91-473: Murano is a series of islands linked by bridges in the Venetian Lagoon , northern Italy . It lies about 1.5 km (1 mi) north of Venice and measures about 1.5 km (1 mi) across with a population of just over 5,000 (2004 figures). It is famous for its glass making . It was once an independent comune , but is now a frazione of the comune of Venice . Murano was initially settled by
182-405: A glass (or vitreous solid) is a non-crystalline solid formed by rapid melt quenching . However, the term "glass" is often defined in a broader sense, to describe any non-crystalline ( amorphous ) solid that exhibits a glass transition when heated towards the liquid state. Glass is an amorphous solid . Although the atomic-scale structure of glass shares characteristics of the structure of
273-436: A supercooled liquid , glass exhibits all the mechanical properties of a solid. As in other amorphous solids , the atomic structure of a glass lacks the long-range periodicity observed in crystalline solids . Due to chemical bonding constraints, glasses do possess a high degree of short-range order with respect to local atomic polyhedra . The notion that glass flows to an appreciable extent over extended periods well below
364-809: A turquoise colour in glass, in contrast to copper(I) oxide (Cu 2 O) which gives a dull red-brown colour. Soda–lime sheet glass is typically used as a transparent glazing material, typically as windows in external walls of buildings. Float or rolled sheet glass products are cut to size either by scoring and snapping the material, laser cutting , water jets , or diamond-bladed saw. The glass may be thermally or chemically tempered (strengthened) for safety and bent or curved during heating. Surface coatings may be added for specific functions such as scratch resistance, blocking specific wavelengths of light (e.g. infrared or ultraviolet ), dirt-repellence (e.g. self-cleaning glass ), or switchable electrochromic coatings. Structural glazing systems represent one of
455-485: A clear "ring" sound when struck. However, lead glass cannot withstand high temperatures well. Lead oxide also facilitates the solubility of other metal oxides and is used in coloured glass. The viscosity decrease of lead glass melt is very significant (roughly 100 times in comparison with soda glass); this allows easier removal of bubbles and working at lower temperatures, hence its frequent use as an additive in vitreous enamels and glass solders . The high ionic radius of
546-443: A green tint in thick sections. Manganese dioxide (MnO 2 ), which gives glass a purple colour, may be added to remove the green tint given by FeO. FeO and chromium(III) oxide (Cr 2 O 3 ) additives are used in the production of green bottles. Iron (III) oxide , on the other-hand, produces yellow or yellow-brown glass. Low concentrations (0.025 to 0.1%) of cobalt oxide (CoO) produce rich, deep blue cobalt glass . Chromium
637-408: A human timescale. Silicon dioxide (SiO 2 ) is a common fundamental constituent of glass. Fused quartz is a glass made from chemically pure silica. It has very low thermal expansion and excellent resistance to thermal shock , being able to survive immersion in water while red hot, resists high temperatures (1000–1500 °C) and chemical weathering, and is very hard. It is also transparent to
728-405: A lighter alternative to traditional glass. Molecular liquids, electrolytes , molten salts , and aqueous solutions are mixtures of different molecules or ions that do not form a covalent network but interact only through weak van der Waals forces or transient hydrogen bonds . In a mixture of three or more ionic species of dissimilar size and shape, crystallization can be so difficult that
819-561: A long period at a temperature just insufficient to cause fusion. In this way, the crystalline, devitrified material, known as Réaumur's glass porcelain is produced. Although generally transparent to visible light, glasses may be opaque to other wavelengths of light . While silicate glasses are generally opaque to infrared wavelengths with a transmission cut-off at 4 μm, heavy-metal fluoride and chalcogenide glasses are transparent to infrared wavelengths of 7 to 18 μm. The addition of metallic oxides results in different coloured glasses as
910-519: A marsh reversed the natural evolution of the Lagoon. Pumping of aquifers since the nineteenth century has increased subsidence . Many of the Lagoon's islands had originally been marshy, but a gradual drainage programme rendered them habitable. Many of the smaller islands are entirely artificial, while some areas around the seaport of the Mestre are also reclaimed islands. The remaining islands—-including those of
1001-482: A mass of hot semi-molten glass, inflating it into a bubble using a hollow blowpipe, and forming it into the required shape by blowing, swinging, rolling, or moulding. While hot, the glass can be worked using hand tools, cut with shears, and additional parts such as handles or feet attached by welding. Flat glass for windows and similar applications is formed by the float glass process, developed between 1953 and 1957 by Sir Alastair Pilkington and Kenneth Bickerstaff of
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#17328525510021092-453: A non-crystalline intergranular phase of grain boundaries . Glass-ceramics exhibit advantageous thermal, chemical, biological, and dielectric properties as compared to metals or organic polymers. The most commercially important property of glass-ceramics is their imperviousness to thermal shock. Thus, glass-ceramics have become extremely useful for countertop cooking and industrial processes. The negative thermal expansion coefficient (CTE) of
1183-401: A plastic resin with glass fibres . It is made by melting glass and stretching the glass into fibres. These fibres are woven together into a cloth and left to set in a plastic resin. Fibreglass has the properties of being lightweight and corrosion resistant and is a good insulator enabling its use as building insulation material and for electronic housing for consumer products. Fibreglass
1274-462: A refractive index of 1.4 to 2.4, and an Abbe number (which characterises dispersion) of 15 to 100. The refractive index may be modified by high-density (refractive index increases) or low-density (refractive index decreases) additives. Glass transparency results from the absence of grain boundaries which diffusely scatter light in polycrystalline materials. Semi-opacity due to crystallization may be induced in many glasses by maintaining them for
1365-412: A spinning metal disk. Several alloys have been produced in layers with thicknesses exceeding 1 millimetre. These are known as bulk metallic glasses (BMG). Liquidmetal Technologies sells several zirconium -based BMGs. Batches of amorphous steel have also been produced that demonstrate mechanical properties far exceeding those found in conventional steel alloys. Experimental evidence indicates that
1456-435: A structural analogue of silica, fluoride , aluminate , phosphate , borate , and chalcogenide glasses) have physicochemical properties useful for their application in fibre-optic waveguides in communication networks and other specialised technological applications. Silica-free glasses may often have poor glass-forming tendencies. Novel techniques, including containerless processing by aerodynamic levitation (cooling
1547-413: A structurally metastable state with respect to its crystalline form, although in certain circumstances, for example in atactic polymers, there is no crystalline analogue of the amorphous phase. Glass is sometimes considered to be a liquid due to its lack of a first-order phase transition where certain thermodynamic variables such as volume , entropy and enthalpy are discontinuous through
1638-585: A surface area of around 160 square kilometres (62 square miles), is the northernmost lagoon in the Adriatic Sea and is sometimes called the "twin sister of the Venice lagoon". The Lagoon of Venice is the most important survivor of a system of estuarine lagoons that in Roman times extended from Ravenna north to Trieste . In the fifth and sixth centuries, the Lagoon gave security to Romanised people fleeing invaders (mostly
1729-518: A wider spectral range than ordinary glass, extending from the visible further into both the UV and IR ranges, and is sometimes used where transparency to these wavelengths is necessary. Fused quartz is used for high-temperature applications such as furnace tubes, lighting tubes, melting crucibles, etc. However, its high melting temperature (1723 °C) and viscosity make it difficult to work with. Therefore, normally, other substances (fluxes) are added to lower
1820-418: Is 3.25 × 10 /°C as compared to about 9 × 10 /°C for a typical soda–lime glass ). They are, therefore, less subject to stress caused by thermal expansion and thus less vulnerable to cracking from thermal shock . They are commonly used for e.g. labware , household cookware , and sealed beam car head lamps . The addition of lead(II) oxide into silicate glass lowers the melting point and viscosity of
1911-552: Is a common volcanic glass with high silica (SiO 2 ) content formed when felsic lava extruded from a volcano cools rapidly. Impactite is a form of glass formed by the impact of a meteorite , where Moldavite (found in central and eastern Europe), and Libyan desert glass (found in areas in the eastern Sahara , the deserts of eastern Libya and western Egypt ) are notable examples. Vitrification of quartz can also occur when lightning strikes sand , forming hollow, branching rootlike structures called fulgurites . Trinitite
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#17328525510022002-702: Is a glassy residue formed from the desert floor sand at the Trinity nuclear bomb test site. Edeowie glass , found in South Australia , is proposed to originate from Pleistocene grassland fires, lightning strikes, or hypervelocity impact by one or several asteroids or comets . Naturally occurring obsidian glass was used by Stone Age societies as it fractures along very sharp edges, making it ideal for cutting tools and weapons. Glassmaking dates back at least 6000 years, long before humans had discovered how to smelt iron. Archaeological evidence suggests that
2093-418: Is a very powerful colouring agent, yielding dark green. Sulphur combined with carbon and iron salts produces amber glass ranging from yellowish to almost black. A glass melt can also acquire an amber colour from a reducing combustion atmosphere. Cadmium sulfide produces imperial red , and combined with selenium can produce shades of yellow, orange, and red. Addition of copper(II) oxide (CuO) produces
2184-449: Is achieved by homogenizing the raw materials mixture ( glass batch ), stirring the melt, and crushing and re-melting the first melt. The obtained glass is usually annealed to prevent breakage during processing. Colour in glass may be obtained by addition of homogenously distributed electrically charged ions (or colour centres ). While ordinary soda–lime glass appears colourless in thin section, iron(II) oxide (FeO) impurities produce
2275-676: Is extensively used for fibreglass , used for making glass-reinforced plastics (boats, fishing rods, etc.), top-of-stove cookware, and halogen bulb glass. The addition of barium also increases the refractive index. Thorium oxide gives glass a high refractive index and low dispersion and was formerly used in producing high-quality lenses, but due to its radioactivity has been replaced by lanthanum oxide in modern eyeglasses. Iron can be incorporated into glass to absorb infrared radiation, for example in heat-absorbing filters for movie projectors, while cerium(IV) oxide can be used for glass that absorbs ultraviolet wavelengths. Fluorine lowers
2366-455: Is in widespread use in optical systems due to its ability to refract, reflect, and transmit light following geometrical optics . The most common and oldest applications of glass in optics are as lenses , windows , mirrors , and prisms . The key optical properties refractive index , dispersion , and transmission , of glass are strongly dependent on chemical composition and, to a lesser degree, its thermal history. Optical glass typically has
2457-481: Is incorrect, as once solidified, glass stops flowing. The sags and ripples observed in old glass were already there the day it was made; manufacturing processes used in the past produced sheets with imperfect surfaces and non-uniform thickness (the near-perfect float glass used today only became widespread in the 1960s). A 2017 study computed the rate of flow of the medieval glass used in Westminster Abbey from
2548-672: Is mostly included in the Metropolitan City of Venice , but the south-western area is part of the Province of Padua . The largest islands or archipelagos by area, excluding coastal reclaimed land and the coastal barrier beaches : Other inhabited islands include: Glass Glass is an amorphous ( non-crystalline ) solid. Because it is often transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window panes, tableware , and optics . Some common objects made of glass are named after
2639-901: Is produced by forcing molten glass through a fine mesh by centripetal force and breaking the extruded glass fibres into short lengths using a stream of high-velocity air. The fibres are bonded with an adhesive spray and the resulting wool mat is cut and packed in rolls or panels. Besides common silica-based glasses many other inorganic and organic materials may also form glasses, including metals , aluminates , phosphates , borates , chalcogenides , fluorides , germanates (glasses based on GeO 2 ), tellurites (glasses based on TeO 2 ), antimonates (glasses based on Sb 2 O 3 ), arsenates (glasses based on As 2 O 3 ), titanates (glasses based on TiO 2 ), tantalates (glasses based on Ta 2 O 5 ), nitrates , carbonates , plastics , acrylic , and many other substances. Some of these glasses (e.g. Germanium dioxide (GeO 2 , Germania), in many respects
2730-463: Is still associated with Venetian glass . Murano's glassmakers were soon numbered among the island's most prominent citizens. By the fourteenth century, glassmakers were allowed to wear swords, enjoyed immunity from prosecution by the Venetian state and found their daughters married into Venice's most affluent families. While benefiting from certain statutory privileges, glassmakers were forbidden to leave
2821-461: Is stronger than most metals, with a theoretical tensile strength for pure, flawless glass estimated at 14 to 35 gigapascals (2,000,000 to 5,100,000 psi) due to its ability to undergo reversible compression without fracture. However, the presence of scratches, bubbles, and other microscopic flaws lead to a typical range of 14 to 175 megapascals (2,000 to 25,400 psi) in most commercial glasses. Several processes such as toughening can increase
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2912-408: Is sufficiently rapid (relative to the characteristic crystallization time) then crystallization is prevented and instead, the disordered atomic configuration of the supercooled liquid is frozen into the solid state at T g . The tendency for a material to form a glass while quenched is called glass-forming ability. This ability can be predicted by the rigidity theory . Generally, a glass exists in
3003-555: Is the largest wetland in the Mediterranean Basin . It is connected to the Adriatic Sea by three inlets : Lido , Malamocco and Chioggia . Situated at one end of a largely enclosed sea, the lagoon is subject to large variations in its water level. The most extreme are the spring tides known as the acqua alta (Italian for "high water"), which regularly flood much of Venice. The nearby Marano-Grado Lagoon , with
3094-436: Is transparent, easily formed, and most suitable for window glass and tableware. However, it has a high thermal expansion and poor resistance to heat. Soda–lime glass is typically used for windows , bottles , light bulbs , and jars . Borosilicate glasses (e.g. Pyrex , Duran ) typically contain 5–13% boron trioxide (B 2 O 3 ). Borosilicate glasses have fairly low coefficients of thermal expansion (7740 Pyrex CTE
3185-636: The Huns and the Lombards ). Later, it provided naturally protected conditions for the growth of the Venetian Republic and its maritime empire . It still provides a base for a seaport , the Venetian Arsenal , and for fishing , as well as a limited amount of hunting and the newer industry of fish farming . The Lagoon was formed about six to seven thousand years ago, when the marine transgression following
3276-510: The Ice Age flooded the upper Adriatic coastal plain. Deposition of river sediments compensated for the sinking coastal plain, and coastwise drift from the mouth of the Po tended to form sandbars that closed tidal inlets. The present aspect of the Lagoon is the result of human intervention. In the fifteenth and sixteenth centuries, Venetian hydraulic projects designed to prevent the lagoon from turning into
3367-513: The Late Bronze Age , there was a rapid growth in glassmaking technology in Egypt and Western Asia . Archaeological finds from this period include coloured glass ingots , vessels, and beads. Much early glass production relied on grinding techniques borrowed from stoneworking , such as grinding and carving glass in a cold state. The term glass has its origins in the late Roman Empire , in
3458-525: The Renaissance period in Europe, the use of large stained glass windows became much less prevalent, although stained glass had a major revival with Gothic Revival architecture in the 19th century. During the 13th century, the island of Murano , Venice , became a centre for glass making, building on medieval techniques to produce colourful ornamental pieces in large quantities. Murano glass makers developed
3549-527: The Roman glass making centre at Trier (located in current-day Germany) where the late-Latin term glesum originated, likely from a Germanic word for a transparent , lustrous substance. Glass objects have been recovered across the Roman Empire in domestic, funerary , and industrial contexts, as well as trade items in marketplaces in distant provinces. Examples of Roman glass have been found outside of
3640-468: The Romans and from the sixth century by people from Altinum and Oderzo . At first, the island prospered as a fishing port and through its production of salt . It was also a centre for trade through the port it controlled on Sant'Erasmo . From the eleventh century, it began to decline as islanders moved to Dorsoduro . It had a Grand Council , like that of Venice, but from the thirteenth century, Murano
3731-465: The dielectric constant of glass. Fluorine is highly electronegative and lowers the polarizability of the material. Fluoride silicate glasses are used in the manufacture of integrated circuits as an insulator. Glass-ceramic materials contain both non-crystalline glass and crystalline ceramic phases. They are formed by controlled nucleation and partial crystallisation of a base glass by heat treatment. Crystalline grains are often embedded within
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3822-436: The glass batch preparation and mixing, the raw materials are transported to the furnace. Soda–lime glass for mass production is melted in glass-melting furnaces . Smaller-scale furnaces for speciality glasses include electric melters, pot furnaces, and day tanks. After melting, homogenization and refining (removal of bubbles), the glass is formed . This may be achieved manually by glassblowing , which involves gathering
3913-501: The 10th century onwards, glass was employed in stained glass windows of churches and cathedrals , with famous examples at Chartres Cathedral and the Basilica of Saint-Denis . By the 14th century, architects were designing buildings with walls of stained glass such as Sainte-Chapelle , Paris, (1203–1248) and the East end of Gloucester Cathedral . With the change in architectural style during
4004-461: The 1930s, which later became known as Depression glass . In the 1950s, Pilkington Bros. , England , developed the float glass process, producing high-quality distortion-free flat sheets of glass by floating on molten tin . Modern multi-story buildings are frequently constructed with curtain walls made almost entirely of glass. Laminated glass has been widely applied to vehicles for windscreens. Optical glass for spectacles has been used since
4095-669: The Ballarin family built in 1506 and artworks by Giovanni Bellini , and the Palazzo da Mula . Glass-related attractions include the many glassworks, some Mediaeval and most open to the public, and the Murano Glass Museum , housed in the large Palazzo Giustinian . Murano's reputation as a center for glassmaking was born when the Venetian Republic , fearing fire and the destruction of the city's mostly wooden buildings, ordered glassmakers to move their furnaces to Murano in 1291. Murano glass
4186-667: The English name for an enclosed, shallow embayment of salt water: a lagoon . The Venetian Lagoon stretches from the River Sile in the north to the Brenta in the south, with a surface area of around 550 square kilometres (212 square miles). It is around 8% land, including Venice itself and many smaller islands. About 11% is permanently covered by open water, or canals , as the network of dredged channels are called, while around 80% consists of mud flats , tidal shallows and salt marshes . The Lagoon
4277-518: The European exploration of the world, was a monk of this community. The monastery was suppressed in 1810 by French forces under Napoleon , in the course of their conquest of the Italian peninsula , and the monks were expelled in 1814. The grounds then became Venice's major cemetery. In 1291, all the glassmakers in Venice were required to move to Murano. In the following century, exports began, and
4368-681: The Middle Ages. The production of lenses has become increasingly proficient, aiding astronomers as well as having other applications in medicine and science. Glass is also employed as the aperture cover in many solar energy collectors. In the 21st century, glass manufacturers have developed different brands of chemically strengthened glass for widespread application in touchscreens for smartphones , tablet computers , and many other types of information appliances . These include Gorilla Glass , developed and manufactured by Corning , AGC Inc. 's Dragontrail and Schott AG 's Xensation. Glass
4459-540: The Pb ion renders it highly immobile and hinders the movement of other ions; lead glasses therefore have high electrical resistance, about two orders of magnitude higher than soda–lime glass (10 vs 10 Ω⋅cm, DC at 250 °C). Aluminosilicate glass typically contains 5–10% alumina (Al 2 O 3 ). Aluminosilicate glass tends to be more difficult to melt and shape compared to borosilicate compositions but has excellent thermal resistance and durability. Aluminosilicate glass
4550-681: The Republic. However, many of them took the risks associated with migration and established glass furnaces in surrounding cities and farther afield — sometimes in England and the Netherlands. Murano's glassmakers held a monopoly on high-quality glassmaking for centuries, developing or refining many technologies including optically clear glass , enamelled glass (smalto), glass with threads of gold (aventurine), multicolored glass ( millefiori ), milk glass (lattimo), and imitation gemstones made of glass. Today,
4641-530: The UK's Pilkington Brothers, who created a continuous ribbon of glass using a molten tin bath on which the molten glass flows unhindered under the influence of gravity. The top surface of the glass is subjected to nitrogen under pressure to obtain a polished finish. Container glass for common bottles and jars is formed by blowing and pressing methods. This glass is often slightly modified chemically (with more alumina and calcium oxide) for greater water resistance. Once
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#17328525510024732-575: The Veneto Region protects and promotes the designation of origin of artistic glassworks created on the island of Murano, since glasswork is an inherent part of Venetian historical and cultural heritage. The "Vetro Artistico Murano" trademark, filed and registered at the European Office for Harmonisation in Alicante, no. 00481812, has been established and is regulated by Regional Law no. 70, 1994 . In
4823-496: The Venice Lagoon was harmed by a reduction in nutrient inputs and by macroalgal biomasses caused by climate change , and by changes in the concentration and distribution of nitrogen , organic phosphorus and organic carbon in the upper sediments. At the same time, however, the seagrasses started a natural process of recolonization, helping to partially restore the pristine conditions of the marine ecosystem. The Venice Lagoon
4914-719: The action of water, making it an ideal material for the manufacture of containers for foodstuffs and most chemicals. Nevertheless, although usually highly resistant to chemical attack, glass will corrode or dissolve under some conditions. The materials that make up a particular glass composition affect how quickly the glass corrodes. Glasses containing a high proportion of alkali or alkaline earth elements are more susceptible to corrosion than other glass compositions. The density of glass varies with chemical composition with values ranging from 2.2 grams per cubic centimetre (2,200 kg/m ) for fused silica to 7.2 grams per cubic centimetre (7,200 kg/m ) for dense flint glass. Glass
5005-400: The artisans of Murano still employ these centuries-old techniques, crafting everything from contemporary art glass and glass jewellery to Murano glass chandeliers and wine stoppers. Venice kept protecting the secret of the production of glass and of crystal but, notwithstanding it, the Republic partially lost its monopoly at the end of the sixteenth century, because of some glass makers who let
5096-535: The coastal strip ( Lido , Pellestrina and Treporti )—-are essentially dunes . Venice Lagoon has been inhabited from the most ancient times, but it was only during and after the fall of the Western Roman Empire that people coming from the Venetian mainland settled in numbers large enough to found the city of Venice . Today, the main cities inside the lagoon are Venice (at the centre of it) and Chioggia (at
5187-411: The cost factor has a low priority. In the laboratory mostly pure chemicals are used. Care must be taken that the raw materials have not reacted with moisture or other chemicals in the environment (such as alkali or alkaline earth metal oxides and hydroxides, or boron oxide ), or that the impurities are quantified (loss on ignition). Evaporation losses during glass melting should be considered during
5278-427: The crystalline ceramic phase can be balanced with the positive CTE of the glassy phase. At a certain point (~70% crystalline) the glass-ceramic has a net CTE near zero. This type of glass-ceramic exhibits excellent mechanical properties and can sustain repeated and quick temperature changes up to 1000 °C. Fibreglass (also called glass fibre reinforced plastic, GRP) is a composite material made by reinforcing
5369-683: The desired form is obtained, glass is usually annealed for the removal of stresses and to increase the glass's hardness and durability. Surface treatments, coatings or lamination may follow to improve the chemical durability ( glass container coatings , glass container internal treatment ), strength ( toughened glass , bulletproof glass , windshields ), or optical properties ( insulated glazing , anti-reflective coating ). New chemical glass compositions or new treatment techniques can be initially investigated in small-scale laboratory experiments. The raw materials for laboratory-scale glass melts are often different from those used in mass production because
5460-446: The entire surrounding district. Muranów was and remains one of Warsaw's most well known areas, especially associated with the city's Jewish history. Murano is composed of seven islands in the Venetian Lagoon , linked by bridges over eight channels. Weakness in the economy has affected Murano but some 260 companies remain in operation, employing 1,100 staff members (2016 data) and the island receives numerous tourists. On 8 July 1797
5551-462: The exceptionally clear colourless glass cristallo , so called for its resemblance to natural crystal, which was extensively used for windows, mirrors, ships' lanterns, and lenses. In the 13th, 14th, and 15th centuries, enamelling and gilding on glass vessels were perfected in Egypt and Syria. Towards the end of the 17th century, Bohemia became an important region for glass production, remaining so until
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#17328525510025642-454: The first true synthetic glass was made in Lebanon and the coastal north Syria , Mesopotamia or ancient Egypt . The earliest known glass objects, of the mid-third millennium BC, were beads , perhaps initially created as accidental by-products of metalworking ( slags ) or during the production of faience , a pre-glass vitreous material made by a process similar to glazing . Early glass
5733-733: The former Roman Empire in China , the Baltics , the Middle East , and India . The Romans perfected cameo glass , produced by etching and carving through fused layers of different colours to produce a design in relief on the glass object. In post-classical West Africa, Benin was a manufacturer of glass and glass beads. Glass was used extensively in Europe during the Middle Ages . Anglo-Saxon glass has been found across England during archaeological excavations of both settlement and cemetery sites. From
5824-555: The glass and melt phases. Important polymer glasses include amorphous and glassy pharmaceutical compounds. These are useful because the solubility of the compound is greatly increased when it is amorphous compared to the same crystalline composition. Many emerging pharmaceuticals are practically insoluble in their crystalline forms. Many polymer thermoplastics familiar to everyday use are glasses. For many applications, like glass bottles or eyewear , polymer glasses ( acrylic glass , polycarbonate or polyethylene terephthalate ) are
5915-493: The glass transition range. The glass transition may be described as analogous to a second-order phase transition where the intensive thermodynamic variables such as the thermal expansivity and heat capacity are discontinuous. However, the equilibrium theory of phase transformations does not hold for glass, and hence the glass transition cannot be classed as one of the classical equilibrium phase transformations in solids. Glass can form naturally from volcanic magma. Obsidian
6006-406: The glass transition temperature is not supported by empirical research or theoretical analysis (see viscosity in solids ). Though atomic motion at glass surfaces can be observed, and viscosity on the order of 10 –10 Pa s can be measured in glass, such a high value reinforces the fact that glass would not change shape appreciably over even large periods of time. For melt quenching, if the cooling
6097-489: The island became famous, initially for glass beads and mirrors . Aventurine glass was invented on the island, and for a while Murano was the main producer of glass in Europe. The island later became known for chandeliers . Although decline set in during the eighteenth century, glassmaking is still the island's main industry. In the fifteenth century, the island became popular as a resort for Venetians, and palaces were built, but this later declined. The countryside of
6188-452: The island was known for its orchards and vegetable gardens until the nineteenth century, when more housing was built. Attractions on the island include the Church of Santa Maria e San Donato (known for its twelfth-century Byzantine mosaic pavement and said to house the bones of the dragon slain by Saint Donatus in the 4th century), the church of San Pietro Martire with the chapel of
6279-645: The lagoon, possibly for feeding. The level of pollution in the lagoon has long been a concern The large phytoplankton and macroalgae blooms in the late 1980s proved particularly devastating. Researchers have identified the lagoon as one of the primary areas where non-indigenous species are introduced into the Mediterranean Sea . Cruise ships crossing the Venetian Lagoon have contributed to air pollution, surface-water pollution, decreased water quality, erosion, and loss of landscape. From 1987 to 2003,
6370-458: The liquid can easily be supercooled into a glass. Examples include LiCl: R H 2 O (a solution of lithium chloride salt and water molecules) in the composition range 4< R <8. sugar glass , or Ca 0.4 K 0.6 (NO 3 ) 1.4 . Glass electrolytes in the form of Ba-doped Li-glass and Ba-doped Na-glass have been proposed as solutions to problems identified with organic liquid electrolytes used in modern lithium-ion battery cells. Following
6461-611: The material, e.g. "glass" , " glasses ", " magnifying glass ". Glass is most often formed by rapid cooling ( quenching ) of the molten form. Some glasses such as volcanic glass are naturally occurring, and obsidian has been used to make arrowheads and knives since the Stone Age . Archaeological evidence suggests glassmaking dates back to at least 3600 BC in Mesopotamia , Egypt , or Syria . The earliest known glass objects were beads , perhaps created accidentally during metalworking or
6552-481: The melt whilst it floats on a gas stream) or splat quenching (pressing the melt between two metal anvils or rollers), may be used to increase the cooling rate or to reduce crystal nucleation triggers. In the past, small batches of amorphous metals with high surface area configurations (ribbons, wires, films, etc.) have been produced through the implementation of extremely rapid rates of cooling. Amorphous metal wires have been produced by sputtering molten metal onto
6643-433: The melt. The high density of lead glass (silica + lead oxide (PbO) + potassium oxide (K 2 O) + soda (Na 2 O) + zinc oxide (ZnO) + alumina) results in a high electron density, and hence high refractive index, making the look of glassware more brilliant and causing noticeably more specular reflection and increased optical dispersion . Lead glass has a high elasticity, making the glassware more workable and giving rise to
6734-619: The melting temperature and simplify glass processing. Sodium carbonate (Na 2 CO 3 , "soda") is a common additive and acts to lower the glass-transition temperature. However, sodium silicate is water-soluble , so lime (CaO, calcium oxide , generally obtained from limestone ), along with magnesium oxide (MgO), and aluminium oxide (Al 2 O 3 ), are commonly added to improve chemical durability. Soda–lime glasses (Na 2 O) + lime (CaO) + magnesia (MgO) + alumina (Al 2 O 3 ) account for over 75% of manufactured glass, containing about 70 to 74% silica by weight. Soda–lime–silicate glass
6825-410: The metallic ions will absorb wavelengths of light corresponding to specific colours. In the manufacturing process, glasses can be poured, formed, extruded and moulded into forms ranging from flat sheets to highly intricate shapes. The finished product is brittle but can be laminated or tempered to enhance durability. Glass is typically inert, resistant to chemical attack, and can mostly withstand
6916-409: The most significant architectural innovations of modern times, where glass buildings now often dominate the skylines of many modern cities . These systems use stainless steel fittings countersunk into recesses in the corners of the glass panels allowing strengthened panes to appear unsupported creating a flush exterior. Structural glazing systems have their roots in iron and glass conservatories of
7007-443: The original Murano Glass art from foreign markets, the most famous Glass Factories of this island have a trademark that certifies glass made products on the island of Murano. The oldest Murano glass factory that is still active today is that of Pauly & C. – Compagnia Venezia Murano , founded in 1866. As part of a broader view of protection and enhancement of typical and traditional Veneto product manufacturing and marketing,
7098-922: The production of faience , which is a form of pottery using lead glazes. Due to its ease of formability into any shape, glass has been traditionally used for vessels, such as bowls , vases , bottles , jars and drinking glasses. Soda–lime glass , containing around 70% silica , accounts for around 90% of modern manufactured glass. Glass can be coloured by adding metal salts or painted and printed with vitreous enamels , leading to its use in stained glass windows and other glass art objects. The refractive , reflective and transmission properties of glass make glass suitable for manufacturing optical lenses , prisms , and optoelectronics materials. Extruded glass fibres have applications as optical fibres in communications networks, thermal insulating material when matted as glass wool to trap air, or in glass-fibre reinforced plastic ( fibreglass ). The standard definition of
7189-704: The secret be known in many European countries. Today, Murano is home to the Museo del Vetro or Murano Glass Museum in the Palazzo Giustinian, which holds displays on the history of glassmaking as well as glass samples ranging from Egyptian times through the present day. Some of the companies that own historical glass factories in Murano are among the most important brands of glass in the world. These companies include Venini, Alessandro Mandruzzato Ferro Murano , Barovier & Toso , Simone Cenedese [1] and Seguso . To protect
7280-424: The selection of the raw materials, e.g., sodium selenite may be preferred over easily evaporating selenium dioxide (SeO 2 ). Also, more readily reacting raw materials may be preferred over relatively inert ones, such as aluminium hydroxide (Al(OH) 3 ) over alumina (Al 2 O 3 ). Usually, the melts are carried out in platinum crucibles to reduce contamination from the crucible material. Glass homogeneity
7371-583: The seventeenth century, the Murano-born Simone Giuseppe Belotti (in Polish, Szymon Józef Bellotti) became Royal Architect to the King of Poland and took part in designing some of Warsaw 's most important landmarks ( pl:Józef Szymon Bellotti ). The palace he built for himself was named after his native island, "Muranów" — a Polish pronunciation of "Murano". This palace eventually gave its name to
7462-471: The southern inlet); Lido di Venezia and Pellestrina are inhabited as well, but they are considered part of Venice. However, most of the inhabitants of Venice, as well as its economic core (its airport and harbor), are on the western border of the lagoon, around the former towns of Mestre and Marghera . There are also two towns at the northern end of the lagoon: Jesolo (a famous sea resort) and Cavallino-Treporti . Bottlenose dolphins occasionally enter
7553-536: The start of the 20th century. By the 17th century, glass in the Venetian tradition was also being produced in England . In about 1675, George Ravenscroft invented lead crystal glass, with cut glass becoming fashionable in the 18th century. Ornamental glass objects became an important art medium during the Art Nouveau period in the late 19th century. Throughout the 20th century, new mass production techniques led to
7644-469: The strength of glass. Carefully drawn flawless glass fibres can be produced with a strength of up to 11.5 gigapascals (1,670,000 psi). The observation that old windows are sometimes found to be thicker at the bottom than at the top is often offered as supporting evidence for the view that glass flows over a timescale of centuries, the assumption being that the glass has exhibited the liquid property of flowing from one shape to another. This assumption
7735-460: The system Al-Fe-Si may undergo a first-order transition to an amorphous form (dubbed "q-glass") on rapid cooling from the melt. Transmission electron microscopy (TEM) images indicate that q-glass nucleates from the melt as discrete particles with uniform spherical growth in all directions. While x-ray diffraction reveals the isotropic nature of q-glass, a nucleation barrier exists implying an interfacial discontinuity (or internal surface) between
7826-451: The widespread availability of glass in much larger amounts, making it practical as a building material and enabling new applications of glass. In the 1920s a mould -etch process was developed, in which art was etched directly into the mould so that each cast piece emerged from the mould with the image already on the surface of the glass. This reduced manufacturing costs and, combined with a wider use of coloured glass, led to cheap glassware in
7917-402: The year 1268. The study found that the room temperature viscosity of this glass was roughly 10 Pa · s which is about 10 times less viscous than a previous estimate made in 1998, which focused on soda-lime silicate glass. Even with this lower viscosity, the study authors calculated that the maximum flow rate of medieval glass is 1 nm per billion years, making it impossible to observe in
8008-510: Was originally used in the United Kingdom and United States during World War II to manufacture radomes . Uses of fibreglass include building and construction materials, boat hulls, car body parts, and aerospace composite materials. Glass-fibre wool is an excellent thermal and sound insulation material, commonly used in buildings (e.g. attic and cavity wall insulation ), and plumbing (e.g. pipe insulation ), and soundproofing . It
8099-484: Was published the first comprehensive history book "Notizie Istorico-geografiche Murano", 1797. about the history of Murano. Venetian Lagoon The Venetian Lagoon ( Italian : Laguna di Venezia ; Venetian : Łaguna de Venesia ) is an enclosed bay of the Adriatic Sea , in northern Italy , in which the city of Venice is situated. Its name in the Italian and Venetian languages , Laguna Veneta (cognate of Latin lacus ' lake ' ), has provided
8190-539: Was rarely transparent and often contained impurities and imperfections, and is technically faience rather than true glass, which did not appear until the 15th century BC. However, red-orange glass beads excavated from the Indus Valley Civilization dated before 1700 BC (possibly as early as 1900 BC) predate sustained glass production, which appeared around 1600 BC in Mesopotamia and 1500 BC in Egypt. During
8281-650: Was ultimately governed by a podestà from Venice. Unlike the other islands in the Lagoon , Murano minted its own coins. Early in the second millennium hermits of the Camaldolese Order occupied one of the islands, seeking a place of solitude for their way of life. There they founded the Monastery of St. Michael ( Italian : S. Michele di Murano ). This monastery became a great center of learning and printing. The famous cartographer , Fra Mauro , whose maps were crucial to
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