural dry zone along the Tropic of Capricorn , which (as nowadays) is a result of the convergence of two great air-masses,

15996-463: Was located to the far south, with Brazil situated near the South Pole . The northwestern edge of Gondwana was an active margin for much of the Devonian, and saw the accretion of many smaller land masses and island arcs. These include Chilenia , Cuyania , and Chaitenia , which now form much of Chile and Patagonia . These collisions were associated with volcanic activity and plutons , but by

16125-442: Was mostly a passive margin, hosting extensive marine deposits in areas such as northwest Africa and Tibet . The eastern margin, though warmer than the west, was equally active. Numerous mountain building events and granite and kimberlite intrusions affected areas equivalent to modern day eastern Australia , Tasmania , and Antarctica. Several island microcontinents (which would later coalesce into modern day Asia) stretched over

16254-491: Was once part of the Martian crust, shows evidence of carbonate-globules with texture and size indicative of terrestrial bacterial activity. Scientists are divided over the likelihood of life arising independently on Mars, or on other planets in our galaxy . One theory traces the origins of life to the abundant carbonate-rich lakes which would have dotted the early Earth . Phosphate would have been an essential cornerstone to

16383-411: Was proposed that porous metal sulfide precipitates would assist RNA synthesis at about 100 °C (212 °F) and ocean-bottom pressures near hydrothermal vents . Under this hypothesis, lipid membranes would be the last major cell components to appear and, until then, the protocells would be confined to the pores. It has been suggested that double-walled "bubbles" of lipids like those that form

16512-434: Was the driest. Reconstruction of tropical sea surface temperature from conodont apatite implies an average value of 30 °C (86 °F) in the Early Devonian. Early Devonian mean annual surface temperatures were approximately 16 °C. CO 2 levels dropped steeply throughout the Devonian Period. The newly evolved forests drew carbon out of the atmosphere, which were then buried into sediments. This may be reflected by

16641-560: Was the newest addition to the Asian microcontinents, it was not the first. North China and the Tarim Block (now northwesternmost China) were located westward and continued to drift northwards, powering over older oceanic crust in the process. Further west was a small ocean (the Turkestan Ocean), followed by the larger microcontinents of Kazakhstania , Siberia , and Amuria . Kazakhstania was

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