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Surtshellir ( Icelandic pronunciation: [ˈsʏr̥(t)sˌhɛtlɪr̥] ) is a lava cave located in western Iceland , around 60 km from the settlement of Borgarnes . Approximately a mile in length, it is one of the longest such caves in the country. It was the first known lava tube in the world, at least by modern speleologists , and remained the longest known lava tube until the end of the 19th century. While mentioned in the medieval historical-geographical work Landnámabók , Eggert Ólafsson was the first to give a thorough documentation of the cave in his 1750 travels of the region. It is named after the fire giant Surtr , a prominent figure in Norse mythology , who is prophesied to one day engulf the world in the fire of his flaming sword.

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91-540: Surtshellir was formed as a lava tube in a massive, effusive, shield-volcano eruption at the northern end of the Prestahnúkur volcanic system. At least three and possibly four vents opened on the edge of Langjökull glacier during this long-lived eruption, which has been dated to the first decades of Iceland's settlement (c. 880-920). Ultimately, the eruption covered 240 km (90 mi) of once fertile grazing and settled land beneath sheets of lava 20 meters thick, or more. Surtshellir

182-452: A combination of these processes. Other mechanisms, such as melting from a meteorite impact , are less important today, but impacts during the accretion of the Earth led to extensive melting, and the outer several hundred kilometers of the early Earth was probably a magma ocean . Impacts of large meteorites in the last few hundred million years have been proposed as one mechanism responsible for

273-420: A depth of 2,488 m (8,163 ft). The temperature of this magma was estimated at 1,050 °C (1,920 °F). Temperatures of deeper magmas must be inferred from theoretical computations and the geothermal gradient. Most magmas contain some solid crystals suspended in the liquid phase. This indicates that the temperature of the magma lies between the solidus , which is defined as the temperature at which

364-427: A dissolved water content in excess of 10%. Water is somewhat less soluble in low-silica magma than high-silica magma, so that at 1,100 °C and 0.5 GPa , a basaltic magma can dissolve 8% H 2 O while a granite pegmatite magma can dissolve 11% H 2 O . However, magmas are not necessarily saturated under typical conditions. Carbon dioxide is much less soluble in magmas than water, and frequently separates into

455-406: A distinct fluid phase even at great depth. This explains the presence of carbon dioxide fluid inclusions in crystals formed in magmas at great depth. Viscosity is a key melt property in understanding the behaviour of magmas. Whereas temperatures in common silicate lavas range from about 800 °C (1,470 °F) for felsic lavas to 1,200 °C (2,190 °F) for mafic lavas, the viscosity of

546-435: A high charge (the high-field-strength elements, or HSFEs), which include such elements as zirconium , niobium , hafnium , tantalum , the rare-earth elements , and the actinides . Potassium can become so enriched in melt produced by a very low degree of partial melting that, when the magma subsequently cools and solidifies, it forms unusual potassic rock such as lamprophyre , lamproite , or kimberlite . When enough rock

637-546: A hypothetical magma formed entirely from melted silica, NBO/T would be 0, while in a hypothetical magma so low in network formers that no polymerization takes place, NBO/T would be 4. Neither extreme is common in nature, but basalt magmas typically have NBO/T between 0.6 and 0.9, andesitic magmas have NBO/T of 0.3 to 0.5, and rhyolitic magmas have NBO/T of 0.02 to 0.2. Water acts as a network modifier, and dissolved water drastically reduces melt viscosity. Carbon dioxide neutralizes network modifiers, so dissolved carbon dioxide increases

728-474: A layer that appears to contain silicate melt and that stretches for at least 1,000 kilometers within the middle crust along the southern margin of the Tibetan Plateau. Granite and rhyolite are types of igneous rock commonly interpreted as products of the melting of continental crust because of increases in temperature. Temperature increases also may contribute to the melting of lithosphere dragged down in

819-420: A magma. In practice, it is difficult to unambiguously identify primary magmas, though it has been suggested that boninite is a variety of andesite crystallized from a primary magma. The Great Dyke of Zimbabwe has also been interpreted as rock crystallized from a primary magma. The interpretation of leucosomes of migmatites as primary magmas is contradicted by zircon data, which suggests leucosomes are

910-691: A measurable amount of magmatic gas in dissolved form. Present day global emissions of volcanic gases to the atmosphere can be classified as eruptive or non-eruptive. Although all volcanic gas species are emitted to the atmosphere, the emissions of CO 2 (a greenhouse gas ) and SO 2 have received the most study. It has long been recognized that eruptions contribute much lower total SO 2 emissions than passive degassing does. Fischer et al (2019) estimated that, from 2005 to 2015, SO 2 emissions during eruptions were 2.6 teragrams (Tg or 10 g or 0.907 gigatons Gt) per year and during non-eruptive periods of passive degassing were 23.2 ± 2Tg per year. During

1001-1710: A residue (a cumulate rock ) left by extraction of a primary magma. When it is impossible to find the primitive or primary magma composition, it is often useful to attempt to identify a parental magma. A parental magma is a magma composition from which the observed range of magma chemistries has been derived by the processes of igneous differentiation . It need not be a primitive melt. Volcanic gas Volcanic gases are gases given off by active (or, at times, by dormant) volcanoes . These include gases trapped in cavities ( vesicles ) in volcanic rocks , dissolved or dissociated gases in magma and lava , or gases emanating from lava, from volcanic craters or vents. Volcanic gases can also be emitted through groundwater heated by volcanic action . The sources of volcanic gases on Earth include: Substances that may become gaseous or give off gases when heated are termed volatile substances. The principal components of volcanic gases are water vapor (H 2 O), carbon dioxide (CO 2 ), sulfur either as sulfur dioxide (SO 2 ) (high-temperature volcanic gases) or hydrogen sulfide (H 2 S) (low-temperature volcanic gases), nitrogen , argon , helium , neon , methane , carbon monoxide and hydrogen . Other compounds detected in volcanic gases are oxygen (meteoric) , hydrogen chloride , hydrogen fluoride , hydrogen bromide , sulfur hexafluoride , carbonyl sulfide , and organic compounds . Exotic trace compounds include mercury , halocarbons (including CFCs ), and halogen oxide radicals . The abundance of gases varies considerably from volcano to volcano, with volcanic activity and with tectonic setting. Water vapour

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1092-425: A rock type commonly enriched in incompatible elements. Bowen's reaction series is important for understanding the idealised sequence of fractional crystallisation of a magma. Magma composition can be determined by processes other than partial melting and fractional crystallization. For instance, magmas commonly interact with rocks they intrude, both by melting those rocks and by reacting with them. Assimilation near

1183-511: A shift toward more reducing conditions. At the surface expression of such hydrothermal systems, low-temperature volcanic gases (<400 °C) are either emanating as steam-gas mixtures or in dissolved form in hot springs . At the ocean floor, such hot supersaturated hydrothermal fluids form gigantic chimney structures called black smokers , at the point of emission into the cold seawater . Over geological time, this process of hydrothermal leaching, alteration, and/or redeposition of minerals in

1274-567: A solidified crust. Most basalt lavas are of ʻAʻā or pāhoehoe types, rather than block lavas. Underwater, they can form pillow lavas , which are rather similar to entrail-type pahoehoe lavas on land. Ultramafic magmas, such as picritic basalt, komatiite , and highly magnesian magmas that form boninite , take the composition and temperatures to the extreme. All have a silica content under 45%. Komatiites contain over 18% magnesium oxide, and are thought to have erupted at temperatures of 1,600 °C (2,910 °F). At this temperature there

1365-407: A subduction zone. When rocks melt, they do so over a range of temperature, because most rocks are made of several minerals , which all have different melting points. The temperature at which the first melt appears (the solidus) is lower than the melting temperature of any one of the pure minerals. This is similar to the lowering of the melting point of ice when it is mixed with salt. The first melt

1456-439: A tetrahedral arrangement around the much smaller silicon ion. This is called a silica tetrahedron . In a magma that is low in silicon, these silica tetrahedra are isolated, but as the silicon content increases, silica tetrahedra begin to partially polymerize, forming chains, sheets, and clumps of silica tetrahedra linked by bridging oxygen ions. These greatly increase the viscosity of the magma. The tendency towards polymerization

1547-974: A total of 18 ± 4 Tg of SO 2 . Such large VEI 6 eruptions are rare and only occur once every 50 – 100 years. The 2010 eruptions of Eyjafjallajökull (VEI 4) in Iceland emitted a total of 5.1 Tg CO 2 . VEI 4 eruptions occur about once per year. For comparison, Le Quéré, C. et al estimates that human burning of fossil fuels and production of cement processed 9.3 Gt carbon per year from 2006 through 2015, creating up to 34.1 Gt CO2 annually. Some recent volcanic CO 2 emission estimates are higher than Fischer et al (2019). The estimates of Burton et al. (2013) of 540 Tg CO 2 /year and of Werner et al. (2019) of 220 - 300 Tg CO 2 /year take into account diffuse CO 2 emissions from volcanic regions. Volcanic gases were collected and analysed as long ago as 1790 by Scipione Breislak in Italy. The composition of volcanic gases

1638-638: A typical viscosity of 3.5 × 10 cP (3,500 Pa⋅s) at 1,200 °C (2,190 °F). This is slightly greater than the viscosity of smooth peanut butter . Intermediate magmas show a greater tendency to form phenocrysts . Higher iron and magnesium tends to manifest as a darker groundmass , including amphibole or pyroxene phenocrysts. Mafic or basaltic magmas have a silica content of 52% to 45%. They are typified by their high ferromagnesian content, and generally erupt at temperatures of 1,100 to 1,200 °C (2,010 to 2,190 °F). Viscosities can be relatively low, around 10 to 10 cP (10 to 100 Pa⋅s), although this

1729-406: A vapour phase. Extended fluid-rock interaction of this hot mixture can leach constituents out of the cooling magmatic rock and also the country rock , causing volume changes and phase transitions, reactions and thus an increase in ionic strength of the upward percolating fluid. This process also decreases the fluid's pH . Cooling can cause phase separation and mineral deposition, accompanied by

1820-633: A viscosity of about 1 cP (0.001 Pa⋅s). Because of this very high viscosity, felsic lavas usually erupt explosively to produce pyroclastic (fragmental) deposits. However, rhyolite lavas occasionally erupt effusively to form lava spines , lava domes or "coulees" (which are thick, short lava flows). The lavas typically fragment as they extrude, producing block lava flows . These often contain obsidian . Felsic lavas can erupt at temperatures as low as 800 °C (1,470 °F). Unusually hot (>950 °C; >1,740 °F) rhyolite lavas, however, may flow for distances of many tens of kilometres, such as in

1911-434: Is super-saturated in volatiles). The gas will initially be distributed throughout the magma as small bubbles, that cannot rise quickly through the magma. As the magma ascends the bubbles grow through a combination of expansion through decompression and growth as the solubility of volatiles in the magma decreases further causing more gas to exsolve. Depending on the viscosity of the magma, the bubbles may start to rise through

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2002-409: Is added to the rock, the temperature remains at 1274 °C until either the anorthite or diopside is fully melted. The temperature then rises as the remaining mineral continues to melt, which shifts the melt composition away from the eutectic. For example, if the content of anorthite is greater than 43%, the entire supply of diopside will melt at 1274 °C., along with enough of the anorthite to keep

2093-444: Is called the eutectic and has a composition that depends on the combination of minerals present. For example, a mixture of anorthite and diopside , which are two of the predominant minerals in basalt , begins to melt at about 1274 °C. This is well below the melting temperatures of 1392 °C for pure diopside and 1553 °C for pure anorthite. The resulting melt is composed of about 43 wt% anorthite. As additional heat

2184-410: Is concentrated in a thin layer in the toothpaste next to the tube, and only here does the toothpaste behave as a fluid. Thixotropic behavior also hinders crystals from settling out of the magma. Once the crystal content reaches about 60%, the magma ceases to behave like a fluid and begins to behave like a solid. Such a mixture of crystals with melted rock is sometimes described as crystal mush . Magma

2275-666: Is consistently the most abundant volcanic gas, normally comprising more than 60% of total emissions. Carbon dioxide typically accounts for 10 to 40% of emissions. Volcanoes located at convergent plate boundaries emit more water vapor and chlorine than volcanoes at hot spots or divergent plate boundaries. This is caused by the addition of seawater into magmas formed at subduction zones . Convergent plate boundary volcanoes also have higher H 2 O/H 2 , H 2 O/CO 2 , CO 2 /He and N 2 /He ratios than hot spot or divergent plate boundary volcanoes. Magma contains dissolved volatile components , as described above. The solubilities of

2366-451: Is dependent on the movement of magma within the volcano. Therefore, sudden changes in gas composition often presage a change in volcanic activity. Accordingly, a large part of hazard monitoring of volcanoes involves regular measurement of gaseous emissions. For example, an increase in the CO 2 content of gases at Stromboli has been ascribed to injection of fresh volatile-rich magma at depth within

2457-456: Is driven out of the oceanic lithosphere in subduction zones , and it causes melting in the overlying mantle. Hydrous magmas with the composition of basalt or andesite are produced directly and indirectly as results of dehydration during the subduction process. Such magmas, and those derived from them, build up island arcs such as those in the Pacific Ring of Fire . These magmas form rocks of

2548-417: Is expressed as NBO/T, where NBO is the number of non-bridging oxygen ions and T is the number of network-forming ions. Silicon is the main network-forming ion, but in magmas high in sodium, aluminium also acts as a network former, and ferric iron can act as a network former when other network formers are lacking. Most other metallic ions reduce the tendency to polymerize and are described as network modifiers. In

2639-466: Is magma extruded onto the surface, are almost all in the range 700 to 1,400 °C (1,300 to 2,600 °F), but very rare carbonatite magmas may be as cool as 490 °C (910 °F), and komatiite magmas may have been as hot as 1,600 °C (2,900 °F). Magma has occasionally been encountered during drilling in geothermal fields, including drilling in Hawaii that penetrated a dacitic magma body at

2730-647: Is melted before the heat supply is exhausted. Pegmatite may be produced by low degrees of partial melting of the crust. Some granite -composition magmas are eutectic (or cotectic) melts, and they may be produced by low to high degrees of partial melting of the crust, as well as by fractional crystallization . Most magmas are fully melted only for small parts of their histories. More typically, they are mixes of melt and crystals, and sometimes also of gas bubbles. Melt, crystals, and bubbles usually have different densities, and so they can separate as magmas evolve. As magma cools, minerals typically crystallize from

2821-416: Is melted, the small globules of melt (generally occurring between mineral grains) link up and soften the rock. Under pressure within the earth, as little as a fraction of a percent of partial melting may be sufficient to cause melt to be squeezed from its source. Melt rapidly separates from its source rock once the degree of partial melting exceeds 30%. However, usually much less than 30% of a magma source rock

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2912-505: Is one of 20 known caves in the Hallmundarhraun lava field that once carried magma from the vents to the farthest ends of the lava field, more than 50 km to the west. Eight of these (including Viðgelmir and Hallmundarhellir) are known to contain archaeological remains of varying age; Surtshellir's are the most extensive. Being of volcanic origin, the walls of the interior are composed of vitrified layers of magma and basalt . The roof of

3003-615: Is practically no polymerization of the mineral compounds, creating a highly mobile liquid. Viscosities of komatiite magmas are thought to have been as low as 100 to 1000 cP (0.1 to 1 Pa⋅s), similar to that of light motor oil. Most ultramafic lavas are no younger than the Proterozoic , with a few ultramafic magmas known from the Phanerozoic in Central America that are attributed to a hot mantle plume . No modern komatiite lavas are known, as

3094-545: Is produced by melting of the mantle or the crust in various tectonic settings, which on Earth include subduction zones , continental rift zones , mid-ocean ridges and hotspots . Mantle and crustal melts migrate upwards through the crust where they are thought to be stored in magma chambers or trans-crustal crystal-rich mush zones. During magma's storage in the crust, its composition may be modified by fractional crystallization , contamination with crustal melts, magma mixing, and degassing. Following its ascent through

3185-448: Is still many orders of magnitude higher than water. This viscosity is similar to that of ketchup . Basalt lavas tend to produce low-profile shield volcanoes or flood basalts , because the fluidal lava flows for long distances from the vent. The thickness of a basalt lava, particularly on a low slope, may be much greater than the thickness of the moving lava flow at any one time, because basalt lavas may "inflate" by supply of lava beneath

3276-459: Is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as lava ) is found beneath the surface of the Earth , and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites . Besides molten rock, magma may also contain suspended crystals and gas bubbles . Magma

3367-413: Is typically also viscoelastic , meaning it flows like a liquid under low stresses, but once the applied stress exceeds a critical value, the melt cannot dissipate the stress fast enough through relaxation alone, resulting in transient fracture propagation. Once stresses are reduced below the critical threshold, the melt viscously relaxes once more and heals the fracture. Temperatures of molten lava, which

3458-408: Is typically the most abundant magmatic gas, followed by carbon dioxide and sulfur dioxide . Other principal magmatic gases include hydrogen sulfide , hydrogen chloride , and hydrogen fluoride . The solubility of magmatic gases in magma depends on pressure, magma composition, and temperature. Magma that is extruded as lava is extremely dry, but magma at depth and under great pressure can contain

3549-429: Is usually determined by different mass spectrometric methods. Certain constituents of volcanic gases may show very early signs of changing conditions at depth, making them a powerful tool to predict imminent unrest. Used in conjunction with monitoring data on seismicity and deformation , correlative monitoring gains great efficiency. Volcanic gas monitoring is a standard tool of any volcano observatory . Unfortunately,

3640-666: The Snake River Plain of the northwestern United States. Intermediate or andesitic magmas contain 52% to 63% silica, and are lower in aluminium and usually somewhat richer in magnesium and iron than felsic magmas. Intermediate lavas form andesite domes and block lavas, and may occur on steep composite volcanoes , such as in the Andes . They are also commonly hotter, in the range of 850 to 1,100 °C (1,560 to 2,010 °F)). Because of their lower silica content and higher eruptive temperatures, they tend to be much less viscous, with

3731-458: The calc-alkaline series, an important part of the continental crust . With low density and viscosity, hydrous magmas are highly buoyant and will move upwards in Earth's mantle. The addition of carbon dioxide is relatively a much less important cause of magma formation than the addition of water, but genesis of some silica-undersaturated magmas has been attributed to the dominance of carbon dioxide over water in their mantle source regions. In

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3822-453: The convection of solid mantle, it will cool slightly as it expands in an adiabatic process , but the cooling is only about 0.3 °C per kilometer. Experimental studies of appropriate peridotite samples document that the solidus temperatures increase by 3 °C to 4 °C per kilometer. If the rock rises far enough, it will begin to melt. Melt droplets can coalesce into larger volumes and be intruded upwards. This process of melting from

3913-472: The Earth's mantle has cooled too much to produce highly magnesian magmas. Some silicic magmas have an elevated content of alkali metal oxides (sodium and potassium), particularly in regions of continental rifting , areas overlying deeply subducted plates , or at intraplate hotspots . Their silica content can range from ultramafic ( nephelinites , basanites and tephrites ) to felsic ( trachytes ). They are more likely to be generated at greater depths in

4004-465: The Earth's upper crust, but this varies widely by region, from a low of 5–10 °C/km within oceanic trenches and subduction zones to 30–80 °C/km along mid-ocean ridges or near mantle plumes . The gradient becomes less steep with depth, dropping to just 0.25 to 0.3 °C/km in the mantle, where slow convection efficiently transports heat. The average geothermal gradient is not normally steep enough to bring rocks to their melting point anywhere in

4095-1005: The SO 2 flux. Direct sampling of volcanic gas sampling is often done by a method involving an evacuated flask with caustic solution, first used by Robert W. Bunsen (1811-1899) and later refined by the German chemist Werner F. Giggenbach (1937-1997), dubbed Giggenbach-bottle . Other methods include collection in evacuated empty containers, in flow-through glass tubes, in gas wash bottles (cryogenic scrubbers), on impregnated filter packs and on solid adsorbent tubes. Analytical techniques for gas samples comprise gas chromatography with thermal conductivity detection (TCD), flame ionization detection (FID) and mass spectrometry (GC-MS) for gases, and various wet chemical techniques for dissolved species (e.g., acidimetric titration for dissolved CO 2 , and ion chromatography for sulfate , chloride , fluoride ). The trace metal, trace organic and isotopic composition

4186-476: The anorthite is melted. If the anorthite content of the mixture is less than 43%, then all the anorthite will melt at the eutectic temperature, along with part of the diopside, and the remaining diopside will then gradually melt as the temperature continues to rise. Because of eutectic melting, the composition of the melt can be quite different from the source rock. For example, a mixture of 10% anorthite with diopside could experience about 23% partial melting before

4277-413: The case where gas and its parent magma ascend together and in equilibrium with each other. The composition of the emitted gas is in equilibrium with the composition of the magma at the pressure, temperature where the gas leaves the system. In 'open system' degassing, the gas leaves its parent magma and rises up through the overlying magma without remaining in equilibrium with that magma. The gas released at

4368-435: The cave is about 10 metres high at the highest point, and the tunnels are around 15m broad at their greatest width. The floor of the lowest and westernmost part of the cave, called Íshellir ("Ice Cave"), is covered in a perpetual sheeting of ice and large ice speleothems are common within the cave. The height of the roof is highly variable throughout the cave, and at the latter extremities is only 2–4 m. Four massive openings in

4459-473: The cave – including bones of domestic sheep/goats, horses, pigs, cattle, and possibly fowl – instead document evidence of Viking Age ritual activities undertaken inside the cave for 65-100 years prior to Iceland's conversion to Christianity around AD 1000. The cave itself has long been a source of superstition for the Icelanders inhabiting the nearby farms. Eggert Ólafsson recalled having been warned by locals of

4550-650: The country rock is an effective process of concentration that generates certain types of economically valuable ore deposits. The gas release can occur by advection through fractures, or via diffuse degassing through large areas of permeable ground as diffuse degassing structures (DDS). At sites of advective gas loss, precipitation of sulfur and rare minerals forms sulfur deposits and small sulfur chimneys, called fumaroles . Very low-temperature (below 100 °C) fumarolic structures are also known as solfataras . Sites of cold degassing of predominantly carbon dioxide are called mofettes . Hot springs on volcanoes often show

4641-458: The crust or upper mantle, so magma is produced only where the geothermal gradient is unusually steep or the melting point of the rock is unusually low. However, the ascent of magma towards the surface in such settings is the most important process for transporting heat through the crust of the Earth. Rocks may melt in response to a decrease in pressure, to a change in composition (such as an addition of water), to an increase in temperature, or to

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4732-553: The crust, magma may feed a volcano and be extruded as lava, or it may solidify underground to form an intrusion , such as a dike , a sill , a laccolith , a pluton , or a batholith . While the study of magma has relied on observing magma after its transition into a lava flow , magma has been encountered in situ three times during geothermal drilling projects , twice in Iceland (see Use in energy production ) and once in Hawaii. Magma consists of liquid rock that usually contains suspended solid crystals. As magma approaches

4823-455: The crystallization process would not change the overall composition of the melt plus solid minerals. This situation is described as equillibrium crystallization . However, in a series of experiments culminating in his 1915 paper, Crystallization-differentiation in silicate liquids , Norman L. Bowen demonstrated that crystals of olivine and diopside that crystallized out of a cooling melt of forsterite , diopside, and silica would sink through

4914-419: The different volatile constituents are dependent on pressure, temperature and the composition of the magma . As magma ascends towards the surface, the ambient pressure decreases, which decreases the solubility of the dissolved volatiles. Once the solubility decreases below the volatile concentration, the volatiles will tend to come out of solution within the magma (exsolve) and form a separate gas phase (the magma

5005-496: The earliest reference to the cave by name, in the 12th-13th century Icelandic "Book of Settlements" (Landnámabók) describes the 150 km journey of a chieftain's son, Þorvaldur holbarki ("hollow throat") Þorðarson, through Iceland's interior to sing a poem of praise (a "drápa") – a ritual act – to the giant that lived inside "hellisins Surts", Surt's cave. Archaeological research inside the cave in 2001, 2012, and 2013 has shown that remains once thought to be evidence of outlaws' activity in

5096-399: The eutectic temperature of 1274 °C. This shifts the remaining melt towards its eutectic composition of 43% diopside. The eutectic is reached at 1274 °C, the temperature at which diopside and anorthite begin crystallizing together. If the melt was 90% diopside, the diopside would begin crystallizing first until the eutectic was reached. If the crystals remained suspended in the melt,

5187-512: The extensive basalt magmatism of several large igneous provinces. Decompression melting occurs because of a decrease in pressure. It is the most important mechanism for producing magma from the upper mantle. The solidus temperatures of most rocks (the temperatures below which they are completely solid) increase with increasing pressure in the absence of water. Peridotite at depth in the Earth's mantle may be hotter than its solidus temperature at some shallower level. If such rock rises during

5278-412: The flux of SO 2 emitted. The Multi-Component Gas Analyzer System (Multi-GAS) is also used to remotely measure CO 2 , SO 2 and H 2 S. The fluxes of other gases are usually estimated by measuring the ratios of different gases within the volcanic plume, e.g. by FTIR, electrochemical sensors at the volcano crater rim, or direct sampling, and multiplying the ratio of the gas of interest to SO 2 by

5369-553: The ghosts that were said to dwell within and was assured that his party would be killed by them if they were to enter. Surtr himself was said to have once lived within the cave and, being a fire giant, to have been the cause of the cave's creation. Surtshellir is in close proximity to another lava cave, Stefánshellir , with which it forms a complex referred to as the Surtshellir-Stefánshellir system. Both caves were profusely decorated with lavacicles and lava stalagmites in

5460-420: The importance of each mechanism being a topic of continuing research. The change of rock composition most responsible for the creation of magma is the addition of water. Water lowers the solidus temperature of rocks at a given pressure. For example, at a depth of about 100 kilometers, peridotite begins to melt near 800 °C in the presence of excess water, but near 1,500 °C in the absence of water. Water

5551-420: The latter case, the gas can flow rapidly through the continuous permeable network towards the surface. This mechanism has been used to explain activity at Santiaguito, Santa Maria volcano , Guatemala and Soufrière Hills Volcano, Montserrat . If the gas cannot escape fast enough from the magma, it will fragment the magma into small particles of ash. The fluidised ash has a much lower resistance to motion than

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5642-468: The magma and coalesce, or they remain relatively fixed in place until they begin to connect and form a continuously connected network. In the former case, the bubbles may rise through the magma and accumulate at a vertical surface, e.g. the 'roof' of a magma chamber. In volcanoes with an open path to the surface, e.g. Stromboli in Italy , the bubbles may reach the surface and as they pop small explosions occur. In

5733-476: The magma completely solidifies, and the liquidus , defined as the temperature at which the magma is completely liquid. Calculations of solidus temperatures at likely depths suggests that magma generated beneath areas of rifting starts at a temperature of about 1,300 to 1,500 °C (2,400 to 2,700 °F). Magma generated from mantle plumes may be as hot as 1,600 °C (2,900 °F). The temperature of magma generated in subduction zones, where water vapor lowers

5824-475: The magma encounters water, seawater, lake water or groundwater, it can be rapidly fragmented. The rapid expansion of gases is the driving mechanism of most explosive volcanic eruptions. However, a significant portion of volcanic gas release occurs during quasi-continuous quiescent phases of active volcanism. As magmatic gas travelling upward encounters meteoric water in an aquifer , steam is produced. Latent magmatic heat can also cause meteoric waters to ascend as

5915-408: The magma. Gabbro may have a liquidus temperature near 1,200 °C, and the derivative granite-composition melt may have a liquidus temperature as low as about 700 °C. Incompatible elements are concentrated in the last residues of magma during fractional crystallization and in the first melts produced during partial melting: either process can form the magma that crystallizes to pegmatite ,

6006-419: The mantle than subalkaline magmas. Olivine nephelinite magmas are both ultramafic and highly alkaline, and are thought to have come from much deeper in the mantle of the Earth than other magmas. Tholeiitic basalt magma Rhyolite magma Some lavas of unusual composition have erupted onto the surface of the Earth. These include: The concentrations of different gases can vary considerably. Water vapor

6097-424: The melt at different temperatures. This resembles the original melting process in reverse. However, because the melt has usually separated from its original source rock and moved to a shallower depth, the reverse process of crystallization is not precisely identical. For example, if a melt was 50% each of diopside and anorthite, then anorthite would begin crystallizing from the melt at a temperature somewhat higher than

6188-438: The melt at the eutectic composition. Further heating causes the temperature to slowly rise as the remaining anorthite gradually melts and the melt becomes increasingly rich in anorthite liquid. If the mixture has only a slight excess of anorthite, this will melt before the temperature rises much above 1274 °C. If the mixture is almost all anorthite, the temperature will reach nearly the melting point of pure anorthite before all

6279-449: The melt deviated from the eutectic, which has the composition of about 43% anorthite. This effect of partial melting is reflected in the compositions of different magmas. A low degree of partial melting of the upper mantle (2% to 4%) can produce highly alkaline magmas such as melilitites , while a greater degree of partial melting (8% to 11%) can produce alkali olivine basalt. Oceanic magmas likely result from partial melting of 3% to 15% of

6370-402: The melt on geologically relevant time scales. Geologists subsequently found considerable field evidence of such fractional crystallization . When crystals separate from a magma, then the residual magma will differ in composition from the parent magma. For instance, a magma of gabbroic composition can produce a residual melt of granitic composition if early formed crystals are separated from

6461-429: The melting temperature, may be as low as 1,060 °C (1,940 °F). Magma densities depend mostly on composition, iron content being the most important parameter. Magma expands slightly at lower pressure or higher temperature. When magma approaches the surface, its dissolved gases begin to bubble out of the liquid. These bubbles had significantly reduced the density of the magma at depth and helped drive it toward

6552-481: The more abundant elements in the source rock. The ions of these elements fit rather poorly in the structure of the minerals making up the source rock, and readily leave the solid minerals to become highly concentrated in melts produced by a low degree of partial melting. Incompatible elements commonly include potassium , barium , caesium , and rubidium , which are large and weakly charged (the large-ion lithophile elements, or LILEs), as well as elements whose ions carry

6643-415: The most abundant chemical elements in the Earth's crust, with smaller quantities of aluminium , calcium , magnesium , iron , sodium , and potassium , and minor amounts of many other elements. Petrologists routinely express the composition of a silicate magma in terms of the weight or molar mass fraction of the oxides of the major elements (other than oxygen) present in the magma. Because many of

6734-543: The past, based on survey of the broken stubs and shattered pieces of these formations. This has resulted from both deliberate vandalism from souvenir hunters and from high traffic through the caves with visitors bumping into and breaking the fragile formations. This is an unfortunate occurrence in many Icelandic caves. 64°47′03″N 20°43′40″W  /  64.7842°N 20.72771°W  / 64.7842; -20.72771 Magma Magma (from Ancient Greek μάγμα ( mágma )  'thick unguent ')

6825-439: The presence of carbon dioxide, experiments document that the peridotite solidus temperature decreases by about 200 °C in a narrow pressure interval at pressures corresponding to a depth of about 70 km. At greater depths, carbon dioxide can have more effect: at depths to about 200 km, the temperatures of initial melting of a carbonated peridotite composition were determined to be 450 °C to 600 °C lower than for

6916-630: The properties of a magma (such as its viscosity and temperature) are observed to correlate with silica content, silicate magmas are divided into four chemical types based on silica content: felsic , intermediate , mafic , and ultramafic . Felsic or silicic magmas have a silica content greater than 63%. They include rhyolite and dacite magmas. With such a high silica content, these magmas are extremely viscous, ranging from 10 cP (10 Pa⋅s) for hot rhyolite magma at 1,200 °C (2,190 °F) to 10 cP (10 Pa⋅s) for cool rhyolite magma at 800 °C (1,470 °F). For comparison, water has

7007-411: The rate of flow is proportional to the shear stress . Instead, a typical magma is a Bingham fluid , which shows considerable resistance to flow until a stress threshold, called the yield stress, is crossed. This results in plug flow of partially crystalline magma. A familiar example of plug flow is toothpaste squeezed out of a toothpaste tube. The toothpaste comes out as a semisolid plug, because shear

7098-412: The roof have formed since at least the 17th century and blocks of lava fallen from the cave's ceiling cover much of the floor in the rest of the cave, documenting the cave's slow collapse. It was long thought that the cave and the passages that intersect the cave's main tunnel were used as hideouts for outlaws and bandits who would steal livestock from the farmers and shepherds living in the area. However,

7189-405: The roof of a magma chamber and fractional crystallization near its base can even take place simultaneously. Magmas of different compositions can mix with one another. In rare cases, melts can separate into two immiscible melts of contrasting compositions. When rock melts, the liquid is a primary magma . Primary magmas have not undergone any differentiation and represent the starting composition of

7280-405: The same composition with no carbon dioxide. Magmas of rock types such as nephelinite , carbonatite , and kimberlite are among those that may be generated following an influx of carbon dioxide into mantle at depths greater than about 70 km. Increase in temperature is the most typical mechanism for formation of magma within continental crust. Such temperature increases can occur because of

7371-442: The same lavas ranges over seven orders of magnitude, from 10 cP (10 Pa⋅s) for mafic lava to 10 cP (10 Pa⋅s) for felsic magmas. The viscosity is mostly determined by composition but is also dependent on temperature. The tendency of felsic lava to be cooler than mafic lava increases the viscosity difference. The silicon ion is small and highly charged, and so it has a strong tendency to coordinate with four oxygen ions, which form

7462-464: The same time interval, CO 2 emissions from volcanoes during eruptions were estimated to be 1.8 ± 0.9 Tg per year and during non-eruptive activity were 51.3 ± 5.7 Tg per year. Therefore, CO 2 emissions during volcanic eruptions are less than 10% of CO 2 emissions released during non-eruptive volcanic activity. The 15 June 1991 eruption of Mount Pinatubo ( VEI 6) in the Philippines released

7553-404: The source rock. Some calk-alkaline granitoids may be produced by a high degree of partial melting, as much as 15% to 30%. High-magnesium magmas, such as komatiite and picrite , may also be the products of a high degree of partial melting of mantle rock. Certain chemical elements, called incompatible elements , have a combination of ionic radius and ionic charge that is unlike that of

7644-468: The surface and the overburden pressure drops, dissolved gases bubble out of the liquid, so that magma near the surface consists of materials in solid, liquid, and gas phases . Most magma is rich in silica . Rare nonsilicate magma can form by local melting of nonsilicate mineral deposits or by separation of a magma into separate immiscible silicate and nonsilicate liquid phases. Silicate magmas are molten mixtures dominated by oxygen and silicon ,

7735-405: The surface has a composition that is a mass-flow average of the magma exsolved at various depths and is not representative of the magma conditions at any one depth. Molten rock (either magma or lava) near the atmosphere releases high-temperature volcanic gas (>400 °C). In explosive volcanic eruptions , the sudden release of gases from magma may cause rapid movements of the molten rock. When

7826-401: The surface in the first place. The temperature within the interior of the earth is described by the geothermal gradient , which is the rate of temperature change with depth. The geothermal gradient is established by the balance between heating through radioactive decay in the Earth's interior and heat loss from the surface of the earth. The geothermal gradient averages about 25 °C/km in

7917-555: The system. Volcanic gases can be sensed (measured in-situ) or sampled for further analysis. Volcanic gas sensing can be: Sulphur dioxide (SO 2 ) absorbs strongly in the ultraviolet wavelengths and has low background concentrations in the atmosphere. These characteristics make sulphur dioxide a good target for volcanic gas monitoring. It can be detected by satellite-based instruments, which allow for global monitoring, and by ground-based instruments such as DOAS. DOAS arrays are placed near some well-monitored volcanoes and used to estimate

8008-613: The upward intrusion of magma from the mantle. Temperatures can also exceed the solidus of a crustal rock in continental crust thickened by compression at a plate boundary . The plate boundary between the Indian and Asian continental masses provides a well-studied example, as the Tibetan Plateau just north of the boundary has crust about 80 kilometers thick, roughly twice the thickness of normal continental crust. Studies of electrical resistivity deduced from magnetotelluric data have detected

8099-462: The upward movement of solid mantle is critical in the evolution of the Earth. Decompression melting creates the ocean crust at mid-ocean ridges , making it by far the most important source of magma on Earth. It also causes volcanism in intraplate regions, such as Europe, Africa and the Pacific sea floor. Intraplate volcanism is attributed to the rise of mantle plumes or to intraplate extension, with

8190-467: The viscosity. Higher-temperature melts are less viscous, since more thermal energy is available to break bonds between oxygen and network formers. Most magmas contain solid crystals of various minerals, fragments of exotic rocks known as xenoliths and fragments of previously solidified magma. The crystal content of most magmas gives them thixotropic and shear thinning properties. In other words, most magmas do not behave like Newtonian fluids, in which

8281-424: The viscous magma, so accelerates, causing further expansion of the gases and acceleration of the mixture. This sequence of events drives explosive volcanism. Whether gas can escape gently (passive eruptions) or not (explosive eruptions) is determined by the total volatile contents of the initial magma and the viscosity of the magma, which is controlled by its composition. The term 'closed system' degassing refers to

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