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121-410: Gunpowder is classified as a low explosive because of its relatively slow decomposition rate, low ignition temperature and consequently low brisance (breaking/shattering) . Low explosives deflagrate (i.e., burn at subsonic speeds), whereas high explosives detonate , producing a supersonic shockwave . Ignition of gunpowder packed behind a projectile generates enough pressure to force the shot from

242-648: A "long lance" sending forth "evil-smelling vapors and smoke", which has been variously interpreted by different historians as the "first-gas attack upon European soil" using gunpowder, "the first use of cannon in Europe", or merely a "toxic gas" with no evidence of gunpowder. It is difficult to accurately translate original Chinese alchemical texts, which tend to explain phenomena through metaphor, into modern scientific language with rigidly defined terminology in English. Early texts potentially mentioning gunpowder are sometimes marked by

363-420: A chemically pure compound, such as nitroglycerin , or a mixture of a fuel and an oxidizer , such as black powder or grain dust and air. Some chemical compounds are unstable in that, when shocked, they react, possibly to the point of detonation. Each molecule of the compound dissociates into two or more new molecules (generally gases) with the release of energy. The above compositions may describe most of

484-452: A combination of Ottoman and Mughal designs. Shah Jahan also countered the British and other Europeans in his province of Gujarāt , which supplied Europe saltpeter for use in gunpowder warfare during the 17th century. Bengal and Mālwa participated in saltpeter production. The Dutch, French, Portuguese, and English used Chhapra as a center of saltpeter refining. Ever since the founding of

605-634: A degree of water resistance. Explosives based on ammonium nitrate have little or no water resistance as ammonium nitrate is highly soluble in water and is hygroscopic. Many explosives are toxic to some extent. Manufacturing inputs can also be organic compounds or hazardous materials that require special handling due to risks (such as carcinogens ). The decomposition products, residual solids, or gases of some explosives can be toxic, whereas others are harmless, such as carbon dioxide and water. Examples of harmful by-products are: "Green explosives" seek to reduce environment and health impacts. An example of such

726-465: A formula with near-identical ideal composition ratios for explosive gunpowder. Other historians urge caution regarding claims of Islamic firearms use in the 1204–1324 period, as late medieval Arabic texts used the same word for gunpowder, naft , that they used for an earlier incendiary, naphtha. The earliest surviving documentary evidence for cannons in the Islamic world is from an Arabic manuscript dated to

847-434: A gunpowder composition containing pure carbon would burn similarly to a match head, at best. The current standard composition for the gunpowder manufactured by pyrotechnicians was adopted as long ago as 1780. Proportions by weight are 75% potassium nitrate (known as saltpeter or saltpetre), 15% softwood charcoal, and 10% sulfur. These ratios have varied over the centuries and by country, and can be altered somewhat depending on

968-730: A linguistic process where semantic change occurred. For instance, the Arabic word naft transitioned from denoting naphtha to denoting gunpowder, and the Chinese word pào changed in meaning from trebuchet to a cannon . This has led to arguments on the exact origins of gunpowder based on etymological foundations. Science and technology historian Bert S. Hall makes the observation that, "It goes without saying, however, that historians bent on special pleading, or simply with axes of their own to grind, can find rich material in these terminological thickets." Another major area of contention in modern studies of

1089-518: A medicine to an incendiary and explosive, and the evolution of the gun from the fire lance to a metal gun, whereas similar records do not exist elsewhere. As Andrade explains, the large amount of variation in gunpowder recipes in China relative to Europe is "evidence of experimentation in China, where gunpowder was at first used as an incendiary and only later became an explosive and a propellant... in contrast, formulas in Europe diverged only very slightly from

1210-433: A number of more exotic explosive materials, and exotic methods of causing explosions. Examples include nuclear explosives , and abruptly heating a substance to a plasma state with a high-intensity laser or electric arc . Laser- and arc-heating are used in laser detonators, exploding-bridgewire detonators , and exploding foil initiators , where a shock wave and then detonation in conventional chemical explosive material

1331-426: A physical shock signal. In other situations, different signals such as electrical or physical shock, or, in the case of laser detonation systems, light, are used to initiate an action, i.e., an explosion. A small quantity, usually milligrams, is sufficient to initiate a larger charge of explosive that is usually safer to handle. Zhenyuan Miaodao Yaolue The Zhenyuan Miaodao Yaolue (真元妙道要略, lit. Essentials of

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1452-685: A practical measure, primary explosives are sufficiently sensitive that they can be reliably initiated with a blow from a hammer; however, PETN can also usually be initiated in this manner, so this is only a very broad guideline. Additionally, several compounds, such as nitrogen triiodide , are so sensitive that they cannot even be handled without detonating. Nitrogen triiodide is so sensitive that it can be reliably detonated by exposure to alpha radiation . Primary explosives are often used in detonators or to trigger larger charges of less sensitive secondary explosives . Primary explosives are commonly used in blasting caps and percussion caps to translate

1573-399: A reaction to be classified as a detonation as opposed to just a deflagration, the propagation of the reaction shockwave through the material being tested must be faster than the speed of sound through that material. The speed of sound through a liquid or solid material is usually orders of magnitude faster than the speed of sound through air or other gases. Traditional explosives mechanics

1694-809: A regular basis outside of China." May also states, "however [, ...] the Mongols used the gunpowder weapon in their wars against the Jin, the Song and in their invasions of Japan." Records show that, in England, gunpowder was being made in 1346 at the Tower of London ; a powder house existed at the Tower in 1461, and in 1515 three King's gunpowder makers worked there. Gunpowder was also being made or stored at other royal castles, such as Portchester . The English Civil War (1642–1645) led to an expansion of

1815-501: A ruler and tried to ward off any Mongol attempt similar to the Siege of Baghdad (1258) . Firearms known as top-o-tufak also existed in many Muslim kingdoms in India by as early as 1366. From then on the employment of gunpowder warfare in India was prevalent, with events such as the "Siege of Belgaum " in 1473 by Sultan Muhammad Shah Bahmani. The shipwrecked Ottoman Admiral Seydi Ali Reis

1936-426: A shell, grenade, or improvised " pipe bomb " or "pressure cooker" casings to form shrapnel . In quarrying, high explosives are generally preferred for shattering rock. However, because of its low brisance , gunpowder causes fewer fractures and results in more usable stone compared to other explosives, making it useful for blasting slate , which is fragile, or monumental stone such as granite and marble . Gunpowder

2057-546: A shipwreck off the shore of Japan dated from 1281, during the Mongol invasions of Japan. By 1083 the Song court was producing hundreds of thousands of fire arrows for their garrisons. Bombs and the first proto-guns, known as "fire lances", became prominent during the 12th century and were used by the Song during the Jin-Song Wars . Fire lances were first recorded to have been used at the Siege of De'an in 1132 by Song forces against

2178-735: A smaller number are manufactured specifically for the purpose of being used as explosives. The remainder are too dangerous, sensitive, toxic, expensive, unstable, or prone to decomposition or degradation over short time spans. In contrast, some materials are merely combustible or flammable if they burn without exploding. The distinction, however, is not very clear. Certain materials—dusts, powders, gases, or volatile organic liquids—may be simply combustible or flammable under ordinary conditions, but become explosive in specific situations or forms, such as dispersed airborne clouds , or confinement or sudden release . Early thermal weapons , such as Greek fire , have existed since ancient times. At its roots,

2299-594: A soldier's position, generating fog that hinders vision, etc.). Some of it ends up as a thick layer of soot inside the barrel, where it also is a nuisance for subsequent shots, and a cause of jamming an automatic weapon. Moreover, this residue is hygroscopic , and with the addition of moisture absorbed from the air forms a corrosive substance . The soot contains potassium oxide or sodium oxide that turns into potassium hydroxide , or sodium hydroxide , which corrodes wrought iron or steel gun barrels. Gunpowder arms therefore require thorough and regular cleaning to remove

2420-406: A stock. Some consider this to be a cannon while others do not. The problem with identifying cannons in early 14th century Arabic texts is the term midfa , which appears from 1342 to 1352 but cannot be proven to be true hand-guns or bombards. Contemporary accounts of a metal-barrel cannon in the Islamic world do not occur until 1365. Needham believes that in its original form the term midfa refers to

2541-618: A thermodynamically favorable process in addition to one that propagates very rapidly. Thus, explosives are substances that contain a large amount of energy stored in chemical bonds . The energetic stability of the gaseous products and hence their generation comes from the formation of strongly bonded species like carbon monoxide, carbon dioxide, and nitrogen gas, which contain strong double and triple bonds having bond strengths of nearly 1 MJ/mole. Consequently, most commercial explosives are organic compounds containing –NO 2 , –ONO 2 and –NHNO 2 groups that, when detonated, release gases like

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2662-473: A wad), and by 1287 at the latest, had become true guns, the hand cannon . According to Iqtidar Alam Khan, it was invading Mongols who introduced gunpowder to the Islamic world. The Muslims acquired knowledge of gunpowder sometime between 1240 and 1280, by which point the Syrian Hasan al-Rammah had written recipes, instructions for the purification of saltpeter, and descriptions of gunpowder incendiaries. It

2783-709: Is mining . Whether the mine is on the surface or is buried underground, the detonation or deflagration of either a high or low explosive in a confined space can be used to liberate a fairly specific sub-volume of a brittle material (rock) in a much larger volume of the same or similar material. The mining industry tends to use nitrate-based explosives such as emulsions of fuel oil and ammonium nitrate solutions, mixtures of ammonium nitrate prills (fertilizer pellets) and fuel oil ( ANFO ) and gelatinous suspensions or slurries of ammonium nitrate and combustible fuels. In materials science and engineering, explosives are used in cladding ( explosion welding ). A thin plate of some material

2904-427: Is a pure substance ( molecule ) that in a chemical reaction can contribute some atoms of one or more oxidizing elements, in which the fuel component of the explosive burns. On the simplest level, the oxidizer may itself be an oxidizing element , such as gaseous or liquid oxygen . The availability and cost of explosives are determined by the availability of the raw materials and the cost, complexity, and safety of

3025-506: Is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light , heat , sound , and pressure . An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be: Explosive materials may be categorized by

3146-430: Is an advantage in a propellant device, where one does not desire a shock that would shatter the gun and potentially harm the operator; however, it is a drawback when an explosion is desired. In that case, the propellant (and most importantly, gases produced by its burning) must be confined. Since it contains its own oxidizer and additionally burns faster under pressure, its combustion is capable of bursting containers such as

3267-402: Is an important consideration in selecting an explosive for a particular purpose. The explosive in an armor-piercing projectile must be relatively insensitive, or the shock of impact would cause it to detonate before it penetrated to the point desired. The explosive lenses around nuclear charges are also designed to be highly insensitive, to minimize the risk of accidental detonation. The index of

3388-440: Is an important element influencing the yield of the energy transmitted for both atmospheric over-pressure and ground acceleration. By definition, a "low explosive", such as black powder, or smokeless gunpowder has a burn rate of 171–631 m/s. In contrast, a "high explosive", whether a primary, such as detonating cord , or a secondary, such as TNT or C-4, has a significantly higher burn rate about 6900–8092 m/s. Stability

3509-520: Is based on the shock-sensitive rapid oxidation of carbon and hydrogen to carbon dioxide, carbon monoxide and water in the form of steam. Nitrates typically provide the required oxygen to burn the carbon and hydrogen fuel. High explosives tend to have the oxygen, carbon and hydrogen contained in one organic molecule, and less sensitive explosives like ANFO are combinations of fuel (carbon and hydrogen fuel oil) and ammonium nitrate . A sensitizer such as powdered aluminum may be added to an explosive to increase

3630-757: Is cited as composed of 79% nitre, 3% sulfur, and 18% charcoal per 100 of dry powder, with about 2% moisture. Prismatic Brown Powder is a large-grained product the Rottweil Company introduced in 1884 in Germany, which was adopted by the British Royal Navy shortly thereafter. The French navy adopted a fine, 3.1 millimeter, not prismatic grained product called Slow Burning Cocoa (SBC) or "cocoa powder". These brown powders reduced burning rate even further by using as little as 2 percent sulfur and using charcoal made from rye straw that had not been completely charred, hence

3751-443: Is created by laser- or electric-arc heating. Laser and electric energy are not currently used in practice to generate most of the required energy, but only to initiate reactions. To determine the suitability of an explosive substance for a particular use, its physical properties must first be known. The usefulness of an explosive can only be appreciated when the properties and the factors affecting them are fully understood. Some of

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3872-448: Is evaluated by a tailored series of tests to assess the material for its intended use. Of the tests listed below, cylinder expansion and air-blast tests are common to most testing programs, and the others support specific applications. In addition to strength, explosives display a second characteristic, which is their shattering effect or brisance (from the French meaning to "break"). Brisance

3993-527: Is implied by al-Rammah's usage of "terms that suggested he derived his knowledge from Chinese sources" and his references to saltpeter as "Chinese snow" ( Arabic : ثلج الصين thalj al-ṣīn ), fireworks as "Chinese flowers", and rockets as "Chinese arrows" that knowledge of gunpowder arrived from China. However, because al-Rammah attributes his material to "his father and forefathers", al-Hassan argues that gunpowder became prevalent in Syria and Egypt by "the end of

4114-468: Is important in determining the effectiveness of an explosion in fragmenting shells, bomb casings, and grenades . The rapidity with which an explosive reaches its peak pressure ( power ) is a measure of its brisance. Brisance values are primarily employed in France and Russia. The sand crush test is commonly employed to determine the relative brisance in comparison to TNT. No test is capable of directly comparing

4235-655: Is known to have introduced the earliest type of matchlock weapons, which the Ottomans used against the Portuguese during the Siege of Diu (1531) . After that, a diverse variety of firearms, large guns in particular, became visible in Tanjore , Dacca , Bijapur , and Murshidabad . Guns made of bronze were recovered from Calicut (1504)- the former capital of the Zamorins The Mughal emperor Akbar mass-produced matchlocks for

4356-541: Is one of the Four Great Inventions of China. Originally developed by Taoists for medicinal purposes, it was first used for warfare around AD 904. Its use in weapons has declined due to smokeless powder replacing it, whilst its relative inefficiency led to newer alternatives such as dynamite and ammonium nitrate/fuel oil replacing it in industrial applications. Gunpowder is a low explosive : it does not detonate , but rather deflagrates (burns quickly). This

4477-400: Is placed atop a thick layer of a different material, both layers typically of metal. Atop the thin layer is placed an explosive. At one end of the layer of explosive, the explosion is initiated. The two metallic layers are forced together at high speed and with great force. The explosion spreads from the initiation site throughout the explosive. Ideally, this produces a metallurgical bond between

4598-465: Is that it was William Lobb , the plant collector, who recognised the possibilities of sodium nitrate during his travels in South America. Lammot du Pont would have known about the use of graphite and probably also knew about the plants in south-west England. In his patent he was careful to state that his claim was for the combination of graphite with sodium nitrate-based powder, rather than for either of

4719-473: Is the ability of an explosive to be stored without deterioration . The following factors affect the stability of an explosive: The term power or performance as applied to an explosive refers to its ability to do work. In practice it is defined as the explosive's ability to accomplish what is intended in the way of energy delivery (i.e., fragment projection, air blast, high-velocity jet, underwater shock and bubble energy, etc.). Explosive power or performance

4840-411: Is the lead-free primary explosive copper(I) 5-nitrotetrazolate, an alternative to lead azide . Explosive material may be incorporated in the explosive train of a device or system. An example is a pyrotechnic lead igniting a booster, which causes the main charge to detonate. The most widely used explosives are condensed liquids or solids converted to gaseous products by explosive chemical reactions and

4961-407: Is used to describe an explosive phenomenon whereby the decomposition is propagated by a shock wave traversing the explosive material at speeds greater than the speed of sound within the substance. The shock front is capable of passing through the high explosive material at supersonic speeds   —   typically thousands of metres per second. In addition to chemical explosives, there are

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5082-416: Is well suited for blank rounds , signal flares , burst charges , and rescue-line launches. It is also used in fireworks for lifting shells, in rockets as fuel, and in certain special effects . Combustion converts less than half the mass of gunpowder to gas; most of it turns into particulate matter. Some of it is ejected, wasting propelling power, fouling the air, and generally being a nuisance (giving away

5203-675: The Delhi Sultanate , and some of the Mongol soldiers remained in northern India after their conversion to Islam. It was written in the Tarikh-i Firishta (1606–1607) that Nasiruddin Mahmud the ruler of the Delhi Sultanate presented the envoy of the Mongol ruler Hulegu Khan with a dazzling pyrotechnics display upon his arrival in Delhi in 1258. Nasiruddin Mahmud tried to express his strength as

5324-466: The Jin . In the early 13th century the Jin used iron-casing bombs. Projectiles were added to fire lances, and re-usable fire lance barrels were developed, first out of hardened paper, and then metal. By 1257 some fire lances were firing wads of bullets. In the late 13th century metal fire lances became 'eruptors', proto-cannons firing co-viative projectiles (mixed with the propellant, rather than seated over it with

5445-499: The Khmer Empire . Within a decade large quantities of gunpowder could be found in the Khmer Empire . By the end of the century firearms were also used by the Trần dynasty . Even though the knowledge of making gunpowder-based weapons was known after the failed Mongol invasion of Java, and the predecessor of firearms, the pole gun ( bedil tombak ), is recorded as being used by Java in 1413,

5566-461: The Mughal Army . Akbar is personally known to have shot a leading Rajput commander during the Siege of Chittorgarh . The Mughals began to use bamboo rockets (mainly for signalling) and employ sappers : special units that undermined heavy stone fortifications to plant gunpowder charges. The Mughal Emperor Shah Jahan is known to have introduced much more advanced matchlocks, their designs were

5687-709: The Sultanate of Mysore by Hyder Ali , French military officers were employed to train the Mysore Army. Hyder Ali and his son Tipu Sultan were the first to introduce modern cannons and muskets , their army was also the first in India to have official uniforms. During the Second Anglo-Mysore War Hyder Ali and his son Tipu Sultan unleashed the Mysorean rockets at their British opponents effectively defeating them on various occasions. The Mysorean rockets inspired

5808-689: The capture of Malacca (1511) resulted in a new type of hybrid tradition matchlock firearm, the istinggar . When the Portuguese came to the archipelago, they referred to the breech-loading swivel gun as berço , while the Spaniards call it verso . By the early 16th century, the Javanese already locally producing large guns, some of them still survived until the present day and dubbed as "sacred cannon" or "holy cannon". These cannons varied between 180- and 260-pounders, weighing anywhere between 3 and 8 tons, length of them between 3 and 6 m. Saltpeter harvesting

5929-414: The droit de fouille or "right to dig", to seize nitrous-containing soil and demolish walls of barnyards, without compensation to the owners. This caused farmers, the wealthy, or entire villages to bribe the petermen and the associated bureaucracy to leave their buildings alone and the saltpeter uncollected. Lavoisier instituted a crash program to increase saltpeter production, revised (and later eliminated)

6050-403: The droit de fouille , researched best refining and powder manufacturing methods, instituted management and record-keeping, and established pricing that encouraged private investment in works. Although saltpeter from new Prussian-style putrefaction works had not been produced yet (the process taking about 18 months), in only a year France had gunpowder to export. A chief beneficiary of this surplus

6171-779: The 9th century AD during the Tang dynasty , first in a formula contained in the Taishang Shengzu Jindan Mijue (太上聖祖金丹秘訣) in 808, and then about 50 years later in a Taoist text known as the Zhenyuan miaodao yaolüe (真元妙道要略). The Taishang Shengzu Jindan Mijue mentions a formula composed of six parts sulfur to six parts saltpeter to one part birthwort herb. According to the Zhenyuan miaodao yaolüe , "Some have heated together sulfur, realgar and saltpeter with honey ; smoke and flames result, so that their hands and faces have been burnt, and even

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6292-454: The Mongols against European forces at the Battle of Mohi in 1241. Professor Kenneth Warren Chase credits the Mongols for introducing into Europe gunpowder and its associated weaponry. However, there is no clear route of transmission, and while the Mongols are often pointed to as the likeliest vector, Timothy May points out that "there is no concrete evidence that the Mongols used gunpowder weapons on

6413-614: The Mysterious Way of the True Origin ) is a Taoist alchemy text that dates to c. 950. It contains one of the earliest known references to gunpowder . The text is attributed to Zheng Yin, an alchemist from the 3rd century who purportedly taught Ge Hong , but the bulk of the text appears to have been written during the 9th century. The document compiles thirty-four recipes of elixirs that potentially could cause harm. Of these, three recipes mention saltpeter as an ingredient. A warning

6534-516: The U.S. until the 1920s that the actual source of corrosion was the potassium chloride residue from potassium chlorate sensitized primers. The bulkier black powder fouling better disperses primer residue. Failure to mitigate primer corrosion by dispersion caused the false impression that nitrocellulose-based powder caused corrosion. Lesmok had some of the bulk of black powder for dispersing primer residue, but somewhat less total bulk than straight black powder, thus requiring less frequent bore cleaning. It

6655-503: The United Kingdom, the finest grain was known as sulfur-free mealed powder ( SMP ). Coarser grains were numbered as sulfur-free gunpowder (SFG n): 'SFG 12', 'SFG 20', 'SFG 40' and 'SFG 90', for example where the number represents the smallest BSS sieve mesh size, which retained no grains. Sulfur's main role in gunpowder is to decrease the ignition temperature. A sample reaction for sulfur-free gunpowder would be: The term black powder

6776-413: The aforementioned (e.g., nitroglycerin , TNT , HMX , PETN , nitrocellulose ). An explosive is classified as a low or high explosive according to its rate of combustion : low explosives burn rapidly (or deflagrate ), while high explosives detonate . While these definitions are distinct, the problem of precisely measuring rapid decomposition makes practical classification of explosives difficult. For

6897-402: The brown color. Lesmok powder was a product developed by DuPont in 1911, one of several semi-smokeless products in the industry containing a mixture of black and nitrocellulose powder. It was sold to Winchester and others primarily for .22 and .32 small calibers. Its advantage was that it was believed at the time to be less corrosive than smokeless powders then in use. It was not understood in

7018-449: The bulk semi-smokeless powders ceased to be manufactured in the 1920s. The original dry-compounded powder used in 15th-century Europe was known as "Serpentine", either a reference to Satan or to a common artillery piece that used it. The ingredients were ground together with a mortar and pestle, perhaps for 24 hours, resulting in a fine flour. Vibration during transportation could cause the components to separate again, requiring remixing in

7139-472: The capacity of an explosive to be initiated into detonation in a sustained manner. It is defined by the power of the detonator which is certain to prime the explosive to a sustained and continuous detonation. Reference is made to the Sellier-Bellot scale that consists of a series of 10 detonators, from n. 1 to n. 10 , each of which corresponds to an increasing charge weight. In practice, most of

7260-425: The choice being determined by the characteristics of the explosive. Dependent upon the method employed, an average density of the loaded charge can be obtained that is within 80–99% of the theoretical maximum density of the explosive. High load density can reduce sensitivity by making the mass more resistant to internal friction . However, if density is increased to the extent that individual crystals are crushed,

7381-425: The compass, and printing did not reach Europe until centuries after they were invented in China. Gunpowder is a granular mixture of: Potassium nitrate is the most important ingredient in terms of both bulk and function because the combustion process releases oxygen from the potassium nitrate, promoting the rapid burning of the other ingredients. To reduce the likelihood of accidental ignition by static electricity ,

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7502-540: The decline of its military might. The earliest Western accounts of gunpowder appear in texts written by English philosopher Roger Bacon in 1267 called Opus Majus and Opus Tertium . The oldest written recipes in continental Europe were recorded under the name Marcus Graecus or Mark the Greek between 1280 and 1300 in the Liber Ignium , or Book of Fires . Some sources mention possible gunpowder weapons being deployed by

7623-421: The development of pressure within rounds of ammunition and separation of mixtures into their constituents. Volatility affects the chemical composition of the explosive such that a marked reduction in stability may occur, which results in an increase in the danger of handling. The introduction of water into an explosive is highly undesirable since it reduces the sensitivity, strength, and velocity of detonation of

7744-698: The development of the Congreve rocket , which the British widely used during the Napoleonic Wars and the War of 1812 . Cannons were introduced to Majapahit when Kublai Khan's Chinese army under the leadership of Ike Mese sought to invade Java in 1293. History of Yuan mentioned that the Mongol used cannons (Chinese: 炮— Pào ) against Daha forces. Cannons were used by the Ayutthaya Kingdom in 1352 during its invasion of

7865-539: The earliest Latin accounts of saltpeter purification are dated after 1200. The earliest chemical formula for gunpowder appeared in the 11th century Song dynasty text, Wujing Zongyao ( Complete Essentials from the Military Classics ), written by Zeng Gongliang between 1040 and 1044. The Wujing Zongyao provides encyclopedia references to a variety of mixtures that included petrochemicals—as well as garlic and honey. A slow match for flame-throwing mechanisms using

7986-450: The early 14th century. The author's name is uncertain but may have been Shams al-Din Muhammad, who died in 1350. Dating from around 1320–1350, the illustrations show gunpowder weapons such as gunpowder arrows, bombs, fire tubes, and fire lances or proto-guns. The manuscript describes a type of gunpowder weapon called a midfa which uses gunpowder to shoot projectiles out of a tube at the end of

8107-756: The end of World War II , and of ICI Nobel 's Roslin gunpowder factory which closed in 1954. This left ICI Nobel's Ardeer site in Scotland , which included a gunpowder factory, as the only factory in Great Britain producing gunpowder. The gunpowder area of the Ardeer site closed in October 1976. Gunpowder and gunpowder weapons were transmitted to India through the Mongol invasions of India . The Mongols were defeated by Alauddin Khalji of

8228-498: The energy of the detonation. Once detonated, the nitrogen portion of the explosive formulation emerges as nitrogen gas and toxic nitric oxides . The chemical decomposition of an explosive may take years, days, hours, or a fraction of a second. The slower processes of decomposition take place in storage and are of interest only from a stability standpoint. Of more interest are the other two rapid forms besides decomposition: deflagration and detonation. In deflagration, decomposition of

8349-604: The energy released by those reactions. The gaseous products of complete reaction are typically carbon dioxide , steam , and nitrogen . Gaseous volumes computed by the ideal gas law tend to be too large at high pressures characteristic of explosions. Ultimate volume expansion may be estimated at three orders of magnitude, or one liter per gram of explosive. Explosives with an oxygen deficit will generate soot or gases like carbon monoxide and hydrogen , which may react with surrounding materials such as atmospheric oxygen . Attempts to obtain more precise volume estimates must consider

8470-445: The explosive material is propagated by a flame front which moves relatively slowly through the explosive material, i.e. at speeds less than the speed of sound within the substance (which is usually still higher than 340 m/s or 1,220 km/h in most liquid or solid materials) in contrast to detonation, which occurs at speeds greater than the speed of sound. Deflagration is a characteristic of low explosive material. This term

8591-651: The explosive material, but a practical explosive will often include small percentages of other substances. For example, dynamite is a mixture of highly sensitive nitroglycerin with sawdust , powdered silica , or most commonly diatomaceous earth , which act as stabilizers. Plastics and polymers may be added to bind powders of explosive compounds; waxes may be incorporated to make them safer to handle; aluminium powder may be introduced to increase total energy and blast effects. Explosive compounds are also often "alloyed": HMX or RDX powders may be mixed (typically by melt-casting) with TNT to form Octol or Cyclotol . An oxidizer

8712-442: The explosive may become more sensitive. Increased load density also permits the use of more explosive, thereby increasing the power of the warhead . It is possible to compress an explosive beyond a point of sensitivity, known also as dead-pressing , in which the material is no longer capable of being reliably initiated, if at all. Volatility is the readiness with which a substance vaporizes . Excessive volatility often results in

8833-414: The explosive properties of two or more compounds; it is important to examine the data from several such tests (sand crush, trauzl , and so forth) in order to gauge relative brisance. True values for comparison require field experiments. Density of loading refers to the mass of an explosive per unit volume. Several methods of loading are available, including pellet loading, cast loading, and press loading,

8954-409: The explosive. Hygroscopicity is a measure of a material's moisture-absorbing tendencies. Moisture affects explosives adversely by acting as an inert material that absorbs heat when vaporized, and by acting as a solvent medium that can cause undesired chemical reactions. Sensitivity, strength, and velocity of detonation are reduced by inert materials that reduce the continuity of the explosive mass. When

9075-429: The explosives on the market today are sensitive to an n. 8 detonator, where the charge corresponds to 2 grams of mercury fulminate . The velocity with which the reaction process propagates in the mass of the explosive. Most commercial mining explosives have detonation velocities ranging from 1,800 m/s to 8,000 m/s. Today, velocity of detonation can be measured with accuracy. Together with density it

9196-474: The fact, and may well have been colored by the contemporary experiences of the chronicler. Translation difficulties have led to errors or loose interpretations bordering on artistic licence . Ambiguous language can make it difficult to distinguish gunpowder weapons from similar technologies that do not rely on gunpowder. A commonly cited example is a report of the Battle of Mohi in Eastern Europe that mentions

9317-414: The field. Also if the quality of the saltpeter was low (for instance if it was contaminated with highly hygroscopic calcium nitrate ), or if the powder was simply old (due to the mildly hygroscopic nature of potassium nitrate), in humid weather it would need to be re-dried. The dust from "repairing" powder in the field was a major hazard. Explosive#Low An explosive (or explosive material )

9438-413: The first time in warfare. The Chinese would incorporate explosives fired from bamboo or bronze tubes known as bamboo firecrackers. The Chinese also inserted live rats inside the bamboo firecrackers; when fired toward the enemy, the flaming rats created great psychological ramifications—scaring enemy soldiers away and causing cavalry units to go wild. The first useful explosive stronger than black powder

9559-606: The former Curtis & Harvey 's Glynneath gunpowder factory at Pontneddfechan in Wales closed down. The factory was demolished by fire in 1932. The last remaining gunpowder mill at the Royal Gunpowder Factory, Waltham Abbey was damaged by a German parachute mine in 1941 and it never reopened. This was followed by the closure and demolition of the gunpowder section at the Royal Ordnance Factory , ROF Chorley , at

9680-411: The granules of modern gunpowder are typically coated with graphite , which prevents the build-up of electrostatic charge. Charcoal does not consist of pure carbon; rather, it consists of partially pyrolyzed cellulose , in which the wood is not completely decomposed. Carbon differs from ordinary charcoal . Whereas charcoal's autoignition temperature is relatively low, carbon's is much greater. Thus,

9801-572: The gunpowder industry, with the repeal of the Royal Patent in August 1641. In late 14th century Europe, gunpowder was improved by corning , the practice of drying it into small clumps to improve combustion and consistency. During this time, European manufacturers also began regularly purifying saltpeter, using wood ashes containing potassium carbonate to precipitate calcium from their dung liquor, and using ox blood, alum , and slices of turnip to clarify

9922-427: The history of chemical explosives lies in the history of gunpowder . During the Tang dynasty in the 9th century, Taoist Chinese alchemists were eagerly trying to find the elixir of immortality. In the process, they stumbled upon the explosive invention of black powder made from coal, saltpeter, and sulfur in 1044. Gunpowder was the first form of chemical explosives and by 1161, the Chinese were using explosives for

10043-463: The history of gunpowder is regarding the transmission of gunpowder. While the literary and archaeological evidence supports a Chinese origin for gunpowder and guns, the manner in which gunpowder technology was transferred from China to the West is still under debate. It is unknown why the rapid spread of gunpowder technology across Eurasia took place over several decades whereas other technologies such as paper,

10164-428: The ideal proportions for use as an explosive and a propellant, suggesting that gunpowder was introduced as a mature technology." However, the history of gunpowder is not without controversy. A major problem confronting the study of early gunpowder history is ready access to sources close to the events described. Often the first records potentially describing use of gunpowder in warfare were written several centuries after

10285-703: The knowledge of making "true" firearms came much later, after the middle of the 15th century. It was brought by the Islamic nations of West Asia, most probably the Arabs . The precise year of introduction is unknown, but it may be safely concluded to be no earlier than 1460. Before the arrival of the Portuguese in Southeast Asia, the natives already possessed primitive firearms, the Java arquebus . Portuguese influence to local weaponry after

10406-566: The late 19th century led to a contraction of the gunpowder industry. After the end of World War I , the majority of the British gunpowder manufacturers merged into a single company, "Explosives Trades limited", and a number of sites were closed down, including those in Ireland. This company became Nobel Industries Limited, and in 1926 became a founding member of Imperial Chemical Industries . The Home Office removed gunpowder from its list of Permitted Explosives . Shortly afterwards, on 31 December 1931,

10527-418: The main problem of using cheaper sodium nitrate formulations when he patented DuPont "B" blasting powder. After manufacturing grains from press-cake in the usual way, his process tumbled the powder with graphite dust for 12 hours. This formed a graphite coating on each grain that reduced its ability to absorb moisture. Neither the use of graphite nor sodium nitrate was new. Glossing gunpowder corns with graphite

10648-450: The manufacturing operations. A primary explosive is an explosive that is extremely sensitive to stimuli such as impact , friction , heat , static electricity , or electromagnetic radiation . Some primary explosives are also known as contact explosives . A relatively small amount of energy is required for initiation . As a very general rule, primary explosives are considered to be those compounds that are more sensitive than PETN . As

10769-518: The median of 17 of these 22 compositions for rockets (75% nitrates, 9.06% sulfur, and 15.94% charcoal), it is nearly identical to the modern reported ideal recipe of 75% potassium nitrate, 10% sulfur, and 15% charcoal. The text also mentions fuses, incendiary bombs, naphtha pots, fire lances, and an illustration and description of the earliest torpedo . The torpedo was called the "egg which moves itself and burns". Two iron sheets were fastened together and tightened using felt. The flattened pear-shaped vessel

10890-445: The mid-17th century fireworks were used for entertainment on an unprecedented scale in Europe, being popular even at resorts and public gardens. With the publication of Deutliche Anweisung zur Feuerwerkerey (1748), methods for creating fireworks were sufficiently well-known and well-described that "Firework making has become an exact science." In 1774 Louis XVI ascended to the throne of France at age 20. After he discovered that France

11011-436: The moisture content evaporates during detonation, cooling occurs, which reduces the temperature of reaction. Stability is also affected by the presence of moisture since moisture promotes decomposition of the explosive and, in addition, causes corrosion of the explosive's metal container. Explosives considerably differ from one another as to their behavior in the presence of water. Gelatin dynamites containing nitroglycerine have

11132-443: The molecule is said to have a zero oxygen balance. The molecule is said to have a positive oxygen balance if it contains more oxygen than is needed and a negative oxygen balance if it contains less oxygen than is needed. The sensitivity, strength , and brisance of an explosive are all somewhat dependent upon oxygen balance and tend to approach their maxima as oxygen balance approaches zero. A chemical explosive may consist of either

11253-457: The more important characteristics are listed below: Sensitivity refers to the ease with which an explosive can be ignited or detonated, i.e., the amount and intensity of shock , friction , or heat that is required. When the term sensitivity is used, care must be taken to clarify what kind of sensitivity is under discussion. The relative sensitivity of a given explosive to impact may vary greatly from its sensitivity to friction or heat. Some of

11374-436: The muzzle at high speed, but usually not enough force to rupture the gun barrel . It thus makes a good propellant but is less suitable for shattering rock or fortifications with its low-yield explosive power. Nonetheless, it was widely used to fill fused artillery shells (and used in mining and civil engineering projects) until the second half of the 19th century, when the first high explosives were put into use. Gunpowder

11495-410: The possibility of such side reactions, condensation of steam, and aqueous solubility of gases like carbon dioxide. Oxygen balance is an expression that is used to indicate the degree to which an explosive can be oxidized. If an explosive molecule contains just enough oxygen to convert all of its carbon to carbon dioxide, all of its hydrogen to water, and all of its metal to metal oxide with no excess,

11616-410: The purest sulfur was supplied from a crater from a mountain near the straits of Bali . On the origins of gunpowder technology, historian Tonio Andrade remarked, "Scholars today overwhelmingly concur that the gun was invented in China." Gunpowder and the gun are widely believed by historians to have originated from China due to the large body of evidence that documents the evolution of gunpowder from

11737-481: The purpose of the powder. For instance, power grades of black powder, unsuitable for use in firearms but adequate for blasting rock in quarrying operations, are called blasting powder rather than gunpowder with standard proportions of 70% nitrate, 14% charcoal, and 16% sulfur; blasting powder may be made with the cheaper sodium nitrate substituted for potassium nitrate and proportions may be as low as 40% nitrate, 30% charcoal, and 30% sulfur. In 1857, Lammot du Pont solved

11858-422: The residue. Gunpowder loads can be used in modern firearms as long as they are not gas-operated . The most compatible modern guns are smoothbore-barreled shotguns that are long-recoil operated with chrome-plated essential parts such as barrels and bores. Such guns have minimal fouling and corrosion and are easier to clean. The first confirmed reference to what can be considered gunpowder in China occurred in

11979-413: The siphon principle and for fireworks and rockets is mentioned. The mixture formulas in this book contain at most 50% saltpeter   —   not enough to create an explosion, they produce an incendiary instead. The Essentials was written by a Song dynasty court bureaucrat and there is little evidence that it had any immediate impact on warfare; there is no mention of its use in the chronicles of

12100-609: The solution. During the Renaissance, two European schools of pyrotechnic thought emerged, one in Italy and the other at Nuremberg, Germany. In Italy, Vannoccio Biringuccio , born in 1480, was a member of the guild Fraternita di Santa Barbara but broke with the tradition of secrecy by setting down everything he knew in a book titled De la pirotechnia , written in vernacular. It was published posthumously in 1540, with 9 editions over 138 years, and also reprinted by MIT Press in 1966. By

12221-558: The speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound ) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Explosives may also be categorized by their sensitivity . Sensitive materials that can be initiated by a relatively small amount of heat or pressure are primary explosives and materials that are relatively insensitive are secondary or tertiary explosives . A wide variety of chemicals can explode;

12342-492: The sum of the masses of the two initial layers. There are applications where a shock wave, and electrostatics, can result in high velocity projectiles such as in an electrostatic particle accelerator . An explosion is a type of spontaneous chemical reaction that, once initiated, is driven by both a large exothermic change (great release of heat) and a large positive entropy change (great quantities of gases are released) in going from reactants to products, thereby constituting

12463-499: The test methods used to determine sensitivity relate to: Specific explosives (usually but not always highly sensitive on one or more of the three above axes) may be idiosyncratically sensitive to such factors as pressure drop, acceleration, the presence of sharp edges or rough surfaces, incompatible materials, or even —  in rare cases —  nuclear or electromagnetic radiation. These factors present special hazards that may rule out any practical utility. Sensitivity

12584-506: The time. The state-controlled manufacture of gunpowder by the Ottoman Empire through early supply chains to obtain nitre, sulfur and high-quality charcoal from oaks in Anatolia contributed significantly to its expansion between the 15th and 18th century. It was not until later in the 19th century when the syndicalist production of Turkish gunpowder was greatly reduced, which coincided with

12705-456: The tube or cylinder of a naphtha projector ( flamethrower ), then after the invention of gunpowder it meant the tube of fire lances, and eventually it applied to the cylinder of hand-guns and cannons. According to Paul E. J. Hammer, the Mamluks certainly used cannons by 1342. According to J. Lavin, cannons were used by Moors at the siege of Algeciras in 1343. A metal cannon firing an iron ball

12826-441: The twelfth century or the beginning of the thirteenth". In Persia saltpeter was known as "Chinese salt" ( Persian : نمک چینی ) namak-i chīnī ) or "salt from Chinese salt marshes" ( نمک شوره چینی namak-i shūra-yi chīnī ). Hasan al-Rammah included 107 gunpowder recipes in his text al-Furusiyyah wa al-Manasib al-Harbiyya ( The Book of Military Horsemanship and Ingenious War Devices ), 22 of which are for rockets. If one takes

12947-460: The two individual technologies. French war powder in 1879 used the ratio 75% saltpeter, 12.5% charcoal, 12.5% sulfur. English war powder in 1879 used the ratio 75% saltpeter, 15% charcoal, 10% sulfur. The British Congreve rockets used 62.4% saltpeter, 23.2% charcoal and 14.4% sulfur, but the British Mark VII gunpowder was changed to 65% saltpeter, 20% charcoal and 15% sulfur. The explanation for

13068-425: The two layers. As the length of time the shock wave spends at any point is small, we can see mixing of the two metals and their surface chemistries, through some fraction of the depth, and they tend to be mixed in some way. It is possible that some fraction of the surface material from either layer eventually gets ejected when the end of material is reached. Hence, the mass of the now "welded" bilayer, may be less than

13189-520: The wars against the Tanguts in the 11th century, and China was otherwise mostly at peace during this century. However, it had already been used for fire arrows since at least the 10th century. Its first recorded military application dates its use to 904 in the form of incendiary projectiles. In the following centuries various gunpowder weapons such as bombs , fire lances , and the gun appeared in China. Explosive weapons such as bombs have been discovered in

13310-405: The whole house where they were working burned down." Based on these Taoist texts, the invention of gunpowder by Chinese alchemists was likely an accidental byproduct from experiments seeking to create the elixir of life . This experimental medicine origin is reflected in its Chinese name huoyao ( Chinese : 火药/火藥 ; pinyin : huǒ yào /xuo yɑʊ/ ), which means "fire medicine". Saltpeter

13431-517: The wide variety in formulation relates to usage. Powder used for rocketry can use a slower burn rate since it accelerates the projectile for a much longer time—whereas powders for weapons such as flintlocks, cap-locks, or matchlocks need a higher burn rate to accelerate the projectile in a much shorter distance. Cannons usually used lower burn-rate powders, because most would burst with higher burn-rate powders. Besides black powder, there are other historically important types of gunpowder. "Brown gunpowder"

13552-799: Was nitroglycerin , developed in 1847. Since nitroglycerin is a liquid and highly unstable, it was replaced by nitrocellulose , trinitrotoluene ( TNT ) in 1863, smokeless powder , dynamite in 1867 and gelignite (the latter two being sophisticated stabilized preparations of nitroglycerin rather than chemical alternatives, both invented by Alfred Nobel ). World War I saw the adoption of TNT in artillery shells. World War II saw extensive use of new explosives (see: List of explosives used during World War II ) . In turn, these have largely been replaced by more powerful explosives such as C-4 and PETN . However, C-4 and PETN react with metal and catch fire easily, yet unlike TNT, C-4 and PETN are waterproof and malleable. The largest commercial application of explosives

13673-518: Was already an accepted technique in 1839, and sodium nitrate-based blasting powder had been made in Peru for many years using the sodium nitrate mined at Tarapacá (now in Chile). Also, in 1846, two plants were built in south-west England to make blasting powder using this sodium nitrate. The idea may well have been brought from Peru by Cornish miners returning home after completing their contracts. Another suggestion

13794-647: Was coined in the late 19th century, primarily in the United States, to distinguish prior gunpowder formulations from the new smokeless powders and semi-smokeless powders. Semi-smokeless powders featured bulk volume properties that approximated black powder, but had significantly reduced amounts of smoke and combustion products. Smokeless powder has different burning properties (pressure vs. time) and can generate higher pressures and work per gram. This can rupture older weapons designed for black powder. Smokeless powders ranged in color from brownish tan to yellow to white. Most of

13915-588: Was described by Shihab al-Din Abu al-Abbas al-Qalqashandi between 1365 and 1376. The musket appeared in the Ottoman Empire by 1465. In 1598, Chinese writer Zhao Shizhen described Turkish muskets as being superior to European muskets. The Chinese military book Wu Pei Chih (1621) later described Turkish muskets that used a rack-and-pinion mechanism, which was not known to have been used in European or Chinese firearms at

14036-508: Was filled with gunpowder, metal filings, "good mixtures", two rods, and a large rocket for propulsion. Judging by the illustration, it was evidently supposed to glide across the water. Fire lances were used in battles between the Muslims and Mongols in 1299 and 1303. Al-Hassan claims that in the Battle of Ain Jalut of 1260, the Mamluks used "the first cannon in history" against the Mongols, utilizing

14157-474: Was known to the Chinese by the mid-1st century AD and was primarily produced in the provinces of Sichuan , Shanxi , and Shandong . There is strong evidence of the use of saltpeter and sulfur in various medicinal combinations. A Chinese alchemical text dated 492 noted saltpeter burnt with a purple flame, providing a practical and reliable means of distinguishing it from other inorganic salts, thus enabling alchemists to evaluate and compare purification techniques;

14278-533: Was last sold by Winchester in 1947. The development of smokeless powders, such as cordite , in the late 19th century created the need for a spark-sensitive priming charge , such as gunpowder. However, the sulfur content of traditional gunpowders caused corrosion problems with Cordite Mk I and this led to the introduction of a range of sulfur-free gunpowders, of varying grain sizes. They typically contain 70.5 parts of saltpeter and 29.5 parts of charcoal. Like black powder, they were produced in different grain sizes. In

14399-584: Was not self-sufficient in gunpowder, a Gunpowder Administration was established; to head it, the lawyer Antoine Lavoisier was appointed. Although from a bourgeois family, after his degree in law Lavoisier became wealthy from a company set up to collect taxes for the Crown; this allowed him to pursue experimental natural science as a hobby. Without access to cheap saltpeter (controlled by the British), for hundreds of years France had relied on saltpetremen with royal warrants,

14520-558: Was recorded by Dutch and German travelers as being common in even the smallest villages and was collected from the decomposition process of large dung hills specifically piled for the purpose. The Dutch punishment for possession of non-permitted gunpowder appears to have been amputation. Ownership and manufacture of gunpowder was later prohibited by the colonial Dutch occupiers. According to colonel McKenzie quoted in Sir Thomas Stamford Raffles ', The History of Java (1817),

14641-585: Was the American Revolution . By careful testing and adjusting the proportions and grinding time, powder from mills such as at Essonne outside Paris became the best in the world by 1788, and inexpensive. Two British physicists, Andrew Noble and Frederick Abel , worked to improve the properties of gunpowder during the late 19th century. This formed the basis for the Noble-Abel gas equation for internal ballistics . The introduction of smokeless powder in

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