Radioactive waste is a type of hazardous waste that contains radioactive material . Radioactive waste is a result of many activities, including nuclear medicine , nuclear research , nuclear power generation, nuclear decommissioning , rare-earth mining, and nuclear weapons reprocessing. The storage and disposal of radioactive waste is regulated by government agencies in order to protect human health and the environment.
173-428: Plutonium is a chemical element ; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized . The element normally exhibits six allotropes and four oxidation states . It reacts with carbon , halogens , nitrogen , silicon , and hydrogen . When exposed to moist air, it forms oxides and hydrides that can expand
346-572: A critical mass . During the early stages of research, animals were used to study the effects of radioactive substances on health. These studies began in 1944 at the University of California at Berkeley's Radiation Laboratory and were conducted by Joseph G. Hamilton. Hamilton was looking to answer questions about how plutonium would vary in the body depending on exposure mode (oral ingestion, inhalation, absorption through skin), retention rates, and how plutonium would be fixed in tissues and distributed among
519-457: A multiplication factor (k eff ) larger than one, which means that if the metal is present in sufficient quantity and with an appropriate geometry (e.g., a sphere of sufficient size), it can form a critical mass . During fission, a fraction of the nuclear binding energy , which holds a nucleus together, is released as a large amount of electromagnetic and kinetic energy (much of the latter being quickly converted to thermal energy). Fission of
692-450: A nuclear chain reaction , leading to applications in nuclear weapons and nuclear reactors . Plutonium-240 has a high rate of spontaneous fission , raising the neutron flux of any sample containing it. The presence of plutonium-240 limits a plutonium sample's usability for weapons or its quality as reactor fuel, and the percentage of plutonium-240 determines its grade ( weapons-grade , fuel-grade, or reactor-grade). Plutonium-238 has
865-738: A pure element . In chemistry, a pure element means a substance whose atoms all (or in practice almost all) have the same atomic number, or number of protons . Nuclear scientists, however, define a pure element as one that consists of only one isotope. For example, a copper wire is 99.99% chemically pure if 99.99% of its atoms are copper, with 29 protons each. However it is not isotopically pure since ordinary copper consists of two stable isotopes, 69% Cu and 31% Cu, with different numbers of neutrons. However, pure gold would be both chemically and isotopically pure, since ordinary gold consists only of one isotope, Au. Atoms of chemically pure elements may bond to each other chemically in more than one way, allowing
1038-411: A vacuum or an inert atmosphere to avoid reaction with air. At 135 °C the metal will ignite in air and will explode if placed in carbon tetrachloride . Plutonium is a reactive metal. In moist air or moist argon , the metal oxidizes rapidly, producing a mixture of oxides and hydrides . If the metal is exposed long enough to a limited amount of water vapor, a powdery surface coating of PuO 2
1211-540: A considerable amount of time. (See element naming controversy ). Precursors of such controversies involved the nationalistic namings of elements in the late 19th century. For example, lutetium was named in reference to Paris, France. The Germans were reluctant to relinquish naming rights to the French, often calling it cassiopeium . Similarly, the British discoverer of niobium originally named it columbium , in reference to
1384-527: A currently uneconomic prospect. A summary of the amounts of radioactive waste and management approaches for most developed countries are presented and reviewed periodically as part of a joint convention of the International Atomic Energy Agency (IAEA). A quantity of radioactive waste typically consists of a number of radionuclides , which are unstable isotopes of elements that undergo decay and thereby emit ionizing radiation , which
1557-517: A developing organism such as a fetus is irradiated, it is possible a birth defect may be induced, but it is unlikely this defect will be in a gamete or a gamete-forming cell . The incidence of radiation-induced mutations in humans is small, as in most mammals, because of natural cellular-repair mechanisms, many just now coming to light. These mechanisms range from DNA, mRNA and protein repair, to internal lysosomic digestion of defective proteins, and even induced cell suicide—apoptosis Depending on
1730-477: A different element in nuclear reactions , which change an atom's atomic number. Historically, the term "chemical element" meant a substance that cannot be broken down into constituent substances by chemical reactions, and for most practical purposes this definition still has validity. There was some controversy in the 1920s over whether isotopes deserved to be recognized as separate elements if they could be separated by chemical means. The term "(chemical) element"
1903-643: A few decay products, to have been differentiated from other elements. Most recently, the synthesis of element 118 (since named oganesson ) was reported in October 2006, and the synthesis of element 117 ( tennessine ) was reported in April 2010. Of these 118 elements, 94 occur naturally on Earth. Six of these occur in extreme trace quantities: technetium , atomic number 43; promethium , number 61; astatine , number 85; francium , number 87; neptunium , number 93; and plutonium , number 94. These 94 elements have been detected in
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#17328454185392076-525: A few elements, such as silver and gold , are found uncombined as relatively pure native element minerals . Nearly all other naturally occurring elements occur in the Earth as compounds or mixtures. Air is mostly a mixture of molecular nitrogen and oxygen , though it does contain compounds including carbon dioxide and water , as well as atomic argon , a noble gas which is chemically inert and therefore does not undergo chemical reactions. The history of
2249-554: A general rule, short-lived waste (mainly non-fuel materials from reactors) is buried in shallow repositories, while long-lived waste (from fuel and fuel reprocessing) is deposited in geological repository. Regulations in the United States do not define this category of waste; the term is used in Europe and elsewhere. ILW makes up 6% of all radioactive waste volume in the UK. High-level waste (HLW)
2422-463: A half-life of 80.8 million years; Pu, with a half-life of 373,300 years; and Pu, with a half-life of 24,110 years. All other isotopes have half-lives of less than 7,000 years. This element also has eight metastable states , though all have half-lives less than a second. Pu has been found in interstellar space and it has the longest half-life of any non-primordial radioisotope. The main decay modes of isotopes with mass numbers lower than
2595-500: A half-life of 87.7 years and emits alpha particles . It is a heat source in radioisotope thermoelectric generators , which are used to power some spacecraft . Plutonium isotopes are expensive and inconvenient to separate, so particular isotopes are usually manufactured in specialized reactors. Producing plutonium in useful quantities for the first time was a major part of the Manhattan Project during World War II that developed
2768-492: A half-life that can stretch to as long as 24,000 years. The amount of HLW worldwide is increasing by about 12,000 tonnes per year. A 1000- megawatt nuclear power plant produces about 27 tonnes of spent nuclear fuel (unreprocessed) every year. For comparison, the amount of ash produced by coal power plants in the United States is estimated at 130,000,000 t per year and fly ash is estimated to release 100 times more radiation than an equivalent nuclear power plant. In 2010, it
2941-428: A kilogram of plutonium-239 can produce an explosion equivalent to 21,000 tons of TNT (88,000 GJ ). It is this energy that makes plutonium-239 useful in nuclear weapons and reactors . The presence of the isotope plutonium-240 in a sample limits its nuclear bomb potential, as Pu has a relatively high spontaneous fission rate (~440 fissions per second per gram; over 1,000 neutrons per second per gram), raising
3114-462: A large range of temperatures (over 2,500 kelvin wide) at which plutonium is liquid, but this range is neither the greatest among all actinides nor among all metals, with neptunium theorized to have the greatest range in both instances. The low melting point as well as the reactivity of the native metal compared to the oxide leads to plutonium oxides being a preferred form for applications such as nuclear fission reactor fuel ( MOX-fuel ). Alpha decay ,
3287-424: A limited pressure range. These allotropes, which are different structural modifications or forms of an element, have very similar internal energies but significantly varying densities and crystal structures . This makes plutonium very sensitive to changes in temperature, pressure, or chemistry, and allows for dramatic volume changes following phase transitions from one allotropic form to another. The densities of
3460-430: A long enough half-life to survive the journey, and hence tiny traces of live interstellar Pu have been found in the deep sea floor. Because Pu also occurs in the decay chain of Pu, it must thus also be present in secular equilibrium , albeit in even tinier quantities. Minute traces of plutonium are usually found in the human body due to the 550 atmospheric and underwater nuclear tests that have been carried out, and to
3633-816: A neutron into a proton to form neptunium-239 (half-life 2.36 days) and another beta decay forms plutonium-239. Egon Bretscher working on the British Tube Alloys project predicted this reaction theoretically in 1940. Plutonium-238 is synthesized by bombarding uranium-238 with deuterons (D or H, the nuclei of heavy hydrogen ) in the following reaction: where a deuteron hitting uranium-238 produces two neutrons and neptunium-238, which decays by emitting negative beta particles to form plutonium-238. Plutonium-238 can also be produced by neutron irradiation of neptunium-237 . Plutonium isotopes undergo radioactive decay, which produces decay heat . Different isotopes produce different amounts of heat per mass. The decay heat
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#17328454185393806-500: A pressure of 1 bar and a given temperature (typically at 298.15K). However, for phosphorus, the reference state is white phosphorus even though it is not the most stable allotrope, and the reference state for carbon is graphite, because the structure of graphite is more stable than that of the other allotropes. In thermochemistry , an element is defined to have an enthalpy of formation of zero in its reference state. Several kinds of descriptive categorizations can be applied broadly to
3979-483: A pressure of one atmosphere, are commonly used in characterizing the various elements. While known for most elements, either or both of these measurements is still undetermined for some of the radioactive elements available in only tiny quantities. Since helium remains a liquid even at absolute zero at atmospheric pressure, it has only a boiling point, and not a melting point, in conventional presentations. The density at selected standard temperature and pressure (STP)
4152-438: A range of applications, such as oil well logging. Substances containing natural radioactivity are known as NORM (naturally occurring radioactive material). After human processing that exposes or concentrates this natural radioactivity (such as mining bringing coal to the surface or burning it to produce concentrated ash), it becomes technologically enhanced naturally occurring radioactive material (TENORM). Much of this waste
4325-504: A reactor. At that point, the fuel has to be replaced in the reactor with fresh fuel, even though there is still a substantial quantity of uranium-235 and plutonium present. In the United States, this used fuel is usually "stored", while in other countries such as Russia, the United Kingdom, France, Japan, and India, the fuel is reprocessed to remove the fission products, and the fuel can then be re-used. The fission products removed from
4498-450: A reduction mechanism similar to FeO 4 , PuO 4 can be stabilized in alkaline solutions and chloroform . Metallic plutonium is produced by reacting plutonium tetrafluoride with barium , calcium or lithium at 1200 °C. Metallic plutonium is attacked by acids , oxygen , and steam but not by alkalis and dissolves easily in concentrated hydrochloric , hydroiodic and perchloric acids . Molten metal must be kept in
4671-405: A result of the processing or consumption of coal, oil, and gas, and some minerals, as discussed below. Waste from the front end of the nuclear fuel cycle is usually alpha-emitting waste from the extraction of uranium. It often contains radium and its decay products. Uranium dioxide (UO 2 ) concentrate from mining is a thousand or so times as radioactive as the granite used in buildings. It
4844-426: A similar way, the alpha emitting actinides and radium are considered very harmful as they tend to have long biological half-lives and their radiation has a high relative biological effectiveness , making it far more damaging to tissues per amount of energy deposited. Because of such differences, the rules determining biological injury differ widely according to the radioisotope, time of exposure, and sometimes also
5017-456: A small group, (the metalloids ), having intermediate properties and often behaving as semiconductors . A more refined classification is often shown in colored presentations of the periodic table. This system restricts the terms "metal" and "nonmetal" to only certain of the more broadly defined metals and nonmetals, adding additional terms for certain sets of the more broadly viewed metals and nonmetals. The version of this classification used in
5190-477: A small number of major nuclear accidents . Most atmospheric and underwater nuclear testing was stopped by the Limited Test Ban Treaty in 1963, which of the nuclear powers was signed and ratified by the United States, United Kingdom and Soviet Union . France would continue atmospheric nuclear testing until 1974 and China would continue atmospheric nuclear testing until 1980. All subsequent nuclear testing
5363-446: A stable state but rather to radioactive decay products within a decay chain before ultimately reaching a stable state. Exposure to radioactive waste may cause health impacts due to ionizing radiation exposure. In humans, a dose of 1 sievert carries a 5.5% risk of developing cancer, and regulatory agencies assume the risk is linearly proportional to dose even for low doses. Ionizing radiation can cause deletions in chromosomes. If
Plutonium - Misplaced Pages Continue
5536-501: A storage area, and the enrichment methods required have high capital costs. Pu-239 decays to U-235 which is suitable for weapons and which has a very long half-life (roughly 10 years). Thus plutonium may decay and leave uranium-235. However, modern reactors are only moderately enriched with U-235 relative to U-238, so the U-238 continues to serve as a denaturation agent for any U-235 produced by plutonium decay. One solution to this problem
5709-474: A whole number. For example, the relative atomic mass of chlorine is 35.453 u, which differs greatly from a whole number as it is an average of about 76% chlorine-35 and 24% chlorine-37. Whenever a relative atomic mass value differs by more than ~1% from a whole number, it is due to this averaging effect, as significant amounts of more than one isotope are naturally present in a sample of that element. Chemists and nuclear scientists have different definitions of
5882-505: Is alpha particle -emitting matter from the decay chains of uranium and thorium. The main source of radiation in the human body is potassium -40 ( K ), typically 17 milligrams in the body at a time and 0.4 milligrams/day intake. Most rocks, especially granite , have a low level of radioactivity due to the potassium-40, thorium and uranium contained. Usually ranging from 1 millisievert (mSv) to 13 mSv annually depending on location, average radiation exposure from natural radioisotopes
6055-486: Is plutonocene . Computational chemistry methods indicate an enhanced covalent character in the plutonium-ligand bonding. Powders of plutonium, its hydrides and certain oxides like Pu 2 O 3 are pyrophoric , meaning they can ignite spontaneously at ambient temperature and are therefore handled in an inert, dry atmosphere of nitrogen or argon. Bulk plutonium ignites only when heated above 400 °C. Pu 2 O 3 spontaneously heats up and transforms into PuO 2 , which
6228-434: Is reactor-grade plutonium . In addition to plutonium-239 , which is highly suitable for building nuclear weapons, it contains large amounts of undesirable contaminants: plutonium-240 , plutonium-241 , and plutonium-238 . These isotopes are extremely difficult to separate, and more cost-effective ways of obtaining fissile material exist (e.g., uranium enrichment or dedicated plutonium production reactors). High-level waste
6401-404: Is 10 (for tin , element 50). The mass number of an element, A , is the number of nucleons (protons and neutrons) in the atomic nucleus. Different isotopes of a given element are distinguished by their mass number, which is written as a superscript on the left hand side of the chemical symbol (e.g., U). The mass number is always an integer and has units of "nucleons". Thus, magnesium-24 (24
6574-482: Is 2.0 mSv per person a year worldwide. This makes up the majority of typical total dosage (with mean annual exposure from other sources amounting to 0.6 mSv from medical tests averaged over the whole populace, 0.4 mSv from cosmic rays , 0.005 mSv from the legacy of past atmospheric nuclear testing, 0.005 mSv occupational exposure, 0.002 mSv from the Chernobyl disaster , and 0.0002 mSv from
6747-606: Is a mixture of C (about 98.9%), C (about 1.1%) and about 1 atom per trillion of C. Most (54 of 94) naturally occurring elements have more than one stable isotope. Except for the isotopes of hydrogen (which differ greatly from each other in relative mass—enough to cause chemical effects), the isotopes of a given element are chemically nearly indistinguishable. All elements have radioactive isotopes (radioisotopes); most of these radioisotopes do not occur naturally. Radioisotopes typically decay into other elements via alpha decay , beta decay , or inverse beta decay ; some isotopes of
6920-406: Is a dimensionless number equal to the atomic mass divided by the atomic mass constant , which equals 1 Da. In general, the mass number of a given nuclide differs in value slightly from its relative atomic mass, since the mass of each proton and neutron is not exactly 1 Da; since the electrons contribute a lesser share to the atomic mass as neutron number exceeds proton number; and because of
7093-496: Is a fertile material that can undergo a neutron capture reaction and two beta minus decays, resulting in the production of fissile U-233 . The SNF of a cycle with thorium will contain U-233. Its radioactive decay will strongly influence the long-term activity curve of the SNF for around a million years. A comparison of the activity associated to U-233 for three different SNF types can be seen in
Plutonium - Misplaced Pages Continue
7266-406: Is a fissile material used in nuclear bombs, plus some material with much higher specific activities, such as Pu-238 or Po. In the past the neutron trigger for an atomic bomb tended to be beryllium and a high activity alpha emitter such as polonium ; an alternative to polonium is Pu-238 . For reasons of national security, details of the design of modern nuclear bombs are normally not released to
7439-424: Is a gamma emitter (increasing external-exposure to workers) and is an alpha emitter which can cause the generation of heat . The plutonium could be separated from the americium by several different processes; these would include pyrochemical processes and aqueous/organic solvent extraction . A truncated PUREX type extraction process would be one possible method of making the separation. Naturally occurring uranium
7612-484: Is a radioactive actinide metal whose isotope , plutonium-239 , is one of the three primary fissile isotopes ( uranium-233 and uranium-235 are the other two); plutonium-241 is also highly fissile. To be considered fissile, an isotope's atomic nucleus must be able to break apart or fission when struck by a slow moving neutron and to release enough additional neutrons to sustain the nuclear chain reaction by splitting further nuclei. Pure plutonium-239 may have
7785-812: Is an ongoing area of scientific study. The lightest elements are hydrogen and helium , both created by Big Bang nucleosynthesis in the first 20 minutes of the universe in a ratio of around 3:1 by mass (or 12:1 by number of atoms), along with tiny traces of the next two elements, lithium and beryllium . Almost all other elements found in nature were made by various natural methods of nucleosynthesis . On Earth, small amounts of new atoms are naturally produced in nucleogenic reactions, or in cosmogenic processes, such as cosmic ray spallation . New atoms are also naturally produced on Earth as radiogenic daughter isotopes of ongoing radioactive decay processes such as alpha decay , beta decay , spontaneous fission , cluster decay , and other rarer modes of decay. Of
7958-460: Is based on a Latin or other traditional word, for example adopting "gold" rather than "aurum" as the name for the 79th element (Au). IUPAC prefers the British spellings " aluminium " and "caesium" over the U.S. spellings "aluminum" and "cesium", and the U.S. "sulfur" over British "sulphur". However, elements that are practical to sell in bulk in many countries often still have locally used national names, and countries whose national language does not use
8131-468: Is broadly classified into 3 categories: low-level waste (LLW), such as paper, rags, tools, clothing, which contain small amounts of mostly short-lived radioactivity; intermediate-level waste (ILW), which contains higher amounts of radioactivity and requires some shielding; and high-level waste (HLW), which is highly radioactive and hot due to decay heat, thus requiring cooling and shielding. In nuclear reprocessing plants, about 96% of spent nuclear fuel
8304-426: Is formed. Also formed is plutonium hydride but an excess of water vapor forms only PuO 2 . Plutonium shows enormous, and reversible, reaction rates with pure hydrogen, forming plutonium hydride . It also reacts readily with oxygen, forming PuO and PuO 2 as well as intermediate oxides; plutonium oxide fills 40% more volume than plutonium metal. The metal reacts with the halogens , giving rise to compounds with
8477-611: Is full of highly radioactive fission products , most of which are relatively short-lived. This is a concern since if the waste is stored, perhaps in deep geological storage, over many years the fission products decay, decreasing the radioactivity of the waste and making the plutonium easier to access. The undesirable contaminant Pu-240 decays faster than the Pu-239, and thus the quality of the bomb material increases with time (although its quantity decreases during that time as well). Thus, some have argued, as time passes, these deep storage areas have
8650-516: Is generated from hospitals and industry, as well as the nuclear fuel cycle . Low-level wastes include paper, rags, tools, clothing, filters, and other materials which contain small amounts of mostly short-lived radioactivity. Materials that originate from any region of an Active Area are commonly designated as LLW as a precautionary measure even if there is only a remote possibility of being contaminated with radioactive materials. Such LLW typically exhibits no higher radioactivity than one would expect from
8823-477: Is harmful to humans and the environment. Different isotopes emit different types and levels of radiation, which last for different periods of time. The radioactivity of all radioactive waste weakens with time. All radionuclides contained in the waste have a half-life —the time it takes for half of the atoms to decay into another nuclide . Eventually, all radioactive waste decays into non-radioactive elements (i.e., stable nuclides ). Since radioactive decay follows
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#17328454185398996-429: Is important to distinguish the processing of uranium to make fuel from the reprocessing of used fuel. Used fuel contains the highly radioactive products of fission (see high-level waste below). Many of these are neutron absorbers, called neutron poisons in this context. These eventually build up to a level where they absorb so many neutrons that the chain reaction stops, even with the control rods completely removed from
9169-456: Is in its α ( alpha ) form . This allotrope is about as hard and brittle as gray cast iron . When plutonium is alloyed with other metals, the high-temperature δ allotrope is stabilized at room temperature, making it soft and ductile. Unlike most metals, it is not a good conductor of heat or electricity . It has a low melting point (640 °C, 1,184 °F) and an unusually high boiling point (3,228 °C, 5,842 °F). This gives
9342-426: Is likely that Hahn and Strassmann were aware that plutonium-239 should be fissile. However, they did not have a strong neutron source. Element 93 was reported by Hahn and Strassmann, as well as Starke, in 1942. Hahn's group did not pursue element 94, likely because they were discouraged by McMillan and Abelson's lack of success in isolating it when they had first found element 93. However, since Hahn's group had access to
9515-420: Is not fissile but can undergo nuclear fission easily with fast neutrons as well as alpha decay. All plutonium isotopes can be "bred" into fissile material with one or more neutron absorptions , whether followed by beta decay or not. This makes non-fissile isotopes of plutonium a fertile material . Twenty-two radioisotopes of plutonium have been characterized, from Pu to Pu. The longest-lived are Pu, with
9688-591: Is not fissile because it contains 99.3% of U-238 and only 0.7% of U-235. Due to historic activities typically related to the radium industry, uranium mining, and military programs, numerous sites contain or are contaminated with radioactivity. In the United States alone, the Department of Energy (DOE) states there are "millions of gallons of radioactive waste" as well as "thousands of tons of spent nuclear fuel and material" and also "huge quantities of contaminated soil and water." Despite copious quantities of waste, in 2007,
9861-436: Is often used in characterizing the elements. Density is often expressed in grams per cubic centimetre (g/cm ). Since several elements are gases at commonly encountered temperatures, their densities are usually stated for their gaseous forms; when liquefied or solidified, the gaseous elements have densities similar to those of the other elements. When an element has allotropes with different densities, one representative allotrope
10034-423: Is produced by nuclear reactors and the reprocessing of nuclear fuel. The exact definition of HLW differs internationally. After a nuclear fuel rod serves one fuel cycle and is removed from the core, it is considered HLW. Spent fuel rods contain mostly uranium with fission products and transuranic elements generated in the reactor core . Spent fuel is highly radioactive and often hot. HLW accounts for over 95% of
10207-403: Is recycled back into uranium-based and mixed-oxide (MOX) fuels . The residual 4% is minor actinides and fission products , the latter of which are a mixture of stable and quickly decaying (most likely already having decayed in the spent fuel pool ) elements, medium lived fission products such as strontium-90 and caesium-137 and finally seven long-lived fission products with half lives in
10380-520: Is refined from yellowcake (U 3 O 8 ), then converted to uranium hexafluoride gas (UF 6 ). As a gas, it undergoes enrichment to increase the U-235 content from 0.7% to about 4.4% (LEU). It is then turned into a hard ceramic oxide (UO 2 ) for assembly as reactor fuel elements. The main by-product of enrichment is depleted uranium (DU), principally the U-238 isotope, with a U-235 content of ~0.3%. It
10553-433: Is responsible for directional covalent bonds in molecules and complexes of plutonium. Plutonium can form alloys and intermediate compounds with most other metals. Exceptions include lithium, sodium , potassium , rubidium and caesium of the alkali metals ; and magnesium , calcium, strontium , and barium of the alkaline earth metals ; and europium and ytterbium of the rare earth metals . Partial exceptions include
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#173284541853910726-411: Is roughly as strong and malleable as aluminium. In fission weapons, the explosive shock waves used to compress a plutonium core will also cause a transition from the usual δ phase plutonium to the denser α form, significantly helping to achieve supercriticality . The ε phase, the highest temperature solid allotrope, exhibits anomalously high atomic self-diffusion compared to other elements. Plutonium
10899-401: Is stable in dry air, but reacts with water vapor when heated. Crucibles used to contain plutonium need to be able to withstand its strongly reducing properties. Refractory metals such as tantalum and tungsten along with the more stable oxides, borides , carbides , nitrides and silicides can tolerate this. Melting in an electric arc furnace can be used to produce small ingots of
11072-432: Is stored, either as UF 6 or as U 3 O 8 . Some is used in applications where its extremely high density makes it valuable such as anti-tank shells , and on at least one occasion even a sailboat keel . It is also used with plutonium for making mixed oxide fuel (MOX) and to dilute, or downblend , highly enriched uranium from weapons stockpiles which is now being redirected to become reactor fuel. The back-end of
11245-580: Is the element with the highest atomic number known to occur in nature. Trace quantities arise in natural uranium deposits when uranium-238 captures neutrons emitted by decay of other uranium-238 atoms. The heavy isotope plutonium-244 has a half-life long enough that extreme trace quantities should have survived primordially (from the Earth's formation) to the present, but so far experiments have not yet been sensitive enough to detect it. Both plutonium-239 and plutonium-241 are fissile , meaning they can sustain
11418-426: Is the mass number) is an atom with 24 nucleons (12 protons and 12 neutrons). Whereas the mass number simply counts the total number of neutrons and protons and is thus an integer, the atomic mass of a particular isotope (or "nuclide") of the element is the mass of a single atom of that isotope, and is typically expressed in daltons (symbol: Da), or universal atomic mass units (symbol: u). Its relative atomic mass
11591-426: Is to recycle the plutonium and use it as a fuel e.g. in fast reactors . In pyrometallurgical fast reactors , the separated plutonium and uranium are contaminated by actinides and cannot be used for nuclear weapons. Waste from nuclear weapons decommissioning is unlikely to contain much beta or gamma activity other than tritium and americium . It is more likely to contain alpha-emitting actinides such as Pu-239 which
11764-532: Is typically selected in summary presentations, while densities for each allotrope can be stated where more detail is provided. For example, the three familiar allotropes of carbon ( amorphous carbon , graphite , and diamond ) have densities of 1.8–2.1, 2.267, and 3.515 g/cm , respectively. The elements studied to date as solid samples have eight kinds of crystal structures : cubic , body-centered cubic , face-centered cubic, hexagonal , monoclinic , orthorhombic , rhombohedral , and tetragonal . For some of
11937-540: Is unusual for metals. This trend continues down to 100 K , below which resistivity rapidly decreases for fresh samples. Resistivity then begins to increase with time at around 20 K due to radiation damage, with the rate dictated by the isotopic composition of the sample. Because of self-irradiation, a sample of plutonium fatigues throughout its crystal structure, meaning the ordered arrangement of its atoms becomes disrupted by radiation with time. Self-irradiation can also lead to annealing which counteracts some of
12110-417: Is used in two different but closely related meanings: it can mean a chemical substance consisting of a single kind of atoms, or it can mean that kind of atoms as a component of various chemical substances. For example, molecules of water (H 2 O) contain atoms of hydrogen (H) and oxygen (O), so water can be said as a compound consisting of the elements hydrogen (H) and oxygen (O) even though it does not contain
12283-427: Is usually listed as watt/kilogram, or milliwatt/gram. In larger pieces of plutonium (e.g. a weapon pit) and inadequate heat removal the resulting self-heating may be significant. At room temperature, pure plutonium is silvery in color but gains a tarnish when oxidized. The element displays four common ionic oxidation states in aqueous solution and one rare one: The color shown by plutonium solutions depends on both
12456-429: Is very strong; fullerenes , which have nearly spherical shapes; and carbon nanotubes , which are tubes with a hexagonal structure (even these may differ from each other in electrical properties). The ability of an element to exist in one of many structural forms is known as 'allotropy'. The reference state of an element is defined by convention, usually as the thermodynamically most stable allotrope and physical state at
12629-585: Is widely used. For example, the French chemical terminology distinguishes élément chimique (kind of atoms) and corps simple (chemical substance consisting of a single kind of atoms); the Russian chemical terminology distinguishes химический элемент and простое вещество . Almost all baryonic matter in the universe is composed of elements (among rare exceptions are neutron stars ). When different elements undergo chemical reactions, atoms are rearranged into new compounds held together by chemical bonds . Only
12802-585: The Cigar Lake Mine uranium deposit ranges from 2.4 × 10 to 44 × 10 . These trace amounts of Pu originate in the following fashion: on rare occasions, U undergoes spontaneous fission, and in the process, the nucleus emits one or two free neutrons with some kinetic energy. When one of these neutrons strikes the nucleus of another U atom, it is absorbed by the atom, which becomes U. With a relatively short half-life, U decays to Np, which decays into Pu. Finally, exceedingly small amounts of plutonium-238, attributed to
12975-465: The Cold War is a nuclear-proliferation and environmental concern. Other sources of plutonium in the environment are fallout from many above-ground nuclear tests, which are now banned . Plutonium, like most metals, has a bright silvery appearance at first, much like nickel , but it oxidizes very quickly to a dull gray, though yellow and olive green are also reported. At room temperature plutonium
13148-480: The International Union of Pure and Applied Chemistry (IUPAC) had recognized a total of 118 elements. The first 94 occur naturally on Earth , and the remaining 24 are synthetic elements produced in nuclear reactions. Save for unstable radioactive elements (radioelements) which decay quickly, nearly all elements are available industrially in varying amounts. The discovery and synthesis of further new elements
13321-625: The Latin alphabet are likely to use the IUPAC element names. According to IUPAC, element names are not proper nouns; therefore, the full name of an element is not capitalized in English, even if derived from a proper noun , as in californium and einsteinium . Isotope names are also uncapitalized if written out, e.g., carbon-12 or uranium-235 . Chemical element symbols (such as Cf for californium and Es for einsteinium), are always capitalized (see below). In
13494-570: The Manhattan Project , for developing an atomic bomb. The three primary research and production sites of the project were the plutonium production facility at what is now the Hanford Site ; the uranium enrichment facilities at Oak Ridge, Tennessee ; and the weapons research and design lab, now known as Los Alamos National Laboratory , LANL. The first production reactor that made Pu was the X-10 Graphite Reactor . It went online in 1943 and
13667-598: The New World . It was used extensively as such by American publications before the international standardization (in 1950). Before chemistry became a science , alchemists designed arcane symbols for both metals and common compounds. These were however used as abbreviations in diagrams or procedures; there was no concept of atoms combining to form molecules . With his advances in the atomic theory of matter, John Dalton devised his own simpler symbols, based on circles, to depict molecules. Nuclear waste Radioactive waste
13840-469: The PUREX -process disposes of them as waste together with the fission products. The waste is subsequently converted into a glass-like ceramic for storage in a deep geological repository . The time radioactive waste must be stored depends on the type of waste and radioactive isotopes it contains. Short-term approaches to radioactive waste storage have been segregation and storage on the surface or near-surface of
14013-423: The kinetic isotope effect is significant). Thus, all carbon isotopes have nearly identical chemical properties because they all have six electrons, even though they may have 6 to 8 neutrons. That is why atomic number, rather than mass number or atomic weight , is considered the identifying characteristic of an element. The symbol for atomic number is Z . Isotopes are atoms of the same element (that is, with
14186-405: The nuclear binding energy and electron binding energy. For example, the atomic mass of chlorine-35 to five significant digits is 34.969 Da and that of chlorine-37 is 36.966 Da. However, the relative atomic mass of each isotope is quite close to its mass number (always within 1%). The only isotope whose atomic mass is exactly a natural number is C, which has a mass of 12 Da; because
14359-422: The parent isotope of the neptunium series , decaying to americium-241 via beta emission. Plutonium-238 and 239 are the most widely synthesized isotopes. Pu is synthesized via the following reaction using uranium (U) and neutrons (n) via beta decay (β) with neptunium (Np) as an intermediate: Neutrons from the fission of uranium-235 are captured by uranium-238 nuclei to form uranium-239; a beta decay converts
14532-464: The 6d and 5f subshells is very low. The size of the 5f shell is just enough to allow the electrons to form bonds within the lattice, on the very boundary between localized and bonding behavior. The proximity of energy levels leads to multiple low-energy electron configurations with near equal energy levels. This leads to competing 5f7s and 5f6d7s configurations, which causes the complexity of its chemical behavior. The highly directional nature of 5f orbitals
14705-638: The 94 naturally occurring elements, those with atomic numbers 1 through 82 each have at least one stable isotope (except for technetium , element 43 and promethium , element 61, which have no stable isotopes). Isotopes considered stable are those for which no radioactive decay has yet been observed. Elements with atomic numbers 83 through 94 are unstable to the point that radioactive decay of all isotopes can be detected. Some of these elements, notably bismuth (atomic number 83), thorium (atomic number 90), and uranium (atomic number 92), have one or more isotopes with half-lives long enough to survive as remnants of
14878-712: The DOE has successfully completed cleanup, or at least closure, of several sites. Radioactive medical waste tends to contain beta particle and gamma ray emitters. It can be divided into two main classes. In diagnostic nuclear medicine a number of short-lived gamma emitters such as technetium-99m are used. Many of these can be disposed of by leaving it to decay for a short time before disposal as normal waste. Other isotopes used in medicine, with half-lives in parentheses, include: Industrial source waste can contain alpha, beta , neutron or gamma emitters. Gamma emitters are used in radiography while neutron emitting sources are used in
15051-569: The DOE stated a goal of cleaning all presently contaminated sites successfully by 2025. The Fernald , Ohio site for example had "31 million pounds of uranium product", "2.5 billion pounds of waste", "2.75 million cubic yards of contaminated soil and debris", and a "223 acre portion of the underlying Great Miami Aquifer had uranium levels above drinking standards." The United States has at least 108 sites designated as areas that are contaminated and unusable, sometimes many thousands of acres. The DOE wishes to clean or mitigate many or all by 2025, using
15224-487: The French, Italians, Greeks, Portuguese and Poles prefer "azote/azot/azoto" (from roots meaning "no life") for "nitrogen". For purposes of international communication and trade, the official names of the chemical elements both ancient and more recently recognized are decided by the International Union of Pure and Applied Chemistry (IUPAC), which has decided on a sort of international English language, drawing on traditional English names even when an element's chemical symbol
15397-542: The MOX fuel results in a lower activity in region 3 of the figure at the bottom right, whereas for RGPu and WGPu the curve is maintained higher due to the presence of U-233 that has not fully decayed. Nuclear reprocessing can remove the actinides from the spent fuel so they can be used or destroyed (see Long-lived fission product § Actinides ). Since uranium and plutonium are nuclear weapons materials, there are proliferation concerns. Ordinarily (in spent nuclear fuel), plutonium
15570-408: The Pu-239; due to the relatively long half-life of these Pu isotopes, these wastes from radioactive decay of bomb core material would be very small, and in any case, far less dangerous (even in terms of simple radioactivity) than the Pu-239 itself. The beta decay of Pu-241 forms Am-241 ; the in-growth of americium is likely to be a greater problem than the decay of Pu-239 and Pu-240 as the americium
15743-1087: The Radioactive Waste Safety Standards (RADWASS), also plays a significant role. The proportion of various types of waste generated in the UK: Uranium tailings are waste by-product materials left over from the rough processing of uranium-bearing ore . They are not significantly radioactive. Mill tailings are sometimes referred to as 11(e)2 wastes , from the section of the US Atomic Energy Act of 1946 that defines them. Uranium mill tailings typically also contain chemically hazardous heavy metal such as lead and arsenic . Vast mounds of uranium mill tailings are left at many old mining sites, especially in Colorado , New Mexico , and Utah . Although mill tailings are not very radioactive, they have long half-lives. Mill tailings often contain radium, thorium and trace amounts of uranium. Low-level waste (LLW)
15916-478: The X-10 reactor. Information from CP-1 was also useful to Met Lab scientists designing the water-cooled plutonium production reactors for Hanford. Construction at the site began in mid-1943. In November 1943 some plutonium trifluoride was reduced to create the first sample of plutonium metal: a few micrograms of metallic beads. Enough plutonium was produced to make it the first synthetically made element to be visible with
16089-483: The advantage of avoiding dealing directly with the highly reactive plutonium metal. Trace amounts of plutonium-238, plutonium-239, plutonium-240, and plutonium-244 can be found in nature. Small traces of plutonium-239, a few parts per trillion , and its decay products are naturally found in some concentrated ores of uranium, such as the natural nuclear fission reactor in Oklo , Gabon . The ratio of plutonium-239 to uranium at
16262-639: The ash content of 'dirty' coals. The more active ash minerals become concentrated in the fly ash precisely because they do not burn well. The radioactivity of fly ash is about the same as black shale and is less than phosphate rocks, but is more of a concern because a small amount of the fly ash ends up in the atmosphere where it can be inhaled. According to U.S. National Council on Radiation Protection and Measurements (NCRP) reports, population exposure from 1000-MWe power plants amounts to 490 person-rem/year for coal power plants, 100 times as great as nuclear power plants (4.8 person-rem/year). The exposure from
16435-487: The atomic masses of the elements (their atomic weights or atomic masses) do not always increase monotonically with their atomic numbers. The naming of various substances now known as elements precedes the atomic theory of matter, as names were given locally by various cultures to various minerals, metals, compounds, alloys, mixtures, and other materials, though at the time it was not known which chemicals were elements and which compounds. As they were identified as elements,
16608-448: The back end of the fuel cycle is especially relevant when designing a complete waste management plan for SNF. When looking at long-term radioactive decay, the actinides in the SNF have a significant influence due to their characteristically long half-lives. Depending on what a nuclear reactor is fueled with, the actinide composition in the SNF will be different. An example of this effect is the use of nuclear fuels with thorium . Th-232
16781-510: The background neutron levels and thus increasing the risk of predetonation . Plutonium is identified as either weapons-grade , fuel-grade, or reactor-grade based on the percentage of Pu that it contains. Weapons-grade plutonium contains less than 7% Pu. Fuel-grade plutonium contains 7%–19%, and power reactor-grade contains 19% or more Pu. Supergrade plutonium , with less than 4% of Pu, is used in U.S. Navy weapons stored near ship and submarine crews, due to its lower radioactivity. Plutonium-238
16954-413: The chemical substances (di)hydrogen (H 2 ) and (di)oxygen (O 2 ), as H 2 O molecules are different from H 2 and O 2 molecules. For the meaning "chemical substance consisting of a single kind of atoms", the terms "elementary substance" and "simple substance" have been suggested, but they have not gained much acceptance in English chemical literature, whereas in some other languages their equivalent
17127-464: The chemistries of thorium and plutonium are rather similar (both are predominantly tetravalent) and hence an excess of thorium would not be strong evidence that some of it was formed as a plutonium daughter. Pu has the longest half-life of all transuranic nuclides and is produced only in the r-process in supernovae and colliding neutron stars ; when nuclei are ejected from these events at high speed to reach Earth, Pu alone among transuranic nuclides has
17300-452: The complete nuclear fuel cycle from mining to waste disposal is 136 person-rem/year; the corresponding value for coal use from mining to waste disposal is "probably unknown". Residues from the oil and gas industry often contain radium and its decay products. The sulfate scale from an oil well can be radium rich, while the water, oil, and gas from a well often contain radon . The radon decays to form solid radioisotopes which form coatings on
17473-502: The complicated phase diagram are not entirely understood. The α form has a low-symmetry monoclinic structure, hence its brittleness, strength, compressibility, and poor thermal conductivity. Plutonium in the δ ( delta ) form normally exists in the 310 °C to 452 °C range but is stable at room temperature when alloyed with a small percentage of gallium , aluminium , or cerium , enhancing workability and allowing it to be welded . The δ form has more typical metallic character, and
17646-408: The dalton is defined as 1/12 of the mass of a free neutral carbon-12 atom in the ground state. The standard atomic weight (commonly called "atomic weight") of an element is the average of the atomic masses of all the chemical element's isotopes as found in a particular environment, weighted by isotopic abundance, relative to the atomic mass unit. This number may be a fraction that is not close to
17819-425: The decay mode and the pharmacokinetics of an element (how the body processes it and how quickly), the threat due to exposure to a given activity of a radioisotope will differ. For instance, iodine-131 is a short-lived beta and gamma emitter, but because it concentrates in the thyroid gland, it is more able to cause injury than caesium -137 which, being water soluble , is rapidly excreted through urine. In
17992-423: The different allotropes vary from 16.00 g/cm to 19.86 g/cm. The presence of these many allotropes makes machining plutonium very difficult, as it changes state very readily. For example, the α form exists at room temperature in unalloyed plutonium. It has machining characteristics similar to cast iron but changes to the plastic and malleable β ( beta ) form at slightly higher temperatures. The reasons for
18165-416: The discovery and use of elements began with early human societies that discovered native minerals like carbon , sulfur , copper and gold (though the modern concept of an element was not yet understood). Attempts to classify materials such as these resulted in the concepts of classical elements , alchemy , and similar theories throughout history. Much of the modern understanding of elements developed from
18338-604: The earth. Burial in a deep geological repository is a favored solution for long-term storage of high-level waste, while re-use and transmutation are favored solutions for reducing the HLW inventory. Boundaries to recycling of spent nuclear fuel are regulatory and economic as well as the issue of radioactive contamination if chemical separation processes cannot achieve a very high purity. Furthermore, elements may be present in both useful and troublesome isotopes, which would require costly and energy intensive isotope separation for their use –
18511-406: The elements are available by name, atomic number, density, melting point, boiling point and chemical symbol , as well as ionization energy . The nuclides of stable and radioactive elements are also available as a list of nuclides , sorted by length of half-life for those that are unstable. One of the most convenient, and certainly the most traditional presentation of the elements, is in the form of
18684-470: The elements are often summarized using the periodic table, which powerfully and elegantly organizes the elements by increasing atomic number into rows ( "periods" ) in which the columns ( "groups" ) share recurring ("periodic") physical and chemical properties. The table contains 118 confirmed elements as of 2021. Although earlier precursors to this presentation exist, its invention is generally credited to Russian chemist Dmitri Mendeleev in 1869, who intended
18857-480: The elements can be uniquely sequenced by atomic number, conventionally from lowest to highest (as in a periodic table), sets of elements are sometimes specified by such notation as "through", "beyond", or "from ... through", as in "through iron", "beyond uranium", or "from lanthanum through lutetium". The terms "light" and "heavy" are sometimes also used informally to indicate relative atomic numbers (not densities), as in "lighter than carbon" or "heavier than lead", though
19030-413: The elements without any stable isotopes are technetium (atomic number 43), promethium (atomic number 61), and all observed elements with atomic number greater than 82. Of the 80 elements with at least one stable isotope, 26 have only one stable isotope. The mean number of stable isotopes for the 80 stable elements is 3.1 stable isotopes per element. The largest number of stable isotopes for a single element
19203-474: The elements, including consideration of their general physical and chemical properties, their states of matter under familiar conditions, their melting and boiling points, their densities, their crystal structures as solids, and their origins. Several terms are commonly used to characterize the general physical and chemical properties of the chemical elements. A first distinction is between metals , which readily conduct electricity , nonmetals , which do not, and
19376-492: The existing names for anciently known elements (e.g., gold, mercury, iron) were kept in most countries. National differences emerged over the element names either for convenience, linguistic niceties, or nationalism. For example, German speakers use "Wasserstoff" (water substance) for "hydrogen", "Sauerstoff" (acid substance) for "oxygen" and "Stickstoff" (smothering substance) for "nitrogen"; English and some other languages use "sodium" for "natrium", and "potassium" for "kalium"; and
19549-630: The explosive stellar nucleosynthesis that produced the heavy metals before the formation of our Solar System . At over 1.9 × 10 years, over a billion times longer than the estimated age of the universe, bismuth-209 has the longest known alpha decay half-life of any isotope, and is almost always considered on par with the 80 stable elements. The heaviest elements (those beyond plutonium, element 94) undergo radioactive decay with half-lives so short that they are not found in nature and must be synthesized . There are now 118 known elements. In this context, "known" means observed well enough, even from just
19722-593: The extremely rare double beta decay of uranium-238, have been found in natural uranium samples. Due to its relatively long half-life of about 80 million years, it was suggested that plutonium-244 occurs naturally as a primordial nuclide , but early reports of its detection could not be confirmed. Based on its likely initial abundance in the Solar System, present experiments as of 2022 are likely about an order of magnitude away from detecting live primordial Pu. However, its long half-life ensured its circulation across
19895-437: The fatigue effects as temperature increases above 100 K. Unlike most materials, plutonium increases in density when it melts, by 2.5%, but the liquid metal exhibits a linear decrease in density with temperature. Near the melting point, the liquid plutonium has very high viscosity and surface tension compared to other metals. Plutonium normally has six allotropes and forms a seventh (zeta, ζ) at high temperature within
20068-411: The figure on the top right. The burnt fuels are thorium with reactor-grade plutonium (RGPu), thorium with weapons-grade plutonium (WGPu), and Mixed oxide fuel (MOX, no thorium). For RGPu and WGPu, the initial amount of U-233 and its decay for around a million years can be seen. This has an effect on the total activity curve of the three fuel types. The initial absence of U-233 and its daughter products in
20241-581: The first atomic bombs. The Fat Man bombs used in the Trinity nuclear test in July 1945, and in the bombing of Nagasaki in August 1945, had plutonium cores . Human radiation experiments studying plutonium were conducted without informed consent , and several criticality accidents , some lethal, occurred after the war. Disposal of plutonium waste from nuclear power plants and dismantled nuclear weapons built during
20414-499: The first self-sustaining chain reaction in a graphite and uranium pile known as CP-1 . Using theoretical information garnered from the operation of CP-1, DuPont constructed an air-cooled experimental production reactor, known as X-10 , and a pilot chemical separation facility at Oak Ridge. The separation facility, using methods developed by Glenn T. Seaborg and a team of researchers at the Met Lab, removed plutonium from uranium irradiated in
20587-554: The first transuranic element neptunium after the planet Neptune , and suggested that element 94, being the next element in the series, be named for what was then considered the next planet, Pluto . Nicholas Kemmer of the Cambridge team independently proposed the same name, based on the same reasoning as the Berkeley team. Seaborg originally considered the name "plutium", but later thought that it did not sound as good as "plutonium". He chose
20760-529: The formation of Earth, they are certain to have completely decayed, and if present in novae, are in quantities too small to have been noted. Technetium was the first purportedly non-naturally occurring element synthesized, in 1937, though trace amounts of technetium have since been found in nature (and also the element may have been discovered naturally in 1925). This pattern of artificial production and later natural discovery has been repeated with several other radioactive naturally occurring rare elements. List of
20933-567: The fuel are a concentrated form of high-level waste as are the chemicals used in the process. While most countries reprocess the fuel carrying out single plutonium cycles, India is planning multiple plutonium recycling schemes and Russia pursues closed cycle. The use of different fuels in nuclear reactors results in different spent nuclear fuel (SNF) composition, with varying activity curves. The most abundant material being U-238 with other uranium isotopes, other actinides, fission products and activation products. Long-lived radioactive waste from
21106-405: The general formula PuX 3 where X can be F , Cl , Br or I and PuF 4 is also seen. The following oxyhalides are observed: PuOCl, PuOBr and PuOI. It will react with carbon to form PuC , nitrogen to form PuN and silicon to form PuSi 2 . The organometallic chemistry of plutonium complexes is typical for organoactinide species; a characteristic example of an organoplutonium compound
21279-416: The half-life rule, the rate of decay is inversely proportional to the duration of decay. In other words, the radiation from a long-lived isotope like iodine-129 will be much less intense than that of a short-lived isotope like iodine-131 . The two tables show some of the major radioisotopes, their half-lives, and their radiation yield as a proportion of the yield of fission of uranium-235. The energy and
21452-431: The half-lives predicted for the observationally stable lead isotopes range from 10 to 10 years. Elements with atomic numbers 43, 61, and 83 through 94 are unstable enough that their radioactive decay can be detected. Three of these elements, bismuth (element 83), thorium (90), and uranium (92) have one or more isotopes with half-lives long enough to survive as remnants of the explosive stellar nucleosynthesis that produced
21625-399: The heaviest elements also undergo spontaneous fission . Isotopes that are not radioactive, are termed "stable" isotopes. All known stable isotopes occur naturally (see primordial nuclide ). The many radioisotopes that are not found in nature have been characterized after being artificially produced. Certain elements have no stable isotopes and are composed only of radioisotopes: specifically
21798-488: The heavy elements before the formation of the Solar System. For example, at over 1.9 × 10 years, over a billion times longer than the estimated age of the universe, bismuth-209 has the longest known alpha decay half-life of any isotope. The last 24 elements (those beyond plutonium, element 94) undergo radioactive decay with short half-lives and cannot be produced as daughters of longer-lived elements, and thus are not known to occur in nature at all. 1 The properties of
21971-411: The hundreds of thousands to millions of years. The minor actinides meanwhile are heavy elements other than uranium and plutonium which are created by neutron capture . Their half lives range from years to millions of years and as alpha emitters they are particularly radiotoxic. While there are proposed – and to a much lesser extent current – uses of all those elements, commercial scale reprocessing using
22144-412: The inside of pipework. In an oil processing plant, the area of the plant where propane is processed is often one of the more contaminated areas of the plant as radon has a similar boiling point to propane. Radioactive elements are an industrial problem in some oil wells where workers operating in direct contact with the crude oil and brine can be exposed to doses having negative health effects. Due to
22317-525: The letters "Pu" as a joke, in reference to the interjection "P U" to indicate an especially disgusting smell, which passed without notice into the periodic table. Alternative names considered by Seaborg and others were "ultimium" or "extremium" because of the erroneous belief that they had found the last possible element on the periodic table . Hahn and Strassmann, and independently Kurt Starke , were at this point also working on transuranic elements in Berlin. It
22490-446: The metal without the need for a crucible. Cerium is used as a chemical simulant of plutonium for development of containment, extraction, and other technologies. Plutonium is an element in which the 5f electrons are the transition border between delocalized and localized; it is therefore considered one of the most complex elements. The anomalous behavior of plutonium is caused by its electronic structure. The energy difference between
22663-399: The most stable isotope, Pu, are spontaneous fission and alpha emission , mostly forming uranium (92 protons ) and neptunium (93 protons) isotopes as decay products (neglecting the wide range of daughter nuclei created by fission processes). The main decay mode for isotopes heavier than Pu, along with Pu and Pu, is beta emission , forming americium isotopes (95 protons). Plutonium-241 is
22836-565: The nature of the chemical compound which contains the radioisotope. No fission products have a half-life in the range of 100 a–210 ka ... ... nor beyond 15.7 Ma Radioactive waste comes from a number of sources. In countries with nuclear power plants, nuclear armament, or nuclear fuel treatment plants, the majority of waste originates from the nuclear fuel cycle and nuclear weapons reprocessing. Other sources include medical and industrial wastes, as well as naturally occurring radioactive materials (NORM) that can be concentrated as
23009-886: The north of Scotland is the Dounreay site which is prepared to withstand a 4m tsunami. [1] Some high-activity LLW requires shielding during handling and transport but most LLW is suitable for shallow land burial. To reduce its volume, it is often compacted or incinerated before disposal. Low-level waste is divided into four classes: class A , class B , class C , and Greater Than Class C ( GTCC ). Intermediate-level waste (ILW) contains higher amounts of radioactivity compared to low-level waste. It generally requires shielding, but not cooling. Intermediate-level wastes includes resins , chemical sludge and metal nuclear fuel cladding, as well as contaminated materials from reactor decommissioning. It may be solidified in concrete or bitumen or mixed with silica sand and vitrified for disposal. As
23182-526: The nuclear fuel cycle). TENORM is not regulated as restrictively as nuclear reactor waste, though there are no significant differences in the radiological risks of these materials. Coal contains a small amount of radioactive uranium, barium, thorium, and potassium, but, in the case of pure coal, this is significantly less than the average concentration of those elements in the Earth's crust . The surrounding strata, if shale or mudstone, often contain slightly more than average and this may also be reflected in
23355-491: The nuclear fuel cycle, mostly spent fuel rods , contains fission products that emit beta and gamma radiation, and actinides that emit alpha particles , such as uranium-234 (half-life 245 thousand years), neptunium-237 (2.144 million years), plutonium-238 (87.7 years) and americium-241 (432 years), and even sometimes some neutron emitters such as californium (half-life of 898 years for californium-251). These isotopes are formed in nuclear reactors . It
23528-440: The open literature. Some designs might contain a radioisotope thermoelectric generator using Pu-238 to provide a long-lasting source of electrical power for the electronics in the device. It is likely that the fissile material of an old nuclear bomb, which is due for refitting, will contain decay products of the plutonium isotopes used in it. These are likely to include U-236 from Pu-240 impurities plus some U-235 from decay of
23701-450: The oxidation state and the nature of the acid anion . It is the acid anion that influences the degree of complexing —how atoms connect to a central atom—of the plutonium species. Additionally, the formal +2 oxidation state of plutonium is known in the complex [K(2.2.2-cryptand)] [PuCp″ 3 ], Cp″ = C 5 H 3 (SiMe 3 ) 2 . A +8 oxidation state is possible as well in the volatile tetroxide PuO 4 . Though it readily decomposes via
23874-418: The periodic table, which groups together elements with similar chemical properties (and usually also similar electronic structures). The atomic number of an element is equal to the number of protons in each atom, and defines the element. For example, all carbon atoms contain 6 protons in their atomic nucleus ; so the atomic number of carbon is 6. Carbon atoms may have different numbers of neutrons; atoms of
24047-426: The periodic tables presented here includes: actinides , alkali metals , alkaline earth metals , halogens , lanthanides , transition metals , post-transition metals , metalloids , reactive nonmetals , and noble gases . In this system, the alkali metals, alkaline earth metals, and transition metals, as well as the lanthanides and the actinides, are special groups of the metals viewed in a broader sense. Similarly,
24220-402: The potential to become "plutonium mines", from which material for nuclear weapons can be acquired with relatively little difficulty. Critics of the latter idea have pointed out the difficulty of recovering useful material from sealed deep storage areas makes other methods preferable. Specifically, high radioactivity and heat (80 °C in surrounding rock) greatly increase the difficulty of mining
24393-412: The pure element to exist in multiple chemical structures ( spatial arrangements of atoms ), known as allotropes , which differ in their properties. For example, carbon can be found as diamond , which has a tetrahedral structure around each carbon atom; graphite , which has layers of carbon atoms with a hexagonal structure stacked on top of each other; graphene , which is a single layer of graphite that
24566-772: The reactive nonmetals and the noble gases are nonmetals viewed in the broader sense. In some presentations, the halogens are not distinguished, with astatine identified as a metalloid and the others identified as nonmetals. Another commonly used basic distinction among the elements is their state of matter (phase), whether solid , liquid , or gas , at standard temperature and pressure (STP). Most elements are solids at STP, while several are gases. Only bromine and mercury are liquid at 0 degrees Celsius (32 degrees Fahrenheit) and 1 atmosphere pressure; caesium and gallium are solid at that temperature, but melt at 28.4°C (83.2°F) and 29.8°C (85.6°F), respectively. Melting and boiling points , typically expressed in degrees Celsius at
24739-477: The recently developed method of geomelting , however the task can be difficult and it acknowledges that some may never be completely remediated. In just one of these 108 larger designations, Oak Ridge National Laboratory (ORNL), there were for example at least "167 known contaminant release sites" in one of the three subdivisions of the 37,000-acre (150 km ) site. Some of the U.S. sites were smaller in nature, however, cleanup issues were simpler to address, and
24912-472: The refractory metals chromium , molybdenum , niobium , tantalum, and tungsten, which are soluble in liquid plutonium, but insoluble or only slightly soluble in solid plutonium. Gallium, aluminium, americium, scandium and cerium can stabilize δ-phase plutonium for room temperature. Silicon , indium , zinc and zirconium allow formation of metastable δ state when rapidly cooled. High amounts of hafnium , holmium and thallium also allows some retention of
25085-588: The relatively high concentration of these elements in the brine, its disposal is also a technological challenge. Since the 1980s, in the United States, the brine is however exempt from the dangerous waste regulations and can be disposed of regardless of radioactive or toxic substances content. Due to natural occurrence of radioactive elements such as thorium and radium in rare-earth ore , mining operations also result in production of waste and mineral deposits that are slightly radioactive. Classification of radioactive waste varies by country. The IAEA, which publishes
25258-408: The release of a high-energy helium nucleus, is the most common form of radioactive decay for plutonium. A 5 kg mass of Pu contains about 12.5 × 10 atoms. With a half-life of 24,100 years, about 11.5 × 10 of its atoms decay each second by emitting a 5.157 MeV alpha particle. This amounts to 9.68 watts of power. Heat produced by the deceleration of these alpha particles makes it warm to
25431-919: The remaining 11 elements have half lives too short for them to have been present at the beginning of the Solar System, and are therefore considered transient elements. Of these 11 transient elements, five ( polonium , radon , radium , actinium , and protactinium ) are relatively common decay products of thorium and uranium . The remaining six transient elements (technetium, promethium, astatine, francium , neptunium , and plutonium ) occur only rarely, as products of rare decay modes or nuclear reaction processes involving uranium or other heavy elements. Elements with atomic numbers 1 through 82, except 43 (technetium) and 61 (promethium), each have at least one isotope for which no radioactive decay has been observed. Observationally stable isotopes of some elements (such as tungsten and lead ), however, are predicted to be slightly radioactive with very long half-lives: for example,
25604-624: The same element can have different numbers of neutrons in their nuclei, known as isotopes of the element. Two or more atoms can combine to form molecules . Some elements are formed from molecules of identical atoms , e. g. atoms of hydrogen (H) form diatomic molecules (H 2 ). Chemical compounds are substances made of atoms of different elements; they can have molecular or non-molecular structure. Mixtures are materials containing different chemical substances; that means (in case of molecular substances) that they contain different types of molecules. Atoms of one element can be transformed into atoms of
25777-495: The same element having different numbers of neutrons are known as isotopes of the element. The number of protons in the nucleus also determines its electric charge , which in turn determines the number of electrons of the atom in its non-ionized state. The electrons are placed into atomic orbitals that determine the atom's chemical properties . The number of neutrons in a nucleus usually has very little effect on an element's chemical properties; except for hydrogen (for which
25950-452: The same material disposed of in a non-active area, such as a normal office block. Example LLW includes wiping rags, mops, medical tubes, laboratory animal carcasses, and more. LLW makes up 94% of all radioactive waste volume in the UK. Most of it is disposed of in Cumbria , first in landfill style trenches, and now using grouted metal containers that are stacked in concrete vaults. A new site in
26123-404: The same number of protons in their nucleus), but having different numbers of neutrons . Thus, for example, there are three main isotopes of carbon. All carbon atoms have 6 protons, but they can have either 6, 7, or 8 neutrons. Since the mass numbers of these are 12, 13 and 14 respectively, said three isotopes are known as carbon-12 , carbon-13 , and carbon-14 ( C, C, and C). Natural carbon
26296-493: The sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric . It is radioactive and can accumulate in bones , which makes the handling of plutonium dangerous. Plutonium was first synthesized and isolated in late 1940 and early 1941, by deuteron bombardment of uranium-238 in the 1.5-metre (60 in) cyclotron at the University of California, Berkeley . First, neptunium-238 ( half-life 2.1 days)
26469-457: The second half of the 20th century, physics laboratories became able to produce elements with half-lives too short for an appreciable amount of them to exist at any time. These are also named by IUPAC, which generally adopts the name chosen by the discoverer. This practice can lead to the controversial question of which research group actually discovered an element, a question that delayed the naming of elements with atomic number of 104 and higher for
26642-411: The solar system before its extinction , and indeed, evidence of the spontaneous fission of extinct Pu has been found in meteorites. The former presence of Pu in the early Solar System has been confirmed, since it manifests itself today as an excess of its daughters, either Th (from the alpha decay pathway) or xenon isotopes (from its spontaneous fission ). The latter are generally more useful, because
26815-414: The stronger cyclotron at Paris at this point, they would likely have been able to detect plutonium had they tried, albeit in tiny quantities (a few becquerels ). The chemistry of plutonium was found to resemble uranium after a few months of initial study. Early research was continued at the secret Metallurgical Laboratory of the University of Chicago . On August 20, 1942, a trace quantity of this element
26988-496: The synthetically produced transuranic elements, available samples have been too small to determine crystal structures. Chemical elements may also be categorized by their origin on Earth, with the first 94 considered naturally occurring, while those with atomic numbers beyond 94 have only been produced artificially via human-made nuclear reactions. Of the 94 naturally occurring elements, 83 are considered primordial and either stable or weakly radioactive. The longest-lived isotopes of
27161-955: The table to illustrate recurring trends in the properties of the elements. The layout of the table has been refined and extended over time as new elements have been discovered and new theoretical models have been developed to explain chemical behavior. Use of the periodic table is now ubiquitous in chemistry, providing an extremely useful framework to classify, systematize and compare all the many different forms of chemical behavior. The table has also found wide application in physics , geology , biology , materials science , engineering , agriculture , medicine , nutrition , environmental health , and astronomy . Its principles are especially important in chemical engineering . The various chemical elements are formally identified by their unique atomic numbers, their accepted names, and their chemical symbols . The known elements have atomic numbers from 1 to 118, conventionally presented as Arabic numerals . Since
27334-637: The total radioactivity produced in the process of nuclear electricity generation but it contributes to less than 1% of volume of all radioactive waste produced in the UK. Overall, the 60-year-long nuclear program in the UK up until 2019 produced 2150 m of HLW. The radioactive waste from spent fuel rods consists primarily of cesium-137 and strontium-90, but it may also include plutonium, which can be considered transuranic waste. The half-lives of these radioactive elements can differ quite extremely. Some elements, such as cesium-137 and strontium-90 have half-lives of approximately 30 years. Meanwhile, plutonium has
27507-400: The touch. Pu due to its much shorter half life heats up to much higher temperatures and glows red hot with blackbody radiation if left without external heating or cooling. This heat has been used in radioisotope thermoelectric generators (see below). The resistivity of plutonium at room temperature is very high for a metal, and it gets even higher with lower temperatures, which
27680-403: The type of the ionizing radiation emitted by a radioactive substance are also important factors in determining its threat to humans. The chemical properties of the radioactive element will determine how mobile the substance is and how likely it is to spread into the environment and contaminate humans. This is further complicated by the fact that many radioisotopes do not decay immediately to
27853-409: The unaided eye. The nuclear properties of plutonium-239 were also studied; researchers found that when it is hit by a neutron it breaks apart (fissions) by releasing more neutrons and energy. These neutrons can hit other atoms of plutonium-239 and so on in an exponentially fast chain reaction. This can result in an explosion large enough to destroy a city if enough of the isotope is concentrated to form
28026-615: The universe at large, in the spectra of stars and also supernovae, where short-lived radioactive elements are newly being made. The first 94 elements have been detected directly on Earth as primordial nuclides present from the formation of the Solar System , or as naturally occurring fission or transmutation products of uranium and thorium. The remaining 24 heavier elements, not found today either on Earth or in astronomical spectra, have been produced artificially: all are radioactive, with short half-lives; if any of these elements were present at
28199-542: The various organs. Hamilton started administering soluble microgram portions of plutonium-239 compounds to rats using different valence states and different methods of introducing the plutonium (oral, intravenous, etc.). Eventually, the lab at Chicago also conducted its own plutonium injection experiments using different animals such as mice, rabbits, fish, and even dogs. The results of the studies at Berkeley and Chicago showed that plutonium's physiological behavior differed significantly from that of radium. The most alarming result
28372-528: The work of Dmitri Mendeleev , a Russian chemist who published the first recognizable periodic table in 1869. This table organizes the elements by increasing atomic number into rows (" periods ") in which the columns (" groups ") share recurring ("periodic") physical and chemical properties . The periodic table summarizes various properties of the elements, allowing chemists to derive relationships between them and to make predictions about elements not yet discovered, and potential new compounds. By November 2016,
28545-447: The δ phase at room temperature. Neptunium is the only element that can stabilize the α phase at higher temperatures. Plutonium alloys can be produced by adding a metal to molten plutonium. If the alloying metal is reductive enough, plutonium can be added in the form of oxides or halides. The δ phase plutonium–gallium alloy (PGA) and plutonium–aluminium alloy are produced by adding Pu(III) fluoride to molten gallium or aluminium, which has
28718-523: Was built at a facility in Oak Ridge that later became the Oak Ridge National Laboratory . Chemical element A chemical element is a chemical substance whose atoms all have the same number of protons . The number of protons is called the atomic number of that element. For example, oxygen has an atomic number of 8, meaning each oxygen atom has 8 protons in its nucleus. Atoms of
28891-467: Was conducted underground. Enrico Fermi and a team of scientists at the University of Rome reported that they had discovered element 94 in 1934. Fermi called the element hesperium and mentioned it in his Nobel Lecture in 1938. The sample actually contained products of nuclear fission , primarily barium and krypton . Nuclear fission, discovered in Germany in 1938 by Otto Hahn and Fritz Strassmann ,
29064-493: Was created directly by the bombardment but decayed by beta emission with a half-life of a little over two days, which indicated the formation of element 94. The first bombardment took place on December 14, 1940, and the new element was first identified through oxidation on the night of February 23–24, 1941. A paper documenting the discovery was prepared by the team and sent to the journal Physical Review in March 1941, but publication
29237-608: Was delayed until a year after the end of World War II due to security concerns. At the Cavendish Laboratory in Cambridge , Egon Bretscher and Norman Feather realized that a slow neutron reactor fuelled with uranium would theoretically produce substantial amounts of plutonium-239 as a by-product. They calculated that element 94 would be fissile, and had the added advantage of being chemically different from uranium, and could easily be separated from it. McMillan had recently named
29410-422: Was isolated and measured for the first time. About 50 micrograms of plutonium-239 combined with uranium and fission products was produced and only about 1 microgram was isolated. This procedure enabled chemists to determine the new element's atomic weight. On December 2, 1942, on a racket court under the west grandstand at the University of Chicago's Stagg Field, researchers headed by Enrico Fermi achieved
29583-431: Was synthesized, which then beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since uranium had been named after the planet Uranus and neptunium after the planet Neptune , element 94 was named after Pluto , which at the time was also considered a planet. Wartime secrecy prevented the University of California team from publishing its discovery until 1948. Plutonium
29756-399: Was that there was significant deposition of plutonium in the liver and in the "actively metabolizing" portion of bone. Furthermore, the rate of plutonium elimination in the excreta differed between species of animals by as much as a factor of five. Such variation made it extremely difficult to estimate what the rate would be for human beings. During World War II the U.S. government established
29929-558: Was unknown at the time. Plutonium (specifically, plutonium-238) was first produced, isolated and then chemically identified between December 1940 and February 1941 by Glenn T. Seaborg , Edwin McMillan , Emilio Segrè , Joseph W. Kennedy , and Arthur Wahl by deuteron bombardment of uranium in the 60-inch (150 cm) cyclotron at the Berkeley Radiation Laboratory at the University of California, Berkeley . Neptunium-238
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