94-448: 1-(3,4-Methylenedioxybenzyl)piperazine ( MDBZP , piperonylpiperazine ) is a chemical compound of the piperazine chemical class related to benzylpiperazine (BZP). MDBZP has been sold as a designer drug and has even been found as an ingredient in street Ecstasy pills. This drug article relating to the nervous system is a stub . You can help Misplaced Pages by expanding it . Chemical compound A chemical compound
188-424: A chemical compound ; the concept is most readily understood when considering pure chemical substances . It follows from their being composed of fixed proportions of two or more types of atoms that chemical compounds can be converted, via chemical reaction , into compounds or substances each having fewer atoms. A chemical formula is a way of expressing information about the proportions of atoms that constitute
282-419: A solid-state reaction , or the electron transfer reaction of reactive metals with reactive non-metals, such as halogen gases. Ionic compounds typically have high melting and boiling points , and are hard and brittle . As solids they are almost always electrically insulating , but when melted or dissolved they become highly conductive , because the ions are mobilized. An intermetallic compound
376-466: A ... white Powder ... with Sulphur it will compose a blood-red and volatile Cinaber. And yet out of all these exotick Compounds, we may recover the very same running Mercury. Boyle used the concept of "corpuscles"—or "atomes", as he also called them—to explain how a limited number of elements could combine into a vast number of compounds: If we assigne to the Corpuscles, whereof each Element consists,
470-530: A compound molecule, using the standard chemical symbols with numerical subscripts . Many chemical compounds have a unique CAS number identifier assigned by the Chemical Abstracts Service . Globally, more than 350,000 chemical compounds (including mixtures of chemicals) have been registered for production and use. The term "compound"—with a meaning similar to the modern—has been used at least since 1661 when Robert Boyle's The Sceptical Chymist
564-412: A continuous three-dimensional network, usually in a crystalline structure . Ionic compounds containing basic ions hydroxide (OH ) or oxide (O ) are classified as bases. Ionic compounds without these ions are also known as salts and can be formed by acid–base reactions . Ionic compounds can also be produced from their constituent ions by evaporation of their solvent , precipitation , freezing ,
658-410: A deficit or a surplus of electrons are called ions . Electrons that are farthest from the nucleus may be transferred to other nearby atoms or shared between atoms. By this mechanism, atoms are able to bond into molecules and other types of chemical compounds like ionic and covalent network crystals . By definition, any two atoms with an identical number of protons in their nuclei belong to
752-463: A different chemical composition by interaction with a second chemical compound via a chemical reaction . In this process, bonds between atoms are broken in both of the interacting compounds, and then bonds are reformed so that new associations are made between atoms. Schematically, this reaction could be described as AB + CD → AD + CB , where A, B, C, and D are each unique atoms; and AB, AD, CD, and CB are each unique compounds. Atom Atoms are
846-422: A different way, is internal conversion —a process that produces high-speed electrons that are not beta rays, followed by production of high-energy photons that are not gamma rays. A few large nuclei explode into two or more charged fragments of varying masses plus several neutrons, in a decay called spontaneous nuclear fission . Each radioactive isotope has a characteristic decay time period—the half-life —that
940-456: A finite set of orbits, and could jump between these orbits only in discrete changes of energy corresponding to absorption or radiation of a photon. This quantization was used to explain why the electrons' orbits are stable and why elements absorb and emit electromagnetic radiation in discrete spectra. Bohr's model could only predict the emission spectra of hydrogen, not atoms with more than one electron. Back in 1815, William Prout observed that
1034-529: A form of light but made of negatively charged particles because they can be deflected by electric and magnetic fields. He measured these particles to be at least a thousand times lighter than hydrogen (the lightest atom). He called these new particles corpuscles but they were later renamed electrons since these are the particles that carry electricity. Thomson also showed that electrons were identical to particles given off by photoelectric and radioactive materials. Thomson explained that an electric current
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#17331164336331128-419: A fractional electric charge. Protons are composed of two up quarks (each with charge + 2 / 3 ) and one down quark (with a charge of − 1 / 3 ). Neutrons consist of one up quark and two down quarks. This distinction accounts for the difference in mass and charge between the two particles. The quarks are held together by the strong interaction (or strong force), which
1222-484: A given accuracy in measuring a position one could only obtain a range of probable values for momentum, and vice versa. Thus, the planetary model of the atom was discarded in favor of one that described atomic orbital zones around the nucleus where a given electron is most likely to be found. This model was able to explain observations of atomic behavior that previous models could not, such as certain structural and spectral patterns of atoms larger than hydrogen. Though
1316-451: A mathematical function that characterises the probability that an electron appears to be at a particular location when its position is measured. Only a discrete (or quantized ) set of these orbitals exist around the nucleus, as other possible wave patterns rapidly decay into a more stable form. Orbitals can have one or more ring or node structures, and differ from each other in size, shape and orientation. Each atomic orbital corresponds to
1410-415: A particular energy level of the electron. The electron can change its state to a higher energy level by absorbing a photon with sufficient energy to boost it into the new quantum state. Likewise, through spontaneous emission , an electron in a higher energy state can drop to a lower energy state while radiating the excess energy as a photon. These characteristic energy values, defined by the differences in
1504-566: A particular chemical compound, using chemical symbols for the chemical elements, and subscripts to indicate the number of atoms involved. For example, water is composed of two hydrogen atoms bonded to one oxygen atom: the chemical formula is H 2 O. In the case of non-stoichiometric compounds , the proportions may be reproducible with regard to their preparation, and give fixed proportions of their component elements, but proportions that are not integral [e.g., for palladium hydride , PdH x (0.02 < x < 0.58)]. Chemical compounds have
1598-796: A peculiar size and shape ... such ... Corpuscles may be mingled in such various Proportions, and ... connected so many ... wayes, that an almost incredible number of ... Concretes may be compos’d of them. In his Logick , published in 1724, the English minister and logician Isaac Watts gave an early definition of chemical element, and contrasted element with chemical compound in clear, modern terms. Among Substances, some are called Simple, some are Compound ... Simple Substances ... are usually called Elements, of which all other Bodies are compounded: Elements are such Substances as cannot be resolved, or reduced, into two or more Substances of different Kinds. ... Followers of Aristotle made Fire, Air, Earth and Water to be
1692-496: A positively charged cation . The nonmetal will gain the electrons from the metal, making the nonmetal a negatively charged anion . As outlined, ionic bonds occur between an electron donor, usually a metal, and an electron acceptor, which tends to be a nonmetal. Hydrogen bonding occurs when a hydrogen atom bonded to an electronegative atom forms an electrostatic connection with another electronegative atom through interacting dipoles or charges. A compound can be converted to
1786-547: A series of experiments in which they bombarded thin foils of metal with a beam of alpha particles . They did this to measure the scattering patterns of the alpha particles. They spotted a small number of alpha particles being deflected by angles greater than 90°. This shouldn't have been possible according to the Thomson model of the atom, whose charges were too diffuse to produce a sufficiently strong electric field. The deflections should have all been negligible. Rutherford proposed that
1880-519: A set of atomic numbers, from the single-proton element hydrogen up to the 118-proton element oganesson . All known isotopes of elements with atomic numbers greater than 82 are radioactive, although the radioactivity of element 83 ( bismuth ) is so slight as to be practically negligible. About 339 nuclides occur naturally on Earth , of which 251 (about 74%) have not been observed to decay, and are referred to as " stable isotopes ". Only 90 nuclides are stable theoretically , while another 161 (bringing
1974-472: A short-ranged attractive potential called the residual strong force . At distances smaller than 2.5 fm this force is much more powerful than the electrostatic force that causes positively charged protons to repel each other. Atoms of the same element have the same number of protons, called the atomic number . Within a single element, the number of neutrons may vary, determining the isotope of that element. The total number of protons and neutrons determine
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#17331164336332068-440: A size that is too small to be measured using available techniques. It was the lightest particle with a positive rest mass measured, until the discovery of neutrino mass. Under ordinary conditions, electrons are bound to the positively charged nucleus by the attraction created from opposite electric charges. If an atom has more or fewer electrons than its atomic number, then it becomes respectively negatively or positively charged as
2162-447: A solid state dependent on how low the temperature of the environment is. A covalent bond , also known as a molecular bond, involves the sharing of electrons between two atoms. Primarily, this type of bond occurs between elements that fall close to each other on the periodic table of elements , yet it is observed between some metals and nonmetals. This is due to the mechanism of this type of bond. Elements that fall close to each other on
2256-432: A tiny atomic nucleus , and are collectively called nucleons . The radius of a nucleus is approximately equal to 1.07 A 3 {\displaystyle 1.07{\sqrt[{3}]{A}}} femtometres , where A {\displaystyle A} is the total number of nucleons. This is much smaller than the radius of the atom, which is on the order of 10 fm. The nucleons are bound together by
2350-469: A unique and defined chemical structure held together in a defined spatial arrangement by chemical bonds . Chemical compounds can be molecular compounds held together by covalent bonds , salts held together by ionic bonds , intermetallic compounds held together by metallic bonds , or the subset of chemical complexes that are held together by coordinate covalent bonds . Pure chemical elements are generally not considered chemical compounds, failing
2444-434: A whole. If an atom has more electrons than protons, then it has an overall negative charge, and is called a negative ion (or anion). Conversely, if it has more protons than electrons, it has a positive charge, and is called a positive ion (or cation). The electrons of an atom are attracted to the protons in an atomic nucleus by the electromagnetic force . The protons and neutrons in the nucleus are attracted to each other by
2538-470: A whole; a charged atom is called an ion . Electrons have been known since the late 19th century, mostly thanks to J.J. Thomson ; see history of subatomic physics for details. Protons have a positive charge and a mass of 1.6726 × 10 kg . The number of protons in an atom is called its atomic number . Ernest Rutherford (1919) observed that nitrogen under alpha-particle bombardment ejects what appeared to be hydrogen nuclei. By 1920 he had accepted that
2632-499: Is 29.5% nitrogen and 70.5% oxygen. Adjusting these figures, in nitrous oxide there is 80 g of oxygen for every 140 g of nitrogen, in nitric oxide there is about 160 g of oxygen for every 140 g of nitrogen, and in nitrogen dioxide there is 320 g of oxygen for every 140 g of nitrogen. 80, 160, and 320 form a ratio of 1:2:4. The respective formulas for these oxides are N 2 O , NO , and NO 2 . In 1897, J. J. Thomson discovered that cathode rays are not
2726-427: Is 88.1% tin and 11.9% oxygen, and the other is a white powder that is 78.7% tin and 21.3% oxygen. Adjusting these figures, in the grey powder there is about 13.5 g of oxygen for every 100 g of tin, and in the white powder there is about 27 g of oxygen for every 100 g of tin. 13.5 and 27 form a ratio of 1:2. Dalton concluded that in the grey oxide there is one atom of oxygen for every atom of tin, and in
2820-541: Is a chemical substance composed of many identical molecules (or molecular entities ) containing atoms from more than one chemical element held together by chemical bonds . A molecule consisting of atoms of only one element is therefore not a compound. A compound can be transformed into a different substance by a chemical reaction , which may involve interactions with other substances. In this process, bonds between atoms may be broken and/or new bonds formed. There are four major types of compounds, distinguished by how
2914-408: Is a measure of the distance out to which the electron cloud extends from the nucleus. This assumes the atom to exhibit a spherical shape, which is only obeyed for atoms in vacuum or free space. Atomic radii may be derived from the distances between two nuclei when the two atoms are joined in a chemical bond . The radius varies with the location of an atom on the atomic chart, the type of chemical bond,
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3008-403: Is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. They can be classified as stoichiometric or nonstoichiometric intermetallic compounds. A coordination complex consists of a central atom or ion, which is usually metallic and is called
3102-573: Is affected by the ratio of protons to neutrons, and also by the presence of certain "magic numbers" of neutrons or protons that represent closed and filled quantum shells. These quantum shells correspond to a set of energy levels within the shell model of the nucleus; filled shells, such as the filled shell of 50 protons for tin, confers unusual stability on the nuclide. Of the 251 known stable nuclides, only four have both an odd number of protons and odd number of neutrons: hydrogen-2 ( deuterium ), lithium-6 , boron-10 , and nitrogen-14 . ( Tantalum-180m
3196-438: Is higher than its proton number, so Rutherford hypothesized that the surplus weight was carried by unknown particles with no electric charge and a mass equal to that of the proton. In 1928, Walter Bothe observed that beryllium emitted a highly penetrating, electrically neutral radiation when bombarded with alpha particles. It was later discovered that this radiation could knock hydrogen atoms out of paraffin wax . Initially it
3290-429: Is mediated by gluons . The protons and neutrons, in turn, are held to each other in the nucleus by the nuclear force , which is a residuum of the strong force that has somewhat different range-properties (see the article on the nuclear force for more). The gluon is a member of the family of gauge bosons , which are elementary particles that mediate physical forces. All the bound protons and neutrons in an atom make up
3384-493: Is neutral overall, but consists of positively charged ions called cations and negatively charged ions called anions . These can be simple ions such as the sodium (Na ) and chloride (Cl ) in sodium chloride , or polyatomic species such as the ammonium ( NH 4 ) and carbonate ( CO 3 ) ions in ammonium carbonate . Individual ions within an ionic compound usually have multiple nearest neighbours, so are not considered to be part of molecules, but instead part of
3478-481: Is not based on these old concepts. In the early 19th century, the scientist John Dalton found evidence that matter really is composed of discrete units, and so applied the word atom to those units. In the early 1800s, John Dalton compiled experimental data gathered by him and other scientists and discovered a pattern now known as the " law of multiple proportions ". He noticed that in any group of chemical compounds which all contain two particular chemical elements,
3572-425: Is not possible due to quantum effects . More than 99.9994% of an atom's mass is in the nucleus. Protons have a positive electric charge and neutrons have no charge, so the nucleus is positively charged. The electrons are negatively charged, and this opposing charge is what binds them to the nucleus. If the numbers of protons and electrons are equal, as they normally are, then the atom is electrically neutral as
3666-502: Is odd-odd and observationally stable, but is predicted to decay with a very long half-life.) Also, only four naturally occurring, radioactive odd-odd nuclides have a half-life over a billion years: potassium-40 , vanadium-50 , lanthanum-138 , and lutetium-176 . Most odd-odd nuclei are highly unstable with respect to beta decay , because the decay products are even-even, and are therefore more strongly bound, due to nuclear pairing effects . The large majority of an atom's mass comes from
3760-477: Is required to bring them together. It is this energy-releasing process that makes nuclear fusion in stars a self-sustaining reaction. For heavier nuclei, the binding energy per nucleon begins to decrease. That means that a fusion process producing a nucleus that has an atomic number higher than about 26, and a mass number higher than about 60, is an endothermic process . Thus, more massive nuclei cannot undergo an energy-producing fusion reaction that can sustain
3854-455: Is responsible for most of the physical changes observed in nature. Chemistry is the science that studies these changes. The basic idea that matter is made up of tiny indivisible particles is an old idea that appeared in many ancient cultures. The word atom is derived from the ancient Greek word atomos , which means "uncuttable". But this ancient idea was based in philosophical reasoning rather than scientific reasoning. Modern atomic theory
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3948-421: Is that an accelerating charged particle radiates electromagnetic radiation, causing the particle to lose kinetic energy. Circular motion counts as acceleration, which means that an electron orbiting a central charge should spiral down into that nucleus as it loses speed. In 1913, the physicist Niels Bohr proposed a new model in which the electrons of an atom were assumed to orbit the nucleus but could only do so in
4042-470: Is the mass loss and c is the speed of light . This deficit is part of the binding energy of the new nucleus, and it is the non-recoverable loss of the energy that causes the fused particles to remain together in a state that requires this energy to separate. The fusion of two nuclei that create larger nuclei with lower atomic numbers than iron and nickel —a total nucleon number of about 60—is usually an exothermic process that releases more energy than
4136-460: Is the passing of electrons from one atom to the next, and when there was no current the electrons embedded themselves in the atoms. This in turn meant that atoms were not indivisible as scientists thought. The atom was composed of electrons whose negative charge was balanced out by some source of positive charge to create an electrically neutral atom. Ions, Thomson explained, must be atoms which have an excess or shortage of electrons. The electrons in
4230-485: The Schroedinger equation , which describes electrons as three-dimensional waveforms rather than points in space. A consequence of using waveforms to describe particles is that it is mathematically impossible to obtain precise values for both the position and momentum of a particle at a given point in time. This became known as the uncertainty principle , formulated by Werner Heisenberg in 1927. In this concept, for
4324-452: The coordination centre , and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those of transition metals , are coordination complexes. A coordination complex whose centre is a metal atom is called a metal complex of d block element. Compounds are held together through a variety of different types of bonding and forces. The differences in
4418-438: The hydrostatic equilibrium of a star. The electrons in an atom are attracted to the protons in the nucleus by the electromagnetic force . This force binds the electrons inside an electrostatic potential well surrounding the smaller nucleus, which means that an external source of energy is needed for the electron to escape. The closer an electron is to the nucleus, the greater the attractive force. Hence electrons bound near
4512-547: The nuclear force . This force is usually stronger than the electromagnetic force that repels the positively charged protons from one another. Under certain circumstances, the repelling electromagnetic force becomes stronger than the nuclear force. In this case, the nucleus splits and leaves behind different elements . This is a form of nuclear decay . Atoms can attach to one or more other atoms by chemical bonds to form chemical compounds such as molecules or crystals . The ability of atoms to attach and detach from each other
4606-468: The nuclide . The number of neutrons relative to the protons determines the stability of the nucleus, with certain isotopes undergoing radioactive decay . The proton, the electron, and the neutron are classified as fermions . Fermions obey the Pauli exclusion principle which prohibits identical fermions, such as multiple protons, from occupying the same quantum state at the same time. Thus, every proton in
4700-449: The oxygen molecule (O 2 ); or it may be heteronuclear , a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H 2 O). A molecule is the smallest unit of a substance that still carries all the physical and chemical properties of that substance. An ionic compound is a chemical compound composed of ions held together by electrostatic forces termed ionic bonding . The compound
4794-455: The 'surface' of these particles is not sharply defined. The neutron was discovered in 1932 by the English physicist James Chadwick . In the Standard Model of physics, electrons are truly elementary particles with no internal structure, whereas protons and neutrons are composite particles composed of elementary particles called quarks . There are two types of quarks in atoms, each having
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#17331164336334888-459: The Earth. Other compounds regarded as chemically identical may have varying amounts of heavy or light isotopes of the constituent elements, which changes the ratio of elements by mass slightly. A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. A molecule may be homonuclear , that is, it consists of atoms of one chemical element, as with two atoms in
4982-524: The Truth ;; tho' they are not all agreed ... Compound Substances are made up of two or more simple Substances ... So a Needle is simple Body, being made only of Steel; but a Sword or a Knife is a compound because its ... Handle is made of Materials different from the Blade. Any substance consisting of two or more different types of atoms ( chemical elements ) in a fixed stoichiometric proportion can be termed
5076-399: The amount of Element A per measure of Element B will differ across these compounds by ratios of small whole numbers. This pattern suggested that each element combines with other elements in multiples of a basic unit of weight, with each element having a unit of unique weight. Dalton decided to call these units "atoms". For example, there are two types of tin oxide : one is a grey powder that
5170-444: The atom logically had to be balanced out by a commensurate amount of positive charge, but Thomson had no idea where this positive charge came from, so he tentatively proposed that it was everywhere in the atom, the atom being in the shape of a sphere. This was the mathematically simplest hypothesis to fit the available evidence, or lack thereof. Following from this, Thomson imagined that the balance of electrostatic forces would distribute
5264-422: The atomic mass unit (for example the mass of a nitrogen-14 is roughly 14 Da), but this number will not be exactly an integer except (by definition) in the case of carbon-12. The heaviest stable atom is lead-208, with a mass of 207.976 6521 Da . As even the most massive atoms are far too light to work with directly, chemists instead use the unit of moles . One mole of atoms of any element always has
5358-491: The atomic weights of many elements were multiples of hydrogen's atomic weight, which is in fact true for all of them if one takes isotopes into account. In 1898, J. J. Thomson found that the positive charge of a hydrogen ion is equal to the negative charge of an electron, and these were then the smallest known charged particles. Thomson later found that the positive charge in an atom is a positive multiple of an electron's negative charge. In 1913, Henry Moseley discovered that
5452-412: The basic particles of the chemical elements . An atom consists of a nucleus of protons and generally neutrons , surrounded by an electromagnetically bound swarm of electrons . The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium , and any atom that contains 29 protons is copper . Atoms with
5546-413: The center of the potential well require more energy to escape than those at greater separations. Electrons, like other particles, have properties of both a particle and a wave . The electron cloud is a region inside the potential well where each electron forms a type of three-dimensional standing wave —a wave form that does not move relative to the nucleus. This behavior is defined by an atomic orbital ,
5640-478: The chemical elements, at least one stable isotope exists. As a rule, there is only a handful of stable isotopes for each of these elements, the average being 3.1 stable isotopes per element. Twenty-six " monoisotopic elements " have only a single stable isotope, while the largest number of stable isotopes observed for any element is ten, for the element tin . Elements 43 , 61 , and all elements numbered 83 or higher have no stable isotopes. Stability of isotopes
5734-431: The constituent atoms are bonded together. Molecular compounds are held together by covalent bonds ; ionic compounds are held together by ionic bonds ; intermetallic compounds are held together by metallic bonds ; coordination complexes are held together by coordinate covalent bonds . Non-stoichiometric compounds form a disputed marginal case. A chemical formula specifies the number of atoms of each element in
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#17331164336335828-450: The core of the Sun protons require energies of 3 to 10 keV to overcome their mutual repulsion—the coulomb barrier —and fuse together into a single nucleus. Nuclear fission is the opposite process, causing a nucleus to split into two smaller nuclei—usually through radioactive decay. The nucleus can also be modified through bombardment by high energy subatomic particles or photons. If this modifies
5922-512: The electrons throughout the sphere in a more or less even manner. Thomson's model is popularly known as the plum pudding model , though neither Thomson nor his colleagues used this analogy. Thomson's model was incomplete, it was unable to predict any other properties of the elements such as emission spectra and valencies . It was soon rendered obsolete by the discovery of the atomic nucleus . Between 1908 and 1913, Ernest Rutherford and his colleagues Hans Geiger and Ernest Marsden performed
6016-506: The energies of the quantum states, are responsible for atomic spectral lines . The amount of energy needed to remove or add an electron—the electron binding energy —is far less than the binding energy of nucleons . For example, it requires only 13.6 eV to strip a ground-state electron from a hydrogen atom, compared to 2.23 million eV for splitting a deuterium nucleus. Atoms are electrically neutral if they have an equal number of protons and electrons. Atoms that have either
6110-665: The energies of the recoiling charged particles, he deduced that the radiation was actually composed of electrically neutral particles which could not be massless like the gamma ray, but instead were required to have a mass similar to that of a proton. Chadwick now claimed these particles as Rutherford's neutrons. In 1925, Werner Heisenberg published the first consistent mathematical formulation of quantum mechanics ( matrix mechanics ). One year earlier, Louis de Broglie had proposed that all particles behave like waves to some extent, and in 1926 Erwin Schroedinger used this idea to develop
6204-400: The fixed ratios. Many solid chemical substances—for example many silicate minerals —are chemical substances, but do not have simple formulae reflecting chemically bonding of elements to one another in fixed ratios; even so, these crystalline substances are often called " non-stoichiometric compounds ". It may be argued that they are related to, rather than being chemical compounds, insofar as
6298-508: The four Elements, of which all earthly Things were compounded; and they suppos'd the Heavens to be a Quintessence, or fifth sort of Body, distinct from all these : But, since experimental Philosophy ... have been better understood, this Doctrine has been abundantly refuted. The Chymists make Spirit, Salt, Sulphur, Water and Earth to be their five Elements, because they can reduce all terrestrial Things to these five : This seems to come nearer
6392-433: The frequencies of X-ray emissions from an excited atom were a mathematical function of its atomic number and hydrogen's nuclear charge. In 1919 Rutherford bombarded nitrogen gas with alpha particles and detected hydrogen ions being emitted from the gas, and concluded that they were produced by alpha particles hitting and splitting the nuclei of the nitrogen atoms. These observations led Rutherford to conclude that
6486-416: The hydrogen nucleus is a distinct particle within the atom and named it proton . Neutrons have no electrical charge and have a mass of 1.6749 × 10 kg . Neutrons are the heaviest of the three constituent particles, but their mass can be reduced by the nuclear binding energy . Neutrons and protons (collectively known as nucleons ) have comparable dimensions—on the order of 2.5 × 10 m —although
6580-445: The hydrogen nucleus is a singular particle with a positive charge equal to the electron's negative charge. He named this particle " proton " in 1920. The number of protons in an atom (which Rutherford called the " atomic number " ) was found to be equal to the element's ordinal number on the periodic table and therefore provided a simple and clear-cut way of distinguishing the elements from each other. The atomic weight of each element
6674-432: The mutual repulsion of the protons requires an increasing proportion of neutrons to maintain the stability of the nucleus. The number of protons and neutrons in the atomic nucleus can be modified, although this can require very high energies because of the strong force. Nuclear fusion occurs when multiple atomic particles join to form a heavier nucleus, such as through the energetic collision of two nuclei. For example, at
6768-509: The nucleus must occupy a quantum state different from all other protons, and the same applies to all neutrons of the nucleus and to all electrons of the electron cloud. A nucleus that has a different number of protons than neutrons can potentially drop to a lower energy state through a radioactive decay that causes the number of protons and neutrons to more closely match. As a result, atoms with matching numbers of protons and neutrons are more stable against decay, but with increasing atomic number,
6862-515: The nucleus to emit particles or electromagnetic radiation. Radioactivity can occur when the radius of a nucleus is large compared with the radius of the strong force, which only acts over distances on the order of 1 fm. The most common forms of radioactive decay are: Other more rare types of radioactive decay include ejection of neutrons or protons or clusters of nucleons from a nucleus, or more than one beta particle . An analog of gamma emission which allows excited nuclei to lose energy in
6956-401: The number of hydrogen atoms. A single carat diamond with a mass of 2 × 10 kg contains about 10 sextillion (10 ) atoms of carbon . If an apple were magnified to the size of the Earth, then the atoms in the apple would be approximately the size of the original apple. Every element has one or more isotopes that have unstable nuclei that are subject to radioactive decay, causing
7050-450: The number of neighboring atoms ( coordination number ) and a quantum mechanical property known as spin . On the periodic table of the elements, atom size tends to increase when moving down columns, but decrease when moving across rows (left to right). Consequently, the smallest atom is helium with a radius of 32 pm , while one of the largest is caesium at 225 pm. When subjected to external forces, like electrical fields ,
7144-451: The number of protons in a nucleus, the atom changes to a different chemical element. If the mass of the nucleus following a fusion reaction is less than the sum of the masses of the separate particles, then the difference between these two values can be emitted as a type of usable energy (such as a gamma ray , or the kinetic energy of a beta particle ), as described by Albert Einstein 's mass–energy equivalence formula, E=mc , where m
7238-536: The periodic table tend to have similar electronegativities , which means they have a similar affinity for electrons. Since neither element has a stronger affinity to donate or gain electrons, it causes the elements to share electrons so both elements have a more stable octet . Ionic bonding occurs when valence electrons are completely transferred between elements. Opposite to covalent bonding, this chemical bond creates two oppositely charged ions. The metals in ionic bonding usually lose their valence electrons, becoming
7332-435: The positive charge of the atom is concentrated in a tiny volume at the center of the atom and that the electrons surround this nucleus in a diffuse cloud. This nucleus carried almost all of the atom's mass, the electrons being so very light. Only such an intense concentration of charge, anchored by its high mass, could produce an electric field that could deflect the alpha particles so strongly. A problem in classical mechanics
7426-448: The protons and neutrons that make it up. The total number of these particles (called "nucleons") in a given atom is called the mass number . It is a positive integer and dimensionless (instead of having dimension of mass), because it expresses a count. An example of use of a mass number is "carbon-12," which has 12 nucleons (six protons and six neutrons). The actual mass of an atom at rest is often expressed in daltons (Da), also called
7520-421: The red powder there is about 42 g of oxygen for every 100 g of iron. 28 and 42 form a ratio of 2:3. Dalton concluded that in these oxides, for every two atoms of iron, there are two or three atoms of oxygen respectively ( Fe 2 O 2 and Fe 2 O 3 ). As a final example: nitrous oxide is 63.3% nitrogen and 36.7% oxygen, nitric oxide is 44.05% nitrogen and 55.95% oxygen, and nitrogen dioxide
7614-412: The same chemical element . Atoms with equal numbers of protons but a different number of neutrons are different isotopes of the same element. For example, all hydrogen atoms admit exactly one proton, but isotopes exist with no neutrons ( hydrogen-1 , by far the most common form, also called protium), one neutron ( deuterium ), two neutrons ( tritium ) and more than two neutrons . The known elements form
7708-498: The same number of atoms (about 6.022 × 10 ). This number was chosen so that if an element has an atomic mass of 1 u, a mole of atoms of that element has a mass close to one gram. Because of the definition of the unified atomic mass unit , each carbon-12 atom has an atomic mass of exactly 12 Da, and so a mole of carbon-12 atoms weighs exactly 0.012 kg. Atoms lack a well-defined outer boundary, so their dimensions are usually described in terms of an atomic radius . This
7802-448: The same number of protons but a different number of neutrons are called isotopes of the same element. Atoms are extremely small, typically around 100 picometers across. A human hair is about a million carbon atoms wide. Atoms are smaller than the shortest wavelength of visible light, which means humans cannot see atoms with conventional microscopes. They are so small that accurately predicting their behavior using classical physics
7896-539: The shape of an atom may deviate from spherical symmetry . The deformation depends on the field magnitude and the orbital type of outer shell electrons, as shown by group-theoretical considerations. Aspherical deviations might be elicited for instance in crystals , where large crystal-electrical fields may occur at low-symmetry lattice sites. Significant ellipsoidal deformations have been shown to occur for sulfur ions and chalcogen ions in pyrite -type compounds. Atomic dimensions are thousands of times smaller than
7990-731: The total to 251) have not been observed to decay, even though in theory it is energetically possible. These are also formally classified as "stable". An additional 35 radioactive nuclides have half-lives longer than 100 million years, and are long-lived enough to have been present since the birth of the Solar System . This collection of 286 nuclides are known as primordial nuclides . Finally, an additional 53 short-lived nuclides are known to occur naturally, as daughter products of primordial nuclide decay (such as radium from uranium ), or as products of natural energetic processes on Earth, such as cosmic ray bombardment (for example, carbon-14). For 80 of
8084-494: The two or more atom requirement, though they often consist of molecules composed of multiple atoms (such as in the diatomic molecule H 2 , or the polyatomic molecule S 8 , etc.). Many chemical compounds have a unique numerical identifier assigned by the Chemical Abstracts Service (CAS): its CAS number . There is varying and sometimes inconsistent nomenclature differentiating substances, which include truly non-stoichiometric examples, from chemical compounds, which require
8178-455: The types of bonds in compounds differ based on the types of elements present in the compound. London dispersion forces are the weakest force of all intermolecular forces . They are temporary attractive forces that form when the electrons in two adjacent atoms are positioned so that they create a temporary dipole . Additionally, London dispersion forces are responsible for condensing non polar substances to liquids, and to further freeze to
8272-445: The unified atomic mass unit (u). This unit is defined as a twelfth of the mass of a free neutral atom of carbon-12 , which is approximately 1.66 × 10 kg . Hydrogen-1 (the lightest isotope of hydrogen which is also the nuclide with the lowest mass) has an atomic weight of 1.007825 Da. The value of this number is called the atomic mass . A given atom has an atomic mass approximately equal (within 1%) to its mass number times
8366-421: The variability in their compositions is often due to either the presence of foreign elements trapped within the crystal structure of an otherwise known true chemical compound , or due to perturbations in structure relative to the known compound that arise because of an excess of deficit of the constituent elements at places in its structure; such non-stoichiometric substances form most of the crust and mantle of
8460-406: The wavelengths of light (400–700 nm ) so they cannot be viewed using an optical microscope , although individual atoms can be observed using a scanning tunneling microscope . To visualize the minuteness of the atom, consider that a typical human hair is about 1 million carbon atoms in width. A single drop of water contains about 2 sextillion ( 2 × 10 ) atoms of oxygen, and twice
8554-432: The white oxide there are two atoms of oxygen for every atom of tin ( SnO and SnO 2 ). Dalton also analyzed iron oxides . There is one type of iron oxide that is a black powder which is 78.1% iron and 21.9% oxygen; and there is another iron oxide that is a red powder which is 70.4% iron and 29.6% oxygen. Adjusting these figures, in the black powder there is about 28 g of oxygen for every 100 g of iron, and in
8648-407: The word atom originally denoted a particle that cannot be cut into smaller particles, in modern scientific usage the atom is composed of various subatomic particles . The constituent particles of an atom are the electron , the proton and the neutron . The electron is the least massive of these particles by four orders of magnitude at 9.11 × 10 kg , with a negative electrical charge and
8742-409: Was published. In this book, Boyle variously used the terms "compound", "compounded body", "perfectly mixt body", and "concrete". "Perfectly mixt bodies" included for example gold, lead, mercury, and wine. While the distinction between compound and mixture is not so clear, the distinction between element and compound is a central theme. Quicksilver ... with Aqua fortis will be brought into
8836-432: Was thought to be high-energy gamma radiation , since gamma radiation had a similar effect on electrons in metals, but James Chadwick found that the ionization effect was too strong for it to be due to electromagnetic radiation, so long as energy and momentum were conserved in the interaction. In 1932, Chadwick exposed various elements, such as hydrogen and nitrogen, to the mysterious "beryllium radiation", and by measuring
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