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57-443: The Mazatzal Group consists mostly of fine-grained light-brown to gray quartzite which often shows cross-bedding ; metaconglomerate containing clasts up to 15 centimeters (6 in) or more in size; and occasional lenses, up to 46 meters (150 ft) in thickness, of maroon to gray argillite showing ripple marks and mudcracks . The lower beds of the group are intruded by rhyolite domes and sills . The total thickness of

114-431: A compound of several minerals and as a synthetic product. Examples include fused quartz , fumed silica , opal , and aerogels . It is used in structural materials , microelectronics , and as components in the food and pharmaceutical industries. All forms are white or colorless, although impure samples can be colored. Silicon dioxide is a common fundamental constituent of glass . In the majority of silicon dioxides,

171-407: A glass with no true melting point, can be used as a glass fibre for fibreglass. Silicon dioxide is mostly obtained by mining, including sand mining and purification of quartz . Quartz is suitable for many purposes, while chemical processing is required to make a purer or otherwise more suitable (e.g. more reactive or fine-grained) product. Precipitated silica or amorphous silica is produced by

228-494: A heat capacity minimum. Its density decreases from 2.08 g/cm at 1950 °C to 2.03 g/cm at 2200 °C. The molecular SiO 2 has a linear structure like CO 2 . It has been produced by combining silicon monoxide (SiO) with oxygen in an argon matrix. The dimeric silicon dioxide, (SiO 2 ) 2 has been obtained by reacting O 2 with matrix isolated dimeric silicon monoxide, (Si 2 O 2 ). In dimeric silicon dioxide there are two oxygen atoms bridging between

285-450: A low value of 140° in α-tridymite, up to 180° in β-tridymite. In α-quartz, the Si–O–Si angle is 144°. Alpha quartz is the most stable form of solid SiO 2 at room temperature. The high-temperature minerals, cristobalite and tridymite, have both lower densities and indices of refraction than quartz. The transformation from α-quartz to beta-quartz takes place abruptly at 573 °C. Since

342-410: A silicon wafer enables it to overcome the surface states that otherwise prevent electricity from reaching the semiconducting layer. The process of silicon surface passivation by thermal oxidation (silicon dioxide) is critical to the semiconductor industry . It is commonly used to manufacture metal–oxide–semiconductor field-effect transistors (MOSFETs) and silicon integrated circuit chips (with

399-477: A very shallow layer of about 1 nm or 10 Å of so-called native oxide. Higher temperatures and alternative environments are used to grow well-controlled layers of silicon dioxide on silicon, for example at temperatures between 600 and 1200 °C, using so-called dry oxidation with O 2 or wet oxidation with H 2 O. The native oxide layer is beneficial in microelectronics , where it acts as electric insulator with high chemical stability. It can protect

456-996: A very thin layer of Irish Atlantic Bog covering it. In the United Kingdom, a craggy ridge of quartzite called the Stiperstones (early Ordovician – Arenig Epoch , 500 Ma) runs parallel with the Pontesford-Linley fault , 6 km north-west of the Long Mynd in south Shropshire . Also to be found in England are the Cambrian " Wrekin quartzite" (in Shropshire), and the Cambrian " Hartshill quartzite" ( Nuneaton area). In Wales , Holyhead Mountain and most of Holy island off Anglesey sport excellent Precambrian quartzite crags and cliffs. In

513-524: A white powder with extremely low bulk density (0.03-0.15 g/cm ) and thus high surface area. The particles act as a thixotropic thickening agent, or as an anti-caking agent, and can be treated to make them hydrophilic or hydrophobic for either water or organic liquid applications. Silica fume is an ultrafine powder collected as a by-product of the silicon and ferrosilicon alloy production. It consists of amorphous (non-crystalline) spherical particles with an average particle diameter of 150 nm, without

570-401: Is a form of silica, it is a possible cause for concern in various workplaces. Cutting, grinding, chipping, sanding, drilling, and polishing natural and manufactured stone products can release hazardous levels of very small, crystalline silica dust particles into the air that workers breathe. Crystalline silica of respirable size is a recognized human carcinogen and may lead to other diseases of

627-479: Is also sometimes used for very hard but unmetamorphosed sandstones that are composed of quartz grains thoroughly cemented with additional quartz. Such sedimentary rock has come to be described as orthoquartzite to distinguish it from metamorphic quartzite, which is sometimes called metaquartzite to emphasize its metamorphic origins. Quartzite is very resistant to chemical weathering and often forms ridges and resistant hilltops. The nearly pure silica content of

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684-439: Is also the primary component of rice husk ash , which is used, for example, in filtration and as supplementary cementitious material (SCM) in cement and concrete manufacturing. Silicification in and by cells has been common in the biological world and it occurs in bacteria, protists, plants, and animals (invertebrates and vertebrates). Prominent examples include: About 95% of the commercial use of silicon dioxide (sand)

741-465: Is in the construction industry, e.g. in the production of concrete ( Portland cement concrete ). Certain deposits of silica sand, with desirable particle size and shape and desirable clay and other mineral content, were important for sand casting of metallic products. The high melting point of silica enables it to be used in such applications such as iron casting; modern sand casting sometimes uses other minerals for other reasons. Crystalline silica

798-651: Is obtained by the dealumination of a low-sodium, ultra-stable Y zeolite with combined acid and thermal treatment. The resulting product contains over 99% silica, and has high crystallinity and specific surface area (over 800 m /g). Faujasite-silica has very high thermal and acid stability. For example, it maintains a high degree of long-range molecular order or crystallinity even after boiling in concentrated hydrochloric acid . Molten silica exhibits several peculiar physical characteristics that are similar to those observed in liquid water : negative temperature expansion, density maximum at temperatures ~5000 °C, and

855-498: Is presently used for decorative dimension stone, as crushed stone in highway construction, and as a source of silica for production of silicon and silicon compounds. Quartzite is a very hard rock composed predominantly of an interlocking mosaic of quartz crystals. The grainy, sandpaper-like surface is glassy in appearance. Minor amounts of former cementing materials, iron oxide, silica, carbonate and clay, often migrate during recrystallization, causing streaks and lenses to form within

912-656: Is puzzling for sediments which must have eroded from igneous rock. Their purity may reflect unusual conditions of chemical weathering, at a time when the Earth's atmosphere was beginning to be oxygenated. In Ireland areas of quartzite are found across the west and northwest, with Errigal in County Donegal as the most prominent outcrop. A good example of a quartzite area is on the Corraun Peninsula in County Mayo , which has

969-421: Is rapidly cooled, it does not crystallize, but solidifies as a glass. Because of this, most ceramic glazes have silica as the main ingredient. The structural geometry of silicon and oxygen in glass is similar to that in quartz and most other crystalline forms of silicon and oxygen, with silicon surrounded by regular tetrahedra of oxygen centres. The difference between the glass and crystalline forms arises from

1026-458: Is sometimes used in road construction. High purity quartzite is used to produce ferrosilicon , industrial silica sand, silicon and silicon carbide . During the Paleolithic , quartzite was used, along with flint , quartz , and other lithic raw materials, for making stone tools . Prehistoric humans in the southeastern United States often made mortars out of quartzite stones. As quartzite

1083-426: Is the major constituent of sand . Even though it is poorly soluble, silica occurs in many plants such as rice . Plant materials with high silica phytolith content appear to be of importance to grazing animals, from chewing insects to ungulates . Silica accelerates tooth wear, and high levels of silica in plants frequently eaten by herbivores may have developed as a defense mechanism against predation. Silica

1140-405: Is the only polymorph of silica stable at the Earth's surface. Metastable occurrences of the high-pressure forms coesite and stishovite have been found around impact structures and associated with eclogites formed during ultra-high-pressure metamorphism . The high-temperature forms of tridymite and cristobalite are known from silica-rich volcanic rocks . In many parts of the world, silica

1197-504: Is the process by which a semiconductor surface is rendered inert, and does not change semiconductor properties as a result of interaction with air or other materials in contact with the surface or edge of the crystal. The formation of a thermally grown silicon dioxide layer greatly reduces the concentration of electronic states at the silicon surface . SiO 2 films preserve the electrical characteristics of p–n junctions and prevent these electrical characteristics from deteriorating by

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1254-567: Is up to 400 meters (1,300 ft) thick and is mostly extremely pure quartzite with a few pelite layers. The unit was first described by E.D. Wilson in 1922 as the Mazatzal Quartzite. It was raised to group rank in 1981 by P. Anderson and W.R. Wirth. The group was assigned to the Tonto Basin Supergroup in 1988 by Karl Karlstrom and Samuel Bowring. Quartzite Quartzite is a hard, non- foliated metamorphic rock which

1311-436: Is used as a fining agent for wine, beer, and juice, with the E number reference E551 . In cosmetics, silica is useful for its light-diffusing properties and natural absorbency. Diatomaceous earth , a mined product, has been used in food and cosmetics for centuries. It consists of the silica shells of microscopic diatoms ; in a less processed form it was sold as "tooth powder". Manufactured or mined hydrated silica

1368-489: Is used as the hard abrasive in toothpaste . Silicon dioxide is widely used in the semiconductor technology: Because silicon dioxide is a native oxide of silicon it is more widely used compared to other semiconductors like gallium arsenide or indium phosphide . Silicon dioxide could be grown on a silicon semiconductor surface. Silicon oxide layers could protect silicon surfaces during diffusion processes , and could be used for diffusion masking. Surface passivation

1425-418: Is used in hydraulic fracturing of formations which contain tight oil and shale gas . Silica is the primary ingredient in the production of most glass . As other minerals are melted with silica, the principle of freezing point depression lowers the melting point of the mixture and increases fluidity. The glass transition temperature of pure SiO 2 is about 1475 K. When molten silicon dioxide SiO 2

1482-538: Is used to produce elemental silicon . The process involves carbothermic reduction in an electric arc furnace : Fumed silica , also known as pyrogenic silica, is prepared by burning SiCl 4 in an oxygen-rich hydrogen flame to produce a "smoke" of SiO 2 . It can also be produced by vaporizing quartz sand in a 3000 °C electric arc. Both processes result in microscopic droplets of amorphous silica fused into branched, chainlike, three-dimensional secondary particles which then agglomerate into tertiary particles,

1539-811: The Mazatzal orogeny , a mountain-building event that took place between 1695 and 1630 Mya. In the northern Mazatzal Mountains, the Mazatzal Group is divided (in ascending stratigraphic order) into the Deadman Quartzite , the Maverick Shale , and the Mazatzal Peak Quartzite . In the upper Salt River Canyon, the Mazatzal Group is represented by the White Ledges Formation . In the Four Peaks area,

1596-501: The Precambrian basement rock of western North America. The quartzites in these successions are interpreted as sedimentary beds deposited atop older greenstone belts . The quartzite-rhyolite successions may record the formation of back-arc basins along the margin of Laurentia , the ancient core of North America, between episodes of mountain building during the assembly of the continent. The quartzites are often nearly pure quartz, which

1653-597: The Scottish Highlands , several mountains (e.g. Foinaven , Arkle ) composed of Cambrian quartzite can be found in the far north-west Moine Thrust Belt running in a narrow band from Loch Eriboll in a south-westerly direction to Skye . In continental Europe , various regionally isolated quartzite deposits exist at surface level in a belt from the Rhenish Massif and the German Central Highlands into

1710-401: The double bond rule . Based on the crystal structural differences, silicon dioxide can be divided into two categories: crystalline and non-crystalline (amorphous). In crystalline form, this substance can be found naturally occurring as quartz , tridymite (high-temperature form), cristobalite (high-temperature form), stishovite (high-pressure form), and coesite (high-pressure form). On

1767-550: The planar process ). Hydrophobic silica is used as a defoamer component . In its capacity as a refractory , it is useful in fiber form as a high-temperature thermal protection fabric. Silica is used in the extraction of DNA and RNA due to its ability to bind to the nucleic acids under the presence of chaotropes . Silica aerogel was used in the Stardust spacecraft to collect extraterrestrial particles. Pure silica (silicon dioxide), when cooled as fused quartz into

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1824-503: The Mazatzal Group is divided (in ascending stratigraphic order) into an informal lower quartzite, an informal lower pelite, and the Four Peaks Quartzite . These are interpreted as a single sequence of sediment deposition. The lower quartzite is an extremely pure quartzite up to 60 meters (200 ft) thick. The lower pelite is about 450 meters (1,480 ft) thick and consists of pelite and psammite beds. The Four Peaks Quartzite

1881-864: The Morenci Copper Mine in Arizona . The town of Quartzsite in western Arizona derives its name from the quartzites in the nearby mountains in both Arizona and Southeastern California. A glassy vitreous quartzite has been described from the Belt Supergroup in the Coeur d’Alene district of northern Idaho . In Canada, the La Cloche Mountains in Ontario are composed primarily of white quartzite. Vast areas of Nova Scotia are underlain by quartzite. Paleoproterozoic quartzite- rhyolite successions are common in

1938-773: The United States, formations of quartzite can be found in some parts of Pennsylvania, the Washington DC area, eastern South Dakota , Central Texas, southwest Minnesota , Devil's Lake State Park in the Baraboo Range in Wisconsin , the Wasatch Range in Utah , near Salt Lake City, Utah and as resistant ridges in the Appalachians and other mountain regions. Quartzite is also found in

1995-870: The Western Czech Republic , for example in the Taunus and Harz mountains. In Poland, quartzite deposits at surface level exists in Świętokrzyskie Mountains . In Norway, deposits are quarried near Austertana , which is one of the largest quarries in the world at 850,000 tonnes (840,000 long tons; 940,000 short tons) annually, and Mårnes near Sandhornøya with an output of 150,000 tonnes (150,000 long tons; 170,000 short tons) annually. Deposits are also quarried in Kragerø Municipality , and several other deposits are known but not actively quarried. The highest mountain in Mozambique , Monte Binga (2436 m), as well as

2052-496: The acidification of solutions of sodium silicate . The gelatinous precipitate or silica gel , is first washed and then dehydrated to produce colorless microporous silica. The idealized equation involving a trisilicate and sulfuric acid is: Approximately one billion kilograms/year (1999) of silica were produced in this manner, mainly for use for polymer composites – tires and shoe soles. Thin films of silica grow spontaneously on silicon wafers via thermal oxidation , producing

2109-552: The branching of the pyrogenic product. The main use is as pozzolanic material for high performance concrete. Fumed silica nanoparticles can be successfully used as an anti-aging agent in asphalt binders. Silica, either colloidal, precipitated, or pyrogenic fumed, is a common additive in food production. It is used primarily as a flow or anti- caking agent in powdered foods such as spices and non-dairy coffee creamer, or powders to be formed into pharmaceutical tablets. It can adsorb water in hygroscopic applications. Colloidal silica

2166-506: The connectivity of the tetrahedral units: Although there is no long-range periodicity in the glassy network, ordering remains at length scales well beyond the SiO bond length. One example of this ordering is the preference to form rings of 6-tetrahedra. The majority of optical fibers for telecommunications are also made from silica. It is a primary raw material for many ceramics such as earthenware , stoneware , and porcelain . Silicon dioxide

2223-488: The densest of the low-pressure forms, which has a density of 2.648 g/cm . The difference in density can be ascribed to the increase in coordination as the six shortest Si–O bond lengths in stishovite (four Si–O bond lengths of 176 pm and two others of 181 pm) are greater than the Si–O bond length (161 pm) in α-quartz. The change in the coordination increases the ionicity of the Si–O bond. Faujasite silica, another polymorph,

2280-411: The gaseous ambient environment. Silicon oxide layers could be used to electrically stabilize silicon surfaces. The surface passivation process is an important method of semiconductor device fabrication that involves coating a silicon wafer with an insulating layer of silicon oxide so that electricity could reliably penetrate to the conducting silicon below. Growing a layer of silicon dioxide on top of

2337-401: The grains to form an irregular or conchoidal fracture. Geologists had recognized by 1941 that some rocks show the macroscopic characteristics of quartzite, even though they have not undergone metamorphism at high pressure and temperature. These rocks have been subject only to the much lower temperatures and pressures associated with diagenesis of sedimentary rock, but diagenesis has cemented

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2394-680: The group is up to 2,000 meters (6,600 ft). The group lies disconformably on top of the Red Rock Rhyolite and is in turn overlain by the Hopi Springs Shale . The group crops out in the Mazatzal Mountains, where it has been strongly deformed (with up to 50% shortening to the northwest) and in the Prescott area, where it has been only mildly metamorphosed . It is also present in the upper Salt River canyon. The group gives its name to

2451-447: The lungs such as silicosis and pulmonary fibrosis . The term quartzite is derived from German : Quarzit . Silica Silicon dioxide , also known as silica , is an oxide of silicon with the chemical formula SiO 2 , commonly found in nature as quartz . In many parts of the world, silica is the major constituent of sand . Silica is one of the most complex and abundant families of materials , existing as

2508-479: The original texture and sedimentary structures are preserved. The typical distinction between a true orthoquartzite and an ordinary quartz sandstone is that an orthoquartzite is so highly cemented that it will fracture across grains, not around them. This is a distinction that can be recognized in the field . In turn, the distinction between an orthoquartzite and a metaquartzite is the onset of recrystallization of existing grains. The dividing line may be placed at

2565-418: The original texture and sedimentary structures of the sandstone are erased by the metamorphism. The recrystallized quartz grains are roughly equal in size, forming what is called a granoblastic texture, and they also show signs of metamorphic annealing, in which the grains become coarser and acquire a more polygonal texture. The grains are so tightly interlocked that when the rock is broken, it fractures through

2622-400: The other hand, amorphous silica can be found in nature as opal and diatomaceous earth . Quartz glass is a form of intermediate state between these structures. All of these distinct crystalline forms always have the same local structure around Si and O. In α-quartz the Si–O bond length is 161 pm, whereas in α-tridymite it is in the range 154–171 pm. The Si–O–Si angle also varies between

2679-487: The point where strained quartz grains begin to be replaced by new, unstrained, small quartz grains, producing a mortar texture that can be identified in thin sections under a polarizing microscope. With increasing grade of metamorphism, further recrystallization produces foam texture , characterized by polygonal grains meeting at triple junctions, and then porphyroblastic texture , characterized by coarse, irregular grains, including some larger grains ( porphyroblasts ). In

2736-473: The quartzite. To be classified as a quartzite by the British Geological Survey , a metamorphic rock must contain at least 80% quartz by volume. Quartzite is commonly regarded as metamorphic in origin. When sandstone is subjected to the great heat and pressure associated with regional metamorphism, the individual quartz grains recrystallize along with the former cementing material. Most or all of

2793-468: The rest of the surrounding Chimanimani Plateau are composed of very hard, pale grey, Precambrian quartzite. Quartzite is also mined in Brazil for use in kitchen countertops. Quartzite is a decorative stone and may be used to cover walls, as roofing tiles, as flooring, and stairsteps. Its use for countertops in kitchens is expanding rapidly. It is harder and more resistant to stains than granite. Crushed quartzite

2850-422: The rock provides little material for soil ; therefore, the quartzite ridges are often bare or covered only with a very thin layer of soil and little (if any) vegetation. Some quartzites contain just enough weather-susceptible nutrient-bearing minerals such as carbonates and chlorite to form a loamy, fairly fertile though shallow and stony soil. Quartzite has been used since prehistoric times for stone tools. It

2907-573: The rock so thoroughly that microscopic examination is necessary to distinguish it from metamorphic quartize. The term orthoquartzite is used to distinguish such sedimentary rock from metaquartzite produced by metamorphism. By extension, the term orthoquartzite has occasionally been more generally applied to any quartz-cemented quartz arenite . Orthoquartzite (in the narrow sense) is often 99% SiO 2 with only very minor amounts of iron oxide and trace resistant minerals such as zircon , rutile and magnetite . Although few fossils are normally present,

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2964-406: The silicon atom shows tetrahedral coordination , with four oxygen atoms surrounding a central Si atom ( see 3-D Unit Cell ). Thus, SiO 2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO 2 is a linear molecule. The starkly different structures of the dioxides of carbon and silicon are a manifestation of

3021-401: The silicon atoms with an Si–O–Si angle of 94° and bond length of 164.6 pm and the terminal Si–O bond length is 150.2 pm. The Si–O bond length is 148.3 pm, which compares with the length of 161 pm in α-quartz. The bond energy is estimated at 621.7 kJ/mol. SiO 2 is most commonly encountered in nature as quartz , which comprises more than 10% by mass of the Earth's crust. Quartz

3078-418: The silicon, store charge, block current, and even act as a controlled pathway to limit current flow. Many routes to silicon dioxide start with an organosilicon compound, e.g., HMDSO, TEOS. Synthesis of silica is illustrated below using tetraethyl orthosilicate (TEOS). Simply heating TEOS at 680–730 °C results in the oxide: Similarly TEOS combusts around 400 °C: TEOS undergoes hydrolysis via

3135-492: The so-called sol-gel process . The course of the reaction and nature of the product are affected by catalysts, but the idealized equation is: Being highly stable, silicon dioxide arises from many methods. Conceptually simple, but of little practical value, combustion of silane gives silicon dioxide. This reaction is analogous to the combustion of methane: However the chemical vapor deposition of silicon dioxide onto crystal surface from silane had been used using nitrogen as

3192-446: The transformation is accompanied by a significant change in volume, it can easily induce fracturing of ceramics or rocks passing through this temperature limit. The high-pressure minerals, seifertite , stishovite, and coesite, though, have higher densities and indices of refraction than quartz. Stishovite has a rutile -like structure where silicon is 6-coordinate. The density of stishovite is 4.287 g/cm , which compares to α-quartz,

3249-424: Was originally pure quartz sandstone . Sandstone is converted into quartzite through heating and pressure usually related to tectonic compression within orogenic belts . Pure quartzite is usually white to grey, though quartzites often occur in various shades of pink and red due to varying amounts of hematite . Other colors, such as yellow, green, blue and orange, are due to other minerals. The term quartzite

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