Silver selenide (Ag 2 Se) is the reaction product formed when selenium toning analog silver gelatine photo papers in photographic print toning . The selenium toner contains sodium selenite (Na 2 SeO 3 ) as one of its active ingredients, which is the source of the selenide (Se ) anion combining with the silver in the toning process.
52-508: Navrongo Solar Power Station is a 2.5 MW (3,400 hp) solar power plant in Ghana . The power station is located near the town of Navrongo , Kassena-Nankana District in the Upper East Region of Ghana. This location lies approximately 820 kilometres (510 mi) by road, north of Accra , the country's capital and largest city. Built at a cost of just over US$ 8 million, the plant
104-408: A monoclinic structure and space group P2 1 /n is known to form for colloidal Ag 2 Se nanocrystals. The crystal structure of this polymorph is highly related to the acanthite phase of silver sulfide . For Ag 2 Se, this polymorph is increasingly unstable for larger crystallites, which explains its absence on the bulk phase diagram. It is thought that the influence of the surface energy plays
156-492: A growing number of countries and regions all over the world. The largest manufacturers of solar equipment were based in China. Although concentrated solar power capacity grew more than tenfold, it remained a tiny proportion of the total, because the cost of utility-scale solar PV fell by 85% between 2010 and 2020, while CSP costs only fell 68% in the same timeframe. Despite the rising cost of materials, such as polysilicon , during
208-582: A high specific heat capacity, and can deliver heat at temperatures compatible with conventional power systems. This method of energy storage is used, for example, by the Solar Two power station, allowing it to store 1.44 TJ in its 68 m storage tank, enough to provide full output for close to 39 hours, with an efficiency of about 99%. In stand alone PV systems , batteries are traditionally used to store excess electricity. With grid-connected photovoltaic power systems , excess electricity can be sent to
260-691: A limited effect on the users, but their effect on self-consumption of solar power may be limited. The original political purpose of incentive policies for PV was to facilitate an initial small-scale deployment to begin to grow the industry, even where the cost of PV was significantly above grid parity, to allow the industry to achieve the economies of scale necessary to reach grid parity. Since reaching grid parity, some policies are implemented to promote national energy independence, high tech job creation and reduction of CO 2 emissions. Financial incentives for photovoltaics differ across countries, including Australia , China , Germany , India , Japan , and
312-490: A local user or users. Utility-scale solar is sometimes used to describe this type of project. This approach differs from concentrated solar power , the other major large-scale solar generation technology, which uses heat to drive a variety of conventional generator systems. Both approaches have their own advantages and disadvantages, but to date, for a variety of reasons, photovoltaic technology has seen much wider use. As of 2019 , about 97% of utility-scale solar power capacity
364-504: A measure more directly comparable to other forms of power generation. Most solar parks are developed at a scale of at least 1 MW p . As of 2018, the world's largest operating photovoltaic power stations surpassed 1 gigawatt . At the end of 2019, about 9,000 solar farms were larger than 4 MW AC (utility scale), with a combined capacity of over 220 GW AC . Commercial concentrating solar power (CSP) plants, also called "solar thermal power stations", were first developed in
416-579: A rate ranging from wholesale to retail rate or above, as can be excess annual credits. A community solar project is a solar power installation that accepts capital from and provides output credit and tax benefits to multiple customers, including individuals, businesses, nonprofits, and other investors. Participants typically invest in or subscribe to a certain kW capacity or kWh generation of remote electrical production. In some countries tariffs (import taxes) are imposed on imported solar panels. The overwhelming majority of electricity produced worldwide
468-487: A role stabilizing this phase on the nanoscale, thus allowing its experimental isolation. Electronic structure calculations for this polymorph of Ag 2 Se suggest that it is a narrow-gap semiconductor, which is supported by experimental evidence as well. Prior to 2021, the crystal structure of this polymorph was unknown, and this material was informally referred to as a " tetragonal " or "pseudo-tetragonal" polymorph of Ag 2 Se. This terminology, while not technically correct,
520-440: A thin coating of boron. The “Bell Solar Battery” was described as 6% efficient, with a square yard of the panels generating 50 watts. The first satellite with solar panels was launched in 1957 . By the 1970s, solar panels were still too expensive for much other than satellites . In 1974 it was estimated that only six private homes in all of North America were entirely heated or cooled by functional solar power systems. However,
572-461: Is (or is predicted to become) the cheapest source of energy in all of Central America, Africa, the Middle East, India, South-east Asia, Australia, and several other regions. Different measurements of solar irradiance (direct normal irradiance, global horizontal irradiance) are mapped below: In cases of self-consumption of solar energy, the payback time is calculated based on how much electricity
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#1733106302510624-478: Is a narrow-gap semiconductor , with space group P2 1 2 1 2 1 . The exact size of the band gap has been given variously from 0.02 eV to 0.22 eV. There is also a high temperature cubic phase, α-Ag 2 Se., which it transforms into at temperatures above 130 °C. This high temperature phase has space group Im 3 m, No. 229, Pearson symbol cI20. The phase transition increases ionic conductivity by 10,000 times to about 2 S/cm. A third metastable phase with
676-497: Is a type of solar cell that includes a perovskite-structured compound, most commonly a hybrid organic–inorganic lead or tin halide-based material as the light-harvesting active layer. Perovskite materials, such as methylammonium lead halides and all-inorganic cesium lead halide, are cheap to produce and simple to manufacture. Concentrated solar power (CSP), also called "concentrated solar thermal", uses lenses or mirrors and tracking systems to concentrate sunlight, then uses
728-455: Is forecast to be solar, surpassing coal as the largest source of installed power capacity. Utility scale is forecast to become the largest source of electricity in all regions except sub-Saharan Africa by 2050. According to a 2021 study, global electricity generation potential of rooftop solar panels is estimated at 27 PWh per year at costs ranging from $ 40 (Asia) to $ 240 per MWh (US, Europe). Its practical realization will however depend on
780-571: Is key for high self-consumption. The match can be improved with batteries or controllable electricity consumption. However, batteries are expensive, and profitability may require the provision of other services from them besides self-consumption increase, for example avoiding power outages . Hot water storage tanks with electric heating with heat pumps or resistance heaters can provide low-cost storage for self-consumption of solar power. Shiftable loads, such as dishwashers, tumble dryers and washing machines, can provide controllable consumption with only
832-421: Is not purchased from the grid. However, in many cases, the patterns of generation and consumption do not coincide, and some or all of the energy is fed back into the grid. The electricity is sold, and at other times when energy is taken from the grid, electricity is bought. The relative costs and prices obtained affect the economics. In many markets, the price paid for sold PV electricity is significantly lower than
884-695: Is potentially an important issue, particularly in off-grid applications and for future 100% renewable energy scenarios. Solar is intermittent due to the day/night cycles and variable weather conditions. However solar power can be forecast somewhat by time of day, location, and seasons. The challenge of integrating solar power in any given electric utility varies significantly. In places with hot summers and mild winters, solar tends to be well matched to daytime cooling demands. Concentrated solar power plants may use thermal storage to store solar energy, such as in high-temperature molten salts. These salts are an effective storage medium because they are low-cost, have
936-513: Is the first grid-ready solar station in the country. It is owned by Volta River Authority (VRA), the Ghanaian parastatal responsible for public electricity generation. The power plant was commissioned in 2013. Solar power Solar power , also known as solar electricity , is the conversion of energy from sunlight into electricity , either directly using photovoltaics (PV) or indirectly using concentrated solar power . Solar panels use
988-481: Is the source with the cheapest levelised cost of electricity for new installations in most countries. As of 2023, 33 countries generated more than a tenth of their electricity from solar, with China making up more than half of solar growth. Almost half the solar power installed in 2022 was mounted on rooftops . Much more low-carbon power is needed for electrification and to limit climate change . The International Energy Agency said in 2022 that more effort
1040-765: Is then used for power generation or energy storage. Thermal storage efficiently allows overnight electricity generation, thus complementing PV. CSP generates a very small share of solar power and in 2022 the IEA said that CSP should be better paid for its storage. As of 2021 the levelized cost of electricity from CSP is over twice that of PV. However, their very high temperatures may prove useful to help decarbonize industries (perhaps via hydrogen) which need to be hotter than electricity can provide. A hybrid system combines solar with energy storage and/or one or more other forms of generation. Hydro, wind and batteries are commonly combined with solar. The combined generation may enable
1092-435: Is used immediately because traditional generators can adapt to demand and storage is usually more expensive. Both solar power and wind power are sources of variable renewable power , meaning that all available output must be used locally, carried on transmission lines to be used elsewhere, or stored (e.g., in a battery). Since solar energy is not available at night, storing it so as to have continuous electricity availability
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#17331063025101144-843: The 1973 oil embargo and 1979 energy crisis caused a reorganization of energy policies around the world and brought renewed attention to developing solar technologies. Deployment strategies focused on incentive programs such as the Federal Photovoltaic Utilization Program in the US and the Sunshine Program in Japan. Other efforts included the formation of research facilities in the United States (SERI, now NREL ), Japan ( NEDO ), and Germany ( Fraunhofer ISE ). Between 1970 and 1983 installations of photovoltaic systems grew rapidly. In
1196-463: The 2021–2022 global energy crisis , utility scale solar was still the least expensive energy source in many countries due to the rising costs of other energy sources, such as natural gas. In 2022, global solar generation capacity exceeded 1 TW for the first time. However, fossil-fuel subsidies have slowed the growth of solar generation capacity. About half of installed capacity is utility scale. Most new renewable capacity between 2022 and 2027
1248-460: The United States and even across states within the US. In net metering the price of the electricity produced is the same as the price supplied to the consumer, and the consumer is billed on the difference between production and consumption. Net metering can usually be done with no changes to standard electricity meters , which accurately measure power in both directions and automatically report
1300-486: The electrical grid . Net metering and feed-in tariff programs give these systems a credit for the electricity they produce. This credit offsets electricity provided from the grid when the system cannot meet demand, effectively trading with the grid instead of storing excess electricity. When wind and solar are a small fraction of the grid power, other generation techniques can adjust their output appropriately, but as these forms of variable power grow, additional balance on
1352-536: The photovoltaic effect to convert light into an electric current . Concentrated solar power systems use lenses or mirrors and solar tracking systems to focus a large area of sunlight to a hot spot, often to drive a steam turbine . Photovoltaics (PV) were initially solely used as a source of electricity for small and medium-sized applications, from the calculator powered by a single solar cell to remote homes powered by an off-grid rooftop PV system. Commercial concentrated solar power plants were first developed in
1404-491: The photovoltaic effect . The first solar cell was constructed by Charles Fritts in the 1880s. The German industrialist Ernst Werner von Siemens was among those who recognized the importance of this discovery. In 1931, the German engineer Bruno Lange developed a photo cell using silver selenide in place of copper oxide , although the prototype selenium cells converted less than 1% of incident light into electricity. Following
1456-562: The 1860s was driven by an expectation that coal would soon become scarce, such as experiments by Augustin Mouchot . Charles Fritts installed the world's first rooftop photovoltaic solar array, using 1%-efficient selenium cells, on a New York City roof in 1884. However, development of solar technologies stagnated in the early 20th century in the face of the increasing availability, economy, and utility of coal and petroleum . Bell Telephone Laboratories’ 1950s research used silicon wafers with
1508-538: The 1980s. Since then, as the cost of solar panels has fallen, grid-connected solar PV systems ' capacity and production has doubled about every three years . Three-quarters of new generation capacity is solar, with both millions of rooftop installations and gigawatt-scale photovoltaic power stations continuing to be built. In 2023, solar power generated 5.5% (1,631 TWh) of global electricity and over 1% of primary energy , adding twice as much new electricity as coal. Along with onshore wind power , utility-scale solar
1560-658: The 1980s. The 377 MW Ivanpah Solar Power Facility , located in California's Mojave Desert, is the world's largest solar thermal power plant project. Other large CSP plants include the Solnova Solar Power Station (150 MW), the Andasol solar power station (150 MW), and Extresol Solar Power Station (150 MW), all in Spain. The principal advantage of CSP is the ability to efficiently add thermal storage, allowing
1612-476: The US, residential solar cost from 2 to 4 dollars/watt (but solar shingles cost much more) and utility solar costs were around $ 1/watt. The productivity of solar power in a region depends on solar irradiance , which varies through the day and year and is influenced by latitude and climate . PV system output power also depends on ambient temperature, wind speed, solar spectrum, the local soiling conditions, and other factors. Onshore wind power tends to be
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1664-543: The United States, President Jimmy Carter set a target of producing 20% of U.S. energy from solar by the year 2000, but his successor, Ronald Reagan , removed the funding for research into renewables. Falling oil prices in the early 1980s moderated the growth of photovoltaics from 1984 to 1996. In the mid-1990s development of both, residential and commercial rooftop solar as well as utility-scale photovoltaic power stations began to accelerate again due to supply issues with oil and natural gas, global warming concerns, and
1716-545: The arid tropics and subtropics. Deserts lying in low latitudes usually have few clouds and can receive sunshine for more than ten hours a day. These hot deserts form the Global Sun Belt circling the world. This belt consists of extensive swathes of land in Northern Africa , Southern Africa , Southwest Asia , Middle East , and Australia , as well as the much smaller deserts of North and South America . Thus solar
1768-429: The availability and cost of scalable electricity storage solutions. A photovoltaic power station , also known as a solar park, solar farm, or solar power plant, is a large-scale grid-connected photovoltaic power system (PV system) designed for the supply of merchant power . They are different from most building-mounted and other decentralized solar power because they supply power at the utility level, rather than to
1820-592: The cheapest source of electricity in Northern Eurasia, Canada, some parts of the United States, and Patagonia in Argentina whereas in other parts of the world mostly solar power (or less often a combination of wind, solar and other low carbon energy) is thought to be best. Modelling by Exeter University suggests that by 2030, solar will be least expensive in all countries except for some in north-eastern Europe. The locations with highest annual solar irradiance lie in
1872-550: The cost of solar power, which is a problem for countries where contracts may not be honoured, such as some African countries. Some countries are considering price caps , whereas others prefer contracts for difference . In many countries, solar power is the lowest cost source of electricity. In Saudi Arabia, a power purchase agreement (PPA) was signed in April 2021 for a new solar power plant in Al-Faisaliah. The project has recorded
1924-614: The desired voltage, and for AC, the desired frequency/phase. Many residential PV systems are connected to the grid when available, especially in developed countries with large markets. In these grid-connected PV systems , use of energy storage is optional. In certain applications such as satellites, lighthouses, or in developing countries, batteries or additional power generators are often added as back-ups. Such stand-alone power systems permit operations at night and at other times of limited sunlight. In "vertical agrivoltaics " system, solar cells are oriented vertically on farmland, to allow
1976-421: The difference, and because it allows homeowners and businesses to generate electricity at a different time from consumption, effectively using the grid as a giant storage battery. With net metering, deficits are billed each month while surpluses are rolled over to the following month. Best practices call for perpetual roll over of kWh credits. Excess credits upon termination of service are either lost or paid for at
2028-586: The dispatching of electricity over up to a 24-hour period. Since peak electricity demand typically occurs at about 5 pm, many CSP power plants use 3 to 5 hours of thermal storage. The typical cost factors for solar power include the costs of the modules, the frame to hold them, wiring, inverters, labour cost, any land that might be required, the grid connection, maintenance and the solar insolation that location will receive. Photovoltaic systems use no fuel, and modules typically last 25 to 40 years. Thus upfront capital and financing costs make up 80% to 90% of
2080-457: The grid is needed. As prices are rapidly declining, PV systems increasingly use rechargeable batteries to store a surplus to be used later at night. Batteries used for grid-storage can stabilize the electrical grid by leveling out peak loads for a few hours. In the future, less expensive batteries could play an important role on the electrical grid, as they can charge during periods when generation exceeds demand and feed their stored energy into
2132-538: The grid when demand is higher than generation. Silver selenide It is found in nature as the mineral naumannite , a comparatively rare silver mineral which has nevertheless become recognized as important silver compound in some low-sulfur silver ores from mines in Nevada and Idaho. Silver selenide has two crystal phases on the bulk phase diagram. At lower temperatures, it has an orthorhombic structure, β-Ag 2 Se. This orthorhombic phase, stable at room temperature,
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2184-551: The improving economic position of PV relative to other energy technologies. In the early 2000s, the adoption of feed-in tariffs —a policy mechanism, that gives renewables priority on the grid and defines a fixed price for the generated electricity—led to a high level of investment security and to a soaring number of PV deployments in Europe. For several years, worldwide growth of solar PV was driven by European deployment , but it then shifted to Asia, especially China and Japan , and to
2236-638: The land to both grow crops and generate renewable energy. Other configurations include floating solar farms , placing solar canopies over parking lots, and installing solar panels on roofs. A thin-film solar cell is a second generation solar cell that is made by depositing one or more thin layers, or thin film (TF) of photovoltaic material on a substrate, such as glass, plastic or metal. Thin-film solar cells are commercially used in several technologies, including cadmium telluride (CdTe), copper indium gallium diselenide (CIGS), and amorphous thin-film silicon (a-Si, TF-Si). A perovskite solar cell (PSC)
2288-431: The market is crystalline silicon . The array of a photovoltaic system , or PV system, produces direct current (DC) power which fluctuates with the sunlight's intensity. For practical use this usually requires conversion to alternating current (AC), through the use of inverters . Multiple solar cells are connected inside panels. Panels are wired together to form arrays, then tied to an inverter, which produces power at
2340-461: The position of the Sun can significantly increase the solar energy potential in areas that are farther from the equator. Daytime cloud cover can reduce the light available for solar cells. Land availability also has a large effect on the available solar energy. Solar power plants use one of two technologies: A solar cell , or photovoltaic cell, is a device that converts light into electric current using
2392-522: The price of bought electricity, which incentivizes self-consumption. Moreover, separate self-consumption incentives have been used in e.g., Germany and Italy. Grid interaction regulation has also included limitations of grid feed-in in some regions in Germany with high amounts of installed PV capacity. By increasing self-consumption, the grid feed-in can be limited without curtailment , which wastes electricity. A good match between generation and consumption
2444-422: The resulting heat to generate electricity from conventional steam-driven turbines. A wide range of concentrating technologies exists: among the best known are the parabolic trough , the compact linear Fresnel reflector , the dish Stirling and the solar power tower . Various techniques are used to track the sun and focus light. In all of these systems a working fluid is heated by the concentrated sunlight and
2496-407: The system to vary power output with demand, or at least smooth the solar power fluctuation. There is much hydro worldwide, and adding solar panels on or around existing hydro reservoirs is particularly useful, because hydro is usually more flexible than wind and cheaper at scale than batteries, and existing power lines can sometimes be used. The early development of solar technologies starting in
2548-506: The work of Russell Ohl in the 1940s, researchers Gerald Pearson, Calvin Fuller and Daryl Chapin created the silicon solar cell in 1954. These early solar cells cost US$ 286/watt and reached efficiencies of 4.5–6%. In 1957, Mohamed M. Atalla developed the process of silicon surface passivation by thermal oxidation at Bell Labs . The surface passivation process has since been critical to solar cell efficiency . As of 2022 over 90% of
2600-471: The world's lowest cost for solar PV electricity production of USD 1.04 cents/ kWh. Expenses of high-power band solar modules has greatly decreased over time. Beginning in 1982, the cost per kW was approximately 27,000 American dollars, and in 2006 the cost dropped to approximately 4,000 American dollars per kW. The PV system in 1992 cost approximately 16,000 American dollars per kW and it dropped to approximately 6,000 American dollars per kW in 2008. In 2021 in
2652-450: Was PV. In some countries, the nameplate capacity of photovoltaic power stations is rated in megawatt-peak (MW p ), which refers to the solar array's theoretical maximum DC power output. In other countries, the manufacturer states the surface and the efficiency. However, Canada, Japan, Spain, and the United States often specify using the converted lower nominal power output in MW AC ,
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#17331063025102704-441: Was needed for grid integration and the mitigation of policy, regulation and financing challenges. Nevertheless solar may greatly cut the cost of energy. Geography affects solar energy potential because different locations receive different amounts of solar radiation. In particular, with some variations, areas that are closer to the equator generally receive higher amounts of solar radiation. However, solar panels that can follow
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