138-466: Boron is a chemical element . It has the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid ; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three valence electrons for forming covalent bonds , resulting in many compounds such as boric acid , the mineral sodium borate , and the ultra-hard crystals of boron carbide and boron nitride . Boron
276-675: A government monopoly on the mining of borate minerals in Turkey, which possesses 72% of the world's known deposits. In 2012, it held a 47% share of production of global borate minerals, ahead of its main competitor, Rio Tinto Group . Almost a quarter (23%) of global boron production comes from the single Rio Tinto Borax Mine (also known as the U.S. Borax Boron Mine) 35°2′34.447″N 117°40′45.412″W / 35.04290194°N 117.67928111°W / 35.04290194; -117.67928111 ( Rio Tinto Borax Mine ) near Boron, California . The average cost of crystalline elemental boron
414-738: A pure element . In chemistry, a pure element means a substance whose atoms all (or in practice almost all) have the same atomic number, or number of protons . Nuclear scientists, however, define a pure element as one that consists of only one isotope. For example, a copper wire is 99.99% chemically pure if 99.99% of its atoms are copper, with 29 protons each. However it is not isotopically pure since ordinary copper consists of two stable isotopes, 69% Cu and 31% Cu, with different numbers of neutrons. However, pure gold would be both chemically and isotopically pure, since ordinary gold consists only of one isotope, Au. Atoms of chemically pure elements may bond to each other chemically in more than one way, allowing
552-451: A superacid . As one example, carboranes form useful molecular moieties that add considerable amounts of boron to other biochemicals in order to synthesize boron-containing compounds for boron neutron capture therapy for cancer. As anticipated by its hydride clusters , boron forms a variety of stable compounds with formal oxidation state less than three. B 2 F 4 and B 4 Cl 4 are well characterized. Binary metal-boron compounds,
690-507: A burial site located in the western industrial zone of Varna , approximately 4 km from the city centre, internationally considered one of the key archaeological sites in world prehistory. The oldest gold treasure in the world, dating from 4,600 BC to 4,200 BC, was discovered at the site. The gold piece dating from 4,500 BC, found in 2019 in Durankulak , near Varna is another important example. Other signs of early metals are found from
828-540: A considerable amount of time. (See element naming controversy ). Precursors of such controversies involved the nationalistic namings of elements in the late 19th century. For example, lutetium was named in reference to Paris, France. The Germans were reluctant to relinquish naming rights to the French, often calling it cassiopeium . Similarly, the British discoverer of niobium originally named it columbium , in reference to
966-477: A different element in nuclear reactions , which change an atom's atomic number. Historically, the term "chemical element" meant a substance that cannot be broken down into constituent substances by chemical reactions, and for most practical purposes this definition still has validity. There was some controversy in the 1920s over whether isotopes deserved to be recognized as separate elements if they could be separated by chemical means. The term "(chemical) element"
1104-410: A ductile to brittle transition and lose their toughness, becoming more brittle and prone to cracking. Metals under continual cyclic loading can suffer from metal fatigue . Metals under constant stress at elevated temperatures can creep . Cold-working processes, in which the product's shape is altered by rolling, fabrication or other processes, while the product is cold, can increase the strength of
1242-643: A few decay products, to have been differentiated from other elements. Most recently, the synthesis of element 118 (since named oganesson ) was reported in October 2006, and the synthesis of element 117 ( tennessine ) was reported in April 2010. Of these 118 elements, 94 occur naturally on Earth. Six of these occur in extreme trace quantities: technetium , atomic number 43; promethium , number 61; astatine , number 85; francium , number 87; neptunium , number 93; and plutonium , number 94. These 94 elements have been detected in
1380-525: A few elements, such as silver and gold , are found uncombined as relatively pure native element minerals . Nearly all other naturally occurring elements occur in the Earth as compounds or mixtures. Air is mostly a mixture of molecular nitrogen and oxygen , though it does contain compounds including carbon dioxide and water , as well as atomic argon , a noble gas which is chemically inert and therefore does not undergo chemical reactions. The history of
1518-646: A fractional difference between the B and B and traditionally expressed in parts per thousand, in natural waters ranging from −16 to +59. There are 13 known isotopes of boron; the shortest-lived isotope is B which decays through proton emission and alpha decay with a half-life of 3.5×10 s. Isotopic fractionation of boron is controlled by the exchange reactions of the boron species B(OH) 3 and [B(OH) 4 ] . Boron isotopes are also fractionated during mineral crystallization, during H 2 O phase changes in hydrothermal systems, and during hydrothermal alteration of rock . The latter effect results in preferential removal of
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#17328511772221656-413: A liquid bath. Metallurgists study the microscopic and macroscopic structure of metals using metallography , a technique invented by Henry Clifton Sorby . In metallography, an alloy of interest is ground flat and polished to a mirror finish. The sample can then be etched to reveal the microstructure and macrostructure of the metal. The sample is then examined in an optical or electron microscope , and
1794-401: A major concern. Cast irons, including ductile iron , are also part of the iron-carbon system. Iron-Manganese-Chromium alloys (Hadfield-type steels) are also used in non-magnetic applications such as directional drilling. Other engineering metals include aluminium , chromium , copper , magnesium , nickel , titanium , zinc , and silicon . These metals are most often used as alloys with
1932-534: A new element and named it boracium . Gay-Lussac and Thénard used iron to reduce boric acid at high temperatures. By oxidizing boron with air, they showed that boric acid is its oxidation product. Jöns Jacob Berzelius identified it as an element in 1824. Pure boron was arguably first produced by the American chemist Ezekiel Weintraub in 1909. Some early routes to elemental boron involved the reduction of boric oxide with metals such as magnesium or aluminium . However,
2070-500: A pressure of 1 bar and a given temperature (typically at 298.15K). However, for phosphorus, the reference state is white phosphorus even though it is not the most stable allotrope, and the reference state for carbon is graphite, because the structure of graphite is more stable than that of the other allotropes. In thermochemistry , an element is defined to have an enthalpy of formation of zero in its reference state. Several kinds of descriptive categorizations can be applied broadly to
2208-483: A pressure of one atmosphere, are commonly used in characterizing the various elements. While known for most elements, either or both of these measurements is still undetermined for some of the radioactive elements available in only tiny quantities. Since helium remains a liquid even at absolute zero at atmospheric pressure, it has only a boiling point, and not a melting point, in conventional presentations. The density at selected standard temperature and pressure (STP)
2346-403: A protective oxide or hydroxide layer is formed on the surface of boron, which prevents further corrosion. The rate of oxidation of boron depends on the crystallinity, particle size, purity and temperature. At higher temperatures boron burns to form boron trioxide : Boron undergoes halogenation to give trihalides; for example, The trichloride in practice is usually made from the oxide. Boron
2484-456: A small group, (the metalloids ), having intermediate properties and often behaving as semiconductors . A more refined classification is often shown in colored presentations of the periodic table. This system restricts the terms "metal" and "nonmetal" to only certain of the more broadly defined metals and nonmetals, adding additional terms for certain sets of the more broadly viewed metals and nonmetals. The version of this classification used in
2622-615: A smelted copper axe dating from 5,500 BC, belonging to the Vinča culture . The Balkans and adjacent Carpathian region were the location of major Chalcolithic cultures including Vinča , Varna , Karanovo , Gumelnița and Hamangia , which are often grouped together under the name of ' Old Europe '. With the Carpatho-Balkan region described as the 'earliest metallurgical province in Eurasia', its scale and technical quality of metal production in
2760-563: A superior metal could be made, an alloy called bronze . This represented a major technological shift known as the Bronze Age . The extraction of iron from its ore into a workable metal is much more difficult than for copper or tin. The process appears to have been invented by the Hittites in about 1200 BC, beginning the Iron Age . The secret of extracting and working iron was a key factor in
2898-484: A tendency to form novel dodecahedral (12-sided) and icosahedral (20-sided) structures composed completely of boron atoms, or with varying numbers of carbon heteroatoms. Organoboron chemicals have been employed in uses as diverse as boron carbide (see below), a complex very hard ceramic composed of boron-carbon cluster anions and cations, to carboranes , carbon-boron cluster chemistry compounds that can be halogenated to form reactive structures including carborane acid ,
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#17328511772223036-403: A trigonal planar configuration. Unlike silicates, boron minerals never contain it with coordination number greater than four. A typical motif is exemplified by the tetraborate anions of the common mineral borax . The formal negative charge of the tetrahedral borate center is balanced by metal cations in the minerals, such as the sodium (Na) in borax. The tourmaline group of borate-silicates is also
3174-608: A very important boron-bearing mineral group, and a number of borosilicates are also known to exist naturally. Boranes are chemical compounds of boron and hydrogen, with the generic formula of B x H y . These compounds do not occur in nature. Many of the boranes readily oxidise on contact with air, some violently. The parent member BH 3 is called borane, but it is known only in the gaseous state, and dimerises to form diborane, B 2 H 6 . The larger boranes all consist of boron clusters that are polyhedral, some of which exist as isomers. For example, isomers of B 20 H 26 are based on
3312-474: A whole number. For example, the relative atomic mass of chlorine is 35.453 u, which differs greatly from a whole number as it is an average of about 76% chlorine-35 and 24% chlorine-37. Whenever a relative atomic mass value differs by more than ~1% from a whole number, it is due to this averaging effect, as significant amounts of more than one isotope are naturally present in a sample of that element. Chemists and nuclear scientists have different definitions of
3450-404: Is 10 (for tin , element 50). The mass number of an element, A , is the number of nucleons (protons and neutrons) in the atomic nucleus. Different isotopes of a given element are distinguished by their mass number, which is written as a superscript on the left hand side of the chemical symbol (e.g., U). The mass number is always an integer and has units of "nucleons". Thus, magnesium-24 (24
3588-455: Is US$ 5/g. Elemental boron is chiefly used in making boron fibers, where it is deposited by chemical vapor deposition on a tungsten core (see below). Boron fibers are used in lightweight composite applications, such as high strength tapes. This use is a very small fraction of total boron use. Boron is introduced into semiconductors as boron compounds, by ion implantation. Estimated global consumption of boron (almost entirely as boron compounds)
3726-606: Is a mixture of C (about 98.9%), C (about 1.1%) and about 1 atom per trillion of C. Most (54 of 94) naturally occurring elements have more than one stable isotope. Except for the isotopes of hydrogen (which differ greatly from each other in relative mass—enough to cause chemical effects), the isotopes of a given element are chemically nearly indistinguishable. All elements have radioactive isotopes (radioisotopes); most of these radioisotopes do not occur naturally. Radioisotopes typically decay into other elements via alpha decay , beta decay , or inverse beta decay ; some isotopes of
3864-401: Is a chemical surface-treatment technique. It involves bonding a thin layer of another metal such as gold , silver , chromium or zinc to the surface of the product. This is done by selecting the coating material electrolyte solution, which is the material that is going to coat the workpiece (gold, silver, zinc). There needs to be two electrodes of different materials: one the same material as
4002-406: Is a dimensionless number equal to the atomic mass divided by the atomic mass constant , which equals 1 Da. In general, the mass number of a given nuclide differs in value slightly from its relative atomic mass, since the mass of each proton and neutron is not exactly 1 Da; since the electrons contribute a lesser share to the atomic mass as neutron number exceeds proton number; and because of
4140-426: Is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements , their inter-metallic compounds , and their mixtures, which are known as alloys . Metallurgy encompasses both the science and the technology of metals, including the production of metals and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy
4278-536: Is a relatively poor electrical and thermal conductor in the planar directions. A large number of organoboron compounds are known and many are useful in organic synthesis . Many are produced from hydroboration , which employs diborane , B 2 H 6 , a simple borane chemical, or carboboration . Organoboron(III) compounds are usually tetrahedral or trigonal planar, for example, tetraphenylborate , [B(C 6 H 5 ) 4 ] vs. triphenylborane , B(C 6 H 5 ) 3 . However, multiple boron atoms reacting with each other have
Boron - Misplaced Pages Continue
4416-448: Is a relatively rare element in the Earth's crust, representing only 0.001% of the crust mass, it can be highly concentrated by the action of water, in which many borates are soluble. It is found naturally combined in compounds such as borax and boric acid (sometimes found in volcanic spring waters). About a hundred borate minerals are known. On 5 September 2017, scientists reported that
4554-452: Is an additive in fiberglass for insulation and structural materials. The next leading use is in polymers and ceramics in high-strength, lightweight structural and heat-resistant materials. Borosilicate glass is desired for its greater strength and thermal shock resistance than ordinary soda lime glass. As sodium perborate , it is used as a bleach . A small amount is used as a dopant in semiconductors , and reagent intermediates in
4692-504: Is an essential plant nutrient . The word boron was coined from borax , the mineral from which it was isolated, by analogy with carbon , which boron resembles chemically. Borax in its mineral form (then known as tincal) first saw use as a glaze, beginning in China circa 300 AD. Some crude borax traveled westward, and was apparently mentioned by the alchemist Jabir ibn Hayyan around 700 AD. Marco Polo brought some glazes back to Italy in
4830-443: Is an industrial coating process that consists of a heat source (flame or other) and a coating material that can be in a powder or wire form, which is melted then sprayed on the surface of the material being treated at a high velocity. The spray treating process is known by many different names such as HVOF (High Velocity Oxygen Fuel), plasma spray, flame spray, arc spray and metalizing. Electroless deposition (ED) or electroless plating
4968-812: Is an ongoing area of scientific study. The lightest elements are hydrogen and helium , both created by Big Bang nucleosynthesis in the first 20 minutes of the universe in a ratio of around 3:1 by mass (or 12:1 by number of atoms), along with tiny traces of the next two elements, lithium and beryllium . Almost all other elements found in nature were made by various natural methods of nucleosynthesis . On Earth, small amounts of new atoms are naturally produced in nucleogenic reactions, or in cosmogenic processes, such as cosmic ray spallation . New atoms are also naturally produced on Earth as radiogenic daughter isotopes of ongoing radioactive decay processes such as alpha decay , beta decay , spontaneous fission , cluster decay , and other rarer modes of decay. Of
5106-460: Is based on a Latin or other traditional word, for example adopting "gold" rather than "aurum" as the name for the 79th element (Au). IUPAC prefers the British spellings " aluminium " and "caesium" over the U.S. spellings "aluminum" and "cesium", and the U.S. "sulfur" over British "sulphur". However, elements that are practical to sell in bulk in many countries often still have locally used national names, and countries whose national language does not use
5244-782: Is called the atomic number of that element. For example, oxygen has an atomic number of 8, meaning each oxygen atom has 8 protons in its nucleus. Atoms of the same element can have different numbers of neutrons in their nuclei, known as isotopes of the element. Two or more atoms can combine to form molecules . Some elements are formed from molecules of identical atoms , e. g. atoms of hydrogen (H) form diatomic molecules (H 2 ). Chemical compounds are substances made of atoms of different elements; they can have molecular or non-molecular structure. Mixtures are materials containing different chemical substances; that means (in case of molecular substances) that they contain different types of molecules. Atoms of one element can be transformed into atoms of
5382-708: Is collected and processed to extract valuable metals. Ore bodies often contain more than one valuable metal. Tailings of a previous process may be used as a feed in another process to extract a secondary product from the original ore. Additionally, a concentrate may contain more than one valuable metal. That concentrate would then be processed to separate the valuable metals into individual constituents. Much effort has been placed on understanding iron –carbon alloy system, which includes steels and cast irons . Plain carbon steels (those that contain essentially only carbon as an alloying element) are used in low-cost, high-strength applications, where neither weight nor corrosion are
5520-455: Is defined as the autocatalytic process through which metals and metal alloys are deposited onto nonconductive surfaces. These nonconductive surfaces include plastics, ceramics, and glass etc., which can then become decorative, anti-corrosive, and conductive depending on their final functions. Electroless deposition is a chemical processes that create metal coatings on various materials by autocatalytic chemical reduction of metal cations in
5658-414: Is distinct from the craft of metalworking . Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist. The science of metallurgy is further subdivided into two broad categories: chemical metallurgy and physical metallurgy . Chemical metallurgy is chiefly concerned with
Boron - Misplaced Pages Continue
5796-644: Is found in the Balkans and Carpathian Mountains , as evidenced by findings of objects made by metal casting and smelting dated to around 6000-5000 BC. Certain metals, such as tin, lead, and copper can be recovered from their ores by simply heating the rocks in a fire or blast furnace in a process known as smelting. The first evidence of copper smelting, dating from the 6th millennium BC, has been found at archaeological sites in Majdanpek , Jarmovac and Pločnik , in present-day Serbia . The site of Pločnik has produced
5934-548: Is high energy spallation neutrons. Such neutrons can be moderated by materials high in light elements, such as polyethylene , but the moderated neutrons continue to be a radiation hazard unless actively absorbed in the shielding. Among light elements that absorb thermal neutrons, Li and B appear as potential spacecraft structural materials which serve both for mechanical reinforcement and radiation protection. Cosmic radiation will produce secondary neutrons if it hits spacecraft structures. Those neutrons will be captured in B, if it
6072-436: Is often used in characterizing the elements. Density is often expressed in grams per cubic centimetre (g/cm ). Since several elements are gases at commonly encountered temperatures, their densities are usually stated for their gaseous forms; when liquefied or solidified, the gaseous elements have densities similar to those of the other elements. When an element has allotropes with different densities, one representative allotrope
6210-420: Is present in the spacecraft's semiconductors , producing a gamma ray , an alpha particle , and a lithium ion. Those resultant decay products may then irradiate nearby semiconductor "chip" structures, causing data loss (bit flipping, or single event upset ). In radiation-hardened semiconductor designs, one countermeasure is to use depleted boron , which is greatly enriched in B and contains almost no B. This
6348-593: Is rare and poorly studied because the pure material is extremely difficult to prepare. Most studies of "boron" involve samples that contain small amounts of carbon. The chemical behavior of boron resembles that of silicon more than aluminium . Crystalline boron is chemically inert and resistant to attack by boiling hydrofluoric or hydrochloric acid . When finely divided, it is attacked slowly by hot concentrated hydrogen peroxide , hot concentrated nitric acid , hot sulfuric acid or hot mixture of sulfuric and chromic acids . When exposed to air, under normal conditions,
6486-624: Is rare in the Universe and solar system due to trace formation in the Big Bang and in stars. It is formed in minor amounts in cosmic ray spallation nucleosynthesis and may be found uncombined in cosmic dust and meteoroid materials. In the high oxygen environment of Earth, boron is always found fully oxidized to borate. Boron does not appear on Earth in elemental form. Extremely small traces of elemental boron were detected in Lunar regolith. Although boron
6624-428: Is selectively taken up by a malignant tumor and tissues near it. The patient is then treated with a beam of low energy neutrons at a relatively low neutron radiation dose. The neutrons, however, trigger energetic and short-range secondary alpha particle and lithium-7 heavy ion radiation that are products of the boron-neutron nuclear reaction , and this ion radiation additionally bombards the tumor, especially from inside
6762-456: Is silvery to black, extremely hard (9.3 on the Mohs scale ), and a poor electrical conductor at room temperature (1.5 × 10 Ω cm room temperature electrical conductivity). The primary use of the element itself is as boron filaments with applications similar to carbon fibers in some high-strength materials. Boron is primarily used in chemical compounds. About half of all production consumed globally
6900-599: Is synthesized entirely by cosmic ray spallation and supernovas and not by stellar nucleosynthesis , so it is a low-abundance element in the Solar System and in the Earth's crust . It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals . These are mined industrially as evaporites , such as borax and kernite . The largest known deposits are in Turkey ,
7038-502: Is the lightest element having an electron in a p-orbital in its ground state. Unlike most other p-elements , it rarely obeys the octet rule and usually places only six electrons (in three molecular orbitals ) onto its valence shell . Boron is the prototype for the boron group (the IUPAC group 13), although the other members of this group are metals and more typical p-elements (only aluminium to some extent shares boron's aversion to
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#17328511772227176-426: Is the mass number) is an atom with 24 nucleons (12 protons and 12 neutrons). Whereas the mass number simply counts the total number of neutrons and protons and is thus an integer, the atomic mass of a particular isotope (or "nuclide") of the element is the mass of a single atom of that isotope, and is typically expressed in daltons (symbol: Da), or universal atomic mass units (symbol: u). Its relative atomic mass
7314-530: Is the more common one in the United Kingdom . The / ˈ m ɛ t əl ɜːr dʒ i / pronunciation is the more common one in the United States US and is the first-listed variant in various American dictionaries, including Merriam-Webster Collegiate and American Heritage . The earliest metal employed by humans appears to be gold , which can be found " native ". Small amounts of natural gold, dating to
7452-439: Is the most common and stable. An α-tetragonal phase also exists (α-T), but is very difficult to produce without significant contamination. Most of the phases are based on B 12 icosahedra, but the γ phase can be described as a rocksalt -type arrangement of the icosahedra and B 2 atomic pairs. It can be produced by compressing other boron phases to 12–20 GPa and heating to 1500–1800 °C; it remains stable after releasing
7590-532: Is typically selected in summary presentations, while densities for each allotrope can be stated where more detail is provided. For example, the three familiar allotropes of carbon ( amorphous carbon , graphite , and diamond ) have densities of 1.8–2.1, 2.267, and 3.515 g/cm , respectively. The elements studied to date as solid samples have eight kinds of crystal structures : cubic , body-centered cubic , face-centered cubic, hexagonal , monoclinic , orthorhombic , rhombohedral , and tetragonal . For some of
7728-549: Is used as an abrasive, as it has a hardness comparable with diamond (the two substances are able to produce scratches on each other). In the BN compound analogue of graphite, hexagonal boron nitride (h-BN), the positively charged boron and negatively charged nitrogen atoms in each plane lie adjacent to the oppositely charged atom in the next plane. Consequently, graphite and h-BN have very different properties, although both are lubricants, as these planes slip past each other easily. However, h-BN
7866-438: Is used in the petrochemical industry as a catalyst. The halides react with water to form boric acid . It is found in nature on Earth almost entirely as various oxides of B(III), often associated with other elements. More than one hundred borate minerals contain boron in oxidation state +3. These minerals resemble silicates in some respect, although it is often found not only in a tetrahedral coordination with oxygen, but also in
8004-417: Is used in two different but closely related meanings: it can mean a chemical substance consisting of a single kind of atoms, or it can mean that kind of atoms as a component of various chemical substances. For example, molecules of water (H 2 O) contain atoms of hydrogen (H) and oxygen (O), so water can be said as a compound consisting of the elements hydrogen (H) and oxygen (O) even though it does not contain
8142-430: Is used up and the fuel becomes less reactive. In future crewed interplanetary spacecraft, B has a theoretical role as structural material (as boron fibers or BN nanotube material) which would also serve a special role in the radiation shield. One of the difficulties in dealing with cosmic rays , which are mostly high energy protons, is that some secondary radiation from interaction of cosmic rays and spacecraft materials
8280-632: Is useful because B is largely immune to radiation damage. Depleted boron is a byproduct of the nuclear industry (see above). B is also a candidate as a fuel for aneutronic fusion . When struck by a proton with energy of about 500 k eV , it produces three alpha particles and 8.7 MeV of energy. Most other fusion reactions involving hydrogen and helium produce penetrating neutron radiation, which weakens reactor structures and induces long-term radioactivity, thereby endangering operating personnel. The alpha particles from B fusion can be turned directly into electric power, and all radiation stops as soon as
8418-446: Is useful for capturing thermal neutrons (see neutron cross section#Typical cross sections ). The nuclear industry enriches natural boron to nearly pure B. The less-valuable by-product, depleted boron, is nearly pure B. Because of its high neutron cross-section, boron-10 is often used to control fission in nuclear reactors as a neutron-capturing substance. Several industrial-scale enrichment processes have been developed; however, only
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#17328511772228556-429: Is very strong; fullerenes , which have nearly spherical shapes; and carbon nanotubes , which are tubes with a hexagonal structure (even these may differ from each other in electrical properties). The ability of an element to exist in one of many structural forms is known as 'allotropy'. The reference state of an element is defined by convention, usually as the thermodynamically most stable allotrope and physical state at
8694-585: Is widely used. For example, the French chemical terminology distinguishes élément chimique (kind of atoms) and corps simple (chemical substance consisting of a single kind of atoms); the Russian chemical terminology distinguishes химический элемент and простое вещество . Almost all baryonic matter in the universe is composed of elements (among rare exceptions are neutron stars ). When different elements undergo chemical reactions, atoms are rearranged into new compounds held together by chemical bonds . Only
8832-670: The Curiosity rover detected boron, an essential ingredient for life on Earth , on the planet Mars . Such a finding, along with previous discoveries that water may have been present on ancient Mars, further supports the possible early habitability of Gale Crater on Mars. Economically important sources of boron are the minerals colemanite , rasorite ( kernite ), ulexite and tincal . Together these constitute 90% of mined boron-containing ore. The largest global borax deposits known, many still untapped, are in Central and Western Turkey , including
8970-480: The International Union of Pure and Applied Chemistry (IUPAC) had recognized a total of 118 elements. The first 94 occur naturally on Earth , and the remaining 24 are synthetic elements produced in nuclear reactions. Save for unstable radioactive elements (radioelements) which decay quickly, nearly all elements are available industrially in varying amounts. The discovery and synthesis of further new elements
9108-625: The Latin alphabet are likely to use the IUPAC element names. According to IUPAC, element names are not proper nouns; therefore, the full name of an element is not capitalized in English, even if derived from a proper noun , as in californium and einsteinium . Isotope names are also uncapitalized if written out, e.g., carbon-12 or uranium-235 . Chemical element symbols (such as Cf for californium and Es for einsteinium), are always capitalized (see below). In
9246-589: The New World . It was used extensively as such by American publications before the international standardization (in 1950). Before chemistry became a science , alchemists designed arcane symbols for both metals and common compounds. These were however used as abbreviations in diagrams or procedures; there was no concept of atoms combining to form molecules . With his advances in the atomic theory of matter, John Dalton devised his own simpler symbols, based on circles, to depict molecules. Metallurgy Metallurgy
9384-423: The kinetic isotope effect is significant). Thus, all carbon isotopes have nearly identical chemical properties because they all have six electrons, even though they may have 6 to 8 neutrons. That is why atomic number, rather than mass number or atomic weight , is considered the identifying characteristic of an element. The symbol for atomic number is Z . Isotopes are atoms of the same element (that is, with
9522-405: The nuclear binding energy and electron binding energy. For example, the atomic mass of chlorine-35 to five significant digits is 34.969 Da and that of chlorine-37 is 36.966 Da. However, the relative atomic mass of each isotope is quite close to its mass number (always within 1%). The only isotope whose atomic mass is exactly a natural number is C, which has a mass of 12 Da; because
9660-590: The synthesis of organic fine chemicals . A few boron-containing organic pharmaceuticals are used or are in study. Natural boron is composed of two stable isotopes, one of which ( boron-10 ) has a number of uses as a neutron-capturing agent. The intersection of boron with biology is very small. Consensus on it as essential for mammalian life is lacking. Borates have low toxicity in mammals (similar to table salt ) but are more toxic to arthropods and are occasionally used as insecticides . Boron-containing organic antibiotics are known. Although only traces are required, it
9798-551: The 13th century. Georgius Agricola , in around 1600, reported the use of borax as a flux in metallurgy . In 1777, boric acid was recognized in the hot springs ( soffioni ) near Florence , Italy, at which point it became known as sal sedativum , with ostensible medical benefits. The mineral was named sassolite , after Sasso Pisano in Italy. Sasso was the main source of European borax from 1827 to 1872, when American sources replaced it. Boron compounds were relatively rarely used until
9936-518: The 6th–5th millennia BC totally overshadowed that of any other contemporary production centre. The earliest documented use of lead (possibly native or smelted) in the Near East dates from the 6th millennium BC, is from the late Neolithic settlements of Yarim Tepe and Arpachiyah in Iraq . The artifacts suggest that lead smelting may have predated copper smelting. Metallurgy of lead has also been found in
10074-638: The 94 naturally occurring elements, those with atomic numbers 1 through 82 each have at least one stable isotope (except for technetium , element 43 and promethium , element 61, which have no stable isotopes). Isotopes considered stable are those for which no radioactive decay has yet been observed. Elements with atomic numbers 83 through 94 are unstable to the point that radioactive decay of all isotopes can be detected. Some of these elements, notably bismuth (atomic number 83), thorium (atomic number 90), and uranium (atomic number 92), have one or more isotopes with half-lives long enough to survive as remnants of
10212-642: The Balkans during the same period. Copper smelting is documented at sites in Anatolia and at the site of Tal-i Iblis in southeastern Iran from c. 5000 BC. Copper smelting is first documented in the Delta region of northern Egypt in c. 4000 BC, associated with the Maadi culture . This represents the earliest evidence for smelting in Africa. The Varna Necropolis , Bulgaria , is
10350-487: The French, Italians, Greeks, Portuguese and Poles prefer "azote/azot/azoto" (from roots meaning "no life") for "nitrogen". For purposes of international communication and trade, the official names of the chemical elements both ancient and more recently recognized are decided by the International Union of Pure and Applied Chemistry (IUPAC), which has decided on a sort of international English language, drawing on traditional English names even when an element's chemical symbol
10488-454: The [B(OH) 4 ] ion onto clays. It results in solutions enriched in B(OH) 3 and therefore may be responsible for the large B enrichment in seawater relative to both oceanic crust and continental crust; this difference may act as an isotopic signature . The exotic B exhibits a nuclear halo , i.e. its radius is appreciably larger than that predicted by the liquid drop model . The B isotope
10626-487: The atomic masses of the elements (their atomic weights or atomic masses) do not always increase monotonically with their atomic numbers. The naming of various substances now known as elements precedes the atomic theory of matter, as names were given locally by various cultures to various minerals, metals, compounds, alloys, mixtures, and other materials, though at the time it was not known which chemicals were elements and which compounds. As they were identified as elements,
10764-476: The borons is then simply the ratio of hydrogen to boron in the molecule. For example, in diborane B 2 H 6 , the boron oxidation state is +3, but in decaborane B 10 H 14 , it is / 5 or +1.4. In these compounds the oxidation state of boron is often not a whole number. The boron nitrides are notable for the variety of structures that they adopt. They exhibit structures analogous to various allotropes of carbon , including graphite, diamond, and nanotubes. In
10902-413: The chemical substances (di)hydrogen (H 2 ) and (di)oxygen (O 2 ), as H 2 O molecules are different from H 2 and O 2 molecules. For the meaning "chemical substance consisting of a single kind of atoms", the terms "elementary substance" and "simple substance" have been suggested, but they have not gained much acceptance in English chemical literature, whereas in some other languages their equivalent
11040-402: The cluster compounds dodecaborate ( B 12 H 12 ), decaborane (B 10 H 14 ), and the carboranes such as C 2 B 10 H 12 . Characteristically such compounds contain boron with coordination numbers greater than four. Boron has two naturally occurring and stable isotopes , B (80.1%) and B (19.9%). The mass difference results in a wide range of δB values, which are defined as
11178-416: The coating material and one that is receiving the coating material. Two electrodes are electrically charged and the coating material is stuck to the work piece. It is used to reduce corrosion as well as to improve the product's aesthetic appearance. It is also used to make inexpensive metals look like the more expensive ones (gold, silver). Shot peening is a cold working process used to finish metal parts. In
11316-471: The contemplated high luminosity version of the Large Hadron Collider . Certain other metal borides find specialized applications as hard materials for cutting tools. Often the boron in borides has fractional oxidation states, such as −1/3 in calcium hexaboride (CaB 6 ). From the structural perspective, the most distinctive chemical compounds of boron are the hydrides. Included in this series are
11454-408: The dalton is defined as 1/12 of the mass of a free neutral carbon-12 atom in the ground state. The standard atomic weight (commonly called "atomic weight") of an element is the average of the atomic masses of all the chemical element's isotopes as found in a particular environment, weighted by isotopic abundance, relative to the atomic mass unit. This number may be a fraction that is not close to
11592-462: The diamond-like structure, called cubic boron nitride (tradename Borazon ), boron atoms exist in the tetrahedral structure of carbon atoms in diamond, but one in every four B-N bonds can be viewed as a coordinate covalent bond , wherein two electrons are donated by the nitrogen atom which acts as the Lewis base to a bond to the Lewis acidic boron(III) centre. Cubic boron nitride, among other applications,
11730-416: The discovery and use of elements began with early human societies that discovered native minerals like carbon , sulfur , copper and gold (though the modern concept of an element was not yet understood). Attempts to classify materials such as these resulted in the concepts of classical elements , alchemy , and similar theories throughout history. Much of the modern understanding of elements developed from
11868-406: The elements are available by name, atomic number, density, melting point, boiling point and chemical symbol , as well as ionization energy . The nuclides of stable and radioactive elements are also available as a list of nuclides , sorted by length of half-life for those that are unstable. One of the most convenient, and certainly the most traditional presentation of the elements, is in the form of
12006-470: The elements are often summarized using the periodic table, which powerfully and elegantly organizes the elements by increasing atomic number into rows ( "periods" ) in which the columns ( "groups" ) share recurring ("periodic") physical and chemical properties. The table contains 118 confirmed elements as of 2021. Although earlier precursors to this presentation exist, its invention is generally credited to Russian chemist Dmitri Mendeleev in 1869, who intended
12144-480: The elements can be uniquely sequenced by atomic number, conventionally from lowest to highest (as in a periodic table), sets of elements are sometimes specified by such notation as "through", "beyond", or "from ... through", as in "through iron", "beyond uranium", or "from lanthanum through lutetium". The terms "light" and "heavy" are sometimes also used informally to indicate relative atomic numbers (not densities), as in "lighter than carbon" or "heavier than lead", though
12282-413: The elements without any stable isotopes are technetium (atomic number 43), promethium (atomic number 61), and all observed elements with atomic number greater than 82. Of the 80 elements with at least one stable isotope, 26 have only one stable isotope. The mean number of stable isotopes for the 80 stable elements is 3.1 stable isotopes per element. The largest number of stable isotopes for a single element
12420-474: The elements, including consideration of their general physical and chemical properties, their states of matter under familiar conditions, their melting and boiling points, their densities, their crystal structures as solids, and their origins. Several terms are commonly used to characterize the general physical and chemical properties of the chemical elements. A first distinction is between metals , which readily conduct electricity , nonmetals , which do not, and
12558-492: The existing names for anciently known elements (e.g., gold, mercury, iron) were kept in most countries. National differences emerged over the element names either for convenience, linguistic niceties, or nationalism. For example, German speakers use "Wasserstoff" (water substance) for "hydrogen", "Sauerstoff" (acid substance) for "oxygen" and "Stickstoff" (smothering substance) for "nitrogen"; English and some other languages use "sodium" for "natrium", and "potassium" for "kalium"; and
12696-630: The explosive stellar nucleosynthesis that produced the heavy metals before the formation of our Solar System . At over 1.9 × 10 years, over a billion times longer than the estimated age of the universe, bismuth-209 has the longest known alpha decay half-life of any isotope, and is almost always considered on par with the 80 stable elements. The heaviest elements (those beyond plutonium, element 94) undergo radioactive decay with half-lives so short that they are not found in nature and must be synthesized . There are now 118 known elements. In this context, "known" means observed well enough, even from just
12834-529: The formation of Earth, they are certain to have completely decayed, and if present in novae, are in quantities too small to have been noted. Technetium was the first purportedly non-naturally occurring element synthesized, in 1937, though trace amounts of technetium have since been found in nature (and also the element may have been discovered naturally in 1925). This pattern of artificial production and later natural discovery has been repeated with several other radioactive naturally occurring rare elements. List of
12972-632: The formation of elemental boron, but exploits the convenient availability of borates. Boron is similar to carbon in its capability to form stable covalently bonded molecular networks. Even nominally disordered ( amorphous ) boron contains regular boron icosahedra which are bonded randomly to each other without long-range order . Crystalline boron is a very hard, black material with a melting point of above 2000 °C. It forms four major allotropes : α-rhombohedral and β-rhombohedral (α-R and β-R), γ-orthorhombic (γ) and β-tetragonal (β-T). All four phases are stable at ambient conditions , and β-rhombohedral
13110-412: The fractionated vacuum distillation of the dimethyl ether adduct of boron trifluoride (DME-BF 3 ) and column chromatography of borates are being used. Enriched boron or B is used in both radiation shielding and is the primary nuclide used in neutron capture therapy of cancer . In the latter ("boron neutron capture therapy" or BNCT), a compound containing B is incorporated into a pharmaceutical which
13248-433: The fusion of two 10-atom clusters. The most important boranes are diborane B 2 H 6 and two of its pyrolysis products, pentaborane B 5 H 9 and decaborane B 10 H 14 . A large number of anionic boron hydrides are known, e.g. [B 12 H 12 ]. The formal oxidation number in boranes is positive, and is based on the assumption that hydrogen is counted as −1 as in active metal hydrides. The mean oxidation number for
13386-431: The half-lives predicted for the observationally stable lead isotopes range from 10 to 10 years. Elements with atomic numbers 43, 61, and 83 through 94 are unstable enough that their radioactive decay can be detected. Three of these elements, bismuth (element 83), thorium (90), and uranium (92) have one or more isotopes with half-lives long enough to survive as remnants of the explosive stellar nucleosynthesis that produced
13524-399: The heaviest elements also undergo spontaneous fission . Isotopes that are not radioactive, are termed "stable" isotopes. All known stable isotopes occur naturally (see primordial nuclide ). The many radioisotopes that are not found in nature have been characterized after being artificially produced. Certain elements have no stable isotopes and are composed only of radioisotopes: specifically
13662-543: The heavy elements before the formation of the Solar System. For example, at over 1.9 × 10 years, over a billion times longer than the estimated age of the universe, bismuth-209 has the longest known alpha decay half-life of any isotope. The last 24 elements (those beyond plutonium, element 94) undergo radioactive decay with short half-lives and cannot be produced as daughters of longer-lived elements, and thus are not known to occur in nature at all. 1 The properties of
13800-619: The highly developed and complex processes of mining metal ores, metal extraction, and metallurgy of the time. Agricola has been described as the "father of metallurgy". Extractive metallurgy is the practice of removing valuable metals from an ore and refining the extracted raw metals into a purer form. In order to convert a metal oxide or sulphide to a purer metal, the ore must be reduced physically, chemically , or electrolytically . Extractive metallurgists are interested in three primary streams: feed, concentrate (metal oxide/sulphide) and tailings (waste). After mining, large pieces of
13938-402: The image contrast provides details on the composition, mechanical properties, and processing history. Crystallography , often using diffraction of x-rays or electrons , is another valuable tool available to the modern metallurgist. Crystallography allows identification of unknown materials and reveals the crystal structure of the sample. Quantitative crystallography can be used to calculate
14076-501: The joining of metals (including welding , brazing , and soldering ). Emerging areas for metallurgists include nanotechnology , superconductors , composites , biomedical materials , electronic materials (semiconductors) and surface engineering . Metallurgy derives from the Ancient Greek μεταλλουργός , metallourgós , "worker in metal", from μέταλλον , métallon , "mine, metal" + ἔργον , érgon , "work" The word
14214-418: The largest producer of boron minerals. Elemental boron is a metalloid that is found in small amounts in meteoroids , but chemically uncombined boron is not otherwise found naturally on Earth. Industrially, the very pure element is produced with difficulty because of contamination by carbon or other elements that resist removal. Several allotropes exist: amorphous boron is a brown powder; crystalline boron
14352-555: The late Paleolithic period, 40,000 BC, have been found in Spanish caves. Silver , copper , tin and meteoric iron can also be found in native form, allowing a limited amount of metalworking in early cultures. Early cold metallurgy, using native copper not melted from mineral has been documented at sites in Anatolia and at the site of Tell Maghzaliyah in Iraq , dating from the 7th/6th millennia BC. The earliest archaeological support of smelting (hot metallurgy) in Eurasia
14490-549: The late 1800s when Francis Marion Smith 's Pacific Coast Borax Company first popularized and produced them in volume at low cost. Boron was not recognized as an element until it was isolated by Sir Humphry Davy and by Joseph Louis Gay-Lussac and Louis Jacques Thénard . In 1808 Davy observed that electric current sent through a solution of borates produced a brown precipitate on one of the electrodes. In his subsequent experiments, he used potassium to reduce boric acid instead of electrolysis . He produced enough boron to confirm
14628-412: The metal borides, contain boron in negative oxidation states. Illustrative is magnesium diboride (MgB 2 ). Each boron atom has a formal −1 charge and magnesium is assigned a formal charge of +2. In this material, the boron centers are trigonal planar with an extra double bond for each boron, forming sheets akin to the carbon in graphite . However, unlike hexagonal boron nitride, which lacks electrons in
14766-450: The most familiar compounds, boron has the formal oxidation state III. These include oxides, borates, sulfides, nitrides, and halides. The trihalides adopt a planar trigonal structure. These compounds are Lewis acids in that they readily form adducts with electron-pair donors, which are called Lewis bases . For example, fluoride (F) and boron trifluoride (BF 3 ) combined to give the tetrafluoroborate anion, BF 4 . Boron trifluoride
14904-553: The noted exception of silicon, which is not a metal. Other forms include: In production engineering , metallurgy is concerned with the production of metallic components for use in consumer or engineering products. This involves production of alloys, shaping, heat treatment and surface treatment of product. The task of the metallurgist is to achieve balance between material properties, such as cost, weight , strength , toughness , hardness , corrosion , fatigue resistance and performance in temperature extremes. To achieve this goal,
15042-428: The octet rule). Boron also has much lower electronegativity than subsequent period 2 elements . For the latter, lithium salts are common e.g. lithium fluoride , lithium hydroxide , lithium amide , and methyllithium , but lithium boryllides are extraordinarily rare. Strong bases do not deprotonate a borohydride R 2 BH to the boryl anion R 2 B, instead forming the octet-complete adduct R 2 HB-base. In
15180-507: The operating environment must be carefully considered. Determining the hardness of the metal using the Rockwell, Vickers, and Brinell hardness scales is a commonly used practice that helps better understand the metal's elasticity and plasticity for different applications and production processes. In a saltwater environment, most ferrous metals and some non-ferrous alloys corrode quickly. Metals exposed to cold or cryogenic conditions may undergo
15318-482: The ore feed are broken through crushing or grinding in order to obtain particles small enough, where each particle is either mostly valuable or mostly waste. Concentrating the particles of value in a form supporting separation enables the desired metal to be removed from waste products. Mining may not be necessary, if the ore body and physical environment are conducive to leaching . Leaching dissolves minerals in an ore body and results in an enriched solution. The solution
15456-418: The periodic table, which groups together elements with similar chemical properties (and usually also similar electronic structures). The atomic number of an element is equal to the number of protons in each atom, and defines the element. For example, all carbon atoms contain 6 protons in their atomic nucleus ; so the atomic number of carbon is 6. Carbon atoms may have different numbers of neutrons; atoms of
15594-426: The periodic tables presented here includes: actinides , alkali metals , alkaline earth metals , halogens , lanthanides , transition metals , post-transition metals , metalloids , reactive nonmetals , and noble gases . In this system, the alkali metals, alkaline earth metals, and transition metals, as well as the lanthanides and the actinides, are special groups of the metals viewed in a broader sense. Similarly,
15732-402: The piece being treated. The compression stress in the surface of the material strengthens the part and makes it more resistant to fatigue failure, stress failures, corrosion failure, and cracking. Thermal spraying techniques are another popular finishing option, and often have better high temperature properties than electroplated coatings. Thermal spraying, also known as a spray welding process,
15870-451: The plane of the covalent atoms, the delocalized electrons in magnesium diboride allow it to conduct electricity similar to isoelectronic graphite. In 2001, this material was found to be a high-temperature superconductor . It is a superconductor under active development. A project at CERN to make MgB 2 cables has resulted in superconducting test cables able to carry 20,000 amperes for extremely high current distribution applications, such as
16008-445: The process of shot peening, small round shot is blasted against the surface of the part to be finished. This process is used to prolong the product life of the part, prevent stress corrosion failures, and also prevent fatigue. The shot leaves small dimples on the surface like a peen hammer does, which cause compression stress under the dimple. As the shot media strikes the material over and over, it forms many overlapping dimples throughout
16146-666: The product by a process called work hardening . Work hardening creates microscopic defects in the metal, which resist further changes of shape. Metals can be heat-treated to alter the properties of strength, ductility, toughness, hardness and resistance to corrosion. Common heat treatment processes include annealing, precipitation strengthening , quenching, and tempering: Often, mechanical and thermal treatments are combined in what are known as thermo-mechanical treatments for better properties and more efficient processing of materials. These processes are common to high-alloy special steels, superalloys and titanium alloys. Electroplating
16284-417: The product was often contaminated with borides of those metals. Pure boron can be prepared by reducing volatile boron halides with hydrogen at high temperatures. Ultrapure boron for use in the semiconductor industry is produced by the decomposition of diborane at high temperatures and then further purified by the zone melting or Czochralski processes . The production of boron compounds does not involve
16422-1008: The production of metals. Metal production begins with the processing of ores to extract the metal, and includes the mixture of metals to make alloys . Metal alloys are often a blend of at least two different metallic elements. However, non-metallic elements are often added to alloys in order to achieve properties suitable for an application. The study of metal production is subdivided into ferrous metallurgy (also known as black metallurgy ) and non-ferrous metallurgy , also known as colored metallurgy. Ferrous metallurgy involves processes and alloys based on iron , while non-ferrous metallurgy involves processes and alloys based on other metals. The production of ferrous metals accounts for 95% of world metal production. Modern metallurgists work in both emerging and traditional areas as part of an interdisciplinary team alongside material scientists and other engineers. Some traditional areas include mineral processing, metal production, heat treatment, failure analysis , and
16560-542: The provinces of Eskişehir , Kütahya and Balıkesir . Global proven boron mineral mining reserves exceed one billion metric tonnes, against a yearly production of about four million tonnes. Turkey and the United States are the largest producers of boron products. Turkey produces about half of the global yearly demand, through Eti Mine Works ( Turkish : Eti Maden İşletmeleri ) a Turkish state-owned mining and chemicals company focusing on boron products. It holds
16698-412: The pure element to exist in multiple chemical structures ( spatial arrangements of atoms ), known as allotropes , which differ in their properties. For example, carbon can be found as diamond , which has a tetrahedral structure around each carbon atom; graphite , which has layers of carbon atoms with a hexagonal structure stacked on top of each other; graphene , which is a single layer of graphite that
16836-772: The reactive nonmetals and the noble gases are nonmetals viewed in the broader sense. In some presentations, the halogens are not distinguished, with astatine identified as a metalloid and the others identified as nonmetals. Another commonly used basic distinction among the elements is their state of matter (phase), whether solid , liquid , or gas , at standard temperature and pressure (STP). Most elements are solids at STP, while several are gases. Only bromine and mercury are liquid at 0 degrees Celsius (32 degrees Fahrenheit) and 1 atmosphere pressure; caesium and gallium are solid at that temperature, but melt at 28.4°C (83.2°F) and 29.8°C (85.6°F), respectively. Melting and boiling points , typically expressed in degrees Celsius at
16974-407: The reactor is turned off. Both B and B possess nuclear spin . The nuclear spin of B is 3 and that of B is 3 / 2 . These isotopes are, therefore, of use in nuclear magnetic resonance spectroscopy; and spectrometers specially adapted to detecting the boron-11 nuclei are available commercially. The B and B nuclei also cause splitting in the resonances of attached nuclei. Boron
17112-641: The reduction and oxidation of metals, and the chemical performance of metals. Subjects of study in chemical metallurgy include mineral processing , the extraction of metals , thermodynamics , electrochemistry , and chemical degradation ( corrosion ). In contrast, physical metallurgy focuses on the mechanical properties of metals, the physical properties of metals, and the physical performance of metals. Topics studied in physical metallurgy include crystallography , material characterization , mechanical metallurgy, phase transformations , and failure mechanisms . Historically, metallurgy has predominately focused on
17250-919: The remaining 11 elements have half lives too short for them to have been present at the beginning of the Solar System, and are therefore considered transient elements. Of these 11 transient elements, five ( polonium , radon , radium , actinium , and protactinium ) are relatively common decay products of thorium and uranium . The remaining six transient elements (technetium, promethium, astatine, francium , neptunium , and plutonium ) occur only rarely, as products of rare decay modes or nuclear reaction processes involving uranium or other heavy elements. Elements with atomic numbers 1 through 82, except 43 (technetium) and 61 (promethium), each have at least one isotope for which no radioactive decay has been observed. Observationally stable isotopes of some elements (such as tungsten and lead ), however, are predicted to be slightly radioactive with very long half-lives: for example,
17388-495: The same element having different numbers of neutrons are known as isotopes of the element. The number of protons in the nucleus also determines its electric charge , which in turn determines the number of electrons of the atom in its non-ionized state. The electrons are placed into atomic orbitals that determine the atom's chemical properties . The number of neutrons in a nucleus usually has very little effect on an element's chemical properties; except for hydrogen (for which
17526-404: The same number of protons in their nucleus), but having different numbers of neutrons . Thus, for example, there are three main isotopes of carbon. All carbon atoms have 6 protons, but they can have either 6, 7, or 8 neutrons. Since the mass numbers of these are 12, 13 and 14 respectively, said three isotopes are known as carbon-12 , carbon-13 , and carbon-14 ( C, C, and C). Natural carbon
17664-457: The second half of the 20th century, physics laboratories became able to produce elements with half-lives too short for an appreciable amount of them to exist at any time. These are also named by IUPAC, which generally adopts the name chosen by the discoverer. This practice can lead to the controversial question of which research group actually discovered an element, a question that delayed the naming of elements with atomic number of 104 and higher for
17802-771: The success of the Philistines . Historical developments in ferrous metallurgy can be found in a wide variety of past cultures and civilizations. This includes the ancient and medieval kingdoms and empires of the Middle East and Near East , ancient Iran , ancient Egypt , ancient Nubia , and Anatolia in present-day Turkey , Ancient Nok , Carthage , the Celts , Greeks and Romans of ancient Europe , medieval Europe, ancient and medieval China , ancient and medieval India , ancient and medieval Japan , amongst others. A 16th century book by Georg Agricola , De re metallica , describes
17940-496: The synthetically produced transuranic elements, available samples have been too small to determine crystal structures. Chemical elements may also be categorized by their origin on Earth, with the first 94 considered naturally occurring, while those with atomic numbers beyond 94 have only been produced artificially via human-made nuclear reactions. Of the 94 naturally occurring elements, 83 are considered primordial and either stable or weakly radioactive. The longest-lived isotopes of
18078-955: The table to illustrate recurring trends in the properties of the elements. The layout of the table has been refined and extended over time as new elements have been discovered and new theoretical models have been developed to explain chemical behavior. Use of the periodic table is now ubiquitous in chemistry, providing an extremely useful framework to classify, systematize and compare all the many different forms of chemical behavior. The table has also found wide application in physics , geology , biology , materials science , engineering , agriculture , medicine , nutrition , environmental health , and astronomy . Its principles are especially important in chemical engineering . The various chemical elements are formally identified by their unique atomic numbers, their accepted names, and their chemical symbols . The known elements have atomic numbers from 1 to 118, conventionally presented as Arabic numerals . Since
18216-532: The temperature and pressure. The β-T phase is produced at similar pressures, but higher temperatures of 1800–2200 °C. The α-T and β-T phases might coexist at ambient conditions, with the β-T phase being the more stable. Compressing boron above 160 GPa produces a boron phase with an as yet unknown structure, and this phase is a superconductor at temperatures below 6–12 K. Borospherene ( fullerene -like B 40 molecules) and borophene (proposed graphene -like structure) were described in 2014. Elemental boron
18354-552: The third millennium BC in Palmela , Portugal, Los Millares , Spain, and Stonehenge , United Kingdom. The precise beginnings, however, have not be clearly ascertained and new discoveries are both continuous and ongoing. In approximately 1900 BC, ancient iron smelting sites existed in Tamil Nadu . In the Near East , about 3,500 BC, it was discovered that by combining copper and tin,
18492-440: The tumor cells. In nuclear reactors, B is used for reactivity control and in emergency shutdown systems . It can serve either function in the form of borosilicate control rods or as boric acid . In pressurized water reactors , B boric acid is added to the reactor coolant after the plant is shut down for refueling. When the plant is started up again, the boric acid is slowly filtered out over many months as fissile material
18630-561: The universe at large, in the spectra of stars and also supernovae, where short-lived radioactive elements are newly being made. The first 94 elements have been detected directly on Earth as primordial nuclides present from the formation of the Solar System , or as naturally occurring fission or transmutation products of uranium and thorium. The remaining 24 heavier elements, not found today either on Earth or in astronomical spectra, have been produced artificially: all are radioactive, with short half-lives; if any of these elements were present at
18768-528: The work of Dmitri Mendeleev , a Russian chemist who published the first recognizable periodic table in 1869. This table organizes the elements by increasing atomic number into rows (" periods ") in which the columns (" groups ") share recurring ("periodic") physical and chemical properties . The periodic table summarizes various properties of the elements, allowing chemists to derive relationships between them and to make predictions about elements not yet discovered, and potential new compounds. By November 2016,
18906-407: Was about 4 million tonnes of B 2 O 3 in 2012. As compounds such as borax and kernite its cost was US$ 377/tonne in 2019. Boron mining and refining capacities are considered to be adequate to meet expected levels of growth through the next decade. Chemical element A chemical element is a chemical substance whose atoms all have the same number of protons . The number of protons
19044-434: Was originally an alchemist 's term for the extraction of metals from minerals, the ending -urgy signifying a process, especially manufacturing: it was discussed in this sense in the 1797 Encyclopædia Britannica . In the late 19th century, metallurgy's definition was extended to the more general scientific study of metals, alloys, and related processes. In English , the / m ɛ ˈ t æ l ər dʒ i / pronunciation
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