72-504: Glina is a word of Slavic origin, meaning " clay ". It may refer to: Glina, Croatia , a town in Croatia Glina (river) in Croatia and Bosnia and Herzegovina Glina, Piotrków County , a village in Łódź Voivodeship, central Poland Glina, Sieradz County , a village in Łódź Voivodeship, central Poland Glina, Tomaszów Mazowiecki County ,
144-554: A chemical reaction between the dry ingredients and water. The chemical reaction results in mineral hydrates that are not very water-soluble. This allows setting in wet conditions or under water and further protects the hardened material from chemical attack. The chemical process for hydraulic cement was found by ancient Romans who used volcanic ash ( pozzolana ) with added lime (calcium oxide). Non-hydraulic cement (less common) does not set in wet conditions or under water. Rather, it sets as it dries and reacts with carbon dioxide in
216-546: A mortar made of sand and roughly burnt gypsum (CaSO 4 · 2H 2 O), which is plaster of Paris, which often contained calcium carbonate (CaCO 3 ), Lime (calcium oxide) was used on Crete and by the Ancient Greeks . There is evidence that the Minoans of Crete used crushed potsherds as an artificial pozzolan for hydraulic cement. Nobody knows who first discovered that a combination of hydrated non-hydraulic lime and
288-432: A fine powder. This product, made into a mortar with sand, set in 5–15 minutes. The success of "Roman cement" led other manufacturers to develop rival products by burning artificial hydraulic lime cements of clay and chalk . Roman cement quickly became popular but was largely replaced by Portland cement in the 1850s. Apparently unaware of Smeaton's work, the same principle was identified by Frenchman Louis Vicat in
360-432: A form of hydraulic cement, is by far the most common type of cement in general use around the world. This cement is made by heating limestone (calcium carbonate) with other materials (such as clay ) to 1,450 °C (2,640 °F) in a kiln , in a process known as calcination that liberates a molecule of carbon dioxide from the calcium carbonate to form calcium oxide , or quicklime, which then chemically combines with
432-575: A gel of orthosilicic acid ).) The clay minerals formed depend on the composition of the source rock and the climate. Acid weathering of feldspar -rich rock, such as granite , in warm climates tends to produce kaolin. Weathering of the same kind of rock under alkaline conditions produces illite . Smectite forms by weathering of igneous rock under alkaline conditions, while gibbsite forms by intense weathering of other clay minerals. There are two types of clay deposits: primary and secondary. Primary clays form as residual deposits in soil and remain at
504-836: A great capacity to take up water, and they increase greatly in volume when they do so. When dried, they shrink back to their original volume. This produces distinctive textures, such as mudcracks or "popcorn" texture, in clay deposits. Soils containing swelling clay minerals (such as bentonite ) pose a considerable challenge for civil engineering, because swelling clay can break foundations of buildings and ruin road beds. Clay minerals most commonly form by prolonged chemical weathering of silicate-bearing rocks. They can also form locally from hydrothermal activity. Chemical weathering takes place largely by acid hydrolysis due to low concentrations of carbonic acid , dissolved in rainwater or released by plant roots. The acid breaks bonds between aluminium and oxygen, releasing other metal ions and silica (as
576-669: A half-century. Technologies of waste cementation have been developed and deployed at industrial scale in many countries. Cementitious wasteforms require a careful selection and design process adapted to each specific type of waste to satisfy the strict waste acceptance criteria for long-term storage and disposal. Modern development of hydraulic cement began with the start of the Industrial Revolution (around 1800), driven by three main needs: Modern cements are often Portland cement or Portland cement blends, but other cement blends are used in some industrial settings. Portland cement,
648-402: A major challenge in civil engineering . The defining mechanical property of clay is its plasticity when wet and its ability to harden when dried or fired. Clays show a broad range of water content within which they are highly plastic, from a minimum water content (called the plastic limit ) where the clay is just moist enough to mould, to a maximum water content (called the liquid limit) where
720-787: A market for use in concrete. The use of concrete in construction grew rapidly from 1850 onward, and was soon the dominant use for cements. Thus Portland cement began its predominant role. Isaac Charles Johnson further refined the production of meso-Portland cement (middle stage of development) and claimed he was the real father of Portland cement. Setting time and "early strength" are important characteristics of cements. Hydraulic limes, "natural" cements, and "artificial" cements all rely on their belite (2 CaO · SiO 2 , abbreviated as C 2 S) content for strength development. Belite develops strength slowly. Because they were burned at temperatures below 1,250 °C (2,280 °F), they contained no alite (3 CaO · SiO 2 , abbreviated as C 3 S), which
792-413: A month for Rosendale cement made it unpopular for constructing highways and bridges, and many states and construction firms turned to Portland cement. Because of the switch to Portland cement, by the end of the 1920s only one of the 15 Rosendale cement companies had survived. But in the early 1930s, builders discovered that, while Portland cement set faster, it was not as durable, especially for highways—to
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#1732854696699864-682: A pozzolan produces a hydraulic mixture (see also: Pozzolanic reaction ), but such concrete was used by the Greeks, specifically the Ancient Macedonians , and three centuries later on a large scale by Roman engineers . There is... a kind of powder which from natural causes produces astonishing results. It is found in the neighborhood of Baiae and in the country belonging to the towns round about Mount Vesuvius . This substance when mixed with lime and rubble not only lends strength to buildings of other kinds but even when piers of it are constructed in
936-442: A type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite , Al 2 Si 2 O 5 ( OH ) 4 ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide . Clays develop plasticity when wet but can be hardened through firing . Clay
1008-726: A very advanced civilisation in El Tajin near Mexico City, in Mexico. A detailed study of the composition of the aggregate and binder show that the aggregate was pumice and the binder was a pozzolanic cement made with volcanic ash and lime. Any preservation of this knowledge in literature from the Middle Ages is unknown, but medieval masons and some military engineers actively used hydraulic cement in structures such as canals , fortresses, harbors , and shipbuilding facilities . A mixture of lime mortar and aggregate with brick or stone facing material
1080-684: A village in northern Poland Glina, Ilfov , a commune in Ilfov County, Romania Glina, Bloke , a village in Slovenia Glina (Gurk) , the Slovene name for the river Glan in Carinthia, Austria See also [ edit ] Glinka (disambiguation) Hlinka Topics referred to by the same term [REDACTED] This disambiguation page lists articles associated with the title Glina . If an internal link led you here, you may wish to change
1152-483: A village in Łódź Voivodeship, central Poland Glina, Lipsko County , a village in Masovian Voivodeship, east-central Poland Glina, Ostrów Mazowiecka County , a village in Masovian Voivodeship, east-central Poland Glina, Otwock County , a village in Masovian Voivodeship, east-central Poland Glina, Węgrów County , a village in Masovian Voivodeship, east-central Poland Glina, Pomeranian Voivodeship ,
1224-452: Is Armenian bole , which is used to soothe an upset stomach. Some animals such as parrots and pigs ingest clay for similar reasons. Kaolin clay and attapulgite have been used as anti-diarrheal medicines. Clay as the defining ingredient of loam is one of the oldest building materials on Earth , among other ancient, naturally occurring geologic materials such as stone and organic materials like wood. Between one-half and two-thirds of
1296-422: Is hydraulic cement , which hardens by hydration of the clinker minerals when water is added. Hydraulic cements (such as Portland cement) are made of a mixture of silicates and oxides, the four main mineral phases of the clinker, abbreviated in the cement chemist notation , being: The silicates are responsible for the cement's mechanical properties — the tricalcium aluminate and brownmillerite are essential for
1368-512: Is pozzolanic , so that ultimate strength is maintained. Because fly ash addition allows a lower concrete water content, early strength can also be maintained. Where good quality cheap fly ash is available, this can be an economic alternative to ordinary Portland cement. Portland pozzolan cement includes fly ash cement, since fly ash is a pozzolan , but also includes cements made from other natural or artificial pozzolans. In countries where volcanic ashes are available (e.g., Italy, Chile, Mexico,
1440-520: Is a major emitter of global carbon dioxide emissions . The lime reacts with silicon dioxide to produce dicalcium silicate and tricalcium silicate. The lime also reacts with aluminium oxide to form tricalcium aluminate. In the last step, calcium oxide, aluminium oxide, and ferric oxide react together to form brownmillerite. A less common form of cement is non-hydraulic cement , such as slaked lime ( calcium oxide mixed with water), which hardens by carbonation in contact with carbon dioxide , which
1512-620: Is a unique type of marine clay indigenous to the glaciated terrains of Norway , North America , Northern Ireland , and Sweden . It is a highly sensitive clay, prone to liquefaction , and has been involved in several deadly landslides . Modelling clay is used in art and handicraft for sculpting . Clays are used for making pottery , both utilitarian and decorative, and construction products, such as bricks, walls, and floor tiles. Different types of clay, when used with different minerals and firing conditions, are used to produce earthenware, stoneware, and porcelain. Prehistoric humans discovered
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#17328546966991584-569: Is about 4.4 billion tonnes per year (2021, estimation), of which about half is made in China, followed by India and Vietnam. The cement production process is responsible for nearly 8% (2018) of global CO 2 emissions, which includes heating raw materials in a cement kiln by fuel combustion and release of CO 2 stored in the calcium carbonate (calcination process). Its hydrated products, such as concrete, gradually reabsorb atmospheric CO 2 (carbonation process), compensating for approximately 30% of
1656-459: Is clay with visible annual layers that are formed by seasonal deposition of those layers and are marked by differences in erosion and organic content. This type of deposit is common in former glacial lakes . When fine sediments are delivered into the calm waters of these glacial lake basins away from the shoreline, they settle to the lake bed. The resulting seasonal layering is preserved in an even distribution of clay sediment banding. Quick clay
1728-417: Is completely evaporated (this process is technically called setting ), the carbonation starts: This reaction is slow, because the partial pressure of carbon dioxide in the air is low (~ 0.4 millibar). The carbonation reaction requires that the dry cement be exposed to air, so the slaked lime is a non-hydraulic cement and cannot be used under water. This process is called the lime cycle . Perhaps
1800-555: Is constantly fed into a rotary kiln, it allowed a continuous manufacturing process to replace lower capacity batch production processes. Calcium aluminate cements were patented in 1908 in France by Jules Bied for better resistance to sulfates. Also in 1908, Thomas Edison experimented with pre-cast concrete in houses in Union, N.J. In the US, after World War One, the long curing time of at least
1872-674: Is important to soil fertility. Clay is a common component of sedimentary rock . Shale is formed largely from clay and is the most common of sedimentary rocks. However, most clay deposits are impure. Many naturally occurring deposits include both silts and clay. Clays are distinguished from other fine-grained soils by differences in size and mineralogy. Silts , which are fine-grained soils that do not include clay minerals, tend to have larger particle sizes than clays. There is, however, some overlap in particle size and other physical properties. The distinction between silt and clay varies by discipline. Geologists and soil scientists usually consider
1944-667: Is more usually added to Portland cement at the concrete mixer. Masonry cements are used for preparing bricklaying mortars and stuccos , and must not be used in concrete. They are usually complex proprietary formulations containing Portland clinker and a number of other ingredients that may include limestone, hydrated lime, air entrainers, retarders, waterproofers, and coloring agents. They are formulated to yield workable mortars that allow rapid and consistent masonry work. Subtle variations of masonry cement in North America are plastic cements and stucco cements. These are designed to produce
2016-403: Is present in the air (~ 412 vol. ppm ≃ 0.04 vol. %). First calcium oxide (lime) is produced from calcium carbonate ( limestone or chalk ) by calcination at temperatures above 825 °C (1,517 °F) for about 10 hours at atmospheric pressure : The calcium oxide is then spent (slaked) by mixing it with water to make slaked lime ( calcium hydroxide ): Once the excess water
2088-483: Is responsible for early strength in modern cements. The first cement to consistently contain alite was made by William Aspdin in the early 1840s: This was what we call today "modern" Portland cement. Because of the air of mystery with which William Aspdin surrounded his product, others ( e.g., Vicat and Johnson) have claimed precedence in this invention, but recent analysis of both his concrete and raw cement have shown that William Aspdin's product made at Northfleet , Kent
2160-429: Is the longest-known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery . Some of the earliest pottery shards have been dated to around 14,000 BCE, and clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtering . Between one-half and two-thirds of
2232-474: Is the most widely used material in existence and is behind only water as the planet's most-consumed resource. Cements used in construction are usually inorganic , often lime - or calcium silicate -based, and are either hydraulic or less commonly non-hydraulic , depending on the ability of the cement to set in the presence of water (see hydraulic and non-hydraulic lime plaster ). Hydraulic cements (e.g., Portland cement ) set and become adhesive through
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2304-438: Is to make concrete. Portland cement may be grey or white . Portland cement blends are often available as inter-ground mixtures from cement producers, but similar formulations are often also mixed from the ground components at the concrete mixing plant. Portland blast-furnace slag cement , or blast furnace cement (ASTM C595 and EN 197-1 nomenclature respectively), contains up to 95% ground granulated blast furnace slag , with
2376-512: Is used in many industrial processes, such as paper making, cement production, and chemical filtering . Bentonite clay is widely used as a mold binder in the manufacture of sand castings . Clay is a common filler used in polymer nanocomposites . It can reduce the cost of the composite, as well as impart modified behavior: increased stiffness , decreased permeability , decreased electrical conductivity , etc. Traditional uses of clay as medicine go back to prehistoric times. An example
2448-474: The Isle of Portland , Dorset, England. However, Aspdins' cement was nothing like modern Portland cement but was a first step in its development, called a proto-Portland cement . Joseph Aspdins' son William Aspdin had left his father's company and in his cement manufacturing apparently accidentally produced calcium silicates in the 1840s, a middle step in the development of Portland cement. William Aspdin's innovation
2520-517: The Art to Prepare a Good Mortar published in St. Petersburg . A few years later in 1825, he published another book, which described various methods of making cement and concrete, and the benefits of cement in the construction of buildings and embankments. Portland cement , the most common type of cement in general use around the world as a basic ingredient of concrete, mortar , stucco , and non-speciality grout ,
2592-526: The New York Commissioner of Highways to construct an experimental section of highway near New Paltz, New York , using one sack of Rosendale to six sacks of Portland cement. It was a success, and for decades the Rosendale-Portland cement blend was used in concrete highway and concrete bridge construction. Cementitious materials have been used as a nuclear waste immobilizing matrix for more than
2664-457: The Philippines), these cements are often the most common form in use. The maximum replacement ratios are generally defined as for Portland-fly ash cement. Portland silica fume cement. Addition of silica fume can yield exceptionally high strengths, and cements containing 5–20% silica fume are occasionally produced, with 10% being the maximum allowed addition under EN 197–1. However, silica fume
2736-603: The absence of pozzolanic ash, the Romans used powdered brick or pottery as a substitute and they may have used crushed tiles for this purpose before discovering natural sources near Rome. The huge dome of the Pantheon in Rome and the massive Baths of Caracalla are examples of ancient structures made from these concretes, many of which still stand. The vast system of Roman aqueducts also made extensive use of hydraulic cement. Roman concrete
2808-623: The air. It is resistant to attack by chemicals after setting. The word "cement" can be traced back to the Ancient Roman term opus caementicium , used to describe masonry resembling modern concrete that was made from crushed rock with burnt lime as binder. The volcanic ash and pulverized brick supplements that were added to the burnt lime, to obtain a hydraulic binder , were later referred to as cementum , cimentum , cäment , and cement . In modern times, organic polymers are sometimes used as cements in concrete. World production of cement
2880-516: The available hydraulic limes, visiting their production sites, and noted that the "hydraulicity" of the lime was directly related to the clay content of the limestone used to make it. Smeaton was a civil engineer by profession, and took the idea no further. In the South Atlantic seaboard of the United States, tabby relying on the oyster-shell middens of earlier Native American populations
2952-415: The cohesion that makes it plastic. In kaolinite clay, the bonding between plates is provided by a film of water molecules that hydrogen bond the plates together. The bonds are weak enough to allow the plates to slip past each other when the clay is being moulded, but strong enough to hold the plates in place and allow the moulded clay to retain its shape after it is moulded. When the clay is dried, most of
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3024-420: The development of new cements. Most famous was Parker's " Roman cement ". This was developed by James Parker in the 1780s, and finally patented in 1796. It was, in fact, nothing like material used by the Romans, but was a "natural cement" made by burning septaria – nodules that are found in certain clay deposits, and that contain both clay minerals and calcium carbonate . The burnt nodules were ground to
3096-607: The earliest known occurrence of cement is from twelve million years ago. A deposit of cement was formed after an occurrence of oil shale located adjacent to a bed of limestone burned by natural causes. These ancient deposits were investigated in the 1960s and 1970s. Cement, chemically speaking, is a product that includes lime as the primary binding ingredient, but is far from the first material used for cementation. The Babylonians and Assyrians used bitumen (asphalt or pitch ) to bind together burnt brick or alabaster slabs. In Ancient Egypt , stone blocks were cemented together with
3168-461: The first decade of the nineteenth century. Vicat went on to devise a method of combining chalk and clay into an intimate mixture, and, burning this, produced an "artificial cement" in 1817 considered the "principal forerunner" of Portland cement and "...Edgar Dobbs of Southwark patented a cement of this kind in 1811." In Russia, Egor Cheliev created a new binder by mixing lime and clay. His results were published in 1822 in his book A Treatise on
3240-516: The first known writing medium. Clay was chosen due to the local material being easy to work with and widely available. Scribes wrote on the tablets by inscribing them with a script known as cuneiform , using a blunt reed called a stylus , which effectively produced the wedge shaped markings of their writing. After being written on, clay tablets could be reworked into fresh tablets and reused if needed, or fired to make them permanent records. Purpose-made clay balls were used as sling ammunition . Clay
3312-402: The formation of the liquid phase during the sintering ( firing ) process of clinker at high temperature in the kiln . The chemistry of these reactions is not completely clear and is still the object of research. First, the limestone (calcium carbonate) is burned to remove its carbon, producing lime (calcium oxide) in what is known as a calcination reaction. This single chemical reaction
3384-426: The initial CO 2 emissions. Cement materials can be classified into two distinct categories: hydraulic cements and non-hydraulic cements according to their respective setting and hardening mechanisms. Hydraulic cement setting and hardening involves hydration reactions and therefore requires water, while non-hydraulic cements only react with a gas and can directly set under air. By far the most common type of cement
3456-400: The link to point directly to the intended article. Retrieved from " https://en.wikipedia.org/w/index.php?title=Glina&oldid=1195120642 " Categories : Disambiguation pages Place name disambiguation pages Hidden categories: Short description is different from Wikidata All article disambiguation pages All disambiguation pages Clay Clay is
3528-404: The low pH (8.5–9.5) of its pore water) limited its use as reinforced concrete for building construction. The next development in the manufacture of Portland cement was the introduction of the rotary kiln . It produced a clinker mixture that was both stronger, because more alite (C 3 S) is formed at the higher temperature it achieved (1450 °C), and more homogeneous. Because raw material
3600-404: The material. The clay mineral kaolinite is transformed into a non-clay material, metakaolin , which remains rigid and hard if moistened again. Further firing through the stoneware and porcelain stages further recrystallizes the metakaolin into yet stronger minerals such as mullite . The tiny size and plate form of clay particles gives clay minerals a high surface area. In some clay minerals,
3672-724: The moulded clay is just dry enough to hold its shape. The plastic limit of kaolinite clay ranges from about 36% to 40% and its liquid limit ranges from about 58% to 72%. High-quality clay is also tough, as measured by the amount of mechanical work required to roll a sample of clay flat. Its toughness reflects a high degree of internal cohesion. Clay has a high content of clay minerals that give it its plasticity. Clay minerals are hydrous aluminium phyllosilicate minerals , composed of aluminium and silicon ions bonded into tiny, thin plates by interconnecting oxygen and hydroxide ions. These plates are tough but flexible, and in moist clay, they adhere to each other. The resulting aggregates give clay
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#17328546966993744-465: The other materials in the mix to form calcium silicates and other cementitious compounds. The resulting hard substance, called 'clinker', is then ground with a small amount of gypsum ( CaSO 4 ·2H 2 O ) into a powder to make ordinary Portland cement , the most commonly used type of cement (often referred to as OPC). Portland cement is a basic ingredient of concrete , mortar , and most non-specialty grout . The most common use for Portland cement
3816-467: The plates carry a negative electrical charge that is balanced by a surrounding layer of positive ions ( cations ), such as sodium, potassium, or calcium. If the clay is mixed with a solution containing other cations, these can swap places with the cations in the layer around the clay particles, which gives clays a high capacity for ion exchange . The chemistry of clay minerals, including their capacity to retain nutrient cations such as potassium and ammonium,
3888-467: The point that some states stopped building highways and roads with cement. Bertrain H. Wait, an engineer whose company had helped construct the New York City's Catskill Aqueduct , was impressed with the durability of Rosendale cement, and came up with a blend of both Rosendale and Portland cements that had the good attributes of both. It was highly durable and had a much faster setting time. Wait convinced
3960-453: The removal of heavy metals from waste water and air purification. Cement A cement is a binder , a chemical substance used for construction that sets , hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate ) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel , produces concrete . Concrete
4032-447: The rest Portland clinker and a little gypsum. All compositions produce high ultimate strength, but as slag content is increased, early strength is reduced, while sulfate resistance increases and heat evolution diminishes. Used as an economic alternative to Portland sulfate-resisting and low-heat cements. Portland-fly ash cement contains up to 40% fly ash under ASTM standards (ASTM C595), or 35% under EN standards (EN 197–1). The fly ash
4104-407: The sea, they set hard underwater. The Greeks used volcanic tuff from the island of Thera as their pozzolan and the Romans used crushed volcanic ash (activated aluminium silicates ) with lime. This mixture could set under water, increasing its resistance to corrosion like rust. The material was called pozzolana from the town of Pozzuoli , west of Naples where volcanic ash was extracted. In
4176-696: The separation to occur at a particle size of 2 μm (clays being finer than silts), sedimentologists often use 4–5 μm, and colloid chemists use 1 μm. Clay-size particles and clay minerals are not the same, despite a degree of overlap in their respective definitions. Geotechnical engineers distinguish between silts and clays based on the plasticity properties of the soil, as measured by the soils' Atterberg limits . ISO 14688 grades clay particles as being smaller than 2 μm and silt particles as being larger. Mixtures of sand , silt and less than 40% clay are called loam . Some clay minerals (such as smectite ) are described as swelling clay minerals, because they have
4248-841: The site of formation. Secondary clays are clays that have been transported from their original location by water erosion and deposited in a new sedimentary deposit. Secondary clay deposits are typically associated with very low energy depositional environments such as large lakes and marine basins. The main groups of clays include kaolinite , montmorillonite - smectite , and illite . Chlorite , vermiculite , talc , and pyrophyllite are sometimes also classified as clay minerals. There are approximately 30 different types of "pure" clays in these categories, but most "natural" clay deposits are mixtures of these different types, along with other weathered minerals. Clay minerals in clays are most easily identified using X-ray diffraction rather than chemical or physical tests. Varve (or varved clay )
4320-542: The useful properties of clay. Some of the earliest pottery shards recovered are from central Honshu , Japan . They are associated with the Jōmon culture, and recovered deposits have been dated to around 14,000 BCE. Cooking pots, art objects, dishware, smoking pipes , and even musical instruments such as the ocarina can all be shaped from clay before being fired. Ancient peoples in Mesopotamia adopted clay tablets as
4392-426: The water molecules are removed, and the plates hydrogen bond directly to each other, so that the dried clay is rigid but still fragile. If the clay is moistened again, it will once more become plastic. When the clay is fired to the earthenware stage, a dehydration reaction removes additional water from the clay, causing clay plates to irreversibly adhere to each other via stronger covalent bonding , which strengthens
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#17328546966994464-735: The world's population live or work in buildings made with clay, often baked into brick, as an essential part of its load-bearing structure. Clay is a very common substance. Shale , formed largely from clay, is the most common sedimentary rock. Although many naturally occurring deposits include both silts and clay, clays are distinguished from other fine-grained soils by differences in size and mineralogy. Silts , which are fine-grained soils that do not include clay minerals, tend to have larger particle sizes than clays. Mixtures of sand , silt and less than 40% clay are called loam . Soils high in swelling clays ( expansive clay ), which are clay minerals that readily expand in volume when they absorb water, are
4536-493: The world's population, in both traditional societies as well as developed countries, still live or work in buildings made with clay, often baked into brick, as an essential part of their load-bearing structure. Also a primary ingredient in many natural building techniques, clay is used to create adobe , cob , cordwood , and structures and building elements such as wattle and daub , clay plaster, clay render case, clay floors and clay paints and ceramic building material . Clay
4608-444: Was a true alite-based cement. However, Aspdin's methods were "rule-of-thumb": Vicat is responsible for establishing the chemical basis of these cements, and Johnson established the importance of sintering the mix in the kiln . In the US the first large-scale use of cement was Rosendale cement , a natural cement mined from a massive deposit of dolomite discovered in the early 19th century near Rosendale, New York . Rosendale cement
4680-479: Was counterintuitive for manufacturers of "artificial cements", because they required more lime in the mix (a problem for his father), a much higher kiln temperature (and therefore more fuel), and the resulting clinker was very hard and rapidly wore down the millstones , which were the only available grinding technology of the time. Manufacturing costs were therefore considerably higher, but the product set reasonably slowly and developed strength quickly, thus opening up
4752-468: Was developed in England in the mid 19th century, and usually originates from limestone . James Frost produced what he called "British cement" in a similar manner around the same time, but did not obtain a patent until 1822. In 1824, Joseph Aspdin patented a similar material, which he called Portland cement , because the render made from it was in color similar to the prestigious Portland stone quarried on
4824-494: Was extremely popular for the foundation of buildings ( e.g. , Statue of Liberty , Capitol Building , Brooklyn Bridge ) and lining water pipes. Sorel cement , or magnesia-based cement, was patented in 1867 by the Frenchman Stanislas Sorel . It was stronger than Portland cement but its poor water resistance (leaching) and corrosive properties ( pitting corrosion due to the presence of leachable chloride anions and
4896-622: Was formalized by French and British engineers in the 18th century. John Smeaton made an important contribution to the development of cements while planning the construction of the third Eddystone Lighthouse (1755–59) in the English Channel now known as Smeaton's Tower . He needed a hydraulic mortar that would set and develop some strength in the twelve-hour period between successive high tides . He performed experiments with combinations of different limestones and additives including trass and pozzolanas and did exhaustive market research on
4968-405: Was rarely used on the outside of buildings. The normal technique was to use brick facing material as the formwork for an infill of mortar mixed with an aggregate of broken pieces of stone, brick, potsherds , recycled chunks of concrete, or other building rubble. Lightweight concrete was designed and used for the construction of structural elements by the pre-Columbian builders who lived in
5040-461: Was used as a mortar in brick chimneys and stone walls where protected from water. Clay, relatively impermeable to water, is also used where natural seals are needed, such as in pond linings, the cores of dams , or as a barrier in landfills against toxic seepage (lining the landfill, preferably in combination with geotextiles ). Studies in the early 21st century have investigated clay's absorption capacities in various applications, such as
5112-407: Was used in house construction from the 1730s to the 1860s. In Britain particularly, good quality building stone became ever more expensive during a period of rapid growth, and it became a common practice to construct prestige buildings from the new industrial bricks, and to finish them with a stucco to imitate stone. Hydraulic limes were favored for this, but the need for a fast set time encouraged
5184-720: Was used in the Eastern Roman Empire as well as in the West into the Gothic period . The German Rhineland continued to use hydraulic mortar throughout the Middle Ages, having local pozzolana deposits called trass . Tabby is a building material made from oyster shell lime, sand, and whole oyster shells to form a concrete. The Spanish introduced it to the Americas in the sixteenth century. The technical knowledge for making hydraulic cement
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