Biodiesel is a renewable biofuel , a form of diesel fuel , derived from biological sources like vegetable oils, animal fats, or recycled greases, and consisting of long-chain fatty acid esters . It is typically made from fats.
110-417: RME may refer to: Science and technology [ edit ] Rapeseed Methyl Ester , a form of biodiesel Receptor-mediated endocytosis , a biological process Rich Media Environment , an Open Mobile Alliance standard for broadcasting multimedia content Reaction mass efficiency, a metric to rate chemical reactions RME-6 or GAPVD1, a protein encoded by
220-456: A Fischer–Tropsch process (FT-SPK); with an alcohol -to-jet (ATJ) process from waste fermentation; or from synthetic biology through a solar reactor . Small piston engines can be modified to burn ethanol . Sustainable biofuels are an alternative to electrofuels . Sustainable aviation fuel is certified as being sustainable by a third-party organisation. Biogas is a mixture composed primarily of methane and carbon dioxide produced by
330-409: A diesel additive to reduce levels of particulates, carbon monoxide , and hydrocarbons from diesel-powered vehicles. The term biofuel is used in different ways. One definition is "Biofuels are biobased products, in solid, liquid, or gaseous forms. They are produced from crops or natural products, such as wood, or agricultural residues, such as molasses and bagasse." Other publications reserve
440-434: A renewable energy source. The use of biofuel has been subject to criticism regarding the " food vs fuel " debate, varied assessments of their sustainability , and ongoing deforestation and biodiversity loss as a result of biofuel production. In general, biofuels emit fewer greenhouse gas emissions when burned in an engine and are generally considered carbon-neutral fuels as the carbon emitted has been captured from
550-560: A " food versus fuel " dilemma, second-generation biofuels and third-generation biofuels (also called advanced biofuels or sustainable biofuels or drop-in biofuels) are made from feedstocks which do not directly compete with food or feed crop such as waste products and energy crops. A wide range of waste feedstocks such as those derived from agriculture and forestry activities like rice straw, rice husk, wood chips, and sawdust can be used to produce advanced biofuels through biochemical and thermochemical processes. The feedstock used to make
660-459: A Sino-Tibetan language cluster Topics referred to by the same term [REDACTED] This disambiguation page lists articles associated with the title RME . If an internal link led you here, you may wish to change the link to point directly to the intended article. Retrieved from " https://en.wikipedia.org/w/index.php?title=RME&oldid=1251886820 " Category : Disambiguation pages Hidden categories: Short description
770-429: A biofuel or a fertilizer. When CO 2 and other impurities are removed from biogas, it is called biomethane . The CO 2 can also be combined with hydrogen in methanation to form more methane. Biogas can be recovered from mechanical biological treatment waste processing systems. Landfill gas , a less clean form of biogas, is produced in landfills through naturally occurring anaerobic digestion. If it escapes into
880-429: A by-product, which has its own commercial applications. Biodiesel's primary application is in transport. There have been efforts to make it a drop-in biofuel , meaning compatible with existing diesel engines and distribution infrastructure. However, it is usually blended with petrodiesel , typically to less than 10%, since most engines cannot run on pure biodiesel without modification. The blend percentage of biodiesel
990-416: A compression ratio of 21:1 over all other blends. The study implied that this increase in efficiency was due to fuel density, viscosity, and heating values of the fuels. Fuel systems on some modern diesel engines were not designed to accommodate biodiesel, while many heavy duty engines are able to run with biodiesel blends up to B20. Traditional direct injection fuel systems operate at roughly 3,000 psi at
1100-504: A diesel fuel system interact with the fuel in a way to ensure efficient operation of the fuel system and so the engine. If an out-of-specification fuel is introduced to a system that has specific parameters of operation, then the integrity of the overall fuel system may be compromised. Some of these parameters such as spray pattern and atomization are directly related to injection timing. One study found that during atomization, biodiesel and its blends produced droplets greater in diameter than
1210-458: A flash point of 125 °F (52 °C). In many European countries, a 5% biodiesel blend is widely used and is available at thousands of gas stations. In France, biodiesel is incorporated at a rate of 8% in the fuel used by all French diesel vehicles. Avril Group produces under the brand Diester , a fifth of 11 million tons of biodiesel consumed annually by the European Union . It
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#17328695666731320-553: A flywheel at its base, ran on its own power for the first time in Augsburg , Germany, on 10 August 1893 running on nothing but peanut oil . In remembrance of this event, 10 August has been declared " International Biodiesel Day ". It is often reported that Diesel designed his engine to run on peanut oil, but this is not the case. Diesel stated in his published papers, "at the Paris Exhibition in 1900 ( Exposition Universelle ) there
1430-466: A high boiling point and low vapor pressure . The flash point of biodiesel can exceed 130 °C (266 °F), significantly higher than that of petroleum diesel which may be as low as 52 °C (126 °F). Biodiesel has a density around ~0.88 g/cm , higher than petrodiesel (~0.85 g/cm ). The calorific value of biodiesel is about 37.27 MJ/kg. This is 9% lower than regular Number 2 petrodiesel. Variations in biodiesel energy density
1540-522: A higher boiling point and flash point than petrodiesel, biodiesel is slightly miscible with water and has distinct lubricating properties. Its calorific value is approximately 9% lower than that of standard diesel, impacting fuel efficiency . Biodiesel production has evolved significantly, with early methods including the direct use of vegetable oils, to more advanced processes like transesterification, which reduces viscosity and improves combustion properties. Notably, biodiesel production generates glycerol as
1650-409: A level of 5%, and into the diesel fuel used by some captive fleets (e.g. public transportation ) at a level of 30%. Renault , Peugeot and other manufacturers have certified truck engines for use with up to that level of partial biodiesel; experiments with 50% biodiesel are underway. During the same period, nations in other parts of the world also saw local production of biodiesel starting up: by 1998,
1760-503: A mix of mono- alkyl esters of long chain fatty acids . The most common form uses methanol (converted to sodium methoxide) to produce methyl esters (commonly referred to as Fatty Acid Methyl Ester – FAME) as it is the cheapest alcohol available, though ethanol can be used to produce an ethyl ester (commonly referred to as Fatty Acid Ethyl Ester – FAEE) biodiesel and higher alcohols such as isopropanol and butanol have also been used. Using alcohols of higher molecular weights improves
1870-442: A number of standards for its quality including European standard EN 14214 , ASTM International D6751, and National Standard of Canada CAN/CGSB-3.524. ASTM D6751 (American Society for Testing and Materials) details standards and specifications for biodiesels blended with middle distillate fuels. This specification standard specifies various test methods to be used in the determination of certain properties for biodiesel blends. Some of
1980-603: A peak vertical climb of 37.4 degrees. In 2009, the Grand Canyon Railway started running engine 4960 on used cooking oil. On 8 July 2014, the then Indian Railway Minister D.V. Sadananda Gowda announced in Railway Budget that 5% bio-diesel will be used in Indian Railways' Diesel Engines. Biodiesel can also be used as a heating fuel in domestic and commercial boilers, a mix of heating oil and biofuel which
2090-451: A process called anaerobic digestion to produce biogas. Anaerobic digestion uses a chemical process to break down organic matter with the use of microorganisms in the absence of oxygen to produce biogas. The processes involved in anaerobic respiration are hydrolysis, acidogenesis , acetogenesis , and methanogenesis . Global biofuel production was 81 Mtoe in 2017 which represented an annual increase of about 3% compared to 2010. In 2017,
2200-624: A short-chain alcohol (usually methanol) in the presence of a catalyst (usually sodium hydroxide [NaOH] can be hydrogenated to give a diesel substitute. The resulting product is a straight-chain hydrocarbon with a high cetane number , low in aromatics and sulfur and does not contain oxygen. Hydrogenated oils can be blended with diesel in all proportions. They have several advantages over biodiesel, including good performance at low temperatures, no storage stability problems and no susceptibility to microbial attack. Biogasoline can be produced biologically and thermochemically. Using biological methods,
2310-468: A similar law. With 80–90% of oil spill costs invested in shoreline cleanup, there is a search for more efficient and cost-effective methods to extract oil spills from the shorelines. Biodiesel has displayed its capacity to significantly dissolve crude oil, depending on the source of the fatty acids. In a laboratory setting, oiled sediments that simulated polluted shorelines were sprayed with a single coat of biodiesel and exposed to simulated tides. Biodiesel
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#17328695666732420-893: A study led by Professor Lee Sang-yup at the Korea Advanced Institute of Science and Technology ( KAIST ) and published in the international science journal Nature used modified E. coli fed with glucose found in plants or other non-food crops to produce biogasoline with the produced enzymes. The enzymes converted the sugar into fatty acids and then turned these into hydrocarbons that were chemically and structurally identical to those found in commercial gasoline fuel. The thermochemical approach of producing biogasoline are similar to those used to produced biodiesel. Biogasoline may also be called drop-in gasoline or renewable gasoline. Bioethers (also referred to as fuel ethers or oxygenated fuels) are cost-effective compounds that act as octane rating enhancers. "Bioethers are produced by
2530-498: A test of a 25% biodiesel / 75% petrodiesel blend during the summer of 2008, purchasing fuel from a biodiesel producer sited along the railroad tracks. The train will be powered by biodiesel made in part from canola grown in agricultural regions through which the short line runs. Also in 2007, Disneyland began running the park trains on B98 (98% biodiesel). The program was discontinued in 2008 due to storage issues, but in January 2009, it
2640-463: A wood-fueled gasification reactor, can be connected to an internal combustion engine. Syngas can be used to produce methanol , dimethyl ether and hydrogen , or converted via the Fischer–Tropsch process to produce a diesel substitute, or a mixture of alcohols that can be blended into gasoline. Gasification normally relies on temperatures greater than 700 °C. Lower-temperature gasification
2750-425: Is a synthetic chemical fuel produced from solar energy. Light is converted to chemical energy , typically by reducing protons to hydrogen , or carbon dioxide to organic compounds . A bio-digester is a mechanized toilet that uses decomposition and sedimentation to turn human waste into a renewable fuel called biogas. Biogas can be made from substances like agricultural waste and sewage. The bio-digester uses
2860-401: Is also being developed as a feedstock for ethanol production. Ethanol can be used as a fuel for vehicles in its pure form (E100), but it is usually used as a gasoline additive to increase octane ratings and improve vehicle emissions. Biodiesel is produced from oils or fats using transesterification . It can be used as a fuel for vehicles in its pure form (B100), but it is usually used as
2970-496: Is an oxygenated fuel, meaning it contains a reduced amount of carbon and higher hydrogen and oxygen content than fossil diesel. This improves the combustion of biodiesel and reduces the particulate emissions from unburnt carbon. However, using pure biodiesel may increase NO x -emissions Biodiesel is also safe to handle and transport because it is non-toxic and biodegradable , and has a high flash point of about 300 °F (148 °C) compared to petroleum diesel fuel, which has
3080-410: Is an effective solvent to oil due to its methyl ester component, which considerably lowers the viscosity of the crude oil. Additionally, it has a higher buoyancy than crude oil, which later aids in its removal. As a result, 80% of oil was removed from cobble and fine sand, 50% in coarse sand, and 30% in gravel. Once the oil is liberated from the shoreline, the oil-biodiesel mixture is manually removed from
3190-495: Is being designed into the parameters of diesel engine fuel systems. The traditional inline injection system is more forgiving to poorer quality fuels as opposed to the common rail fuel system. The higher pressures and tighter tolerances of the common rail system allows for greater control over atomization and injection timing. This control of atomization as well as combustion allows for greater efficiency of modern diesel engines as well as greater control over emissions. Components within
3300-417: Is commonly produced by the transesterification of the vegetable oil or animal fat feedstock, and other non-edible raw materials such as frying oil, etc. There are several methods for carrying out this transesterification reaction including the common batch process, heterogeneous catalysts, supercritical processes, ultrasonic methods, and even microwave methods. Chemically, transesterified biodiesel comprises
3410-458: Is currently produced from natural gas , a non-renewable fossil fuel. In the future it is hoped to be produced from biomass as biomethanol . This is technically feasible, but the production is currently being postponed for concerns that the economic viability is still pending. The methanol economy is an alternative to the hydrogen economy to be contrasted with today's hydrogen production from natural gas. Butanol ( C 4 H 9 OH )
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3520-493: Is desirable when co-producing biochar , but results in syngas polluted with tar . The term "biofuels" is also used for solid fuels that are made from biomass, even though this is less common. Algae can be produced in ponds or tanks on land, and out at sea. Algal fuels have high yields, a high ignition point , can be grown with minimal impact on fresh water resources, can be produced using saline water and wastewater , and are biodegradable and relatively harmless to
3630-437: Is different from Wikidata All article disambiguation pages All disambiguation pages Rapeseed Methyl Ester The roots of biodiesel as a fuel source can be traced back to when J. Patrick and E. Duffy first conducted transesterification of vegetable oil in 1853, predating Rudolf Diesel 's development of the diesel engine. Diesel's engine, initially designed for mineral oil, successfully ran on peanut oil at
3740-408: Is formed by ABE fermentation (acetone, butanol, ethanol) and experimental modifications of the process show potentially high net energy gains with biobutanol as the only liquid product. Biobutanol is often claimed to provide a direct replacement for gasoline, because it will produce more energy than ethanol and allegedly can be burned "straight" in existing gasoline engines (without modification to
3850-414: Is fossilised or embedded in geological formations". This means that coal or other fossil fuels is not a form of biomass in this context. First-generation biofuels (also denoted as "conventional biofuels") are made from food crops grown on arable land. The crop's sugar, starch, or oil content is converted into biodiesel or ethanol , using transesterification , or yeast fermentation. To avoid
3960-638: Is indicated by a "B" factor. B100 represents pure biodiesel, while blends like B20 contain 20% of biodiesel, with the remainder being traditional petrodiesel. These blends offer a compromise between the environmental benefits of biodiesel and performance characteristics of standard diesel fuel. Biodiesel blends can be used as heating oil . The environmental impact of biodiesel is complex and varies based on factors like feedstock type, land use changes, and production methods. While it can potentially reduce greenhouse gas emissions compared to fossil fuels, concerns about biodiesel include land use changes, deforestation, and
4070-441: Is known as Evolution Diesel. Straight unmodified edible vegetable oil is generally not used as fuel, but lower-quality oil has been used for this purpose. Used vegetable oil is increasingly being processed into biodiesel, or (more rarely) cleaned of water and particulates and then used as a fuel. The IEA estimates that biodiesel production used 17% of global vegetable oil supplies in 2021. Oils and fats reacted with 10 pounds of
4180-657: Is made using fossil fuel inputs. However, there are sources of renewable methanol made using carbon dioxide or biomass as feedstock, making their production processes free of fossil fuels. Drop-in biofuels Biofuel is a fuel that is produced over a short time span from biomass , rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricultural, domestic or industrial biowaste . Biofuels are mostly used for transportation, but can also be used for heating and electricity. Biofuels (and bioenergy in general) are regarded as
4290-443: Is more dependent on the feedstock used than the production process. Still, these variations are less than for petrodiesel. It has been claimed biodiesel gives better lubricity and more complete combustion thus increasing the engine energy output and partially compensating for the higher energy density of petrodiesel. Biodiesel also contains virtually no sulfur and although lacking sulfur compounds that in petrodiesel provide much of
4400-408: Is nonreactive to biodiesel. Biodiesel has been known to break down deposits of residue in the fuel lines where petrodiesel has been used. As a result, fuel filters may become clogged with particulates if a quick transition to pure biodiesel is made. Therefore, it is recommended to change the fuel filters on engines and heaters shortly after first switching to a biodiesel blend. Since the passage of
4510-418: Is not sufficient to convert the biomass completely to carbon dioxide and water). Before partial combustion the biomass is dried and sometimes pyrolysed . Syngas is more efficient than direct combustion of the original biofuel; more of the energy contained in the fuel is extracted. Syngas may be burned directly in internal combustion engines, turbines or high-temperature fuel cells. The wood gas generator ,
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4620-407: Is predicted to increase by 56% over 2022–2027. By 2027 worldwide biofuel production is expected to supply 5.4% of the world's fuels for transport including 1% of aviation fuel. Demand for aviation biofuel is forecast to increase. However some policy has been criticised for favoring ground transportation over aviation. The two most common types of biofuel are bioethanol and biodiesel . Brazil
4730-976: Is sometimes called biogasoline , which is incorrect as it is chemically different, being an alcohol and not a hydrocarbon like gasoline. Biodiesel is the most common biofuel in Europe. It is produced from oils or fats using transesterification and is a liquid similar in composition to fossil/mineral diesel. Chemically, it consists mostly of fatty acid methyl (or ethyl) esters ( FAMEs ). Feedstocks for biodiesel include animal fats, vegetable oils, soy , rapeseed , jatropha , mahua , mustard , flax , sunflower , palm oil , hemp , field pennycress , Pongamia pinnata and algae . Pure biodiesel (B100, also known as "neat" biodiesel) currently reduces emissions with up to 60% compared to diesel Second generation B100. As of 2020 , researchers at Australia's CSIRO have been studying safflower oil as an engine lubricant , and researchers at Montana State University 's Advanced Fuels Center in
4840-825: Is standardized and taxed slightly differently from diesel fuel used for transportation. Bioheat fuel is a proprietary blend of biodiesel and traditional heating oil. Bioheat is a registered trademark of the National Biodiesel Board [NBB] and the National Oilheat Research Alliance [NORA] in the United States, and Columbia Fuels in Canada. Heating biodiesel is available in various blends. ASTM 396 recognizes blends of up to 5 percent biodiesel as equivalent to pure petroleum heating oil. Blends of higher levels of up to 20% biofuel are used by many consumers. Research
4950-410: Is still at the research level. The biofuels that are secreted by the bioengineered organisms are expected to have higher photon-to-fuel conversion efficiency, compared to older generations of biofuels. One of the advantages of this class of biofuels is that the cultivation of the organisms that produce the biofuels does not require the use of arable land. The disadvantages include the cost of cultivating
5060-498: Is the largest producer of bioethanol, while the EU is the largest producer of biodiesel. The energy content in the global production of bioethanol and biodiesel is 2.2 and 1.8 EJ per year, respectively. Bioethanol is an alcohol made by fermentation , mostly from carbohydrates produced in sugar or starch crops such as maize , sugarcane , or sweet sorghum . Cellulosic biomass , derived from non-food sources, such as trees and grasses,
5170-528: Is the leading European producer of biodiesel. Green diesel can be produced from a combination of biochemical and thermochemical processes. Conventional green diesel is produced through hydroprocessing biological oil feedstocks, such as vegetable oils and animal fats. Recently, it is produced using series of thermochemical processes such as pyrolysis and hydroprocessing. In the thermochemical route, syngas produced from gasification, bio-oil produced from pyrolysis or biocrude produced from hydrothermal liquefaction
5280-473: Is to start using biodiesel as a blend, and decreasing the petroleum proportion over time can allow the varnishes to come off more gradually and be less likely to clog. Due to biodiesel's strong solvent properties, the furnace is cleaned out and generally becomes more efficient. A law passed under Massachusetts Governor Deval Patrick requires all home heating diesel in that state to be 2% biofuel by July 1, 2010, and 5% biofuel by 2013. New York City has passed
5390-409: Is underway to determine whether such blends affect performance. Older furnaces may contain rubber parts that would be affected by biodiesel's solvent properties, but can otherwise burn biodiesel without any conversion required. Care must be taken, given that varnishes left behind by petrodiesel will be released and can clog pipes—fuel filtering and prompt filter replacement is required. Another approach
5500-629: Is upgraded to green diesel using hydroprocessing. Hydroprocessing is the process of using hydrogen to reform a molecular structure. For example, hydrocracking which is a widely used hydroprocessing technique in refineries is used at elevated temperatures and pressure in the presence of a catalyst to break down larger molecules , such as those found in vegetable oils , into shorter hydrocarbon chains used in diesel engines. Green diesel may also be called renewable diesel, drop-in biodiesel, hydrotreated vegetable oil (HVO fuel) or hydrogen-derived renewable diesel. Unlike biodiesel, green diesel has exactly
5610-467: Is used to decarbonize medium and long-haul air travel. These types of travel generate the most emissions, and could extend the life of older aircraft types by lowering their carbon footprint. Synthetic paraffinic kerosene (SPK) refers to any non-petroleum-based fuel designed to replace kerosene jet fuel , which is often, but not always, made from biomass. Biofuels are biomass -derived fuels from plants, animals, or waste; depending on which type of biomass
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#17328695666735720-545: Is used, they could lower CO 2 emissions by 20–98% compared to conventional jet fuel . The first test flight using blended biofuel was in 2008, and in 2011, blended fuels with 50% biofuels were allowed on commercial flights. In 2023 SAF production was 600 million liters, representing 0.2% of global jet fuel use. Aviation biofuel can be produced from plant or animal sources such as Jatropha , algae , tallows , waste oils, palm oil , Babassu , and Camelina (bio-SPK); from solid biomass using pyrolysis processed with
5830-404: The 1900 Paris Exposition . This landmark event highlighted the potential of vegetable oils as an alternative fuel source. The interest in using vegetable oils as fuels resurfaced periodically, particularly during resource-constrained periods such as World War II. However, challenges such as high viscosity and resultant engine deposits were significant hurdles. The modern form of biodiesel emerged in
5940-573: The EN 14214 standard. The use of the specified biodiesel type in its cars will not void any warranty. Mercedes-Benz does not allow diesel fuels containing greater than 5% biodiesel (B5) due to concerns about "production shortcomings". Any damages caused by the use of such non-approved fuels will not be covered by the Mercedes-Benz Limited Warranty. Starting in 2004, the city of Halifax, Nova Scotia decided to update its bus system to allow
6050-645: The Energy Policy Act of 2005 , biodiesel use has been increasing in the United States. In the UK, the Renewable Transport Fuel Obligation obliges suppliers to include 5% renewable fuel in all transport fuel sold in the UK by 2010. For road diesel, this effectively means 5% biodiesel (B5). In 2005, Chrysler (then part of DaimlerChrysler) released the Jeep Liberty CRD diesels from the factory into
6160-640: The GAPVD1 gene Transport [ edit ] Ronsdorf-Müngstener Eisenbahn or Ronsdorf-Müngsten Railway, North Rhine-Westphalia, Germany; see Wuppertal-Ronsdorf station IATA Airport Code for Griffiss International Airport in Rome, New York Other uses [ edit ] River Music Experience , in Davenport, Iowa ISO 639:rme , Angloromani language, spoken by the Romani people Rme, known as Qiang language ,
6270-564: The coal-tar products of the present time." Despite the widespread use of petroleum-derived diesel fuels, interest in vegetable oils as fuels for internal combustion engines was reported in several countries during the 1920s and 30s and later during World War II. Belgium , France, Italy, the United Kingdom, Portugal , Germany, Brazil , Argentina , Japan and China were reported to have tested and used vegetable oils as diesel fuels during this time. Some operational problems were reported due to
6380-626: The diesel particulate filter , D.P.F., are both designed to mitigate the production of harmful emissions. The feedstock used to make the biodiesel fuel can significantly alter the resulting exhaust gas and particulate matter emissions, even when blended with commercial diesel fuel. A study performed by the Chonbuk National University concluded that a B30 biodiesel blend reduced carbon monoxide emissions by approximately 83% and particulate matter emissions by roughly 33%. NO x emissions, however, were found to increase without
6490-425: The 1930s, when a method was found for transforming vegetable oils for fuel use, laying the groundwork for contemporary biodiesel production. The physical and chemical properties of biodiesel vary depending on its source and production method. The US National Biodiesel Board defines "biodiesel" as a mono-alkyl ester. It has been experimented with in railway locomotives and power generators. Generally characterized by
6600-499: The Austrian Biofuels Institute had identified 21 countries with commercial biodiesel projects. 100% biodiesel is now available at many normal service stations across Europe. The color of biodiesel ranges from clear to golden to dark brown, depending on the production method and the feedstock used to make the fuel. This also changes the resulting fuel properties. In general, biodiesel is slightly miscible with water, has
6710-592: The Brazilian scientist. Research into the use of transesterified sunflower oil , and refining it to diesel fuel standards, was initiated in South Africa in 1979. By 1983, the process for producing fuel-quality, engine-tested biodiesel was completed and published internationally. An Austrian company, Gaskoks, obtained the technology from the South African Agricultural Engineers; the company erected
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#17328695666736820-537: The D.P.F. and so interfere with the clearances of the filter. This may cause the filter to clog and interfere with the regeneration process. In a study on the impact of E.G.R. rates with blends of jathropa biodiesel it was shown that there was a decrease in fuel efficiency and torque output due to the use of biodiesel on a diesel engine designed with an E.G.R. system. It was found that CO and CO 2 emissions increased with an increase in exhaust gas recirculation but NO x levels decreased. The opacity level of
6930-521: The European market with 5% biodiesel blends, indicating at least partial acceptance of biodiesel as an acceptable diesel fuel additive. In 2007, DaimlerChrysler indicated its intention to increase warranty coverage to 20% biodiesel blends if biofuel quality in the United States can be standardized. The Volkswagen Group has released a statement indicating that several of its vehicles are compatible with B5 and B100 made from rape seed oil and compatible with
7040-414: The U.S. Environmental Protection Agency ( E.P.A. ). As these emissions are a byproduct of the combustion process, in order to ensure E.P.A. compliance a fuel system must be capable of controlling the combustion of fuels as well as the mitigation of emissions. There are a number of new technologies being phased in to control the production of diesel emissions. The exhaust gas recirculation system, E.G.R., and
7150-416: The UK, it is highly unlikely they will become a fuel in and of itself due to the low energy density. An aviation biofuel (also known as bio-jet fuel or bio-aviation fuel (BAF) ) is a biofuel used to power aircraft and is a sustainable aviation fuel (SAF). The International Air Transport Association (IATA) considers it a key element in reducing the environmental impact of aviation . Aviation biofuel
7260-498: The US have been studying the oil's performance in a large diesel engine , with results described as a "breakthrough". Biodiesel can be used in any diesel engine and modified equipment when mixed with mineral diesel. It can also be used in its pure form (B100) in diesel engines, but some maintenance and performance problems may occur during wintertime utilization, since the fuel becomes somewhat more viscous at lower temperatures, depending on
7370-490: The US was the largest biofuel producer in the world producing 37 Mtoe, followed by Brazil and South America at 23 Mtoe and Europe (mainly Germany) at 12 Mtoe. An assessment from 2017 found that: "Biofuels will never be a major transport fuel as there is just not enough land in the world to grow plants to make biofuel for all vehicles. It can however, be part of an energy mix to take us into a future of renewable energy ." In 2021, worldwide biofuel production provided 4.3% of
7480-474: The University of Brussels (Belgium) was granted a patent for a "Procedure for the transformation of vegetable oils for their uses as fuels" (fr. " Procédé de Transformation d’Huiles Végétales en Vue de Leur Utilisation comme Carburants ") Belgian Patent 422,877. This patent described the alcoholysis (often referred to as transesterification) of vegetable oils using ethanol (and mentions methanol) in order to separate
7590-487: The applicability to power production of the Arachide, or earth-nut, which grows in considerable quantities in their African colonies, and can easily be cultivated there." Diesel himself later conducted related tests and appeared supportive of the idea. In a 1912 speech Diesel said, "the use of vegetable oils for engine fuels may seem insignificant today but such oils may become, in the course of time, as important as petroleum and
7700-598: The application of an E.G.R. system. The study also concluded that, with E.G.R, a B20 biodiesel blend considerably reduced the emissions of the engine. Additionally, analysis by the California Air Resources Board found that biodiesel had the lowest carbon emissions of the fuels tested, those being ultra-low-sulfur diesel , gasoline, corn-based ethanol , compressed natural gas , and five types of biodiesel from varying feedstocks. Their conclusions also showed great variance in carbon emissions of biodiesel based on
7810-463: The atmosphere by the crops used in production. However, life-cycle assessments of biofuels have shown large emissions associated with the potential land-use change required to produce additional biofuel feedstocks. The outcomes of lifecycle assessments (LCAs) for biofuels are highly situational and dependent on many factors including the type of feedstock, production routes, data variations, and methodological choices. This could be added to emphasize
7920-410: The atmosphere, it acts as a greenhouse gas . In Sweden, "waste-to-energy" power plants capture methane biogas from garbage and use it to power transport systems. Farmers can produce biogas from cattle manure via anaerobic digesters. Syngas , a mixture of carbon monoxide , hydrogen and various hydrocarbons, is produced by partial combustion of biomass (combustion with an amount of oxygen that
8030-429: The biofuel-producing organisms being very high. Electrofuels and solar fuels may or may not be biofuels, depending on whether they contain biological elements. Electrofuels are made by storing electrical energy in the chemical bonds of liquids and gases. The primary targets are butanol , biodiesel, and hydrogen , but include other alcohols and carbon-containing gases such as methane and butane . A solar fuel
8140-401: The brake thermal efficiency of B40 was superior to traditional petroleum counterpart at higher compression ratios (this higher brake thermal efficiency was recorded at compression ratios of 21:1). It was noted that, as the compression ratios increased, the efficiency of all fuel types – as well as blends being tested – increased; though it was found that a blend of B40 was the most economical at
8250-446: The byproducts that result in smog, ozone, and sulfur emissions. The use of these generators in residential areas around schools, hospitals, and the general public result in substantial reductions in poisonous carbon monoxide and particulate matter. The power output of biodiesel depends on its blend, quality, and load conditions under which the fuel is burnt. The thermal efficiency for example of B100 as compared to B20 will vary due to
8360-631: The cold flow properties of the resulting ester, at the cost of a less efficient transesterification reaction. A lipid transesterification production process is used to convert the base oil to the desired esters. Any free fatty acids (FFAs) in the base oil are either converted to soap and removed from the process, or they are esterified (yielding more biodiesel) using an acidic catalyst. After this processing, unlike straight vegetable oil , biodiesel has combustion properties very similar to those of petroleum diesel, and can replace it in most current uses. The methanol used in most biodiesel production processes
8470-457: The complexity and variability in assessing the environmental impacts of biofuels. Estimates about the climate impact from biofuels vary widely based on the methodology and exact situation examined. Therefore, the climate change mitigation potential of biofuel varies considerably: in some scenarios emission levels are comparable to fossil fuels, and in other scenarios the biofuel emissions result in negative emissions . Global demand for biofuels
8580-419: The differing energy content of the various blends. Thermal efficiency of a fuel is based in part on fuel characteristics such as: viscosity , specific density , and flash point ; these characteristics will change as the blends as well as the quality of biodiesel varies. The American Society for Testing and Materials has set standards in order to judge the quality of a given fuel sample. One study found that
8690-407: The droplet size and the distance from the injector tip. It was found that B100 had the greatest spray penetration, this was attributed to the greater density of B100. Having a greater droplet size can lead to inefficiencies in the combustion, increased emissions, and decreased horse power. In another study it was found that there is a short injection delay when injecting biodiesel. This injection delay
8800-407: The droplets produced by traditional petrodiesel. The smaller droplets were attributed to the lower viscosity and surface tension of traditional diesel fuel. It was found that droplets at the periphery of the spray pattern were larger in diameter than the droplets at the center. This was attributed to the faster pressure drop at the edge of the spray pattern; there was a proportional relationship between
8910-400: The engine itself, although this depends on the fuel rail design. Since biodiesel is an effective solvent and cleans residues deposited by mineral diesel, engine filters may need to be replaced more often, as the biofuel dissolves old deposits in the fuel tank and pipes. It also effectively cleans the engine combustion chamber of carbon deposits, helping to maintain efficiency. Biodiesel
9020-490: The engine or car), is less corrosive and less water-soluble than ethanol, and could be distributed via existing infrastructures. Escherichia coli strains have also been successfully engineered to produce butanol by modifying their amino acid metabolism . One drawback to butanol production in E. coli remains the high cost of nutrient rich media , however, recent work has demonstrated E. coli can produce butanol with minimal nutritional supplementation. Biobutanol
9130-608: The environment if spilled. However, production requires large amounts of energy and fertilizer, the produced fuel degrades faster than other biofuels, and it does not flow well in cold temperatures. By 2017, due to economic considerations, most efforts to produce fuel from algae have been abandoned or changed to other applications. Third and fourth-generation biofuels also include biofuels that are produced by bioengineered organisms i.e. algae and cyanobacteria. Algae and cyanobacteria will use water, carbon dioxide, and solar energy to produce biofuels. This method of biofuel production
9240-575: The factory, will be rated for up to B20 (blend of 20% biodiesel / 80% regular diesel) biodiesel compatibility British train operating company Virgin Trains West Coast claimed to have run the UK's first "biodiesel train", when a Class 220 was converted to run on 80% petrodiesel and 20% biodiesel. The British Royal Train on 15 September 2007 completed its first ever journey run on 100% biodiesel fuel supplied by Green Fuels Ltd. Prince Charles and Green Fuels managing director James Hygate were
9350-440: The fatty acids from the glycerol by replacing the glycerol with short linear alcohols. This appears to be the first account of the production of what is known as "biodiesel" today. This is similar (copy) to the patented methods used in the 18th century to make lamp-oil, and may be inspired by some old historical oil lamps, in some places. More recently, in 1977, Brazilian scientist Expedito Parente invented and submitted for patent,
9460-407: The feedstock used. Electronically controlled ' common rail ' and ' Unit Injector ' type systems from the late 1990s onwards can only use biodiesel blended with conventional diesel fuel. These engines have finely metered and atomized multiple-stage injection systems that are very sensitive to the viscosity of the fuel. Many current-generation diesel engines are designed to run on B100 without altering
9570-425: The feedstock used. Of soy , tallow , canola , corn , and used cooking oil , soy showed the highest carbon emissions, while used cooking oil produced the lowest. While studying the effect of biodiesel on diesel particulate filters , it was found that though the presence of sodium and potassium carbonates aided in the catalytic conversion of ash, as the diesel particulates are catalyzed, they may congregate inside
9680-694: The fermentation of sugars or starches (easiest to produce) or cellulose (more difficult to produce).The IEA estimates that ethanol production used 20% of sugar supplies and 13% of corn supplies in 2021. Ethanol fuel is the most common biofuel worldwide, particularly in Brazil . Alcohol fuels are produced by fermentation of sugars derived from wheat , corn , sugar beets , sugar cane , molasses and any sugar or starch from which alcoholic beverages such as whiskey , can be made (such as potato and fruit waste, etc.). Production methods used are enzyme digestion (to release sugars from stored starches), fermentation of
9790-580: The first biodiesel pilot plant in November 1987, and the first industrial-scale plant in April 1989 (with a capacity of 30,000 tons of rapeseed per annum). Throughout the 1990s, plants were opened in many European countries, including the Czech Republic , Germany and Sweden . France launched local production of biodiesel fuel (referred to as diester ) from rapeseed oil, which is mixed into regular diesel fuel at
9900-401: The first industrial process for the production of biodiesel. This process is classified as biodiesel by international norms, conferring a "standardized identity and quality. No other proposed biofuel has been validated by the motor industry." As of 2010, Parente's company Tecbio is working with Boeing and NASA to certify bioquerosene (bio-kerosene), another product produced and patented by
10010-516: The first passengers on a train fueled entirely by biodiesel fuel. Since 2007, the Royal Train has operated successfully on B100 (100% biodiesel). A government white paper also proposed converting large portions of the UK railways to biodiesel but the proposal was subsequently dropped in favour of further electrification. Similarly, a state-owned short-line railroad in Eastern Washington ran
10120-433: The fleet of city buses to run entirely on a fish-oil based biodiesel. This caused the city some initial mechanical issues, but after several years of refining, the entire fleet had successfully been converted. In 2007, McDonald's of UK announced it would start producing biodiesel from the waste oil byproduct of its restaurants. This fuel would be used to run its fleet. The 2014 Chevy Cruze Clean Turbo Diesel, direct from
10230-425: The food vs. fuel debate. The debate centers on the impact of biodiesel production on food prices and availability, as well as its overall carbon footprint. Despite these challenges, biodiesel remains a key component in the global strategy to reduce reliance on fossil fuels and mitigate the impacts of climate change . Blends of biodiesel and conventional hydrocarbon-based diesel are most commonly distributed for use in
10340-428: The fuels either grow on arable land but are byproducts of the main crop, or they are grown on marginal land. Second-generation feedstocks also include straw, bagasse, perennial grasses, jatropha, waste vegetable oil, municipal solid waste and so forth. Biologically produced alcohols , most commonly ethanol, and less commonly propanol and butanol , are produced by the action of microorganisms and enzymes through
10450-440: The high viscosity of vegetable oils compared to petroleum diesel fuel, which results in poor atomization of the fuel in the fuel spray and often leads to deposits and coking of the injectors, combustion chamber and valves. Attempts to overcome these problems included heating of the vegetable oil, blending it with petroleum-derived diesel fuel or ethanol, pyrolysis and cracking of the oils. On 31 August 1937, Georges Chavanne of
10560-418: The injector tip while the modern common rail fuel system operates upwards of 30,000 PSI at the injector tip. Components are designed to operate at a great temperature range, from below freezing to over 1,000 °F (560 °C). Diesel fuel is expected to burn efficiently and produce as few emissions as possible. As emission standards are being introduced to diesel engines the need to control harmful emissions
10670-621: The jathropa blends was in an acceptable range, where traditional diesel was out of acceptable standards. It was shown that a decrease in Nox emissions could be obtained with an E.G.R. system. This study showed an advantage over traditional diesel within a certain operating range of the E.G.R. system. As of 2017, blended biodiesel fuels (especially B5, B8, and B20) are regularly used in many heavy-duty vehicles, especially transit buses in US cities. Characterization of exhaust emissions showed significant emission reductions compared to regular diesel. Biodiesel
10780-1061: The lubricity, it has promising lubricating properties and cetane ratings compared to low sulfur diesel fuels and often serves as an additive to ultra-low-sulfur diesel (ULSD) fuel to aid with lubrication. Biodiesel Fuels with higher lubricity may increase the usable life of high-pressure fuel injection equipment that relies on the fuel for its lubrication. Depending on the engine, this might include high pressure injection pumps, pump injectors (also called unit injectors ) and fuel injectors . Biodiesel can be used in pure form (B100) or may be blended with petroleum diesel at any concentration in most injection pump diesel engines. New extreme high-pressure (29,000 psi) common rail engines have strict factory limits of B5 or B20, depending on manufacturer. Biodiesel has different solvent properties from petrodiesel, and will degrade natural rubber gaskets and hoses in vehicles (mostly vehicles manufactured before 1992), although these tend to wear out naturally and most likely will have already been replaced with FKM , which
10890-417: The most commonly used ethers in fuel to replace lead. Ethers were introduced in Europe in the 1970s to replace the highly toxic compound. Although Europeans still use bioether additives, the U.S. Energy Policy Act of 2005 lifted a requirement for reformulated gasoline to include an oxygenate, leading to less MTBE being added to fuel. Although bioethers are likely to replace ethers produced from petroleum in
11000-437: The process of anaerobic digestion of organic material by micro-organisms . Other trace components of this mixture includes water vapor, hydrogen sulfide , siloxanes, hydrocarbons, ammonia, oxygen, carbon monoxide, and nitrogen. It can be produced either from biodegradable waste materials or by the use of energy crops fed into anaerobic digesters to supplement gas yields. The solid byproduct, digestate , can be used as
11110-761: The reaction of reactive iso-olefins, such as iso-butylene, with bioethanol." Bioethers are created from wheat or sugar beets, and also be produced from the waste glycerol that results from the production of biodiesel. They also enhance engine performance, while significantly reducing engine wear and toxic exhaust emissions . By greatly reducing the amount of ground-level ozone emissions, they contribute to improved air quality. In transportation fuel there are six ether additives: dimethyl ether (DME), diethyl ether (DEE), methyl tert -butyl ether (MTBE), ethyl tert -butyl ether (ETBE), tert -amyl methyl ether (TAME), and tert -amyl ethyl ether (TAEE). The European Fuel Oxygenates Association identifies MTBE and ETBE as
11220-695: The retail diesel fuel marketplace. Much of the world uses a system known as the "B" factor to state the amount of biodiesel in any fuel mix: Blends of 20% biodiesel and lower can be used in diesel equipment with no, or only minor modifications, although certain manufacturers do not extend warranty coverage if equipment is damaged by these blends. The B6 to B20 blends are covered by the ASTM D7467 specification. Biodiesel can also be used in its pure form (B100), but may require certain engine modifications to avoid maintenance and performance problems. Blending B100 with petroleum diesel may be accomplished by: Biodiesel has
11330-563: The same chemical properties as petroleum-based diesel. It does not require new engines, pipelines or infrastructure to distribute and use, but has not been produced at a cost that is competitive with petroleum . Gasoline versions are also being developed. Green diesel is being developed in Louisiana and Singapore by ConocoPhillips , Neste Oil , Valero , Dynamic Fuels, and Honeywell UOP as well as Preem in Gothenburg, Sweden, creating what
11440-442: The sugars, distillation and drying. The distillation process requires significant energy input to generate heat. Heat is sometimes generated with unsustainable natural gas fossil fuel, but cellulosic biomass such as bagasse is the most common fuel in Brazil, while pellets, wood chips and also waste heat are more common in Europe. Corn-to-ethanol and other food stocks has led to the development of cellulosic ethanol . Methanol
11550-401: The term biofuel for liquid or gaseous fuels, used for transportation. The IPCC Sixth Assessment Report defines biofuel as "A fuel, generally in liquid form, produced from biomass . Biofuels include bioethanol from sugarcane, sugar beet or maize, and biodiesel from canola or soybeans.". It goes on to define biomass in this context as "organic material excluding the material that
11660-434: The tests mentioned include flash point and kinematic viscosity. [2] Transesterification of a vegetable oil was conducted as early as 1853 by Patrick Duffy, four decades before the first diesel engine became functional. Earlier processes for making lamp oil, were patented (1810, Prague) but not published in peer-reviewed publications. Rudolf Diesel 's prime model, a single 10 ft (3.05 m) iron cylinder with
11770-505: The water surface with skimmers. Any remaining mixture is easily broken down due to the high biodegradability of biodiesel, and the increased surface area exposure of the mixture. In 2001, UC Riverside installed a 6-megawatt backup power system that is entirely fueled by biodiesel. Backup diesel-fueled generators allow companies to avoid damaging blackouts of critical operations at the expense of high pollution and emission rates. By using B100, these generators were able to essentially eliminate
11880-465: Was announced that the park would then be running all trains on biodiesel manufactured from its own used cooking oils. This is a change from running the trains on soy-based biodiesel. In 2007, the historic Mt. Washington Cog Railway added the first biodiesel locomotive to its all-steam locomotive fleet. The fleet has climbed up the western slopes of Mount Washington in New Hampshire since 1868 with
11990-444: Was attributed to the greater viscosity of Biodiesel. It was noted that the higher viscosity and the greater cetane rating of biodiesel over traditional petrodiesel lead to poor atomization, as well as mixture penetration with air during the ignition delay period. Another study noted that this ignition delay may aid in a decrease of NO x emission. Emissions are inherent to the combustion of diesel fuels that are regulated by
12100-506: Was shown by the Otto Company a small Diesel engine, which, at the request of the French government ran on arachide (earth-nut or pea-nut) oil (see biodiesel), and worked so smoothly that only a few people were aware of it. The engine was constructed for using mineral oil, and was then worked on vegetable oil without any alterations being made. The French Government at the time thought of testing
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