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Pearl GTL

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The Pearl GTL is a gas to liquids (GTL) plant based in Ras Laffan , Qatar . It converts natural gas into liquid petroleum products. It is the largest GTL plant in the world. The first commercial shipment from the Pearl GTL was made on 13 June 2011. Pearl GTL received the 2021 "Asset of the Year" award by Shell .

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67-523: Upon achieving its full capacity in 2012, the Pearl GTL will convert 1.6 billion cubic feet per day (45 × 10 ^  m/d) of natural gas into 140,000 barrels per day (22,000 m/d) of petroleum liquids and 120,000 barrels of oil equivalent (730,000 GJ) into natural gas liquids and ethane . The integrated process automation and control system for the main plant and the onplot tank farm will be designed and implemented by Honeywell , while that for

134-413: A boost, where it is added through the turbocharger, to mix with diesel fuel droplets. Propane droplets' very high hydrogen content helps the diesel fuel to burn hotter and therefore more completely. This provides more torque, more horsepower, and a cleaner exhaust for the trucks. It is normal for a 7-liter medium-duty diesel truck engine to increase fuel economy by 20 to 33 percent when a propane boost system

201-465: A byproduct of natural gas extraction. It is also known as "condensate", "natural gasoline", "casing head gas", "raw gas", "white gas" and "liquid gold". Drip gas is defined in the United States Code of Federal Regulations as consisting of butane , pentane , and hexane hydrocarbons . Within set ranges of distillation , drip gas may be extracted and used to denature fuel alcohol. Drip gas

268-457: A chimney, (known as lower heating value ) is −2043.455 kJ/mol. The lower heat value is the amount of heat available from burning the substance where the combustion products are vented to the atmosphere; for example, the heat from a fireplace when the flue is open. The density of propane gas at 25 °C (77 °F) is 1.808 kg/m , about 1.5× the density of air at the same temperature. The density of liquid propane at 25 °C (77 °F)

335-456: A gas, very high pressure is required to store useful quantities. This poses the hazard that, in an accident, just as with any compressed gas cylinder (such as a CO 2 cylinder used for a soda concession) a CNG cylinder may burst with great force, or leak rapidly enough to become a self-propelled missile. Therefore, CNG is much less efficient to store than propane, due to the large cylinder volume required. An alternative means of storing natural gas

402-732: A mention in Terrence Malick's movie Badlands . Drip gas was sold commercially at gas stations and hardware stores in North America until the early 1950s. The white gas sold today is a similar product but is produced at refineries with the carcinogen benzene removed. In 1975, the New Mexico State Police's drip gas detail – three men in pickup trucks – began patrolling oil and gas fields, catching thieves and recovering barrels of stolen gas. The detail stopped its work in 1987. The use of drip gas in cars and trucks

469-399: A significant risk of fire or explosion. Vendors and advocates of hydrocarbon refrigerants argue against such bans on the grounds that there have been very few such incidents relative to the number of vehicle air conditioning systems filled with hydrocarbons. Propane is also instrumental in providing off-the-grid refrigeration, as the energy source for a gas absorption refrigerator and

536-422: A visible flame. The enthalpy of combustion of propane gas where all products return to standard state, for example where water returns to its liquid state at standard temperature (known as higher heating value ), is (2,219.2 ± 0.5) kJ/mol, or (50.33 ± 0.01) MJ/kg. The enthalpy of combustion of propane gas where products do not return to standard state, for example where the hot gases including water vapor exit

603-438: Is 0.493 g/cm , which is equivalent to 4.11 pounds per U.S. liquid gallon or 493 g/L. Propane expands at 1.5% per 10 °F. Thus, liquid propane has a density of approximately 4.2 pounds per gallon (504 g/L) at 60 °F (15.6 °C). As the density of propane changes with temperature, this fact must be considered every time when the application is connected with safety or custody transfer operations. Propane

670-469: Is a gas at standard temperature and pressure , but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is often a constituent of liquefied petroleum gas (LPG), which is commonly used as a fuel in domestic and industrial applications and in low-emissions public transportation; other constituents of LPG may include propylene , butane , butylene , butadiene , and isobutylene . Discovered in 1857 by

737-479: Is a low-density mixture of hydrocarbon liquids that are present as gaseous components in the raw natural gas produced from many natural gas fields . Some gas species within the raw natural gas will condense to a liquid state if the temperature is reduced to below the hydrocarbon dew point temperature at a set pressure. The natural gas condensate is also called condensate , or gas condensate , or sometimes natural gasoline because it contains hydrocarbons within

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804-415: Is a popular choice for barbecues and portable stoves because the low boiling point of −42 °C (−44 °F) makes it vaporize as soon as it is released from its pressurized container. Therefore, no carburetor or other vaporizing device is required; a simple metering nozzle suffices. Blends of pure, dry "isopropane" [isobutane/propane mixtures of propane (R-290) and isobutane (R-600a)] can be used as

871-486: Is a simple asphyxiant . Unlike natural gas , it is denser than air. It may accumulate in low spaces and near the floor. When abused as an inhalant , it may cause hypoxia (lack of oxygen), pneumonia , cardiac failure or cardiac arrest . Propane has low toxicity since it is not readily absorbed and is not biologically active . Commonly stored under pressure at room temperature, propane and its mixtures will flash evaporate at atmospheric pressure and cool well below

938-400: Is also used as a cleaner and solvent as well as a lantern and stove fuel. Some early internal combustion engines —such as the first types made by Karl Benz , and early Wright brothers aircraft engines—used natural gasoline , which could be either drip gas or a similar range of hydrocarbons distilled from crude oil. Natural gasoline has an octane rating of about 30 to 50, sufficient for

1005-524: Is as a cryogenic liquid in an insulated container as liquefied natural gas (LNG). This form of storage is at low pressure and is around 3.5 times as efficient as storing it as CNG. Unlike propane, if a spill occurs, CNG will evaporate and dissipate because it is lighter than air. Propane is much more commonly used to fuel vehicles than is natural gas, because that equipment costs less. Propane requires just 1,220 kilopascals (177 psi) of pressure to keep it liquid at 37.8 °C (100 °F). Propane

1072-581: Is commonly used for camping and recreational vehicles. It has also been proposed to use propane as a refrigerant in heat pumps . Since it can be transported easily, it is a popular fuel for home heat and backup electrical generation in sparsely populated areas that do not have natural gas pipelines. In June 2023, Stanford researchers found propane combustion emitted detectable and repeatable levels of benzene that in some homes raised indoor benzene concentrations above well-established health benchmarks. The research also shows that gas and propane fuels appear to be

1139-424: Is dangerous for crew due to the danger of explosions, oxygen displacement and the threat of asphyxiating and anaesthetizing, which can occur within a few human breaths. Because condensate is typically liquid in ambient conditions and also has very low viscosity, condensate is often used to dilute highly viscous heavier oils that cannot otherwise be efficiently transported via pipelines . In particular, condensate

1206-454: Is delivered to end-users via small or medium-sized individual cylinders, while empty cylinders are removed for refilling at a central location. There are also community propane systems, with a central cylinder feeding individual homes. In the U.S., over 190,000 on-road vehicles use propane, and over 450,000 forklifts use it for power. It is the third most popular vehicle fuel in the world, behind gasoline and diesel fuel . In other parts of

1273-464: Is far less than current refrigerants, propane was chosen as one of five replacement refrigerants approved by the EPA in 2015, for use in systems specially designed to handle its flammability. Such substitution is widely prohibited or discouraged in motor vehicle air conditioning systems, on the grounds that using flammable hydrocarbons in systems originally designed to carry non-flammable refrigerant presents

1340-422: Is frequently mixed with bitumen from oil sands to create dilbit . In 2013, the increased use of condensate as diluent significantly increased its price in certain regions. Drip gas , so named because it can be drawn off the bottom of small chambers (called drips ) sometimes installed in pipelines from gas wells, is another name for natural-gas condensate, a naturally occurring form of gasoline obtained as

1407-539: Is known as a BLEVE or boiling liquid expanding vapor explosion . The Kingman Explosion involved a railroad tank car in Kingman, Arizona, U.S., in 1973 during a propane transfer. The fire and subsequent explosions resulted in twelve fatalities and numerous injuries. Propane is produced as a by-product of two other processes, natural gas processing and petroleum refining . The processing of natural gas involves removal of butane , propane, and large amounts of ethane from

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1474-457: Is much cleaner than that of coal or unleaded gasoline. Propane's per-BTU production of CO 2 is almost as low as that of natural gas. Propane burns hotter than home heating oil or diesel fuel because of the very high hydrogen content. The presence of C–C bonds , plus the multiple bonds of propylene and butylene , produce organic exhausts besides carbon dioxide and water vapor during typical combustion. These bonds also cause propane to burn with

1541-519: Is not suited for most vehicle fuels. HD-5 is a specification that establishes a maximum concentration of 5% propene in propane. Propane and other LP gas specifications are established in ASTM D-1835. All propane fuels include an odorant , almost always ethanethiol , so that the gas can be smelled easily in case of a leak. Propane as HD-5 was originally intended for use as vehicle fuel. HD-5 is currently being used in all propane applications. Typically in

1608-440: Is now illegal in many states. It is also harmful to modern engines due to its low octane rating, much higher combustion temperature than that of gasoline, and lack of additives. It has a distinctive smell when used as a fuel, which allowed police to sometimes catch people using drip gas illegally. Propane Propane ( / ˈ p r oʊ p eɪ n / ) is a three- carbon alkane with the molecular formula C 3 H 8 . It

1675-741: Is present for complete combustion, carbon monoxide , soot ( carbon ), or both, are formed as well: C 3 H 8 + 9 2 O 2 ⟶ 2 CO 2 + CO + 4 H 2 O + heat {\displaystyle {\ce {C3H8 + 9/2 O2 -> 2 CO2 + CO + 4 H2O + heat}}} C 3 H 8 + 2 O 2 ⟶ 3 C + 4 H 2 O + heat {\displaystyle {\ce {C3H8 + 2 O2 -> 3 C + 4 H2O + heat}}} The complete combustion of propane produces about 50 MJ/kg of heat. Propane combustion

1742-511: Is rated HD-5 (Heavy Duty 5%). HD-5 grade has a maximum of 5 percent butane, but propane sold in Europe has a maximum allowable amount of butane of 30 percent, meaning it is not the same fuel as HD-5. The LPG used as auto fuel and cooking gas in Asia and Australia also has very high butane content. Propylene (also called propene) can be a contaminant of commercial propane. Propane containing too much propene

1809-537: Is that theft is much more difficult than with gasoline or diesel fuels. Propane is also used as fuel for small engines , especially those used indoors or in areas with insufficient fresh air and ventilation to carry away the more toxic exhaust of an engine running on gasoline or diesel fuel. More recently, there have been lawn-care products like string trimmers , lawn mowers and leaf blowers intended for outdoor use, but fueled by propane in order to reduce air pollution . Many heavy-duty highway trucks use propane as

1876-711: Is used for heat and cooking in recreational vehicles and campers . Propane is becoming popular as a replacement refrigerant (R290) for heatpumps also as it offers greater efficiency than the current refrigerants: R410A / R32, higher temperature heat output and less damage to the atmosphere for escaped gasses - at the expense of high gas flammability. Propane was first synthesized by the French chemist Marcellin Berthelot in 1857 during his researches on hydrogenation . Berthelot made propane by heating propylene dibromide (C 3 H 6 Br 2 ) with potassium iodide and water. Propane

1943-474: Is used. It is cheaper because propane is much cheaper than diesel fuel. The longer distance a cross-country trucker can travel on a full load of combined diesel and propane fuel means they can maintain federal hours of work rules with two fewer fuel stops in a cross-country trip. Truckers, tractor pulling competitions, and farmers have been using a propane boost system for over forty years in North America. The North American standard grade of automotive-use propane

2010-643: The space group P2 1 /n. The low space-filling of 58.5% (at 90 K), due to the bad stacking properties of the molecule, is the reason for the particularly low melting point. Propane undergoes combustion reactions in a similar fashion to other alkanes . In the presence of excess oxygen, propane burns to form water and carbon dioxide . C 3 H 8 + 5 O 2 ⟶ 3 CO 2 + 4 H 2 O + heat {\displaystyle {\ce {C3H8 + 5 O2 -> 3 CO2 + 4 H2O + heat}}} When insufficient oxygen

2077-499: The 1930s included the introduction of railroad tank car transport, gas odorization, and the construction of local bottle-filling plants. The year 1945 marked the first year that annual LP gas sales reached a billion gallons. By 1947, 62% of all U.S. homes had been equipped with either natural gas or propane for cooking. In 1950, 1,000 propane-fueled buses were ordered by the Chicago Transit Authority , and by 1958, sales in

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2144-589: The December 2015 EIA figure for the East Coast at $ 2.67 per gallon and the Midwest at $ 1.43 per gallon. As of August 2018 , the average US propane retail cost was approximately $ 2.48 per gallon. The wholesale price of propane in the U.S. always drops in the summer as most homes do not require it for home heating. The wholesale price of propane in the summer of 2018 was between 86 cents to 96 cents per U.S. gallon, based on

2211-528: The Energy Information Administration (EIA) quotes a $ 2.995 per gallon average on the East Coast for October 2013, while the figure for the Midwest was $ 1.860 for the same period. As of December 2015 , the propane retail cost was approximately $ 1.97 per gallon, which meant filling a 500-gallon propane tank to 80% capacity costed $ 788, a 16.9% decrease or $ 160 less from November 2013. Similar regional differences in prices are present with

2278-778: The French chemist Marcellin Berthelot , it became commercially available in the US by 1911. Propane has lower volumetric energy density than gasoline or coal, but has higher gravimetric energy density than them and burns more cleanly. Propane gas has become a popular choice for barbecues and portable stoves because its low −42 °C boiling point makes it vaporise inside pressurised liquid containers (it exists in two phases, vapor above liquid). It retains its ability to vaporise even in cold weather, making it better-suited for outdoor use in cold climates than alternatives with higher boiling points like butane. LPG powers buses, forklifts, automobiles, outboard boat motors, and ice resurfacing machines , and

2345-522: The Pearl GTL plant is naphtha and transport fuels, with paraffins and lubricant oils as smaller by-products of the process. The transport fuel can be used in existing light and heavy diesel engines and has been shown to have a number of benefits, such as lower emissions and engine performance enhancement. 25°54′18″N 51°30′19″E  /  25.90500°N 51.50528°E  / 25.90500; 51.50528 Natural gas liquids Natural-gas condensate , also called natural gas liquids ,

2412-572: The U.S. had reached 7 billion US gallons (26,000,000 m ) annually. In 2004, it was reported to be a growing $ 8-billion to $ 10-billion industry with over 15 billion US gallons (57,000,000 m ) of propane being used annually in the U.S. During the COVID-19 pandemic , propane shortages were reported in the United States due to increased demand. The " prop- " root found in "propane" and names of other compounds with three-carbon chains

2479-747: The United States and Canada, LPG is primarily propane (at least 90%), while the rest is mostly ethane , propylene , butane , and odorants including ethyl mercaptan . This is the HD-5 standard, (maximum allowable propylene content, and no more than 5% butanes and ethane) defined by the American Society for Testing and Materials by its Standard 1835 for internal combustion engines. Not all products labeled "LPG" conform to this standard, however. In Mexico, for example, gas labeled "LPG" may consist of 60% propane and 40% butane. "The exact proportion of this combination varies by country, depending on international prices, on

2546-568: The air separation systems are supplied by Linde . Half of the 24 reactors for the Fischer–Tropsch process were supplied by MAN AG . The Pearl GTL project builds upon the foundations of the smaller scale GTL project in Bintulu , Malaysia , which has been in operation since 1993. The plant is expected to reach full production in mid-2012. In 2003, the project cost was estimated to be US$ 5 billion. However, after facing huge cost escalation, it

2613-432: The availability of components and, especially, on the climatic conditions that favor LPG with higher butane content in warmer regions and propane in cold areas". Propane is bought and stored in a liquid form, LPG. It can easily be stored in a relatively small space. By comparison, compressed natural gas (CNG) cannot be liquefied by compression at normal temperatures, as these are well above its critical temperature . As

2680-577: The circulating refrigerant in suitably constructed compressor-based refrigeration. Compared to fluorocarbons, propane has a negligible ozone depletion potential and very low global warming potential (having a GWP value of 0.072, 13.9 times lower than the GWP of carbon dioxide) and can serve as a functional replacement for R-12 , R-22 , R-134a , and other chlorofluorocarbon or hydrofluorocarbon refrigerants in conventional stationary refrigeration and air conditioning systems. Because its global warming effect

2747-619: The dominant source of benzene produced by cooking. In rural areas of North America, as well as northern Australia, propane is used to heat livestock facilities, in grain dryers, and other heat-producing appliances. When used for heating or grain drying it is usually stored in a large, permanently-placed cylinder which is refilled by a propane-delivery truck. As of 2014 , 6.2 million American households use propane as their primary heating fuel. In North America, local delivery trucks with an average cylinder size of 3,000 US gallons (11 m ), fill up large cylinders that are permanently installed on

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2814-566: The floor to the pilot light on the furnace or water heater, and results in an explosion or fire. This property makes propane generally unsuitable as a fuel for boats. In 2007, a heavily investigated vapor-related explosion occurred in Ghent, West Virginia, U.S., killing four people and completely destroying the Little General convenience store on Flat Top Road , causing several injuries. Another hazard associated with propane storage and transport

2881-408: The freezing point of water. The cold gas, which appears white due to moisture condensing from the air, may cause frostbite. Propane is denser than air. If a leak in a propane fuel system occurs, the vaporized gas will have a tendency to sink into any enclosed area and thus poses a risk of explosion and fire. The typical scenario is a leaking cylinder stored in a basement; the propane leak drifts across

2948-422: The fuel. Most were also equipped with thermosiphon cooling systems that used no water pumps. Natural convection allowed the water to flow up and out of the engine block and into the top of the radiator, where it cooled and dropped and fell to continue the cycle. Woody Guthrie 's autobiographical novel Seeds of Man begins with Woody and his uncle Jeff tapping a natural gas pipeline for drip gas. The gas also has

3015-856: The gasoline boiling range, and is also referred to by the shortened name condy by many workers on gas installations. Raw natural gas used to create condensate may come from any type of gas well such as: There are many condensate sources, and each has its own unique gas condensate composition. In general, gas condensate has a specific gravity ranging from 0.5 to 0.8, and is composed of hydrocarbons such as propane , butane , pentane , and hexane . Natural gas compounds with more than two carbon atoms exist as liquids at ambient temperatures and pressures. Propane , butane , and isobutane are liquid at normal temperatures only under pressure. Additionally, condensate may contain: There are hundreds of different equipment configurations to separate natural gas condensate from raw natural gas. The schematic flow diagram to

3082-419: The heavy fuel would flow to the carburetor. Shutters or curtains were typically used to restrict airflow to the radiator, keeping the engine sufficiently hot for efficient operation. Coolant temperatures in the 200 degree F range were normal. John Deere two-cylinder all-fuel tractors worked well on heavy fuel, as their long piston strokes, slow engine speeds and low compression ratios allowed for effective use of

3149-411: The heavy fuel. They were equipped with a small gasoline tank and a large fuel tank, both of which fed into a common valve supplying the fuel to the carburetor. The engine would be started on gasoline and the tractor would then be worked until the engine was sufficiently warm to change over. At that point, the fuel valve would be turned to switch the fuel supply from the gasoline tank to the fuel tank and

3216-493: The high and low pressure separators may need to be processed to remove hydrogen sulfide ( H 2 S ) before the water can be disposed of underground or reused in some fashion. Some of the raw natural gas may be re-injected into the producing formation to help maintain the reservoir pressure, or for storage pending later installation of a pipeline. Natural gas condensate is generally more flammable and explosive than normal crude oil. Operating in areas where condensate has escaped

3283-561: The low pressure separator is sent to a "booster" compressor that raises the gas pressure and sends it through a cooler, and then to the main gas compressor. At the raw natural gas processing plant, the gas will be dehydrated and acid gases and other impurities will be removed from the gas. Then, the ethane ( C 2 ), propane ( C 3 ), butanes ( C 4 ), and pentanes ( C 5 )—plus higher molecular weight hydrocarbons referred to as C 5+ —will also be removed and recovered as byproducts. The water removed from both

3350-461: The low-compression engines of the early 20th century. By 1930, improved engines and higher compression ratios required higher-octane, refined gasolines to produce power without knocking or detonation. Beginning in the Great Depression , drip gas was used as a replacement for commercial gasoline by people in oil-producing areas. "In the days of simple engines in automobiles and farm tractors it

3417-699: The offplot tank farm and the loading berths will be designed and implemented by Invensys . Page Europa was contracted as overall Telecom System Integrator for both onshore and offshore telecommunications systems. ABB Group was contracted to supply all of the electrical and control systems. The first train will be commissioned in 2010, followed by the second train in 2011. The main contractors are KBR and JGC Corporation . Other contractors are J. Ray McDermott , CB&I , Consolidated Contractors Company , Kentz , Descon Engineering Limited . The process pumps are supplied by Flowserve , chemical injection pumps are by LEWA Germany and eight turbomachinery trains for use in

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3484-420: The operating pressure of and the distance to the raw natural gas processing plant and may require a multi-stage compressor. The gas condensate from the high pressure separator flows through a throttling control valve to a low pressure separator. The reduction in pressure across the control valve causes the condensate to undergo a partial vaporization referred to as flash vaporization . The raw natural gas from

3551-511: The propane consumed each year, with about 70% of that coming from Canada via pipeline and rail. The remaining 30% of imported propane comes to the United States from other sources via ocean transport. After it is separated from the crude oil, North American propane is stored in huge salt caverns . Examples of these are Fort Saskatchewan , Alberta ; Mont Belvieu, Texas ; and Conway, Kansas . These salt caverns can store 80,000,000 barrels (13,000,000 m ) of propane. As of October 2013 ,

3618-514: The property, or other service trucks exchange empty cylinders of propane with filled cylinders. Large tractor-trailer trucks, with an average cylinder size of 10,000 US gallons (38 m ), transport propane from the pipeline or refinery to the local bulk plant. The bobtail tank truck is not unique to the North American market, though the practice is not as common elsewhere, and the vehicles are generally called tankers . In many countries, propane

3685-425: The raw gas, to prevent condensation of these volatiles in natural gas pipelines. Additionally, oil refineries produce some propane as a by-product of cracking petroleum into gasoline or heating oil. The supply of propane cannot easily be adjusted to meet increased demand, because of the by-product nature of propane production. About 90% of U.S. propane is domestically produced. The United States imports about 10% of

3752-437: The retail cost of propane was approximately $ 2.37 per gallon, or roughly $ 25.95 per 1 million BTUs. This means that filling a 500-gallon propane tank, which is what households that use propane as their main source of energy usually require, cost $ 948 (80% of 500 gallons or 400 gallons), a 7.5% increase on the 2012–2013 winter season average US price. However, propane costs per gallon change significantly from one state to another:

3819-409: The right depicts just one of the possible configurations. The raw natural gas feedstock from a gas well or a group of wells is cooled to lower the gas temperature to below its hydrocarbon dew point at the feedstock pressure. This condenses a large part of the gas condensate hydrocarbons. The feedstock mixture of gas, liquid condensate and water is then routed to a high pressure separator vessel where

3886-425: The tractors were referred to as "all-fuel". The most important factor in burning heavy fuels in a spark-ignition engine is proper fuel vaporization. Tractors designed to run on those fuels usually used a "hot" intake air manifold that allowed exhaust heat to warm the manifold and carburetor to aid vaporization. Given the poor vaporization at low temperatures, all-fuel tractors were started on gasoline, then switched to

3953-404: The water and the raw natural gas are separated and removed. If a pressure boost is required, the raw natural gas from the high pressure separator is sent to the main gas compressor , which raises the pressure of the gases to whatever pressure is required for the pipeline transportation of the gas to the raw natural gas processing plant. The main gas compressor discharge pressure will depend upon

4020-547: The world, propane used in vehicles is known as autogas. In 2007, approximately 13 million vehicles worldwide use autogas. The advantage of propane in cars is its liquid state at a moderate pressure. This allows fast refill times, affordable fuel cylinder construction, and price ranges typically just over half that of gasoline. Meanwhile, it is noticeably cleaner (both in handling, and in combustion), results in less engine wear (due to carbon deposits) without diluting engine oil (often extending oil-change intervals), and until recently

4087-543: Was derived from " propionic acid ", which in turn was named after the Greek words protos (meaning first) and pion (fat), as it was the "first" member of the series of fatty acids . Propane is a colorless, odorless gas. Ethyl mercaptan is added as a safety precaution as an odorant , and is commonly called a "rotten egg" smell. At normal pressure it liquifies below its boiling point at −42 °C and solidifies below its melting point at −187.7 °C. Propane crystallizes in

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4154-443: Was developed by Frank Peterson and its patent was granted on July 2, 1912. The 1920s saw increased production of LP gases, with the first year of recorded production totaling 223,000 US gallons (840 m ) in 1922. In 1927, annual marketed LP gas production reached 1 million US gallons (3,800 m ), and by 1935, the annual sales of LP gas had reached 56 million US gallons (210,000 m ). Major industry developments in

4221-529: Was during this time that Snelling — in cooperation with Frank P. Peterson, Chester Kerr, and Arthur Kerr — developed ways to liquefy the LP gases during the refining of gasoline. Together, they established American Gasol Co., the first commercial marketer of propane. Snelling had produced relatively pure propane by 1911, and on March 25, 1913, his method of processing and producing LP gases was issued patent #1,056,845. A separate method of producing LP gas through compression

4288-656: Was found dissolved in Pennsylvanian light crude oil by Edmund Ronalds in 1864. Walter O. Snelling of the U.S. Bureau of Mines highlighted it as a volatile component in gasoline in 1910, which marked the "birth of the propane industry" in the United States. The volatility of these lighter hydrocarbons caused them to be known as "wild" because of the high vapor pressures of unrefined gasoline. On March 31, 1912, The New York Times reported on Snelling's work with liquefied gas, saying "a steel bottle will carry enough gas to light an ordinary home for three weeks". It

4355-603: Was not uncommon for anyone having access to a condensate well to fill his tank with 'drip,'" according to the Oklahoma Historical Society. Sometimes it worked fine. "At other times it might cause thundering backfires and clouds of foul-smelling smoke." Certain manufacturers such as John Deere made farm tractors specifically designed to run on heavy, low-octane fuels which were commonly called " distillate " or "tractor fuel". Other names were tractor vaporising oil (United Kingdom) and "power kerosene" (Australia). Often

4422-467: Was relatively low-cost in North America. The octane rating of propane is relatively high at 110. In the United States the propane fueling infrastructure is the most developed of all alternative vehicle fuels. Many converted vehicles have provisions for topping off from "barbecue bottles". Purpose-built vehicles are often in commercially owned fleets, and have private fueling facilities. A further saving for propane fuel vehicle operators, especially in fleets,

4489-427: Was reported to be $ 18 billion in 2007, and, according to QatarEnergy sources, final project cost is expected to reach as high as $ 24 billion. Because Shell's contract provided them with the input gas for free, the project was calculated to be viable once the price of oil exceeded $ 40 per barrel . The project is a Production Sharing Agreement (PSA) between QatarEnergy and Shell . The primary products of

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