141-509: ICI Hillhouse was a chlorine -production facility in Lancashire , England. A division of Imperial Chemical Industries (ICI), it was active between 1941 and 1992. Its triangular footprint spread from the banks of the River Wyre at Stanah in the east, to Hillylaid Road in the southwest, to the southern edge of Fleetwood in the north. Its entrances were on Hillylaid Road (via the extant gate at
282-640: A salt works in China dates to approximately the same period. Salt was prized by the ancient Hebrews , Greeks , Romans , Byzantines , Hittites , Egyptians , and Indians . Salt became an important article of trade and was transported by boat across the Mediterranean Sea , along specially built salt roads , and across the Sahara on camel caravans . The scarcity and universal need for salt have led nations to go to war over it and use it to raise tax revenues. Salt
423-427: A 1:1 mixture of HCl and H 2 O, the system separates completely into two separate liquid phases. Hydrochloric acid forms an azeotrope with boiling point 108.58 °C at 20.22 g HCl per 100 g solution; thus hydrochloric acid cannot be concentrated beyond this point by distillation. Unlike hydrogen fluoride, anhydrous liquid hydrogen chloride is difficult to work with as a solvent, because its boiling point
564-430: A chlorine derivative of perchloric acid (HOClO 3 ), similar to the thermally unstable chlorine derivatives of other oxoacids: examples include chlorine nitrate (ClONO 2 , vigorously reactive and explosive), and chlorine fluorosulfate (ClOSO 2 F, more stable but still moisture-sensitive and highly reactive). Dichlorine hexoxide is a dark-red liquid that freezes to form a solid which turns yellow at −180 °C: it
705-414: A chlorofluorinating agent, adding chlorine and fluorine across a multiple bond or by oxidation: for example, it will attack carbon monoxide to form carbonyl chlorofluoride, COFCl. It will react analogously with hexafluoroacetone , (CF 3 ) 2 CO, with a potassium fluoride catalyst to produce heptafluoroisopropyl hypochlorite, (CF 3 ) 2 CFOCl; with nitriles RCN to produce RCF 2 NCl 2 ; and with
846-747: A dangerously powerful and unstable oxidizer. Near the end of the nineteenth century, E. S. Smith patented a method of sodium hypochlorite production involving electrolysis of brine to produce sodium hydroxide and chlorine gas, which then mixed to form sodium hypochlorite. This is known as the chloralkali process , first introduced on an industrial scale in 1892, and now the source of most elemental chlorine and sodium hydroxide. In 1884 Chemischen Fabrik Griesheim of Germany developed another chloralkali process which entered commercial production in 1888. Elemental chlorine solutions dissolved in chemically basic water (sodium and calcium hypochlorite ) were first used as anti- putrefaction agents and disinfectants in
987-438: A fertilizer, applying a moderate concentration helps avoid potential toxicity; typically, 1–3 grams (0.035–0.106 oz) per liter is considered safe and effective for most plants. Sodium chloride is one of the largest volume inorganic raw materials. It is a feedstock in the production of caustic soda and chlorine . These are used in the manufacture of PVC , paper pulp and many other inorganic and organic compounds. Salt
1128-445: A fluoride ion donor or acceptor (Lewis base or acid), although it does not dissociate appreciably into ClF 2 and ClF 4 ions. Chlorine pentafluoride (ClF 5 ) is made on a large scale by direct fluorination of chlorine with excess fluorine gas at 350 °C and 250 atm, and on a small scale by reacting metal chlorides with fluorine gas at 100–300 °C. It melts at −103 °C and boils at −13.1 °C. It
1269-443: A healthy level of sodium intake of between 4 and 5 grams (equivalent to 10-13 g salt) a day. One of the two most prominent dietary risks for disability in the world are diets high in sodium. Only a small percentage of the salt manufactured in the world is used in food. The remainder is used in agriculture, water treatment, chemical production, de-icing, and other industrial use cases. In the practice of watering plants with salt as
1410-422: A high sodium content and fill a similar role to table salt in western cultures. They are most often used for cooking rather than as table condiments. Human salt taste is detected by sodium taste receptors present in taste bud cells on the tongue. Human sensory taste testing studies have shown that proteolyzed forms of epithelial sodium channel (ENaC) function as the human salt taste receptor. Table salt
1551-464: A higher oxidation state than bromination with Br 2 when multiple oxidation states are available, such as in MoCl 5 and MoBr 3 . Chlorides can be made by reaction of an element or its oxide, hydroxide, or carbonate with hydrochloric acid, and then dehydrated by mildly high temperatures combined with either low pressure or anhydrous hydrogen chloride gas. These methods work best when the chloride product
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#17328515774551692-784: A low-pressure discharge tube. The yellow [Cl 3 ] cation is more stable and may be produced as follows: This reaction is conducted in the oxidising solvent arsenic pentafluoride . The trichloride anion, [Cl 3 ] , has also been characterised; it is analogous to triiodide . The three fluorides of chlorine form a subset of the interhalogen compounds, all of which are diamagnetic . Some cationic and anionic derivatives are known, such as ClF 2 , ClF 4 , ClF 2 , and Cl 2 F . Some pseudohalides of chlorine are also known, such as cyanogen chloride (ClCN, linear), chlorine cyanate (ClNCO), chlorine thiocyanate (ClSCN, unlike its oxygen counterpart), and chlorine azide (ClN 3 ). Chlorine monofluoride (ClF)
1833-510: A metaphor. Uses include the tale of how Lot's wife is turned into a pillar of salt when looking back at the cities of Sodom and Gomorrah as they are destroyed. In the New Testament , Jesus refers to his followers as the " salt of the earth ". In Aztec mythology, Huixtocihuatl was a fertility goddess who presided over salt and salt water. Salt is an auspicious substance in Hinduism and
1974-461: A mildly "fishy" or "sea-air" odour, the latter from organobromine compounds . Sediments, the proportion of which varies with the source, give the salt a dull grey appearance. Since taste and aroma compounds are often detectable by humans in minute concentrations, sea salt may have a more complex flavour than pure sodium chloride when sprinkled on top of food. When salt is added during cooking however, these flavours would likely be overwhelmed by those of
2115-519: A reduction in oxidation state , which can also be achieved by reducing a higher chloride using hydrogen or a metal as a reducing agent. This may also be achieved by thermal decomposition or disproportionation as follows: Most metal chlorides with the metal in low oxidation states (+1 to +3) are ionic. Nonmetals tend to form covalent molecular chlorides, as do metals in high oxidation states from +3 and above. Both ionic and covalent chlorides are known for metals in oxidation state +3 (e.g. scandium chloride
2256-408: A result of the increasing molecular weight of the halogens down the group, the density and heats of fusion and vaporisation of chlorine are again intermediate between those of bromine and fluorine, although all their heats of vaporisation are fairly low (leading to high volatility) thanks to their diatomic molecular structure. The halogens darken in colour as the group is descended: thus, while fluorine
2397-522: A salt spring in Lunca , Neamț County , Romania. Evidence indicates that Neolithic people of the Precucuteni Culture were boiling the salt-laden spring water through the process of briquetage to extract salt as far back as 6050 BC. The salt extracted from this operation may have directly correlated with the rapid growth of this society's population soon after production began. The harvest of salt from
2538-504: A salty bread or to add salt to the bread if this bread is unsalted when doing Kiddush for Shabbat . It is customary to spread some salt over the bread or to dip the bread in a little salt when passing the bread around the table after the Kiddush. To preserve the covenant between their people and God, Jews dip the Sabbath bread in salt. Salt plays a role within different Christian traditions. It
2679-426: A scrubbing agent when combined with oil. Salt is present in most foods , but in naturally occurring foodstuffs such as meats, vegetables and fruit, it is present in very small quantities. It is often added to processed foods (such as canned foods and especially salted foods , pickled foods , and snack foods or other convenience foods ), where it functions as both a preservative and a flavouring . Dairy salt
2820-482: A separate gaseous substance was recognised by the Brabantian chemist and physician Jan Baptist van Helmont . The element was first studied in detail in 1774 by Swedish chemist Carl Wilhelm Scheele , and he is credited with the discovery. Scheele produced chlorine by reacting MnO 2 (as the mineral pyrolusite ) with HCl: Scheele observed several of the properties of chlorine: the bleaching effect on litmus ,
2961-625: A solution of sodium carbonate. The resulting liquid, known as " Eau de Javel " (" Javel water "), was a weak solution of sodium hypochlorite . This process was not very efficient, and alternative production methods were sought. Scottish chemist and industrialist Charles Tennant first produced a solution of calcium hypochlorite ("chlorinated lime"), then solid calcium hypochlorite (bleaching powder). These compounds produced low levels of elemental chlorine and could be more efficiently transported than sodium hypochlorite, which remained as dilute solutions because when purified to eliminate water, it became
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#17328515774553102-505: A virtually inexhaustible source of salt, and this abundance of supply means that reserves have not been calculated. The evaporation of seawater is the production method of choice in marine countries with high evaporation and low precipitation rates. Salt evaporation ponds are filled from the ocean and salt crystals can be harvested as the water dries up. Sometimes these ponds have vivid colours, as some species of algae and other micro-organisms thrive in conditions of high salinity. Away from
3243-439: A yellow colour. Folic acid helps prevent neural tube defects and anaemia, which affect young mothers, especially in developing countries. A lack of fluoride in the diet is the cause of a greatly increased incidence of dental caries . Fluoride salts can be added to table salt with the goal of reducing tooth decay, especially in countries that have not benefited from fluoridated toothpastes and fluoridated water. The practice
3384-606: A £50 million agreement with ICI to create new housing, leisure, supermarket and shopping facilities on the Burn Naze portion of the land. Another section became the Hillhouse Enterprise Zone. A plaque beside the Thornton-Cleveleys War Memorial at Four Lane Ends honours ICI Hillhouse workers who served in the first and second World Wars. Poulton & Wyre Railway Society have placed a plaque honouring
3525-416: Is hydrogen chloride , HCl, a major chemical in industry as well as in the laboratory, both as a gas and dissolved in water as hydrochloric acid . It is often produced by burning hydrogen gas in chlorine gas, or as a byproduct of chlorinating hydrocarbons . Another approach is to treat sodium chloride with concentrated sulfuric acid to produce hydrochloric acid, also known as the "salt-cake" process: In
3666-441: Is sodium chlorate , mostly used to make chlorine dioxide to bleach paper pulp. The decomposition of chlorate to chloride and oxygen is a common way to produce oxygen in the laboratory on a small scale. Chloride and chlorate may comproportionate to form chlorine as follows: Perchlorates and perchloric acid (HOClO 3 ) are the most stable oxo-compounds of chlorine, in keeping with the fact that chlorine compounds are most stable when
3807-414: Is a chemical element ; it has symbol Cl and atomic number 17. The second-lightest of the halogens , it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent : among the elements, it has the highest electron affinity and
3948-423: Is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt . In the form of a natural crystalline mineral, salt is also known as rock salt or halite . Salt is essential for life in general (being the source of the essential dietary minerals sodium and chlorine ), and saltiness is one of the basic human tastes . Salt
4089-474: Is a pale yellow gas, chlorine is distinctly yellow-green. This trend occurs because the wavelengths of visible light absorbed by the halogens increase down the group. Specifically, the colour of a halogen, such as chlorine, results from the electron transition between the highest occupied antibonding π g molecular orbital and the lowest vacant antibonding σ u molecular orbital. The colour fades at low temperatures, so that solid chlorine at −195 °C
4230-399: Is a poor solvent, only able to dissolve small molecular compounds such as nitrosyl chloride and phenol , or salts with very low lattice energies such as tetraalkylammonium halides. It readily protonates electrophiles containing lone-pairs or π bonds. Solvolysis , ligand replacement reactions, and oxidations are well-characterised in hydrogen chloride solution: Nearly all elements in
4371-486: Is a very poor conductor of electricity, and indeed its conductivity is so low as to be practically unmeasurable. Chlorine has two stable isotopes, Cl and Cl. These are its only two natural isotopes occurring in quantity, with Cl making up 76% of natural chlorine and Cl making up the remaining 24%. Both are synthesised in stars in the oxygen-burning and silicon-burning processes . Both have nuclear spin 3/2+ and thus may be used for nuclear magnetic resonance , although
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4512-432: Is a very strong fluorinating agent, although it is still not as effective as chlorine trifluoride. Only a few specific stoichiometric reactions have been characterised. Arsenic pentafluoride and antimony pentafluoride form ionic adducts of the form [ClF 4 ] [MF 6 ] (M = As, Sb) and water reacts vigorously as follows: The product, chloryl fluoride , is one of the five known chlorine oxide fluorides. These range from
4653-442: Is a weak ligand, weaker than water, a few compounds involving coordinated ClO 4 are known. The Table below presents typical oxidation states for chlorine element as given in the secondary schools or colleges. There are more complex chemical compounds, the structure of which can only be explained using modern quantum chemical methods, for example, cluster technetium chloride [(CH 3 ) 4 N] 3 [Tc 6 Cl 14 ], in which 6 of
4794-681: Is about 10 g per day, and it is higher than that in many countries in Eastern Europe and Asia. The high level of sodium in many processed foods has a major impact on the total amount consumed. In the United States, 75% of the sodium eaten comes from processed and restaurant foods, 11% from cooking and table use and the rest from what is found naturally in foodstuffs. Because consuming too much sodium increases risk of cardiovascular diseases , health organizations generally recommend that people reduce their dietary intake of salt. High sodium intake
4935-501: Is almost colourless. Like solid bromine and iodine, solid chlorine crystallises in the orthorhombic crystal system , in a layered lattice of Cl 2 molecules. The Cl–Cl distance is 198 pm (close to the gaseous Cl–Cl distance of 199 pm) and the Cl···Cl distance between molecules is 332 pm within a layer and 382 pm between layers (compare the van der Waals radius of chlorine, 180 pm). This structure means that chlorine
5076-472: Is also produced when photolysing the solid at −78 °C: it is a dark brown solid that explodes below 0 °C. The ClO radical leads to the depletion of atmospheric ozone and is thus environmentally important as follows: Chlorine perchlorate (ClOClO 3 ) is a pale yellow liquid that is less stable than ClO 2 and decomposes at room temperature to form chlorine, oxygen, and dichlorine hexoxide (Cl 2 O 6 ). Chlorine perchlorate may also be considered
5217-469: Is an important micronutrient for humans, and a deficiency of the element can cause lowered production of thyroxine ( hypothyroidism ) and enlargement of the thyroid gland ( endemic goitre ) in adults or cretinism in children. Iodized salt has been used to correct these conditions since 1924 and consists of table salt mixed with a minute amount of potassium iodide , sodium iodide , or sodium iodate . A small amount of dextrose may be added to stabilize
5358-561: Is associated with a greater risk of stroke , total cardiovascular disease and kidney disease . A reduction in sodium intake by 1,000 mg per day may reduce cardiovascular disease by about 30 percent. In adults and children with no acute illness, a decrease in the intake of sodium from the typical high levels reduces blood pressure. A low sodium diet results in a greater improvement in blood pressure in people with hypertension . The World Health Organization recommends that adults should consume less than 2,000 mg of sodium (which
5499-420: Is contained in 5 g of salt) per day. Guidelines by the United States recommend that people with hypertension, African Americans, and middle-aged and older adults should limit consumption to no more than 1,500 mg of sodium per day and meet the potassium recommendation of 4,700 mg/day with a healthy diet of fruits and vegetables. While reduction of sodium intake to less than 2,300 mg per day
5640-419: Is dug out by the room and pillar method, where about half the material is left in place to support the upper levels. Extraction of Himalayan salt is expected to last 350 years at the present rate of extraction of around 385,000 tons per annum.The mine is also a major tourist attraction, receiving around a quarter of a million visitors a year. Salt has long held an important place in religion and culture. At
5781-693: Is either beneficial or harmful. Evidence shows a more complicated relationship between salt and cardiovascular disease. "The association between sodium consumption and cardiovascular disease or mortality is U-shaped, with increased risk at both high and low sodium intake." The findings showed that increased mortality from excessive salt intake was primarily associated with individuals with hypertension. The levels of increased mortality among those with restricted salt intake appeared to be similar regardless of blood pressure. This evidence shows that while those with hypertension should primarily focus on reducing sodium to recommended levels, all groups should seek to maintain
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5922-658: Is even more unstable and cannot be isolated or concentrated without decomposition: it is known from the decomposition of aqueous chlorine dioxide. However, sodium chlorite is a stable salt and is useful for bleaching and stripping textiles, as an oxidising agent, and as a source of chlorine dioxide. Chloric acid (HOClO 2 ) is a strong acid that is quite stable in cold water up to 30% concentration, but on warming gives chlorine and chlorine dioxide. Evaporation under reduced pressure allows it to be concentrated further to about 40%, but then it decomposes to perchloric acid, chlorine, oxygen, water, and chlorine dioxide. Its most important salt
6063-887: Is extremely dangerous, and poisonous to most living organisms. As a chemical warfare agent, chlorine was first used in World War ;I as a poison gas weapon. In the form of chloride ions , chlorine is necessary to all known species of life. Other types of chlorine compounds are rare in living organisms, and artificially produced chlorinated organics range from inert to toxic. In the upper atmosphere , chlorine-containing organic molecules such as chlorofluorocarbons have been implicated in ozone depletion . Small quantities of elemental chlorine are generated by oxidation of chloride ions in neutrophils as part of an immune system response against bacteria. The most common compound of chlorine, sodium chloride, has been known since ancient times; archaeologists have found evidence that rock salt
6204-551: Is extremely thermally stable, and is sold commercially in 500-gram steel lecture bottles. It is a colourless gas that melts at −155.6 °C and boils at −100.1 °C. It may be produced by the reaction of its elements at 225 °C, though it must then be separated and purified from chlorine trifluoride and its reactants. Its properties are mostly intermediate between those of chlorine and fluorine. It will react with many metals and nonmetals from room temperature and above, fluorinating them and liberating chlorine. It will also act as
6345-515: Is less reactive than fluorine and more reactive than bromine. It is also a weaker oxidising agent than fluorine, but a stronger one than bromine. Conversely, the chloride ion is a weaker reducing agent than bromide, but a stronger one than fluoride. It is intermediate in atomic radius between fluorine and bromine, and this leads to many of its atomic properties similarly continuing the trend from iodine to bromine upward, such as first ionisation energy , electron affinity , enthalpy of dissociation of
6486-442: Is less than +1.395 V, it would be expected that chlorine should be able to oxidise water to oxygen and hydrochloric acid. However, the kinetics of this reaction are unfavorable, and there is also a bubble overpotential effect to consider, so that electrolysis of aqueous chloride solutions evolves chlorine gas and not oxygen gas, a fact that is very useful for the industrial production of chlorine. The simplest chlorine compound
6627-479: Is low, it has a small liquid range, its dielectric constant is low and it does not dissociate appreciably into H 2 Cl and HCl 2 ions – the latter, in any case, are much less stable than the bifluoride ions ( HF 2 ) due to the very weak hydrogen bonding between hydrogen and chlorine, though its salts with very large and weakly polarising cations such as Cs and NR 4 (R = Me , Et , Bu ) may still be isolated. Anhydrous hydrogen chloride
6768-437: Is made by reacting anhydrous sodium perchlorate or barium perchlorate with concentrated hydrochloric acid, filtering away the chloride precipitated and distilling the filtrate to concentrate it. Anhydrous perchloric acid is a colourless mobile liquid that is sensitive to shock that explodes on contact with most organic compounds, sets hydrogen iodide and thionyl chloride on fire and even oxidises silver and gold. Although it
6909-534: Is made up of just under 40% sodium by weight, so a 6 g serving (1 teaspoon) contains about 2,400 mg of sodium. Sodium serves a vital purpose in the human body: via its role as an electrolyte, it helps nerves and muscles to function correctly, and it is one factor involved in the osmotic regulation of water content in body organs ( fluid balance ). Most of the sodium in the Western diet comes from salt. The habitual salt intake in many Western countries
7050-583: Is mandatory in the rite of the Tridentine Mass . Salt is used in the third item (which includes an Exorcism ) of the Celtic Consecration ( cf. Gallican Rite ) that is employed in the consecration of a church, and it is permitted to be added to the water "where it is customary" in the Roman Catholic rite of Holy water. The Bible makes multiple mentions of salt , both of the mineral itself and as
7191-547: Is more common in some European countries where water fluoridation is not carried out. In France , 35% of the table salt sold contains added sodium fluoride . Unrefined sea salt contains small amounts of magnesium and calcium halides and sulfates , traces of algal products , salt-resistant bacteria and sediment particles. The calcium and magnesium salts confer a faintly bitter overtone, and they make unrefined sea salt hygroscopic (i.e., it gradually absorbs moisture from air if stored uncovered). Algal products contribute
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#17328515774557332-409: Is mostly sodium chloride (NaCl). Sea salt and mined salt may contain trace elements . Mined salt is often refined. Salt crystals are translucent and cubic in shape; they normally appear white but impurities may give them a blue or purple tinge. When dissolved in water sodium chloride separates into Na and Cl ions, and the solubility is 359 grams per litre. From cold solutions, salt crystallises as
7473-427: Is mostly ionic, but aluminium chloride is not). Silver chloride is very insoluble in water and is thus often used as a qualitative test for chlorine. Although dichlorine is a strong oxidising agent with a high first ionisation energy, it may be oxidised under extreme conditions to form the [Cl 2 ] cation. This is very unstable and has only been characterised by its electronic band spectrum when produced in
7614-415: Is one of the most reactive elements. Chlorine is a weaker oxidising agent than fluorine but a stronger one than bromine or iodine. This can be seen from the standard electrode potentials of the X 2 /X couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At , approximately +0.3 V). However, this trend is not shown in the bond energies because fluorine
7755-427: Is one of the oldest and most ubiquitous food seasonings , and is known to uniformly improve the taste perception of food, including otherwise unpalatable food. Salting , brining , and pickling are ancient and important methods of food preservation . Some of the earliest evidence of salt processing dates to around 6000 BC, when people living in the area of present-day Romania boiled spring water to extract salts;
7896-428: Is prepared by roasting salt in a bamboo container plugged with mud at both ends. This product absorbs minerals from the bamboo and the mud, and has been claimed to increase the anticlastogenic and antimutagenic properties of doenjang (a fermented bean paste). Kosher or kitchen salt has a larger grain size than table salt and is used in cooking. It can be useful for brining , in bread or pretzel making, and as
8037-400: Is present in solid crystalline hydrogen chloride at low temperatures, similar to the hydrogen fluoride structure, before disorder begins to prevail as the temperature is raised. Hydrochloric acid is a strong acid (p K a = −7) because the hydrogen bonds to chlorine are too weak to inhibit dissociation. The HCl/H 2 O system has many hydrates HCl· n H 2 O for n = 1, 2, 3, 4, and 6. Beyond
8178-419: Is produced in the atmosphere by spallation of Ar by interactions with cosmic ray protons . In the top meter of the lithosphere , Cl is generated primarily by thermal neutron activation of Cl and spallation of K and Ca . In the subsurface environment, muon capture by Ca becomes more important as a way to generate Cl. Chlorine is intermediate in reactivity between fluorine and bromine, and
8319-401: Is quite slow at temperatures below 70 °C in spite of the very favourable equilibrium constant of 10 . The chlorate ions may themselves disproportionate to form chloride and perchlorate (4 ClO 3 ⇌ Cl + 3 ClO 4 ) but this is still very slow even at 100 °C despite the very favourable equilibrium constant of 10 . The rates of reaction for the chlorine oxyanions increases as
8460-435: Is recommended by developed countries, one review recommended that sodium intake be reduced to at least 1,200 mg (contained in 3 g of salt) per day, as a further reduction in salt intake led to a greater fall in systolic blood pressure for all age groups and ethnicities. Another review indicated that there is inconsistent/insufficient evidence to conclude that reducing sodium intake to lower than 2,300 mg per day
8601-543: Is refined by treatment with chemicals that precipitate most impurities (largely magnesium and calcium salts). Multiple stages of evaporation are then applied. Some salt is produced using the Alberger process , which involves vacuum pan evaporation combined with the seeding of the solution with cubic crystals, and produces a grainy-type flake. The Ayoreo , an indigenous group from the Paraguayan Chaco , obtain their salt from
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#17328515774558742-510: Is singular due to its small size, low polarisability, and inability to show hypervalence . As another difference, chlorine has a significant chemistry in positive oxidation states while fluorine does not. Chlorination often leads to higher oxidation states than bromination or iodination but lower oxidation states than fluorination. Chlorine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Cl bonds. Given that E°( 1 / 2 O 2 /H 2 O) = +1.229 V, which
8883-567: Is stable to hydrolysis; otherwise, the possibilities include high-temperature oxidative chlorination of the element with chlorine or hydrogen chloride, high-temperature chlorination of a metal oxide or other halide by chlorine, a volatile metal chloride, carbon tetrachloride , or an organic chloride. For instance, zirconium dioxide reacts with chlorine at standard conditions to produce zirconium tetrachloride , and uranium trioxide reacts with hexachloropropene when heated under reflux to give uranium tetrachloride . The second example also involves
9024-553: Is the anhydride of perchloric acid (HClO 4 ) and can readily be obtained from it by dehydrating it with phosphoric acid at −10 °C and then distilling the product at −35 °C and 1 mmHg. It is a shock-sensitive, colourless oily liquid. It is the least reactive of the chlorine oxides, being the only one to not set organic materials on fire at room temperature. It may be dissolved in water to regenerate perchloric acid or in aqueous alkalis to regenerate perchlorates. However, it thermally decomposes explosively by breaking one of
9165-430: Is the anhydride. It is thus an effective bleach and is mostly used to make hypochlorites . It explodes on heating or sparking or in the presence of ammonia gas. Chlorine dioxide (ClO 2 ) was the first chlorine oxide to be discovered in 1811 by Humphry Davy . It is a yellow paramagnetic gas (deep-red as a solid or liquid), as expected from its having an odd number of electrons: it is stable towards dimerisation due to
9306-409: Is used as a flux in the production of aluminium . For this purpose, a layer of melted salt floats on top of the molten metal and removes iron and other metal contaminants. It is used in the manufacture of soaps and glycerine , where it is used to saponify fats. As an emulsifier, salt is used in the manufacture of synthetic rubber , and another use is in the firing of pottery , when salt added to
9447-456: Is used extensively in cooking as a flavouring, and in cooking techniques such as with salt crusts and brining . The main sources of salt in the Western diet, apart from direct use, are bread and cereals, meat, and dairy products. In many East Asian cultures, salt is not traditionally used as a condiment. In its place, condiments such as soy sauce , fish sauce and oyster sauce tend to have
9588-460: Is used in ceremonies like house-warmings and weddings. In Jainism , devotees lay an offering of raw rice with a pinch of salt before a deity to signify their devotion and salt is sprinkled on a person's cremated remains before the ashes are buried. Salt is believed to ward off evil spirits in Mahayana Buddhist tradition, and when returning home from a funeral , a pinch of salt is thrown over
9729-441: Is used in many cuisines, and it is often found in salt shakers on diners' eating tables for their personal use on food. Salt is also an ingredient in many manufactured foodstuffs. Table salt is a refined salt containing about 97 to 99 percent sodium chloride . Usually, anticaking agents such as sodium aluminosilicate or magnesium carbonate are added to make it free-flowing. Iodized salt , containing potassium iodide ,
9870-477: Is used in religious ceremonies and has other cultural and traditional significance. Salt is processed from salt mines , and by the evaporation of seawater ( sea salt ) and mineral-rich spring water in shallow pools. The greatest single use for salt (sodium chloride) is as a feedstock for the production of chemicals. It is used to produce caustic soda and chlorine , and in the manufacture of products such as polyvinyl chloride , plastics , and paper pulp . Of
10011-617: Is used in the preparation of butter and cheese products. As a flavouring, salt enhances the taste of other foods by suppressing the bitterness of those foods making them more palatable and relatively sweeter. Before the advent of electrically powered refrigeration , salting was one of the main methods of food preservation . Thus, herring contains 67 mg sodium per 100 g, while kipper , its preserved form, contains 990 mg. Similarly, pork typically contains 63 mg while bacon contains 1,480 mg, and potatoes contain 7 mg but potato crisps 800 mg per 100 g. Salt
10152-472: Is usually made by reaction of chlorine dioxide with oxygen. Despite attempts to rationalise it as the dimer of ClO 3 , it reacts more as though it were chloryl perchlorate, [ClO 2 ] [ClO 4 ] , which has been confirmed to be the correct structure of the solid. It hydrolyses in water to give a mixture of chloric and perchloric acids: the analogous reaction with anhydrous hydrogen fluoride does not proceed to completion. Dichlorine heptoxide (Cl 2 O 7 )
10293-434: Is widely available. Some people put a desiccant , such as a few grains of uncooked rice or a saltine cracker , in their salt shakers to absorb extra moisture and help break up salt clumps that may otherwise form. Some table salt sold for consumption contains additives that address a variety of health concerns, especially in the developing world. The identities and amounts of additives vary from country to country. Iodine
10434-570: The Committee on Toxicity in 1988. Other anticaking agents sometimes used include tricalcium phosphate , calcium or magnesium carbonates, fatty acid salts ( acid salts ), magnesium oxide , silicon dioxide , calcium silicate , sodium aluminosilicate and calcium aluminosilicate . Both the European Union and the United States Food and Drug Administration permitted the use of aluminium in
10575-525: The Fleetwood branch line —was built to connect Burn Naze to Poulton-le-Fylde and beyond. The line still exists today, although the sidings at Burn Naze were removed after all freight traffic ceased in 1999. Water from the Lancaster Canal , beside Nateby Hall bridge, was extracted by ICI Hillhouse via a 25-year lease. Around 6,000 megalitres (1.3 million gallons ) of water was obtained. The boreholes
10716-613: The German word Salz , salt. Hallstatt was the site of the world's first salt mine . The town gave its name to the Hallstatt culture that began mining for salt in the area in about 800 BC. Around 400 BC, the townsfolk, who had previously used pickaxes and shovels , began open pan salt making . During the first millennium BC, Celtic communities grew rich trading salt and salted meat to Ancient Greece and Ancient Rome in exchange for wine and other luxuries. The word salary comes from
10857-672: The Latin word for salt. The reason for this is unknown; a persistent modern claim that the Roman Legions were sometimes paid in salt is baseless. The word salad literally means "salted", and comes from the ancient Roman practice of salting leaf vegetables . Wars have been fought over salt. Venice won a war with Genoa over the product, and it played a role in the American Revolution . Cities on overland trade routes grew rich by levying duties , and towns like Liverpool flourished on
10998-413: The dihydrate NaCl·2H 2 O. Solutions of sodium chloride have very different properties from those of pure water; the freezing point is −21.12 °C (−6.02 °F) for 23.31 wt% of salt, and the boiling point of saturated salt solution is around 108.7 °C (227.7 °F). Salt is essential to the health of humans and other animals, and it is one of the five basic taste sensations . Salt
11139-473: The neutron activation of natural chlorine. The most stable chlorine radioisotope is Cl. The primary decay mode of isotopes lighter than Cl is electron capture to isotopes of sulfur ; that of isotopes heavier than Cl is beta decay to isotopes of argon ; and Cl may decay by either mode to stable S or Ar. Cl occurs in trace quantities in nature as a cosmogenic nuclide in a ratio of about (7–10) × 10 to 1 with stable chlorine isotopes: it
11280-483: The noble gases xenon and radon do not escape fluorination. An impermeable fluoride layer is formed by sodium , magnesium , aluminium , zinc , tin , and silver , which may be removed by heating. Nickel , copper, and steel containers are usually used due to their great resistance to attack by chlorine trifluoride, stemming from the formation of an unreactive layer of metal fluoride. Its reaction with hydrazine to form hydrogen fluoride, nitrogen, and chlorine gases
11421-797: The obsidian trade in Anatolia in the Neolithic Era . Salt was included among funeral offerings found in ancient Egyptian tombs from the third millennium BC, as were salted birds, and salt fish. From about 2800 BC, the Egyptians began exporting salt fish to the Phoenicians in return for Lebanon cedar , glass, and the dye Tyrian purple ; the Phoenicians traded Egyptian salted fish and salt from North Africa throughout their Mediterranean trade empire. Herodotus described salt trading routes across Libya back in
11562-450: The tanning of hides, the preservation of meat and fish and the canning of meat and vegetables. Food-grade salt accounts for only a small part of salt production in industrialized countries (7% in Europe), although worldwide, food uses account for 17.5% of total production. In 2018, total world production of salt was 300 million tonnes , the top six producers being China (68 million),
11703-414: The 14 chlorine atoms are formally divalent, and oxidation states are fractional. In addition, all the above chemical regularities are valid for "normal" or close to normal conditions, while at ultra-high pressures (for example, in the cores of large planets), chlorine can exhibit an oxidation state of -3, forming a Na3Cl compound with sodium, which does not fit into traditional concepts of chemistry. Like
11844-535: The 1820s, in France, long before the establishment of the germ theory of disease . This practice was pioneered by Antoine-Germain Labarraque , who adapted Berthollet's "Javel water" bleach and other chlorine preparations. Elemental chlorine has since served a continuous function in topical antisepsis (wound irrigation solutions and the like) and public sanitation, particularly in swimming and drinking water. Chlorine gas
11985-598: The 5th century BC. In the early years of the Roman Empire, roads were built for the transportation of salt from the salt imported at Ostia to the capital. In Africa, salt was used as currency south of the Sahara, and slabs of rock salt were used as coins in Abyssinia . The Tuareg have traditionally maintained routes across the Sahara especially for the transportation of salt by Azalai (salt caravans). The caravans still cross
12126-521: The Earth's crust is in the form of ionic chloride compounds, which includes table salt. It is the second-most abundant halogen (after fluorine) and 20th most abundant element in Earth's crust. These crystal deposits are nevertheless dwarfed by the huge reserves of chloride in seawater. Elemental chlorine is commercially produced from brine by electrolysis , predominantly in the chloralkali process . The high oxidising potential of elemental chlorine led to
12267-537: The German and Dutch names of oxygen : sauerstoff or zuurstof , both translating into English as acid substance ), so a number of chemists, including Claude Berthollet , suggested that Scheele's dephlogisticated muriatic acid air must be a combination of oxygen and the yet undiscovered element, muriaticum . In 1809, Joseph Louis Gay-Lussac and Louis-Jacques Thénard tried to decompose dephlogisticated muriatic acid air by reacting it with charcoal to release
12408-487: The Greek word χλωρος ( chlōros , "green-yellow"), in reference to its colour. The name " halogen ", meaning "salt producer", was originally used for chlorine in 1811 by Johann Salomo Christoph Schweigger . This term was later used as a generic term to describe all the elements in the chlorine family (fluorine, bromine, iodine), after a suggestion by Jöns Jakob Berzelius in 1826. In 1823, Michael Faraday liquefied chlorine for
12549-457: The UK the recommended iodine content of iodized salt is 10–22 ppm. Sodium ferrocyanide , yellow prussiate of soda, is sometimes added to salt as an anticaking agent . Such anticaking agents have been added since at least 1911 when magnesium carbonate was first added to salt to make it flow more freely. The safety of sodium ferrocyanide as a food additive was found to be provisionally acceptable by
12690-490: The United States (42 million), India (29 million), Germany (13 million), Canada (13 million) and Australia (12 million). The manufacture of salt is one of the oldest chemical industries. A major source of salt is seawater, which has a salinity of approximately 3.5%. This means that there are about 35 g (1.2 oz) of dissolved salts , predominantly sodium ( Na ) and chloride ( Cl ) ions , per kilogram (2.2 lbs) of water. The world's oceans are
12831-496: The X 2 molecule (X = Cl, Br, I), ionic radius, and X–X bond length. (Fluorine is anomalous due to its small size.) All four stable halogens experience intermolecular van der Waals forces of attraction, and their strength increases together with the number of electrons among all homonuclear diatomic halogen molecules. Thus, the melting and boiling points of chlorine are intermediate between those of fluorine and bromine: chlorine melts at −101.0 °C and boils at −34.0 °C. As
12972-429: The annual global production of around three hundred million tonnes , only a small percentage is used for human consumption. Other uses include water conditioning processes, de-icing highways, and agricultural use. Edible salt is sold in forms such as sea salt and table salt, the latter of which usually contains an anti-caking agent and may be iodised to prevent iodine deficiency . As well as its use in cooking and at
13113-674: The ash produced by burning the timber of the Indian salt tree ( Maytenus vitis-idaea ) and other trees. The largest mine operated by underground workings in the world is the Sifto mine, located mostly 550 meters below Lake Huron, in Goderich, Ontario (Canada). About seven million tons of salt are extracted from it annually. The Khewra Salt Mine in Pakistan has nineteen storeys, eleven of which are underground, and 400 km (250 mi) of passages. The salt
13254-650: The availability of salt has been pivotal to civilization. What is now thought to have been the first city in Europe is Solnitsata , in Bulgaria , which was a salt mine, providing the area now known as the Balkans with salt since 5400 BC. Salt was the best-known food preservative, especially for meat, for many thousands of years. A very ancient salt-works operation has been discovered at the Poiana Slatinei archaeological site next to
13395-606: The central Cl–O bonds, producing the radicals ClO 3 and ClO 4 which immediately decompose to the elements through intermediate oxides. Chlorine forms four oxoacids: hypochlorous acid (HOCl), chlorous acid (HOClO), chloric acid (HOClO 2 ), and perchloric acid (HOClO 3 ). As can be seen from the redox potentials given in the adjacent table, chlorine is much more stable towards disproportionation in acidic solutions than in alkaline solutions: The hypochlorite ions also disproportionate further to produce chloride and chlorate (3 ClO ⇌ 2 Cl + ClO 3 ) but this reaction
13536-424: The chlorine atom is in its lowest (−1) or highest (+7) possible oxidation states. Perchloric acid and aqueous perchlorates are vigorous and sometimes violent oxidising agents when heated, in stark contrast to their mostly inactive nature at room temperature due to the high activation energies for these reactions for kinetic reasons. Perchlorates are made by electrolytically oxidising sodium chlorate, and perchloric acid
13677-400: The coast natives lost their previous profits; as of the late 1950s, sea salt was still the currency best appreciated in the interior. Salzburg , Hallstatt , and Hallein lie within 17 km (11 mi) of each other on the river Salzach in central Austria in an area with extensive salt deposits. Salzach means "salt river" while Salzburg means "salt castle", both taking their names from
13818-429: The dark. Crystalline clathrate hydrates ClO 2 · n H 2 O ( n ≈ 6–10) separate out at low temperatures. However, in the presence of light, these solutions rapidly photodecompose to form a mixture of chloric and hydrochloric acids. Photolysis of individual ClO 2 molecules result in the radicals ClO and ClOO, while at room temperature mostly chlorine, oxygen, and some ClO 3 and Cl 2 O 6 are produced. Cl 2 O 3
13959-424: The deadly effect on insects, the yellow-green colour, and the smell similar to aqua regia . He called it " dephlogisticated muriatic acid air " since it is a gas (then called "airs") and it came from hydrochloric acid (then known as "muriatic acid"). He failed to establish chlorine as an element. Common chemical theory at that time held that an acid is a compound that contains oxygen (remnants of this survive in
14100-576: The delocalisation of the unpaired electron. It explodes above −40 °C as a liquid and under pressure as a gas and therefore must be made at low concentrations for wood-pulp bleaching and water treatment. It is usually prepared by reducing a chlorate as follows: Its production is thus intimately linked to the redox reactions of the chlorine oxoacids. It is a strong oxidising agent, reacting with sulfur , phosphorus , phosphorus halides, and potassium borohydride . It dissolves exothermically in water to form dark-green solutions that very slowly decompose in
14241-444: The desert from southern Niger to Bilma , although much of the trade now takes place by truck. Each camel takes two bales of fodder and two of trade goods northwards and returns laden with salt pillars and dates. In Gabon, before the arrival of Europeans, the coast people carried on a remunerative trade with those of the interior by the medium of sea salt. This was gradually displaced by the salt that Europeans brought in sacks, so that
14382-574: The development of commercial bleaches and disinfectants , and a reagent for many processes in the chemical industry. Chlorine is used in the manufacture of a wide range of consumer products, about two-thirds of them organic chemicals such as polyvinyl chloride (PVC), many intermediates for the production of plastics , and other end products which do not contain the element. As a common disinfectant, elemental chlorine and chlorine-generating compounds are used more directly in swimming pools to keep them sanitary . Elemental chlorine at high concentration
14523-552: The end of today's The Hawthorns) and on Butts Road in Burn Naze . Burn Naze Halt railway station served those arriving by train. ICI Hillhouse expanded on a United Alkali Company venture begun in 1890. ICI General Chemical Divisions purchased the assets of Hillhouse and Burn Hall Works from the Ministry of Supply . A power plant was built on today's Bourne Way in 1958, providing ICI with electricity and steam power. A railway line—part of
14664-520: The export of salt extracted from the salt mines of Cheshire . Various governments have at different times imposed salt taxes on their peoples. The voyages of Christopher Columbus are said to have been financed from salt production in southern Spain, and the oppressive salt tax in France was one of the causes of the French Revolution . After being repealed, this tax was reimposed by Napoleon when he became emperor to pay for his foreign wars , and
14805-509: The facility previously used resulted in the water turning brackish due to a fault line which runs between Barrow-in-Furness and the Fylde . ICI Hillhouse closed in 1992, after which the Burn Naze area, where most of the workers lived, subsequently suffered a downturn in fortunes. The chlorine plant was demolished in 1994. The power station was demolished in 2007; its chimney followed on 7 November 2009. In 1999, Glasgow-based NPL Estates reached
14946-447: The first time, and demonstrated that what was then known as "solid chlorine" had a structure of chlorine hydrate (Cl 2 ·H 2 O). Chlorine gas was first used by French chemist Claude Berthollet to bleach textiles in 1785. Modern bleaches resulted from further work by Berthollet, who first produced sodium hypochlorite in 1789 in his laboratory in the town of Javel (now part of Paris , France), by passing chlorine gas through
15087-482: The first two. Chlorine has the electron configuration [Ne]3s 3p , with the seven electrons in the third and outermost shell acting as its valence electrons . Like all halogens, it is thus one electron short of a full octet, and is hence a strong oxidising agent, reacting with many elements in order to complete its outer shell. Corresponding to periodic trends , it is intermediate in electronegativity between fluorine and bromine (F: 3.98, Cl: 3.16, Br: 2.96, I: 2.66), and
15228-478: The food ingredients. The refined salt industry cites scientific studies saying that raw sea and rock salts do not contain enough iodine salts to prevent iodine deficiency diseases . Salts have diverse mineralities depending on their source, giving each a unique flavour. Fleur de sel , a natural sea salt from the surface of evaporating brine in salt pans, has a distinctive flavour varying with its source. In traditional Korean cuisine , so-called " bamboo salt "
15369-538: The free element muriaticum (and carbon dioxide). They did not succeed and published a report in which they considered the possibility that dephlogisticated muriatic acid air is an element, but were not convinced. In 1810, Sir Humphry Davy tried the same experiment again, and concluded that the substance was an element, and not a compound. He announced his results to the Royal Society on 15 November that year. At that time, he named this new element "chlorine", from
15510-435: The furnace vaporises before condensing onto the surface of the ceramic material, forming a strong glaze . When drilling through loose materials such as sand or gravel, salt may be added to the drilling fluid to provide a stable "wall" to prevent the hole collapsing. There are many other processes in which salt is involved. These include its use as a mordant in textile dying, to regenerate resins in water softening, for
15651-606: The gaseous products were discarded, and hydrogen chloride may have been produced many times before it was discovered that it can be put to chemical use. One of the first such uses was the synthesis of mercury(II) chloride (corrosive sublimate), whose production from the heating of mercury either with alum and ammonium chloride or with vitriol and sodium chloride was first described in the De aluminibus et salibus ("On Alums and Salts", an eleventh- or twelfth century Arabic text falsely attributed to Abu Bakr al-Razi and translated into Latin in
15792-453: The heaviest elements beyond bismuth ); and having an electronegativity higher than chlorine's ( oxygen and fluorine ) so that the resultant binary compounds are formally not chlorides but rather oxides or fluorides of chlorine. Even though nitrogen in NCl 3 is bearing a negative charge, the compound is usually called nitrogen trichloride . Chlorination of metals with Cl 2 usually leads to
15933-503: The high temperature environment of forest fires, and dioxins have been found in the preserved ashes of lightning-ignited fires that predate synthetic dioxins. In addition, a variety of simple chlorinated hydrocarbons including dichloromethane, chloroform, and carbon tetrachloride have been isolated from marine algae. A majority of the chloromethane in the environment is produced naturally by biological decomposition, forest fires, and volcanoes. Common salt In common usage, salt
16074-640: The iodine. Iodine deficiency affects about two billion people around the world and is the leading preventable cause of intellectual disabilities . Iodized table salt has significantly reduced disorders of iodine deficiency in countries where it is used. The amount of iodine and the specific iodine compound added to salt varies. In the United States , the Food and Drug Administration (FDA) recommends 150 micrograms of iodine per day for both men and women. US iodized salt contains 46–77 ppm (parts per million), whereas in
16215-455: The laboratory, hydrogen chloride gas may be made by drying the acid with concentrated sulfuric acid. Deuterium chloride, DCl, may be produced by reacting benzoyl chloride with heavy water (D 2 O). At room temperature, hydrogen chloride is a colourless gas, like all the hydrogen halides apart from hydrogen fluoride , since hydrogen cannot form strong hydrogen bonds to the larger electronegative chlorine atom; however, weak hydrogen bonding
16356-412: The latter two compounds. In "doubly fortified salt", both iodide and iron salts are added. The latter alleviates iron deficiency anaemia , which interferes with the mental development of an estimated 40% of infants in the developing world. A typical iron source is ferrous fumarate . Another additive, especially important for pregnant women, is folic acid (vitamin B 9 ), which gives the table salt
16497-563: The most reactive chemical compounds known, the list of elements it sets on fire is diverse, containing hydrogen , potassium , phosphorus , arsenic , antimony , sulfur , selenium , tellurium , bromine , iodine , and powdered molybdenum , tungsten , rhodium , iridium , and iron . It will also ignite water, along with many substances which in ordinary circumstances would be considered chemically inert such as asbestos , concrete, glass, and sand. When heated, it will even corrode noble metals as palladium , platinum , and gold , and even
16638-794: The multiple bonds on alkenes and alkynes as well, giving di- or tetrachloro compounds. However, due to the expense and reactivity of chlorine, organochlorine compounds are more commonly produced by using hydrogen chloride, or with chlorinating agents such as phosphorus pentachloride (PCl 5 ) or thionyl chloride (SOCl 2 ). The last is very convenient in the laboratory because all side products are gaseous and do not have to be distilled out. Many organochlorine compounds have been isolated from natural sources ranging from bacteria to humans. Chlorinated organic compounds are found in nearly every class of biomolecules including alkaloids , terpenes , amino acids , flavonoids , steroids , and fatty acids . Organochlorides, including dioxins , are produced in
16779-560: The nature of free chlorine gas as a separate substance was only recognised around 1630 by Jan Baptist van Helmont . Carl Wilhelm Scheele wrote a description of chlorine gas in 1774, supposing it to be an oxide of a new element. In 1809, chemists suggested that the gas might be a pure element, and this was confirmed by Sir Humphry Davy in 1810, who named it after the Ancient Greek χλωρός ( khlōrós , "pale green") because of its colour. Because of its great reactivity, all chlorine in
16920-458: The other carbon–halogen bonds, the C–Cl bond is a common functional group that forms part of core organic chemistry . Formally, compounds with this functional group may be considered organic derivatives of the chloride anion. Due to the difference of electronegativity between chlorine (3.16) and carbon (2.55), the carbon in a C–Cl bond is electron-deficient and thus electrophilic . Chlorination modifies
17061-605: The oxidation state of chlorine decreases. The strengths of the chlorine oxyacids increase very quickly as the oxidation state of chlorine increases due to the increasing delocalisation of charge over more and more oxygen atoms in their conjugate bases. Most of the chlorine oxoacids may be produced by exploiting these disproportionation reactions. Hypochlorous acid (HOCl) is highly reactive and quite unstable; its salts are mostly used for their bleaching and sterilising abilities. They are very strong oxidising agents, transferring an oxygen atom to most inorganic species. Chlorous acid (HOClO)
17202-406: The periodic table form binary chlorides. The exceptions are decidedly in the minority and stem in each case from one of three causes: extreme inertness and reluctance to participate in chemical reactions (the noble gases , with the exception of xenon in the highly unstable XeCl 2 and XeCl 4 ); extreme nuclear instability hampering chemical investigation before decay and transmutation (many of
17343-418: The physical properties of hydrocarbons in several ways: chlorocarbons are typically denser than water due to the higher atomic weight of chlorine versus hydrogen, and aliphatic organochlorides are alkylating agents because chloride is a leaving group . Alkanes and aryl alkanes may be chlorinated under free-radical conditions, with UV light. However, the extent of chlorination is difficult to control:
17484-529: The reaction is not regioselective and often results in a mixture of various isomers with different degrees of chlorination, though this may be permissible if the products are easily separated. Aryl chlorides may be prepared by the Friedel-Crafts halogenation , using chlorine and a Lewis acid catalyst. The haloform reaction , using chlorine and sodium hydroxide , is also able to generate alkyl halides from methyl ketones, and related compounds. Chlorine adds to
17625-503: The sea, salt is extracted from the vast sedimentary deposits which have been laid down over the millennia from the evaporation of seas and lakes. These sources are either mined directly, producing rock salt, or are extracted by pumping water into the deposit. In either case, the salt may be purified by mechanical evaporation of brine. Traditionally, purification was achieved in shallow open pans that were heated to accelerate evaporation. Vacuum -based methods are also employed. The raw salt
17766-610: The second half of the twelfth century by Gerard of Cremona , 1144–1187). Another important development was the discovery by pseudo-Geber (in the De inventione veritatis , "On the Discovery of Truth", after c. 1300) that by adding ammonium chloride to nitric acid , a strong solvent capable of dissolving gold (i.e., aqua regia ) could be produced. Although aqua regia is an unstable mixture that continually gives off fumes containing free chlorine gas, this chlorine gas appears to have been ignored until c. 1630, when its nature as
17907-481: The spin magnitude being greater than 1/2 results in non-spherical nuclear charge distribution and thus resonance broadening as a result of a nonzero nuclear quadrupole moment and resultant quadrupolar relaxation. The other chlorine isotopes are all radioactive, with half-lives too short to occur in nature primordially . Of these, the most commonly used in the laboratory are Cl ( t 1/2 = 3.0×10 y) and Cl ( t 1/2 = 37.2 min), which may be produced from
18048-702: The spread of civilization, salt became one of the world's main trading commodities. It was of high value to the ancient Hebrews, the Greeks, the Romans, the Byzantines, the Hittites and other peoples of antiquity. In the Middle East, salt was used to seal an agreement ceremonially, and the ancient Hebrews made a " covenant of salt " with God and sprinkled salt on their offerings to show their trust in him. An ancient practice in time of war
18189-437: The sulfur oxides SO 2 and SO 3 to produce ClSO 2 F and ClOSO 2 F respectively. It will also react exothermically with compounds containing –OH and –NH groups, such as water: Chlorine trifluoride (ClF 3 ) is a volatile colourless molecular liquid which melts at −76.3 °C and boils at 11.8 °C. It may be formed by directly fluorinating gaseous chlorine or chlorine monofluoride at 200–300 °C. One of
18330-487: The surface of Xiechi Lake near Yuncheng in Shanxi , China, dates back to at least 6000 BC, making it one of the oldest verifiable saltworks. There is more salt in animal tissues, such as meat, blood, and milk, than in plant tissues. Nomads who subsist on their flocks and herds do not eat salt with their food, but agriculturalists, feeding mainly on cereals and vegetable matter, need to supplement their diet with salt. With
18471-623: The table, salt is present in many processed foods. Sodium is an essential element for human health via its role as an electrolyte and osmotic solute . However, excessive salt consumption increases the risk of cardiovascular diseases such as hypertension . Such health effects of salt have long been studied. Accordingly, numerous world health associations and experts in developed countries recommend reducing consumption of popular salty foods. The World Health Organization recommends that adults consume less than 2,000 mg of sodium, equivalent to 5 grams of salt, per day. All through history,
18612-586: The thermally unstable FClO to the chemically unreactive perchloryl fluoride (FClO 3 ), the other three being FClO 2 , F 3 ClO, and F 3 ClO 2 . All five behave similarly to the chlorine fluorides, both structurally and chemically, and may act as Lewis acids or bases by gaining or losing fluoride ions respectively or as very strong oxidising and fluorinating agents. The chlorine oxides are well-studied in spite of their instability (all of them are endothermic compounds). They are important because they are produced when chlorofluorocarbons undergo photolysis in
18753-497: The third-highest electronegativity on the revised Pauling scale , behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval alchemists , which commonly involved the heating of chloride salts like ammonium chloride ( sal ammoniac ) and sodium chloride ( common salt ), producing various chemical substances containing chlorine such as hydrogen chloride , mercury(II) chloride (corrosive sublimate), and aqua regia . However,
18894-528: The time of Brahmanic sacrifices, in Hittite rituals and during festivals held by Semites and Greeks at the time of the new moon , salt was thrown into a fire where it produced crackling noises. The ancient Egyptians, Greeks and Romans invoked their gods with offerings of salt and water and some people think this to be the origin of Holy Water in the Christian faith. In Judaism , it is recommended to have either
19035-406: The upper atmosphere and cause the destruction of the ozone layer. None of them can be made from directly reacting the elements. Dichlorine monoxide (Cl 2 O) is a brownish-yellow gas (red-brown when solid or liquid) which may be obtained by reacting chlorine gas with yellow mercury(II) oxide . It is very soluble in water, in which it is in equilibrium with hypochlorous acid (HOCl), of which it
19176-444: The wars' soldiers at Burn Naze Halt. On 26 July 1963, a fire broke out in an electric furnace at ICI Hillhouse. The furnace was used to heat anthracite to make carbide electro paste. While local brigades (Blackpool and Lancashire) also attended, the fire was fought by the on-site ICI Works fire brigade. A rush of flames injured seven firefighters, with Raymond Pearson, 40, dying a day later in hospital. Chlorine Chlorine
19317-544: Was salting the earth : scattering salt around in a defeated city to prevent plant growth. The Bible tells the story of King Abimelech who was ordered by God to do this at Shechem , and various texts claim that the Roman general Scipio Aemilianus Africanus ploughed over and sowed the city of Carthage with salt after it was defeated in the Third Punic War (146 BC). Salt may have been used for barter in connection with
19458-556: Was first used as a weapon on April 22, 1915, at the Second Battle of Ypres by the German Army . The effect on the allies was devastating because the existing gas masks were difficult to deploy and had not been broadly distributed. Chlorine is the second halogen , being a nonmetal in group 17 of the periodic table. Its properties are thus similar to fluorine , bromine , and iodine , and are largely intermediate between those of
19599-456: Was not finally abolished until 1946. In 1930, Mahatma Gandhi led a crowd of 100,000 protestors on the "Dandi March" or " Salt Satyagraha ", during which they made their own salt from the sea as a demonstration of their opposition to the colonial salt tax . This act of civil disobedience inspired numerous Indians and transformed the Indian independence movement into a national struggle. Salt
19740-619: Was used as early as 3000 BC and brine as early as 6000 BC. Around 900, the authors of the Arabic writings attributed to Jabir ibn Hayyan (Latin: Geber) and the Persian physician and alchemist Abu Bakr al-Razi ( c. 865–925, Latin: Rhazes) were experimenting with sal ammoniac ( ammonium chloride ), which when it was distilled together with vitriol (hydrated sulfates of various metals) produced hydrogen chloride . However, it appears that in these early experiments with chloride salts ,
19881-434: Was used in experimental rocket engine, but has problems largely stemming from its extreme hypergolicity resulting in ignition without any measurable delay. Today, it is mostly used in nuclear fuel processing, to oxidise uranium to uranium hexafluoride for its enriching and to separate it from plutonium , as well as in the semiconductor industry, where it is used to clean chemical vapor deposition chambers. It can act as
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