Soil , also commonly referred to as earth , is a mixture of organic matter , minerals , gases , liquids , and organisms that together support the life of plants and soil organisms . Some scientific definitions distinguish dirt from soil by restricting the former term specifically to displaced soil.
96-748: Soil consists of a solid phase of minerals and organic matter (the soil matrix), as well as a porous phase that holds gases (the soil atmosphere) and water (the soil solution). Accordingly, soil is a three- state system of solids, liquids, and gases. Soil is a product of several factors: the influence of climate , relief (elevation, orientation, and slope of terrain), organisms, and the soil's parent materials (original minerals) interacting over time. It continually undergoes development by way of numerous physical, chemical and biological processes, which include weathering with associated erosion . Given its complexity and strong internal connectedness , soil ecologists regard soil as an ecosystem . Most soils have
192-399: A better estimation can be obtained by examining the lithology of the particles. Porosity can be proportional to hydraulic conductivity ; for two similar sandy aquifers , the one with a higher porosity will typically have a higher hydraulic conductivity (more open area for the flow of water), but there are many complications to this relationship. The principal complication is that there
288-429: A crucial function in the global carbon cycle , with the global soil carbon pool estimated to be 2,500 gigatons . This is 3.3 times the amount of the atmospheric pool at 750 gigatons and 4.5 times the biotic pool at 560 gigatons. The pool of organic carbon , which occurs primarily in the form of SOM, accounts for approximately 1,550 gigatons of the total global carbon pool, with soil inorganic carbon (SIC) accounting for
384-618: A dry bulk density (density of soil taking into account voids when dry) between 1.1 and 1.6 g/cm, though the soil particle density is much higher, in the range of 2.6 to 2.7 g/cm. Little of the soil of planet Earth is older than the Pleistocene and none is older than the Cenozoic , although fossilized soils are preserved from as far back as the Archean . Collectively the Earth's body of soil
480-446: A medium for plant growth , making it a critically important provider of ecosystem services . Since soil has a tremendous range of available niches and habitats , it contains a prominent part of the Earth's genetic diversity . A gram of soil can contain billions of organisms, belonging to thousands of species, mostly microbial and largely still unexplored. Soil has a mean prokaryotic density of roughly 10 organisms per gram, whereas
576-416: A net absorption of oxygen and methane and undergo a net release of carbon dioxide and nitrous oxide . Soils offer plants physical support, air, water, temperature moderation, nutrients, and protection from toxins. Soils provide readily available nutrients to plants and animals by converting dead organic matter into various nutrient forms. Components of a silt loam soil by percent volume A typical soil
672-545: A pH of 9, plant growth is reduced. High pH results in low micro-nutrient mobility, but water-soluble chelates of those nutrients can correct the deficit. Sodium can be reduced by the addition of gypsum (calcium sulphate) as calcium adheres to clay more tightly than does sodium causing sodium to be pushed into the soil water solution where it can be washed out by an abundance of water. There are acid-forming cations (e.g. hydronium, aluminium, iron) and there are base-forming cations (e.g. calcium, magnesium, sodium). The fraction of
768-449: A reserve of plant nutrients , especially nitrogen (N), phosphorus (P), and sulfur (S), along with micronutrients , which the mineralization of SOM slowly releases. As such, the amount of SOM and soil fertility are significantly correlated. SOM also acts as a major sink and source of soil carbon (C). Although the C content of SOM varies considerably, SOM is ordinarily estimated to contain 58% C, and " soil organic carbon " (SOC)
864-726: A result of a trade-off between toxicity and requirement most nutrients are better available to plants at moderate pH, although most minerals are more soluble in acid soils. Soil organisms are hindered by high acidity, and most agricultural crops do best with mineral soils of pH 6.5 and organic soils of pH 5.5. Given that at low pH toxic metals (e.g. cadmium, zinc, lead) are positively charged as cations and organic pollutants are in non-ionic form, thus both made more available to organisms, it has been suggested that plants, animals and microbes commonly living in acid soils are pre-adapted to every kind of pollution, whether of natural or human origin. In high rainfall areas, soils tend to acidify as
960-399: A result, layers (horizons) form in the soil profile. The alteration and movement of materials within a soil causes the formation of distinctive soil horizons . However, more recent definitions of soil embrace soils without any organic matter, such as those regoliths that formed on Mars and analogous conditions in planet Earth deserts. An example of the development of a soil would begin with
1056-505: A small, insoluble particle ranging in size from 1 nanometer to 1 micrometer , thus small enough to remain suspended by Brownian motion in a fluid medium without settling. Most soils contain organic colloidal particles called humus as well as the inorganic colloidal particles of clays . The very high specific surface area of colloids and their net electrical charges give soil its ability to hold and release ions . Negatively charged sites on colloids attract and release cations in what
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#17328449213351152-411: A soil can be said to be developed, and can be described further in terms of color, porosity, consistency, reaction ( acidity ), etc. Water is a critical agent in soil development due to its involvement in the dissolution, precipitation, erosion, transport, and deposition of the materials of which a soil is composed. The mixture of water and dissolved or suspended materials that occupy the soil pore space
1248-401: A soil determines its ability to supply available plant nutrients and affects its physical properties and the health of its living population. In addition, a soil's chemistry also determines its corrosivity , stability, and ability to absorb pollutants and to filter water. It is the surface chemistry of mineral and organic colloids that determines soil's chemical properties. A colloid is
1344-471: A valence of two, converts to (40 ÷ 2) × 1 milliequivalent = 20 milliequivalents of hydrogen ion per 100 grams of dry soil or 20 meq/100 g. The modern measure of CEC is expressed as centimoles of positive charge per kilogram (cmol/kg) of oven-dry soil. Most of the soil's CEC occurs on clay and humus colloids, and the lack of those in hot, humid, wet climates (such as tropical rainforests ), due to leaching and decomposition, respectively, explains
1440-549: Is 0.04%, but in the soil pore space it may range from 10 to 100 times that level, thus potentially contributing to the inhibition of root respiration. Calcareous soils regulate CO 2 concentration by carbonate buffering , contrary to acid soils in which all CO 2 respired accumulates in the soil pore system. At extreme levels, CO 2 is toxic. This suggests a possible negative feedback control of soil CO 2 concentration through its inhibitory effects on root and microbial respiration (also called soil respiration ). In addition,
1536-428: Is a fraction between 0 and 1, typically ranging from less than 0.005 for solid granite to more than 0.5 for peat and clay . The porosity of a rock, or sedimentary layer, is an important consideration when attempting to evaluate the potential volume of water or hydrocarbons it may contain. Sedimentary porosity is a complicated function of many factors, including but not limited to: rate of burial, depth of burial,
1632-595: Is a measure of the acidity or alkalinity of the soil. More precisely, it is a measure of hydronium concentration in an aqueous solution and ranges in values from 0 to 14 (acidic to basic) but practically speaking for soils, pH ranges from 3.5 to 9.5, as pH values beyond those extremes are toxic to life forms. At 25 °C an aqueous solution that has a pH of 3.5 has 10 moles H 3 O (hydronium ions) per litre of solution (and also 10 moles per litre OH). A pH of 7, defined as neutral, has 10 moles of hydronium ions per litre of solution and also 10 moles of OH per litre; since
1728-455: Is a measure of the void (i.e. "empty") spaces in a material , and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure the "accessible void", the total amount of void space accessible from the surface (cf. closed-cell foam ). There are many ways to test porosity in a substance or part, such as industrial CT scanning . The term porosity
1824-409: Is about 50% solids (45% mineral and 5% organic matter), and 50% voids (or pores) of which half is occupied by water and half by gas. The percent soil mineral and organic content can be treated as a constant (in the short term), while the percent soil water and gas content is considered highly variable whereby a rise in one is simultaneously balanced by a reduction in the other. The pore space allows for
1920-418: Is also a net sink of methane (CH 4 ) but a net producer of methane (a strong heat-absorbing greenhouse gas ) when soils are depleted of oxygen and subject to elevated temperatures. Soil atmosphere is also the seat of emissions of volatiles other than carbon and nitrogen oxides from various soil organisms, e.g. roots, bacteria, fungi, animals. These volatiles are used as chemical cues, making soil atmosphere
2016-453: Is an associated concept. The ratio of holes to solid that the wind "sees". Aerodynamic porosity is less than visual porosity, by an amount that depends on the constriction of holes. Casting porosity is a consequence of one or more of the following: gasification of contaminants at molten-metal temperatures; shrinkage that takes place as molten metal solidifies; and unexpected or uncontrolled changes in temperature or humidity. While porosity
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#17328449213352112-552: Is an important characteristic of soil. This ventilation can be accomplished via networks of interconnected soil pores , which also absorb and hold rainwater making it readily available for uptake by plants. Since plants require a nearly continuous supply of water, but most regions receive sporadic rainfall, the water-holding capacity of soils is vital for plant survival. Soils can effectively remove impurities, kill disease agents, and degrade contaminants , this latter property being called natural attenuation . Typically, soils maintain
2208-462: Is assumed acid-forming cations). Base saturation is almost in direct proportion to pH (it increases with increasing pH). It is of use in calculating the amount of lime needed to neutralise an acid soil (lime requirement). The amount of lime needed to neutralize a soil must take account of the amount of acid forming ions on the colloids (exchangeable acidity), not just those in the soil water solution (free acidity). The addition of enough lime to neutralize
2304-425: Is between 1.5 and 1.7 g/cm . This calculates to a porosity between 0.43 and 0.36. Typical bulk density of clay soil is between 1.1 and 1.3 g/cm . This calculates to a porosity between 0.58 and 0.51. This seems counterintuitive because clay soils are termed heavy , implying lower porosity. Heavy apparently refers to a gravitational moisture content effect in combination with terminology that harkens back to
2400-412: Is called the pedosphere . The pedosphere interfaces with the lithosphere , the hydrosphere , the atmosphere , and the biosphere . Soil has four important functions : All of these functions, in their turn, modify the soil and its properties. Soil science has two basic branches of study: edaphology and pedology . Edaphology studies the influence of soils on living things. Pedology focuses on
2496-401: Is called the soil solution. Since soil water is never pure water, but contains hundreds of dissolved organic and mineral substances, it may be more accurately called the soil solution. Water is central to the dissolution , precipitation and leaching of minerals from the soil profile . Finally, water affects the type of vegetation that grows in a soil, which in turn affects the development of
2592-469: Is complex. Traditional models regard porosity as continuous. This fails to account for anomalous features and produces only approximate results. Furthermore, it cannot help model the influence of environmental factors which affect pore geometry. A number of more complex models have been proposed, including fractals , bubble theory, cracking theory, Boolean grain process, packed sphere, and numerous other models. The characterisation of pore space in soil
2688-421: Is dependent on the type of parent material , the processes that modify those parent materials, and the soil-forming factors that influence those processes. The biological influences on soil properties are strongest near the surface, though the geochemical influences on soil properties increase with depth. Mature soil profiles typically include three basic master horizons: A, B, and C. The solum normally includes
2784-490: Is especially critical for soil functions and quality . The benefits of SOM result from several complex, interactive, edaphic factors; a non-exhaustive list of these benefits to soil function includes improvement of soil structure , aggregation , water retention , soil biodiversity , absorption and retention of pollutants , buffering capacity , and the cycling and storage of plant nutrients . SOM increases soil fertility by providing cation exchange sites and being
2880-597: Is generally excluded from SOM. The primary source of SOM is vegetal detritus. In forests and prairies , for example, different organisms decompose the fresh detritus into simpler compounds. This involves several stages, the first being primarily mechanical and becoming more chemical as decomposition progresses. The microbial decomposers are included in the SOM and form a food web of organisms that prey upon each other and subsequently become prey. Above detritivores , there are also herbivores that consume fresh vegetal matter,
2976-399: Is induced. Capillary action is responsible for moving groundwater from wet regions of the soil to dry areas. Subirrigation designs (e.g., wicking beds , sub-irrigated planters ) rely on capillarity to supply water to plant roots. Capillary action can result in an evaporative concentration of salts, causing land degradation through salination . Soil moisture measurement —measuring
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3072-459: Is inherent in die casting manufacturing, its presence may lead to component failure where pressure integrity is a critical characteristic. Porosity may take on several forms from interconnected micro-porosity, folds, and inclusions to macro porosity visible on the part surface. The end result of porosity is the creation of a leak path through the walls of a casting that prevents the part from holding pressure. Porosity may also lead to out-gassing during
3168-530: Is likely home to 59 ± 15% of the species on Earth. Enchytraeidae (worms) have the greatest percentage of species in soil (98.6%), followed by fungi (90%), plants (85.5%), and termites ( Isoptera ) (84.2%). Many other groups of animals have substantial fractions of species living in soil, e.g. about 30% of insects , and close to 50% of arachnids . While most vertebrates live above ground (ignoring aquatic species), many species are fossorial , that is, they live in soil, such as most blind snakes . The chemistry of
3264-475: Is more advanced. Most plant nutrients, with the exception of nitrogen , originate from the minerals that make up the soil parent material. Some nitrogen originates from rain as dilute nitric acid and ammonia , but most of the nitrogen is available in soils as a result of nitrogen fixation by bacteria . Once in the soil-plant system, most nutrients are recycled through living organisms, plant and microbial residues (soil organic matter), mineral-bound forms, and
3360-402: Is more easily measured through the volume of gas or liquid that can flow into the rock, whereas fluids cannot access unconnected pores. Porosity is the ratio of pore volume to its total volume. Porosity is controlled by: rock type, pore distribution, cementation, diagenetic history and composition. Porosity is not controlled by grain size, as the volume of between-grain space is related only to
3456-478: Is not a direct proportionality between porosity and hydraulic conductivity but rather an inferred proportionality. There is a clear proportionality between pore throat radii and hydraulic conductivity. Also, there tends to be a proportionality between pore throat radii and pore volume. If the proportionality between pore throat radii and porosity exists then a proportionality between porosity and hydraulic conductivity may exist. However, as grain size or sorting decreases
3552-492: Is often used as a synonym for SOM, with measured SOC content often serving as a proxy for SOM. Soil represents one of the largest C sinks on Earth and is significant in the global carbon cycle and, therefore, for climate change mitigation . Therefore, SOM/SOC dynamics and the capacity of soils to provide the ecosystem service of carbon sequestration through SOM management have received considerable attention. The concentration of SOM in soils generally ranges from 1% to 6% of
3648-409: Is referred to as cation exchange . Cation-exchange capacity is the amount of exchangeable cations per unit weight of dry soil and is expressed in terms of milliequivalents of positively charged ions per 100 grams of soil (or centimoles of positive charge per kilogram of soil; cmol c /kg ). Similarly, positively charged sites on colloids can attract and release anions in the soil, giving
3744-455: Is the initial porosity of the sediment at the surface of soil (before its burial), and k {\displaystyle k} is the compaction coefficient (m ). The letter e {\displaystyle e} with a negative exponent denotes the decreasing exponential function. The porosity of the sediment exponentially decreases with depth, as a function of its compaction. A value for porosity can alternatively be calculated from
3840-418: Is used in multiple fields including pharmaceutics , ceramics , metallurgy , materials , manufacturing , petrophysics , hydrology , earth sciences , soil mechanics , rock mechanics , and engineering . In gas-liquid two-phase flow , the void fraction is defined as the fraction of the flow-channel volume that is occupied by the gas phase or, alternatively, as the fraction of the cross-sectional area of
3936-537: Is very little organic material. Basaltic minerals commonly weather relatively quickly, according to the Goldich dissolution series . The plants are supported by the porous rock as it is filled with nutrient-bearing water that carries minerals dissolved from the rocks. Crevasses and pockets, local topography of the rocks, would hold fine materials and harbour plant roots. The developing plant roots are associated with mineral-weathering mycorrhizal fungi that assist in breaking up
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4032-489: The aeration of the soil and the ability of water to infiltrate and to be held within the soil. Soil water content can be measured as volume or weight . Soil moisture levels, in order of decreasing water content, are saturation, field capacity , wilting point , air dry, and oven dry. Field capacity describes a drained wet soil at the point water content reaches equilibrium with gravity. Irrigating soil above field capacity risks percolation losses. Wilting point describes
4128-626: The bulk density ρ bulk {\displaystyle \rho _{\text{bulk}}} , saturating fluid density ρ fluid {\displaystyle \rho _{\text{fluid}}} and particle density ρ particle {\displaystyle \rho _{\text{particle}}} : If the void space is filled with air, the following simpler form may be used: A mean normal particle density can be taken as approximately 2.65 g/cm ( silica , siliceous sediments or aggregates), or 2.70 g/cm ( calcite , carbonate sediments or aggregates), although
4224-559: The humus form ), the copedon (in intermediary position, where most weathering of minerals takes place) and the lithopedon (in contact with the subsoil). The soil texture is determined by the relative proportions of the individual particles of sand , silt , and clay that make up the soil. The interaction of the individual mineral particles with organic matter, water, gases via biotic and abiotic processes causes those particles to flocculate (stick together) to form aggregates or peds . Where these aggregates can be identified,
4320-424: The mineralogy of those particles can strongly modify those properties. The mineralogy of the finest soil particles, clay, is especially important. Large numbers of microbes , animals , plants and fungi are living in soil. However, biodiversity in soil is much harder to study as most of this life is invisible, hence estimates about soil biodiversity have been unsatisfactory. A recent study suggested that soil
4416-447: The A and B horizons. The living component of the soil is largely confined to the solum, and is generally more prominent in the A horizon. It has been suggested that the pedon , a column of soil extending vertically from the surface to the underlying parent material and large enough to show the characteristics of all its horizons, could be subdivided in the humipedon (the living part, where most soil organisms are dwelling, corresponding to
4512-581: The CEC increases. Hence, pure sand has almost no buffering ability, though soils high in colloids (whether mineral or organic) have high buffering capacity . Buffering occurs by cation exchange and neutralisation . However, colloids are not the only regulators of soil pH. The role of carbonates should be underlined, too. More generally, according to pH levels, several buffer systems take precedence over each other, from calcium carbonate buffer range to iron buffer range. Porosity Porosity or void fraction
4608-404: The acronym CROPT. The physical properties of soils, in order of decreasing importance for ecosystem services such as crop production , are texture , structure , bulk density , porosity , consistency, temperature , colour and resistivity . Soil texture is determined by the relative proportion of the three kinds of soil mineral particles, called soil separates: sand , silt , and clay . At
4704-443: The addition of any more hydronium ions or aluminum hydroxyl cations drives the pH even lower (more acidic) as the soil has been left with no buffering capacity. In areas of extreme rainfall and high temperatures, the clay and humus may be washed out, further reducing the buffering capacity of the soil. In low rainfall areas, unleached calcium pushes pH to 8.5 and with the addition of exchangeable sodium, soils may reach pH 10. Beyond
4800-449: The apparent sterility of tropical soils. Live plant roots also have some CEC, linked to their specific surface area. Anion exchange capacity is the soil's ability to remove anions (such as nitrate , phosphate ) from the soil water solution and sequester those for later exchange as the plant roots release carbonate anions to the soil water solution. Those colloids which have low CEC tend to have some AEC. Amorphous and sesquioxide clays have
4896-435: The atmosphere due to increased biological activity at higher temperatures, a positive feedback (amplification). This prediction has, however, been questioned on consideration of more recent knowledge on soil carbon turnover. Soil acts as an engineering medium, a habitat for soil organisms , a recycling system for nutrients and organic wastes , a regulator of water quality , a modifier of atmospheric composition , and
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#17328449213354992-424: The basic cations are forced off the soil colloids by the mass action of hydronium ions from usual or unusual rain acidity against those attached to the colloids. High rainfall rates can then wash the nutrients out, leaving the soil inhabited only by those organisms which are particularly efficient to uptake nutrients in very acid conditions, like in tropical rainforests . Once the colloids are saturated with H 3 O,
5088-408: The basis of humus . New reactions occur between these compounds and some proteins and other products that contain nitrogen, thus incorporating nitrogen and avoiding its mineralization . Other nutrients are also protected in this way from mineralization. Humic substances are classified into three genera based on their solubility in acids and alkalis, and also according to their stability: Soil has
5184-503: The channel that is occupied by the gas phase. Void fraction usually varies from location to location in the flow channel (depending on the two-phase flow pattern). It fluctuates with time and its value is usually time averaged. In separated (i.e., non- homogeneous ) flow, it is related to volumetric flow rates of the gas and the liquid phase, and to the ratio of the velocity of the two phases (called slip ratio ). Used in geology , hydrogeology , soil science , and building science ,
5280-435: The dry limit for growing plants. During growing season, soil moisture is unaffected by functional groups or specie richness. Available water capacity is the amount of water held in a soil profile available to plants. As water content drops, plants have to work against increasing forces of adhesion and sorptivity to withdraw water. Irrigation scheduling avoids moisture stress by replenishing depleted water before stress
5376-522: The dry weight of the organic matter in the soil, other elements present are essential for the nutrition of plants, including nitrogen, phosphorus, potassium, sulfur, calcium, magnesium, and many micronutrients . Organic compounds in vegetal detritus include: Vegetal detritus generally is not soluble in water and, therefore, is inaccessible to plants. It constitutes, nevertheless, the raw matter from which plant nutrients derive. Soil microbes decompose it through enzymatic biochemical processes, obtain
5472-517: The formation, description (morphology), and classification of soils in their natural environment. In engineering terms, soil is included in the broader concept of regolith , which also includes other loose material that lies above the bedrock, as can be found on the Moon and other celestial objects . Soil is a major component of the Earth 's ecosystem . The world's ecosystems are impacted in far-reaching ways by
5568-699: The gaps between larger particles). The graphic illustrates how some smaller grains can effectively fill the pores (where all water flow takes place), drastically reducing porosity and hydraulic conductivity, while only being a small fraction of the total volume of the material. For tables of common porosity values for earth materials , see the "further reading" section in the Hydrogeology article. Consolidated rocks (e.g., sandstone , shale , granite or limestone ) potentially have more complex "dual" porosities, as compared with alluvial sediment . This can be split into connected and unconnected porosity. Connected porosity
5664-413: The highest AEC, followed by the iron oxides. Levels of AEC are much lower than for CEC, because of the generally higher rate of positively (versus negatively) charged surfaces on soil colloids, to the exception of variable-charge soils. Phosphates tend to be held at anion exchange sites. Iron and aluminum hydroxide clays are able to exchange their hydroxide anions (OH) for other anions. The order reflecting
5760-629: The infiltration and movement of air and water, both of which are critical for life existing in soil. Compaction , a common problem with soils, reduces this space, preventing air and water from reaching plant roots and soil organisms. Given sufficient time, an undifferentiated soil will evolve a soil profile that consists of two or more layers, referred to as soil horizons. These differ in one or more properties such as in their texture , structure , density , porosity, consistency, temperature, color, and reactivity . The horizons differ greatly in thickness and generally lack sharp boundaries; their development
5856-597: The method of grain packing. Rocks normally decrease in porosity with age and depth of burial. Tertiary age Gulf Coast sandstones are in general more porous than Cambrian age sandstones. There are exceptions to this rule, usually because of the depth of burial and thermal history. Porosity of surface soil typically decreases as particle size increases. This is due to soil aggregate formation in finer textured surface soils when subject to soil biological processes. Aggregation involves particulate adhesion and higher resistance to compaction. Typical bulk density of sandy soil
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#17328449213355952-541: The nature of the connate fluids , the nature of overlying sediments (which may impede fluid expulsion). One commonly used relationship between porosity and depth is the decreasing exponential function given by the Athy (1930) equation: where, ϕ ( z ) {\displaystyle \phi (z)} is the porosity of the sediment at a given depth ( z {\displaystyle z} ) (m), ϕ 0 {\displaystyle \phi _{0}}
6048-406: The nature of the compound. The ranking, from fast to slow rates, is: The reactions that occur can be included in one of three genera: The mineral products are: As vegetal detritus decomposes, some microbially resistant compounds are formed, including modified lignins, oils, fats, and waxes. Secondly, some new compounds are synthesized, like polysaccharides and polyuronids . These compounds are
6144-459: The necessary energy from the same matter, and produce the mineral compounds that plant roots are apt to absorb. The decomposition of organic compounds specifically into mineral, i. e., inorganic, compounds is denominated " mineralization ". A portion of organic matter is not mineralized and instead decomposed into stable organic matter that is denominated " humus ". The decomposition of organic compounds occurs at very different rates, depending on
6240-427: The negatively charged colloids resist being washed downward by water and are out of reach of plant roots, thereby preserving the soil fertility in areas of moderate rainfall and low temperatures. There is a hierarchy in the process of cation exchange on colloids, as cations differ in the strength of adsorption by the colloid and hence their ability to replace one another ( ion exchange ). If present in equal amounts in
6336-412: The negatively-charged soil colloid exchange sites (CEC) that are occupied by base-forming cations is called base saturation . If a soil has a CEC of 20 meq and 5 meq are aluminium and hydronium cations (acid-forming), the remainder of positions on the colloids ( 20 − 5 = 15 meq ) are assumed occupied by base-forming cations, so that the base saturation is 15 ÷ 20 × 100% = 75% (the compliment 25%
6432-417: The next larger scale, soil structures called peds or more commonly soil aggregates are created from the soil separates when iron oxides , carbonates , clay, silica and humus , coat particles and cause them to adhere into larger, relatively stable secondary structures. Soil bulk density , when determined at standardized moisture conditions, is an estimate of soil compaction . Soil porosity consists of
6528-469: The ocean has no more than 10 prokaryotic organisms per milliliter (gram) of seawater. Organic carbon held in soil is eventually returned to the atmosphere through the process of respiration carried out by heterotrophic organisms, but a substantial part is retained in the soil in the form of soil organic matter; tillage usually increases the rate of soil respiration , leading to the depletion of soil organic matter. Since plant roots need oxygen, aeration
6624-633: The other cations more weakly bound to colloids are pushed into solution as hydrogen ions occupy exchange sites ( protonation ). A low pH may cause the hydrogen of hydroxyl groups to be pulled into solution, leaving charged sites on the colloid available to be occupied by other cations. This ionisation of hydroxy groups on the surface of soil colloids creates what is described as pH-dependent surface charges. Unlike permanent charges developed by isomorphous substitution , pH-dependent charges are variable and increase with increasing pH. Freed cations can be made available to plants but are also prone to be leached from
6720-575: The painting process, leaching of plating acids and tool chatter in machining pressed metal components. Several methods can be employed to measure porosity: where Soil organic matter Soil organic matter (SOM) is the organic matter component of soil , consisting of plant and animal detritus at various stages of decomposition , cells and tissues of soil microbes , and substances that soil microbes synthesize. SOM provides numerous benefits to soil's physical and chemical properties and its capacity to provide regulatory ecosystem services . SOM
6816-490: The plant roots release hydrogen ions to the solution. CEC is the amount of exchangeable hydrogen cation (H) that will combine with 100 grams dry weight of soil and whose measure is one milliequivalents per 100 grams of soil (1 meq/100 g). Hydrogen ions have a single charge and one-thousandth of a gram of hydrogen ions per 100 grams dry soil gives a measure of one milliequivalent of hydrogen ion. Calcium, with an atomic weight 40 times that of hydrogen and with
6912-540: The porosity of a porous medium (such as rock or sediment ) describes the fraction of void space in the material, where the void may contain, for example, air or water. It is defined by the ratio : where V V is the volume of void-space (such as fluids) and V T is the total or bulk volume of material, including the solid and void components. Both the mathematical symbols ϕ {\displaystyle \phi } and n {\displaystyle n} are used to denote porosity. Porosity
7008-482: The porous lava, and by these means organic matter and a finer mineral soil accumulate with time. Such initial stages of soil development have been described on volcanoes, inselbergs, and glacial moraines. How soil formation proceeds is influenced by at least five classic factors that are intertwined in the evolution of a soil: parent material, climate, topography (relief), organisms, and time. When reordered to climate, relief, organisms, parent material, and time, they form
7104-411: The processes carried out in the soil, with effects ranging from ozone depletion and global warming to rainforest destruction and water pollution . With respect to Earth's carbon cycle , soil acts as an important carbon reservoir , and it is potentially one of the most reactive to human disturbance and climate change . As the planet warms, it has been predicted that soils will add carbon dioxide to
7200-677: The proportionality between pore throat radii and porosity begins to fail and therefore so does the proportionality between porosity and hydraulic conductivity. For example: clays typically have very low hydraulic conductivity (due to their small pore throat radii) but also have very high porosities (due to the structured nature of clay minerals ), which means clays can hold a large volume of water per volume of bulk material, but they do not release water rapidly and therefore have low hydraulic conductivity. Well sorted (grains of approximately all one size) materials have higher porosity than similarly sized poorly sorted materials (where smaller particles fill
7296-411: The rate of diffusion of gases into and out of soil. Platy soil structure and soil compaction (low porosity) impede gas flow, and a deficiency of oxygen may encourage anaerobic bacteria to reduce (strip oxygen) from nitrate NO 3 to the gases N 2 , N 2 O, and NO, which are then lost to the atmosphere, thereby depleting the soil of nitrogen, a detrimental process called denitrification . Aerated soil
7392-458: The relative force required to pull a tillage implement through the clayey soil at field moisture content as compared to sand. Porosity of subsurface soil is lower than in surface soil due to compaction by gravity. Porosity of 0.20 is considered normal for unsorted gravel size material at depths below the biomantle . Porosity in finer material below the aggregating influence of pedogenesis can be expected to approximate this value. Soil porosity
7488-572: The residue of which then passes to the soil. The products of the metabolisms of these organisms are the secondary sources of SOM, which also includes their corpses. Some animals, like earthworms , termites , ants , and millipedes contribute to both vertical and horizontal translocation of organic matter. Additional sources of SOM include plant root exudates and charcoal . The water content of most vegetal detritus ranges from 60% to 90%. The dry matter consists mainly of carbon, oxygen, and hydrogen. Although these three elements make up about 92% of
7584-438: The seat of interaction networks playing a decisive role in the stability, dynamics and evolution of soil ecosystems. Biogenic soil volatile organic compounds are exchanged with the aboveground atmosphere, in which they are just 1–2 orders of magnitude lower than those from aboveground vegetation. Humans can get some idea of the soil atmosphere through the well-known 'after-the-rain' scent, when infiltering rainwater flushes out
7680-440: The soil anion exchange capacity. The cation exchange, that takes place between colloids and soil water, buffers (moderates) soil pH, alters soil structure, and purifies percolating water by adsorbing cations of all types, both useful and harmful. The negative or positive charges on colloid particles make them able to hold cations or anions, respectively, to their surfaces. The charges result from four sources. Cations held to
7776-536: The soil by volatilisation (loss to the atmosphere as gases) or leaching. Soil is said to be formed when organic matter has accumulated and colloids are washed downward, leaving deposits of clay, humus , iron oxide , carbonate , and gypsum , producing a distinct layer called the B horizon. This is a somewhat arbitrary definition as mixtures of sand, silt, clay and humus will support biological and agricultural activity before that time. These constituents are moved from one level to another by water and animal activity. As
7872-419: The soil solution composition (attenuate changes in the soil solution) as soils wet up or dry out, as plants take up nutrients, as salts are leached, or as acids or alkalis are added. Plant nutrient availability is affected by soil pH , which is a measure of the hydrogen ion activity in the soil solution. Soil pH is a function of many soil forming factors, and is generally lower (more acidic) where weathering
7968-401: The soil solution. Both living soil organisms (microbes, animals and plant roots) and soil organic matter are of critical importance to this recycling, and thereby to soil formation and soil fertility . Microbial soil enzymes may release nutrients from minerals or organic matter for use by plants and other microorganisms, sequester (incorporate) them into living cells, or cause their loss from
8064-471: The soil voids are saturated with water vapour, at least until the point of maximal hygroscopicity , beyond which a vapour-pressure deficit occurs in the soil pore space. Adequate porosity is necessary, not just to allow the penetration of water, but also to allow gases to diffuse in and out. Movement of gases is by diffusion from high concentrations to lower, the diffusion coefficient decreasing with soil compaction . Oxygen from above atmosphere diffuses in
8160-429: The soil water solution will be insufficient to change the pH, as the acid forming cations stored on the soil colloids will tend to restore the original pH condition as they are pushed off those colloids by the calcium of the added lime. The resistance of soil to change in pH, as a result of the addition of acid or basic material, is a measure of the buffering capacity of a soil and (for a particular soil type) increases as
8256-424: The soil water solution: Al replaces H replaces Ca replaces Mg replaces K same as NH 4 replaces Na If one cation is added in large amounts, it may replace the others by the sheer force of its numbers. This is called law of mass action . This is largely what occurs with the addition of cationic fertilisers ( potash , lime ). As the soil solution becomes more acidic (low pH , meaning an abundance of H),
8352-461: The soil where it is consumed and levels of carbon dioxide in excess of above atmosphere diffuse out with other gases (including greenhouse gases ) as well as water. Soil texture and structure strongly affect soil porosity and gas diffusion. It is the total pore space ( porosity ) of soil, not the pore size, and the degree of pore interconnection (or conversely pore sealing), together with water content, air turbulence and temperature, that determine
8448-500: The soil, a complex feedback which is exemplified in the dynamics of banded vegetation patterns in semi-arid regions. Soils supply plants with nutrients , most of which are held in place by particles of clay and organic matter ( colloids ) The nutrients may be adsorbed on clay mineral surfaces, bound within clay minerals ( absorbed ), or bound within organic compounds as part of the living organisms or dead soil organic matter. These bound nutrients interact with soil water to buffer
8544-411: The soil, possibly making the soil less fertile. Plants are able to excrete H into the soil through the synthesis of organic acids and by that means, change the pH of the soil near the root and push cations off the colloids, thus making those available to the plant. Cation exchange capacity is the soil's ability to remove cations from the soil water solution and sequester those to be exchanged later as
8640-407: The strength of anion adhesion is as follows: The amount of exchangeable anions is of a magnitude of tenths to a few milliequivalents per 100 g dry soil. As pH rises, there are relatively more hydroxyls, which will displace anions from the colloids and force them into solution and out of storage; hence AEC decreases with increasing pH (alkalinity). Soil reactivity is expressed in terms of pH and
8736-495: The total mass of topsoil for most upland soils. Soils whose upper horizons consist of less than 1% of organic matter are mainly limited to deserts , while the SOM content of soils in low-lying, wet areas can be as great as 90%. Soils containing 12% to 18% SOC are generally classified as organic soils . SOM can be divided into three genera: the living biomass of microbes , fresh and partially decomposed detritus, and humus . Surface plant litter , i.e., fresh vegetal residue,
8832-485: The two concentrations are equal, they are said to neutralise each other. A pH of 9.5 has 10 moles hydronium ions per litre of solution (and also 10 moles per litre OH). A pH of 3.5 has one million times more hydronium ions per litre than a solution with pH of 9.5 ( 9.5 − 3.5 = 6 or 10) and is more acidic. The effect of pH on a soil is to remove from the soil or to make available certain ions. Soils with high acidity tend to have toxic amounts of aluminium and manganese . As
8928-472: The void part of the soil volume and is occupied by gases or water. Soil consistency is the ability of soil materials to stick together. Soil temperature and colour are self-defining. Resistivity refers to the resistance to conduction of electric currents and affects the rate of corrosion of metal and concrete structures which are buried in soil. These properties vary through the depth of a soil profile, i.e. through soil horizons . Most of these properties determine
9024-552: The water content of the soil, as can be expressed in terms of volume or weight—can be based on in situ probes (e.g., capacitance probes , neutron probes ), or remote sensing methods. Soil moisture measurement is an important factor in determining changes in soil activity. The atmosphere of soil, or soil gas , is very different from the atmosphere above. The consumption of oxygen by microbes and plant roots, and their release of carbon dioxide, decreases oxygen and increases carbon dioxide concentration. Atmospheric CO 2 concentration
9120-461: The weathering of lava flow bedrock, which would produce the purely mineral-based parent material from which the soil texture forms. Soil development would proceed most rapidly from bare rock of recent flows in a warm climate, under heavy and frequent rainfall. Under such conditions, plants (in a first stage nitrogen-fixing lichens and cyanobacteria then epilithic higher plants ) become established very quickly on basaltic lava, even though there
9216-474: The whole soil atmosphere after a drought period, or when soil is excavated, a bulk property attributed in a reductionist manner to particular biochemical compounds such as petrichor or geosmin . Soil particles can be classified by their chemical composition ( mineralogy ) as well as their size. The particle size distribution of a soil, its texture, determines many of the properties of that soil, in particular hydraulic conductivity and water potential , but
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