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47-406: The plant uses lignite coal to produce synthetic natural gas utilizing a coal gasification process. The plant processes 16 thousand tons of coal daily. Coal is oxidized to coal gas, which is then converted from a mixture of carbon monoxide , carbon dioxide and hydrogen to methane , by hydrogenation over a nickel catalyst. The synthetic natural gas (95% methane, 975 BTU per cubic foot)

94-409: A carbon content around 25–35% and is considered the lowest rank of coal due to its relatively low heat content . When removed from the ground, it contains a very high amount of moisture , which partially explains its low carbon content. Lignite is mined all around the world and is used almost exclusively as a fuel for steam-electric power generation . Lignite combustion produces less heat for

141-485: A carbon content of 60–70 percent on a dry ash-free basis. However, its inherent moisture content is sometimes as high as 75 percent and its ash content ranges from 6–19 percent, compared with 6–12 percent for bituminous coal . As a result, its carbon content on the as-received basis (i.e., containing both inherent moisture and mineral matter) is typically just 25-35 percent. The energy content of lignite ranges from 10 to 20 MJ/kg (9–17 million BTU per short ton ) on

188-459: A director on the board. Senator Heidi Heitkamp served as an external director until December 2012 after she was elected to the U.S. Senate . This North Dakota –related article is a stub . You can help Misplaced Pages by expanding it . Lignite Lignite (derived from Latin lignum meaning 'wood'), often referred to as brown coal , is a soft, brown, combustible sedimentary rock formed from naturally compressed peat . It has

235-560: A fuel for poor people compared to higher value hard coals. In Germany, briquettes are still readily available to end consumers in home improvement stores and supermarkets. An environmentally beneficial use of lignite is in agriculture. Lignite may have value as an environmentally benign soil amendment , improving cation exchange and phosphorus availability in soils while reducing availability of heavy metals, and may be superior to commercial K humates. Lignite fly ash produced by combustion of lignite in power plants may also be valuable as

282-558: A higher carbon content. The rank of coal is correlated with its geologic history, as described in Hilt's law . In the ASTM system, any coal with more than 69% fixed carbon is classified by its content of carbon and volatiles. Coal with less than 69% fixed carbon is classified by its heating value . Volatiles and carbon are on a dry mineral free base; heating value is based on the moisture content as mined, but without any free water. The ISO also has

329-720: A moist, mineral-matter-free basis. The energy content of lignite consumed in the United States averages 15 MJ/kg (13 million BTU/ton), on the as-received basis. The energy content of lignite consumed in Victoria, Australia, averages 8.6 MJ/kg (8.2 million BTU/ton) on a net wet basis. Lignite has a high content of volatile matter which makes it easier to convert into gas and liquid petroleum products than higher-ranking coals. Its high moisture content and susceptibility to spontaneous combustion can cause problems in transportation and storage. Processes which remove water from brown coal reduce

376-436: A moulded specimen of the coal ash through an observation window in a high-temperature furnace. The ash, in the form of a cone, pyramid or cube, is heated steadily past 1000 °C to as high a temperature as possible, preferably 1,600 °C (2,910 °F). The following temperatures are recorded; The simplest test to evaluate whether a coal is suitable for production of coke is the free swelling index test. This involves heating

423-430: A result of increased temperatures and pressures underground. Lignite forms from peat that has not been subjected to deep burial and heating. It forms at temperatures below 100 °C (212 °F), primarily by biochemical degradation. This includes the process of humification, in which microorganisms extract hydrocarbons from peat and form humic acids, which decrease the rate of bacterial decay. In lignite, humification

470-512: A small sample of coal in a standardised crucible to around 800 degrees Celsius (1500 °F). After heating for a specified time, or until all volatiles are driven off, a small coke button remains in the crucible. The cross sectional profile of this coke button compared to a set of standardised profiles determines the Free Swelling Index. Several international standards classify coals by their rank, where increasing rank corresponds to coal with

517-413: A soil amendment and fertilizer. However, rigorous studies of the long-term benefits of lignite products in agriculture are lacking. Lignite may also be used for the cultivation and distribution of biological control microbes that suppress plant pests. The carbon increases the organic matter in the soil while the biological control microbes provide an alternative to chemical pesticides. Leonardite

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564-476: Is a hardened, gem-like form of lignite used in various types of jewelry. Germany is the largest producer of lignite, followed by China , Russia , and United States . Lignite accounted for 8% of all U.S. coal production in 2019. – no data available Coal assay#Ash Coal analysis techniques are specific analytical methods designed to measure the particular physical and chemical properties of coals . These methods are used primarily to determine

611-563: Is a soil conditioner rich in humic acids that is formed by natural oxidation when lignite comes in contact with air. The process can be replicated artificially on a large scale. The less matured xyloid (wood-shaped) lignite also contains high amounts of humic acid. Reaction with quaternary amine forms a product called amine-treated lignite (ATL), which is used in drilling mud to reduce fluid loss during drilling. Lignite may have potential uses as an industrial adsorbent . Experiments show that its adsorption of methylene blue falls within

658-735: Is a subsidiary of the Basin Electric Power Cooperative which is located in Bismarck, North Dakota . On August 16, 2021, it was announced Bakken Energy would be acquiring the Dakota Gasification Company to be transformed to a blue hydrogen project. The board of Dakota Gasification Company is made up of five directors chosen from among the various directors of Basin Electric plus three additional external directors. Former Governor of Wyoming Jim Geringer currently serves as

705-399: Is an important property of coal, as all coals are mined wet. Groundwater and other extraneous moisture is known as adventitious moisture and is readily evaporated. Moisture held within the coal itself is known as inherent moisture and is analysed quantitatively. Moisture may occur in four possible forms within coal: Total moisture is analysed by loss of mass between an untreated sample and

752-536: Is called slacking or slackening . Most lignite is used to generate electricity. However, small amounts are used in agriculture , in industry , and even, as jet , in jewelry . Its historical use as fuel for home heating has continuously declined and is now of lower importance than its use to generate electricity. Lignite is often found in thick beds located near the surface, making it inexpensive to mine. However, because of its low energy density , tendency to crumble, and typically high moisture content, brown coal

799-407: Is determined by measuring the loss of mass of the four metal blades. Aside from physical or chemical analyses to determine the handling and pollutant profile of a coal, the energy output of a coal is determined using a bomb calorimeter which measures the specific energy output of a coal during complete combustion. This is required particularly for coals used in steam generation. The behaviour of

846-722: Is inefficient to transport and is not traded extensively on the world market compared with higher coal grades. It is often burned in power stations near the mines, such as in Poland's Bełchatów plant and Turów plant , Australia's Latrobe Valley and Luminant 's Monticello plant and Martin Lake plant in Texas. Primarily because of latent high moisture content and low energy density of brown coal, carbon dioxide emissions from traditional brown-coal-fired plants are generally much higher per megawatt-hour generated than for comparable black-coal plants, with

893-406: Is mined, so that suitable crushing machinery can be designed to optimise the particle size for transport and use. Coal plies and particles have different relative densities, determined by vitrinite content, rank, ash value/mineral content and porosity. Coal is usually washed by passing it over a bath of liquid of known density. This removes high-ash value particle and increases the saleability of

940-487: Is partial, coming to completion only when the coal reaches sub-bituminous rank. The most characteristic chemical change in the organic material during formation of lignite is the sharp reduction in the number of C=O and C-O-R functional groups. Lignite deposits are typically younger than higher-ranked coals, with the majority of them having formed during the Tertiary period. Lignite is often found in thick beds located near

987-622: Is pipelined to the Northern Border Pipeline which transports gas from Canada, Montana and North Dakota to the Ventura, Iowa area, where the pipeline interconnects with many pipelines supplying the eastern United States. The company ships generated byproduct carbon dioxide via a high pressure pipeline to an oilfield in Saskatchewan in Canada where it is used for enhanced oil recovery from

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1034-472: Is the property of the coal which describes its propensity and ability to wear away machinery and undergo autonomous grinding. While carbonaceous matter in coal is relatively soft, quartz and other mineral constituents in coal are quite abrasive. This is tested in a calibrated mill, containing four blades of known mass. The coal is agitated in the mill for 12,000 revolutions at a rate of 1,500 revolutions per minute.(I.E 1500 revolution for 8 min.) The abrasion index

1081-592: The railway network was dependent on lignite either through steam trains or electrified lines mostly fed with lignite derived power. As per the table below, East Germany was the largest producer of lignite for much of its existence as an independent state. In 2014, about 12 percent of Germany's energy and, specifically, 27 percent of Germany's electricity came from lignite power plants, while in 2014 in Greece , lignite provided about 50 percent of its power needs. Germany has announced plans to phase out lignite by 2038 at

1128-492: The Weyburn oil field near Weyburn, Saskatchewan (Canada). The plant also produces ammonium sulfate , anhydrous ammonia , phenol , cresylic acid , methanol , and urea naphtha . These materials are by-products of coal gasification. The plant also produces liquid nitrogen , krypton and xenon as a by-product of liquid oxygen production. Oxygen is utilized in the initial oxidation of coal. The Dakota Gasification Company

1175-410: The absence of air. This is usually a mixture of short- and long-chain hydrocarbons, aromatic hydrocarbons and some sulfur. Volatile matter also evaluate the adsorption application of an activated carbon. The volatile matter of coal is determined under rigidly controlled standards. In Australian and British laboratories this involves heating the coal sample to 900 ± 5 °C (1650 ±10 °F) for 7 min. Also as

1222-419: The amount of carbon dioxide and sulfur released than other ranks of coal. As a result, lignite is the most harmful coal to human health. Depending on the source, various toxic heavy metals , including naturally occurring radioactive materials , may be present in lignite and left over in the coal fly ash produced from its combustion, further increasing health risks. Lignite is brownish-black in color and has

1269-420: The area remains saturated with water, which covers dead vegetation and protects it from atmospheric oxygen. Otherwise, peat swamps are found in a variety of climates and geographical settings. Anaerobic bacteria may contribute to the degradation of peat, but this process takes a long time, particularly in acidic water. Burial by other sediments further slows biological degradation, and subsequent transformations are

1316-423: The coal as well as its energy content per unit volume. Thus, coals must be subjected to a float-sink test in the laboratory, which will determine the optimum particle size for washing, the density of the wash liquid required to remove the maximum ash value with the minimum work. Float-Sink testing is achieved on crushed and pulverised coal in a process similar to metallurgical testing on metallic ore . Abrasion

1363-450: The coal because some carbon is lost in hydrocarbons with the volatiles. Fixed carbon is used as an estimate of the amount of coke that will be yielded from a sample of coal. Fixed carbon is determined by removing the mass of volatiles determined by the volatility test, above, from the original mass of the coal sample. Relative density or specific gravity of the coal depends on the rank of the coal and degree of mineral impurity. Knowledge of

1410-463: The coal's ash residue at high temperature is a critical factor in selecting coals for steam power generation. Most furnaces are designed to remove ash as a powdery residue. Coal which has ash that fuses into a hard glassy slag known as clinker is usually unsatisfactory in furnaces as it requires cleaning. However, furnaces can be designed to handle the clinker, generally by removing it as a molten liquid. Ash fusion temperatures are determined by viewing

1457-422: The density of each coal play is necessary to determine the properties of composites and blends. The density of the coal seam is necessary for conversion of resources into reserves. Relative density is normally determined by the loss of a sample's weight in water. This is best achieved using finely ground coal, as bulk samples are quite porous. To determine in-place coal tonnages however, it is important to preserve

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1504-906: The governments of Japan and Australia has begun extracting hydrogen from brown coal. The liquefied hydrogen will be shipped via the transporter Suiso Frontier to Japan. The largest lignite deposits in North America are the Gulf Coast lignites and the Fort Union lignite field. The Gulf Coast lignites are located in a band running from Texas to Alabama roughly parallel to the Gulf Coast. The Fort Union lignite field stretches from North Dakota to Saskatchewan . Both are important commercial sources of lignite. Lignite can be separated into two types: xyloid lignite or fossil wood , and compact lignite or perfect lignite. Although xyloid lignite may sometimes have

1551-863: The land has been restored to full productivity. A bond (not necessary in this form) for mine reclamation is required in the US by the Surface Mining Control and Reclamation Act of 1977 . The Latrobe Valley in Victoria , Australia , contains estimated reserves of some 65 billion tonnes of brown coal. The deposit is equivalent to 25 percent of known world reserves. The coal seams are up to 98 m (322 ft) thick, with multiple coal seams often giving virtually continuous brown coal thickness of up to 230 m (755 ft). Seams are covered by very little overburden (10 to 20 m (33 to 66 ft)). A partnership led by Kawasaki Heavy Industries and backed by

1598-466: The latest. Greece has confirmed that the last coal plant will be shut in 2025 after receiving pressure from the European Union and plans to heavily invest in renewable energy . Lignite was and is used as a replacement for or in combination with firewood for home heating. It is usually pressed into briquettes for that use. Due to the smell it gives off when burned, lignite was often seen as

1645-407: The lignite is removed, restoration involves grading the mine spoil to as close an approximation as practical of the original ground surface (Approximate Original Contour or AOC). Subsoil and topsoil are restored and the land reseeded with various grasses. In North Dakota , a performance bond is held against the mining company for at least ten years after the end of mining operations to guarantee that

1692-405: The quality of coal. Ash content may be determined as air dried basis and on oven dried basis. The main difference between the two is that the latter is determined after expelling the moisture content in the sample of coal. The fixed carbon content of the coal is the carbon found in the material which is left after volatile materials are driven off. This differs from the ultimate carbon content of

1739-728: The range of activated carbons currently used by industry. Jet is a form of lignite that has been used as a gemstone. The earliest jet artifacts date to 10,000 BCE and jet was used extensively in necklaces and other ornamentation in Britain from the Neolithic until the end of Roman Britain . Jet experienced a brief revival in Victorian Britain . Lignite begins as partially decayed plant material, or peat. Peat tends to accumulate in areas with high moisture, slow land subsidence , and no disturbance by rivers or oceans – under these conditions,

1786-456: The rank of coal increases the volatile matter decreases (AMK). Ash content of coal is the non-combustible residue left after coal is burnt. It represents the bulk mineral matter after carbon, oxygen, sulfur and water (including from clays) has been driven off during combustion. Analysis is fairly straightforward, with the coal thoroughly burnt and the ash material expressed as a percentage of the original weight. It can also give an indication about

1833-414: The risk of spontaneous combustion to the same level as black coal, increase the calorific value of brown coal to a black coal equivalent fuel, and significantly reduce the emissions profile of 'densified' brown coal to a level similar to or better than most black coals. However, removing the moisture increases the cost of the final lignite fuel. Lignite rapidly degrades when exposed to air. This process

1880-436: The sample once analysed. This is achieved by any of the following methods; Methods 1 and 2 are suitable with low-rank coals, but method 3 is only suitable for high-rank coals as free air drying low-rank coals may promote oxidation. Inherent moisture is analysed similarly, though it may be done in a vacuum. Volatile matter in coal refers to the components of coal, except for moisture, which are liberated at high temperature in

1927-422: The subsurface beds. Topsoil and subsoil must be properly removed and either used to reclaim previously mined-out areas or stored for future reclamation. Excavator and truck overburden removal prepares the area for dragline overburden removal to expose the lignite beds. These are broken up using specially equipped tractors ( coal ripping ) and then loaded into bottom dump trucks using front loaders . Once

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1974-446: The suitability of coal for coking , power generation or for iron ore smelting in the manufacture of steel . Coal comes in four main types or ranks: lignite or brown coal , bituminous coal or black coal, anthracite and graphite . Each type of coal has a certain set of physical parameters which are mostly controlled by moisture, volatile content (in terms of aliphatic or aromatic hydrocarbons ) and carbon content. Moisture

2021-409: The surface. These are inexpensive to extract using various forms of surface mining , though this can result in serious environmental damage. Regulations in the United States and other countries require that land that is surface mined must be restored to its original productivity once mining is complete. Strip mining of lignite in the United States begins with drilling to establish the extent of

2068-401: The tenacity and the appearance of ordinary wood, it can be seen that the combustible woody tissue has experienced a great modification. It is reducible to a fine powder by trituration , and if submitted to the action of a weak solution of potash , it yields a considerable quantity of humic acid . Leonardite is an oxidized form of lignite, which also contains high levels of humic acid. Jet

2115-436: The void space when measuring the specific gravity. The particle size distribution of milled coal depends partly on the rank of the coal, which determines its brittleness, and on the handling, crushing and milling it has undergone. Generally coal is utilised in furnaces and coking ovens at a certain size, so the crushability of the coal must be determined and its behaviour quantified. It is necessary to know these data before coal

2162-497: The world's highest-emitting plant being Australia's Hazelwood Power Station until its closure in March 2017. The operation of traditional brown-coal plants, particularly in combination with strip mining , is politically contentious due to environmental concerns. The German Democratic Republic relied extensively on lignite to become energy self-sufficient , and eventually obtained 70% of its energy requirements from lignite. Lignite

2209-490: Was also an important chemical industry feedstock via Bergius process or Fischer-Tropsch synthesis in lieu of petroleum, which had to be imported for hard currency following a change in policy by the Soviet Union in the 1970s, which had previously delivered petroleum at below market rates. East German scientists even converted lignite into coke suitable for metallurgical uses ( high temperature lignite coke ) and much of

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