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98-536: The Bidahochi Formation contains basalt flows that form an erosional protecting unit above the highly erodable Chinle Formation . The Bidahochi Formation extends approximately 112 miles north–south, or north-northwest by south-southeast, a length approximately equivalent to today's Great Salt Lake of Utah . The Bidahochi is possibly the only extensive nonvolcanic Neogene formation of the Colorado Plateau. It has been studied by geologists for clues to conditions on

196-654: A discontinuous patchwork up to the San Rafael Swell . The stratigraphic nomenclature used in southern Utah is also utilized in Monument Valley , where the coarse-grained lower members of the Chinle form a caprock for many famous buttes which characterize the valley. In this region, the stratigraphically lowest unit in the Chinle is usually the Shinarump Conglomerate (or Shinarump Member), which thins northward but

294-588: A dissected limestone pavement . This process is most effective along the joints, widening and deepening them. In unpolluted environments, the pH of rainwater due to dissolved carbon dioxide is around 5.6. Acid rain occurs when gases such as sulfur dioxide and nitrogen oxides are present in the atmosphere. These oxides react in the rain water to produce stronger acids and can lower the pH to 4.5 or even 3.0. Sulfur dioxide , SO 2 , comes from volcanic eruptions or from fossil fuels, and can become sulfuric acid within rainwater, which can cause solution weathering to

392-855: A local extinction, or simply represents a time period which is truncated by slow deposition or a geological hiatus. The thin Sonsela Sandstone bed, the namesake of its corresponding member, has been dated to 216.6 Ma (2019) at its type locality at Sonsela Buttes in Arizona. The first Chinle U-Pb age data to be published referred to the Black Forest Bed, a sandstone layer near the top of the Petrified Forest Member in PEFO. U-Pb estimates for this layer include ~213 Ma (2003 maximum), ~211 Ma (2009), and ~210 Ma (2011, 2020). A presumably older exposure of

490-528: A maximum thickness of a little over 520 meters (1,710 ft). Typically, the Chinle rests unconformably on the Moenkopi Formation . The Chinle Formation was probably mostly deposited in the Norian stage, according to a plethora of chronological techniques. It is a thick and fossiliferous formation with numerous named members (subunits) throughout its area of deposition. While colorful Triassic sediments of

588-691: A mineral crystal exposes ions whose electrical charge attracts water molecules. Some of these molecules break into H+ that bonds to exposed anions (usually oxygen) and OH- that bonds to exposed cations. This further disrupts the surface, making it susceptible to various hydrolysis reactions. Additional protons replace cations exposed on the surface, freeing the cations as solutes. As cations are removed, silicon-oxygen and silicon-aluminium bonds become more susceptible to hydrolysis, freeing silicic acid and aluminium hydroxides to be leached away or to form clay minerals. Laboratory experiments show that weathering of feldspar crystals begins at dislocations or other defects on

686-418: A more humid chemical microenvironment. The attachment of these organisms to the rock surface enhances physical as well as chemical breakdown of the surface microlayer of the rock. Lichens have been observed to pry mineral grains loose from bare shale with their hyphae (rootlike attachment structures), a process described as plucking , and to pull the fragments into their body, where the fragments then undergo

784-403: A process of chemical weathering not unlike digestion. On a larger scale, seedlings sprouting in a crevice and plant roots exert physical pressure as well as providing a pathway for water and chemical infiltration. Most rock forms at elevated temperature and pressure, and the minerals making up the rock are often chemically unstable in the relatively cool, wet, and oxidizing conditions typical of

882-477: A result, thermal stress weathering is sometimes called insolation weathering , but this is misleading. Thermal stress weathering can be caused by any large change of temperature, and not just intense solar heating. It is likely as important in cold climates as in hot, arid climates. Wildfires can also be a significant cause of rapid thermal stress weathering. The importance of thermal stress weathering has long been discounted by geologists, based on experiments in

980-512: A role in the original incision of the Grand Canyon. According to this hypothesis, the lake filled to the point where it overtopped its basin to the west, resulting in rapid incision and formation of the canyon. However, the characteristics of maars and scoria cones in the Bidahochi suggest that Hopi Lake was quite shallow, and a deep lake would have filled very quickly. An alternate hypothesis is that

1078-485: A segment of Triassic sediments which are so diverse and extensive that it is sometimes raised to its own formation, subdivided further, or redefined more narrowly. In its widest definition, the Petrified Forest Member (or Formation) is split into three sections: the muddy Lower Petrified Forest and Upper Petrified Forest, and the sandy Sonsela Sandstone bed, which separates them. The Lower "Petrified Forest Member"

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1176-460: A series of smaller ephemeral lakes, or whether Hopi Lake was a shallow playa lake or a deep lake. However, the evidence from the maars and scoria cones erupted through the formation favors a shallow, possibly ephemeral, lake. The formation has been likened to the Ogallala Formation of eastern New Mexico and west Texas in both age and depositional environment. The Bidahochi is possibly

1274-407: A slower reaction kinetics , this process is thermodynamically favored at low temperature, because colder water holds more dissolved carbon dioxide gas (due to the retrograde solubility of gases). Carbonate dissolution is therefore an important feature of glacial weathering. Carbonate dissolution involves the following steps: Carbonate dissolution on the surface of well-jointed limestone produces

1372-465: A threat to the environment and occupant safety. Design strategies can moderate the impact of environmental effects, such as using of pressure-moderated rain screening, ensuring that the HVAC system is able to effectively control humidity accumulation and selecting concrete mixes with reduced water content to minimize the impact of freeze-thaw cycles. Granitic rock, the most abundant crystalline rock exposed at

1470-426: Is acid hydrolysis , in which protons (hydrogen ions), which are present in acidic water, attack chemical bonds in mineral crystals. The bonds between different cations and oxygen ions in minerals differ in strength, and the weakest will be attacked first. The result is that minerals in igneous rock weather in roughly the same order in which they were originally formed ( Bowen's Reaction Series ). Relative bond strength

1568-550: Is 14 megapascals (2,000 psi). This is still much greater than the tensile strength of granite, which is about 4 megapascals (580 psi). This makes frost wedging, in which pore water freezes and its volumetric expansion fractures the enclosing rock, appear to be a plausible mechanism for frost weathering. Ice will simply expand out of a straight open fracture before it can generate significant pressure. Thus, frost wedging can only take place in small tortuous fractures. The rock must also be almost completely saturated with water, or

1666-700: Is a crucial part of the rock cycle ; sedimentary rock , the product of weathered rock, covers 66% of the Earth's continents and much of the ocean floor . Physical weathering , also called mechanical weathering or disaggregation , is the class of processes that causes the disintegration of rocks without chemical change. Physical weathering involves the breakdown of rocks into smaller fragments through processes such as expansion and contraction, mainly due to temperature changes. Two types of physical breakdown are freeze-thaw weathering and thermal fracturing. Pressure release can also cause weathering without temperature change. It

1764-403: Is a less well characterized mechanism of physical weathering. It takes place because ice grains always have a surface layer, often just a few molecules thick, that resembles liquid water more than solid ice, even at temperatures well below the freezing point. This premelted liquid layer has unusual properties, including a strong tendency to draw in water by capillary action from warmer parts of

1862-535: Is a reliable component of outcrops throughout the region. In several areas, a thin layer of mottled paleosols , the Temple Mountain Member , may be superimposed onto the Shinarump and underlying Moenkopi Formation. The Monitor Butte Member overlies the Shinarump and Temple Mountain members in southeast Utah and Monument Valley. This unit comprises drab and generally fine-grained sediments, equivalent to

1960-440: Is also important, acting to oxidize many minerals, as is carbon dioxide, whose weathering reactions are described as carbonation . The process of mountain block uplift is important in exposing new rock strata to the atmosphere and moisture, enabling important chemical weathering to occur; significant release occurs of Ca and other ions into surface waters. Dissolution (also called simple solution or congruent dissolution )

2058-715: Is also known as sheeting . As with thermal weathering, pressure release is most effective in buttressed rock. Here the differential stress directed toward the unbuttressed surface can be as high as 35 megapascals (5,100 psi), easily enough to shatter rock. This mechanism is also responsible for spalling in mines and quarries, and for the formation of joints in rock outcrops. Retreat of an overlying glacier can also lead to exfoliation due to pressure release. This can be enhanced by other physical wearing mechanisms. Salt crystallization (also known as salt weathering , salt wedging or haloclasty ) causes disintegration of rocks when saline solutions seep into cracks and joints in

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2156-461: Is an Upper Triassic continental geological formation of fluvial , lacustrine , and palustrine to eolian deposits spread across the U.S. states of Nevada , Utah , northern Arizona , western New Mexico , and western Colorado . In New Mexico, it is often raised to the status of a geological group, the Chinle Group . Some authors have controversially considered the Chinle to be synonymous to

2254-612: Is chemically weathered to iron(II) sulfate and gypsum , which then crystallize as salt lenses. Salt crystallization can take place wherever salts are concentrated by evaporation. It is thus most common in arid climates where strong heating causes strong evaporation and along coasts. Salt weathering is likely important in the formation of tafoni , a class of cavernous rock weathering structures. Living organisms may contribute to mechanical weathering, as well as chemical weathering (see § Biological weathering below). Lichens and mosses grow on essentially bare rock surfaces and create

2352-442: Is distinct from erosion , which involves the transport of rocks and minerals by agents such as water , ice , snow , wind , waves and gravity . Weathering processes are either physical or chemical. The former involves the breakdown of rocks and soils through such mechanical effects as heat, water, ice and wind. The latter covers reactions to water, atmospheric gases and biologically produced chemicals with rocks and soils. Water

2450-907: Is entirely Late Triassic in age. Tetrapod biostratigraphy for the Chinle was first developed based on phytosaurs and aetosaurs , which in 1998 were combined into global biozones in Spencer G. Lucas 's Land Vertebrate Faunachrons system. Simplified stratigraphy based on Litwin. Note that age inferences devised by Lucas do not necessarily align with other chronological methods used in the Chinle Formation. Other works on Chinle biostratigraphy, such as Martz & Parker (2017), are better integrated with magnetostratigraphy and radiometric dating, and are considered more accurate. Machaeroprosopus ( Smilosuchus , Leptosuchus , etc.) ( Paleorhinus / Parasuchus ) Since 2011, widespread radiometric dating has helped to refine precise age data for part of

2548-562: Is followed by the youngest and sandiest subunit of the Chinle, the Rock Point Member . The Rock Point is distinct enough that it was previously considered a unit of the Wingate Sandstone , a latest Triassic - early Jurassic aeolian formation which overlies the Chinle in many areas. Unambiguous exposures of the Chinle Formation extend into central New Mexico, beyond the eastern edge of the Colorado Plateau. Most of these are found in

2646-519: Is generally known as the Blue Mesa Member . In Petrified Forest National Park (PEFO) and its vicinities, the Sonsela Sandstone is thick enough that it can be resolved into several distinct sandstone-rich layers. It is renamed as the Sonsela Member in this situation. The Sonsela Sandstone is a collection of braided-stream channel facies. The Upper "Petrified Forest Member" is sometimes called

2744-569: Is in equilibrium with kaolinite. Soil formation requires between 100 and 1,000 years, a brief interval in geologic time. As a result, some formations show numerous paleosol (fossil soil) beds. For example, the Willwood Formation of Wyoming contains over 1,000 paleosol layers in a 770 meters (2,530 ft) section representing 3.5 million years of geologic time. Paleosols have been identified in formations as old as Archean (over 2.5 billion years in age). They are difficult to recognize in

2842-407: Is interpreted as mostly alluvium , though eolian , lacustrine , and spring deposits are also present, in addition to lava flows and ash beds. The lower member has been interpreted as a lacustrine facies and the upper member as a fluvial facies. The lacustrine deposits suggests widespread lakes in the area, though geologists continue to debate whether there was a single large lake (Hopi Lake) or

2940-468: Is likely the more important mechanism in nature. Geomorphologists have begun to reemphasize the importance of thermal stress weathering, particularly in cold climates. Pressure release or unloading is a form of physical weathering seen when deeply buried rock is exhumed . Intrusive igneous rocks, such as granite , are formed deep beneath the Earth's surface. They are under tremendous pressure because of

3038-579: Is often synonymized with the Shinarump Conglomerate, though it may be derived from a different erosional source. It is often preceded by a very thin layer of silty mottled strata. This mottled strata is sometimes termed the Zuni Mountains Formation, though the application of this term beyond the Zuni Mountains is questionable. In the Chama Basin at least, the mottled strata is derived from

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3136-505: Is only 5 feet (1.5 m) thick, consists of volcaniclastics , mostly basalt and quartzite pebbles. The upper member is over 274 feet (84 m) thick, forms ledges and slopes, and is mostly mudrock and sandstone . The formation is exposed over an area of over 16,000 square kilometers (6,200 sq mi) in the Black Mesa and San Juan Basins . In many locations, the formation includes lava flows , which can appear at any level in

3234-611: Is practically identical to the Blue Mesa Member, and likely represents the same depositional environment along the ancient river system responsible for the Chinle Formation. It is also distinct from the Monitor Butte Member, which has more evaporite deposits and fewer red sandy layers. The drab mudstone of the Monitor Butte and Cameron members are succeeded in a few areas by a thin section of massive conglomeratic sandstone,

3332-484: Is relatively poor in potassium, the basalt weathers directly to potassium-poor montmorillonite , then to kaolinite . Where leaching is continuous and intense, as in rain forests, the final weathering product is bauxite , the principal ore of aluminium. Where rainfall is intense but seasonal, as in monsoon climates, the final weathering product is iron- and titanium-rich laterite . Conversion of kaolinite to bauxite occurs only with intense leaching, as ordinary river water

3430-449: Is shown in the following table: This table is only a rough guide to order of weathering. Some minerals, such as illite , are unusually stable, while silica is unusually unstable given the strength of the silicon–oxygen bond . Carbon dioxide that dissolves in water to form carbonic acid is the most important source of protons, but organic acids are also important natural sources of acidity. Acid hydrolysis from dissolved carbon dioxide

3528-421: Is sometimes described as carbonation , and can result in weathering of the primary minerals to secondary carbonate minerals. For example, weathering of forsterite can produce magnesite instead of brucite via the reaction: Carbonic acid is consumed by silicate weathering, resulting in more alkaline solutions because of the bicarbonate . This is an important reaction in controlling the amount of CO 2 in

3626-555: Is the informally-named “ siltstone member ”. This unit is best exposed at Ghost Ranch, where it has produced the famous Whitaker Quarry, also known as the Coelophysis quarry due to a high concentration of fossils belonging to the theropod dinosaur Coelophysis bauri . The "siltstone member" may be equivalent to the Rock Point Member, and some authors refer to it as such. The Chinle continues northwards into southern Utah and

3724-427: Is the principal agent behind both kinds, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Biological chemical weathering is also called biological weathering. The materials left after the rock breaks down combine with organic material to create soil . Many of Earth's landforms and landscapes are the result of weathering, erosion and redeposition. Weathering

3822-417: Is the process in which a mineral dissolves completely without producing any new solid substance. Rainwater easily dissolves soluble minerals, such as halite or gypsum , but can also dissolve highly resistant minerals such as quartz , given sufficient time. Water breaks the bonds between atoms in the crystal: [REDACTED] The overall reaction for dissolution of quartz is The dissolved quartz takes

3920-431: Is usually much less important than chemical weathering, but can be significant in subarctic or alpine environments. Furthermore, chemical and physical weathering often go hand in hand. For example, cracks extended by physical weathering will increase the surface area exposed to chemical action, thus amplifying the rate of disintegration. Frost weathering is the most important form of physical weathering. Next in importance

4018-426: Is wedging by plant roots, which sometimes enter cracks in rocks and pry them apart. The burrowing of worms or other animals may also help disintegrate rock, as can "plucking" by lichens. Frost weathering is the collective name for those forms of physical weathering that are caused by the formation of ice within rock outcrops. It was long believed that the most important of these is frost wedging , which results from

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4116-626: The Moss Back Member . This member represents sandy river channel deposits and is likely equivalent to part of the Sonsela Member. Elsewhere, the Monitor Butte grades into the Petrified Forest Member, which in Utah includes the thin but geographically extensive Correo Sandstone Bed. The Petrified Forest Member is followed by the Owl Rock Member. A unit of drab interbedded coarse and fine sediments,

4214-631: The Chama Basin of north-central New Mexico, particularly several famed paleontological sites at Ghost Ranch near Abiquiu . Minor exposures also occur in the Lucero Uplift west of Albuquerque , as well as other areas along the Rio Grande Rift . As in the Colorado Plateau, the lowest major unit in north-central New Mexico is a sandstone-rich member. This layer, the Agua Zarca Sandstone ,

4312-589: The Chinle Formation , and is typically the uppermost named unit in its outcrop area. The formation is likely middle Miocene to middle Pliocene in age, and the lower part of the formation may correlate with the Fence Lake Formation . One of the lava flows within the formation has a radiometric age of 4.1 million years, and radiometric dating of other associated flows and ash beds gives the formation an age range of 15.5 to 4 million years. The formation

4410-584: The Colorado Plateau have been investigated since the 19th century, the Chinle Formation was only formally named and described by Herbert E. Gregory in 1917. It was named for Chinle Valley in Apache County, Arizona , land which is largely within the Navajo Nation . Gregory did not designate a type locality . He split the Chinle into four subunits, labelled A (youngest) to D (oldest). This did not include

4508-569: The Dockum Group of eastern Colorado and New Mexico, western Texas , the Oklahoma panhandle, and southwestern Kansas . The Chinle Formation is part of the Colorado Plateau , Basin and Range , and the southern section of the Interior Plains . A probable separate depositional basin within the Chinle is found in northwestern Colorado and northeastern Utah. The southern portion of the Chinle reaches

4606-726: The Kane Springs beds , develops in the Paradox Basin. The Kane Springs beds are river deposits which are likely equivalent to the Owl Rock Member and the upper part of the Petrified Forest Member. Finally, either the Rock Point Member or Church Rock Member overlie the Owl Rock. Some researchers feel that the Church Rock and Rock Point members may be synonymous. They are complex heterolithic units, representing variously braided-river facies, lacustrine, and overbank deposits. The Chinle Formation

4704-566: The Mesa Redondo Member at PEFO have been dated to ~225 Ma (2011) or ~228 Ma (2013), though these may be influenced by recycled grains. Later estimates from a major core drilling project support a more recent depositional age of 223-222 Ma (2020). This firmly suggests that practically all of the Chinle Formation was deposited in the Norian stage; According to the consensus "long Norian" hypothesis and radiometric assessments of marine strata,

4802-794: The Painted Desert area. In western New Mexico (particularly the Zuni Mountains area), the Mesa Redondo Member may be replaced by another sandy unit known as the Zuni Mountains Formation . Sediments from this time interval are followed by a geological unit called the Bluewater Creek Formation . Most Chinle outcrops in the Painted Desert have traditionally been placed within the following Petrified Forest Member ,

4900-564: The Sonsela Member , though a high concentration of reworked zircons must be accounted for when inferring an accurate age of deposition. The true duration of the Sonsela Member is likely from around 218 Ma to 213 Ma (2020), though older estimates place its base at 220-219 Ma (2011, 2013). A prominent biological turnover is found at the Adamanian-Revueltian boundary in the middle of the Sonsela Member, around 214 Ma. It may correspond to

4998-512: The Blue Mesa Member and Bluewater Creek Formation found further south. The facies of this interval have been interpreted as overbank (distal floodplain ) and lacustrine deposits. At Zion National Park, the Monitor Butte Member is replaced by a thick time-equivalent unit, the Cameron Member , which is also found in the Navajo Nation near its namesake of Cameron, Arizona . The Cameron Member

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5096-613: The Carnian-Norian boundary is tentatively set to ~227 Ma. At PEFO, U-Pb estimates from the Blue Mesa Member include 223 Ma (2011), 222 Ma (2020), and 221-218 Ma (2020). Dated outcrops of drab mudstone near St. Johns, Arizona fit this general time period as well. The fossiliferous Placerias quarry, previously regarded as belonging to an older subunit, is likely part of the Blue Mesa Member based on an age date of 219.4 Ma (2014). At Six Mile Canyon near Fort Wingate, New Mexico ,

5194-567: The Chinle Formation, particularly in areas with a more complete stratigraphic record such as Petrified Forest National Park (PEFO). Volcanism further southwest along the Cordilleran magmatic arc supplies zircon crystals to the Chinle system, allowing for U-Pb dating of layers which host zircon grains. Eroded sediments from the Ancestral Rocky Mountains , Ouachita Mountains and Mogollon Highlands also supply older reworked zircon to

5292-482: The Chinle. "red siltstone member" "sandstone and conglomerate member" (UT) "ocher siltstone member" (UT) Kane Springs beds (in part) Kane Springs beds (in part) Bluewater Creek Formation (NM) Cameron Member Gartra Member ? Shinarump Conglomerate Zuni Mountains Formation (NM) "mottled strata" Temple Mountain Member Some of the most extensive deposits of the Chinle Formation are found in

5390-650: The Colorado River originally joined a drainage to the north, the Bell River, and the western part of the canyon was flooded by Hualapai Lake, which backed up to the Bidahochi basin. Only after the opening of the Gulf of California was the Colorado River integrated into a drainage to the south. Old delta deposits in the Bidahochi Formation at the mouths of paleocanyons are cited as evidence for this hypothesis. The formation

5488-408: The Earth's surface, begins weathering with the destruction of hornblende . Biotite then weathers to vermiculite , and finally oligoclase and microcline are destroyed. All are converted into a mixture of clay minerals and iron oxides. The resulting soil is depleted in calcium, sodium, and ferrous iron compared with the bedrock, and magnesium is reduced by 40% and silicon by 15%. At the same time,

5586-411: The Earth's surface. Chemical weathering takes place when water, oxygen, carbon dioxide, and other chemical substances react with rock to change its composition. These reactions convert some of the original primary minerals in the rock to secondary minerals, remove other substances as solutes, and leave the most stable minerals as a chemically unchanged resistate . In effect, chemical weathering changes

5684-748: The Four Corners Region was established by the late 1950s. In 1956, Economic geologist Raymond C. Robeck identified and named the Temple Mountain member as the basal-most unit in the area of the San Rafael Swell of Utah. In 1957, John H. Stewart revised the Shinarump Conglomerate and renamed it the Shinarump member of the Chinle formation. Study of the formation expanded northwards into northern Utah and Colorado, facilitated through papers by Forrest G. Poole and Stewart (1964) and Steve W. Sikich (1965), who named informal local members equivalent to those of Arizona and New Mexico. The complete areal extent of

5782-512: The Four Corners area, though it thins greatly to the northwest. A narrow band of undifferentiated purplish sediments from the lower part of the formation extend into vicinity of St. George . The formation thickens eastward into Zion National Park and Grand Staircase–Escalante National Monument . The Chinle is a prominent component of badlands and outcrops in the various national parks, monuments, and recreation areas of southeast Utah, extending in

5880-543: The Painted Desert Member, or simply referred to as the Petrified Forest Member in a more restricted definition of the term. The Petrified Forest is predominately overbank deposits with thin lenses of channel-deposit facies and lacustrine deposits. The Petrified Forest Member grades into the Owl Rock Member , a marginal lacustrine to lacustrine facies possibly representing a large lake system. The Owl Rock Member

5978-696: The Petrified Forest Member, the Hayden Quarry at Ghost Ranch, is dated to 212 Ma (2011). A similar age was found for the middle part of the member in PEFO. The end of the Petrified Forest Member was probably close to 208 Ma, meaning that overlying strata is presumably latest Norian-Rhaetian in age. Geologic Province: Parklands: Other: Weathering Weathering is the deterioration of rocks , soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases , sunlight , and biological organisms. It occurs in situ (on-site, with little or no movement), and so

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6076-409: The affected rocks a reddish-brown coloration on the surface which crumbles easily and weakens the rock. Many other metallic ores and minerals oxidize and hydrate to produce colored deposits, as does sulfur during the weathering of sulfide minerals such as chalcopyrites or CuFeS 2 oxidizing to copper hydroxide and iron oxides . Mineral hydration is a form of chemical weathering that involves

6174-466: The atmosphere and can affect climate. Aluminosilicates containing highly soluble cations, such as sodium or potassium ions, will release the cations as dissolved bicarbonates during acid hydrolysis: Within the weathering environment, chemical oxidation of a variety of metals occurs. The most commonly observed is the oxidation of Fe ( iron ) by oxygen and water to form Fe oxides and hydroxides such as goethite , limonite , and hematite . This gives

6272-468: The base of the Blue Mesa Member (or its local equivalent) is defined by a distinct sandstone bed, which has been dated to 221-219 Ma (2009) or 218 Ma (2011). The underlying Bluewater Creek Formation has also been dated to 221-219 Ma (2014), suggesting that it overlaps in time with the Arizonan Blue Mesa Member and possibly part of the Sonsela Member. Radiometric dates are well-recorded for

6370-902: The basin. Chinle radiometric dating is complicated by lithological quirks of zircon deposition. Taken at face value, U-Pb dates from coarse-grained layers are often several million years older than expected based on magnetostratigraphy, while mud-dominated layers are generally more accurate despite a lower sample size. This is likely because sandy rivers receive a higher proportion of recycled zircon grains from distant eroded rocks, while muddy plains are supplied with fresh zircon-rich ash from contemporary volcanic eruptions. While zircons from sandstone-rich layers are less useful for inferring direct depositional ages, they can be very useful for inferring sediment sources: each igneous or metamorphic sediment source has its own set of old (usually Precambrian) zircon ages, which can be traced in Triassic sediments. Outcrops of

6468-819: The carbon dioxide level to 30% of all soil gases, aided by adsorption of CO 2 on clay minerals and the very slow diffusion rate of CO 2 out of the soil. The CO 2 and organic acids help break down aluminium - and iron -containing compounds in the soils beneath them. Roots have a negative electrical charge balanced by protons in the soil next to the roots, and these can be exchanged for essential nutrient cations such as potassium. Decaying remains of dead plants in soil may form organic acids which, when dissolved in water, cause chemical weathering. Chelating compounds, mostly low molecular weight organic acids, are capable of removing metal ions from bare rock surfaces, with aluminium and silicon being particularly susceptible. The ability to break down bare rock allows lichens to be among

6566-530: The early 20th century that seemed to show that its effects were unimportant. These experiments have since been criticized as unrealistic, since the rock samples were small, were polished (which reduces nucleation of fractures), and were not buttressed. These small samples were thus able to expand freely in all directions when heated in experimental ovens, which failed to produce the kinds of stress likely in natural settings. The experiments were also more sensitive to thermal shock than thermal fatigue, but thermal fatigue

6664-528: The eroded and pedogenically modified surface of the Moenkopi Formation. The coarse lower unit grades into the fine-grained Salitral Formation , which is equivalent to the Blue Mesa Member and Bluewater Creek Formation. In south-central New Mexico, it may instead grade into the San Pedro Arroyo Formation , a similar heterolithic unit. Coarse sandstone returns along a sharp contact with

6762-586: The erosional surface using X-ray crystallography indicate a lack of chemical weathering . This in turn is an indication that the southern Colorado Plateau has been semiarid throughout most of the Neogene, even at times when the rest of western North America was relatively damp. The plateau may then have been a deep basin in the rain shadow of the southern Rocky Mountains and the Central Arizona Highlands. It has also been suggested that Hopi Lake played

6860-427: The expansion of pore water when it freezes. A growing body of theoretical and experimental work suggests that ice segregation, whereby supercooled water migrates to lenses of ice forming within the rock, is the more important mechanism. When water freezes, its volume increases by 9.2%. This expansion can theoretically generate pressures greater than 200 megapascals (29,000 psi), though a more realistic upper limit

6958-404: The expense of silica, titanium, aluminum, ferrous iron, and calcium. Buildings made of any stone, brick or concrete are susceptible to the same weathering agents as any exposed rock surface. Also statues , monuments and ornamental stonework can be badly damaged by natural weathering processes. This is accelerated in areas severely affected by acid rain . Accelerated building weathering may be

7056-488: The first colonizers of dry land. The accumulation of chelating compounds can easily affect surrounding rocks and soils, and may lead to podsolisation of soils. The symbiotic mycorrhizal fungi associated with tree root systems can release inorganic nutrients from minerals such as apatite or biotite and transfer these nutrients to the trees, thus contributing to tree nutrition. It was also recently evidenced that bacterial communities can impact mineral stability leading to

7154-564: The following Poleo Formation , an equivalent of the Sonsela Member. The Poleo Formation grades into the thick colorful sediments of the Petrified Forest Member. Authors which raise this member to a formation subdivide it into the lower Mesa Montosa Member and the upper Painted Desert Member. The Petrified Forest Member is fossiliferous in the Chama Basin, with major sites including the Hayden, Canjilon, and Snyder quarries of Ghost Ranch. The stratigraphically highest unit in north-central New Mexico

7252-463: The form of silicic acid . A particularly important form of dissolution is carbonate dissolution, in which atmospheric carbon dioxide enhances solution weathering. Carbonate dissolution affects rocks containing calcium carbonate , such as limestone and chalk . It takes place when rainwater combines with carbon dioxide to form carbonic acid , a weak acid , which dissolves calcium carbonate (limestone) and forms soluble calcium bicarbonate . Despite

7350-403: The formation, but are most common in the middle informal member. The lava flows within the formation are typically found capping mesas. The contacts between the informal members do not define consistent stratigraphic positions, and the members are probably better interpreted as depositional facies rather than stratigraphic units. The formation is underlain by various Mesozoic formations, such as

7448-669: The geologic record. Indications that a sedimentary bed is a paleosol include a gradational lower boundary and sharp upper boundary, the presence of much clay, poor sorting with few sedimentary structures, rip-up clasts in overlying beds, and desiccation cracks containing material from higher beds. The degree of weathering of soil can be expressed as the chemical index of alteration , defined as 100 Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O) . This varies from 47 for unweathered upper crust rock to 100 for fully weathered material. Wood can be physically and chemically weathered by hydrolysis and other processes relevant to minerals and

7546-439: The ice will simply expand into the air spaces in the unsaturated rock without generating much pressure. These conditions are unusual enough that frost wedging is unlikely to be the dominant process of frost weathering. Frost wedging is most effective where there are daily cycles of melting and freezing of water-saturated rock, so it is unlikely to be significant in the tropics, in polar regions or in arid climates. Ice segregation

7644-540: The most effective biological agents of chemical weathering. For example, an experimental study on hornblende granite in New Jersey, US, demonstrated a 3x – 4x increase in weathering rate under lichen covered surfaces compared to recently exposed bare rock surfaces. The most common forms of biological weathering result from the release of chelating compounds (such as certain organic acids and siderophores ) and of carbon dioxide and organic acids by plants. Roots can build up

7742-559: The name Dolores Formation as a parochial synonym for the Chinle Group. Overviews of the Chinle were created by Dubiel and others (1992) and Hintze and Axen (1995). The Chinle Formation is fossiliferous, with a diverse array of extinct reptile, fish, and plant fossils, including early dinosaurs and the famous petrified wood of Petrified Forest National Park in Arizona . The formation members and their thicknesses are highly variable across

7840-430: The only large non-volcanic geologic formation of Neogene age on the Colorado Plateau. This has made it of interest to geologists attempting to reconstruct conditions on the Colorado Plateau during the Neogene and for theories of the formation of the Grand Canyon. In some locations, the Bidahochi Formation preserves an erosional surface in the underlying Mesozoic bedrock (Hopi Buttes surface). Examination of clay minerals in

7938-551: The original set of minerals in the rock into a new set of minerals that is in closer equilibrium with surface conditions. True equilibrium is rarely reached, because weathering is a slow process, and leaching carries away solutes produced by weathering reactions before they can accumulate to equilibrium levels. This is particularly true in tropical environments. Water is the principal agent of chemical weathering, converting many primary minerals to clay minerals or hydrated oxides via reactions collectively described as hydrolysis . Oxygen

8036-443: The overlying rock material. When erosion removes the overlying rock material, these intrusive rocks are exposed and the pressure on them is released. The outer parts of the rocks then tend to expand. The expansion sets up stresses which cause fractures parallel to the rock surface to form. Over time, sheets of rock break away from the exposed rocks along the fractures, a process known as exfoliation . Exfoliation due to pressure release

8134-616: The plateau during this time interval and to test hypotheses for the initial incision of the Grand Canyon At its reference section near Indian Wells, Arizona , the Bidahochi Formation is divided into three informal members . The lower member is 214 feet (65 m) thick and consists mostly of mudstone and fine sandstone with a basal conglomerate of limestone and siltstone pebbles. The beds show distorted crossbedding and ripple marks, and plant fossils (impressions and petrified wood ) are present. The middle volcanic member, which

8232-402: The production of weathering agents, such as protons, organic acids and chelating molecules. Weathering of basaltic oceanic crust differs in important respects from weathering in the atmosphere. Weathering is relatively slow, with basalt becoming less dense, at a rate of about 15% per 100 million years. The basalt becomes hydrated, and is enriched in total and ferric iron, magnesium, and sodium at

8330-416: The release of inorganic nutrients. A large range of bacterial strains or communities from diverse genera have been reported to be able to colonize mineral surfaces or to weather minerals, and for some of them a plant growth promoting effect has been demonstrated. The demonstrated or hypothesised mechanisms used by bacteria to weather minerals include several oxidoreduction and dissolution reactions as well as

8428-448: The rigid attachment of water molecules or H+ and OH- ions to the atoms and molecules of a mineral. No significant dissolution takes place. For example, iron oxides are converted to iron hydroxides and the hydration of anhydrite forms gypsum . Bulk hydration of minerals is secondary in importance to dissolution, hydrolysis, and oxidation, but hydration of the crystal surface is the crucial first step in hydrolysis. A fresh surface of

8526-455: The rock surface, which gradually pry the rock apart. Thermal stress weathering results from the expansion and contraction of rock due to temperature changes. Thermal stress weathering is most effective when the heated portion of the rock is buttressed by surrounding rock, so that it is free to expand in only one direction. Thermal stress weathering comprises two main types, thermal shock and thermal fatigue . Thermal shock takes place when

8624-413: The rock. This results in growth of the ice grain that puts considerable pressure on the surrounding rock, up to ten times greater than is likely with frost wedging. This mechanism is most effective in rock whose temperature averages just below the freezing point, −4 to −15 °C (25 to 5 °F). Ice segregation results in growth of ice needles and ice lenses within fractures in the rock and parallel to

8722-408: The rocks and evaporate, leaving salt crystals behind. As with ice segregation, the surfaces of the salt grains draw in additional dissolved salts through capillary action, causing the growth of salt lenses that exert high pressure on the surrounding rock. Sodium and magnesium salts are the most effective at producing salt weathering. Salt weathering can also take place when pyrite in sedimentary rock

8820-425: The rocks on which it falls. Hydrolysis (also called incongruent dissolution ) is a form of chemical weathering in which only part of a mineral is taken into solution. The rest of the mineral is transformed into a new solid material, such as a clay mineral . For example, forsterite (magnesium olivine ) is hydrolyzed into solid brucite and dissolved silicic acid: Most hydrolysis during weathering of minerals

8918-536: The soil is enriched in aluminium and potassium by at least 50%; by titanium, whose abundance triples, and ferric iron, whose abundance increases by an order of magnitude compared with the bedrock. Basaltic rock is more easily weathered than granitic rock due to its formation at higher temperatures and drier conditions. The fine grain size and presence of volcanic glass also hasten weathering. In tropical settings, it rapidly weathers to clay minerals, aluminium hydroxides, and titanium-enriched iron oxides. Because most basalt

9016-535: The southern Colorado Plateau, including Arizona and the western portion of New Mexico. In this region, the oldest and stratigraphically lowest portion of the Chinle is the Shinarump Conglomerate . The Shinarump includes braided-river system channel-deposit facies . The Shinarump interfingers with a finer-grained subunit, the Mesa Redondo Member , one of the oldest widespread units in the badlands of

9114-419: The stresses are so great that the rock cracks immediately, but this is uncommon. More typical is thermal fatigue, in which the stresses are not great enough to cause immediate rock failure, but repeated cycles of stress and release gradually weaken the rock. Thermal stress weathering is an important mechanism in deserts , where there is a large diurnal temperature range, hot in the day and cold at night. As

9212-454: The surface of the crystal, and that the weathering layer is only a few atoms thick. Diffusion within the mineral grain does not appear to be significant. Mineral weathering can also be initiated or accelerated by soil microorganisms. Soil organisms make up about 10 mg/cm of typical soils, and laboratory experiments have demonstrated that albite and muscovite weather twice as fast in live versus sterile soil. Lichens on rocks are among

9310-446: The underlying Shinarump Conglomerate (named by G. K. Gilbert and Edwin E. Howell in 1875), which he considered a separate formation. United States Geological Survey geologists and paleontologists continued to map out the Chinle Formation through the 20th century, revising the unnamed subunits of Gregory. A basic stratigraphy of the formation was developed for north-central New Mexico by Wood and Northrop (1946), and stratigraphy in

9408-412: The unit was mapped by R.F. Wilson and Stewart in 1967. Stewart and his colleagues created an expansive overview and revision of the formation in 1972, summarizing previous knowledge on Chinle stratigraphy. V.C. Kelley assigned more members and revised the unit in 1972. Spencer G. Lucas and S.N. Hayden did the same thing in 1989. The Rock Point Member was assigned by R.F. Dubiel in 1989. The Chinle

9506-595: Was first named by A.B. Regan in 1924, for outcrops throughout the Hopi Buttes volcanic field . In 1954, Charles Repenning and James Irwin defined a reference section near Indian Wells, and divided the unit into informal lower, volcanic, and upper members. D.W. Love concluded that the members defined in the formation by earlier investigators were mere depositional facies and recommended their abandonment. Limestone fossils Bidahochi & Petrified Forest Bidahochi Formation Chinle Formation The Chinle Formation

9604-434: Was raised to group rank by Lucas in 1993, thus also raising many of the members to formation status. He also included the formations of the Dockum Group of eastern New Mexico and west Texas within the "Chinle Group". This modified nomenclature is controversial; many still retain the Chinle as a formation and separate out the Dockum Group . The Dockum was named in 1890, before the Chinle. Lucas also advocated abandoning

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