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118-643: Part of the Appalachian Mountains chain, the region does not consist of true mountains, geologically speaking, but instead a dissected plateau that is part of the Allegheny Plateau . The Catskill Mountains are the highest expression of the plateau, located to the east of the Endless Mountains, and separated from them by the Delaware River . The current geography was slightly modified during

236-441: A bath solution containing vegetable tannins, such as found in gallnuts , the leaves of sumac , the leaves of certain acacia trees, the outer green shells of walnuts , among other plants. The use of vegetable tanning is a process that takes longer than mineral tanning when converting rawhides into leather. Mineral tanned leather is used principally for shoes, car seats, and upholstery in homes (sofas, etc.). Vegetable tanned leather

354-513: A campaign to destroy the Iroquois threat by a " scorched earth " drive up the Susquehanna and Chemung Rivers into central and western New York. The region's economy was formerly based on mining , lumbering (especially of hemlock for tanning ) and industry but is now largely agricultural with forestry and tourism contributing to the economic base. Much of the land is steep, but there are

472-430: A few good farms on rolling hilltops or valley bottoms; many of these farms have been occupied by Mennonite and Amish people who have migrated northward as their traditional homelands became developed. Quarrying remains an important local industry with the region's high quality blue stone being particularly valuable. The area is on the edge of Pennsylvania's Coal Region , with some minor veins of coal extending into

590-463: A fragile ecosystem known as the Southern Appalachian spruce–fir forest . Fraser fir rarely occurs below 5,500 ft (1,700 m), and becomes the dominant tree type at 6,200 ft (1,900 m). By contrast, balsam fir is found from near sea level to the tree line in the northern Appalachians, but ranges only as far south as Virginia and West Virginia in the central Appalachians, where it

708-713: A great thickness of sediment accumulated. Eventually, the tectonic forces pulling the two continents apart became so strong that an ocean formed off the eastern coast of the Laurentian margin. This was called the Iapetus Ocean and was the precursor of the modern Atlantic Ocean. The rocks of the Valley and Ridge province formed over millions of years, in the Iapetus. Shells and other hard parts of ancient marine plants and animals accumulated to form limey deposits that later became limestone. This

826-427: A high content of glycine , proline , and hydroxyproline , usually in the repeat -gly-pro-hypro-gly-. These residues give rise to collagen's helical structure. Collagen's high content of hydroxyproline allows cross-linking by hydrogen bonding within the helical structure. Ionized carboxyl groups (RCO 2 ) are formed by the action of hydroxide. This conversion occurs during the liming process, before introduction of

944-480: A large factor in how hazardous wastewater results in contaminating the environment. This is especially prominent in small and medium-sized tanneries in developing countries. The UN Leather Working Group (LWG) "provides an environmental audit protocol, designed to assess the facilities of leather manufacturers," for "traceability, energy conservation, [and] responsible management of waste products." Untanned hides can be dried and made pliable by rubbing and stretching

1062-656: A new ocean opened up, the Rheic Ocean , during the Middle to Late Devonian, and subsequently its closure would result in the formation of the Alleghanian orogeny . As the continental plates moved closer together, fragments of oceanic crust, islands, and other continental masses collided with the eastern margin of ancestral North America. By this time, plants had appeared on land, followed by scorpions, insects, and amphibians. The ocean continued to shrink until, about 270 million years ago,

1180-504: A number of deciduous rhododendrons (azaleas), and smaller heaths such as teaberry ( Gaultheria procumbens ) and trailing arbutus ( Epigaea repens ). The evergreen great rhododendron ( Rhododendron maximum ) is characteristic of moist stream valleys. These occurrences are in line with the prevailing acidic character of most oak forest soils. In contrast, the much rarer chinquapin oak ( Quercus muehlenbergii ) demands alkaline soils and generally grows where limestone rock

1298-444: A number of serious insect and disease outbreaks. Among the most conspicuous is that of the introduced spongy moth ( Lymantria dispar ), which infests primarily oaks, causing severe defoliation and tree mortality. But it also has the benefit of eliminating weak individuals, and thus improving the genetic stock, as well as creating rich habitat of a type through accumulation of dead wood. Because hardwoods sprout so readily, this moth

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1416-403: A process which permanently alters the protein structure of skin, making it more durable and less susceptible to decomposition and coloring. The place where hides are processed is known as a tannery . The English word for tanning is from medieval Latin tannāre , derivative of tannum ( oak bark ), from French tan (tanbark), from old-Cornish tann (oak). These terms are related to

1534-430: A salt solution. After the hair was loosened, the tanners scraped it off with a knife. Once the hair was removed, the tanners would " bate " (soften) the material by pounding dung into the skin, or soaking the skin in a solution of animal brains. Bating was a fermentative process that relied on enzymes produced by bacteria found in the dung. Among the kinds of dung commonly used were those of dogs or pigeons. Historically

1652-442: A tanning agent. They are then soaked, stretched, dried, and sometimes smoked. Preparing hides begins by curing them with salt to prevent putrefaction of the collagen from bacterial growth during the time lag from procuring the hide to when it is processed. Curing removes water from the hides and skins using a difference in osmotic pressure. The moisture content of hides and skins is greatly reduced, and osmotic pressure increased, to

1770-438: A topography of very low relief. When the area was uplifted, the river's bends were preserved as incised meanders . The large river cut a deep valley and established a low baseline for its tributaries , which then cut the plateau into the rugged hills of the present day. Several Native American bands settled the area in prehistoric times. By the early colonial period, Munsee - Lenape , Susquehannock , and Iroquois peoples were

1888-539: A variety of oaks ( Quercus spp.), hickories ( Carya spp.) and, in the past, by the American chestnut ( Castanea dentata ). The American chestnut was virtually eliminated as a canopy species by the introduced fungal chestnut blight ( Cryphonectaria parasitica ), but lives on as sapling-sized sprouts that originate from roots, which are not killed by the fungus. In present-day forest canopies, chestnut has been largely replaced by oaks. The oak forests of

2006-548: A variety of other destructive activities continue, albeit in diminished forms; and thus far only a few ecologically based management practices have taken hold. Appalachian bogs are boreal ecosystems , which occur in many places in the Appalachians, particularly the Allegheny and Blue Ridge subranges. Though popularly called bogs , many of them are technically fens . Tanning (leather) Tanning , or hide tanning ,

2124-646: Is "section". The Appalachian Uplands are one of the seven physiographic divisions in Canada . Canada's GSC does not use the same classification system as the USGS below the division level. The agency does break the divisions of the Appalachian Uplands into 13 subsections that are in four different political provinces of Canada. While the Appalachian Highlands and Appalachian Uplands are generally continuous across

2242-682: Is a 2,175-mile (3,500 km) hiking trail that runs all the way from Mount Katahdin in Maine to Springer Mountain in Georgia , passing over or past a large part of the Appalachian range. The International Appalachian Trail is an extension of this hiking trail into the Canadian portion of the Appalachian range in New Brunswick and Quebec . While exploring inland along the northern coast of Florida in 1528,

2360-483: Is a boreal species that forms a few high elevation outliers as far south as West Virginia. All of these species except white pine tend to occupy sandy, rocky, poor soil sites, which are mostly acidic in character. White pine, a large species valued for its timber, tends to do best in rich, moist soil, either acidic or alkaline in character. Pitch pine is also at home in acidic, boggy soil, and Table Mountain pine may occasionally be found in this habitat as well. Shortleaf pine

2478-419: Is considered one of the most effective tanning compounds. Chromium-tanned leather can contain between 4 and 5% of chromium. This efficiency is characterized by its increased hydrothermal stability of the skin, and its resistance to shrinkage in heated water. Vegetable tanning uses tannins (a class of polyphenol astringent chemicals), which occur naturally in the bark and leaves of many plants. Tannins bind to

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2596-403: Is consistent with cross-linking by polychromium species, of the sort arising from olation and oxolation. Before the introduction of the basic chromium species in tanning, several steps are required to produce a tannable hide. The pH must be very acidic when the chromium is introduced to ensure that the chromium complexes are small enough to fit between the fibers and residues of the collagen. Once

2714-416: Is excellent for use in handbags and garments. After application of the chromium agent, the bath is treated with sodium bicarbonate in the basification process to increase the pH to 3.8–4.0, inducing cross-linking between the chromium and the collagen. The pH increase is normally accompanied by a gradual temperature increase up to 40 °C. Chromium's ability to form such stable bridged bonds explains why it

2832-403: Is found at high elevations in the northern Appalachians, and in bogs as far south as Pennsylvania. The Appalachians are also home to two species of fir, the boreal balsam fir ( Abies balsamea ), and the southern high elevation endemic, Fraser fir ( Abies fraseri ). Fraser fir is endemic to the highest parts of the southern Appalachian Mountains, where along with red spruce it forms

2950-533: Is generally found in warmer habitats and at lower elevations than the other species. All the species listed do best in open or lightly shaded habitats, although white pine also thrives in shady coves, valleys, and on floodplains. The Appalachians are characterized by a wealth of large, beautiful deciduous broadleaf (hardwood) trees. Their occurrences are best summarized and described in E. Lucy Braun 's 1950 classic, Deciduous Forests of Eastern North America (Macmillan, New York). The most diverse and richest forests are

3068-414: Is near the surface. Hence no ericaceous shrubs are associated with it. The Appalachian flora also include a diverse assemblage of bryophytes (mosses and liverworts), as well as fungi . Some species are rare and/or endemic. As with vascular plants , these tend to be closely related to the character of the soils and the thermal environment in which they are found. Eastern deciduous forests are subject to

3186-465: Is not as harmful as the hemlock woolly adelgid . Perhaps more serious is the introduced beech bark disease complex, which includes both a scale insect ( Cryptococcus fagisuga ) and fungal components. During the 19th and early 20th centuries, the Appalachian forests were subject to severe and destructive logging and land clearing, which resulted in the designation of the national forests and parks as well many state-protected areas. However, these and

3304-419: Is not very flexible. It is used for luggage, furniture, footwear, belts, and other clothing accessories. Wet white is a term used for leathers produced using alternative tanning methods that produce an off-white colored leather. Like wet blue, wet white is also a semifinished stage. Wet white can be produced using aldehydes , aluminum, zirconium, titanium, or iron salts, or a combination thereof. Concerns with

3422-517: Is now the southern United States, the Ococee Basin was formed. Seawater filled the basin. Rivers from the surrounding countryside carried clay, silt, sand, and gravel to the basin, much as rivers today carry sediment from the midcontinent region to the Gulf of Mexico. The sediment spread out in layers on the basin floor. The basin continued to subside, and over a long period of time, probably millions of years,

3540-591: Is one of the provinces of the Appalachian Highlands. The Appalachian range runs from the Island of Newfoundland in Canada, 2,050 mi (3,300 km) southwestward to Central Alabama in the United States; south of Newfoundland, it crosses the 96-square-mile (248.6 km ) archipelago of Saint Pierre and Miquelon , an overseas collectivity of France , meaning it is technically in three countries. The highest peak of

3658-535: Is possible that the cratons of Kalahari , and Rio Plato , were also part of that early collision since they were present as Rodinia broke up). Mountain-building referred to as the Grenville Orogeny occurred along the boundaries of the cratons. The present Appalachian Mountains have at least two areas which are made from rock formations that were formed during this orogeny - the Blue Ridge Mountains and

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3776-428: Is preferred. Once bating is complete, the hides and skins are treated by first soaking them in a bath containing common salt (sodium chloride), usually 1 quart of salt to 1 gallon of hot water. When the water cools, one fluid ounce of sulfuric acid is added. Small skins are left in this liquor for 2 days, while larger skins between 1 week and as much as 2 months. In vegetable tanning, the hides are made to soak in

3894-479: Is present today. The Appalachian Mountains are a barrier to east–west travel, as they form a series of alternating ridgelines and valleys oriented in opposition to most highways and railroads running east–west. This barrier was extremely important in shaping the expansion of the United States in the colonial era. The range is the home of a very popular recreational feature, the Appalachian Trail . This

4012-645: Is subject to the hemlock woolly adelgid ( Adelges tsugae ), an introduced insect, that is rapidly extirpating it as a forest tree. Less abundant, and restricted to the southern Appalachians, is Carolina hemlock ( Tsuga caroliniana ). Like Canada hemlock, this tree suffers severely from the hemlock woolly adelgid. Several species of pines characteristic of the Appalachians are eastern white pine ( Pinus strobus ), Virginia pine ( Pinus virginiana ), pitch pine ( Pinus rigida ), Table Mountain pine ( Pinus pungens ) and shortleaf pine ( Pinus echinata ). Red pine ( Pinus resinosa )

4130-421: Is tawed by soaking in a warm potash alum and salts solution, between 20 and 30 °C (68 and 86 °F). The process increases the hide's pliability, stretchability, softness, and quality. Then, the hide is air dried (crusted) for several weeks, which allows it to stabilize. The use of alum alone for tanning rawhides is not recommended, as it shrinks the surface area of the skin, making it thicker and hard to

4248-420: Is the characteristic of the keratin class of proteins that gives strength to hair and wools (keratin typically makes up 90% of the dry weight of hair). The hydrogen atoms supplied by the sharpening agent weaken the cystine molecular link whereby the covalent disulfide bond links are ultimately ruptured, weakening the keratin. To some extent, sharpening also contributes to unhairing, as it tends to break down

4366-455: Is the process of treating skins and hides of animals to produce leather . A tannery is the place where the skins are processed. Historically, vegetable based tanning used tannin , an acidic chemical compound derived from the bark of certain trees, in the production of leather. An alternative method, developed in the 1800s, is chrome tanning, where chromium salts are used instead of natural tannins. Tanning hide into leather involves

4484-506: Is the same process by which limestone forms in modern oceans. The weathering of limestone, now exposed at the land surface, produces the lime-rich soils that are so prevalent in the fertile farmland of the Valley and Ridge province. During this continental break-up, around 600 million to 560 million years ago, volcanic activity was present along the tectonic margins. There is evidence of this activity in today's Blue Ridge Mountains. Mount Rogers , Whitetop Mountain , and Pine Mountain are all

4602-439: Is used as a leather tanning agent, can cause problems in the kidneys and liver and is also considered a carcinogen . Formaldehyde and arsenic, which are used for leather finishing, cause health problems in the eyes, lungs, liver, kidneys, skin, and lymphatic system and are also considered carcinogens. The waste from leather tanneries is detrimental to the environment and the people who live in it. The use of old technologies plays

4720-461: Is used in leather crafting and in making small leather items, such as wallets, handbags and clothes. Chromium(III) sulfate ( [Cr(H 2 O) 6 ] 2 (SO 4 ) 3 ) has long been regarded as the most efficient and effective tanning agent. Chromium(III) compounds of the sort used in tanning are significantly less toxic than hexavalent chromium , although the latter arises in inadequate waste treatment. Chromium(III) sulfate dissolves to give

4838-459: Is usually confined above 3,900 ft (1,200 m) asl, except in cold valleys. Curiously, it is associated with oaks in Virginia. The balsam fir of Virginia and West Virginia is thought by some to be a natural hybrid between the more northern variety and Fraser fir. While red spruce is common in both upland and bog habitats, balsam fir, as well as black spruce and tamarack, are more characteristic of

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4956-611: The Adirondacks . After the Grenville orogeny, the direction of the continental drift reversed, and the single supercontinent Rodinia began to break up. The mountains formed during the Grenvillian era underwent erosion due to weathering, glaciation, and other natural processes, resulting in the leveling of the landscape. The eroded sediments from these mountains contributed to the formation of sedimentary basins and valleys. For example, in what

5074-581: The Coal Region of northeastern Pennsylvania . The bituminous coal fields of western Pennsylvania , western Maryland , southeastern Ohio, eastern Kentucky, southwestern Virginia , and West Virginia contain the sedimentary form of coal. The mountain top removal method of coal mining , in which entire mountain tops are removed, is currently threatening vast areas and ecosystems of the Appalachian Mountain region. The surface coal mining that started in

5192-723: The Gulf of Mexico . In the central section, north of the New River, the rivers, rising in or just beyond the Valley Ridges, flow through great gorges to the Great Valley, and then across the Blue Ridge to tidal estuaries penetrating the coastal plain via the Roanoke River, James River , Potomac River , and Susquehanna River . In the northern section the height of land lies on the inland side of

5310-704: The Iapetus Ocean , from the North America/Europe collision (See Caledonian orogeny ). By the end of the Mesozoic Era , the Appalachian Mountains had been eroded to an almost flat plain. It was not until the region was uplifted during the Cenozoic Era that the distinctive topography of the present formed. Uplift rejuvenated the streams, which rapidly responded by cutting downward into the ancient bedrock. Some streams flowed along weak layers that define

5428-484: The North American craton . Volcanoes grew along the continental margin coincident with the initiation of subduction . Thrust faulting uplifted and warped older sedimentary rock laid down on the passive margin. As the mountains rose, erosion began to wear them down over time. Streams carried rock debris downslope to be deposited in nearby lowlands. The Taconic orogeny ended after about 60 million years, but built much of

5546-497: The Sumerians began using leather, affixed by copper studs , on chariot wheels . The process of tanning was also used for boats and fishing vessels: ropes, nets, and sails were tanned using tree bark. Formerly, tanning was considered a noxious or "odoriferous trade" and relegated to the outskirts of town, among the poor. Tanning by ancient methods is so foul-smelling that tanneries are still isolated from those towns today where

5664-706: The eastern seaboard of the United States and the Midwest region of the country. The Eastern Continental Divide follows the Appalachian Mountains from Pennsylvania to Georgia. The Appalachians, particularly the Central and Southern regions, is one of the most biodiverse places in North America. The north–south orientation of the long ridges and valleys contributes to the high number of plant and animal species. Species were able to migrate through these from either direction during alternating periods of warming and cooling, settling in

5782-1546: The mixed-mesophytic or medium-moisture types, which are largely confined to rich, moist montane soils of the southern and central Appalachians, particularly in the Cumberland and Allegheny Mountains, but also thrive in the southern Appalachian coves. Characteristic canopy species are white basswood ( Tilia heterophylla ), yellow buckeye ( Aesculus octandra ), sugar maple ( Acer saccharum ), American beech ( Fagus grandifolia ), tuliptree ( Liriodendron tulipifera ), white ash ( Fraxinus americana ) and yellow birch ( Betula alleganiensis ). Other common trees are red maple ( Acer rubrum ), shagbark and bitternut hickories ( Carya ovata and C. cordiformis ) and black or sweet birch ( Betula lenta ). Small understory trees and shrubs include paw paw ( Asimina tribola ), flowering dogwood ( Cornus florida ), hophornbeam ( Ostrya virginiana ), witch-hazel ( Hamamelis virginiana ) and spicebush ( Lindera benzoin ). There are also hundreds of perennial and annual herbs, among them such herbal and medicinal plants as American ginseng ( Panax quinquefolius ), goldenseal ( Hydrastis canadensis ), bloodroot ( Sanguinaria canadensis ) and black cohosh ( Cimicifuga racemosa ). The foregoing trees, shrubs, and herbs are also more widely distributed in less rich mesic forests that generally occupy coves, stream valleys and flood plains throughout

5900-581: The 1940s has significantly impacted the central Appalachian Mountains in Kentucky , Tennessee , Virginia and West Virginia. Early mining methods were unregulated and mined land reclamation research, including acid base reaction , was led by the West Virginia University in the 1960s and 1970s. West Virginia developed rigorous mine reclamation standards for state coal mines in the late 1960s. Regulations were introduced by most federal states to protect

6018-546: The Appalachian Basin. Some plateaus of the Appalachian Mountains contain metallic minerals such as iron and zinc . There are many geological issues concerning the rivers and streams of the Appalachians. In spite of the existence of the Great Appalachian Valley, many of the main rivers are transverse to the mountain system axis. The drainage divide of the Appalachians follows a tortuous course that crosses

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6136-610: The Appalachian Mountains by the late 1960s. Social and political activism brought about the Surface Mining Control and Reclamation Act of 1977 . The 1859 discovery of commercial quantities of petroleum in the Appalachian Mountains of western Pennsylvania started the modern United States petroleum industry . Recent discoveries of commercial natural gas deposits in the Marcellus Shale formation and Utica Shale formations have once again focused oil industry attention on

6254-536: The Blue Ridge again reaches 2,000 ft (600 m) and higher. In the Virginia Blue Ridge, the following are some of the highest peaks north of the Roanoke River : Stony Man 4,031 ft (1,229 m), Hawksbill Mountain 4,066 ft (1,239 m), Apple Orchard Mountain 4,225 ft (1,288 m) and Peaks of Otter 4,001 and 3,875 ft (1,220 and 1,181 m). South of the Roanoke River, along

6372-708: The Blue Ridge, are Virginia's highest peaks including Whitetop Mountain 5,520 ft (1,680 m) and Mount Rogers 5,729 ft (1,746 m), the highest point in the Commonwealth. Chief summits in the southern section of the Blue Ridge are located along two main crests, the Western or Unaka Front along the Tennessee - North Carolina border and the Eastern Front in North Carolina, or one of several "cross ridges" between

6490-883: The Great Balsams. The Western Blue Ridge Front is subdivided into the Unaka Range , the Bald Mountains , the Great Smoky Mountains , and the Unicoi Mountains , and its major peaks include Roan Mountain 6,285 ft (1,916 m) in the Unakas, Big Bald 5,516 ft (1,681 m) and Max Patch 4,616 ft (1,407 m) in the Bald Mountains, Kuwohi 6,643 ft (2,025 m), Mount Le Conte 6,593 feet (2,010 m), and Mount Guyot 6,621 ft (2,018 m) in

6608-727: The Great Smokies, and Big Frog Mountain 4,224 ft (1,287 m) near the Tennessee- Georgia -North Carolina border. Prominent summits in the cross ridges include Waterrock Knob (6,292 ft (1,918 m)) in the Plott Balsams . Across northern Georgia, numerous peaks exceed 4,000 ft (1,200 m), including Brasstown Bald , the state's highest, at 4,784-and-4,696 ft (1,458-and-1,431 m) Rabun Bald . In north-central Alabama , Mount Cheaha rises prominently to 1,445 feet (440 m) over its surroundings, as part of

6726-564: The Penn proprietors (William Penn's sons, Richard and Thomas, and his grandson, John), who also claimed the land. (See Pennamite Wars ). During the American Revolution in 1778, a combined British, Tory, Iroquois, Munsee, and Lenape force attacked the Wyoming Valley settlers on the eastern edge of this region, and killed many of the settlers. Washington sent Major General John Sullivan on

6844-608: The Shawnee, Nanticoke, Conoy, and Tutelo were evicted by the terms of the 1768 Treaty of Fort Stanwix, which was between the Iroquois League and the British Crown. After 1768, hundreds of British, Irish, and German families flooded in from New England, New York, New Jersey, and Pennsylvania to occupy lands purchased from the Susquehanna and Connecticut Land companies of Connecticut. These settlements eventually led to armed conflict with

6962-515: The U.S./Canadian border, the St. Lawrence Valley area is handled differently in the physiographic classification schemas. The part of the St. Lawrence Valley in the United States is one of the second-level classifications, part of the Appalachian Highlands. In Canada, the area is part of the first-level classification, the St. Lawrence Lowlands . This includes the area around the city of Montreal, Anticosti Island , and

7080-411: The actual tanning process used vegetable tanning. In some variations of the process, cedar oil , alum , or tannin was applied to the skin as a tanning agent. As the skin was stretched, it would lose moisture and absorb the agent. Following the adoption in medicine of soaking gut sutures in a chromium (III) solution after 1840, it was discovered that this method could also be used with leather and thus

7198-457: The adjective Appalachian is / ˌ æ p ə ˈ l æ tʃ i ə n / , with the last two syllables "-ian" pronounced as in the word "Romanian". Perhaps partly because the range runs through large portions of both the United States and Canada, and partly because the range was formed over numerous geologic time periods, one of which is sometimes termed the Appalachian orogeny , writing communities struggle to agree on an encyclopedic definition of

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7316-551: The area. Camptown, Pennsylvania in the Endless Mountains is featured in the lyrics of " Camptown Races ", an 1850 song by Stephen Foster . 41°37′18″N 76°03′08″W  /  41.6218°N 76.0521°W  / 41.6218; -76.0521 Appalachian Mountains The Appalachian Mountains , often called the Appalachians , are a mountain range in eastern to northeastern North America . The term "Appalachian" refers to several different regions associated with

7434-485: The case of Bangladesh, chickens (the nation's most common source of protein). Up to 25% of the chickens in Bangladesh contained harmful levels of hexavalent chromium, adding to the national health problem load. Chromium is not solely responsible for these diseases. Methylisothiazolinone , which is used for microbiological protection (fungal or bacterial growth), causes problems with the eyes and skin. Anthracene , which

7552-459: The collagen proteins in the hide and coat them, causing them to become less water-soluble and more resistant to bacterial attack. The process also causes the hide to become more flexible. The primary barks processed in bark mills and used in modern times are chestnut , oak , redoul , tanoak , hemlock , quebracho , mangrove , wattle (acacia; see catechol ), and myrobalans from Terminalia spp., such as Terminalia chebula . In Ethiopia ,

7670-416: The collagen's carboxyl groups, amine groups from the side chains of the amino acids , and masking agents. Masking agents are carboxylic acids , such as acetic acid , used to suppress formation of polychromium(III) chains. Masking agents allow the tanner to further increase the pH to increase collagen's reactivity without inhibiting the penetration of the chromium(III) complexes. Collagen is characterized by

7788-540: The combined vegetable oils of Niger seed ( Guizotia abyssinica ) and flaxseeds were used in treating the flesh side of the leather, as a means of tawing, rather than of tanning. In Yemen and Egypt , hides were tanned by soaking them in a bath containing the crushed leaves and bark of the Salam acacia (Acacia etbaica; A. nilotica kraussiana). Hides that have been stretched on frames are immersed for several weeks in vats of increasing concentrations of tannin. Vegetable-tanned hide

7906-457: The continent that are now exposed. The first mountain-building tectonic plate collision that initiated the construction of what are today the Appalachians occurred at least a billion years ago when the pre-North American craton called Laurentia collided with at least one other craton - Amazonia . All the other cratons of the earth also collided at about this time to form the supercontinent Rodinia and were surrounded by one single ocean. (It

8024-641: The continents that were ancestral to North America and Africa collided during the formation of the supercontinent Pangea . Because North America and Africa were once geographically connected, the Appalachians formed part of the same mountain chain as the Little Atlas in Morocco . This mountain range, known as the Central Pangean Mountains , extended into Scotland , before the Mesozoic Era opening of

8142-412: The deciduous needle-leaf conifer, the tamarack , or eastern larch ( Larix laricina ). The dominant northern and high elevation conifer is the red spruce ( Picea rubens ), which grows from near sea level to above 4,000 ft (1,200 m) above sea level (asl) in northern New England and southeastern Canada. It also grows southward along the Appalachian crest to the highest elevations of

8260-409: The desired level of penetration of chrome into the substance is achieved, the pH of the material is raised again to facilitate the process. This step is known as basification. In the raw state, chrome-tanned skins are greyish-blue, so are referred to as wet blue . Chrome tanning is faster than vegetable tanning (taking less than a day for this part of the process) and produces a stretchable leather which

8378-529: The driest sites are dominated by chestnut oak, or sometimes by scarlet or northern red oaks. In the northern Appalachians the oaks, except for white and northern red, drop out, while the latter extends farthest north. The oak forests generally lack the diverse small tree, shrub and herb layers of mesic forests. Shrubs are generally ericaceous , and include the evergreen mountain laurel ( Kalmia latifolia ), various species of blueberries ( Vaccinium spp.), black huckleberry ( Gaylussacia baccata ),

8496-440: The eight physiographic regions of the contiguous 48 United States. The Appalachian Uplands is the name of one of seven physiographic regions of Canada. The second level in the physiographic classification schema for the USGS is "province", the same word as Canada uses to divide its political subdivisions, meaning that the terminology used by the two countries do not match below the region level. The lowest level of classification

8614-425: The end use of the leather, hides may be treated with enzymes to soften them, a process called bating . In modern tanning, these enzymes are purified agents, and the process no longer requires bacterial fermentation (as from dung-water soaking) to produce them. Pickling is another term for tanning, or what is the modern equivalent of turning rawhide into leather by the use of modern chemical agents, if mineral tanning

8732-562: The fibers with a hide stretcher, and fatting. However the hide will revert to rawhide if not periodically replenished with fat or oil, especially if it gets wet. Many Native Americans of the arid western regions wore clothing made by this process. Smoke tanning is listed among the conventional methods like chrome tanning and vegetable tanning. Impregnation of the hide's cells with formaldehyde (from smoke) offers some microbial and water resistance. Leftover leather would historically be turned into glue . Tanners would place scraps of hides in

8850-425: The folds and faults created many millions of years earlier. Other streams downcut so rapidly that they cut right across the resistant folded rocks of the mountain core, carving canyons across rock layers and geologic structures. The Appalachian Mountains contain major deposits of anthracite coal as well as bituminous coal . In the folded mountains the coal is in metamorphosed form as anthracite , represented by

8968-443: The formation of the Appalachian Mountains started 1.1 billion years ago. The first mountain range in the region was created when the continents of Laurentia and Amazonia collided, creating a supercontinent called Rodinia . The collision of these continents caused the rocks to be folded and faulted, creating the first mountains in the region. Many of the rocks and minerals that were formed during that event can currently be seen at

9086-418: The hair proteins. The isoelectric point of the collagen (a tissue-strengthening protein unrelated to keratin) in the hide is also shifted to around pH 4.7 due to liming. Any hairs remaining after liming are removed mechanically by scraping the skin with a dull knife, a process known as scudding. The pH of the collagen is then reduced so the enzymes may act on it in a process known as deliming. Depending on

9204-406: The hexaaquachromium(III) cation, [Cr(H 2 O) 6 ] , which at higher pH undergoes processes called olation to give polychromium(III) compounds that are active in tanning, being the cross-linking of the collagen subunits. The chemistry of [Cr(H 2 O) 6 ] is more complex in the tanning bath rather than in water due to the presence of a variety of ligands. Some ligands include the sulfate anion,

9322-406: The hides are soaked in clean water to remove the salt left over from curing and increase the moisture so that the hide or skin can be further treated. To prevent damage of the skin by bacterial growth during the soaking period, biocides , typically dithiocarbamates , may be used. Fungicides such as TCMTB may also be added later in the process, to protect wet leathers from mold growth. After 1980,

9440-512: The hypothetical Proto-Indo-European * dʰonu meaning ' fir tree'. (The same word is source for Old High German tanna meaning 'fir', related to modern German Tannenbaum ). Ancient civilizations used leather for waterskins , bags, harnesses and tack, boats, armour , quivers , scabbards , boots , and sandals . Tanning was being carried out by the inhabitants of Mehrgarh in Pakistan between 7000 and 3300 BCE. Around 2500 BCE ,

9558-480: The land mass that is now New England and southwestward to Pennsylvania. The Taconic Orogeny was the second of four mountain building plate collisions that contributed to the formation of the Appalachians, culminating in the collision of North America and Africa (see Alleghanian orogeny ). The third mountain-building event was the Acadian orogeny which occurred between 375 and 359 million years ago. The Acadian orogeny

9676-566: The last ice age by the Wisconsin Glacier about 15,000 years ago. Glacial striations can be found on the rocks of some of the high ridges, but the area was at the margin of the ice sheet, and the impact was much less than in New York just to the north. The mountains are made up of sedimentary rocks (mostly sandstone and shales , with a little conglomerate ) that were part of a lowland that collected sediments eroded from mountains to

9794-469: The latter. However, balsam fir also does well in soils with a pH as high as 6. Eastern or Canada hemlock ( Tsuga canadensis ) is another important evergreen needle-leaf conifer that grows along the Appalachian chain from north to south but is confined to lower elevations than red spruce and the firs. It generally occupies richer and less acidic soils than the spruce and firs and is characteristic of deep, shaded and moist mountain valleys and coves . It

9912-572: The members of the Narváez expedition , including Álvar Núñez Cabeza de Vaca , found a Native American village near present-day Tallahassee, Florida whose name they transcribed as Apalchen or Apalachen [a.paˈla.tʃɛn] . The name was soon altered by the Spanish to Apalachee and used as a name for the tribe and region spreading well inland to the north. Pánfilo de Narváez 's expedition first entered Apalachee territory on June 15, 1528, and applied

10030-528: The microclimates that best suited them. The flora of the Appalachians are diverse and vary primarily in response to geology, latitude, elevation and moisture availability. Geobotanically, they constitute a floristic province of the North American Atlantic Region . The Appalachians consist primarily of deciduous broad-leaf trees and evergreen needle-leaf conifers, but also contain the evergreen broad-leaf American holly ( Ilex opaca ), and

10148-752: The more notable peaks in West Virginia. The Blue Ridge Mountains , rising in southern Pennsylvania and there known as South Mountain , attain elevations of about 2,000 ft (600 m) in Pennsylvania. South Mountain achieves its highest point just below the Mason-Dixon line in Maryland at Quirauk Mountain 2,145 ft (654 m) and then diminishes in height southward to the Potomac River . Once in Virginia ,

10266-638: The mountain range is Mount Mitchell in North Carolina at 6,684 feet (2,037 m), which is also the highest point in the United States east of the Mississippi River . The range is older than the other major mountain range in North America, the Rocky Mountains of the west. Some of the outcrops in the Appalachians contain rocks formed during the Precambrian era. The geologic processes that led to

10384-607: The mountain range, and its surrounding terrain. The general definition used is one followed by the United States Geological Survey and the Geological Survey of Canada to describe the respective countries' physiographic regions. The U.S. uses the term Appalachian Highlands and Canada uses the term Appalachian Uplands ; the Appalachian Mountains are not synonymous with the Appalachian Plateau , which

10502-410: The mountain range. However, each of the governments has an agency that informs the public about the major landforms that make up the countries, the United States Geological Survey (USGS) and the Geological Survey of Canada (GSC). The landforms are referred to as physiographic regions. The regions create precise boundaries from which maps can be drawn. The Appalachian Highlands is the name of one of

10620-745: The mountainous belt just north of the New River in Virginia. South of the New River, rivers head into the Blue Ridge, cross the higher Unakas, receive important tributaries from the Great Valley, and traversing the Cumberland Plateau in spreading gorges ( water gaps ), escape by way of the Cumberland River and the Tennessee River rivers to the Ohio River and the Mississippi River, and thence to

10738-538: The mountainous belt, and thus the main lines of drainage run from north to south, exemplified by the Hudson River . However, the valley through which the Hudson River flows was cut by the gigantic glaciers of the ice ages —the same glaciers that deposited their terminal moraines in southern New York and formed the east–west Long Island . The Appalachian region is generally considered the geographical divide between

10856-475: The name. Now spelled "Appalachian", it is the fourth-oldest surviving European place-name in the US. After the 1540 expedition of Hernando de Soto , Spanish cartographers began to apply the name of the tribe to the mountains themselves. The first cartographic appearance of Apalchen is on Diego Gutiérrez 's map of 1562; the first use for the mountain range is the map of Jacques le Moyne de Morgues in 1565. The name

10974-531: The northwest coastline of Newfoundland. The dissected plateau area, while not actually made up of geological mountains, is popularly called "mountains", especially in eastern Kentucky and West Virginia, and while the ridges are not high, the terrain is extremely rugged. In Ohio and New York, some of the plateau has been glaciated , which has rounded off the sharp ridges and filled the valleys to some extent. The glaciated regions are usually referred to as hill country rather than mountains. The Appalachian belt includes

11092-424: The oceans, but there were no plants or animals on land. Then, during the middle Ordovician Period about 500 to 470 million years ago, the motion of the crustal plates changed, and the continents began to move back toward each other. The once-quiet Appalachian passive margin changed to a very active plate boundary when a neighboring Iapetus oceanic plate containing a volcanic arc collided with and began sinking beneath

11210-447: The old methods are used. Skins typically arrived at the tannery dried stiff and dirty with soil and gore. First, the ancient tanners would soak the skins in water to clean and soften them. Then they would pound and scour the skin to remove any remaining flesh and fat . Hair was removed by soaking the skin in urine , painting it with an alkaline lime mixture, or simply allowing the skin to putrefy for several months then dipping it in

11328-704: The plateaus sloping southward to the Atlantic Ocean in New England , and southeastward to the border of the coastal plain through the central and southern Atlantic states; and on the northwest, the Allegheny and Cumberland plateaus declining toward the Great Lakes and the interior plains. A remarkable feature of the belt is the longitudinal chain of broad valleys, including the Great Appalachian Valley , which in

11446-611: The point that bacteria are unable to grow. In wet-salting, the hides are heavily salted, then pressed into packs for about 30 days. In brine -curing, the hides are agitated in a saltwater bath for about 16 hours. Curing can also be accomplished by preserving the hides and skins at very low temperatures. The steps in the production of leather between curing and tanning are collectively referred to as beamhouse operations. They include, in order, soaking, liming , removal of extraneous tissues (unhairing, scudding and fleshing), deliming , bating or puering, drenching, and pickling. In soaking,

11564-710: The principal occupants of the region. The majority of the local place names were derived from the Munsee-Lenape, however; places like Lock-ah Hanna ( Lackawanna or Sand River), Tunk Hanna Unk ( Tunkhannock or Bend River Place), Why-ohm Ing ( Wyoming or Food Place), Min Nees Unk ( Minisink ), Toe-be Hanna ( Tobyhanna or Cool River), Mesh-op Ing ( Meshoppen ), Why-ah-loose Ing ( Wyalusing ), Schick-shin Ing ( Shickshinny ), and Mawsch Unk (Bear Place, present-day Jim Thorpe ) are examples. The Munsee and other native peoples like

11682-508: The process. Chemicals used in tanned leather production increase the levels of chemical oxygen demand and total dissolved solids in water when not disposed of responsibly. These processes also use large quantities of water and produce large amounts of pollutants. Boiling and sun drying can oxidize and convert the various chromium(III) compounds used in tanning into carcinogenic hexavalent chromium , or chromium(VI). This hexavalent chromium runoff and scraps are then consumed by animals, in

11800-482: The result of volcanic activity that occurred around this time. Evidence of subsurface activity, dikes and sills intruding into the overlying rock, is present in the Blue Ridge as well. For instance, mafic rocks have been found along the Fries Fault in the central Blue Ridge area of Montgomery County, VA. The Iapetus continued to expand and during that time bacteria, algae, and many species of invertebrates flourished in

11918-706: The same side of the Great Valley, south of the Potomac, are the Pinnacle 3,007 feet (917 m) and Pidgeon Roost 3,400 ft (1,000 m). In West Virginia, more than 150 peaks rise above 4,000 ft (1,200 m), including Spruce Knob 4,863 ft (1,482 m), the highest point in the Allegheny Mountains . A number of other points in the state rise above 4,800 ft (1,500 m). Cheat Mountain ( Snowshoe Mountain ) at Thorny Flat 4,848 ft (1,478 m) and Bald Knob 4,842 ft (1,476 m) are among

12036-409: The same trend as the system itself. None of the summits reaches the region of perpetual snow. In Pennsylvania , there are over sixty summits that rise over 2,500 ft (800 m); the summits of Mount Davis and Blue Knob rise over 3,000 ft (900 m). In Maryland, Eagle Rock and Dans Mountain are conspicuous points reaching 3,162 and 2,882 ft (964 and 878 m) respectively. On

12154-459: The southeast in Mississippian and Pennsylvanian geologic time. The area has been uplifted and lowered several times. The highest points are all nearly the same elevation, establishing that the area had once been eroded into a nearly level peneplain , which has since been uplifted. The present Susquehanna River established its meandering course during that time, when it was a mature stream on

12272-481: The southerly sections divides the mountain system into two unequal portions, but in the northernmost lies west of all the ranges possessing typical Appalachian features, and separates them from the Adirondack group. The mountain system has no axis of dominating altitudes, but in every portion, the summits rise to rather uniform heights, and, especially in the central section, the various ridges and intermontane valleys have

12390-416: The southern Appalachians, as in North Carolina and Tennessee . In the central Appalachians it is usually confined above 3,000 ft (900 m) asl, except for a few cold valleys in which it reaches lower elevations. In the southern Appalachians, it is restricted to higher elevations. Another species is the black spruce ( Picea mariana ), which extends farthest north of any conifer in North America,

12508-413: The southern and central Appalachians consist largely of black , northern red , white , chestnut and scarlet oaks ( Quercus velutina, Q. rubra, Q. alba, Q. prinus and Q. coccinea ) and hickories, such as the pignut ( Carya glabra ) in particular. The richest forests, which grade into mesic types, usually in coves and on gentle slopes, have predominantly white and northern red oaks, while

12626-511: The southern and central Appalachians at low and intermediate elevations. In the northern Appalachians and at higher elevations of the central and southern Appalachians these diverse mesic forests give way to less diverse northern hardwood forests with canopies dominated only by American beech, sugar maple, American basswood ( Tilia americana ) and yellow birch and with far fewer species of shrubs and herbs. Drier and rockier uplands and ridges are occupied by oak–chestnut forests dominated by

12744-535: The southernmost spur of the Blue Ridge Mountains. Sources written prior to the recognition of the concept of physiographic regions divided the Appalachian Mountains into three major sections: Plate tectonics over the period dating back at least 1 billion years led to geological creation of the land that is now the Appalachian Mountain range. The continental movement led to collisions that built mountains and they later pulled apart creating oceans over parts of

12862-495: The surface of the present Appalachian range. Around 480 million years ago, geologic processes began that led to three distinct orogenic eras that created much of the surface structure seen in today's Appalachians. During this period, mountains once reached elevations similar to those of the Alps and the Rockies before natural erosion occurred over the last 240 million years leading to what

12980-403: The tanning agent (chromium salts). Later during pickling, collagen carboxyl groups are temporarily protonated for ready transport of chromium ions. During basification step of tanning, the carboxyl groups are ionized and coordinate as ligands to the chromium(III) centers of the oxo-hydroxide clusters. Tanning increases the spacing between protein chains in collagen from 10 to 17 Å. The difference

13098-411: The third syllable sounding like "latch". In northern parts of the mountain range, it is pronounced / ˌ æ p ə ˈ l eɪ tʃ ɪ n z / or / ˌ æ p ə ˈ l eɪ ʃ ɪ n z / ; the third syllable is like "lay", and the fourth "chins" or "shins". There is often great debate between the residents of the regions regarding the correct pronunciation. Elsewhere, a commonly accepted pronunciation for

13216-407: The touch. If alum is applied to the fur, it makes the fur dull and harsh. Depending on the finish desired, the leather may be waxed, rolled, lubricated, injected with oil, split, shaved, or dyed. The tanning process involves chemical and organic compounds that can have a detrimental effect on the environment. Agents such as chromium, vegetable tannins, and aldehydes are used in the tanning step of

13334-492: The toxicity and environmental impact of any chromium (VI) that may form during the tanning process have led to increased research into more efficient wet white methods. The conditions present in bogs, including highly acidic water, low temperature, and a lack of oxygen, combine to preserve but severely tan the skin of bog bodies . Tawing is a method that uses alum and other aluminium salts , generally in conjunction with binders such as egg yolk, flour, or other salts. The hide

13452-607: The two main crests. Major subranges of the Eastern Front include the Black Mountains , Great Craggy Mountains , and Great Balsam Mountains , and its chief summits include Grandfather Mountain 5,964 ft (1,818 m) near the Tennessee-North Carolina border, Mount Mitchell 6,684 ft (2,037 m) in the Blacks, and Black Balsam Knob 6,214 ft (1,894 m) and Cold Mountain 6,030 ft (1,840 m) in

13570-418: The use of pentachlorophenol and mercury -based biocides and their derivatives was forbidden. After soaking, the hides are treated with milk of lime (a basic agent) typically supplemented by "sharpening agents" (disulfide reducing agents) such as sodium sulfide , cyanides , amines , etc. This: The weakening of hair is dependent on the breakdown of the disulfide link of the amino acid cystine , which

13688-487: Was adopted by tanners. The tanning process begins with obtaining an animal skin. When an animal skin is to be tanned, the animal is killed and skinned before the body heat leaves the tissues. This can be done by the tanner, or by obtaining a skin at a slaughterhouse, farm, or local fur trader. Before tanning, the skins are often dehaired, then have fat, meat and connective tissue removed. They are then washed and soaked in water with various compounds, and prepared to receive

13806-639: Was caused by a series of collisions of pieces of crust from the Avalonia Terrane, sections broken off from continent of Gondwana , with the North American Plate. The collision initiating this orogeny resulted in the closing of the southern Iapetus Ocean and the formation of a high mountain belt. After the Acadian collision took place, Gondwana began to retreat from Laurentia with the newly accreted Avalonian terranes left behind. As Gondwana moved away,

13924-442: Was not commonly used for the whole mountain range until the late 19th century. A competing and often more popular name was the "Allegheny Mountains", "Alleghenies", and even "Alleghania". In the early 19th century, Washington Irving proposed renaming the United States either Appalachia or Alleghania. In U.S. dialects in the southern regions of the Appalachians, the word is pronounced / ˌ æ p ə ˈ l æ tʃ ɪ n z / , with

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