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94-439: Cams and saddles are available in several different types, including brass and stainless steel. Stainless steel models were introduced in 1985. Aluminium cams were announced in 2004 and released in 2005. The 2310 , their current OEM model, is the only tremolo to offer the aluminum cam - though parts are interchangeable - and offers brass rollers. Steel rollers can also be used. The 2500 and 2520 (the former having steel rollers;

188-491: A precipitate of aluminium hydroxide , Al(OH) 3 , forms. This is useful for clarification of water, as the precipitate nucleates on suspended particles in the water, hence removing them. Increasing the pH even further leads to the hydroxide dissolving again as aluminate , [Al(H 2 O) 2 (OH) 4 ] , is formed. Aluminium hydroxide forms both salts and aluminates and dissolves in acid and alkali, as well as on fusion with acidic and basic oxides. This behavior of Al(OH) 3

282-515: A "less classical sound". This name persisted: although the -um spelling was occasionally used in Britain, the American scientific language used -ium from the start. Most scientists throughout the world used -ium in the 19th century; and it was entrenched in several other European languages, such as French , German , and Dutch . In 1828, an American lexicographer, Noah Webster , entered only

376-494: A Kahler product line having interchangeable parts and bearing numerous improvements in fulcrum vibrato technology. The "Steeler", "Killer", and "Spyder" vibratos included Floyd Rose patent technology licensed by Kahler. Today, Kahler no longer produces fulcrum-based tremolos. Neal Moser offers Kahler bridges on many models, and the Jackson and ESP Custom Shops currently offer Kahlers as a custom option. ESP and B.C. Rich also offer

470-492: A Swedish chemist, Jöns Jacob Berzelius , in which the name aluminium is given to the element that would be synthesized from alum. (Another article in the same journal issue also refers to the metal whose oxide is the basis of sapphire , i.e. the same metal, as to aluminium .) A January 1811 summary of one of Davy's lectures at the Royal Society mentioned the name aluminium as a possibility. The next year, Davy published

564-546: A chemistry textbook in which he used the spelling aluminum . Both spellings have coexisted since. Their usage is currently regional: aluminum dominates in the United States and Canada; aluminium is prevalent in the rest of the English-speaking world. In 1812, British scientist Thomas Young wrote an anonymous review of Davy's book, in which he proposed the name aluminium instead of aluminum , which he thought had

658-407: A disk of dust and gas orbiting the newly formed Sun. It formed via accretion, where planetesimals and other smaller rocky bodies collided and stuck, gradually growing into a planet. This process generated an enormous amount of heat, which caused early Earth to melt completely. As planetary accretion slowed, Earth began to cool, forming its first crust, called a primary or primordial crust. This crust

752-479: A great affinity towards oxygen , forming a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver , both in its color and in its great ability to reflect light. It is soft, nonmagnetic , and ductile . It has one stable isotope, Al, which is highly abundant, making aluminium the twelfth-most common element in the universe. The radioactivity of Al leads to it being used in radiometric dating . Chemically, aluminium

846-441: A probable cause for it being soft with a low melting point and low electrical resistivity . Aluminium metal has an appearance ranging from silvery white to dull gray depending on its surface roughness . Aluminium mirrors are the most reflective of all metal mirrors for near ultraviolet and far infrared light. It is also one of the most reflective for light in the visible spectrum, nearly on par with silver in this respect, and

940-683: A process termed passivation . Because of its general resistance to corrosion, aluminium is one of the few metals that retains silvery reflectance in finely powdered form, making it an important component of silver-colored paints. Aluminium is not attacked by oxidizing acids because of its passivation. This allows aluminium to be used to store reagents such as nitric acid , concentrated sulfuric acid , and some organic acids. In hot concentrated hydrochloric acid , aluminium reacts with water with evolution of hydrogen, and in aqueous sodium hydroxide or potassium hydroxide at room temperature to form aluminates —protective passivation under these conditions

1034-525: A refractory material, and in ceramics , as well as being the starting material for the electrolytic production of aluminium. Sapphire and ruby are impure corundum contaminated with trace amounts of other metals. The two main oxide-hydroxides, AlO(OH), are boehmite and diaspore . There are three main trihydroxides: bayerite , gibbsite , and nordstrandite , which differ in their crystalline structure ( polymorphs ). Many other intermediate and related structures are also known. Most are produced from ores by

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1128-474: A stable noble gas configuration. Accordingly, the combined first three ionization energies of aluminium are far lower than the fourth ionization energy alone. Such an electron configuration is shared with the other well-characterized members of its group, boron , gallium , indium , and thallium ; it is also expected for nihonium . Aluminium can surrender its three outermost electrons in many chemical reactions (see below ). The electronegativity of aluminium

1222-815: A variety of wet processes using acid and base. Heating the hydroxides leads to formation of corundum. These materials are of central importance to the production of aluminium and are themselves extremely useful. Some mixed oxide phases are also very useful, such as spinel (MgAl 2 O 4 ), Na-β-alumina (NaAl 11 O 17 ), and tricalcium aluminate (Ca 3 Al 2 O 6 , an important mineral phase in Portland cement ). The only stable chalcogenides under normal conditions are aluminium sulfide (Al 2 S 3 ), selenide (Al 2 Se 3 ), and telluride (Al 2 Te 3 ). All three are prepared by direct reaction of their elements at about 1,000 °C (1,800 °F) and quickly hydrolyze completely in water to yield aluminium hydroxide and

1316-567: A way of purifying bauxite to yield alumina, now known as the Bayer process , in 1889. Modern production of aluminium is based on the Bayer and Hall–Héroult processes. As large-scale production caused aluminium prices to drop, the metal became widely used in jewelry, eyeglass frames, optical instruments, tableware, and foil , and other everyday items in the 1890s and early 20th century. Aluminium's ability to form hard yet light alloys with other metals provided

1410-728: Is Al : while it was present along with stable Al in the interstellar medium from which the Solar System formed, having been produced by stellar nucleosynthesis as well, its half-life is only 717,000 years and therefore a detectable amount has not survived since the formation of the planet. However, minute traces of Al are produced from argon in the atmosphere by spallation caused by cosmic ray protons. The ratio of Al to Be has been used for radiodating of geological processes over 10 to 10  year time scales, in particular transport, deposition, sediment storage, burial times, and erosion. Most meteorite scientists believe that

1504-434: Is Al. Al was present in the early Solar System with abundance of 0.005% relative to Al but its half-life of 728,000 years is too short for any original nuclei to survive; Al is therefore extinct . Unlike for Al, hydrogen burning is the primary source of Al, with the nuclide emerging after a nucleus of Mg catches a free proton. However, the trace quantities of Al that do exist are the most common gamma ray emitter in

1598-407: Is paramagnetic and thus essentially unaffected by static magnetic fields. The high electrical conductivity, however, means that it is strongly affected by alternating magnetic fields through the induction of eddy currents . Aluminium combines characteristics of pre- and post-transition metals. Since it has few available electrons for metallic bonding, like its heavier group 13 congeners, it has

1692-483: Is 1.61 (Pauling scale). A free aluminium atom has a radius of 143  pm . With the three outermost electrons removed, the radius shrinks to 39 pm for a 4-coordinated atom or 53.5 pm for a 6-coordinated atom. At standard temperature and pressure , aluminium atoms (when not affected by atoms of other elements) form a face-centered cubic crystal system bound by metallic bonding provided by atoms' outermost electrons; hence aluminium (at these conditions)

1786-435: Is 2.835 g/cm , with density increasing with depth from an average of 2.66 g/cm in the uppermost crust to 3.1 g/cm at the base of the crust. In contrast to the continental crust, the oceanic crust is composed predominantly of pillow lava and sheeted dikes with the composition of mid-ocean ridge basalt, with a thin upper layer of sediments and a lower layer of gabbro . Earth formed approximately 4.6 billion years ago from

1880-418: Is a post-transition metal in the boron group ; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state . The aluminium cation Al is small and highly charged ; as such, it has more polarizing power , and bonds formed by aluminium have a more covalent character. The strong affinity of aluminium for oxygen leads to the common occurrence of its oxides in nature. Aluminium

1974-548: Is a metal. This crystal system is shared by many other metals, such as lead and copper ; the size of a unit cell of aluminium is comparable to that of those other metals. The system, however, is not shared by the other members of its group: boron has ionization energies too high to allow metallization, thallium has a hexagonal close-packed structure, and gallium and indium have unusual structures that are not close-packed like those of aluminium and thallium. The few electrons that are available for metallic bonding in aluminium are

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2068-515: Is almost never found in the elemental state; instead it is found in oxides or silicates. Feldspars , the most common group of minerals in the Earth's crust, are aluminosilicates. Aluminium also occurs in the minerals beryl , cryolite , garnet , spinel , and turquoise . Impurities in Al 2 O 3 , such as chromium and iron , yield the gemstones ruby and sapphire , respectively. Native aluminium metal

2162-405: Is also easily machined and cast . Aluminium is an excellent thermal and electrical conductor , having around 60% the conductivity of copper , both thermal and electrical, while having only 30% of copper's density. Aluminium is capable of superconductivity , with a superconducting critical temperature of 1.2 kelvin and a critical magnetic field of about 100 gauss (10 milliteslas ). It

2256-401: Is enriched in incompatible elements compared to the basaltic ocean crust and much enriched compared to the underlying mantle. The most incompatible elements are enriched by a factor of 50 to 100 in the continental crust relative to primitive mantle rock, while oceanic crust is enriched with incompatible elements by a factor of about 10. The estimated average density of the continental crust

2350-546: Is extremely rare and can only be found as a minor phase in low oxygen fugacity environments, such as the interiors of certain volcanoes. Native aluminium has been reported in cold seeps in the northeastern continental slope of the South China Sea . It is possible that these deposits resulted from bacterial reduction of tetrahydroxoaluminate Al(OH) 4 . Although aluminium is a common and widespread element, not all aluminium minerals are economically viable sources of

2444-438: Is found on Earth primarily in rocks in the crust , where it is the third-most abundant element , after oxygen and silicon , rather than in the mantle , and virtually never as the free metal . It is obtained industrially by mining bauxite , a sedimentary rock rich in aluminium minerals. The discovery of aluminium was announced in 1825 by Danish physicist Hans Christian Ørsted . The first industrial production of aluminium

2538-536: Is greatly reduced by aqueous salts, particularly in the presence of dissimilar metals. Aluminium reacts with most nonmetals upon heating, forming compounds such as aluminium nitride (AlN), aluminium sulfide (Al 2 S 3 ), and the aluminium halides (AlX 3 ). It also forms a wide range of intermetallic compounds involving metals from every group on the periodic table. The vast majority of compounds, including all aluminium-containing minerals and all commercially significant aluminium compounds, feature aluminium in

2632-492: Is in fact more basic than that of gallium. Aluminium also bears minor similarities to the metalloid boron in the same group: AlX 3 compounds are valence isoelectronic to BX 3 compounds (they have the same valence electronic structure), and both behave as Lewis acids and readily form adducts . Additionally, one of the main motifs of boron chemistry is regular icosahedral structures, and aluminium forms an important part of many icosahedral quasicrystal alloys, including

2726-452: Is made of peridotite and is therefore significantly denser than the crust. The boundary between the crust and mantle is conventionally placed at the Mohorovičić discontinuity , a boundary defined by a contrast in seismic velocity. The temperature of the crust increases with depth, reaching values typically in the range from about 100 °C (212 °F) to 600 °C (1,112 °F) at

2820-500: Is negligible. Aqua regia also dissolves aluminium. Aluminium is corroded by dissolved chlorides , such as common sodium chloride , which is why household plumbing is never made from aluminium. The oxide layer on aluminium is also destroyed by contact with mercury due to amalgamation or with salts of some electropositive metals. As such, the strongest aluminium alloys are less corrosion-resistant due to galvanic reactions with alloyed copper , and aluminium's corrosion resistance

2914-515: Is not as important. It is a polymer with the formula (AlH 3 ) n , in contrast to the corresponding boron hydride that is a dimer with the formula (BH 3 ) 2 . Aluminium's per-particle abundance in the Solar System is 3.15 ppm (parts per million). It is the twelfth most abundant of all elements and third most abundant among the elements that have odd atomic numbers, after hydrogen and nitrogen. The only stable isotope of aluminium, Al,

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3008-416: Is quite soft and lacking in strength. In most applications various aluminium alloys are used instead because of their higher strength and hardness. The yield strength of pure aluminium is 7–11 MPa , while aluminium alloys have yield strengths ranging from 200 MPa to 600 MPa. Aluminium is ductile , with a percent elongation of 50-70%, and malleable allowing it to be easily drawn and extruded . It

3102-422: Is surrounded by six fluorine atoms in a distorted octahedral arrangement, with each fluorine atom being shared between the corners of two octahedra. Such {AlF 6 } units also exist in complex fluorides such as cryolite , Na 3 AlF 6 . AlF 3 melts at 1,290 °C (2,354 °F) and is made by reaction of aluminium oxide with hydrogen fluoride gas at 700 °C (1,300 °F). With heavier halides,

3196-547: Is termed amphoterism and is characteristic of weakly basic cations that form insoluble hydroxides and whose hydrated species can also donate their protons. One effect of this is that aluminium salts with weak acids are hydrolyzed in water to the aquated hydroxide and the corresponding nonmetal hydride: for example, aluminium sulfide yields hydrogen sulfide . However, some salts like aluminium carbonate exist in aqueous solution but are unstable as such; and only incomplete hydrolysis takes place for salts with strong acids, such as

3290-416: Is that of the preceding noble gas , whereas those of its heavier congeners gallium , indium , thallium , and nihonium also include a filled d-subshell and in some cases a filled f-subshell. Hence, the inner electrons of aluminium shield the valence electrons almost completely, unlike those of aluminium's heavier congeners. As such, aluminium is the most electropositive metal in its group, and its hydroxide

3384-433: Is the eighteenth most abundant nucleus in the universe. It is created almost entirely after fusion of carbon in massive stars that will later become Type II supernovas : this fusion creates Mg, which upon capturing free protons and neutrons, becomes aluminium. Some smaller quantities of Al are created in hydrogen burning shells of evolved stars, where Mg can capture free protons. Essentially all aluminium now in existence

3478-411: Is well tolerated by plants and animals. Because of the abundance of these salts, the potential for a biological role for them is of interest, and studies are ongoing. Of aluminium isotopes, only Al is stable. This situation is common for elements with an odd atomic number. It is the only primordial aluminium isotope, i.e. the only one that has existed on Earth in its current form since

3572-519: The -ium spelling as primary, and they list both where it is appropriate. The production of aluminium starts with the extraction of bauxite rock from the ground. The bauxite is processed and transformed using the Bayer process into alumina , which is then processed using the Hall–Héroult process , resulting in the final aluminium. Earth%27s crust Earth's crust is its thick outer shell of rock , referring to less than one percent of

3666-734: The Canadian Shield , and on other cratonic regions such as those on the Fennoscandian Shield . Some zircon with age as great as 4.3 billion years has been found in the Narryer Gneiss Terrane . Continental crust is a tertiary crust, formed at subduction zones through recycling of subducted secondary (oceanic) crust. The average age of Earth's current continental crust has been estimated to be about 2.0 billion years. Most crustal rocks formed before 2.5 billion years ago are located in cratons . Such an old continental crust and

3760-455: The Friedel–Crafts reactions . Aluminium trichloride has major industrial uses involving this reaction, such as in the manufacture of anthraquinones and styrene ; it is also often used as the precursor for many other aluminium compounds and as a reagent for converting nonmetal fluorides into the corresponding chlorides (a transhalogenation reaction ). Aluminium forms one stable oxide with

3854-466: The London Metal Exchange , the oldest industrial metal exchange in the world, in 1978. The output continued to grow: the annual production of aluminium exceeded 50,000,000 metric tons in 2013. The real price for aluminium declined from $ 14,000 per metric ton in 1900 to $ 2,340 in 1948 (in 1998 United States dollars). Extraction and processing costs were lowered over technological progress and

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3948-467: The aluminum spelling in his American Dictionary of the English Language . In the 1830s, the -um spelling gained usage in the United States; by the 1860s, it had become the more common spelling there outside science. In 1892, Hall used the -um spelling in his advertising handbill for his new electrolytic method of producing the metal, despite his constant use of the -ium spelling in all

4042-423: The chemical formula Al 2 O 3 , commonly called alumina . It can be found in nature in the mineral corundum , α-alumina; there is also a γ-alumina phase. Its crystalline form, corundum, is very hard ( Mohs hardness 9), has a high melting point of 2,045 °C (3,713 °F), has very low volatility, is chemically inert, and a good electrical insulator, it is often used in abrasives (such as toothpaste), as

4136-542: The interstellar gas ; if the original Al were still present, gamma ray maps of the Milky Way would be brighter. Overall, the Earth is about 1.59% aluminium by mass (seventh in abundance by mass). Aluminium occurs in greater proportion in the Earth's crust than in the universe at large. This is because aluminium easily forms the oxide and becomes bound into rocks and stays in the Earth's crust , while less reactive metals sink to

4230-476: The 2300 series of Kahler tremolo, and instead have to use a stud-mounted 2200 series. For a period spanning from the late-1980s to the time when Kahler ceased production in the early 1990s, Kahler also produced fulcrum-based systems similar to the Floyd Rose brand of vibratos. Nashville luthier David Petschulat, doing R&D at Kahler at the time, designed the "Steeler", "Killer", and "Spyder" fulcrum vibratos as

4324-516: The 5th century BCE. The ancients are known to have used alum as a dyeing mordant and for city defense. After the Crusades , alum, an indispensable good in the European fabric industry, was a subject of international commerce; it was imported to Europe from the eastern Mediterranean until the mid-15th century. The nature of alum remained unknown. Around 1530, Swiss physician Paracelsus suggested alum

4418-472: The Al–Zn–Mg class. Aluminium has a high chemical affinity to oxygen, which renders it suitable for use as a reducing agent in the thermite reaction. A fine powder of aluminium reacts explosively on contact with liquid oxygen ; under normal conditions, however, aluminium forms a thin oxide layer (~5 nm at room temperature) that protects the metal from further corrosion by oxygen, water, or dilute acid,

4512-750: The Kahler X-TREM on their more affordable signature models for Jeff Hanneman and Kerry King respectively. ESP and B.C. Rich offer the Kahler Hybrid model on their mid-range guitars such as LTD JH-600 and B.C. Rich Wartribe, both with EMG pickups . Gibson has included the Kahler system on limited edition guitars such as the Gibson Shred-X Explorer and the Gibson Tribal Explorer. Peavey 's PXD Void III and Twenty-Three III guitars also feature

4606-508: The Kahler system. Because they are suitable for left handed as well as right handed guitars, Gaskell Guitars offers all Kahler models on their custom left handed guitar builds. Aluminium Aluminium (or aluminum in North American English ) is a chemical element ; it has symbol   Al and atomic number  13. Aluminium has a density lower than that of other common metals , about one-third that of steel . It has

4700-418: The United States dollar, and alumina prices. The BRIC countries' combined share in primary production and primary consumption grew substantially in the first decade of the 21st century. China is accumulating an especially large share of the world's production thanks to an abundance of resources, cheap energy, and governmental stimuli; it also increased its consumption share from 2% in 1972 to 40% in 2010. In

4794-510: The United States, Western Europe, and Japan, most aluminium was consumed in transportation, engineering, construction, and packaging. In 2021, prices for industrial metals such as aluminium have soared to near-record levels as energy shortages in China drive up costs for electricity. The names aluminium and aluminum are derived from the word alumine , an obsolete term for alumina , the primary naturally occurring oxide of aluminium . Alumine

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4888-578: The aluminium atoms have tetrahedral four-coordination and the other half have trigonal bipyramidal five-coordination. Four pnictides – aluminium nitride (AlN), aluminium phosphide (AlP), aluminium arsenide (AlAs), and aluminium antimonide (AlSb) – are known. They are all III-V semiconductors isoelectronic to silicon and germanium , all of which but AlN have the zinc blende structure. All four can be made by high-temperature (and possibly high-pressure) direct reaction of their component elements. Aluminium alloys well with most other metals (with

4982-475: The boundary with the underlying mantle. The temperature increases by as much as 30 °C (54 °F) for every kilometer locally in the upper part of the crust. Earth's 40-kilometre (25-mile) deep crust—just one percent of Earth’s mass —contains all known life in the Universe . The crust of Earth is of two distinct types: The average thickness of the crust is about 15 – 20 km (9 – 12 mi). Because both

5076-436: The characteristic physical properties of a post-transition metal, with longer-than-expected interatomic distances. Furthermore, as Al is a small and highly charged cation, it is strongly polarizing and bonding in aluminium compounds tends towards covalency ; this behavior is similar to that of beryllium (Be ), and the two display an example of a diagonal relationship . The underlying core under aluminium's valence shell

5170-502: The composition is not uniform, with the upper crust averaging a more felsic composition similar to that of dacite , while the lower crust averages a more mafic composition resembling basalt. The most abundant minerals in Earth 's continental crust are feldspars , which make up about 41% of the crust by weight, followed by quartz at 12%, and pyroxenes at 11%. All the other constituents except water occur only in very small quantities and total less than 1%. Continental crust

5264-484: The continental and oceanic crust are less dense than the mantle below, both types of crust "float" on the mantle. The surface of the continental crust is significantly higher than the surface of the oceanic crust, due to the greater buoyancy of the thicker, less dense continental crust (an example of isostasy ). As a result, the continents form high ground surrounded by deep ocean basins. The continental crust has an average composition similar to that of andesite , though

5358-419: The coordination numbers are lower. The other trihalides are dimeric or polymeric with tetrahedral four-coordinate aluminium centers. Aluminium trichloride (AlCl 3 ) has a layered polymeric structure below its melting point of 192.4 °C (378 °F) but transforms on melting to Al 2 Cl 6 dimers. At higher temperatures those increasingly dissociate into trigonal planar AlCl 3 monomers similar to

5452-428: The core. In the Earth's crust, aluminium is the most abundant metallic element (8.23% by mass ) and the third most abundant of all elements (after oxygen and silicon). A large number of silicates in the Earth's crust contain aluminium. In contrast, the Earth's mantle is only 2.38% aluminium by mass. Aluminium also occurs in seawater at a concentration of 2 μg/kg. Because of its strong affinity for oxygen, aluminium

5546-497: The energy released by the decay of Al was responsible for the melting and differentiation of some asteroids after their formation 4.55 billion years ago. The remaining isotopes of aluminium, with mass numbers ranging from 21 to 43, all have half-lives well under an hour. Three metastable states are known, all with half-lives under a minute. An aluminium atom has 13 electrons, arranged in an electron configuration of [ Ne ] 3s 3p , with three electrons beyond

5640-478: The exception of most alkali metals and group 13 metals) and over 150 intermetallics with other metals are known. Preparation involves heating fixed metals together in certain proportion, followed by gradual cooling and annealing . Bonding in them is predominantly metallic and the crystal structure primarily depends on efficiency of packing. There are few compounds with lower oxidation states. A few aluminium(I) compounds exist: AlF, AlCl, AlBr, and AlI exist in

5734-520: The fact that its nuclei are much lighter, while difference in the unit cell size does not compensate for this difference. The only lighter metals are the metals of groups 1 and 2 , which apart from beryllium and magnesium are too reactive for structural use (and beryllium is very toxic). Aluminium is not as strong or stiff as steel, but the low density makes up for this in the aerospace industry and for many other applications where light weight and relatively high strength are crucial. Pure aluminium

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5828-442: The formation of the planet. It is therefore a mononuclidic element and its standard atomic weight is virtually the same as that of the isotope. This makes aluminium very useful in nuclear magnetic resonance (NMR), as its single stable isotope has a high NMR sensitivity. The standard atomic weight of aluminium is low in comparison with many other metals. All other isotopes of aluminium are radioactive . The most stable of these

5922-730: The gas phase after explosion and in stellar absorption spectra. More thoroughly investigated are compounds of the formula R 4 Al 2 which contain an Al–Al bond and where R is a large organic ligand . A variety of compounds of empirical formula AlR 3 and AlR 1.5 Cl 1.5 exist. The aluminium trialkyls and triaryls are reactive, volatile, and colorless liquids or low-melting solids. They catch fire spontaneously in air and react with water, thus necessitating precautions when handling them. They often form dimers, unlike their boron analogues, but this tendency diminishes for branched-chain alkyls (e.g. Pr , Bu , Me 3 CCH 2 ); for example, triisobutylaluminium exists as an equilibrium mixture of

6016-453: The gaseous phase when the respective trihalide is heated with aluminium, and at cryogenic temperatures. A stable derivative of aluminium monoiodide is the cyclic adduct formed with triethylamine , Al 4 I 4 (NEt 3 ) 4 . Al 2 O and Al 2 S also exist but are very unstable. Very simple aluminium(II) compounds are invoked or observed in the reactions of Al metal with oxidants. For example, aluminium monoxide , AlO, has been detected in

6110-646: The halides, nitrate , and sulfate . For similar reasons, anhydrous aluminium salts cannot be made by heating their "hydrates": hydrated aluminium chloride is in fact not AlCl 3 ·6H 2 O but [Al(H 2 O) 6 ]Cl 3 , and the Al–O bonds are so strong that heating is not sufficient to break them and form Al–Cl bonds instead: All four trihalides are well known. Unlike the structures of the three heavier trihalides, aluminium fluoride (AlF 3 ) features six-coordinate aluminium, which explains its involatility and insolubility as well as high heat of formation . Each aluminium atom

6204-532: The latter brass), were designed as an alternative to the stock Fender tremolo system, and were offered on several Fenders during the 1980s. Kahler also produces a bass tremolo system. The first two bridges Kahler sold after their return in 2005 were 2410 bass tremolos. Guitars that have carved tops (as opposed to flat, like the Fender Stratocaster ), such as the Gibson Les Paul , cannot properly mount

6298-433: The low-pressure polymerization of ethene and propene . There are also some heterocyclic and cluster organoaluminium compounds involving Al–N bonds. The industrially most important aluminium hydride is lithium aluminium hydride (LiAlH 4 ), which is used as a reducing agent in organic chemistry . It can be produced from lithium hydride and aluminium trichloride . The simplest hydride, aluminium hydride or alane,

6392-529: The metal remained rare; its cost exceeded that of gold. The first industrial production of aluminium was established in 1856 by French chemist Henri Etienne Sainte-Claire Deville and companions. Deville had discovered that aluminium trichloride could be reduced by sodium, which was more convenient and less expensive than potassium, which Wöhler had used. Even then, aluminium was still not of great purity and produced aluminium differed in properties by sample. Because of its electricity-conducting capacity, aluminium

6486-628: The metal to be isolated from alum was alumium , which Davy suggested in an 1808 article on his electrochemical research, published in Philosophical Transactions of the Royal Society . It appeared that the name was created from the English word alum and the Latin suffix -ium ; but it was customary then to give elements names originating in Latin, so this name was not adopted universally. This name

6580-465: The metal with many uses at the time. During World War I , major governments demanded large shipments of aluminium for light strong airframes; during World War II , demand by major governments for aviation was even higher. By the mid-20th century, aluminium had become a part of everyday life and an essential component of housewares. In 1954, production of aluminium surpassed that of copper , historically second in production only to iron, making it

6674-486: The metal. Almost all metallic aluminium is produced from the ore bauxite (AlO x (OH) 3–2 x ). Bauxite occurs as a weathering product of low iron and silica bedrock in tropical climatic conditions. In 2017, most bauxite was mined in Australia, China, Guinea, and India. The history of aluminium has been shaped by usage of alum . The first written record of alum, made by Greek historian Herodotus , dates back to

6768-485: The monomer and dimer. These dimers, such as trimethylaluminium (Al 2 Me 6 ), usually feature tetrahedral Al centers formed by dimerization with some alkyl group bridging between both aluminium atoms. They are hard acids and react readily with ligands, forming adducts. In industry, they are mostly used in alkene insertion reactions, as discovered by Karl Ziegler , most importantly in "growth reactions" that form long-chain unbranched primary alkenes and alcohols, and in

6862-506: The most produced non-ferrous metal . During the mid-20th century, aluminium emerged as a civil engineering material, with building applications in both basic construction and interior finish work, and increasingly being used in military engineering, for both airplanes and land armor vehicle engines. Earth's first artificial satellite , launched in 1957, consisted of two separate aluminium semi-spheres joined and all subsequent space vehicles have used aluminium to some extent. The aluminium can

6956-599: The next decade, the -um spelling dominated American usage. In 1925, the American Chemical Society adopted this spelling. The International Union of Pure and Applied Chemistry (IUPAC) adopted aluminium as the standard international name for the element in 1990. In 1993, they recognized aluminum as an acceptable variant; the most recent 2005 edition of the IUPAC nomenclature of inorganic chemistry also acknowledges this spelling. IUPAC official publications use

7050-594: The old ocean crust means that the oldest ocean crust on Earth today is only about 200 million years old. In contrast, the bulk of the continental crust is much older. The oldest continental crustal rocks on Earth have ages in the range from about 3.7 to 4.28 billion years and have been found in the Narryer Gneiss Terrane in Western Australia , in the Acasta Gneiss in the Northwest Territories on

7144-407: The oxidation state 3+. The coordination number of such compounds varies, but generally Al is either six- or four-coordinate. Almost all compounds of aluminium(III) are colorless. In aqueous solution, Al exists as the hexaaqua cation [Al(H 2 O) 6 ] , which has an approximate K a of 10 . Such solutions are acidic as this cation can act as a proton donor and progressively hydrolyze until

7238-460: The patents he filed between 1886 and 1903. It is unknown whether this spelling was introduced by mistake or intentionally, but Hall preferred aluminum since its introduction because it resembled platinum , the name of a prestigious metal. By 1890, both spellings had been common in the United States, the -ium spelling being slightly more common; by 1895, the situation had reversed; by 1900, aluminum had become twice as common as aluminium ; in

7332-401: The planet's radius and volume . It is the top component of the lithosphere , a solidified division of Earth 's layers that includes the crust and the upper part of the mantle . The lithosphere is broken into tectonic plates whose motion allows heat to escape the interior of Earth into space. The crust lies on top of the mantle, a configuration that is stable because the upper mantle

7426-423: The respective hydrogen chalcogenide . As aluminium is a small atom relative to these chalcogens, these have four-coordinate tetrahedral aluminium with various polymorphs having structures related to wurtzite , with two-thirds of the possible metal sites occupied either in an orderly (α) or random (β) fashion; the sulfide also has a γ form related to γ-alumina, and an unusual high-temperature hexagonal form where half

7520-485: The scale of the economies. However, the need to exploit lower-grade poorer quality deposits and the use of fast increasing input costs (above all, energy) increased the net cost of aluminium; the real price began to grow in the 1970s with the rise of energy cost. Production moved from the industrialized countries to countries where production was cheaper. Production costs in the late 20th century changed because of advances in technology, lower energy prices, exchange rates of

7614-408: The structure of BCl 3 . Aluminium tribromide and aluminium triiodide form Al 2 X 6 dimers in all three phases and hence do not show such significant changes of properties upon phase change. These materials are prepared by treating aluminium with the halogen. The aluminium trihalides form many addition compounds or complexes; their Lewis acidic nature makes them useful as catalysts for

7708-536: The two therefore look similar. Aluminium is also good at reflecting solar radiation , although prolonged exposure to sunlight in air adds wear to the surface of the metal; this may be prevented if aluminium is anodized , which adds a protective layer of oxide on the surface. The density of aluminium is 2.70 g/cm , about 1/3 that of steel, much lower than other commonly encountered metals, making aluminium parts easily identifiable through their lightness. Aluminium's low density compared to most other metals arises from

7802-430: The underlying mantle yields basaltic magmas and new ocean crust forms. This "ridge push" is one of the driving forces of plate tectonics, and it is constantly creating new ocean crust. Consequently, old crust must be destroyed, so opposite a spreading center, there is usually a subduction zone: a trench where an ocean plate is sinking back into the mantle. This constant process of creating a new ocean crust and destroying

7896-415: The underlying mantle asthenosphere are less dense than elsewhere on Earth and so are not readily destroyed by subduction. Formation of new continental crust is linked to periods of intense orogeny , which coincide with the formation of the supercontinents such as Rodinia , Pangaea and Gondwana . The crust forms in part by aggregation of island arcs including granite and metamorphic fold belts, and it

7990-421: Was a crucial strategic resource for aviation . In 1954, aluminium became the most produced non-ferrous metal , surpassing copper . In the 21st century, most aluminium was consumed in transportation, engineering, construction, and packaging in the United States, Western Europe, and Japan. Despite its prevalence in the environment, no living organism is known to metabolize aluminium salts , but this aluminium

8084-461: Was a salt of an earth of alum. In 1595, German doctor and chemist Andreas Libavius experimentally confirmed this. In 1722, German chemist Friedrich Hoffmann announced his belief that the base of alum was a distinct earth. In 1754, German chemist Andreas Sigismund Marggraf synthesized alumina by boiling clay in sulfuric acid and subsequently adding potash . Attempts to produce aluminium date back to 1760. The first successful attempt, however,

8178-485: Was borrowed from French, which in turn derived it from alumen , the classical Latin name for alum , the mineral from which it was collected. The Latin word alumen stems from the Proto-Indo-European root *alu- meaning "bitter" or "beer". British chemist Humphry Davy , who performed a number of experiments aimed to isolate the metal, is credited as the person who named the element. The first name proposed for

8272-422: Was completed in 1824 by Danish physicist and chemist Hans Christian Ørsted . He reacted anhydrous aluminium chloride with potassium amalgam , yielding a lump of metal looking similar to tin. He presented his results and demonstrated a sample of the new metal in 1825. In 1827, German chemist Friedrich Wöhler repeated Ørsted's experiments but did not identify any aluminium. (The reason for this inconsistency

8366-492: Was criticized by contemporary chemists from France, Germany, and Sweden, who insisted the metal should be named for the oxide, alumina, from which it would be isolated. The English name alum does not come directly from Latin, whereas alumine / alumina obviously comes from the Latin word alumen (upon declension , alumen changes to alumin- ). One example was Essai sur la Nomenclature chimique (July 1811), written in French by

8460-509: Was initiated by French chemist Henri Étienne Sainte-Claire Deville in 1856. Aluminium became much more available to the public with the Hall–Héroult process developed independently by French engineer Paul Héroult and American engineer Charles Martin Hall in 1886, and the mass production of aluminium led to its extensive use in industry and everyday life. In the First and Second World Wars, aluminium

8554-418: Was invented in 1956 and employed as a storage for drinks in 1958. Throughout the 20th century, the production of aluminium rose rapidly: while the world production of aluminium in 1900 was 6,800 metric tons, the annual production first exceeded 100,000 metric tons in 1916; 1,000,000 tons in 1941; 10,000,000 tons in 1971. In the 1970s, the increased demand for aluminium made it an exchange commodity; it entered

8648-475: Was likely repeatedly destroyed by large impacts, then reformed from the magma ocean left by the impact. None of Earth's primary crust has survived to today; all was destroyed by erosion , impacts, and plate tectonics over the past several billion years. Since then, Earth has been forming a secondary and tertiary crust, which correspond to oceanic and continental crust, respectively. Secondary crust forms at mid-ocean spreading centers , where partial-melting of

8742-433: Was only discovered in 1921.) He conducted a similar experiment in the same year by mixing anhydrous aluminium chloride with potassium and produced a powder of aluminium. In 1845, he was able to produce small pieces of the metal and described some physical properties of this metal. For many years thereafter, Wöhler was credited as the discoverer of aluminium. As Wöhler's method could not yield great quantities of aluminium,

8836-571: Was used as the cap of the Washington Monument , completed in 1885. The tallest building in the world at the time, the non-corroding metal cap was intended to serve as a lightning rod peak. The first industrial large-scale production method was independently developed in 1886 by French engineer Paul Héroult and American engineer Charles Martin Hall ; it is now known as the Hall–Héroult process . The Hall–Héroult process converts alumina into metal. Austrian chemist Carl Joseph Bayer discovered

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