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92-582: As of 2011, NLC was responsible for transporting approximately 50 percent of Pakistan's domestic crude oil , amounting to about 76,000 barrels per day. The National Logistics Cell was founded following the 1977–1978 wheat crisis in Pakistan, due to insufficient railway capabilities to transport wheat from the Karachi seaport inland. Initially, the Pakistan Army was asked to address the crisis, which ultimately led to

184-561: A blend with conventional jet fuel. As of the end of 2017, four other pathways to SPK are certified, with their designations and maximum blend percentage in brackets: Hydroprocessed Esters and Fatty Acids (HEFA SPK, 50%); synthesized iso-paraffins from hydroprocessed fermented sugars (SIP, 10%); synthesized paraffinic kerosene plus aromatics (SPK/A, 50%); alcohol-to-jet SPK (ATJ-SPK, 30%). Both FT and HEFA based SPKs blended with JP-8 are specified in MIL-DTL-83133H. Some synthetic jet fuels show

276-465: A carriage capacity of 50,000 tons of dry cargo and 9 million liters of fluid cargo, with a fleet of 2,000 vehicles. Its assets were valued at around Rs 5 billion. Since its establishment, NLC had also diversified into the construction industry , undertaking various military and civilian infrastructure projects in Pakistan, including roads and bridges . In July 2011, the Government of Pakistan allowed

368-520: A fluid resembling petroleum, which when treated in the same way as the seep oil gave similar products. Young found that by slow distillation he could obtain several useful liquids from it, one of which he named "paraffine oil" because at low temperatures it congealed into a substance resembling paraffin wax. The production of these oils and solid paraffin wax from coal formed the subject of his patent dated October 17, 1850. In 1850, Young & Meldrum and Edward William Binney entered into partnership under

460-635: A high- octane gasoline known as avgas ) has a high volatility to improve its carburetion characteristics and high autoignition temperature to prevent preignition in high compression aircraft engines. Turbine engines (as with diesel engines ) can operate with a wide range of fuels because fuel is injected into the hot combustion chamber. Jet and gas turbine ( turboprop , helicopter ) aircraft engines typically use lower cost fuels with higher flash points , which are less flammable and therefore safer to transport and handle. The first axial compressor jet engine in widespread production and combat service,

552-512: A much shallower level. The Athabasca oil sands are one example of this. An alternative mechanism to the one described above was proposed by Russian scientists in the mid-1850s, the hypothesis of abiogenic petroleum origin (petroleum formed by inorganic means), but this is contradicted by geological and geochemical evidence. Abiogenic sources of oil have been found, but never in commercially profitable amounts. "The controversy isn't over whether abiogenic oil reserves exist," said Larry Nation of

644-476: A process known as catagenesis . Formation of petroleum occurs from hydrocarbon pyrolysis in a variety of mainly endothermic reactions at high temperatures or pressures, or both. These phases are described in detail below. In the absence of plentiful oxygen, aerobic bacteria were prevented from decaying the organic matter after it was buried under a layer of sediment or water. However, anaerobic bacteria were able to reduce sulfates and nitrates among

736-506: A process to make jet fuel from seawater. The technology requires an input of electrical energy to separate Oxygen (O 2 ) and Hydrogen (H 2 ) gas from seawater using an iron-based catalyst, followed by an oligomerization step wherein carbon monoxide (CO) and hydrogen are recombined into long-chain hydrocarbons, using zeolite as the catalyst. The technology is expected to be deployed in the 2020s by U.S. Navy warships, especially nuclear-powered aircraft carriers. On February 8, 2021,

828-465: A reduction in pollutants such as SOx, NOx, particulate matter, and sometimes carbon emissions. It is envisaged that usage of synthetic jet fuels will increase air quality around airports which will be particularly advantageous at inner city airports. Qatar Airways became the first airline to operate a commercial flight on a 50:50 blend of synthetic Gas to Liquid (GTL) jet fuel and conventional jet fuel. The natural gas derived synthetic kerosene for

920-669: A result, a few aircraft engine manufacturers, most notably Thielert and Austro Engine , have begun offering aircraft diesel engines which run on jet fuel which may simplify airport logistics by reducing the number of fuel types required. Jet fuel is available in most places in the world, whereas avgas is only widely available in a few countries which have a large number of general aviation aircraft. A diesel engine may be more fuel-efficient than an avgas engine. However, very few diesel aircraft engines have been certified by aviation authorities. Diesel aircraft engines are uncommon today, even though opposed-piston aviation diesel powerplants such as

1012-516: A set of parallel reactions, and oil eventually breaks down to natural gas by another set of reactions. The latter set is regularly used in petrochemical plants and oil refineries . Jet fuel Jet fuel or aviation turbine fuel ( ATF , also abbreviated avtur ) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines . It is colorless to straw-colored in appearance. The most commonly used fuels for commercial aviation are Jet A and Jet A-1, which are produced to

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1104-643: A significant amount of petroleum while drilling for lignite in Wietze , Germany. Wietze later provided about 80% of German consumption in the Wilhelminian Era. The production stopped in 1963, but Wietze has hosted a Petroleum Museum since 1970. Oil sands have been mined since the 18th century. In Wietze in lower Saxony, natural asphalt/bitumen has been explored since the 18th century. Both in Pechelbronn as in Wietze,

1196-574: A source of internal and inter-state conflict, leading to both state-led wars and other resource conflicts . Production of petroleum is estimated to reach peak oil before 2035 as global economies lower dependencies on petroleum as part of climate change mitigation and a transition towards renewable energy and electrification . The word petroleum comes from Medieval Latin petroleum (literally 'rock oil'), which comes from Latin petra 'rock' (from Greek pétra πέτρα ) and oleum 'oil' (from Greek élaion ἔλαιον ). The origin of

1288-413: A standardized international specification. The only other jet fuel commonly used in civilian turbine-engine powered aviation is Jet B, which is used for its enhanced cold-weather performance. Jet fuel is a mixture of a variety of hydrocarbons . Because the exact composition of jet fuel varies widely based on petroleum source, it is impossible to define jet fuel as a ratio of specific hydrocarbons. Jet fuel

1380-411: A variety of liquid, gaseous, and solid components. Lighter hydrocarbons are the gases methane , ethane , propane and butane . Otherwise, the bulk of the liquid and solids are largely heavier organic compounds, often hydrocarbons (C and H only). The proportion of light hydrocarbons in the petroleum mixture varies among oil fields . An oil well produces predominantly crude oil. Because the pressure

1472-520: A visit to Fort Duquesne in 1750. Early British explorers to Myanmar documented a flourishing oil extraction industry based in Yenangyaung that, in 1795, had hundreds of hand-dug wells under production. Merkwiller-Pechelbronn is said to be the first European site where petroleum has been explored and used. The still active Erdpechquelle, a spring where petroleum appears mixed with water has been used since 1498, notably for medical purposes. There

1564-547: A year before Drake's Pennsylvania operation and could be argued to be the first commercial oil well in North America. The discovery at Oil Springs touched off an oil boom which brought hundreds of speculators and workers to the area. Advances in drilling continued into 1862 when local driller Shaw reached a depth of 62 metres using the spring-pole drilling method. On January 16, 1862, after an explosion of natural gas , Canada's first oil gusher came into production, shooting into

1656-406: Is a naphtha-kerosene fuel that is used for its enhanced cold-weather performance. However, Jet B's lighter composition makes it more dangerous to handle. For this reason, it is rarely used, except in very cold climates. A blend of approximately 30% kerosene and 70% gasoline, it is known as wide-cut fuel. It has a very low freezing point of −60 °C (−76 °F), and a low flash point as well. It

1748-487: Is called diagenesis , a word that means a transformation of materials by dissolution and recombination of their constituents. Kerogen formation continued to a depth of about 1 km from the Earth's surface where temperatures may reach around 50 °C . Kerogen formation represents a halfway point between organic matter and fossil fuels : kerogen can be exposed to oxygen, oxidize and thus be lost, or it could be buried deeper inside

1840-717: Is considered a sticky, black, tar-like form of crude oil which is so thick and heavy that it must be heated or diluted before it will flow. Venezuela also has large amounts of oil in the Orinoco oil sands , although the hydrocarbons trapped in them are more fluid than in Canada and are usually called extra heavy oil . These oil sands resources are called unconventional oil to distinguish them from oil which can be extracted using traditional oil well methods. Between them, Canada and Venezuela contain an estimated 3.6 trillion barrels (570 × 10 ^  m ) of bitumen and extra-heavy oil, about twice

1932-476: Is considered one of the few customers of biofuels large enough to potentially bring biofuels up to the volume production needed to reduce costs. The U.S. Navy has also flown a Boeing F/A-18E/F Super Hornet dubbed the "Green Hornet" at 1.7 times the speed of sound using a biofuel blend. The Defense Advanced Research Projects Agency (DARPA) funded a $ 6.7 million project with Honeywell UOP to develop technologies to create jet fuels from biofeedstocks for use by

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2024-738: Is done after a study of the relevant structural geology , analysis of the sedimentary basin , and characterization of the petroleum reservoir . There are also unconventional reserves such as oil sands and oil shale which are recovered by other means such as fracking . Once extracted, oil is refined and separated, most easily by distillation , into innumerable products for direct use or use in manufacturing. Products include fuels such as gasoline (petrol), diesel , kerosene and jet fuel ; asphalt and lubricants ; chemical reagents used to make plastics ; solvents , textiles , refrigerants , paint , synthetic rubber , fertilizers , pesticides , pharmaceuticals , and thousands of others. Petroleum

2116-473: Is lower at the surface than underground, some of the gas will come out of solution and be recovered (or burned) as associated gas or solution gas . A gas well produces predominantly natural gas . However, because the underground temperature is higher than at the surface, the gas may contain heavier hydrocarbons such as pentane, hexane , and heptane (" natural-gas condensate ", often shortened to condensate. ) Condensate resembles gasoline in appearance and

2208-737: Is now called the Drake Well in Cherrytree Township, Pennsylvania .There also was a company associated with it, and it sparked a major oil drilling boom. The first commercial oil well in Canada became operational in 1858 at Oil Springs, Ontario (then Canada West ). Businessman James Miller Williams dug several wells between 1855 and 1858 before discovering a rich reserve of oil four metres below ground. Williams extracted 1.5 million litres of crude oil by 1860, refining much of it into kerosene lamp oil. Williams's well became commercially viable

2300-584: Is primarily used in northern Canada and Alaska , where the extreme cold makes its low freezing point necessary, and which helps mitigate the danger of its lower flash point. TS-1 is a jet fuel made to Russian standard GOST 10227 for enhanced cold-weather performance. It has somewhat higher volatility than Jet A-1 (flash point is 28 °C (82 °F) minimum). It has a very low freezing point, below −50 °C (−58 °F). The DEF STAN 91-091 (UK) and ASTM D1655 (international) specifications allow for certain additives to be added to jet fuel, including: As

2392-451: Is similar in composition to some volatile light crude oils . The hydrocarbons in crude oil are mostly alkanes , cycloalkanes and various aromatic hydrocarbons , while the other organic compounds contain nitrogen , oxygen , and sulfur , and traces of metals such as iron, nickel, copper and vanadium . Many oil reservoirs contain live bacteria. The exact molecular composition of crude oil varies widely from formation to formation but

2484-399: Is the mandatory addition of an antistatic additive to Jet A-1 fuel. Jet A and Jet A-1 fuel trucks and storage tanks, as well as plumbing that carries them, are all marked "Jet A" or "Jet A-1" in white italicized text within a black rectangle background, adjacent to one or two diagonal black stripes. Jet A-1 fuel must meet: Jet A fuel must reach ASTM specification D1655 (Jet A). Jet B

2576-569: Is therefore defined as a performance specification rather than a chemical compound. Furthermore, the range of molecular mass between hydrocarbons (or different carbon numbers) is defined by the requirements for the product, such as the freezing point or smoke point. Kerosene -type jet fuel (including Jet A and Jet A-1, JP-5, and JP-8) has a carbon number distribution between about 8 and 16 (carbon atoms per molecule); wide-cut or naphtha -type jet fuel (including Jet B and JP-4), between about 5 and 15. Fuel for piston-engine powered aircraft (usually

2668-473: Is used in manufacturing a vast variety of materials essential for modern life, and it is estimated that the world consumes about 100 million barrels (16 million cubic metres ) each day. Petroleum production played a key role in industrialization and economic development. Some countries, known as petrostates , gained significant economic and international power over their control of oil production and trade. Petroleum exploitation can be damaging to

2760-499: Is very similar to diesel fuel , and in some cases, may be used in diesel engines . The possibility of environmental legislation banning the use of leaded avgas (fuel in spark-ignited internal combustion engine, which usually contains tetraethyllead (TEL), a toxic substance added to prevent engine knocking ), and the lack of a replacement fuel with similar performance, has left aircraft designers and pilot's organizations searching for alternative engines for use in small aircraft. As

2852-670: The Earth's crust and be subjected to conditions which allow it to slowly transform into fossil fuels like petroleum. The latter happened through catagenesis in which the reactions were mostly radical rearrangements of kerogen. These reactions took thousands to millions of years and no external reactants were involved. Due to the radical nature of these reactions, kerogen reacted towards two classes of products: those with low H/C ratio ( anthracene or products similar to it) and those with high H/C ratio ( methane or products similar to it); i.e., carbon-rich or hydrogen-rich products. Because catagenesis

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2944-622: The Junkers Jumo 004 used on the Messerschmitt Me 262A fighter and the Arado Ar 234B jet recon-bomber, burned either a special synthetic "J2" fuel or diesel fuel. Gasoline was a third option but unattractive due to high fuel consumption. Other fuels used were kerosene or kerosene and gasoline mixtures. Most jet fuels in use since the end of World War II are kerosene-based. Both British and American standards for jet fuels were first established at

3036-503: The Junkers Jumo 205 family had been used during the Second World War. Jet fuel is often used in diesel-powered ground-support vehicles at airports. However, jet fuel tends to have poor lubricating ability in comparison to diesel, which increases wear in fuel injection equipment. An additive may be required to restore its lubricity . Jet fuel is more expensive than diesel fuel but the logistical advantages of using one fuel can offset

3128-484: The Orinoco Belt . While significant volumes of oil are extracted from oil sands, particularly in Canada, logistical and technical hurdles remain, as oil extraction requires large amounts of heat and water, making its net energy content quite low relative to conventional crude oil. Thus, Canada's oil sands are not expected to provide more than a few million barrels per day in the foreseeable future. Petroleum consists of

3220-780: The Soviet Union in total output. In 1973 , Saudi Arabia and other Arab nations imposed an oil embargo against the United States, United Kingdom, Japan and other Western nations which supported Israel in the Yom Kippur War of October 1973. The embargo caused an oil crisis . This was followed by the 1979 oil crisis , which was caused by a drop in oil production in the wake of the Iranian Revolution and caused oil prices to more than double. The two oil price shocks had many short- and long-term effects on global politics and

3312-533: The United States , but is responsible for only one percent of electricity generation. Petroleum's worth as a portable, dense energy source powering the vast majority of vehicles and as the base of many industrial chemicals makes it one of the world's most important commodities . The top three oil-producing countries as of 2018 are the United States, Russia , and Saudi Arabia . In 2018, due in part to developments in hydraulic fracturing and horizontal drilling ,

3404-455: The actinomycetales order of bacteria also produced antibiotic compounds (e.g., streptomycin ). Thus the action of anaerobic bacteria ceased at about 10 m below the water or sediment. The mixture at this depth contained fulvic acids, unreacted and partially reacted fats and waxes, slightly modified lignin , resins and other hydrocarbons. As more layers of organic matter settled into the sea or lake bed, intense heat and pressure built up in

3496-567: The 12th century. It has also been present in Romania since the 13th century, being recorded as păcură. Sophisticated oil pits, 4.5 to 6 metres (15 to 20 ft) deep, were dug by the Seneca people and other Iroquois in Western Pennsylvania as early as 1415–1450. The French General Louis-Joseph de Montcalm encountered Seneca using petroleum for ceremonial fires and as a healing lotion during

3588-494: The American Association of Petroleum Geologists. "The controversy is over how much they contribute to Earth's overall reserves and how much time and effort geologists should devote to seeking them out." Three conditions must be present for oil reservoirs to form: The reactions that produce oil and natural gas are often modeled as first order breakdown reactions, where hydrocarbons are broken down to oil and natural gas by

3680-643: The B-1B, B-52H, C-17, Lockheed Martin C-130J Super Hercules , McDonnell Douglas F-4 Phantom (as QF-4 target drones ), McDonnell Douglas F-15 Eagle , Lockheed Martin F-22 Raptor , and Northrop T-38 Talon to use the synthetic fuel blend. The U.S. Air Force's C-17 Globemaster III, F-16 and F-15 are certified for use of hydrotreated renewable jet fuels. The USAF plans to certify over 40 models for fuels derived from waste oils and plants by 2013. The U.S. Army

3772-455: The Earth's surface. Unusual magma intrusions, however, could have created greater localized heating. Geologists often refer to the temperature range in which oil forms as an "oil window" . Below the minimum temperature oil remains trapped in the form of kerogen. Above the maximum temperature the oil is converted to natural gas through the process of thermal cracking . Sometimes, oil formed at extreme depths may migrate and become trapped at

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3864-637: The NLC to participate in the bidding process for the acquisition of a state-owned construction company, which was a change from its original charter. The decision was made to refocus the NLC and align its activities with its statutory framework. The NLC sought to acquire international assets owned by the National Power Construction Company. As of 2011, NLC was responsible for transporting approximately 50 percent of Pakistan's imported crude oil , amounting to about 76,000 barrels per day. In 2014, NLC

3956-572: The Soviet Union included the goal to capture the Baku oilfields , as it would provide much-needed oil supplies for the German military which was suffering from blockades. Oil exploration in North America during the early 20th century later led to the U.S. becoming the leading producer by mid-century. As petroleum production in the U.S. peaked during the 1960s, the United States was surpassed by Saudi Arabia and

4048-462: The State Standard ( GOST ) number, or a Technical Condition number, with the principal grade available being TS-1. Jet A specification fuel has been used in the United States since the 1950s and is usually not available outside the United States and a few Canadian airports such as Toronto , Montreal , and Vancouver , whereas Jet A-1 is the standard specification fuel used in most of the rest of

4140-680: The United States LSD is now only available to the off-road construction, locomotive and marine markets. As more EPA regulations are introduced, more refineries are hydrotreating their jet fuel production, thus limiting the lubricating abilities of jet fuel, as determined by ASTM Standard D445. JP-8 , which is similar to Jet A-1, is used in NATO diesel vehicles as part of the single-fuel policy. Fischer–Tropsch (FT) Synthesized Paraffinic Kerosene (SPK) synthetic fuels are certified for use in United States and international aviation fleets at up to 50% in

4232-805: The United States and NATO militaries. In April 2011, four USAF F-15E Strike Eagles flew over the Philadelphia Phillies opening ceremony using a blend of traditional jet fuel and synthetic biofuels. This flyover made history as it was the first flyover to use biofuels in the Department of Defense . The air transport industry is responsible for 2–3 percent of man-made carbon dioxide emitted. Boeing estimates that biofuels could reduce flight-related greenhouse-gas emissions by 60 to 80 percent. One possible solution which has received more media coverage than others would be blending synthetic fuel derived from algae with existing jet fuel: Solazyme produced

4324-561: The United States became the world's largest producer. About 80 percent of the world's readily accessible reserves are located in the Middle East , with 62.5 percent coming from the Arab five: Saudi Arabia , United Arab Emirates , Iraq , Qatar , and Kuwait . A large portion of the world's total oil exists as unconventional sources, such as bitumen in Athabasca oil sands and extra heavy oil in

4416-481: The United States, ASTM International produces standards for civilian fuel types, and the U.S. Department of Defense produces standards for military use. The British Ministry of Defence establishes standards for both civil and military jet fuels. For reasons of inter-operational ability, British and United States military standards are harmonized to a degree. In Russia and the CIS members, grades of jet fuels are covered by

4508-609: The air at a recorded rate of 480 cubic metres (3,000 bbl) per day. By the end of the 19th century the Russian Empire, particularly the Branobel company in Azerbaijan , had taken the lead in production. Access to oil was and still is a major factor in several military conflicts of the 20th century, including World War II , during which oil facilities were a major strategic asset and were extensively bombed . The German invasion of

4600-539: The area around modern Baku , Azerbaijan . These fields were described by the Persian geographer Abu Bakr al-Razi in the 10th century, and by Marco Polo in the 13th century, who described the output of those wells as hundreds of shiploads. Arab and Persian chemists also distilled crude oil to produce flammable products for military purposes. Through Islamic Spain , distillation became available in Western Europe by

4692-420: The aviation industry's jet kerosene demands have increased to more than 5% of all refined products derived from crude, it has been necessary for the refiner to optimize the yield of jet kerosene, a high-value product, by varying process techniques. New processes have allowed flexibility in the choice of crudes, the use of coal tar sands as a source of molecules and the manufacture of synthetic blend stocks. Due to

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4784-474: The coal industry dominated the petroleum technologies. Chemist James Young in 1847 noticed a natural petroleum seepage in the coal mine at riddings Alfreton , Derbyshire from which he distilled a light thin oil suitable for use as lamp oil, at the same time obtaining a more viscous oil suitable for lubricating machinery. In 1848, Young set up a small business refining crude oil. Young eventually succeeded, by distilling cannel coal at low heat, in creating

4876-473: The detection of free water in jet fuel uses a water-sensitive filter pad that turns green if the fuel exceeds the specification limit of 30 ppm (parts per million) free water. A critical test to rate the ability of jet fuel to release emulsified water when passed through coalescing filters is ASTM standard D3948 Standard Test Method for Determining Water Separation Characteristics of Aviation Turbine Fuels by Portable Separometer. Military organizations around

4968-564: The earliest Chinese writings, cites that oil in its raw state, without refining, was first discovered, extracted, and used in China in the first century BCE. In addition, the Chinese were the first to record the use of petroleum as fuel as early as the fourth century BCE. By 347 CE, oil was produced from bamboo-drilled wells in China. In the 7th century, petroleum was among the essential ingredients for Greek fire , an incendiary projectile weapon that

5060-589: The end of World War II. British standards derived from standards for kerosene use for lamps—known as paraffin in the UK—whereas American standards derived from aviation gasoline practices. Over the subsequent years, details of specifications were adjusted, such as minimum freezing point, to balance performance requirements and availability of fuels. Very low temperature freezing points reduce the availability of fuel. Higher flash point products required for use on aircraft carriers are more expensive to produce. In

5152-469: The environment and human health. Extraction , refining and burning of petroleum fuels all release large quantities of greenhouse gases , so petroleum is one of the major contributors to climate change . Other negative environmental effects include direct releases, such as oil spills , as well as air and water pollution at almost all stages of use. These environmental effects have direct and indirect health consequences for humans. Oil has also been

5244-473: The extra expense of its use in certain circumstances. Jet fuel contains more sulfur, up to 1,000 ppm, which therefore means it has better lubricity and does not currently require a lubricity additive as all pipeline diesel fuels require. The introduction of Ultra Low Sulfur Diesel or ULSD brought with it the need for lubricity modifiers. Pipeline diesels before ULSD were able to contain up to 500 ppm of sulfur and were called Low Sulfur Diesel or LSD. In

5336-425: The fact that it happened at relatively low temperatures (when compared to commercial pyrolysis plants) of 60 to several hundred °C. Pyrolysis was possible because of the long reaction times involved. Heat for catagenesis came from the decomposition of radioactive materials of the crust, especially K , Th , U and U . The heat varied with geothermal gradient and was typically 10–30 °C per km of depth from

5428-505: The first six months of 2008, largely due to fuel costs. In 2015 ASTM approved a modification to Specification D1655 Standard Specification for Aviation Turbine Fuels to permit up to 50 ppm (50 mg/kg) of FAME ( fatty acid methyl ester ) in jet fuel to allow higher cross-contamination from biofuel production. Worldwide demand of jet fuel has been steadily increasing since 1980. Consumption more than tripled in 30 years from 1,837,000 barrels/day in 1980, to 5,220,000 in 2010. Around 30% of

5520-455: The fiscal year 1994-1995, the NLC was allocated approximately Rs 245 million by the Government of Pakistan to invest in stock markets and bonds , aimed at funding vehicle replacements and other infrastructural developments. The government was the sole financer of the NLC's infrastructure development during this period. By 2004, the NLC had evolved into a major logistics organization, boasting

5612-602: The formation of the NLC as an independent entity. Later, it was given the role of supplying military equipment to Mujahideen fighting the Soviet Union during the presidency of Muhammad Zia-ul-Haq . During this period, NLC also acquired the freight business of Pakistan Railways . In the early stages of the Afghan refugee crisis, the NLC used the Pakistan Army's transport capabilities to provide logistical support to approximately three million Afghan refugees between 1982 and 1989. In

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5704-794: The global economy. They led to sustained reductions in demand as a result of substitution to other fuels, especially coal and nuclear, and improvements in energy efficiency , facilitated by government policies. High oil prices also induced investment in oil production by non-OPEC countries, including Prudhoe Bay in Alaska, the North Sea offshore fields of the United Kingdom and Norway, the Cantarell offshore field of Mexico, and oil sands in Canada. About 90 percent of vehicular fuel needs are met by oil. Petroleum also makes up 40 percent of total energy consumption in

5796-408: The heavier end of the range, paraffin wax is an alkane with approximately 25 carbon atoms, while asphalt has 35 and up, although these are usually cracked in modern refineries into more valuable products. The lightest fraction, the so-called petroleum gases are subjected to diverse processing depending on cost. These gases are either flared off , sold as liquefied petroleum gas , or used to power

5888-638: The invention of the modern kerosene lamp (1853), the introduction of the first modern street lamp in Europe (1853), and the construction of the world's first modern oil "mine" (1854). at Bóbrka , near Krosno (still operational as of 2020). The demand for petroleum as a fuel for lighting in North America and around the world quickly grew. The first oil well in the Americas was drilled in 1859 by Edwin Drake at what

5980-446: The large number of co-eluted hydrocarbons within oil, many cannot be resolved by traditional gas chromatography. This unresolved complex mixture (UCM) of hydrocarbons is particularly apparent when analysing weathered oils and extracts from tissues of organisms exposed to oil. Crude oil varies greatly in appearance depending on its composition. It is usually black or dark brown (although it may be yellowish, reddish, or even greenish). In

6072-440: The low temperatures in the upper atmosphere . This causes precipitation of the dissolved water from the fuel. The separated water then drops to the bottom of the tank, because it is denser than the fuel. Since the water is no longer in solution, it can form droplets which can supercool to below 0 °C (32 °F). If these supercooled droplets collide with a surface they can freeze and may result in blocked fuel inlet pipes. This

6164-411: The lower regions. As a consequence, compounds of this mixture began to combine in poorly understood ways to kerogen . Combination happened in a similar fashion as phenol and formaldehyde molecules react to urea-formaldehyde resins, but kerogen formation occurred in a more complex manner due to a bigger variety of reactants. The total process of kerogen formation from the beginning of anaerobic decay

6256-899: The matter to H 2 S and N 2 respectively by using the matter as a source for other reactants. Due to such anaerobic bacteria, at first, this matter began to break apart mostly via hydrolysis : polysaccharides and proteins were hydrolyzed to simple sugars and amino acids respectively. These were further anaerobically oxidized at an accelerated rate by the enzymes of the bacteria: e.g., amino acids went through oxidative deamination to imino acids , which in turn reacted further to ammonia and α-keto acids . Monosaccharides in turn ultimately decayed to CO 2 and methane . The anaerobic decay products of amino acids, monosaccharides, phenols and aldehydes combined into fulvic acids . Fats and waxes were not extensively hydrolyzed under these mild conditions. Some phenolic compounds produced from previous reactions worked as bactericides and

6348-439: The military court of Pakistan. Crude oil Petroleum is a naturally occurring yellowish-black liquid mixture. It consists mainly of hydrocarbons , and is found in geological formations . The term petroleum refers both to naturally occurring unprocessed crude oil, as well as to petroleum products that consist of refined crude oil. Conventional reserves of petroleum are primarily recovered by drilling , which

6440-405: The number and severity of the processes used, it is often necessary and sometimes mandatory to use additives. These additives may, for example, prevent the formation of harmful chemical species or improve a property of a fuel to prevent further engine wear. It is very important that jet fuel be free from water contamination . During flight, the temperature of the fuel in the tanks decreases, due to

6532-658: The program to certify the Boeing C-17 Globemaster III and then the Rockwell B-1B Lancer to use the fuel. To test these two aircraft, the USAF has ordered 281,000 US gal (1,060,000 L) of FT fuel. The USAF intends to test and certify every airframe in its inventory to use the fuel by 2011. They will also supply over 9,000 US gal (34,000 L; 7,500 imp gal) to NASA for testing in various aircraft and engines. The USAF has certified

6624-556: The proportion of chemical elements varies over fairly narrow limits as follows: Four different types of hydrocarbon appear in crude oil. The relative percentage of each varies from oil to oil, determining the properties of each oil. The alkanes from pentane (C 5 H 12 ) to octane (C 8 H 18 ) are refined into gasoline, the ones from nonane (C 9 H 20 ) to hexadecane (C 16 H 34 ) into diesel fuel , kerosene and jet fuel . Alkanes with more than 16 carbon atoms can be refined into fuel oil and lubricating oil . At

6716-644: The refinery's own burners. During the winter, butane (C 4 H 10 ), is blended into the gasoline pool at high rates, because its high vapour pressure assists with cold starts. The aromatic hydrocarbons are unsaturated hydrocarbons that have one or more benzene rings . They tend to burn with a sooty flame, and many have a sweet aroma. Some are carcinogenic . These different components are separated by fractional distillation at an oil refinery to produce gasoline, jet fuel, kerosene, and other hydrocarbon fractions. The components in an oil sample can be determined by gas chromatography and mass spectrometry . Due to

6808-412: The reservoir it is usually found in association with natural gas, which being lighter forms a "gas cap" over the petroleum, and saline water which, being heavier than most forms of crude oil, generally sinks beneath it. Crude oil may also be found in a semi-solid form mixed with sand and water, as in the Athabasca oil sands in Canada, where it is usually referred to as crude bitumen . In Canada, bitumen

6900-509: The same time the world's first, small, oil refinery was opened at Jasło in Poland (then Austria), with a larger one opened at Ploiești in Romania shortly after. Romania (then being a vassal of the Ottoman empire) is the first country in the world to have had its annual crude oil output officially recorded in international statistics: 275 tonnes for 1857. In 1858, Georg Christian Konrad Hunäus found

6992-518: The second half of the 19th century, the term became commonly known for the liquid form of hydrocarbons. Petroleum, in one form or another, has been used since ancient times. More than 4300 years ago, bitumen was mentioned when the Sumerians used it to make boats. A tablet of the legend of the birth of Sargon of Akkad mentions a basket which was closed by straw and bitumen. More than 4000 years ago, according to Herodotus and Diodorus Siculus , asphalt

7084-481: The six-hour flight from London to Doha came from Shell's GTL plant in Bintulu , Malaysia . The world's first passenger aircraft flight to use only synthetic jet fuel was from Lanseria International Airport to Cape Town International Airport on September 22, 2010. The fuel was developed by Sasol . Chemist Heather Willauer is leading a team of researchers at the U.S. Naval Research Laboratory who are developing

7176-408: The term stems from monasteries in southern Italy where it was in use by the end of the first millennium as an alternative for the older term " naphtha ". After that, the term was used in numerous manuscripts and books, such as in the treatise De Natura Fossilium , published in 1546 by the German mineralogist Georg Bauer , also known as Georgius Agricola. After the advent of the oil industry, during

7268-565: The test program. This program is part of the Department of Defense Assured Fuel Initiative, an effort to develop secure domestic sources for the military energy needs. The Pentagon hopes to reduce its use of crude oil from foreign producers and obtain about half of its aviation fuel from alternative sources by 2016. With the B-52 now approved to use the FT blend, the USAF will use the test protocols developed during

7360-528: The title of E.W. Binney & Co. at Bathgate in West Lothian and E. Meldrum & Co. at Glasgow; their works at Bathgate were completed in 1851 and became the first truly commercial oil-works in the world with the first modern oil refinery. The world's first oil refinery was built in 1856 by Ignacy Łukasiewicz in Austria. His achievements also included the discovery of how to distill kerosene from seep oil,

7452-468: The volume of the world's reserves of conventional oil. Petroleum is a fossil fuel derived from fossilized organic materials , such as zooplankton and algae . Vast amounts of these remains settled to sea or lake bottoms where they were covered in stagnant water (water with no dissolved oxygen ) or sediments such as mud and silt faster than they could decompose aerobically . Approximately 1 m below this sediment, water oxygen concentration

7544-405: The world use a different classification system of JP (for "Jet Propellant") numbers. Some are almost identical to their civilian counterparts and differ only by the amounts of a few additives; Jet A-1 is similar to JP-8 , Jet B is similar to JP-4 . Other military fuels are highly specialized products and are developed for very specific applications. Jet fuel

7636-443: The world's first 100 percent algae-derived jet fuel, Solajet, for both commercial and military applications. Oil prices increased about fivefold from 2003 to 2008, raising fears that world petroleum production is becoming unable to keep up with demand . The fact that there are few alternatives to petroleum for aviation fuel adds urgency to the search for alternatives . Twenty-five airlines were bankrupted or stopped operations in

7728-452: The world's first scheduled passenger flight flew with some synthetic kerosene from a non-fossil fuel source. 500 liters of synthetic kerosene was mixed with regular jet fuel. Synthetic kerosene was produced by Shell and the flight was operated by KLM. On August 8, 2007, Air Force Secretary Michael Wynne certified the B-52H as fully approved to use the FT blend, marking the formal conclusion of

7820-414: The world, the main exceptions being Russia and the CIS members, where TS-1 fuel type is the most common standard. Both Jet A and Jet A-1 have a flash point higher than 38 °C (100 °F), with an autoignition temperature of 210 °C (410 °F). The differences between Jet A and Jet A-1 are twofold. The primary difference is the lower freezing point of Jet A-1 fuel: The other difference

7912-612: Was activity in various parts of the world in the mid-19th century. A group directed by Major Alexeyev of the Bakinskii Corps of Mining Engineers hand-drilled a well in the Baku region of Bibi-Heybat in 1846. There were engine-drilled wells in West Virginia in the same year as Drake's well. An early commercial well was hand dug in Poland in 1853, and another in nearby Romania in 1857. At around

8004-499: Was awarded the contract to construct the Rawalpindi section of Rawalpindi-Islamabad Metrobus at 1.04 per cent higher than the estimated cost. In 2010, a corruption scandal was unearthed that involved two Pakistan Army generals, (Maj Gen Khalid Zaheer Akhtar and Lt Gen Muhammad Afzal), and caused a loss of Rs. 1.8 billion to the company through speculative investments between 2004 and 2008. In 2015, both of them were convicted by

8096-414: Was closed off from external reactants, the resulting composition of the fuel mixture was dependent on the composition of the kerogen via reaction stoichiometry . Three types of kerogen exist: type I (algal), II (liptinic) and III (humic), which were formed mainly from algae , plankton and woody plants (this term includes trees , shrubs and lianas ) respectively. Catagenesis was pyrolytic despite

8188-423: Was low, below 0.1 mg/L, and anoxic conditions existed. Temperatures also remained constant. As further layers settled into the sea or lake bed, intense heat and pressure built up in the lower regions. This process caused the organic matter to change, first into a waxy material known as kerogen , found in various oil shales around the world, and then with more heat into liquid and gaseous hydrocarbons via

8280-495: Was the cause of the British Airways Flight 38 accident. Removing all water from fuel is impractical; therefore, fuel heaters are usually used on commercial aircraft to prevent water in fuel from freezing. There are several methods for detecting water in jet fuel. A visual check may detect high concentrations of suspended water, as this will cause the fuel to become hazy in appearance. An industry standard chemical test for

8372-475: Was used by Byzantine Greeks against Arab ships, which were then attacking Constantinople . Crude oil was also distilled by Persian chemists , with clear descriptions given in Arabic handbooks such as those of Abu Bakr al-Razi (Rhazes). The streets of Baghdad were paved with tar , derived from petroleum that became accessible from natural fields in the region. In the 9th century, oil fields were exploited in

8464-539: Was used in the construction of the walls and towers of Babylon ; there were oil pits near Ardericca and Babylon, and a pitch spring on Zakynthos . Great quantities of it were found on the banks of the river Issus , one of the tributaries of the Euphrates . Ancient Persian tablets indicate the medicinal and lighting uses of petroleum in the upper levels of their society. The use of petroleum in ancient China dates back to more than 2000 years ago. The I Ching , one of

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