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Hirnantian Isotopic Carbon Excursion

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The Hirnantian Isotopic Carbon Excursion (HICE) is a positive carbon isotope excursion which took place at the end of the Ordovician period, during the Hirnantian Age from around 445.2 Ma to 443.8 Ma (million years ago). The HICE is connected to a large scale, but short glaciation, as well as the End Ordovician mass extinction , which wiped out 85% of marine life. The exact cause of the HICE is still debated, however it is a key event for defining the Ordovician-Silurian boundary.

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32-565: The HICE is widely recognized as short in terms of geologic time, but just how short is still debated. The current official timing of the Hirnantian, and thus the HICE, in the geologic record according to the International Commission on Stratigraphy is 445.2 (±1.3) Ma to 443.8 (± 1.5). Another proposed date for the HICE is 443.14 (± 0.24) Ma to 442.67 Ma (± 0.34). Major uncertainty over the age

64-759: A global scale. It is the largest subordinate body of the International Union of Geological Sciences (IUGS). The ICS is essentially a permanent working subcommittee , which meets far more regularly than the quadrennial meetings scheduled by the IUGS, when it meets as a congress or membership of the whole . One of its main aims, a project begun in 1974, is to establish a multidisciplinary standard and global geologic time scale that will ease paleontological and geobiological comparisons region to region by benchmarks with stringent and rigorous strata criteria called Global Boundary Stratotype Section and Points (GSSPs) within

96-469: A positive shift of +3-6%, although some sections show values as high as +7% or as low as +2%. Upper Husbergøya, and Lower Solvik Formations) The exact cause of the HICE is still debated, although there are 2 main hypotheses. One hypothesis states that it was primarily due to enhanced burial of carbon. High water levels and enhanced weathering in the earlier Katian Age created more space and nutrients for marine eukaryotes, which grew larger and thus sank to

128-412: A regular trend of initial deep sea rocks like shale and mudstones, then deposition of shallow limestone's during the Hirnantian. These then returned to deep shales and muds as water rose again at the end of the Hirnantian due to de-glaciation. Rocks which stayed in deep water environments during the HICE continued to deposit mudstones or shale. Most sections analyzed for carbon 13 isotope ratio’s (δ13C) show

160-436: A section. The samples are analyzed to determine their detrital remanent magnetism (DRM), that is, the polarity of Earth's magnetic field at the time a stratum was deposited. For sedimentary rocks this is possible because, as they fall through the water column, very fine-grained magnetic minerals (< 17  μm ) behave like tiny compasses , orienting themselves with Earth's magnetic field . Upon burial, that orientation

192-416: Is a branch of geology concerned with the study of rock layers ( strata ) and layering (stratification). It is primarily used in the study of sedimentary and layered volcanic rocks . Stratigraphy has three related subfields: lithostratigraphy (lithologic stratigraphy), biostratigraphy (biologic stratigraphy), and chronostratigraphy (stratigraphy by age). Catholic priest Nicholas Steno established

224-431: Is also commonly used to delineate the nature and extent of hydrocarbon -bearing reservoir rocks, seals, and traps of petroleum geology . Chronostratigraphy is the branch of stratigraphy that places an absolute age, rather than a relative age on rock strata . The branch is concerned with deriving geochronological data for rock units, both directly and inferentially, so that a sequence of time-relative events that created

256-534: Is due to physical contrasts in rock type ( lithology ). This variation can occur vertically as layering (bedding), or laterally, and reflects changes in environments of deposition (known as facies change). These variations provide a lithostratigraphy or lithologic stratigraphy of the rock unit. Key concepts in stratigraphy involve understanding how certain geometric relationships between rock layers arise and what these geometries imply about their original depositional environment. The basic concept in stratigraphy, called

288-902: Is partly due to the short time frame of both the HICE and Hirnantian age and comparatively large statistical error on these dates. Complete sections of Hirnantian age rocks outcrop primarily across the Northern Hemisphere, with notable sections in China , Scotland , Canada , the United States , Norway , and Latvia , summarized in Table 1. Due to erosion from the associated glaciation, the thickness of these sections are small, often not larger than several meters to tens to meters in thickness. Most preserved rocks are shallow water deposits, but some notable deeper water deposits exist in China. These formations mostly show

320-411: Is preserved. For volcanic rocks, magnetic minerals, which form in the melt, orient themselves with the ambient magnetic field, and are fixed in place upon crystallization of the lava. Oriented paleomagnetic core samples are collected in the field; mudstones , siltstones , and very fine-grained sandstones are the preferred lithologies because the magnetic grains are finer and more likely to orient with

352-628: The International Stratigraphic Chart , a combined working proposal and guideline-to-date released after the last ICS deliberations prior to the upcoming (next) meeting of the IUGS. Until the IUGS accepts the recommendations, they are unofficial since the IUGS parent approves or dismisses the individual deliberation reports of the ICS, which are presented as recommendations, and span dating and strata selection criteria, and related issues including nomenclatures. In de facto everyday matters,

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384-774: The Neogene System and Neogene Period. Despite the strong debate, the Quaternary saw official ratification as a geological unit from the IUGS in June 2009, placing its lower boundary to the Gelasian Stage/Age at Monte San Nicola, Sicily, Italy (until then uppermost part of the Pliocene Series/Epoch, and thus of the Neogene System/Period), 2.58 Ma BP . In addition to publishing paper and document (PDF) versions of

416-511: The Phanerozoic . The closest comparable excursion to the HICE is the Steptoean positive carbon isotope excursion (SPICE), a positive excursion of up to +5% δ13C which lasted for 2-4 million years and occurred around 295 Ma ago. Both excursions have similar proposed causes, including enhanced burial of carbon and weathering of carbonates. The two excursions are also of a similar time frame, lasting in

448-431: The law of superposition , states: in an undeformed stratigraphic sequence, the oldest strata occur at the base of the sequence. Chemostratigraphy studies the changes in the relative proportions of trace elements and isotopes within and between lithologic units. Carbon and oxygen isotope ratios vary with time, and researchers can use those to map subtle changes that occurred in the paleoenvironment. This has led to

480-547: The natural remanent magnetization (NRM) to reveal the DRM. Following statistical analysis, the results are used to generate a local magnetostratigraphic column that can then be compared against the Global Magnetic Polarity Time Scale. This technique is used to date sequences that generally lack fossils or interbedded igneous rocks. The continuous nature of the sampling means that it is also a powerful technique for

512-556: The paleontology , geology , geobiology and chronostratigraphy fields, among others. The International Commission on Stratigraphy has spawned numerous subcommittee level organizations organized and mobilized on a local country-wide or regional basis that are the true working committees of the IUGS, and these do the field work, basis comparisons in conference or co-ordination research committee meetings of local or wide-scale scope. The ICS publishes various reports and findings as well as revised references periodically, summarized in

544-453: The HICE at the start of the Hirnantian, while others are interpreted to not reach their peak until later into the age. This, along with the small section thicknesses, can make it difficult to correlate sections worldwide with one another. The HICE is far shorter and smaller in magnitude than other isotopic excursions from the earlier Precambrian , but is of a comparable to lower magnitude compared to other positive carbon isotope excursions in

576-682: The International Stratigraphic Chart, the ICS also provides a machine-readable version of the chart formulated using the Web Ontology Language (OWL) and, in particular, Time Ontology in OWL . The ICS' chart web page also provides an interactive version of the chart, based on the OWL data. The logo of International Commission on Stratigraphy was designed after the Chinese character of "mountain", 山. Stratigraphy Stratigraphy

608-588: The ambient field during deposition. If the ancient magnetic field were oriented similar to today's field ( North Magnetic Pole near the North Rotational Pole ), the strata would retain a normal polarity. If the data indicate that the North Magnetic Pole were near the South Rotational Pole , the strata would exhibit reversed polarity. Results of the individual samples are analyzed by removing

640-495: The deliberative results reported out of any meetings of the ICS are widely accepted and immediately enter everyday use, except in the rare cases where they result in a strong body of dissenting opinion, which matters are resolved before the full IUGS. One such controversy arose in 2009 when the ICS deliberated and decided that the Pliocene Series of the current but unofficially named Quaternary Period should be shifted into

672-404: The exact timing of the HICE. Biostratigraphy is often used to aid in identifying the Hirnantian, and thus the HICE, where the Hirnantian is defined as encompassing the N. extraordinarius biozone and the N. presculptus biozone. When some or entire sections of these fossils are missing, it can complicate reconstruction and correlation of sections. Some localities are interpreted to show the peak of

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704-598: The fossil record. (i.e. section of the rock record as of a core sample section or accessible exposed strata, which when a core sample are usually "trayed" in long pieces, also called "sections" about a meter in length.) Additionally the ICS defines an alternative type of benchmark and criteria called Global Standard Stratigraphic Ages (GSSAs) where the characteristics and dating criteria set solely by physical sciences methods (such as magnetic alignment sequences, radiological criteria, etcetera.) as well as encouraging an international and open debate amongst Earth scientists in

736-512: The gap may be due to removal by erosion, in which case it may be called a stratigraphic vacuity. It is called a hiatus because deposition was on hold for a period of time. A physical gap may represent both a period of non-deposition and a period of erosion. A geologic fault may cause the appearance of a hiatus. Magnetostratigraphy is a chronostratigraphic technique used to date sedimentary and volcanic sequences. The method works by collecting oriented samples at measured intervals throughout

768-487: The ocean floor more readily, burying more organic carbon in the sediments. The other hypothesis states that a cooling trend through the Katian created glacial conditions, and the retreating glaciers exposed large numbers of near-shore marine carbonates to weathering. The weathering of these carbonates pumped more carbon back into the ocean, raising the buried δ13C. Many of the deeper water sections show lower increases in δ13C than

800-437: The rock layers. Strata from widespread locations containing the same fossil fauna and flora are said to be correlatable in time. Biologic stratigraphy was based on William Smith's principle of faunal succession , which predated, and was one of the first and most powerful lines of evidence for, biological evolution . It provides strong evidence for the formation ( speciation ) and extinction of species . The geologic time scale

832-480: The rocks formation can be derived. The ultimate aim of chronostratigraphy is to place dates on the sequence of deposition of all rocks within a geological region, and then to every region, and by extension to provide an entire geologic record of the Earth. A gap or missing strata in the geological record of an area is called a stratigraphic hiatus. This may be the result of a halt in the deposition of sediment. Alternatively,

864-420: The shallow water sections. It's been proposed that the deep water rocks represent the true signal of the HICE, while the shallow water rocks show a higher value due to alteration. Aside from the cause and age, other parts of the HICE are also still debated. For example, some studies have shown that there may have been multiple cycles of sea level rise and fall within this time period. Disagreement also exists over

896-405: The significance of strata or rock layering and the importance of fossil markers for correlating strata; he created the first geologic map of England. Other influential applications of stratigraphy in the early 19th century were by Georges Cuvier and Alexandre Brongniart , who studied the geology of the region around Paris. Variation in rock units, most obviously displayed as visible layering,

928-403: The single digit millions of years. International Commission on Stratigraphy The International Commission on Stratigraphy ( ICS ), sometimes unofficially referred to as the " International Stratigraphic Commission ", is a daughter or major subcommittee grade scientific daughter organization that concerns itself with stratigraphical , geological , and geochronological matters on

960-406: The specialized field of isotopic stratigraphy. Cyclostratigraphy documents the often cyclic changes in the relative proportions of minerals (particularly carbonates ), grain size, thickness of sediment layers ( varves ) and fossil diversity with time, related to seasonal or longer term changes in palaeoclimates . Biostratigraphy or paleontologic stratigraphy is based on fossil evidence in

992-429: The theoretical basis for stratigraphy when he introduced the law of superposition , the principle of original horizontality and the principle of lateral continuity in a 1669 work on the fossilization of organic remains in layers of sediment. The first practical large-scale application of stratigraphy was by William Smith in the 1790s and early 19th century. Known as the "Father of English geology", Smith recognized

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1024-525: Was developed during the 19th century, based on the evidence of biologic stratigraphy and faunal succession. This timescale remained a relative scale until the development of radiometric dating , which was based on an absolute time framework, leading to the development of chronostratigraphy. One important development is the Vail curve , which attempts to define a global historical sea-level curve according to inferences from worldwide stratigraphic patterns. Stratigraphy

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