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103-543: Stanlow Refinery is an oil refinery owned by Essar Energy in Ellesmere Port , North West England . Until 2011, it was owned by Shell UK . The refinery is situated on the south bank of the Manchester Ship Canal , which is used to transport seaborne oil for refining and chemicals for Essar. Stanlow has a refining capacity of 12 million tonnes per year with a barrel per day capacity of 296,000. Consequently, it

206-402: A devolatilization process to separate usable oil from the waste asphaltene material. Certain cracked streams are particularly suitable to produce petrochemicals includes polypropylene, heavier polymers, and block polymers based on the molecular weight and the characteristics of the olefin specie that is cracked from the source feedstock. Oil refineries are large-scale plants, processing about

309-632: A broad range of several applications. Once separated and purified of any contaminants and impurities, the fuel or lubricant can be sold without further processing. Smaller molecules such as isobutane and propylene or butylenes can be recombined to meet specific octane requirements by processes such as alkylation , or more commonly, dimerization . The octane grade of gasoline can also be improved by catalytic reforming , which involves removing hydrogen from hydrocarbons producing compounds with higher octane ratings such as aromatics . Intermediate products such as gasoils can even be reprocessed to break

412-748: A capacity of 940,000 bbl/d (149,000 m /d) but effective run rates have been dramatically lower due to the impact of 20 years of sanctions , and SK Energy 's Ulsan in South Korea with 840,000 bbl/d (134,000 m /d) are the second and third largest, respectively. Prior to World War II in the early 1940s, most petroleum refineries in the United States consisted simply of crude oil distillation units (often referred to as atmospheric crude oil distillation units). Some refineries also had vacuum distillation units as well as thermal cracking units such as visbreakers (viscosity breakers, units to lower

515-570: A decade or so, and nitrous oxides last about 100 years. The graph gives some indication of which regions have contributed most to human-induced climate change. When these numbers are calculated per capita cumulative emissions based on then-current population the situation is shown even more clearly. The ratio in per capita emissions between industrialized countries and developing countries was estimated at more than 10 to 1. Non- OECD countries accounted for 42% of cumulative energy-related CO 2 emissions between 1890 and 2007. Over this time period,

618-800: A few percent sulfur -containing molecules, elemental sulfur is also often produced as a petroleum product. Carbon , in the form of petroleum coke , and hydrogen may also be produced as petroleum products. The hydrogen produced is often used as an intermediate product for other oil refinery processes such as hydrocracking and hydrodesulfurization . Petroleum products are usually grouped into four categories: light distillates (LPG, gasoline, naphtha), middle distillates (kerosene, jet fuel, diesel), heavy distillates, and residuum (heavy fuel oil, lubricating oils, wax, asphalt). These require blending various feedstocks, mixing appropriate additives, providing short-term storage, and preparation for bulk loading to trucks, barges, product ships, and railcars. This classification

721-406: A fuel. In July 2024, EET Fuels announced its plan to build Europe’s first hydrogen-ready combined heat and power plant at Stanlow, which is currently scheduled for completion in 2027 and operational by 2028 or 2029. In the same month, it was reported that the refinery plans to invest in infrastructure and extra capacity to increase its national footprint. Stanlow Island is a small island found on

824-428: A heavy, long-chained oil into a lighter short-chained one, by various forms of cracking such as fluid catalytic cracking , thermal cracking , and hydrocracking . The final step in gasoline production is the blending of fuels with different octane ratings, vapor pressures , and other properties to meet product specifications. Another method for reprocessing and upgrading these intermediate products (residual oils) uses

927-430: A hundred thousand to several hundred thousand barrels of crude oil a day. Because of the high capacity, many of the units operate continuously , as opposed to processing in batches , at steady state or nearly steady state for months to years. The high capacity also makes process optimization and advanced process control very desirable. Petroleum products are materials derived from crude oil ( petroleum ) as it

1030-517: A lack of comparability, which is problematic when monitoring progress towards targets. There are arguments for the adoption of a common measurement tool, or at least the development of communication between different tools. Emissions may be tracked over long time periods, known as historical or cumulative emissions measurements. Cumulative emissions provide some indicators of what is responsible for greenhouse gas atmospheric concentration build-up. The national accounts balance tracks emissions based on

1133-645: A large amount of steam and cooling water need to have an abundant source of water. Oil refineries, therefore, are often located nearby navigable rivers or on a seashore, nearby a port. Such location also gives access to transportation by river or by sea. The advantages of transporting crude oil by pipeline are evident, and oil companies often transport a large volume of fuel to distribution terminals by pipeline. A pipeline may not be practical for products with small output, and railcars, road tankers, and barges are used. Petrochemical plants and solvent manufacturing (fine fractionating) plants need spaces for further processing of

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1236-658: A large volume of refinery products, or to mix chemical additives with a product at source rather than at blending terminals. The refining process releases a number of different chemicals into the atmosphere (see AP 42 Compilation of Air Pollutant Emission Factors ) and a notable odor normally accompanies the presence of a refinery. Aside from air pollution impacts there are also wastewater concerns, risks of industrial accidents such as fire and explosion, and noise health effects due to industrial noise . Many governments worldwide have mandated restrictions on contaminants that refineries release, and most refineries have installed

1339-462: A number of further chemical processes are integrated into it. For example, light hydrocarbons are steam-cracked in an ethylene plant, and the produced ethylene is polymerized to produce polyethene . To ensure both proper separation and environmental protection, a very low sulfur content is necessary in all but the heaviest products. The crude sulfur contaminant is transformed to hydrogen sulfide via catalytic hydrodesulfurization and removed from

1442-856: A particular base year. Choosing between base years of 1750, 1900, 1950, and 1990 has a significant effect for most countries. Within the G8 group of countries, it is most significant for the UK, France and Germany. These countries have a long history of CO 2 emissions (see the section on Cumulative and historical emissions ). The Global Carbon Project continuously releases data about CO 2 emissions, budget and concentration. and industry (excluding cement carbonation) Gt C change Gt C Gt C Gt CO 2 (projection) Distribution of global greenhouse gas emissions based on type of greenhouse gas, without land-use change, using 100 year global warming potential (data from 2020). Total: 49.8 GtCO 2 e Carbon dioxide (CO 2 )

1545-539: A shoreline necklace of refineries, built in the early 20th century before this area was populated, and associated chemical plants are adjacent to urban areas in Richmond , Martinez , Pacheco , Concord , Pittsburg , Vallejo and Benicia , with occasional accidental events that require " shelter in place " orders to the adjacent populations. A number of refineries are located in Sherwood Park, Alberta , directly adjacent to

1648-475: A significant contributor to warming. Although CFCs are greenhouse gases, they are regulated by the Montreal Protocol which was motivated by CFCs' contribution to ozone depletion rather than by their contribution to global warming. Ozone depletion has only a minor role in greenhouse warming, though the two processes are sometimes confused in the media. In 2016, negotiators from over 170 nations meeting at

1751-457: A significant margin, Asia's and the world's largest emitter: it emits nearly 10 billion tonnes each year, more than one-quarter of global emissions. Other countries with fast growing emissions are South Korea , Iran, and Australia (which apart from the oil rich Persian Gulf states, now has the highest per capita emission rate in the world). On the other hand, annual per capita emissions of the EU-15 and

1854-538: A two shift, six days per week system. In 1987 Shell undertook a review of the distribution of oil across the UK. It intended to make the most of improved road networks in the country. As a result the company spent £17 million in developing a new distribution network. This included development and rebuilding of the distribution centre adjacent to the Stanlow ;refinery and at the oil terminal at Shell Haven in Essex. However,

1957-442: A £3 million joint venture bulk hydrocarbon liquid distribution centre at Haydock , Lancashire (53.47764 N, 2.65983 W). This was built on a 90-acre (36.4 ha), site although only 20.2 ha were developed in the first stage. The terminal reflected the growing use of oil as an energy source in the development of North West England. The oil supply companies wished to make oil available at appropriate locations and when needed; and to modernise

2060-450: Is a framework of methods to measure and track how much greenhouse gas an organization emits. Cumulative anthropogenic (i.e., human-emitted) emissions of CO 2 from fossil fuel use are a major cause of global warming , and give some indication of which countries have contributed most to human-induced climate change. In particular, CO 2 stays in the atmosphere for at least 150 years and up to 1000 years, whilst methane disappears within

2163-433: Is based on the way crude oil is distilled and separated into fractions. Over 6,000 items are made from petroleum waste by-products, including fertilizer , floor coverings , perfume , insecticide , petroleum jelly , soap , vitamin capsules . The image below is a schematic flow diagram of a typical oil refinery that depicts the various unit processes and the flow of intermediate product streams that occurs between

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2266-408: Is cooled by exchanging heat with the incoming crude oil. All of the fractions (i.e., the overhead naphtha, the sidecuts, and the bottom residue) are sent to intermediate storage tanks before being processed further. A party searching for a site to construct a refinery or a chemical plant needs to consider the following issues: Factors affecting site selection for oil refinery: Refineries that use

2369-421: Is exported. In comparison, methane has not increased appreciably, and N 2 O by 0.25% y . Using different base years for measuring emissions has an effect on estimates of national contributions to global warming. This can be calculated by dividing a country's highest contribution to global warming starting from a particular base year, by that country's minimum contribution to global warming starting from

2472-424: Is processed in oil refineries . The majority of petroleum is converted to petroleum products, which includes several classes of fuels. Oil refineries also produce various intermediate products such as hydrogen , light hydrocarbons, reformate and pyrolysis gasoline . These are not usually transported but instead are blended or processed further on-site. Chemical plants are thus often adjacent to oil refineries or

2575-413: Is removed from the distillation column by a pumparound system as shown in the diagram below. As shown in the flow diagram, the overhead distillate fraction from the distillation column is naphtha. The fractions removed from the side of the distillation column at various points between the column top and bottom are called sidecuts . Each of the sidecuts (i.e., the kerosene, light gas oil, and heavy gas oil)

2678-633: Is responsible for around 73% of emissions. Deforestation and other changes in land use also emit carbon dioxide and methane . The largest source of anthropogenic methane emissions is agriculture , closely followed by gas venting and fugitive emissions from the fossil-fuel industry . The largest agricultural methane source is livestock . Agricultural soils emit nitrous oxide partly due to fertilizers . Similarly, fluorinated gases from refrigerants play an outsized role in total human emissions. The current CO 2 -equivalent emission rates averaging 6.6 tonnes per person per year, are well over twice

2781-451: Is the dominant emitted greenhouse gas, while methane ( CH 4 ) emissions almost have the same short-term impact. Nitrous oxide (N 2 O) and fluorinated gases (F-gases) play a lesser role in comparison. Greenhouse gas emissions are measured in CO 2 equivalents determined by their global warming potential (GWP), which depends on their lifetime in the atmosphere. Estimations largely depend on

2884-563: Is the first major source of greenhouse gas emissions from transportation, followed by aircraft and maritime. Waterborne transportation is still the least carbon-intensive mode of transportation on average, and it is an essential link in sustainable multimodal freight supply chains . Buildings, like industry, are directly responsible for around one-fifth of greenhouse gas emissions, primarily from space heating and hot water consumption. When combined with power consumption within buildings, this figure climbs to more than one-third. Within

2987-729: Is the second largest in the United Kingdom after Fawley Refinery , and produces a sixth of the UK's petrol needs. Stanlow is also a large producer for commodities such as jet fuel and diesel. Although situated in North West England , the refinery serves much of England as it is linked to the UK oil pipeline network . Oil is delivered to the Tranmere Oil Terminal via ship, then pumped to Stanlow for refining and stored for delivery. The refinery occupies nearly 1,900 acres (7.7 km) near

3090-475: Is then processed further in the other refinery processing units. The CDU is often referred to as the atmospheric distillation unit because it operates at slightly above atmospheric pressure. Below is a schematic flow diagram of a typical crude oil distillation unit. The incoming crude oil is preheated by exchanging heat with some of the hot, distilled fractions and other streams. It is then desalted to remove inorganic salts (primarily sodium chloride). Following

3193-479: Is transformed and refined into products such as gasoline (petrol), diesel fuel , asphalt base , fuel oils , heating oil , kerosene , liquefied petroleum gas and petroleum naphtha . Petrochemical feedstock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha. The crude oil feedstock has typically been processed by an oil production plant . [1] There

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3296-590: Is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products. In 2020, the total capacity of global refineries for crude oil was about 101.2 million barrels per day. Oil refineries are typically large, sprawling industrial complexes with extensive piping running throughout, carrying streams of fluids between large chemical processing units, such as distillation columns. In many ways, oil refineries use many different technologies and can be thought of as types of chemical plants . Since December 2008,

3399-665: Is very complex, and is affected by how carbon sinks are allocated between regions and the dynamics of the climate system . The graphic shows the logarithm of 1850–2019 fossil fuel CO 2 emissions; natural log on left, actual value of Gigatons per year on right. Although emissions increased during the 170-year period by about 3% per year overall, intervals of distinctly different growth rates (broken at 1913, 1945, and 1973) can be detected. The regression lines suggest that emissions can rapidly shift from one growth regime to another and then persist for long periods of time. The most recent drop in emissions growth – by almost 3 percentage points –

3502-626: The Allies , during the Oil Campaign of World War II . Another close contender for the title of hosting the world's oldest oil refinery is Salzbergen in Lower Saxony , Germany. Salzbergen's refinery was opened in 1860. At one point, the refinery in Ras Tanura , Saudi Arabia owned by Saudi Aramco was claimed to be the largest oil refinery in the world. For most of the 20th century, the largest refinery

3605-461: The COVID-19 pandemic . In September 2021 it was reported that the facility is at the "brink of collapse". In February 2023, Essar launched Essar Energy Transition for the development of what has been reported as the 'UK's leading energy transition hub' as part of the regional decarbonisation cluster known as Hynet, alongside a $ 2.4 billion (£1.9 billion) investment in the refinery. In December 2023,

3708-605: The Edeleanu process . This increased the refining efficiency compared to pure fractional distillation and allowed a massive development of the refining plants. Successively, the process was implemented in France, Germany, U.S. and in a few decades became worldwide spread. In 1910 Edeleanu founded "Allgemeine Gesellschaft für Chemische Industrie" in Germany, which, given the success of the name, changed to Edeleanu GmbH, in 1930. During Nazi's time,

3811-642: The Mersey Docks and Harbour Company from its Liverpool headquarters, and is transferred via a fifteen-mile (24 km) pipeline to storage at Stanlow. Output is delivered via various means, including by pipeline via the UK oil pipeline network , road and the Manchester Ship Canal . There is also a pipeline for jet fuel to Manchester Airport . In 2010, Royal Dutch Shell declared their desire to sell off some refineries in Europe to concentrate on emerging markets in Asia and

3914-491: The Middle East , which led to the possibility that Stanlow would be shut down indefinitely. However, Shell said that a number of refineries in their portfolio offered over-capacity and consequently Stanlow, their last British refinery, was put up for sale. After a prolonged period of negotiation, Stanlow was sold by Shell to Essar Energy for approximately $ 1.3 billion (£814 million) in 2011. Essar has stated their desire to expand

4017-497: The River Mersey and dates back to 1924, when a small bitumen plant was established. Stanlow & Thornton railway station was opened in 1940 to give workers access to the site and the facility an extra mode of transport. However, this station is now only served by three trains daily towards each of Ellesmere Port (westbound) and Helsby (eastbound), with these services scheduled to depart at times which would be inconvenient for

4120-493: The hydrocarbons to be separated by distillation . Since the lighter liquid products are in great demand for use in internal combustion engines, a modern refinery will convert heavy hydrocarbons and lighter gaseous elements into these higher-value products. Oil can be used in a variety of ways because it contains hydrocarbons of varying molecular masses , forms and lengths such as paraffins , aromatics , naphthenes (or cycloalkanes ), alkenes , dienes , and alkynes . While

4223-416: The octane rating of their product gasoline, lower the sulfur content of their diesel fuel and home heating fuels to comply with environmental regulations and comply with environmental air pollution and water pollution requirements. In the 19th century, refineries in the U.S. processed crude oil primarily to recover the kerosene . There was no market for the more volatile fraction, including gasoline, which

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4326-422: The petrochemical industry with increased risk of various cancers, such as mesothelioma . It also found reduced risks of other cancers, such as stomach and rectal . The systematic review did mention that several of the associations were not due to factors directly related to the petroleum industry, rather were related to lifestyle factors such as smoking . Evidence for adverse health effects for nearby residents

4429-408: The vacuum distillation unit may also produce fractions that can be refined into end products such as spindle oil used in the textile industry, light machine oil, motor oil, and various waxes. The crude oil distillation unit (CDU) is the first processing unit in virtually all petroleum refineries. The CDU distills the incoming crude oil into various fractions of different boiling ranges, each of which

4532-399: The viscosity of the oil). All of the many other refining processes discussed below were developed during the war or within a few years after the war. They became commercially available within 5 to 10 years after the war ended and the worldwide petroleum industry experienced very rapid growth. The driving force for that growth in technology and in the number and size of refineries worldwide was

4635-617: The 12th century. In the Northern Song dynasty (960–1127), a workshop called the "Fierce Oil Workshop", was established in the city of Kaifeng to produce refined oil for the Song military as a weapon. The troops would then fill iron cans with refined oil and throw them toward the enemy troops, causing a fire – effectively the world's first " fire bomb ". The workshop was one of the world's earliest oil refining factories where thousands of people worked to produce Chinese oil-powered weaponry. Prior to

4738-844: The 1800s, primarily producing kerosene for oil lamps. In the early twentieth century, the introduction of the internal combustion engine and its use in automobiles created a market for gasoline that was the impetus for fairly rapid growth of the petroleum industry. The early finds of petroleum like those in Ontario and Pennsylvania were soon outstripped by large oil "booms" in Oklahoma , Texas and California . Samuel Kier established America's first oil refinery in Pittsburgh on Seventh Avenue near Grant Street, in 1853. Polish pharmacist and inventor Ignacy Łukasiewicz established an oil refinery in Jasło , then part of

4841-520: The 2030 Paris Agreement increase of 1.5 °C (2.7 °F) over pre-industrial levels. While cities are sometimes considered to be disproportionate contributors to emissions, per-capita emissions tend to be lower for cities than the averages in their countries. A 2017 survey of corporations responsible for global emissions found that 100 companies were responsible for 71% of global direct and indirect emissions , and that state-owned companies were responsible for 59% of their emissions. China is, by

4944-570: The Austro-Hungarian Empire (now in Poland ) in 1854. The first large refinery opened at Ploiești , Romania, in 1856–1857. It was in Ploiesti that, 51 years later, in 1908, Lazăr Edeleanu , a Romanian chemist of Jewish origin who got his PhD in 1887 by discovering amphetamine , invented, patented and tested on industrial scale the first modern method of liquid extraction for refining crude oil,

5047-519: The City of Edmonton , which has a population of over 1,000,000 residents. NIOSH criteria for occupational exposure to refined petroleum solvents have been available since 1977. Modern petroleum refining involves a complicated system of interrelated chemical reactions that produce a wide variety of petroleum-based products. Many of these reactions require precise temperature and pressure parameters.   The equipment and monitoring required to ensure

5150-495: The EU, the agricultural sector presently accounts for roughly 10% of total greenhouse gas emissions, with methane from livestock accounting for slightly more than half of 10%. Estimates of total CO 2 emissions do include biotic carbon emissions, mainly from deforestation. Including biotic emissions brings about the same controversy mentioned earlier regarding carbon sinks and land-use change. The actual calculation of net emissions

5253-522: The Earth can cool off. The major anthropogenic (human origin) sources of greenhouse gases are carbon dioxide (CO 2 ), nitrous oxide ( N 2 O ), methane and three groups of fluorinated gases ( sulfur hexafluoride ( SF 6 ), hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs, sulphur hexafluoride (SF 6 ), and nitrogen trifluoride (NF 3 )). Though the greenhouse effect is heavily driven by water vapor , human emissions of water vapor are not

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5356-608: The Manchester Ship Canal outside the Stanlow oil refinery. The island was occupied until the 1990s when the locals left due to isolation and the hazards of living nearby the refinery. Notable structures are the remains of Stanlow Abbey founded in 1178 that remain at Stanlow Point. Access to the island using a 24-hour request ferry that links the Essar refinery to Stanlow Island with special permission. In 1969 Shell-Mex & BP opened

5459-578: The U.S. from 1976 until 2014 when the small Dakota Prairie Refinery in North Dakota began operation. More than half the refineries that existed in 1981 are now closed due to low utilization rates and accelerating mergers. As a result of these closures total US refinery capacity fell between 1981 and 1995, though the operating capacity stayed fairly constant in that time period at around 15,000,000 barrels per day (2,400,000 m /d). Increases in facility size and improvements in efficiencies have offset much of

5562-712: The US accounted for 28% of emissions; the EU, 23%; Japan, 4%; other OECD countries 5%; Russia, 11%; China, 9%; India, 3%; and the rest of the world, 18%. The European Commission adopted a set of legislative proposals targeting a reduction of the CO 2 emissions by 55% by 2030. Overall, developed countries accounted for 83.8% of industrial CO 2 emissions over this time period, and 67.8% of total CO 2 emissions. Developing countries accounted for industrial CO 2 emissions of 16.2% over this time period, and 32.2% of total CO 2 emissions. However, what becomes clear when we look at emissions across

5665-548: The US are gradually decreasing over time. Emissions in Russia and Ukraine have decreased fastest since 1990 due to economic restructuring in these countries. 2015 was the first year to see both total global economic growth and a reduction of carbon emissions. Annual per capita emissions in the industrialized countries are typically as much as ten times the average in developing countries. Due to China's fast economic development, its annual per capita emissions are quickly approaching

5768-419: The ability of oceans and land sinks to absorb these gases. Short-lived climate pollutants (SLCPs) including methane, hydrofluorocarbons (HFCs) , tropospheric ozone and black carbon persist in the atmosphere for a period ranging from days to 15 years; whereas carbon dioxide can remain in the atmosphere for millennia. Reducing SLCP emissions can cut the ongoing rate of global warming by almost half and reduce

5871-509: The case of Jupiter , or from its host star as in the case of the Earth . In the case of Earth, the Sun emits shortwave radiation ( sunlight ) that passes through greenhouse gases to heat the Earth's surface. In response, the Earth's surface emits longwave radiation that is mostly absorbed by greenhouse gases. The absorption of longwave radiation prevents it from reaching space, reducing the rate at which

5974-588: The company reported $ 66.3 million (£51.7 million) of profit on $ 11.8 billion (£9 billion) of revenue in its annual results to March 2023. Stanlow operator, Essar Oil UK, changed its trading name to EET Fuels in January 2024 and announced that $ 1.2 billion would be allocated to support the refinery’s industrial decarbonisation. The refinery announced its plan to reduce carbon emissions  by 95 per cent by 2030 through industrial carbon capture and switching from natural gas and other refinery fuel sources to hydrogen as

6077-541: The company was bought by the Deutsche Erdöl-AG and Edeleanu, being of Jewish origin, moved back to Romania. After the war, the trademark was used by the successor company EDELEANU Gesellschaft mbH Alzenau (RWE) for many petroleum products, while the company was lately integrated as EDL in the Pörner Group . The Ploiești refineries, after being taken over by Nazi Germany , were bombed in the 1943 Operation Tidal Wave by

6180-667: The concentration of carbon dioxide and other greenhouse gases. Emissions have grown rapidly since about 1950 with ongoing expansions in global population and economic activity following World War II. As of 2021, measured atmospheric concentrations of carbon dioxide were almost 50% higher than pre-industrial levels. The main sources of greenhouse gases due to human activity (also called carbon sources ) are: Global greenhouse gas emissions are about 50 Gt per year and for 2019 have been estimated at 57 Gt CO 2 eq including 5 Gt due to land use change. In 2019, approximately 34% [20 GtCO 2 -eq] of total net anthropogenic GHG emissions came from

6283-555: The construction of new refineries may have also contributed to rising fuel prices in the United States. Additionally, many refineries (more than 100 since the 1980s) have closed due to obsolescence and/or merger activity within the industry itself. Environmental and safety concerns mean that oil refineries are sometimes located some distance away from major urban areas. Nevertheless, there are many instances where refinery operations are close to populated areas and pose health risks. In California's Contra Costa County and Solano County ,

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6386-667: The crude oil and depending on the demands of the market, refineries can produce different shares of petroleum products. The largest share of oil products is used as "energy carriers", i.e. various grades of fuel oil and gasoline . These fuels include or can be blended to give gasoline, jet fuel , diesel fuel , heating oil , and heavier fuel oils. Heavier (less volatile ) fractions can also be used to produce asphalt , tar , paraffin wax , lubricating and other heavy oils. Refineries also produce other chemicals , some of which are used in chemical processes to produce plastics and other useful materials. Since petroleum often contains

6489-487: The desalter, the crude oil is further heated by exchanging heat with some of the hot, distilled fractions and other streams. It is then heated in a fuel-fired furnace (fired heater) to a temperature of about 398 °C and routed into the bottom of the distillation unit. The cooling and condensing of the distillation tower overhead is provided partially by exchanging heat with the incoming crude oil and partially by either an air-cooled or water-cooled condenser. Additional heat

6592-413: The difference between a country's exports and imports. For many richer nations, the balance is negative because more goods are imported than they are exported. This result is mostly due to the fact that it is cheaper to produce goods outside of developed countries, leading developed countries to become increasingly dependent on services and not goods. A positive account balance would mean that more production

6695-490: The distribution of oil to improve efficiency. The terminal was designed to store up to 1 million tonnes of oil, making it the largest inland oil depot in Europe. It handled 5,000 tonnes of oil products daily, comprising 22 million gallons (100,000 m) of white oils and 42 million gallons (191,000 m) of black oils a year. The terminal was near the St Helens branch railway from which a branch led to loading and off-loading sidings in

6798-440: The energy supply sector, 24% [14 GtCO 2 -eq] from industry, 22% [13 GtCO 2 -eq]from agriculture, forestry and other land use (AFOLU), 15% [8.7 GtCO 2 -eq] from transport and 6% [3.3 GtCO 2 -eq] from buildings. Global carbon dioxide emissions by country in 2023: The current CO 2 -equivalent emission rates averaging 6.6 tonnes per person per year, are well over twice the estimated rate 2.3 tons required to stay within

6901-489: The entire life cycle from the production of a good or service along the supply chain to its final consumption. Carbon accounting (or greenhouse gas accounting) is a framework of methods to measure and track how much greenhouse gas an organization emits. The greenhouse effect occurs when greenhouse gases in a planet's atmosphere insulate the planet from losing heat to space, raising its surface temperature. Surface heating can happen from an internal heat source as in

7004-443: The equipment needed to comply with the requirements of the pertinent environmental protection regulatory agencies. In the United States, there is strong pressure to prevent the development of new refineries, and no major refinery has been built in the country since Marathon's Garyville, Louisiana facility in 1976. However, many existing refineries have been expanded during that time. Environmental restrictions and pressure to prevent

7107-414: The estimated rate 2.3 tons required to stay within the 2030 Paris Agreement increase of 1.5 °C (2.7 °F) over pre-industrial levels. Annual per capita emissions in the industrialized countries are typically as much as ten times the average in developing countries. The carbon footprint (or greenhouse gas footprint ) serves as an indicator to compare the amount of greenhouse gases emitted over

7210-412: The growing demand for automotive gasoline and aircraft fuel. In the United States, for various complex economic and political reasons, the construction of new refineries came to a virtual stop in about the 1980s. However, many of the existing refineries in the United States have revamped many of their units and/or constructed add-on units in order to: increase their crude oil processing capacity, increase

7313-514: The highly automated and technically advanced nature of modern petroleum refineries, nearly all processes are contained within engineering controls and represent a substantially decreased risk of exposure to workers compared to earlier times. However, certain situations or work tasks may subvert these safety mechanisms, and expose workers to a number of chemical (see table above) or physical (described below) hazards. Examples of these scenarios include: A 2021 systematic review associated working in

7416-542: The hundreds of different hydrocarbon molecules in crude oil are separated in a refinery into components that can be used as fuels , lubricants , and feedstocks in petrochemical processes that manufacture such products as plastics , detergents , solvents , elastomers , and fibers such as nylon and polyesters . Petroleum fossil fuels are burned in internal combustion engines to provide power for ships , automobiles , aircraft engines , lawn mowers , dirt bikes , and other machines. Different boiling points allow

7519-824: The importing country, rather than the exporting, country. A substantial proportion of CO 2 emissions is traded internationally. The net effect of trade was to export emissions from China and other emerging markets to consumers in the US, Japan, and Western Europe. Emission intensity is a ratio between greenhouse gas emissions and another metric, e.g., gross domestic product (GDP) or energy use. The terms "carbon intensity" and " emissions intensity " are also sometimes used. Emission intensities may be calculated using market exchange rates (MER) or purchasing power parity (PPP). Calculations based on MER show large differences in intensities between developed and developing countries, whereas calculations based on PPP show smaller differences. Carbon accounting (or greenhouse gas accounting)

7622-480: The inlet crude oil feedstock and the final end products. The diagram depicts only one of the literally hundreds of different oil refinery configurations. The diagram also does not include any of the usual refinery facilities providing utilities such as steam, cooling water, and electric power as well as storage tanks for crude oil feedstock and for intermediate products and end products. There are many process configurations other than that depicted above. For example,

7725-468: The lapse of formerly declining trends in carbon intensity of both developing and developed nations. China was responsible for most of global growth in emissions during this period. Localised plummeting emissions associated with the collapse of the Soviet Union have been followed by slow emissions growth in this region due to more efficient energy use , made necessary by the increasing proportion of it that

7828-609: The late Northern Wei dynasty , the Chinese geographer, writer and politician Li Daoyuan introduced the process of refining oil into various lubricants in his famous work Commentary on the Water Classic . Crude oil was often distilled by Persian chemists , with clear descriptions given in handbooks such as those of Muhammad ibn Zakarīya Rāzi ( c.  865–925 ). The streets of Baghdad were paved with tar , derived from petroleum that became accessible from natural fields in

7931-411: The less profitable refineries. Raw or unprocessed crude oil is not generally useful in industrial applications, although "light, sweet" (low viscosity, low sulfur ) crude oil has been used directly as a burner fuel to produce steam for the propulsion of seagoing vessels. The lighter elements, however, form explosive vapors in the fuel tanks and are therefore hazardous, especially in warships . Instead,

8034-707: The levels of those in the Annex I group of the Kyoto Protocol (i.e., the developed countries excluding the US). Africa and South America are both fairly small emitters, accounting for 3-4% of global emissions each. Both have emissions almost equal to international aviation and shipping. There are several ways of measuring greenhouse gas emissions. Some variables that have been reported include: These measures are sometimes used by countries to assert various policy/ethical positions on climate change. The use of different measures leads to

8137-415: The lost physical capacity of the industry. In 1982 (the earliest data provided), the United States operated 301 refineries with a combined capacity of 17.9 million barrels (2,850,000 m ) of crude oil each calendar day. In 2010, there were 149 operable U.S. refineries with a combined capacity of 17.6 million barrels (2,800,000 m ) per calendar day. By 2014 the number of refinery had reduced to 140 but

8240-496: The main international treaty on climate change (the UNFCCC ), countries report on emissions produced within their borders, e.g., the emissions produced from burning fossil fuels. Under a production-based accounting of emissions, embedded emissions on imported goods are attributed to the exporting, rather than the importing, country. Under a consumption-based accounting of emissions, embedded emissions on imported goods are attributed to

8343-456: The major source of greenhouse gas emissions in the EU . Greenhouse gas emissions from the transportation sector continue to rise, in contrast to power generation and nearly all other sectors. Since 1990, transportation emissions have increased by 30%. The transportation sector accounts for around 70% of these emissions. The majority of these emissions are caused by passenger vehicles and vans. Road travel

8446-436: The molecules in crude oil include different atoms such as sulfur and nitrogen, the hydrocarbons are the most common form of molecules, which are molecules of varying lengths and complexity made of hydrogen and carbon atoms , and a small number of oxygen atoms. The differences in the structure of these molecules account for their varying physical and chemical properties , and it is this variety that makes crude oil useful in

8549-482: The nineteenth century, petroleum was known and utilized in various fashions in Babylon , Egypt , China , Philippines , Rome and Azerbaijan . However, the modern history of the petroleum industry is said to have begun in 1846 when Abraham Gessner of Nova Scotia , Canada devised a process to produce kerosene from coal. Shortly thereafter, in 1854, Ignacy Łukasiewicz began producing kerosene from hand-dug oil wells near

8652-460: The product stream via amine gas treating . Using the Claus process , hydrogen sulfide is afterward transformed to elementary sulfur to be sold to the chemical industry. The rather large heat energy freed by this process is directly used in the other parts of the refinery. Often an electrical power plant is combined into the whole refinery process to take up the excess heat. According to the composition of

8755-455: The proper progression of these processes is complex, and has evolved through the advancement of the scientific field of petroleum engineering . The wide array of high pressure and/or high temperature reactions, along with the necessary chemical additives or extracted contaminants, produces an astonishing number of potential health hazards to the oil refinery worker.  Through the advancement of technical chemical and petroleum engineering,

8858-615: The region. In the 9th century, oil fields were exploited in the area around modern Baku , Azerbaijan. These fields were described by the Arab geographer Abu al-Hasan 'Alī al-Mas'ūdī in the 10th century, and by Marco Polo in the 13th century, who described the output of those wells as hundreds of shiploads. Arab and Persian chemists also distilled crude oil in order to produce flammable products for military purposes. Through Islamic Spain , distillation became available in Western Europe by

8961-464: The review identified that the Haydock terminal should close. Thirty-two of the tanker drivers based at Haydock were transferred to Stanlow, together with some clerical jobs at Haydock. The Haydock terminal closed in 1988. The site was eventually redeveloped as a commercial estate. Oil refinery An oil refinery or petroleum refinery is an industrial process plant where petroleum (crude oil)

9064-631: The site with a 25% increase in output. Following the bankruptcy of Petroplus which ran the Coryton Refinery in January 2012, Essar stated their belief that Stanlow, being a large refinery, would be able to compete with refineries in Asia and the Middle East. Essar plan a £250 million expansion of Stanlow, with production of diesel and aviation fuel to be increased. In April 2021 the company was reported to be heavily in debt after fossil fuel demand dropped during

9167-607: The summit of the United Nations Environment Programme reached a legally binding accord to phase out hydrofluorocarbons (HFCs) in the Kigali Amendment to the Montreal Protocol . The use of CFC-12 (except some essential uses) has been phased out due to its ozone depleting properties. The phasing-out of less active HCFC-compounds will be completed in 2030. Starting about 1750, industrial activity powered by fossil fuels began to significantly increase

9270-516: The terminal. Heavy oils were delivered by two trains per day from Stanlow, and one daily train from Heysham refinery. The terminal was supplied with light oils via a 41.6 km (150 mm diameter) pipeline from Stanlow refinery. Oil products were loaded into a fleet of 100 road tankers for distribution. Upon arrival at the terminal road tankers  were directed automatically to an empty stand where filling took place from an overhead gantry. The terminal employed 260 staff including 170 drivers working

9373-604: The time, reports of the health impacts of working in an oil refinery can be found as early as the 1800s. For instance, an explosion in a Chicago refinery killed 20 workers in 1890. Since then, numerous fires, explosions, and other significant events have from time to time drawn the public's attention to the health of oil refinery workers. Such events continue in the 21st century, with explosions reported in refineries in Wisconsin and Germany in 2018. However, there are many less visible hazards that endanger oil refinery workers. Given

9476-458: The total capacity increased to 18.02 million barrels (2,865,000 m ) per calendar day. Indeed, in order to reduce operating costs and depreciation, refining is operated in fewer sites but of bigger capacity. In 2009 through 2010, as revenue streams in the oil business dried up and profitability of oil refineries fell due to lower demand for product and high reserves of supply preceding the economic recession , oil companies began to close or sell

9579-601: The town of Krosno , Poland . Romania was registered as the first country in world oil production statistics, according to the Academy Of World Records . In North America, the first oil well was drilled in 1858 by James Miller Williams in Oil Springs, Ontario , Canada. In the United States, the petroleum industry began in 1859 when Edwin Drake found oil near Titusville , Pennsylvania . The industry grew slowly in

9682-420: The vast majority of these processes are automated and enclosed, thus greatly reducing the potential health impact to workers.   However, depending on the specific process in which a worker is engaged, as well as the particular method employed by the refinery in which he/she works, significant health hazards remain. Although occupational injuries in the United States were not routinely tracked and reported at

9785-536: The workers. In 1974 an oil pipeline was commissioned from Amlwch , Anglesey to Stanlow. Crude oil was pumped ashore from tankers moored at deep-water pontoons to a holding station at Rhosgoch, from there it was pumped through two 36-inch diameter pipelines, 127 km to Stanlow. The pipeline had closed by 1990. Crude oil is now received lower down river on the Mersey at the Tranmere Oil Terminal, operated by

9888-452: The world today is that the countries with the highest emissions over history are not always the biggest emitters today. For example, in 2017, the UK accounted for just 1% of global emissions. In comparison, humans have emitted more greenhouse gases than the Chicxulub meteorite impact event which caused the extinction of the dinosaurs . Transport, together with electricity generation , is

9991-588: The world's largest oil refinery has been the Jamnagar Refinery owned by Reliance Industries , located in Gujarat , India, with a processing capacity of 1.24 million barrels (197,000 m ) per day. Oil refineries are an essential part of the petroleum industry's downstream sector. The Chinese were among the first civilizations to refine oil. As early as the first century, the Chinese were refining crude oil for use as an energy source. Between 512 and 518, in

10094-582: The year 1995). A country's emissions may also be reported as a proportion of global emissions for a particular year. Another measurement is of per capita emissions. This divides a country's total annual emissions by its mid-year population. Per capita emissions may be based on historical or annual emissions. One way of attributing greenhouse gas emissions is to measure the embedded emissions (also referred to as "embodied emissions") of goods that are being consumed. Emissions are usually measured according to production, rather than consumption. For example, in

10197-604: Was also weak, with the evidence primarily centering around neighborhoods in developed countries . Carbon emission Carbon dioxide (CO 2 ) is the main greenhouse gas resulting from human activities. It accounts for more than half of warming. Methane (CH 4 ) emissions have almost the same short-term impact. Nitrous oxide (N 2 O) and fluorinated gases (F-gases) play a lesser role in comparison. Emissions of carbon dioxide, methane and nitrous oxide in 2023 were all higher than ever before. Electricity generation , heat and transport are major emitters; overall energy

10300-406: Was at about the time of the 1970s energy crisis . Percent changes per year were estimated by piecewise linear regression on the log data and are shown on the plot; the data are from The Integrated Carbon Observation system. The sharp acceleration in CO 2 emissions since 2000 to more than a 3% increase per year (more than 2 ppm per year) from 1.1% per year during the 1990s is attributable to

10403-503: Was considered waste and was often dumped directly into the nearest river. The invention of the automobile shifted the demand to gasoline and diesel, which remain the primary refined products today. Today, national and state legislation require refineries to meet stringent air and water cleanliness standards. In fact, oil companies in the U.S. perceive obtaining a permit to build a modern refinery to be so difficult and costly that no new refineries were built (though many have been expanded) in

10506-569: Was occurring within a country, so more operational factories would increase carbon emission levels. Emissions may also be measured across shorter time periods. Emissions changes may, for example, be measured against the base year of 1990. 1990 was used in the United Nations Framework Convention on Climate Change (UNFCCC) as the base year for emissions, and is also used in the Kyoto Protocol (some gases are also measured from

10609-810: Was the Abadan Refinery in Iran . This refinery suffered extensive damage during the Iran–Iraq War . Since 25 December 2008, the world's largest refinery complex is the Jamnagar Refinery Complex, consisting of two refineries side by side operated by Reliance Industries Limited in Jamnagar, India with a combined production capacity of 1,240,000 barrels per day (197,000 m /d). PDVSA 's Paraguaná Refinery Complex in Paraguaná Peninsula , Venezuela , with

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