A metallurgical furnace , often simply referred to as a furnace when the context is known, is an industrial furnace used to heat , melt, or otherwise process metals . Furnaces have been a central piece of equipment throughout the history of metallurgy ; processing metals with heat is even its own engineering specialty known as pyrometallurgy .
94-488: A bloomery is a type of metallurgical furnace once used widely for smelting iron from its oxides . The bloomery was the earliest form of smelter capable of smelting iron. Bloomeries produce a porous mass of iron and slag called a bloom . The mix of slag and iron in the bloom, termed sponge iron , is usually consolidated and further forged into wrought iron . Blast furnaces , which produce pig iron , have largely superseded bloomeries. A bloomery consists of
188-415: A pit or chimney with heat-resistant walls made of earth, clay , or stone . Near the bottom, one or more pipes (made of clay or metal) enter through the side walls. These pipes, called tuyeres , allow air to enter the furnace, either by natural draught or forced with bellows or a trompe . An opening at the bottom of the bloomery may be used to remove the bloom, or the bloomery can be tipped over and
282-412: A BOS process is manufactured in one-twelfth the time. Today, electric arc furnaces (EAF) are a common method of reprocessing scrap metal to create new steel. They can also be used for converting pig iron to steel, but they use a lot of electrical energy (about 440 kWh per metric ton), and are thus generally only economical when there is a plentiful supply of cheap electricity. The steel industry
376-453: A bloomery is iron that is easily forgeable , it requires a low carbon content. The temperature and ratio of charcoal to iron ore must be carefully controlled to keep the iron from absorbing too much carbon and thus becoming unforgeable. Cast iron occurs when the iron absorbs 2% to 4% carbon. Because the bloomery is self- fluxing , the addition of limestone is not required to form a slag. The small particles of iron produced in this way fall to
470-399: A bloomery's size is increased, the iron ore is exposed to burning charcoal for a longer time. When combined with the strong air blast required to penetrate the large ore and charcoal stack, this may cause part of the iron to melt and become saturated with carbon in the process, producing unforgeable pig iron, which requires oxidation to be reduced into cast iron, steel, and iron. This pig iron
564-531: A brittle alloy commonly called pig iron . Alloy steel is steel to which other alloying elements have been intentionally added to modify the characteristics of steel. Common alloying elements include: manganese , nickel , chromium , molybdenum , boron , titanium , vanadium , tungsten , cobalt , and niobium . Additional elements, most frequently considered undesirable, are also important in steel: phosphorus , sulphur , silicon , and traces of oxygen , nitrogen , and copper . Plain carbon-iron alloys with
658-684: A carbon-intermediate steel by the 1st century AD. There is evidence that carbon steel was made in Western Tanzania by the ancestors of the Haya people as early as 2,000 years ago by a complex process of "pre-heating" allowing temperatures inside a furnace to reach 1300 to 1400 °C. Evidence of the earliest production of high carbon steel in South Asia is found in Kodumanal in Tamil Nadu ,
752-444: A change of volume. In this case, expansion occurs. Internal stresses from this expansion generally take the form of compression on the crystals of martensite and tension on the remaining ferrite, with a fair amount of shear on both constituents. If quenching is done improperly, the internal stresses can cause a part to shatter as it cools. At the very least, they cause internal work hardening and other microscopic imperfections. It
846-428: A ferrite BCC crystal form, but at higher carbon content it takes a body-centred tetragonal (BCT) structure. There is no thermal activation energy for the transformation from austenite to martensite. There is no compositional change so the atoms generally retain their same neighbours. Martensite has a lower density (it expands during the cooling) than does austenite, so that the transformation between them results in
940-538: A furnace is seen as an unfortunate event. Conversely, starting up a new furnace, or one that had been temporarily shut down, is often a special occasion. In traditional bloomeries, several rounds of fuel would need to be burnt away before the furnace was ready to accept a charge of ore. In English, this process became known as "blowing in" the furnace, while a furnace that had to be shut down and went cold had been "blown out", terms that are still applied to contemporary blast furnaces. A reverberatory furnace still exposes
1034-583: A hard oxide forms on the metal surface; this is known as stainless steel . Tungsten slows the formation of cementite , keeping carbon in the iron matrix and allowing martensite to preferentially form at slower quench rates, resulting in high-speed steel . The addition of lead and sulphur decrease grain size, thereby making the steel easier to turn , but also more brittle and prone to corrosion. Such alloys are nevertheless frequently used for components such as nuts, bolts, and washers in applications where toughness and corrosion resistance are not paramount. For
SECTION 10
#17328587597921128-445: A hard but brittle martensitic structure. The steel is then tempered, which is just a specialized type of annealing, to reduce brittleness. In this application the annealing (tempering) process transforms some of the martensite into cementite, or spheroidite and hence it reduces the internal stresses and defects. The result is a more ductile and fracture-resistant steel. When iron is smelted from its ore, it contains more carbon than
1222-432: A high iron content, it can also be broken up and may be recycled into the bloomery with the new ore. In operation, after the bloomery is heated typically with a wood fire, shifting to burning sized charcoal, iron ore and additional charcoal are introduced through the top. Again, traditional methods vary, but normally smaller charges of ore are added at the start of the main smelting sequence, increasing to larger amounts as
1316-460: A higher carbon content) by manipulating the charge of and air flow to the bloomery is also possible. As the era of modern commercial steelmaking began, the word "bloom" was extended to another sense referring to an intermediate-stage piece of steel , of a size comparable to many traditional iron blooms, that was ready to be further worked into billet . The onset of the Iron Age in most parts of
1410-434: A higher than 2.1% carbon content are known as cast iron . With modern steelmaking techniques such as powder metal forming, it is possible to make very high-carbon (and other alloy material) steels, but such are not common. Cast iron is not malleable even when hot, but it can be formed by casting as it has a lower melting point than steel and good castability properties. Certain compositions of cast iron, while retaining
1504-569: A lesser extent) to remove any moisture in the ore. Any large impurities (as silica) in the ore can be removed as it is crushed. The desired particle size depends primarily on which of several ore types may be available, which will also have a relationship to the layout and operation of the furnace, of which a number of regional, historic/traditional forms exist. Natural iron ores can vary considerably in oxide form ( Fe 2 O 3 / Fe 3 O 4 / FeO(OH) ), and importantly in relative iron content. Since slag from previous blooms may have
1598-412: A narrow range of concentrations of mixtures of carbon and iron that make steel, several different metallurgical structures, with very different properties can form. Understanding such properties is essential to making quality steel. At room temperature , the most stable form of pure iron is the body-centred cubic (BCC) structure called alpha iron or α-iron. It is a fairly soft metal that can dissolve only
1692-403: A natural draft effect (into the range of 200 cm tall), and increasing bloom sizes into the range of 10–15 kg. Contemporary experimenters had routinely made blooms using Northern European-derived "short-shaft" furnaces with blown air supplies in the 5–10 kg range The use of waterwheels , spreading around the turn of the first millennium and used to power more massive bellows, allowed
1786-448: A noncarburized bloom, this pound, fold, and weld process resulted in a more homogeneous product and removed much of the slag. The process had to be repeated up to 15 times when high-quality steel was needed, as for a sword. The alternative was to carburize the surface of a finished product. Each welding's heat oxidises some carbon, so the master smith had to make sure enough carbon was in the starting mixture. In England and Wales, despite
1880-559: A single chamber. Mechanisms, such as bellows or motorized fans, then drive pressurized blasts of air into the chamber. These blasts make the fuel burn hotter and drive chemical reactions. Furnaces of this type include: Even smaller, pre-industrial bloomeries possess significant thermal mass . Raising a cold furnace to the necessary temperature for smelting iron requires a significant amount of energy, regardless of modern technology. For this reason, metallurgists will try their best to keep blast furnaces running continuously, and shutting down
1974-534: A small concentration of carbon, no more than 0.005% at 0 °C (32 °F) and 0.021 wt% at 723 °C (1,333 °F). The inclusion of carbon in alpha iron is called ferrite . At 910 °C, pure iron transforms into a face-centred cubic (FCC) structure, called gamma iron or γ-iron. The inclusion of carbon in gamma iron is called austenite. The more open FCC structure of austenite can dissolve considerably more carbon, as much as 2.1%, (38 times that of ferrite) carbon at 1,148 °C (2,098 °F), which reflects
SECTION 20
#17328587597922068-416: A spongy mass referred to as the bloom . Because the bloom is typically porous , and its open spaces can be full of slag, the extracted mass must be beaten with heavy hammers to both compress voids and drive out any molten slag remaining. This process may require several additional heating and compaction cycles, working at high 'welding' temperatures. Iron treated this way is said to be wrought (worked), and
2162-448: A steel's final rolling, it is heat treated for strength; however, this is relatively rare. Steel was known in antiquity and was produced in bloomeries and crucibles . The earliest known production of steel is seen in pieces of ironware excavated from an archaeological site in Anatolia ( Kaman-Kalehöyük ) which are nearly 4,000 years old, dating from 1800 BC. Wootz steel
2256-477: A subsequent step. Other materials are often added to the iron/carbon mixture to produce steel with the desired properties. Nickel and manganese in steel add to its tensile strength and make the austenite form of the iron-carbon solution more stable, chromium increases hardness and melting temperature, and vanadium also increases hardness while making it less prone to metal fatigue . To inhibit corrosion, at least 11% chromium can be added to steel so that
2350-424: A wind-driven furnace was found in an excavation site. Such furnaces were powered by the monsoon winds and have been dated to 300 BC using radiocarbon-dating techniques. These ancient Lankan furnaces might have produced the best-quality steel for legendary Damascus swords as referred in earlier Syrian records. Field trials using replica furnaces confirmed that this furnace type uses a wind-based air-supply principle that
2444-672: Is continuously cast into long slabs, cut and shaped into bars and extrusions and heat treated to produce a final product. Today, approximately 96% of steel is continuously cast, while only 4% is produced as ingots. The ingots are then heated in a soaking pit and hot rolled into slabs, billets , or blooms . Slabs are hot or cold rolled into sheet metal or plates. Billets are hot or cold rolled into bars, rods, and wire. Blooms are hot or cold rolled into structural steel , such as I-beams and rails . In modern steel mills these processes often occur in one assembly line , with ore coming in and finished steel products coming out. Sometimes after
2538-425: Is smelting , where metal ores are reduced under high heat to separate the metal content from mineral gangue . The heat energy to fuel a furnace may be supplied directly by fuel combustion or by electricity . Different processes and the unique properties of specific metals and ores have led to many different furnace types. Many furnace designs for smelting combine ore, fuel, and other reagents like flux in
2632-629: Is also very reusable: it is one of the world's most-recycled materials, with a recycling rate of over 60% globally . The noun steel originates from the Proto-Germanic adjective * * stahliją or * * stakhlijan 'made of steel', which is related to * * stahlaz or * * stahliją 'standing firm'. The carbon content of steel is between 0.02% and 2.14% by weight for plain carbon steel ( iron - carbon alloys ). Too little carbon content leaves (pure) iron quite soft, ductile, and weak. Carbon contents higher than those of steel make
2726-416: Is always the main element in steel, but many other elements may be present or added. Stainless steels , which are resistant to corrosion and oxidation , typically need an additional 11% chromium . Iron is the base metal of steel. Depending on the temperature, it can take two crystalline forms (allotropic forms): body-centred cubic and face-centred cubic . The interaction of the allotropes of iron with
2820-403: Is common for quench cracks to form when steel is water quenched, although they may not always be visible. There are many types of heat treating processes available to steel. The most common are annealing , quenching , and tempering . Annealing is the process of heating the steel to a sufficiently high temperature to relieve local internal stresses. It does not create a general softening of
2914-403: Is desirable. To become steel, it must be reprocessed to reduce the carbon to the correct amount, at which point other elements can be added. In the past, steel facilities would cast the raw steel product into ingots which would be stored until use in further refinement processes that resulted in the finished product. In modern facilities, the initial product is close to the final composition and
Bloomery - Misplaced Pages Continue
3008-528: Is distinct from either forced or natural draught, and show also that they are capable of producing high-carbon steel. Wrought iron was used in the construction of monuments such as the iron pillar of Delhi , built in the third century AD during the Gupta Empire . The latter was built using a towering series of disc-shaped iron blooms. Similar to China, high-carbon steel was eventually used in India, although cast iron
3102-405: Is extracted from iron ore by removing the oxygen through its combination with a preferred chemical partner such as carbon which is then lost to the atmosphere as carbon dioxide. This process, known as smelting , was first applied to metals with lower melting points, such as tin , which melts at about 250 °C (482 °F), and copper , which melts at about 1,100 °C (2,010 °F), and
3196-408: Is heat treated to contain both a ferritic and martensitic microstructure to produce a formable, high strength steel. Transformation Induced Plasticity (TRIP) steel involves special alloying and heat treatments to stabilize amounts of austenite at room temperature in normally austenite-free low-alloy ferritic steels. By applying strain, the austenite undergoes a phase transition to martensite without
3290-661: Is located in Fengxiang County , Shaanxi (a museum exists on the site today). The earliest records of bloomery-type furnaces in East Africa are discoveries of smelted iron and carbon in Nubia in ancient Sudan dated at least to the seventh to the sixth century BC. The ancient bloomeries that produced metal tools for the Nubians and Kushites produced a surplus for sale. All traditional sub-Saharan African iron-smelting processes are variants of
3384-687: Is often considered an indicator of economic progress, because of the critical role played by steel in infrastructural and overall economic development . In 1980, there were more than 500,000 U.S. steelworkers. By 2000, the number of steelworkers had fallen to 224,000. The economic boom in China and India caused a massive increase in the demand for steel. Between 2000 and 2005, world steel demand increased by 6%. Since 2000, several Indian and Chinese steel firms have expanded to meet demand, such as Tata Steel (which bought Corus Group in 2007), Baosteel Group and Shagang Group . As of 2017 , though, ArcelorMittal
3478-544: Is one of the world's most-recycled materials, with a recycling rate of over 60% globally; in the United States alone, over 82,000,000 metric tons (81,000,000 long tons; 90,000,000 short tons) were recycled in the year 2008, for an overall recycling rate of 83%. As more steel is produced than is scrapped, the amount of recycled raw materials is about 40% of the total of steel produced - in 2016, 1,628,000,000 tonnes (1.602 × 10 long tons; 1.795 × 10 short tons) of crude steel
3572-510: Is particularly useful for recycling (still relatively pure) scrap metal, or remelting ingots for casting in foundries . The absence of any fuel or exhaust gases also makes these designs versatile for heating all kinds of metals. Such designs include: Other metallurgical furnaces have special design features or uses. One function is heating material short of melting, in order to perform heat treatment or hot working . Basic furnaces used this way include: Another class of furnaces isolate
3666-529: Is the world's largest steel producer . In 2005, the British Geological Survey stated China was the top steel producer with about one-third of the world share; Japan , Russia , and the United States were second, third, and fourth, respectively, according to the survey. The large production capacity of steel results also in a significant amount of carbon dioxide emissions inherent related to
3760-631: The Golconda area in Andhra Pradesh and Karnataka , regions of India , as well as in Samanalawewa and Dehigaha Alakanda, regions of Sri Lanka . This came to be known as wootz steel , produced in South India by about the sixth century BC and exported globally. The steel technology existed prior to 326 BC in the region as they are mentioned in literature of Sangam Tamil , Arabic, and Latin as
3854-627: The Nsukka region of southeast Nigeria in what is now Igboland . The site of Gbabiri, in the Central African Republic , has also yielded evidence of iron metallurgy, from a reduction furnace and blacksmith workshop, with earliest dates of 896–773 and 907–796 BC, respectively. During a hydroelectric plant project, in the southern foothills of the Central Highlands, Samanalawewa, in Sri Lanka ,
Bloomery - Misplaced Pages Continue
3948-586: The cementation process was described in a treatise published in Prague in 1574 and was in use in Nuremberg from 1601. A similar process for case hardening armour and files was described in a book published in Naples in 1589. The process was introduced to England in about 1614 and used to produce such steel by Sir Basil Brooke at Coalbrookdale during the 1610s. The raw material for this process were bars of iron. During
4042-419: The hardness , quenching behaviour , need for annealing , tempering behaviour , yield strength , and tensile strength of the resulting steel. The increase in steel's strength compared to pure iron is possible only by reducing iron's ductility. Steel was produced in bloomery furnaces for thousands of years, but its large-scale, industrial use began only after more efficient production methods were devised in
4136-576: The missions , encomiendas , and pueblos . As part of the Franciscan Spanish missions in Alta California , the "Catalan forges" at Mission San Juan Capistrano from the 1790s are the oldest existing facilities of their kind in the present day state of California . The bloomeries' sign proclaims the site as being "part of Orange County 's first industrial complex". The archaeology at Jamestown Virginia ( circa 1610–1615) had recovered
4230-602: The 12th century. The oldest bloomery in Sweden, also found in the same area, has been carbon-14 dated to 700 BCE. Bloomeries survived in Spain and southern France as Catalan forges into the mid-19th century, and in Austria as the Stückofen to 1775. Iron smelting was unknown in pre-Columbian America . Excavations at L'Anse aux Meadows , Newfoundland, have found considerable evidence for
4324-445: The 17th century, it was realized that the best steel came from oregrounds iron of a region north of Stockholm , Sweden. This was still the usual raw material source in the 19th century, almost as long as the process was used. Crucible steel is steel that has been melted in a crucible rather than having been forged , with the result that it is more homogeneous. Most previous furnaces could not reach high enough temperatures to melt
4418-470: The 17th century, the first step in European steel production has been the smelting of iron ore into pig iron in a blast furnace . Originally employing charcoal, modern methods use coke , which has proven more economical. In these processes, pig iron made from raw iron ore was refined (fined) in a finery forge to produce bar iron , which was then used in steel-making. The production of steel by
4512-607: The 17th century, with the introduction of the blast furnace and production of crucible steel . This was followed by the Bessemer process in England in the mid-19th century, and then by the open-hearth furnace . With the invention of the Bessemer process, a new era of mass-produced steel began. Mild steel replaced wrought iron . The German states were the major steel producers in Europe in
4606-475: The 19th century. American steel production was centred in Pittsburgh , Bethlehem, Pennsylvania , and Cleveland until the late 20th century. Currently, world steel production is centered in China, which produced 54% of the world's steel in 2023. Further refinements in the process, such as basic oxygen steelmaking (BOS), largely replaced earlier methods by further lowering the cost of production and increasing
4700-600: The Arabs from Persia, who took it from India. It was originally created from several different materials including various trace elements , apparently ultimately from the writings of Zosimos of Panopolis . In 327 BC, Alexander the Great was rewarded by the defeated King Porus , not with gold or silver but with 30 pounds of steel. A recent study has speculated that carbon nanotubes were included in its structure, which might explain some of its legendary qualities, though, given
4794-463: The Linz-Donawitz process of basic oxygen steelmaking (BOS), developed in 1952, and other oxygen steel making methods. Basic oxygen steelmaking is superior to previous steelmaking methods because the oxygen pumped into the furnace limited impurities, primarily nitrogen, that previously had entered from the air used, and because, with respect to the open hearth process, the same quantity of steel from
SECTION 50
#17328587597924888-480: The West, iron began to be used around 1200 BC. China has long been considered the exception to the general use of bloomeries. The Chinese are thought to have skipped the bloomery process completely, starting with the blast furnace and the finery forge to produce wrought iron; by the fifth century BC, metalworkers in the southern state of Wu had invented the blast furnace and the means to both cast iron and to decarburize
4982-401: The alloying elements, primarily carbon, gives steel and cast iron their range of unique properties. In pure iron, the crystal structure has relatively little resistance to the iron atoms slipping past one another, and so pure iron is quite ductile , or soft and easily formed. In steel, small amounts of carbon, other elements, and inclusions within the iron act as hardening agents that prevent
5076-722: The arrival of the blast furnace in the Weald in about 1491, bloomery forges, probably using waterpower for the hammer and the bellows, were operating in the West Midlands region beyond 1580. In Furness and Cumberland , they operated into the early 17th century and the last one in England (near Garstang ) did not close until about 1770. One of the oldest-known blast furnaces in Europe has been found in Lapphyttan in Sweden , carbon-14 dated to be from
5170-436: The austenite grain boundaries until the percentage of carbon in the grains has decreased to the eutectoid composition (0.8% carbon), at which point the pearlite structure forms. For steels that have less than 0.8% carbon (hypoeutectoid), ferrite will first form within the grains until the remaining composition rises to 0.8% of carbon, at which point the pearlite structure will form. No large inclusions of cementite will form at
5264-471: The austenite is for it to precipitate out of solution as cementite , leaving behind a surrounding phase of BCC iron called ferrite with a small percentage of carbon in solution. The two, cementite and ferrite, precipitate simultaneously producing a layered structure called pearlite , named for its resemblance to mother of pearl . In a hypereutectoid composition (greater than 0.8% carbon), the carbon will first precipitate out as large inclusions of cementite at
5358-483: The bloom removed from the top. The first step taken before the bloomery can be used is the preparation of the charcoal and the iron ore. Charcoal is nearly pure carbon , which, when burned, both produces the high temperature needed for the smelting process and provides the carbon monoxide needed for reduction of the metal. The ore is broken into small pieces and usually roasted in a fire, to make rock-based ores easier to break up, bake out some impurities, and (to
5452-708: The bloomery process. There is considerable discussion about the origins of iron metallurgy in Africa . Smelting in bloomery type furnaces in West Africa and forging of tools appeared in the Nok culture of central Nigeria by at least 550 BC and possibly several centuries earlier. Also, evidence indicates iron smelting with bloomery-style furnaces dated to 750 BC in Opi (Augustin Holl 2009) and Lejja dated to 2,000 BC (Pamela Eze-Uzomaka 2009), both sites in
5546-409: The bloomery to become larger and hotter, with associated trip hammers allowing the consolidation forging of the larger blooms created. Progressively larger bloomeries were constructed in the late 14th century, with a capacity of about 15 kg on average, though exceptions did exist. European average bloom sizes quickly rose to 300 kg, where they levelled off until the demise of the bloomery. As
5640-474: The bottom of the furnace, where they combine with molten slag, often consisting of fayalite , a compound of silicon , oxygen , and iron mixed with other impurities from the ore. The hot liquid slag, running to the bottom of the furnace, cools against the base and lower side walls of the furnace, effectively forming a bowl still containing fluid slag. As the individual iron particles form, they fall into this bowl and sinter together under their own weight, forming
5734-494: The boundaries in hypoeutectoid steel. The above assumes that the cooling process is very slow, allowing enough time for the carbon to migrate. As the rate of cooling is increased the carbon will have less time to migrate to form carbide at the grain boundaries but will have increasingly large amounts of pearlite of a finer and finer structure within the grains; hence the carbide is more widely dispersed and acts to prevent slip of defects within those grains, resulting in hardening of
SECTION 60
#17328587597925828-443: The carbon-rich pig iron produced in a blast furnace to a low-carbon, wrought iron-like material. Recent evidence, however, shows that bloomeries were used earlier in ancient China , migrating in from the west as early as 800 BC, before being supplanted by the locally developed blast furnace. Supporting this theory was the discovery of "more than ten" iron-digging implements found in the tomb of Duke Jing of Qin (d. 537 BCE), whose tomb
5922-455: The combination, bronze, which has a melting point lower than 1,083 °C (1,981 °F). In comparison, cast iron melts at about 1,375 °C (2,507 °F). Small quantities of iron were smelted in ancient times, in the solid-state, by heating the ore in a charcoal fire and then welding the clumps together with a hammer and in the process squeezing out the impurities. With care, the carbon content could be controlled by moving it around in
6016-448: The economies of melting and casting, can be heat treated after casting to make malleable iron or ductile iron objects. Steel is distinguishable from wrought iron (now largely obsolete), which may contain a small amount of carbon but large amounts of slag . Iron is commonly found in the Earth's crust in the form of an ore , usually an iron oxide, such as magnetite or hematite . Iron
6110-625: The finest steel in the world exported to the Roman, Egyptian, Chinese and Arab worlds at that time – what they called Seric Iron . A 200 BC Tamil trade guild in Tissamaharama , in the South East of Sri Lanka, brought with them some of the oldest iron and steel artifacts and production processes to the island from the classical period . The Chinese and locals in Anuradhapura , Sri Lanka had also adopted
6204-573: The fire. Unlike copper and tin, liquid or solid iron dissolves carbon quite readily. All of these temperatures could be reached with ancient methods used since the Bronze Age . Since the oxidation rate of iron increases rapidly beyond 800 °C (1,470 °F), it is important that smelting take place in a low-oxygen environment. Smelting, using carbon to reduce iron oxides, results in an alloy ( pig iron ) that retains too much carbon to be called steel. The excess carbon and other impurities are removed in
6298-503: The form of charcoal) in a crucible, was produced in Merv by the 9th to 10th century AD. In the 11th century, there is evidence of the production of steel in Song China using two techniques: a "berganesque" method that produced inferior, inhomogeneous steel, and a precursor to the modern Bessemer process that used partial decarburization via repeated forging under a cold blast . Since
6392-599: The hardenability of thick sections. High strength low alloy steel has small additions (usually < 2% by weight) of other elements, typically 1.5% manganese, to provide additional strength for a modest price increase. Recent corporate average fuel economy (CAFE) regulations have given rise to a new variety of steel known as Advanced High Strength Steel (AHSS). This material is both strong and ductile so that vehicle structures can maintain their current safety levels while using less material. There are several commercially available grades of AHSS, such as dual-phase steel , which
6486-517: The iron content of the primary bog iron ore found in the purpose built 'furnace hut' with the iron remaining in that slag, an estimated 3 kg iron bloom was produced. At a yield of at best 20% from what is a good iron rich ore, this suggests the workers processing the ore had not been particularly skilled. This supports the idea that iron processing knowledge was widespread and not restricted to major centers of trade and commerce. Archaeologists also found 98 nail, and importantly, ship rivet fragments, at
6580-439: The main production route. At the end of 2008, the steel industry faced a sharp downturn that led to many cut-backs. In 2021, it was estimated that around 7% of the global greenhouse gas emissions resulted from the steel industry. Reduction of these emissions are expected to come from a shift in the main production route using cokes, more recycling of steel and the application of carbon capture and storage technology. Steel
6674-579: The material from the surrounding atmosphere and contaminants, enabling advanced heat treatments and other techniques: Steel Steel is an alloy of iron and carbon with improved strength and fracture resistance compared to other forms of iron. Because of its high tensile strength and low cost, steel is one of the most commonly manufactured materials in the world. Steel is used in buildings, as concrete reinforcing rods, in bridges, infrastructure, tools, ships, trains, cars, bicycles, machines, electrical appliances, furniture, and weapons. Iron
6768-450: The most part, however, p-block elements such as sulphur, nitrogen , phosphorus , and lead are considered contaminants that make steel more brittle and are therefore removed from steel during the melting processing. The density of steel varies based on the alloying constituents but usually ranges between 7,750 and 8,050 kg/m (484 and 503 lb/cu ft), or 7.75 and 8.05 g/cm (4.48 and 4.65 oz/cu in). Even in
6862-446: The movement of dislocations . The carbon in typical steel alloys may contribute up to 2.14% of its weight. Varying the amount of carbon and many other alloying elements, as well as controlling their chemical and physical makeup in the final steel (either as solute elements, or as precipitated phases), impedes the movement of the dislocations that make pure iron ductile, and thus controls and enhances its qualities. These qualities include
6956-471: The processing of bog iron and the production of iron in a bloomery by the Norse. The cluster of Viking Age ( c. 1000 –1022 AD) at L'Anse aux Meadows are situated on a raised marine terrace, between a sedge peat bog and the ocean. Estimates from the smaller amount of slag recovered archaeologically suggest 15 kg of slag was produced during what appears to have been a single smelting attempt. By comparing
7050-449: The product but only locally relieves strains and stresses locked up within the material. Annealing goes through three phases: recovery , recrystallization , and grain growth . The temperature required to anneal a particular steel depends on the type of annealing to be achieved and the alloying constituents. Quenching involves heating the steel to create the austenite phase then quenching it in water or oil . This rapid cooling results in
7144-693: The production methods of creating wootz steel from the Chera Dynasty Tamils of South India by the 5th century AD. In Sri Lanka, this early steel-making method employed a unique wind furnace, driven by the monsoon winds, capable of producing high-carbon steel. Since the technology was acquired from the Tamilians from South India, the origin of steel technology in India can be conservatively estimated at 400–500 BC. The manufacture of wootz steel and Damascus steel , famous for its durability and ability to hold an edge, may have been taken by
7238-426: The quality of the final product. Today more than 1.6 billion tons of steel is produced annually. Modern steel is generally identified by various grades defined by assorted standards organizations . The modern steel industry is one of the largest manufacturing industries in the world, but also one of the most energy and greenhouse gas emission intense industries, contributing 8% of global emissions. However, steel
7332-749: The reaction chamber, where metal or ore is combined with reagents, to a stream of exhaust gases. However, no fuel is directly added to the chamber, and combustion occurs in a separate chamber. Furnaces of this type include: In metallurgy, furnaces used to refine metals further, particularly iron into steel, are also often called converters : Just as other industries have trended towards electrification , electric furnaces have become prevalent in metallurgy. However, while any furnace can theoretically use an electrical heating element , process specifics mostly limit this approach to furnaces with lower power demands. Instead, electric metallurgical furnaces often apply an electric current directly to batches of metal. This
7426-575: The remains of a simple short-shaft bloomery furnace, likely intended as yet another "resource test" like the one in Vinland much earlier. The English settlers of the Thirteen Colonies were prevented by law from manufacture; for a time, the British sought to situate most of the skilled artisanry at domestic locations. In fact, this was one of the problems that led to the revolution. The Falling Creek Ironworks
7520-418: The resulting iron, with reduced amounts of slag, is called wrought iron or bar iron. Because of the creation process, individual blooms can often have differing carbon contents between the original top and bottom surfaces, differences that will also be somewhat blended together through the flattening, folding, and hammer-welding sequences. Intentionally producing blooms that are coated in steel (i.e. iron with
7614-540: The site as well as considerable evidence for woodworking – which points to boat or possibly ship repairs being undertaken at the site. (An important consideration remains that a potential 3 kg raw bloom most certainly does not make enough refined bar to manufacture the 3 kg of recovered nails and rivets.) In the Spanish colonization of the Americas , bloomeries or "Catalan forges" were part of "self-sufficiency" at some of
7708-404: The smelt progresses. Overall, a typical ratio of total charcoal to ore added is in a roughly one-to-one ratio. Inside the furnace, carbon monoxide from the incomplete combustion of the charcoal reduces the iron oxides in the ore to metallic iron without melting the ore; this allows the bloomery to operate at lower temperatures than the melting temperature of the ore. As the desired product of
7802-401: The steel. At the very high cooling rates produced by quenching, the carbon has no time to migrate but is locked within the face-centred austenite and forms martensite . Martensite is a highly strained and stressed, supersaturated form of carbon and iron and is exceedingly hard but brittle. Depending on the carbon content, the martensitic phase takes different forms. Below 0.2% carbon, it takes on
7896-556: The steel. The early modern crucible steel industry resulted from the invention of Benjamin Huntsman in the 1740s. Blister steel (made as above) was melted in a crucible or in a furnace, and cast (usually) into ingots. The modern era in steelmaking began with the introduction of Henry Bessemer 's process in 1855, the raw material for which was pig iron. His method let him produce steel in large quantities cheaply, thus mild steel came to be used for most purposes for which wrought iron
7990-555: The technology of that time, such qualities were produced by chance rather than by design. Natural wind was used where the soil containing iron was heated by the use of wood. The ancient Sinhalese managed to extract a ton of steel for every 2 tons of soil, a remarkable feat at the time. One such furnace was found in Samanalawewa and archaeologists were able to produce steel as the ancients did. Crucible steel , formed by slowly heating and cooling pure iron and carbon (typically in
8084-522: The upper carbon content of steel, beyond which is cast iron. When carbon moves out of solution with iron, it forms a very hard, but brittle material called cementite (Fe 3 C). When steels with exactly 0.8% carbon (known as a eutectoid steel), are cooled, the austenitic phase (FCC) of the mixture attempts to revert to the ferrite phase (BCC). The carbon no longer fits within the FCC austenite structure, resulting in an excess of carbon. One way for carbon to leave
8178-515: The world coincides with the first widespread use of the bloomery. While earlier examples of iron are found, their high nickel content indicates that this is meteoric iron . Other early samples of iron may have been produced by accidental introduction of iron ore in copper-smelting operations. Iron appears to have been smelted in the Middle East as early as 3000 BC, but coppersmiths, not being familiar with iron, did not put it to use until much later. In
8272-510: Was considered a waste product detracting from the largest bloomeries' yield, and early blast furnaces , identical in construction, but dedicated to the production of molten iron, were not built until the 14th century. Bloomery type furnaces typically produced a range of iron products from very low-carbon iron to steel containing around 0.2–1.5% carbon. The master smith had to select pieces of low-carbon iron, carburize them, and pattern-weld them together to make steel sheets. Even when applied to
8366-646: Was developed in Southern India and Sri Lanka in the 1st millennium BCE. Metal production sites in Sri Lanka employed wind furnaces driven by the monsoon winds, capable of producing high-carbon steel. Large-scale wootz steel production in India using crucibles occurred by the sixth century BC, the pioneering precursor to modern steel production and metallurgy. High-carbon steel was produced in Britain at Broxmouth Hillfort from 490–375 BC, and ultrahigh-carbon steel
8460-502: Was formerly used. The Gilchrist-Thomas process (or basic Bessemer process ) was an improvement to the Bessemer process, made by lining the converter with a basic material to remove phosphorus. Another 19th-century steelmaking process was the Siemens-Martin process , which complemented the Bessemer process. It consisted of co-melting bar iron (or steel scrap) with pig iron. These methods of steel production were rendered obsolete by
8554-426: Was not used for architecture until modern times. Early European bloomeries were relatively small, primarily due to the mechanical limits of human-powered bellows and the amount of force possible to apply with hand-driven sledge hammers. Those known archaeologically from the pre-Roman Iron Age tend to be in the 2 kg range, produced in low shaft furnaces. Roman-era production often used furnaces tall enough to create
8648-438: Was produced globally, with 630,000,000 tonnes (620,000,000 long tons; 690,000,000 short tons) recycled. Modern steels are made with varying combinations of alloy metals to fulfil many purposes. Carbon steel , composed simply of iron and carbon, accounts for 90% of steel production. Low alloy steel is alloyed with other elements, usually molybdenum , manganese, chromium, or nickel, in amounts of up to 10% by weight to improve
8742-729: Was produced in the Netherlands from the 2nd-4th centuries AD. The Roman author Horace identifies steel weapons such as the falcata in the Iberian Peninsula , while Noric steel was used by the Roman military . The Chinese of the Warring States period (403–221 BC) had quench-hardened steel, while Chinese of the Han dynasty (202 BC—AD 220) created steel by melting together wrought iron with cast iron, thus producing
8836-541: Was the first in the United States. The Neabsco Iron Works is an example of the early Virginian effort to form a workable American industry. The earliest iron forge in colonial Pennsylvania was Thomas Rutter 's bloomery near Pottstown , founded in 1716. In the Adirondacks , New York, new bloomeries using the hot blast technique were built in the 19th century. Metallurgical furnace One important furnace application, especially in iron and steel production,
#791208