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Clarence Moreton Basin

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Limonite ( / ˈ l aɪ m ə ˌ n aɪ t / ) is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)· n H 2 O , although this is not entirely accurate as the ratio of oxide to hydroxide can vary quite widely. Limonite is one of the three principal iron ores , the others being hematite and magnetite , and has been mined for the production of iron since at least 400 BC.

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62-591: The Clarence Moreton Basin is a Mesozoic sedimentary basin on the easternmost part of the Australian continent. It is located in the far north east of the state of New South Wales around Lismore and Grafton and in the south east corner of Queensland . It is the part of the Great Artesian Basin that extends to the east coast in Australia's central eastern lowlands. It formed by oblique extension of

124-476: A boom of dinosaurian evolution on land as the continents began to separate from each other (Nyasasaurus from 243 to 210 million years ago, approximately 235–30 ma, some of them separated into Sauropodomorphs, Theropods and Herrerasaurids), as well as the first pterosaurs . During the Late Triassic, some advanced cynodonts gave rise to the first Mammaliaformes . All this climatic change, however, resulted in

186-478: A clay or mudstone. However, there are limonite pseudomorphs after other minerals such as pyrite . This means that chemical weathering transforms the crystals of pyrite into limonite by hydrating the molecules, but the external shape of the pyrite crystal remains. Limonite pseudomorphs have also been formed from other iron oxides, hematite and magnetite; from the carbonate siderite and from iron rich silicates such as almandine garnets . Limonite usually forms from

248-435: A cliff. The Corindi Conglomerate is a local name for a hailstone sized gravel near Corindi . The Mill Creek Siltstone. are often olive green or yellow-brown with bright red joint planes. The Marburg Subgroup extends for 225 kilometres (140 mi) along the western side of the basin into Queensland from Corindi. It is mostly clay cemented cross bedded quartz sandstone, but this is interbedded with claystone and shale. At

310-582: A coating. This contrasts with the earth's current flora, in which the dominant land plants in terms of number of species are angiosperms . The earliest members of the genus Ginkgo first appeared during the Middle Jurassic. This genus is represented today by a single species, Ginkgo biloba . Modern conifer groups began to radiate during the Jurassic. Bennettitales , an extinct group of gymnosperms with foliage superficially resembling that of cycads gained

372-584: A decline in diversity of sauropods, stegosaurs, and other high-browsing groups, with sauropods particularly scarce in North America. Some island-hopping dinosaurs, such as Eustreptospondylus , evolved to cope with the coastal shallows and small islands of ancient Europe. Other dinosaurs rose up to fill the empty space that the Jurassic-Cretaceous extinction left behind, such as Carcharodontosaurus and Spinosaurus . Seasons came back into effect and

434-477: A few million years before the Triassic–Jurassic extinction event. Sea levels began to rise during the Jurassic, probably caused by an increase in seafloor spreading . The formation of new crust beneath the surface displaced ocean waters by as much as 200 m (656 ft) above today's sea level, flooding coastal areas. Furthermore, Pangaea began to rift into smaller divisions, creating new shoreline around

496-477: A global distribution during the Late Triassic, and represented one of the most common groups of Mesozoic seed plants. Flowering plants radiated during the early Cretaceous, first in the tropics , but the even temperature gradient allowed them to spread toward the poles throughout the period. By the end of the Cretaceous, angiosperms dominated tree floras in many areas, although some evidence suggests that biomass

558-659: A large die-out known as the Triassic–Jurassic extinction event, in which many archosaurs (excluding pterosaurs, dinosaurs and crocodylomorphs ), most synapsids , and almost all large amphibians became extinct, as well as 34% of marine life, in the Earth's fourth mass extinction event. The cause is debatable; flood basalt eruptions at the Central Atlantic magmatic province is cited as one possible cause. The Jurassic ranges from 200 million years to 145 million years ago and features three major epochs: The Early Jurassic,

620-403: A source of iron. Iron caps or gossans of siliceous iron oxide typically form as the result of intensive oxidation of sulfide ore deposits. These gossans were used by prospectors as guides to buried ore. Limonite was mined for its ancillary gold content. The oxidation of sulfide deposits which contained gold , often resulted in the concentration of gold in the iron oxide and quartz of

682-435: A variety of niches, beginning in the mid-Triassic 4 million to 6 million years after the extinction, and not fully proliferated until 30 million years after the extinction. Animal life was then dominated by various archosaurs: dinosaurs , pterosaurs, and aquatic reptiles such as ichthyosaurs, plesiosaurs, and mosasaurs . The climatic changes of the late Jurassic and Cretaceous favored further adaptive radiation. The Jurassic

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744-472: Is also a unit in the coal measures. The conglomerate includes a 15-metre (49 ft) thick layer of basalt exposed at Copes Creek. The Neranleigh-Fernvale Beds are up to 3,500 metres thick. The Red Cliff Coal Measures date to the Late Triassic. It forms an outcropping belt 2.5 kilometres (1.6 mi) wide and 19 kilometres (12 mi) long from Buchanans Head through Red Cliff . The Evans Head Coal Measures are correlated with these, but are further up

806-645: Is characterized by the dominance of gymnosperms such as cycads , ginkgoaceae and araucarian conifers, and of archosaurian reptiles such as the dinosaurs ; a hot greenhouse climate; and the tectonic break-up of Pangaea . The Mesozoic is the middle of the three eras since complex life evolved : the Paleozoic , the Mesozoic, and the Cenozoic . The era began in the wake of the Permian–Triassic extinction event ,

868-735: Is likely to be present in the basin. The oldest rocks in the Clarence Moreton Basin of New South Wales are the Chillingham Volcanics . These are from some time in the Triassic period, and crop out in a band north and south of Chillingham . They consist of conglomerate at the base, rhyolite, lithic rhyolitic tuff, and shale. The Nymboida Coal Measures extend from Nymboida to Kangaroo Creek. They consist of lithic sandstones (wackes, minor arenites), siltstone, polymictic conglomerate, coal, rhyolitic tuff, and basalt. The total thickness

930-455: Is not due to angular sand grains, but results from silica crystallization. It is up to 150 metres (490 ft) thick. The Grafton Formation is the sedimentary unit in the core of the basin. It is the youngest of the beds being between Late Jurassic and Early Cretaceous. It occurs from Grafton to Casino consisting of soft sandstone, siltstone and claystone. Dolerite has intruded this at Glenugie Peak , and near Banyabba . Rifting along

992-524: Is often deposited in run-off streams from mining operations. Nickel-rich limonite ores represent the largest reserves of nickel. Such minerals are classified as lateritic nickel ore deposits . One of the first uses was as a pigment . The yellow form produced yellow ochre for which Cyprus was famous, while the darker forms produced more earthy tones. Roasting the limonite changed it partially to hematite, producing red ochres, burnt umbers and siennas . Bog iron ore and limonite mudstones are mined as

1054-496: Is over 1,000 metres (3,300 ft). The outcrop is 90 square kilometres (35 sq mi), and it forms a north west trending band 29 kilometres (18 mi) long on the southwest tip of the basin. Fossils reveal a date of middle Triassic. A lower part is called Cloughers Creek Formation . The Basin Creek Formation includes the coal mined at Nymboida. The Bardool Conglomerate forming a 180 metres (590 ft) thick layer,

1116-493: Is quite variable, ranging from 1 to 5. In thin section it appears as red, yellow, or brown and has a high index of refraction, 2.0–2.4. Limonite minerals are strongly birefringent, but grain sizes are usually too small for this to be detectable. Although originally defined as a single mineral, limonite is now recognized as a field term for a mixture of related hydrated iron oxide minerals, among them goethite , lepidocrocite , akaganeite , and jarosite . Determination of

1178-403: Is sometimes called brown hematite or brown iron ore . Limonite is relatively dense with a specific gravity varying from 2.7 to 4.3. It is usually medium to dark yellowish brown in color. The streak of limonite on an unglazed porcelain plate is always yellowish brown, a character which distinguishes it from hematite with a red streak, or from magnetite with a black streak. The hardness

1240-522: Is thought that a large meteor smashed into earth 66 million years ago, creating the Chicxulub Crater in an event known as the K-Pg Extinction (formerly K-T), the fifth and most recent mass extinction event, in which 75% of life became extinct, including all non-avian dinosaurs. Compared to the vigorous convergent plate mountain-building of the late Paleozoic, Mesozoic tectonic deformation

1302-628: The Greek prefix meso- ( μεσο- 'between') and zōon ( ζῷον 'animal, living being'). In this way, the Mesozoic is comparable to the Cenozoic ( lit.   ' new life ' ) and Paleozoic ('old life') eras as well as the Proterozoic ('earlier life') Eon. The Mesozoic Era was originally described as the "secondary" era, following the "primary" ( Paleozoic ), and preceding the Tertiary . Following

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1364-698: The Indian subcontinent , which collided with the Asian plate during the Cenozoic, giving rise to the Himalayas . The Triassic was generally dry, a trend that began in the late Carboniferous , and highly seasonal, especially in the interior of Pangaea. Low sea levels may have also exacerbated temperature extremes. With its high specific heat capacity , water acts as a temperature-stabilizing heat reservoir, and land areas near large bodies of water—especially oceans—experience less variation in temperature. Because much of Pangaea's land

1426-554: The Permian Period allowed for the radiation of many new lifeforms. In particular, the extinction of the large herbivorous pareiasaurs and carnivorous gorgonopsians left those ecological niches empty. Some were filled by the surviving cynodonts and dicynodonts , the latter of which subsequently became extinct. Recent research indicates that it took much longer for the reestablishment of complex ecosystems with high biodiversity, complex food webs, and specialized animals in

1488-453: The Atlantic seaway, which has grown continually larger until today. The further separation of the continents gave opportunity for the diversification of new dinosaurs. The Cretaceous is the longest period of the Mesozoic, but has only two epochs: Early and Late Cretaceous. The Early Cretaceous spans from 145 to 100 million years ago. The Early Cretaceous saw the expansion of seaways and

1550-771: The Cretaceous–Paleogene extinction event. Approximately 50% of all genera became extinct, including all of the non- avian dinosaurs. The Triassic ranges roughly from 252 million to 201 million years ago, preceding the Jurassic Period. The period is bracketed between the Permian–Triassic extinction event and the Triassic–Jurassic extinction event , two of the " big five ", and it is divided into three major epochs: Early, Middle, and Late Triassic. The Early Triassic, about 252 to 247 million years ago,

1612-537: The Jurassic, having evolved from a branch of theropod dinosaurs, then true toothless birds appeared in the Cretaceous. The first mammals also appeared during the Mesozoic, but would remain small—less than 15 kg (33 lb)—until the Cenozoic. Flowering plants appeared in the Early Cretaceous and would rapidly diversify through the end of the era, replacing conifers and other gymnosperms ( sensu lato ), such as ginkgoales , cycads and bennettitales as

1674-458: The Late Cretaceous declined for poorly understood reasons, though this might be due to tendencies of the fossil record, as their diversity seems to be much higher than previously thought. Birds became increasingly common and diversified into a variety of enantiornithe and ornithurine forms. Though mostly small, marine hesperornithes became relatively large and flightless, adapted to life in

1736-546: The Marburg formation. The Walloon Coal Measures forms a U shape around the east, south and west sides of the basin. It consists of claystone, shale, siltstone, arenites , and coal seams and the plant fossils in it show a Jurassic age. The next layer of rocks in the basin forming a nested U shape in its exposure is the Kangaroo Creek Sandstone . This sandstone has saccharoidal texture, and glistens white and cream. This

1798-463: The Mesozoic was varied, alternating between warming and cooling periods. Overall, however, the Earth was hotter than it is today. Dinosaurs first appeared in the Mid-Triassic, and became the dominant terrestrial vertebrates in the Late Triassic or Early Jurassic, occupying this position for about 150 or 135 million years until their demise at the end of the Cretaceous. Archaic birds appeared in

1860-498: The Middle Jurassic, and the Late Jurassic. The Early Jurassic spans from 200 to 175 million years ago. The climate was tropical and much more humid than the Triassic, as a result of the large seas appearing between the land masses. In the oceans, plesiosaurs , ichthyosaurs and ammonites were abundant. On land, dinosaurs and other archosaurs staked their claim as the dominant race, with theropods such as Dilophosaurus at

1922-617: The Paleozoic, the Mesozoic extended roughly 186 million years, from 251.902 to 66 million years ago when the Cenozoic Era began. This time frame is separated into three geologic periods . From oldest to youngest: The lower boundary of the Mesozoic is set by the Permian–Triassic extinction event , during which it has been estimated that up to 90-96% of marine species became extinct although those approximations have been brought into question with some paleontologists estimating

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1984-468: The Tethys Ocean. Temperatures continued to increase, then began to stabilize. Humidity also increased with the proximity of water, and deserts retreated. The climate of the Cretaceous is less certain and more widely disputed. Probably, higher levels of carbon dioxide in the atmosphere are thought to have almost eliminated the north–south temperature gradient : temperatures were about the same across

2046-594: The actual numbers as low as 81%. It is also known as the "Great Dying" because it is considered the largest mass extinction in the Earth's history. The upper boundary of the Mesozoic is set at the Cretaceous–Paleogene extinction event (or K–Pg extinction event ), which may have been caused by an asteroid impactor that created Chicxulub Crater on the Yucatán Peninsula . Towards the Late Cretaceous, large volcanic eruptions are also believed to have contributed to

2108-497: The base is the Blaxland Fossil Wood Conglomerate Member at Blaxlands Creek. The fossil wood is in the form of horizontal tree trunks up to 18 metres (59 ft) long and 600 millimetres (24 in) in diameter. The fossilization process replaced the wood with limonite and hematite . The Towallum Basalt is a 15-metre (49 ft) thick layer near Nymboida, Glenreagh and Moleton trig station overlying

2170-510: The beginnings of the breakup of Pangaea and the opening of the Tethys Ocean . Ecosystems had recovered from the Permian extinction. Algae, sponge, corals, and crustaceans all had recovered, and new aquatic reptiles evolved, such as ichthyosaurs and nothosaurs . On land, pine forests flourished, as did groups of insects such as mosquitoes and fruit flies. Reptiles began to get bigger and bigger, and

2232-431: The current level (about 21%) throughout the Mesozoic, some concluding they were lower in the Triassic and part of the Jurassic but higher in the Cretaceous, and some concluding they were higher throughout most or all of the Triassic, Jurassic and Cretaceous. The dominant land plant species of the time were gymnosperms , which are vascular, cone-bearing, non-flowering plants such as conifers that produce seeds without

2294-679: The dawn of the Mesozoic, ocean plankton communities transitioned from ones dominated by green archaeplastidans to ones dominated by endosymbiotic algae with red-algal-derived plastids. This transition is speculated to have been caused by an increasing paucity of many trace metals in the Mesozoic ocean. Limonite Limonite is named for the Ancient Greek word λειμών ( leimṓn [leː.mɔ̌ːn] ), meaning " wet meadow ", or λίμνη ( límnē [lím.nɛː] ), meaning "marshy lake", as an allusion to its occurrence as bog iron ore in meadows and marshes . In its brown form, it

2356-452: The dominant group of plants. The phrase "Age of Reptiles" was introduced by the 19th century paleontologist Gideon Mantell who viewed it as dominated by diapsids such as Iguanodon , Megalosaurus , Plesiosaurus , and Pterodactylus . The current name was proposed in 1840 by the British geologist John Phillips (1800–1874). "Mesozoic" literally means 'middle life', deriving from

2418-600: The dramatic rifting of the supercontinent Pangaea, which gradually split into a northern continent, Laurasia , and a southern continent, Gondwana . This created the passive continental margin that characterizes most of the Atlantic coastline (such as along the U.S. East Coast ) today. By the end of the era, the continents had rifted into nearly their present forms, though not their present positions. Laurasia became North America and Eurasia , while Gondwana split into South America , Africa , Australia , Antarctica and

2480-518: The east coast of Australia commenced and uplifted the eastern side of the Clarence Moreton Basin. This resulted in the splitting off of the Lord Howe Rise and the opening of the ocean floor. Mesozoic The Mesozoic Era is the era of Earth's geological history , lasting from about 252 to 66 million years ago , comprising the Triassic , Jurassic and Cretaceous Periods . It

2542-467: The fern prairies, chased by many new predators such as Allosaurus . Conifer forests made up a large portion of the forests. In the oceans, plesiosaurs were quite common, and ichthyosaurs flourished. This epoch was the peak of the reptiles. The Late Jurassic spans from 163 to 145 million years ago. During this epoch, the first avialans , such as Archaeopteryx , evolved from small coelurosaurian dinosaurs. The increase in sea levels opened up

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2604-460: The first crocodilians and dinosaurs evolved, which sparked competition with the large amphibians that had previously ruled the freshwater world, respectively mammal-like reptiles on land. Following the bloom of the Middle Triassic, the Late Triassic, from 237 to 201 million years ago, featured frequent heat spells and moderate precipitation (10–20 inches per year). The recent warming led to

2666-478: The food web. In the oceans, mosasaurs ruled, filling the role of the ichthyosaurs, which, after declining, had disappeared in the Cenomanian-Turonian boundary event . Though pliosaurs had gone extinct in the same event, long-necked plesiosaurs such as Elasmosaurus continued to thrive. Flowering plants, possibly appearing as far back as the Triassic, became truly dominant for the first time. Pterosaurs in

2728-432: The fossil record. The Late Cretaceous spans from 100 to 66 million years ago. The Late Cretaceous featured a cooling trend that would continue in the Cenozoic Era. Eventually, tropics were restricted to the equator and areas beyond the tropic lines experienced extreme seasonal changes in weather. Dinosaurs still thrived, as new taxa such as Tyrannosaurus , Ankylosaurus , Triceratops and hadrosaurs dominated

2790-465: The gossans. The gold of the primary veins was concentrated into the limonites of the deeply weathered rocks. In another example the deeply weathered iron formations of Brazil served to concentrate gold with the limonite of the resulting soils. Limonite was one of the earliest materials used as a pigment by humans, and can be seen in Neolithic cave paintings and pictographs . While the first iron ore

2852-407: The hydration of hematite and magnetite, from the oxidation and hydration of iron rich sulfide minerals, and chemical weathering of other iron rich minerals such as olivine , pyroxene , amphibole , and biotite . It is often the major iron component in lateritic soils , and limonite laterite ores are a source of nickel and potentially cobalt and other valuable metals, present as trace elements. It

2914-406: The largest mass extinction in Earth's history, and ended with the Cretaceous–Paleogene extinction event , another mass extinction whose victims included the non-avian dinosaurs , pterosaurs , mosasaurs , and plesiosaurs . The Mesozoic was a time of significant tectonic, climatic, and evolutionary activity. The supercontinent Pangaea began to break apart into separate landmasses. The climate of

2976-452: The north coast at Evans Head . The basin was next uplifted and eroded and then deepened considerably and Bundamba group rocks form a complete V shape on both sides of the basin. In the northern parts the rock is mostly friable sandstone, but in the south it is divided into conglomerate below and siltstone above. The Laytons Range Conglomerate rests on the basin floor and extends from Baryulgil , to Nymboida. The conglomerate often appears as

3038-455: The open sea. Metatherians and primitive eutherian also became common and even produced large and specialised genera such as Didelphodon and Schowalteria . Still, the dominant mammals were multituberculates, cimolodonts in the north and gondwanatheres in the south. At the end of the Cretaceous, the Deccan traps and other volcanic eruptions were poisoning the atmosphere. As this continued, it

3100-559: The ores of choice when smelting was by bloomeries , and it was only with the development of blast furnaces in the 1st century BCE in China and about 1150 CE in Europe, that the brown iron ore of limonite could be used to best advantage. Bog iron ore and limonite were mined in the US, but this ended with the development of advanced mining techniques. Goldbearing limonite gossans were productively mined in

3162-437: The planet, and about 10° C higher than today. The circulation of oxygen to the deep ocean may also have been disrupted, preventing the decomposition of large volumes of organic matter, which was eventually deposited as " black shale ". Different studies have come to different conclusions about the amount of oxygen in the atmosphere during different parts of the Mesozoic, with some concluding oxygen levels were lower than

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3224-641: The poles got seasonally colder, but some dinosaurs still inhabited the polar forests year round, such as Leaellynasaura and Muttaburrasaurus . The poles were too cold for crocodiles, and became the last stronghold for large amphibians such as Koolasuchus . Pterosaurs got larger as genera such as Tapejara and Ornithocheirus evolved. Mammals continued to expand their range: eutriconodonts produced fairly large, wolverine -like predators such as Repenomamus and Gobiconodon , early therians began to expand into metatherians and eutherians , and cimolodont multituberculates went on to become common in

3286-472: The precise mineral composition is practical only with X-ray diffraction techniques. Individual minerals in limonite may form crystals , but limonite does not, although specimens may show a fibrous or microcrystalline structure, and limonite often occurs in concretionary forms or in compact and earthy masses; sometimes mammillary, botryoidal , reniform or stalactitic. Because of its amorphous nature, and occurrence in hydrated areas limonite often presents as

3348-497: The top of the food chain. The first true crocodiles evolved, pushing the large amphibians to near extinction. All-in-all, archosaurs rose to rule the world. Meanwhile, the first true mammals evolved, remaining relatively small, but spreading widely; the Jurassic Castorocauda , for example, had adaptations for swimming, digging and catching fish. Fruitafossor , from the late Jurassic Period about 150 million years ago,

3410-594: The underlying Paleozoic New England Orogen basement. It consists of continental deposits, starting with a small amount of Triassic coal beds, and then mostly Jurassic and Cretaceous sedimentary rocks. The basin covers 16,000 square kilometres (6,200 sq mi). The basin was named when the Clarence Basin (named after the Clarence River ) and Moreton Basin in Queensland were proved to be one structure. Oil

3472-531: Was about the size of a chipmunk, and its teeth, forelimbs and back suggest that it dug open the nests of social insects (probably termites , as ants had not yet appeared) ; Volaticotherium was able to glide for short distances, such as modern flying squirrels . The first multituberculates such as Rugosodon evolved. The Middle Jurassic spans from 175 to 163 million years ago. During this epoch, dinosaurs flourished as huge herds of sauropods, such as Brachiosaurus and Diplodocus , filled

3534-877: Was comparatively mild. The sole major Mesozoic orogeny occurred in what is now the Arctic , creating the Innuitian orogeny , the Brooks Range , the Verkhoyansk and Cherskiy Ranges in Siberia, and the Khingan Mountains in Manchuria. This orogeny was related to the opening of the Arctic Ocean and suturing of the North China and Siberian cratons to Asia. In contrast, the era featured

3596-523: Was distant from its shores, temperatures fluctuated greatly, and the interior probably included expansive deserts . Abundant red beds and evaporites such as halite support these conclusions, but some evidence suggests the generally dry climate of the Triassic was punctuated by episodes of increased rainfall. The most important humid episodes were the Carnian Pluvial Event and one in the Rhaetian ,

3658-533: Was dominated by deserts in the interior of the Pangaea supercontinent. The Earth had just witnessed a massive die-off in which 95% of all life became extinct, and the most common vertebrate life on land were Lystrosaurus , labyrinthodonts , and Euparkeria along with many other creatures that managed to survive the Permian extinction. Temnospondyls reached peak diversity during the early Triassic. The Middle Triassic, from 247 to 237 million years ago, featured

3720-693: Was likely meteoric iron , and hematite was far easier to smelt , in Africa, where the first evidence of iron metallurgy occurs, limonite is the most prevalent iron ore. Before smelting, as the ore was heated and the water driven off, more and more of the limonite was converted to hematite. The ore was then pounded as it was heated above 1250 °C, at which temperature the metallic iron begins sticking together and non-metallic impurities are thrown off as sparks. Complex systems developed, notably in Tanzania, to process limonite. Nonetheless, hematite and magnetite remained

3782-578: Was still dominated by cycads and ferns until after the Cretaceous–Paleogene extinction. Some plant species had distributions that were markedly different from succeeding periods; for example, the Schizeales , a fern order, were skewed to the Northern Hemisphere in the Mesozoic, but are now better represented in the Southern Hemisphere. The extinction of nearly all animal species at the end of

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3844-485: Was the height of archosaur diversity, and the first birds and eutherian mammals also appeared. Some have argued that insects diversified in symbiosis with angiosperms, because insect anatomy , especially the mouth parts, seems particularly well-suited for flowering plants. However, all major insect mouth parts preceded angiosperms, and insect diversification actually slowed when they arrived, so their anatomy originally must have been suited for some other purpose. At

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