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123-607: The St. Thomas Church ( German : Thomaskirche ) is a Lutheran church in Leipzig , Germany, located at the western part of the inner city ring road in Leipzig's central district . Martin Luther preached in the church in 1539. It is associated with several well-known composers, especially Johann Sebastian Bach , who was its Thomaskantor (music director) from 1723 until his death in 1750. The church holds his remains. Although rebuilt over

246-460: A de facto official language of Namibia after the end of German colonial rule alongside English and Afrikaans , and had de jure co-official status from 1984 until its independence from South Africa in 1990. However, the Namibian government perceived Afrikaans and German as symbols of apartheid and colonialism, and decided English would be the sole official language upon independence, stating that it

369-487: A roof pitch of 63 degrees. It rises to a crown that is 45 meters high. The tower is 68 meters in height. The church features a number of works of art, including a baptismal font (1614–15) made by Franz Döteber and Portraits show the Stadtsuperintendent of Leipzig, the oldest dating from 1614. A crucifix made by Caspar Freidrich Löbel is one of the few remaining pieces from the times of Bach. The church also contains

492-402: A second language , and 75–100   million as a foreign language . This would imply the existence of approximately 175–220   million German speakers worldwide. German sociolinguist Ulrich Ammon estimated a number of 289 million German foreign language speakers without clarifying the criteria by which he classified a speaker. As of 2012 , about 90   million people, or 16% of

615-587: A "commonly used" language and the Pan South African Language Board is obligated to promote and ensure respect for it. Cameroon was also a colony of the German Empire from the same period (1884 to 1916). However, German was replaced by French and English, the languages of the two successor colonial powers, after its loss in World War I . Nevertheless, since the 21st century, German has become

738-465: A component of bad breath odor. Not all organic sulfur compounds smell unpleasant at all concentrations: the sulfur-containing monoterpenoid grapefruit mercaptan in small concentrations is the characteristic scent of grapefruit, but has a generic thiol odor at larger concentrations. Sulfur mustard , a potent vesicant , was used in World War ;I as a disabling agent. Sulfur–sulfur bonds are

861-556: A greater need for regularity in written conventions. While the major changes of the MHG period were socio-cultural, High German was still undergoing significant linguistic changes in syntax, phonetics, and morphology as well (e.g. diphthongization of certain vowel sounds: hus (OHG & MHG "house") → haus (regionally in later MHG)→ Haus (NHG), and weakening of unstressed short vowels to schwa [ə]: taga (OHG "days")→ tage (MHG)). A great wealth of texts survives from

984-572: A major industrial product, especially in automobile tires. Because of the heat and sulfur, the process was named vulcanization , after the Roman god of the forge and volcanism . Being abundantly available in native form, sulfur was known in ancient times and is referred to in the Torah ( Genesis ). English translations of the Christian Bible commonly referred to burning sulfur as "brimstone", giving rise to

1107-566: A munitions depot for the French army. During the Battle of Leipzig in 1813, it was used as a military hospital. Richard Wagner was baptized here on 16 August 1813. In 1828, he studied piano and counterpoint with the then Thomaskantor , Christian Th. Weinlig. Most of the Baroque internal trappings of the church known to Bach were removed in a Gothic revival renovation between 1884 and 1889. The pulpit and

1230-453: A native tongue today, mostly descendants of German colonial settlers . The period of German colonialism in Namibia also led to the evolution of a Standard German-based pidgin language called " Namibian Black German ", which became a second language for parts of the indigenous population. Although it is nearly extinct today, some older Namibians still have some knowledge of it. German remained

1353-764: A neo-baroque stoplist and mechanical key and stop action was built in 1966/7 (by the Alexander Schuke Potsdam Orgelbau company). It was dismantled in May 1999 for the new Woehl-Organ. 42 stops and other parts from the Schuke-organ in St. Thomas was re-used in the 68 stop-Schuke-organ, built in 2000 to 2005 in Fürstenwalde Cathedral . The Schuke-organ was later replaced by a new organ, built by Gerald Woehl 's organ building company from 1999 to 2000. This "Bach organ"

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1476-480: A number of notable epitaphs, such as the one for the knight Harras (d. 1451) and for councilor Daniel Leicher (1612). The colored windows in the choir were added after 1889. They show a number of historic motifs: a memorial to the fallen of World War I, King Gustavus Adolphus of Sweden , Johann Sebastian Bach, Martin Luther with Elector Friedrich der Weise and Philip Melanchthon as well as Emperor Wilhelm I . The remains of Johann Sebastian Bach have been buried in

1599-679: A popular foreign language among pupils and students, with 300,000 people learning or speaking German in Cameroon in 2010 and over 230,000 in 2020. Today Cameroon is one of the African countries outside Namibia with the highest number of people learning German. In the United States, German is the fifth most spoken language in terms of native and second language speakers after English, Spanish , French , and Chinese (with figures for Cantonese and Mandarin combined), with over 1 million total speakers. In

1722-475: A result, the surviving texts are written in highly disparate regional dialects and exhibit significant Latin influence, particularly in vocabulary. At this point monasteries, where most written works were produced, were dominated by Latin, and German saw only occasional use in official and ecclesiastical writing. While there is no complete agreement over the dates of the Middle High German (MHG) period, it

1845-416: A structural component used to stiffen rubber, similar to the disulfide bridges that rigidify proteins (see biological below). In the most common type of industrial "curing" or hardening and strengthening of natural rubber , elemental sulfur is heated with the rubber to the point that chemical reactions form disulfide bridges between isoprene units of the polymer. This process, patented in 1843, made rubber

1968-433: A tracer in hydrologic studies. Differences in the natural abundances can be used in systems where there is sufficient variation in the S of ecosystem components. Rocky Mountain lakes thought to be dominated by atmospheric sources of sulfate have been found to have measurably different S values than lakes believed to be dominated by watershed sources of sulfate. The radioactive S is formed in cosmic ray spallation of

2091-567: A trip to India. In 1355, the Romanesque choir was changed to Gothic style . Following an inflow of wealth into Leipzig from the discovery of silver in the Ore Mountains (Erzgebirge), the Romanesque nave was demolished and replaced between 1482 and 1496 by the current late-Gothic hall church . The current building was consecrated by Thilo of Trotha, the Bishop of Merseburg , on 10 April 1496. During

2214-458: A work by the master Christophorus Gros from 1585. A clock bell in the lantern of the tower strikes the quarters. In 2020/21 the aforementioned bells were refurbished. Also four new bells were created in the Bachert bell foundry with inscriptions that reflect words from the motets by Johann Sebastian Bach. On Reformation Day 2021, all eight bells rang out together for the first time. The Thomanerchor ,

2337-688: Is a West Germanic language in the Indo-European language family , mainly spoken in Western and Central Europe . It is the most spoken native language within the European Union . It is the most widely spoken and official (or co-official) language in Germany , Austria , Switzerland , Liechtenstein , and the Italian autonomous province of South Tyrol . It is also an official language of Luxembourg , Belgium and

2460-465: Is a common reagent in organic synthesis . Bromine also oxidizes sulfur to form sulfur dibromide and disulfur dibromide . Sulfur oxidizes cyanide and sulfite to give thiocyanate and thiosulfate , respectively. Sulfur reacts with many metals. Electropositive metals give polysulfide salts. Copper, zinc, and silver are attacked by sulfur; see tarnishing . Although many metal sulfides are known, most are prepared by high temperature reactions of

2583-580: Is a recognized minority language in the following countries: In France, the High German varieties of Alsatian and Moselle Franconian are identified as " regional languages ", but the European Charter for Regional or Minority Languages of 1998 has not yet been ratified by the government. Namibia also was a colony of the German Empire, from 1884 to 1915. About 30,000 people still speak German as

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2706-511: Is a soft, bright-yellow solid that is odorless. It melts at 115.21 °C (239.38 °F), and boils at 444.6 °C (832.3 °F). At 95.2 °C (203.4 °F), below its melting temperature, cyclo-octasulfur begins slowly changing from α-octasulfur to the β- polymorph . The structure of the S 8 ring is virtually unchanged by this phase transition, which affects the intermolecular interactions. Cooling molten sulfur freezes at 119.6 °C (247.3 °F), as it predominantly consists of

2829-599: Is about 2 g/cm , depending on the allotrope; all of the stable allotropes are excellent electrical insulators. Sulfur sublimes more or less between 20 °C (68 °F) and 50 °C (122 °F). Sulfur is insoluble in water but soluble in carbon disulfide and, to a lesser extent, in other nonpolar organic solvents, such as benzene and toluene . Under normal conditions, sulfur hydrolyzes very slowly to mainly form hydrogen sulfide and sulfuric acid : The reaction involves adsorption of protons onto S 8 clusters, followed by disproportionation into

2952-451: Is also called brimstone , which means "burning stone". Almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum . The greatest commercial use of the element is the production of sulfuric acid for sulfate and phosphate fertilizers , and other chemical processes. Sulfur is used in matches , insecticides , and fungicides . Many sulfur compounds are odoriferous, and

3075-596: Is also notable for its broad spectrum of dialects , with many varieties existing in Europe and other parts of the world. Some of these non-standard varieties have become recognized and protected by regional or national governments. Since 2004, heads of state of the German-speaking countries have met every year, and the Council for German Orthography has been the main international body regulating German orthography . German

3198-546: Is an Indo-European language that belongs to the West Germanic group of the Germanic languages . The Germanic languages are traditionally subdivided into three branches: North Germanic , East Germanic , and West Germanic . The first of these branches survives in modern Danish , Swedish , Norwegian , Faroese , and Icelandic , all of which are descended from Old Norse . The East Germanic languages are now extinct, and Gothic

3321-472: Is called the "German Sprachraum ". German is the official language of the following countries: German is a co-official language of the following countries: Although expulsions and (forced) assimilation after the two World wars greatly diminished them, minority communities of mostly bilingual German native speakers exist in areas both adjacent to and detached from the Sprachraum. Within Europe, German

3444-430: Is complicated by the existence of several varieties whose status as separate "languages" or "dialects" is disputed for political and linguistic reasons, including quantitatively strong varieties like certain forms of Alemannic and Low German . With the inclusion or exclusion of certain varieties, it is estimated that approximately 90–95 million people speak German as a first language , 10–25   million speak it as

3567-417: Is explained by its production in the so-called alpha-process (one of the main classes of nuclear fusion reactions) in exploding stars. Other stable sulfur isotopes are produced in the bypass processes related with Ar, and their composition depends on a type of a stellar explosion. For example, proportionally more S comes from novae than from supernovae . On the planet Earth the sulfur isotopic composition

3690-520: Is generally seen as ending when the 1346–53 Black Death decimated Europe's population. Modern High German begins with the Early New High German (ENHG) period, which Wilhelm Scherer dates 1350–1650, terminating with the end of the Thirty Years' War . This period saw the further displacement of Latin by German as the primary language of courtly proceedings and, increasingly, of literature in

3813-595: Is generally seen as lasting from 1050 to 1350. This was a period of significant expansion of the geographical territory occupied by Germanic tribes, and consequently of the number of German speakers. Whereas during the Old High German period the Germanic tribes extended only as far east as the Elbe and Saale rivers, the MHG period saw a number of these tribes expanding beyond this eastern boundary into Slavic territory (known as

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3936-464: Is higher than the melting point of sulfur. Native sulfur is synthesized by anaerobic bacteria acting on sulfate minerals such as gypsum in salt domes . Significant deposits in salt domes occur along the coast of the Gulf of Mexico , and in evaporites in eastern Europe and western Asia. Native sulfur may be produced by geological processes alone. Fossil-based sulfur deposits from salt domes were once

4059-559: Is less closely related to languages based on Low Franconian dialects (e.g., Dutch and Afrikaans), Low German or Low Saxon dialects (spoken in northern Germany and southern Denmark ), neither of which underwent the High German consonant shift. As has been noted, the former of these dialect types is Istvaeonic and the latter Ingvaeonic, whereas the High German dialects are all Irminonic; the differences between these languages and standard German are therefore considerable. Also related to German are

4182-573: Is mildly acidic: Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide (see below, under precautions ). The two principal sulfur oxides are obtained by burning sulfur: Many other sulfur oxides are observed including the sulfur-rich oxides include sulfur monoxide , disulfur monoxide , disulfur dioxides, and higher oxides containing peroxo groups. Sulfur reacts with fluorine to give

4305-435: Is one of the major languages of the world . German is the second-most widely spoken Germanic language , after English, both as a first and as a second language . German is also widely taught as a foreign language , especially in continental Europe (where it is the third most taught foreign language after English and French), and in the United States. Overall, German is the fourth most commonly learned second language, and

4428-587: Is one of the three biggest newspapers in Namibia and the only German-language daily in Africa. An estimated 12,000 people speak German or a German variety as a first language in South Africa, mostly originating from different waves of immigration during the 19th and 20th centuries. One of the largest communities consists of the speakers of "Nataler Deutsch", a variety of Low German concentrated in and around Wartburg . The South African constitution identifies German as

4551-401: Is partly derived from Latin and Greek , along with fewer words borrowed from French and Modern English . English, however, is the main source of more recent loanwords . German is a pluricentric language ; the three standardized variants are German , Austrian , and Swiss Standard German . Standard German is sometimes called High German , which refers to its regional origin. German

4674-399: Is produced by rapid cooling of molten sulfur—for example, by pouring it into cold water. X-ray crystallography studies show that the amorphous form may have a helical structure with eight atoms per turn. The long coiled polymeric molecules make the brownish substance elastic , and in bulk it has the feel of crude rubber. This form is metastable at room temperature and gradually reverts to

4797-481: Is rung only on solemnities. Their weight is 5,2 metric tons, the tone an a. Its famous incised drawings were created by Nikolaus Eisenberg. The second bell, Mittelglocke (midbell), was cast in 1574 by Wolf Hilliger, and the so-called Mönchs- oder Beichtglocke (monk's or confessional bell) founded in 1634 by Jakob König, which also strikes the hours. The smallest of the historical bells is the Gebetsglocke (prayer's bell),

4920-510: Is the Sachsenspiegel , the first book of laws written in Middle Low German ( c.  1220 ). The abundance and especially the secular character of the literature of the MHG period demonstrate the beginnings of a standardized written form of German, as well as the desire of poets and authors to be understood by individuals on supra-dialectal terms. The Middle High German period

5043-557: Is the 10th most common element in the universe . Sulfur, usually as sulfide, is present in many types of meteorites . Ordinary chondrites contain on average 2.1% sulfur, and carbonaceous chondrites may contain as much as 6.6%. It is normally present as troilite (FeS), but there are exceptions, with carbonaceous chondrites containing free sulfur, sulfates and other sulfur compounds. The distinctive colors of Jupiter 's volcanic moon Io are attributed to various forms of molten, solid, and gaseous sulfur. In July 2024, elemental sulfur

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5166-566: Is the only language in this branch which survives in written texts. The West Germanic languages, however, have undergone extensive dialectal subdivision and are now represented in modern languages such as English, German, Dutch , Yiddish , Afrikaans , and others. Within the West Germanic language dialect continuum, the Benrath and Uerdingen lines (running through Düsseldorf - Benrath and Krefeld - Uerdingen , respectively) serve to distinguish

5289-481: Is understood in all areas where German is spoken. Approximate distribution of native German speakers (assuming a rounded total of 95 million) worldwide: As a result of the German diaspora , as well as the popularity of German taught as a foreign language , the geographical distribution of German speakers (or "Germanophones") spans all inhabited continents. However, an exact, global number of native German speakers

5412-408: Is used as a reagent to make the polymer rayon and many organosulfur compounds. Unlike carbon monoxide , carbon monosulfide is stable only as an extremely dilute gas, found between solar systems. Organosulfur compounds are responsible for some of the unpleasant odors of decaying organic matter. They are widely known as the odorant in domestic natural gas, garlic odor, and skunk spray, as well as

5535-673: The Ostsiedlung ). With the increasing wealth and geographic spread of the Germanic groups came greater use of German in the courts of nobles as the standard language of official proceedings and literature. A clear example of this is the mittelhochdeutsche Dichtersprache employed in the Hohenstaufen court in Swabia as a standardized supra-dialectal written language. While these efforts were still regionally bound, German began to be used in place of Latin for certain official purposes, leading to

5658-627: The Alamanni , Bavarian, and Thuringian groups, all belonging to the Elbe Germanic group ( Irminones ), which had settled in what is now southern-central Germany and Austria between the second and sixth centuries, during the great migration. In general, the surviving texts of Old High German (OHG) show a wide range of dialectal diversity with very little written uniformity. The early written tradition of OHG survived mostly through monasteries and scriptoria as local translations of Latin originals; as

5781-522: The Early Middle Ages . German is an inflected language , with four cases for nouns, pronouns, and adjectives (nominative, accusative, genitive, dative); three genders (masculine, feminine, neuter) and two numbers (singular, plural). It has strong and weak verbs . The majority of its vocabulary derives from the ancient Germanic branch of the Indo-European language family, while a smaller share

5904-417: The European Union 's population, spoke German as their mother tongue, making it the second most widely spoken language on the continent after Russian and the second biggest language in terms of overall speakers (after English), as well as the most spoken native language. The area in central Europe where the majority of the population speaks German as a first language and has German as a (co-)official language

6027-514: The German states . While these states were still part of the Holy Roman Empire , and far from any form of unification, the desire for a cohesive written language that would be understandable across the many German-speaking principalities and kingdoms was stronger than ever. As a spoken language German remained highly fractured throughout this period, with a vast number of often mutually incomprehensible regional dialects being spoken throughout

6150-490: The Hershey-Chase experiment . Because of the weak beta activity of S, its compounds are relatively safe as long as they are not ingested or absorbed by the body. S is created inside massive stars, at a depth where the temperature exceeds 2.5×10  K, by the fusion of one nucleus of silicon plus one nucleus of helium. As this nuclear reaction is part of the alpha process that produces elements in abundance, sulfur

6273-724: The Holy Roman Emperor Maximilian I , and the other being Meißner Deutsch , used in the Electorate of Saxony in the Duchy of Saxe-Wittenberg . Alongside these courtly written standards, the invention of the printing press led to the development of a number of printers' languages ( Druckersprachen ) aimed at making printed material readable and understandable across as many diverse dialects of German as possible. The greater ease of production and increased availability of written texts brought about increased standardisation in

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6396-644: The Old High German language in several Elder Futhark inscriptions from as early as the sixth century AD (such as the Pforzen buckle ), the Old High German period is generally seen as beginning with the Abrogans (written c.  765–775 ), a Latin-German glossary supplying over 3,000 Old High German words with their Latin equivalents. After the Abrogans , the first coherent works written in Old High German appear in

6519-464: The Reformation it was converted to Lutheranism . The reformer Martin Luther preached here on Pentecost Sunday in 1539. The collegiate buildings were demolished in 1541 following the college's dissolution. The current church tower was first built in 1537 and rebuilt in 1702. Chapels added in the 17th century and an ante-building along the northern front of the nave with two stairways were removed at

6642-640: The Sprachraum in Europe. German is used in a wide variety of spheres throughout the country, especially in business, tourism, and public signage, as well as in education, churches (most notably the German-speaking Evangelical Lutheran Church in Namibia (GELK) ), other cultural spheres such as music, and media (such as German language radio programs by the Namibian Broadcasting Corporation ). The Allgemeine Zeitung

6765-504: The St. John Church , also damaged by bombs in 1943, and in 1950 the remains of Johann Sebastian Bach were moved from there to the St. Thomas church. In the 20th century, sulfur emitted from nearby coal mines , and other pollutants in the atmosphere caused the deterioration of exterior stonework and statuary, and even of interior Gothic paintings . In addition, the roof structure suffered from damage due to insects and moisture. For these reasons,

6888-570: The St. Paul Church , the church of the University of Leipzig, destroyed in 1968 by the Communist authorities) was located in the St. Thomas Church. It was moved to the new St. Paul Church in 2014 and replaced in 2016 with a Gothic-revival altar by Constantin Lipsius made in 1888, which had been removed in 1964. A statue of Felix Mendelssohn Bartholdy , who lived in Leipzig from 1835 until his death in 1847,

7011-536: The Standard German language in its written form, and the Duden Handbook was declared its standard definition. Punctuation and compound spelling (joined or isolated compounds) were not standardized in the process. The Deutsche Bühnensprache ( lit.   ' German stage language ' ) by Theodor Siebs had established conventions for German pronunciation in theatres , three years earlier; however, this

7134-454: The Upper German dialects spoken in the southern German-speaking countries , such as Swiss German ( Alemannic dialects ) and the various Germanic dialects spoken in the French region of Grand Est , such as Alsatian (mainly Alemannic, but also Central–and   Upper Franconian dialects) and Lorraine Franconian (Central Franconian). After these High German dialects, standard German

7257-408: The noble gases . Sulfur polycations, S 2+ 8 , S 2+ 4 and S 2+ 16 are produced when sulfur is reacted with oxidizing agents in a strongly acidic solution. The colored solutions produced by dissolving sulfur in oleum were first reported as early as 1804 by C. F. Bucholz, but the cause of the color and the structure of the polycations involved was only determined in

7380-462: The pagan Germanic tradition. Of particular interest to scholars, however, has been the Hildebrandslied , a secular epic poem telling the tale of an estranged father and son unknowingly meeting each other in battle. Linguistically, this text is highly interesting due to the mixed use of Old Saxon and Old High German dialects in its composition. The written works of this period stem mainly from

7503-473: The sulfate minerals , such as gypsum (calcium sulfate), alunite (potassium aluminium sulfate), and barite (barium sulfate). On Earth, just as upon Jupiter's moon Io, elemental sulfur occurs naturally in volcanic emissions, including emissions from hydrothermal vents . The main industrial source of sulfur has become petroleum and natural gas . Common oxidation states of sulfur range from −2 to +6. Sulfur forms stable compounds with all elements except

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7626-409: The (among others) protein keratin , found in outer skin, hair, and feathers. Sulfur is one of the core chemical elements needed for biochemical functioning and is an elemental macronutrient for all living organisms. Sulfur forms several polyatomic molecules. The best-known allotrope is octasulfur , cyclo-S 8 . The point group of cyclo-S 8 is D 4d and its dipole moment is 0 D. Octasulfur

7749-414: The 2010s, it was thought that sulfate reduction could fractionate sulfur isotopes up to 46 permil and fractionation larger than 46 permil recorded in sediments must be due to disproportionation of sulfur compounds in the sediment. This view has changed since the 2010s as experiments showed that sulfate-reducing bacteria can fractionate to 66 permil. As substrates for disproportionation are limited by

7872-530: The 3rd century, the Chinese had discovered that sulfur could be extracted from pyrite . Chinese Daoists were interested in sulfur's flammability and its reactivity with certain metals, yet its earliest practical uses were found in traditional Chinese medicine . The Wujing Zongyao of 1044 AD described various formulas for Chinese black powder , which is a mixture of potassium nitrate ( KNO 3 ), charcoal , and sulfur. Indian alchemists, practitioners of

7995-714: The Empire. Its use indicated that the speaker was a merchant or someone from an urban area, regardless of nationality. Prague (German: Prag ) and Budapest ( Buda , German: Ofen ), to name two examples, were gradually Germanized in the years after their incorporation into the Habsburg domain; others, like Pressburg ( Pozsony , now Bratislava), were originally settled during the Habsburg period and were primarily German at that time. Prague, Budapest, Bratislava, and cities like Zagreb (German: Agram ) or Ljubljana (German: Laibach ), contained significant German minorities. In

8118-718: The Frisian languages— North Frisian (spoken in Nordfriesland ), Saterland Frisian (spoken in Saterland ), and West Frisian (spoken in Friesland )—as well as the Anglic languages of English and Scots. These Anglo-Frisian dialects did not take part in the High German consonant shift, and the Anglic languages also adopted much vocabulary from both Old Norse and the Norman language . The history of

8241-524: The German language begins with the High German consonant shift during the Migration Period , which separated Old High German dialects from Old Saxon . This sound shift involved a drastic change in the pronunciation of both voiced and voiceless stop consonants ( b , d , g , and p , t , k , respectively). The primary effects of the shift were the following below. While there is written evidence of

8364-447: The German states; the invention of the printing press c.  1440 and the publication of Luther's vernacular translation of the Bible in 1534, however, had an immense effect on standardizing German as a supra-dialectal written language. The ENHG period saw the rise of several important cross-regional forms of chancery German, one being gemeine tiutsch , used in the court of

8487-675: The Germanic dialects that were affected by the High German consonant shift (south of Benrath) from those that were not (north of Uerdingen). The various regional dialects spoken south of these lines are grouped as High German dialects, while those spoken to the north comprise the Low German and Low Franconian dialects. As members of the West Germanic language family, High German, Low German, and Low Franconian have been proposed to be further distinguished historically as Irminonic , Ingvaeonic , and Istvaeonic , respectively. This classification indicates their historical descent from dialects spoken by

8610-547: The Irminones (also known as the Elbe group), Ingvaeones (or North Sea Germanic group), and Istvaeones (or Weser–Rhine group). Standard German is based on a combination of Thuringian - Upper Saxon and Upper Franconian dialects, which are Central German and Upper German dialects belonging to the High German dialect group. German is therefore closely related to the other languages based on High German dialects, such as Luxembourgish (based on Central Franconian dialects ) and Yiddish . Also closely related to Standard German are

8733-644: The Italian autonomous region of Friuli-Venezia Giulia , as well as a recognized national language in Namibia . There are also notable German-speaking communities in France ( Alsace ), the Czech Republic ( North Bohemia ), Poland ( Upper Silesia ), Slovakia ( Košice Region , Spiš , and Hauerland ), Denmark ( North Schleswig ), Romania and Hungary ( Sopron ). Overseas, sizeable communities of German-speakers are found in Brazil ( Blumenau and Pomerode ), South Africa ( Kroondal ), Namibia , among others, some communities have decidedly Austrian German or Swiss German characters (e.g. Pozuzo , Peru). German

8856-581: The Johanniskirche burned down. The bones from Bach and Christian Fürchtegott Gellert were found without damages in 1949 in the crypt of the ruin. The bone from Bach was transferred to the Thomaskirche. The new grave with a bronze cover (sponsored by the Leipzig cultural officer of the Soviet Army) was inaugurated on 28 July 1950, 200 years after the death of the composer, who is now buried in the sanctuary of

8979-507: The MHG period. Significantly, these texts include a number of impressive secular works, such as the Nibelungenlied , an epic poem telling the story of the dragon -slayer Siegfried ( c.  thirteenth century ), and the Iwein , an Arthurian verse poem by Hartmann von Aue ( c.  1203 ), lyric poems , and courtly romances such as Parzival and Tristan . Also noteworthy

9102-455: The Thomaskirche since 1950. After his death on 28 July 1750, Bach was laid to rest in the hospital cemetery of the Johanniskirche in Leipzig. With the start of the Bach renaissance in the 19th century, the public started to become interested in his remains and their whereabouts. In 1894, the anatomy professor Wilhelm His was commissioned to identify the composer's remains amongst disinterred bones from

9225-515: The Thomaskirche. Another notable feature of the Thomaskirche is that it contains two pipe organs . The older one is a Romantic organ by Wilhelm Sauer , built from 1884 to 1889 with three manuals, 63 stops and mechanical key and pneumatic stop action. Thomasorganist Carl Piutti ordered in 1902 two new stops and a higher wind pressure from Sauer. To 1908 Sauer rebuilt and enlarged the organ after instructions from Karl Straube , it contains now pneumatic key action and 88 stops. Between 1934 and 1940, in

9348-494: The activity of sulfate-reducing bacteria in the time of formation of the sample, or suggest the main sources of sulfur in ecosystems. However, there are ongoing discussions over the real reason for the δ S shifts, biological activity or postdeposit alteration. For example, when sulfide minerals are precipitated, isotopic equilibration among solids and liquid may cause small differences in the δ S values of co-genetic minerals. The differences between minerals can be used to estimate

9471-436: The atmospheric Ar . This fact may be used to verify the presence of recent (up to 1 year) atmospheric sediments in various materials. This isotope may be obtained artificially by different ways. In practice, the reaction Cl + n → S + p is used by irradiating potassium chloride with neutrons. The isotope S is used in various sulfur-containing compounds as a radioactive tracer for many biological studies, for example,

9594-592: The basis for commercial production in the United States, Russia, Turkmenistan, and Ukraine. Such sources have become of secondary commercial importance, and most are no longer worked but commercial production is still carried out in the Osiek mine in Poland. Common naturally occurring sulfur compounds include the sulfide minerals , such as pyrite (iron sulfide), cinnabar (mercury sulfide), galena (lead sulfide), sphalerite (zinc sulfide), and stibnite (antimony sulfide); and

9717-462: The cemetery where Bach had been buried. He concluded that "the assumption that the bones of an elderly man, which had been found in an oak coffin near the Johanneskirche, were the remains of Johann Sebastian Bach" (translated from German) was very likely. On 16 July 1900 the bones were placed into a stone sarcophagus underneath the Johanniskirche. During the bombardment of Leipzig on 4 December 1943

9840-407: The centuries and damaged by Allied incendiary bombs in 1943, the church mainly retains the character of a late-Gothic hall church . The Thomanerchor , the church choir, likely founded in 1212, is an internationally known boys' choir . The current property was the site of a church at least since the 12th century. Foundations of a Romanesque building were discovered in the choir and crossing of

9963-530: The chemical formula S 8 . Elemental sulfur is a bright yellow, crystalline solid at room temperature . Sulfur is the tenth most abundant element by mass in the universe and the fifth most common on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals . Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India , ancient Greece , China , and ancient Egypt . Historically and in literature sulfur

10086-509: The choir of the Thomaskirche, was founded in 1212 and is one of the oldest and most famous boys' choirs in Germany. It is headed by the Thomaskantor , an office that has been held by many well-known composers and musicians, including Johann Sebastian Bach from 1723 until his death in 1750. German language German (German: Deutsch , pronounced [dɔʏtʃ] )

10209-565: The church was listed in the 2000 World Monuments Watch by the World Monuments Fund . Repairs were swiftly undertaken with financial support from the Fund and from American Express . Repairs on the church from 1961 to 1964 also attempted to emphasize the Gothic hall church character of the building. Another renovation followed in 1991. From 1993 to 2014, a 15th-century Gothic altar (originally in

10332-501: The composition of reaction products. While reaction between sulfur and oxygen under normal conditions gives sulfur dioxide (oxidation state +4), formation of sulfur trioxide (oxidation state +6) requires a temperature of 400–600 °C (750–1,100 °F) and presence of a catalyst. In reactions with elements of lesser electronegativity , it reacts as an oxidant and forms sulfides, where it has oxidation state −2. Sulfur reacts with nearly all other elements except noble gases, even with

10455-451: The crystalline molecular allotrope, which is no longer elastic. This process happens over a matter of hours to days, but can be rapidly catalyzed. Sulfur has 23 known isotopes , four of which are stable: S ( 94.99% ± 0.26% ), S ( 0.75% ± 0.02% ), S ( 4.25% ± 0.24% ), and S ( 0.01% ± 0.01% ). Other than S, with a half-life of 87 days, the radioactive isotopes of sulfur have half-lives less than 3 hours. The preponderance of S

10578-460: The current church. Between 1212 and 1222 the earlier structure became the church of the new St. Thomas college of Augustinian canons founded by Markgraf Dietrich von Meissen. This college later became the core of the University of Leipzig (founded in 1409). In 1217, the minnesinger Heinrich von Morungen bequeathed to the church a relic of St. Thomas as he entered the order of canons after

10701-430: The development of non-local forms of language and exposed all speakers to forms of German from outside their own area. With Luther's rendering of the Bible in the vernacular, German asserted itself against the dominance of Latin as a legitimate language for courtly, literary, and now ecclesiastical subject-matter. His Bible was ubiquitous in the German states: nearly every household possessed a copy. Nevertheless, even with

10824-452: The dialect so as to make the work as natural and accessible to German speakers as possible. Copies of Luther's Bible featured a long list of glosses for each region, translating words which were unknown in the region into the regional dialect. Luther said the following concerning his translation method: One who would talk German does not ask the Latin how he shall do it; he must ask the mother in

10947-507: The eastern provinces of Banat , Bukovina , and Transylvania (German: Banat, Buchenland, Siebenbürgen ), German was the predominant language not only in the larger towns—like Temeschburg ( Timișoara ), Hermannstadt ( Sibiu ), and Kronstadt ( Brașov )—but also in many smaller localities in the surrounding areas. In 1901, the Second Orthographic Conference ended with a (nearly) complete standardization of

11070-464: The elements. Geoscientists also study the isotopes of metal sulfides in rocks and sediment to study environmental conditions in the Earth's past. Some of the main classes of sulfur-containing organic compounds include the following: Compounds with carbon–sulfur multiple bonds are uncommon, an exception being carbon disulfide , a volatile colorless liquid that is structurally similar to carbon dioxide. It

11193-409: The end of the 19th century. The composer Johann Sebastian Bach was Thomaskantor , director of music, from 1723 until his death in 1750 and taught at its affiliated school . A statue of Bach by the Leipzig sculptor Carl Seffner that stands next to the church was dedicated in 1908. Wolfgang Amadeus Mozart played the church organ on one of his European tours in 1789. In 1806, the church served as

11316-406: The highly reactive sulfur tetrafluoride and the highly inert sulfur hexafluoride . Whereas fluorine gives S(IV) and S(VI) compounds, chlorine gives S(II) and S(I) derivatives. Thus, sulfur dichloride , disulfur dichloride , and higher chlorosulfanes arise from the chlorination of sulfur. Sulfuryl chloride and chlorosulfuric acid are derivatives of sulfuric acid; thionyl chloride (SOCl 2 )

11439-435: The home, the children on the streets, the common man in the market-place and note carefully how they talk, then translate accordingly. They will then understand what is said to them because it is German. When Christ says ' ex abundantia cordis os loquitur ,' I would translate, if I followed the papists, aus dem Überflusz des Herzens redet der Mund . But tell me is this talking German? What German understands such stuff? No,

11562-474: The influence of Luther's Bible as an unofficial written standard, a widely accepted standard for written German did not appear until the middle of the eighteenth century. German was the language of commerce and government in the Habsburg Empire , which encompassed a large area of Central and Eastern Europe . Until the mid-nineteenth century, it was essentially the language of townspeople throughout most of

11685-555: The largest concentrations of German speakers are in the states of Rio Grande do Sul (where Riograndenser Hunsrückisch developed), Santa Catarina , and Espírito Santo . Sulfur This is an accepted version of this page Sulfur (also spelled sulphur in British English ) is a chemical element ; it has symbol S and atomic number 16. It is abundant , multivalent and nonmetallic . Under normal conditions , sulfur atoms form cyclic octatomic molecules with

11808-484: The largest documented single crystal measuring 22 cm × 16 cm × 11 cm (8.7 in × 6.3 in × 4.3 in). Historically, Sicily was a major source of sulfur in the Industrial Revolution . Lakes of molten sulfur up to about 200 m (660 ft) in diameter have been found on the sea floor, associated with submarine volcanoes , at depths where the boiling point of water

11931-415: The late 1960s. S 2+ 8 is deep blue, S 2+ 4 is yellow and S 2+ 16 is red. Reduction of sulfur gives various polysulfides with the formula S x , many of which have been obtained in crystalline form. Illustrative is the production of sodium tetrasulfide : Some of these dianions dissociate to give radical anions , such as S − 3 gives the blue color of

12054-461: The main portal in the west facade also date from this period. During the Nazi era, the church office worked with government officials to identify which congregants were of Sinti-Romani heritage, ultimately leading to the death of certain parishioners at concentration camps. On 4 December 1943, the tower was damaged in an Allied bombing raid on Leipzig, requiring repair. In 1949 the authorities demolished

12177-402: The mother in the home and the plain man would say, Wesz das Herz voll ist, des gehet der Mund über . Luther's translation of the Bible into High German was also decisive for the German language and its evolution from Early New High German to modern Standard German. The publication of Luther's Bible was a decisive moment in the spread of literacy in early modern Germany , and promoted

12300-630: The ninth century, chief among them being the Muspilli , Merseburg charms , and Hildebrandslied , and other religious texts (the Georgslied , Ludwigslied , Evangelienbuch , and translated hymns and prayers). The Muspilli is a Christian poem written in a Bavarian dialect offering an account of the soul after the Last Judgment , and the Merseburg charms are transcriptions of spells and charms from

12423-573: The notoriously unreactive metal iridium (yielding iridium disulfide ). Some of those reactions require elevated temperatures. Sulfur forms over 30 solid allotropes , more than any other element. Besides S 8 , several other rings are known. Removing one atom from the crown gives S 7 , which is of a deeper yellow than S 8 . HPLC analysis of "elemental sulfur" reveals an equilibrium mixture of mainly S 8 , but with S 7 and small amounts of S 6 . Larger rings have been prepared, including S 12 and S 18 . Amorphous or "plastic" sulfur

12546-407: The product of sulfate reduction , the isotopic effect of disproportionation should be less than 16 permil in most sedimentary settings. In forest ecosystems, sulfate is derived mostly from the atmosphere; weathering of ore minerals and evaporites contribute some sulfur. Sulfur with a distinctive isotopic composition has been used to identify pollution sources, and enriched sulfur has been added as

12669-462: The pronunciation of the ending -ig as [ɪk] instead of [ɪç]. In Northern Germany, High German was a foreign language to most inhabitants, whose native dialects were subsets of Low German. It was usually encountered only in writing or formal speech; in fact, most of High German was a written language, not identical to any spoken dialect, throughout the German-speaking area until well into the 19th century. However, wider standardization of pronunciation

12792-420: The reaction products. The second, fourth and sixth ionization energies of sulfur are 2252 kJ/mol, 4556 kJ/mol and 8495.8 kJ/mol, respectively. The composition of reaction products of sulfur with oxidants (and its oxidation state) depends on whether releasing of reaction energy overcomes these thresholds. Applying catalysts and/or supply of external energy may vary sulfur's oxidation state and

12915-509: The rock lapis lazuli . This reaction highlights a distinctive property of sulfur: its ability to catenate (bind to itself by formation of chains). Protonation of these polysulfide anions produces the polysulfanes , H 2 S x , where x = 2, 3, and 4. Ultimately, reduction of sulfur produces sulfide salts: The interconversion of these species is exploited in the sodium–sulfur battery . Treatment of sulfur with hydrogen gives hydrogen sulfide . When dissolved in water, hydrogen sulfide

13038-719: The smells of odorized natural gas, skunk scent, bad breath , grapefruit , and garlic are due to organosulfur compounds. Hydrogen sulfide gives the characteristic odor to rotting eggs and other biological processes. Sulfur is an essential element for all life, almost always in the form of organosulfur compounds or metal sulfides. Amino acids (two proteinogenic : cysteine and methionine , and many other non-coded : cystine , taurine , etc.) and two vitamins ( biotin and thiamine ) are organosulfur compounds crucial for life. Many cofactors also contain sulfur, including glutathione , and iron–sulfur proteins . Disulfides , S–S bonds, confer mechanical strength and insolubility of

13161-541: The states of North Dakota and South Dakota , German is the most common language spoken at home after English. As a legacy of significant German immigration to the country , German geographical names can be found throughout the Midwest region , such as New Ulm and Bismarck (North Dakota's state capital), plus many other regions. A number of German varieties have developed in the country and are still spoken today, such as Pennsylvania Dutch and Texas German . In Brazil,

13284-465: The temperature of equilibration. The δ C and δ S of coexisting carbonate minerals and sulfides can be used to determine the pH and oxygen fugacity of the ore-bearing fluid during ore formation. Scientists measure the sulfur isotopes of minerals in rocks and sediments to study the redox conditions in past oceans. Sulfate-reducing bacteria in marine sediment fractionate sulfur isotopes as they take in sulfate and produce sulfide . Prior to

13407-457: The term " fire-and-brimstone " sermons , in which listeners are reminded of the fate of eternal damnation that await the unbelieving and unrepentant. It is from this part of the Bible that Hell is implied to "smell of sulfur" (likely due to its association with volcanic activity). According to the Ebers Papyrus , a sulfur ointment was used in ancient Egypt to treat granular eyelids. Sulfur

13530-496: The third most commonly learned second language in the United States in K-12 education. The language has been influential in the fields of philosophy, theology, science, and technology. It is the second most commonly used language in science and the third most widely used language on websites . The German-speaking countries are ranked fifth in terms of annual publication of new books, with one-tenth of all books (including e-books) in

13653-507: The working time from Günther Ramin , 16 romantic stops were changed against neo-baroque stops. The German organ builder Christian Scheffler reconstructed and repaired the Sauer-organ in two phases: 1988 to 1993 and in the years to 2005. He restored the organ in the situation in 1908. Since the Sauer-Organ was considered unsuitable for Bach's music, a second organ with three manuals, 47 stops,

13776-543: The world being published in German. German is most closely related to other West Germanic languages, namely Afrikaans , Dutch , English , the Frisian languages , and Scots . It also contains close similarities in vocabulary to some languages in the North Germanic group , such as Danish , Norwegian , and Swedish . Modern German gradually developed from Old High German , which in turn developed from Proto-Germanic during

13899-579: The written form of German. One of the central events in the development of ENHG was the publication of Luther's translation of the Bible into High German (the New Testament was published in 1522; the Old Testament was published in parts and completed in 1534). Luther based his translation primarily on the Meißner Deutsch of Saxony , spending much time among the population of Saxony researching

14022-419: The β-S 8 molecules. Between its melting and boiling temperatures, octasulfur changes its allotrope again, turning from β-octasulfur to γ-sulfur, again accompanied by a lower density but increased viscosity due to the formation of polymers . At higher temperatures, the viscosity decreases as depolymerization occurs. Molten sulfur assumes a dark red color above 200 °C (392 °F). The density of sulfur

14145-429: Was a "neutral" language as there were virtually no English native speakers in Namibia at that time. German, Afrikaans, and several indigenous languages thus became "national languages" by law, identifying them as elements of the cultural heritage of the nation and ensuring that the state acknowledged and supported their presence in the country. Today, Namibia is considered to be the only German-speaking country outside of

14268-615: Was accidentally discovered to exist on Mars after the Curiosity rover drove over and crushed a rock, revealing sulfur crystals inside it. Sulfur is the fifth most common element by mass in the Earth. Elemental sulfur can be found near hot springs and volcanic regions in many parts of the world, especially along the Pacific Ring of Fire ; such volcanic deposits are mined in Indonesia, Chile, and Japan. These deposits are polycrystalline, with

14391-530: Was an artificial standard that did not correspond to any traditional spoken dialect. Rather, it was based on the pronunciation of German in Northern Germany, although it was subsequently regarded often as a general prescriptive norm, despite differing pronunciation traditions especially in the Upper-German-speaking regions that still characterise the dialect of the area today – especially

14514-423: Was dedicated on 18 October 2008, when it was re-erected opposite the St. Thomas Church on the occasion of the year of his 200th birthday. The 6-meter (20 ft) statue depicts the former Gewandhaus Orchestra director and composer in bronze. Celebratory speeches were given by Kurt Masur , also a former Gewandhaus Orchestra director, and Burkhard Jung, mayor of Leipzig. The original statue designed by Werner Stein

14637-729: Was designed to look similar to the Johann-Scheibe-organ, on which Bach had played in the Paulinerkirche, the stoplist is inspired from the Stertzing-organ, designed by Johann Christoph Bach in St. Georg´s Church in Eisenach during J. S. Bach´s childness. The two bell chambers of the tower hold eight bells with a total weight of 10,8 metric tons. The largest and most precious bell is the Gloriosa, made in 1477 by Theodericus Reinhard; it

14760-549: Was determined by the Sun. Though it was assumed that the distribution of different sulfur isotopes would be more or less equal, it has been found that proportions of the two most abundant sulfur isotopes S and S varies in different samples. Assaying of the isotope ratio ( δ S ) in the samples suggests their chemical history, and with support of other methods, it allows to age-date the samples, estimate temperature of equilibrium between ore and water, determine pH and oxygen fugacity , identify

14883-485: Was established on the basis of public speaking in theatres and the media during the 20th century and documented in pronouncing dictionaries. Official revisions of some of the rules from 1901 were not issued until the controversial German orthography reform of 1996 was made the official standard by governments of all German-speaking countries. Media and written works are now almost all produced in Standard German which

15006-501: Was first dedicated on 26 May 1892. It had been located on the east side of the Gewandhaus until 9 November 1936, when it was taken down by the Nazis because of the composer's Jewish background. The church measures 76 meters in length, of which the nave accounts for 50 meters. The nave is 25 meters wide and its walls reach a maximum height of 18 meters. The church's roof is unusually steep with

15129-622: Was used for fumigation in preclassical Greece ; this is mentioned in the Odyssey . Pliny the Elder discusses sulfur in book 35 of his Natural History , saying that its best-known source is the island of Melos . He mentions its use for fumigation, medicine, and bleaching cloth. A natural form of sulfur known as shiliuhuang ( 石硫黄 ) was known in China since the 6th century BC and found in Hanzhong . By

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