88-459: Shand Power Station is a coal fired station owned by SaskPower in the Canadian province of Saskatchewan , near the city of Estevan . The Shand Power Station consists of: The boilers are supplied by Babcock & Wilcox and the turbines/generator are supplied by Hitachi . The site is sized for a potential second unit in the future. A single 148 m (486 ft) smokestack is located at
176-460: A greenhouse gas which is a major contributor to global warming . The results of a recent study show that the net income available to shareholders of large companies could see a significant reduction from the greenhouse gas emissions liability related to only natural disasters in the United States from a single coal-fired power plant. However, as of 2015, no such cases have awarded damages in
264-630: A cooler cooling system. However, it may be used in cogeneration plants to heat buildings, produce hot water, or to heat materials on an industrial scale, such as in some oil refineries , plants, and chemical synthesis plants. Typical thermal efficiency for utility-scale electrical generators is around 37% for coal and oil-fired plants, and 56 – 60% (LEV) for combined-cycle gas-fired plants. Plants designed to achieve peak efficiency while operating at capacity will be less efficient when operating off-design (i.e. temperatures too low.) Practical fossil fuels stations operating as heat engines cannot exceed
352-404: A cooler medium must be equal or larger than the ratio of absolute temperatures of the cooling system (environment) and the heat source (combustion furnace). Raising the furnace temperature improves the efficiency but complicates the design, primarily by the selection of alloys used for construction, making the furnace more expensive. The waste heat cannot be converted into mechanical energy without
440-516: A decline in basic activity level and information usage at 1000 ppm, when compared to 500 ppm. However a review of the literature found that a reliable subset of studies on the phenomenon of carbon dioxide induced cognitive impairment to only show a small effect on high-level decision making (for concentrations below 5000 ppm). Most of the studies were confounded by inadequate study designs, environmental comfort, uncertainties in exposure doses and differing cognitive assessments used. Similarly
528-503: A factory or data center, or may also be operated in parallel with the local utility system to reduce peak power demand charge from the utility. Diesel engines can produce strong torque at relatively low rotational speeds, which is generally desirable when driving an alternator , but diesel fuel in long-term storage can be subject to problems resulting from water accumulation and chemical decomposition . Rarely used generator sets may correspondingly be installed as natural gas or LPG to minimize
616-487: A fine filter that collects the ash particles, electrostatic precipitators use an electric field to trap ash particles on high-voltage plates, and cyclone collectors use centrifugal force to trap particles to the walls. A recent study indicates that sulfur emissions from fossil fueled power stations in China may have caused a 10-year lull in global warming (1998-2008). Fossil-fuel power stations, particularly coal-fired plants, are
704-446: A fixed structure. However, in a Coulomb explosion imaging experiment, an instantaneous image of the molecular structure can be deduced. Such an experiment has been performed for carbon dioxide. The result of this experiment, and the conclusion of theoretical calculations based on an ab initio potential energy surface of the molecule, is that none of the molecules in the gas phase are ever exactly linear. This counter-intuitive result
792-478: A fossil fuel power plant the chemical energy stored in fossil fuels such as coal , fuel oil , natural gas or oil shale and oxygen of the air is converted successively into thermal energy , mechanical energy and, finally, electrical energy . Each fossil fuel power plant is a complex, custom-designed system. Multiple generating units may be built at a single site for more efficient use of land , natural resources and labor . Most thermal power stations in
880-611: A glass state similar to other members of its elemental family, like silicon dioxide (silica glass) and germanium dioxide . Unlike silica and germania glasses, however, carbonia glass is not stable at normal pressures and reverts to gas when pressure is released. At temperatures and pressures above the critical point, carbon dioxide behaves as a supercritical fluid known as supercritical carbon dioxide . Table of thermal and physical properties of saturated liquid carbon dioxide: Table of thermal and physical properties of carbon dioxide (CO 2 ) at atmospheric pressure: Carbon dioxide
968-636: A major source of industrial wastewater . Wastewater streams include flue-gas desulfurization, fly ash, bottom ash and flue gas mercury control. Plants with air pollution controls such as wet scrubbers typically transfer the captured pollutants to the wastewater stream. Ash ponds , a type of surface impoundment, are a widely used treatment technology at coal-fired plants. These ponds use gravity to settle out large particulates (measured as total suspended solids ) from power plant wastewater. This technology does not treat dissolved pollutants. Power stations use additional technologies to control pollutants, depending on
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#17328511819021056-491: A mature forest will produce as much CO 2 from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants. Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon and remain valuable carbon sinks , helping to maintain the carbon balance of Earth's atmosphere. Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO 2 in
1144-428: A much larger denominator and a much smaller value than the true K a1 . The bicarbonate ion is an amphoteric species that can act as an acid or as a base, depending on pH of the solution. At high pH, it dissociates significantly into the carbonate ion ( CO 2− 3 ): In organisms, carbonic acid production is catalysed by the enzyme known as carbonic anhydrase . In addition to altering its acidity,
1232-408: A particular fuel. As an example, a new 1500 MW supercritical lignite-fueled power station running on average at half its capacity might have annual CO 2 emissions estimated as: = 1500MW x 0.5 x 100/40 x 101000 kg/TJ x 1year = 1500MJ/s x 0.5 x 2.5 x 0.101 kg/MJ x 365x24x60x60s = 1.5x10 x 5x10 x 2.5 x 1.01 x 3.1536x10 kg = 59.7 x10 kg = 5.97 Mt Thus the example power station
1320-447: A reciprocating gas engine . All plants use the energy extracted from the expansion of a hot gas, either steam or combustion gases. Although different energy conversion methods exist, all thermal power station conversion methods have their efficiency limited by the Carnot efficiency and therefore produce waste heat . Fossil fuel power stations provide most of the electrical energy used in
1408-433: A serious impact on public health. Power plants remove particulate from the flue gas with the use of a bag house or electrostatic precipitator . Several newer plants that burn coal use a different process, Integrated Gasification Combined Cycle in which synthesis gas is made out of a reaction between coal and water. The synthesis gas is processed to remove most pollutants and then used initially to power gas turbines. Then
1496-416: A study on the effects of the concentration of CO 2 in motorcycle helmets has been criticized for having dubious methodology in not noting the self-reports of motorcycle riders and taking measurements using mannequins. Further when normal motorcycle conditions were achieved (such as highway or city speeds) or the visor was raised the concentration of CO 2 declined to safe levels (0.2%). Poor ventilation
1584-467: A typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls . Since it is centrosymmetric, the molecule has no electric dipole moment . As a linear triatomic molecule, CO 2 has four vibrational modes as shown in the diagram. In the symmetric and the antisymmetric stretching modes, the atoms move along the axis of the molecule. There are two bending modes, which are degenerate , meaning that they have
1672-485: A waste product. In turn, oxygen is consumed and CO 2 is released as waste by all aerobic organisms when they metabolize organic compounds to produce energy by respiration . CO 2 is released from organic materials when they decay or combust, such as in forest fires. When carbon dioxide dissolves in water, it forms carbonate and mainly bicarbonate ( HCO − 3 ), which causes ocean acidification as atmospheric CO 2 levels increase. Carbon dioxide
1760-469: Is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone , where what was previously atmospheric carbon can remain fixed for geological timescales. Plants can grow as much as 50% faster in concentrations of 1,000 ppm CO 2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients. Elevated CO 2 levels cause increased growth reflected in
1848-419: Is 304.128(15) K (30.978(15) °C) at 7.3773(30) MPa (72.808(30) atm). Another form of solid carbon dioxide observed at high pressure is an amorphous glass-like solid. This form of glass, called carbonia , is produced by supercooling heated CO 2 at extreme pressures (40–48 GPa , or about 400,000 atmospheres) in a diamond anvil . This discovery confirmed the theory that carbon dioxide could exist in
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#17328511819021936-566: Is 53% more dense than dry air, but is long lived and thoroughly mixes in the atmosphere. About half of excess CO 2 emissions to the atmosphere are absorbed by land and ocean carbon sinks . These sinks can become saturated and are volatile, as decay and wildfires result in the CO 2 being released back into the atmosphere. CO 2 is eventually sequestered (stored for the long term) in rocks and organic deposits like coal , petroleum and natural gas . Nearly all CO2 produced by humans goes into
2024-406: Is a chemical compound with the chemical formula CO 2 . It is made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle , atmospheric CO 2 is the primary carbon source for life on Earth. In
2112-476: Is a deceiving baseline for comparison: just the Chernobyl nuclear disaster released, in iodine-131 alone, an estimated 1.76 EBq. of radioactivity, a value one order of magnitude above this value for total emissions from all coal burned within a century, while the iodine-131, the major radioactive substance which comes out in accident situations, has a half life of just 8 days. Carbon dioxide Carbon dioxide
2200-424: Is a relatively cheap fuel. Coal is an impure fuel and produces more greenhouse gas and pollution than an equivalent amount of petroleum or natural gas. For instance, the operation of a 1000-MWe coal-fired power plant results in a nuclear radiation dose of 490 person-rem/year, compared to 136 person-rem/year for an equivalent nuclear power plant, including uranium mining, reactor operation and waste disposal. Coal
2288-415: Is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism . This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates , the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians ) or the gills (e.g., fish ), from where it dissolves in
2376-419: Is burned that significant amounts of these substances are released. A 1,000 MW coal-burning power plant could have an uncontrolled release of as much as 5.2 metric tons per year of uranium (containing 74 pounds (34 kg) of uranium-235 ) and 12.8 metric tons per year of thorium. In comparison, a 1,000 MW nuclear plant will generate about 30 metric tons of high-level radioactive solid packed waste per year. It
2464-550: Is caused by the emission of nitrogen oxides and sulfur dioxide . These gases may be only mildly acidic themselves, yet when they react with the atmosphere, they create acidic compounds such as sulfurous acid , nitric acid and sulfuric acid which fall as rain, hence the term acid rain. In Europe and the US, stricter emission laws and decline in heavy industries have reduced the environmental hazards associated with this problem, leading to lower emissions after their peak in 1960s. In 2008,
2552-402: Is commercially used in its solid form, commonly known as " dry ice ". The solid-to-gas phase transition occurs at 194.7 Kelvin and is called sublimation . The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3 pm , noticeably shorter than the roughly 140 pm length of
2640-428: Is converted to steam in the boiler; additional heating stages may be included to superheat the steam. The hot steam is sent through controlling valves to a turbine. As the steam expands and cools, its energy is transferred to the turbine blades which turn a generator. The spent steam has very low pressure and energy content; this water vapor is fed through a condenser, which removes heat from the steam. The condensed water
2728-403: Is delivered by highway truck , rail , barge , collier ship or coal slurry pipeline . Generating stations adjacent to a mine may receive coal by conveyor belt or massive diesel-electric -drive trucks . Coal is usually prepared for use by crushing the rough coal to pieces less than 2 inches (5 cm) in size. Gas is a very common fuel and has mostly replaced coal in countries where gas
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2816-499: Is estimated that during 1982, US coal burning released 155 times as much uncontrolled radioactivity into the atmosphere as the Three Mile Island incident . The collective radioactivity resulting from all coal burning worldwide between 1937 and 2040 is estimated to be 2,700,000 curies or 0.101 EBq. During normal operation, the effective dose equivalent from coal plants is 100 times that from nuclear plants. Normal operation however,
2904-421: Is estimated to emit about 6 megatonnes of carbon dioxide each year. The results of similar estimations are mapped by organisations such as Global Energy Monitor , Carbon Tracker and ElectricityMap. Alternatively it may be possible to measure CO 2 emissions (perhaps indirectly via another gas) from satellite observations. Another problem related to coal combustion is the emission of particulates that have
2992-632: Is one of the main causes of excessive CO 2 concentrations in closed spaces, leading to poor indoor air quality . Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO 2 concentration has stabilized) are sometimes used to estimate ventilation rates per person. Higher CO 2 concentrations are associated with occupant health, comfort and performance degradation. ASHRAE Standard 62.1–2007 ventilation rates may result in indoor concentrations up to 2,100 ppm above ambient outdoor conditions. Thus if
3080-410: Is ordinarily a difficult and slow reaction: The redox potential for this reaction near pH 7 is about −0.53 V versus the standard hydrogen electrode . The nickel-containing enzyme carbon monoxide dehydrogenase catalyses this process. Photoautotrophs (i.e. plants and cyanobacteria ) use the energy contained in sunlight to photosynthesize simple sugars from CO 2 absorbed from
3168-405: Is produced as a by-product. Ribulose-1,5-bisphosphate carboxylase oxygenase , commonly abbreviated to RuBisCO, is the enzyme involved in the first major step of carbon fixation, the production of two molecules of 3-phosphoglycerate from CO 2 and ribulose bisphosphate , as shown in the diagram at left. RuBisCO is thought to be the single most abundant protein on Earth. Phototrophs use
3256-646: Is referred to as a combined cycle power plant because it combines the Brayton cycle of the gas turbine with the Rankine cycle of the HRSG. The turbines are fueled either with natural gas or fuel oil. Diesel engine generator sets are often used for prime power in communities not connected to a widespread power grid. Emergency (standby) power systems may use reciprocating internal combustion engines operated by fuel oil or natural gas. Standby generators may serve as emergency power for
3344-464: Is still important as the fuel source for diesel engine power plants used especially in isolated communities not interconnected to a grid. Liquid fuels may also be used by gas turbine power plants, especially for peaking or emergency service. Of the three fossil fuel sources, oil has the advantages of easier transportation and handling than solid coal, and easier on-site storage than natural gas. Combined heat and power (CHP), also known as cogeneration ,
3432-502: Is still unknown as to which kinds of particulate matter pose the most harm, which makes it difficult to come up with adequate legislation for regulating particulate matter. There are several methods of helping to reduce the particulate matter emissions from coal-fired plants. Roughly 80% of the ash falls into an ash hopper, but the rest of the ash then gets carried into the atmosphere to become coal-fly ash. Methods of reducing these emissions of particulate matter include: The baghouse has
3520-472: Is the true first acid dissociation constant, defined as where the denominator includes only covalently bound H 2 CO 3 and does not include hydrated CO 2 (aq). The much smaller and often-quoted value near 4.16 × 10 (or pK a1 = 6.38) is an apparent value calculated on the (incorrect) assumption that all dissolved CO 2 is present as carbonic acid, so that Since most of the dissolved CO 2 remains as CO 2 molecules, K a1 (apparent) has
3608-414: Is the " nameplate capacity " or the maximum allowed output of the plant, " capacity factor " or "load factor" is a measure of the amount of power that a plant produces compared with the amount it would produce if operated at its rated capacity nonstop, heat rate is thermal energy in/electrical energy out, emission intensity (also called emission factor ) is the CO 2 emitted per unit of heat generated for
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3696-545: Is the main cause of these increased CO 2 concentrations, which are the primary cause of climate change . Its concentration in Earth's pre-industrial atmosphere since late in the Precambrian was regulated by organisms and geological features. Plants , algae and cyanobacteria use energy from sunlight to synthesize carbohydrates from carbon dioxide and water in a process called photosynthesis , which produces oxygen as
3784-536: Is the use of a thermal power station to provide both electric power and heat (the latter being used, for example, for district heating purposes). This technology is practiced not only for domestic heating (low temperature) but also for industrial process heat, which is often high temperature heat. Calculations show that Combined Heat and Power District Heating (CHPDH) is the cheapest method in reducing (but not eliminating) carbon emissions, if conventional fossil fuels remain to be burned. Thermal power plants are one of
3872-433: Is then pumped into the boiler to repeat the cycle. Emissions from the boiler include carbon dioxide, oxides of sulfur, and in the case of coal fly ash from non-combustible substances in the fuel. Waste heat from the condenser is transferred either to the air, or sometimes to a cooling pond, lake or river. One type of fossil fuel power plant uses a gas turbine in conjunction with a heat recovery steam generator (HRSG). It
3960-419: Is trivially due to the fact that the nuclear motion volume element vanishes for linear geometries. This is so for all molecules except diatomic molecules . Carbon dioxide is soluble in water, in which it reversibly forms H 2 CO 3 (carbonic acid), which is a weak acid , because its ionization in water is incomplete. The hydration equilibrium constant of carbonic acid is, at 25 °C: Hence,
4048-465: Is used in CO 2 scrubbers and has been suggested as a possible starting point for carbon capture and storage by amine gas treating . Only very strong nucleophiles, like the carbanions provided by Grignard reagents and organolithium compounds react with CO 2 to give carboxylates : In metal carbon dioxide complexes , CO 2 serves as a ligand , which can facilitate the conversion of CO 2 to other chemicals. The reduction of CO 2 to CO
4136-465: Is what remains after the coal has been combusted, so it consists of the incombustible materials that are found in the coal. The size and chemical composition of these particles affects the impacts on human health. Currently coarse (diameter greater than 2.5 μm) and fine (diameter between 0.1 μm and 2.5 μm) particles are regulated, but ultrafine particles (diameter less than 0.1 μm) are currently unregulated, yet they pose many dangers. Unfortunately much
4224-462: The Carnot cycle limit for conversion of heat energy into useful work. Fuel cells do not have the same thermodynamic limits as they are not heat engines. The efficiency of a fossil fuel plant may be expressed as its heat rate , expressed in BTU/kilowatthour or megajoules/kilowatthour. In a steam turbine power plant, fuel is burned in a furnace and the hot gasses flow through a boiler. Water
4312-810: The European Environment Agency (EEA) documented fuel-dependent emission factors based on actual emissions from power plants in the European Union . Electricity generation using carbon-based fuels is responsible for a large fraction of carbon dioxide (CO 2 ) emissions worldwide and for 34% of U.S. man-made carbon dioxide emissions in 2010. In the U.S. 70% of electricity is generated by combustion of fossil fuels. Coal contains more carbon than oil or natural gas fossil fuels, resulting in greater volumes of carbon dioxide emissions per unit of electricity generated. In 2010, coal contributed about 81% of CO 2 emissions from generation and contributed about 45% of
4400-460: The fossil fuels contains carbon dioxide and water vapor, as well as pollutants such as nitrogen oxides (NO x ), sulfur oxides (SO x ), and, for coal-fired plants, mercury , traces of other metals, and fly ash . Usually all of the carbon dioxide and some of the other pollution is discharged to the air. Solid waste ash from coal-fired boilers must also be removed. Fossil fueled power stations are major emitters of carbon dioxide (CO 2 ),
4488-436: The greenhouse gas carbon dioxide within the atmosphere will "very likely" lead to higher average temperatures on a global scale ( global warming ). Concerns regarding the potential for such warming to change the global climate prompted IPCC recommendations calling for large cuts to CO 2 emissions worldwide. Emissions can be reduced with higher combustion temperatures, yielding more efficient production of electricity within
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#17328511819024576-518: The United States. Per unit of electric energy, brown coal emits nearly twice as much CO 2 as natural gas, and black coal emits somewhat less than brown. As of 2019 , carbon capture and storage of emissions is not economically viable for fossil fuel power stations, and keeping global warming below 1.5 °C is still possible but only if no more fossil fuel power plants are built and some existing fossil fuel power plants are shut down early, together with other measures such as reforestation . In
4664-439: The air and water: Carbon dioxide is colorless. At low concentrations, the gas is odorless; however, at sufficiently high concentrations, it has a sharp, acidic odor. At standard temperature and pressure , the density of carbon dioxide is around 1.98 kg/m , about 1.53 times that of air . Carbon dioxide has no liquid state at pressures below 0.51795(10) MPa (5.11177(99) atm ). At a pressure of 1 atm (0.101325 MPa),
4752-444: The air, carbon dioxide is transparent to visible light but absorbs infrared radiation , acting as a greenhouse gas . Carbon dioxide is soluble in water and is found in groundwater , lakes , ice caps , and seawater . It is a trace gas in Earth's atmosphere at 421 parts per million (ppm) , or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels
4840-430: The atmosphere. Less than 1% of CO2 produced annually is put to commercial use, mostly in the fertilizer industry and in the oil and gas industry for enhanced oil recovery . Other commercial applications include food and beverage production, metal fabrication, cooling, fire suppression and stimulating plant growth in greenhouses. Carbon dioxide cannot be liquefied at atmospheric pressure. Low-temperature carbon dioxide
4928-577: The communities include: buffaloberry , bur oak , choke cherry , Colorado blue spruce , eastern red cedar , green ash , jack pine , lodgepole pine , Manitoba maple , pin cherry , plains cottonwood , red alder , red-osier dogwood , Saskatoon berry , Scots pine , sea-buckthorn , shrub willow , Siberian crab , Siberian larch , trembling aspen or white poplar , villosa lilac , western sandcherry , white birch or paper birch , willow , and Woods' rose . Fossil fuel power plant 2021 world electricity generation by source. Total generation
5016-806: The condition. There are few studies of the health effects of long-term continuous CO 2 exposure on humans and animals at levels below 1%. Occupational CO 2 exposure limits have been set in the United States at 0.5% (5000 ppm) for an eight-hour period. At this CO 2 concentration, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption. Studies in animals at 0.5% CO 2 have demonstrated kidney calcification and bone loss after eight weeks of exposure. A study of humans exposed in 2.5 hour sessions demonstrated significant negative effects on cognitive abilities at concentrations as low as 0.1% (1000 ppm) CO 2 likely due to CO 2 induced increases in cerebral blood flow. Another study observed
5104-423: The cycle. As of 2019 the price of emitting CO 2 to the atmosphere is much lower than the cost of adding carbon capture and storage (CCS) to fossil fuel power stations, so owners have not done so. The CO 2 emissions from a fossil fuel power station can be estimated with the following formula: CO 2 emissions = capacity x capacity factor x heat rate x emission intensity x time where "capacity"
5192-510: The degenerate pair of bending modes at 667 cm (wavelength 15.0 μm). The symmetric stretching mode does not create an electric dipole so is not observed in IR spectroscopy, but it is detected in Raman spectroscopy at 1388 cm (wavelength 7.20 μm), with a Fermi resonance doublet at 1285 cm . In the gas phase, carbon dioxide molecules undergo significant vibrational motions and do not keep
5280-566: The dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of Goma by CO 2 emissions from the nearby volcano Mount Nyiragongo . The Swahili term for this phenomenon is mazuku . Adaptation to increased concentrations of CO 2 occurs in humans, including modified breathing and kidney bicarbonate production, in order to balance
5368-541: The effects of blood acidification ( acidosis ). Several studies suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine ) since the adaptation is physiological and reversible, as deterioration in performance or in normal physical activity does not happen at this level of exposure for five days. Yet, other studies show a decrease in cognitive function even at much lower levels. Also, with ongoing respiratory acidosis , adaptation or compensatory mechanisms will be unable to reverse
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#17328511819025456-551: The electrical conductivity of fully deionized water without CO 2 saturation is comparably low in relation to these data. CO 2 is a potent electrophile having an electrophilic reactivity that is comparable to benzaldehyde or strongly electrophilic α,β-unsaturated carbonyl compounds . However, unlike electrophiles of similar reactivity, the reactions of nucleophiles with CO 2 are thermodynamically less favored and are often found to be highly reversible. The reversible reaction of carbon dioxide with amines to make carbamates
5544-510: The electricity generated in the United States. In 2000, the carbon intensity (CO 2 emissions) of U.S. coal thermal combustion was 2249 lbs/MWh (1,029 kg/MWh) while the carbon intensity of U.S. oil thermal generation was 1672 lb/MWh (758 kg/MWh or 211 kg/ GJ ) and the carbon intensity of U.S. natural gas thermal production was 1135 lb/MWh (515 kg/MWh or 143 kg/GJ). The Intergovernmental Panel on Climate Change ( IPCC ) reports that increased quantities of
5632-431: The first central stations used reciprocating steam engines to drive generators. As the size of the electrical load to be served grew, reciprocating units became too large and cumbersome to install economically. The steam turbine rapidly displaced all reciprocating engines in central station service. Coal is the most abundant fossil fuel on the planet, and widely used as the source of energy in thermal power stations and
5720-568: The fuel system maintenance requirements. Spark-ignition internal combustion engines operating on gasoline (petrol), propane , or LPG are commonly used as portable temporary power sources for construction work, emergency power, or recreational uses. Reciprocating external combustion engines such as the Stirling engine can be run on a variety of fossil fuels, as well as renewable fuels or industrial waste heat. Installations of Stirling engines for power production are relatively uncommon. Historically,
5808-469: The gas deposits directly to a solid at temperatures below 194.6855(30) K (−78.4645(30) °C) and the solid sublimes directly to a gas above this temperature. In its solid state, carbon dioxide is commonly called dry ice . Liquid carbon dioxide forms only at pressures above 0.51795(10) MPa (5.11177(99) atm); the triple point of carbon dioxide is 216.592(3) K (−56.558(3) °C) at 0.51795(10) MPa (5.11177(99) atm) (see phase diagram). The critical point
5896-597: The harvestable yield of crops, with wheat, rice and soybean all showing increases in yield of 12–14% under elevated CO 2 in FACE experiments. Increased atmospheric CO 2 concentrations result in fewer stomata developing on plants which leads to reduced water usage and increased water-use efficiency . Studies using FACE have shown that CO 2 enrichment leads to decreased concentrations of micronutrients in crop plants. This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain
5984-460: The hot exhaust gases from the gas turbines are used to generate steam to power a steam turbine. The pollution levels of such plants are drastically lower than those of "classic" coal power plants. Particulate matter from coal-fired plants can be harmful and have negative health impacts. Studies have shown that exposure to particulate matter is related to an increase of respiratory and cardiac mortality. Particulate matter can irritate small airways in
6072-428: The lungs, which can lead to increased problems with asthma, chronic bronchitis, airway obstruction, and gas exchange. There are different types of particulate matter, depending on the chemical composition and size. The dominant form of particulate matter from coal-fired plants is coal fly ash , but secondary sulfate and nitrate also comprise a major portion of the particulate matter from coal-fired plants. Coal fly ash
6160-476: The main artificial sources of producing toxic gases and particulate matter . Fossil fuel power plants cause the emission of pollutants such as NO x , SO x , CO 2 , CO, PM, organic gases and polycyclic aromatic hydrocarbons. World organizations and international agencies, like the IEA, are concerned about the environmental impact of burning fossil fuels , and coal in particular. The combustion of coal contributes
6248-444: The majority of the carbon dioxide is not converted into carbonic acid, but remains as CO 2 molecules, not affecting the pH. The relative concentrations of CO 2 , H 2 CO 3 , and the deprotonated forms HCO − 3 ( bicarbonate ) and CO 2− 3 ( carbonate ) depend on the pH . As shown in a Bjerrum plot , in neutral or slightly alkaline water (pH > 6.5), the bicarbonate form predominates (>50%) becoming
6336-443: The most prevalent (>95%) at the pH of seawater. In very alkaline water (pH > 10.4), the predominant (>50%) form is carbonate. The oceans, being mildly alkaline with typical pH = 8.2–8.5, contain about 120 mg of bicarbonate per liter. Being diprotic , carbonic acid has two acid dissociation constants , the first one for the dissociation into the bicarbonate (also called hydrogen carbonate) ion ( HCO − 3 ): This
6424-488: The most to acid rain and air pollution , and has been connected with global warming . Due to the chemical composition of coal there are difficulties in removing impurities from the solid fuel prior to its combustion. Modern day coal power plants pollute less than older designs due to new " scrubber " technologies that filter the exhaust air in smoke stacks. However, emission levels of various pollutants are still on average several times greater than natural gas power plants and
6512-607: The particular wastestream in the plant. These include dry ash handling, closed-loop ash recycling, chemical precipitation, biological treatment (such as an activated sludge process), membrane systems, and evaporation-crystallization systems. In 2015 EPA published a regulation pursuant to the Clean Water Act that requires US power plants to use one or more of these technologies. Technological advancements in ion exchange membranes and electrodialysis systems has enabled high efficiency treatment of flue-gas desulfurization wastewater to meet
6600-586: The plant, the tallest freestanding structure in Saskatchewan. The unit at Shand would have to be retired by 2030 under federal regulations unless carbon capture and storage was installed. Shand Greenhouse was built in 1991 near the power station and is part of an initiative to offset the environmental impact of burning coal. The greenhouse grow and distribute seedlings free of charge to schools, communities and individuals for conservation and wildlife habitat projects. The species of trees that are grown and given to
6688-495: The presence of carbon dioxide in water also affects its electrical properties. When carbon dioxide dissolves in desalinated water, the electrical conductivity increases significantly from below 1 μS/cm to nearly 30 μS/cm. When heated, the water begins to gradually lose the conductivity induced by the presence of C O 2 {\displaystyle \mathrm {CO_{2}} } , especially noticeable as temperatures exceed 30 °C. The temperature dependence of
6776-499: The presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour. Concentrations of more than 10% may cause convulsions, coma, and death. CO 2 levels of more than 30% act rapidly leading to loss of consciousness in seconds. Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without
6864-496: The products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides , nucleic acids , and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales. A globally significant species of coccolithophore
6952-420: The same amount of protein. The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered in plants exposed to high concentrations of CO 2 . Plants also emit CO 2 during respiration, and so the majority of plants and algae, which use C3 photosynthesis , are only net absorbers during the day. Though a growing forest will absorb many tons of CO 2 each year,
7040-411: The same frequency and same energy, because of the symmetry of the molecule. When a molecule touches a surface or touches another molecule, the two bending modes can differ in frequency because the interaction is different for the two modes. Some of the vibrational modes are observed in the infrared (IR) spectrum : the antisymmetric stretching mode at wavenumber 2349 cm (wavelength 4.25 μm) and
7128-530: The scrubbers transfer the captured pollutants to wastewater, which still requires treatment in order to avoid pollution of receiving water bodies. In these modern designs, pollution from coal-fired power plants comes from the emission of gases such as carbon dioxide, nitrogen oxides , and sulfur dioxide into the air, as well a significant volume of wastewater which may contain lead , mercury , cadmium and chromium , as well as arsenic , selenium and nitrogen compounds ( nitrates and nitrites ). Acid rain
7216-531: The updated EPA discharge limits. Coal is a sedimentary rock formed primarily from accumulated plant matter, and it includes many inorganic minerals and elements which were deposited along with organic material during its formation. As the rest of the Earth's crust , coal also contains low levels of uranium , thorium , and other naturally occurring radioactive isotopes whose release into the environment leads to radioactive contamination . While these substances are present as very small trace impurities, enough coal
7304-535: The upper ocean and thereby promotes the absorption of CO 2 from the atmosphere. Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (412 ppm), depending on the location. In humans, exposure to CO 2 at concentrations greater than 5% causes the development of hypercapnia and respiratory acidosis . Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in
7392-546: The water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration. Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and cyanobacteria into energy-rich organic molecules such as glucose , thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic compounds can be constructed, and oxygen
7480-438: The world use fossil fuel, outnumbering nuclear , geothermal , biomass , or concentrated solar power plants. The second law of thermodynamics states that any closed-loop cycle can only convert a fraction of the heat produced during combustion into mechanical work . The rest of the heat, called waste heat , must be released into a cooler environment during the return portion of the cycle. The fraction of heat released into
7568-484: The world. Some fossil-fired power stations are designed for continuous operation as baseload power plants , while others are used as peaker plants . However, starting from the 2010s, in many countries plants designed for baseload supply are being operated as dispatchable generation to balance increasing generation by variable renewable energy . By-products of fossil fuel power plant operation must be considered in their design and operation. Flue gas from combustion of
7656-423: Was 28 petawatt-hours . A fossil fuel power station is a thermal power station which burns a fossil fuel , such as coal , oil , or natural gas , to produce electricity . Fossil fuel power stations have machinery to convert the heat energy of combustion into mechanical energy , which then operates an electrical generator . The prime mover may be a steam turbine , a gas turbine or, in small plants,
7744-455: Was found in the late 20th century or early 21st century, such as the US and UK. Sometimes coal-fired steam plants are refitted to use natural gas to reduce net carbon dioxide emissions. Oil-fuelled plants may be converted to natural gas to lower operating cost. Heavy fuel oil was once a significant source of energy for electric power generation. After oil price increases of the 1970s, oil was displaced by coal and later natural gas. Distillate oil
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