Ironstone is a sedimentary rock , either deposited directly as a ferruginous sediment or created by chemical replacement, that contains a substantial proportion of an iron ore compound from which iron (Fe) can be smelted commercially.
92-593: Not to be confused with native or telluric iron , which is very rare and found in metallic form, the term ironstone is customarily restricted to hard, coarsely banded, non-banded, and non- cherty sedimentary rocks of post-Precambrian age. The Precambrian deposits, which have a different origin, are generally known as banded iron formations . The iron minerals comprising ironstones can consist either of oxides, i.e. limonite , hematite , and magnetite ; carbonates, i.e. siderite ; silicates, i.e. chamosite ; or some combination of these minerals. Freshly cleaved ironstone
184-730: A hexagonal crystal lattice with all atoms covalently bonded and properties similar to those of diamond. Fullerenes are a synthetic crystalline formation with a graphite-like structure, but in place of flat hexagonal cells only, some of the cells of which fullerenes are formed may be pentagons, nonplanar hexagons, or even heptagons of carbon atoms. The sheets are thus warped into spheres, ellipses, or cylinders. The properties of fullerenes (split into buckyballs, buckytubes, and nanobuds) have not yet been fully analyzed and represent an intense area of research in nanomaterials . The names fullerene and buckyball are given after Richard Buckminster Fuller , popularizer of geodesic domes , which resemble
276-706: A nuclear halo , which means its radius is appreciably larger than would be expected if the nucleus were a sphere of constant density. Formation of the carbon atomic nucleus occurs within a giant or supergiant star through the triple-alpha process . This requires a nearly simultaneous collision of three alpha particles (helium nuclei), as the products of further nuclear fusion reactions of helium with hydrogen or another helium nucleus produce lithium-5 and beryllium-8 respectively, both of which are highly unstable and decay almost instantly back into smaller nuclei. The triple-alpha process happens in conditions of temperatures over 100 megakelvins and helium concentration that
368-540: A porous , sponge-iron type of material that pulverizes at the strike of a hammer. Type 2 telluric iron also contains around 0.05 to 4% nickel, but typically less than 0.7% carbon. Type 2 is a malleable nickel-iron which responds well to cold working. The carbon and nickel content have a great effect on the final hardness of the cold-worked piece. Type 2 is found as small grains mixed within basalt rock. The grains are usually 1–5 millimeters in diameter. The grains are usually found individually, separated by
460-434: A π-cloud , graphite conducts electricity , but only in the plane of each covalently bonded sheet. This results in a lower bulk electrical conductivity for carbon than for most metals. The delocalization also accounts for the energetic stability of graphite over diamond at room temperature. At very high pressures, carbon forms the more compact allotrope, diamond, having nearly twice the density of graphite. Here, each atom
552-418: A carbon atom with six bonds. More specifically, the dication could be described structurally by the formulation [MeC(η -C 5 Me 5 )] , making it an "organic metallocene " in which a MeC fragment is bonded to a η -C 5 Me 5 fragment through all five of the carbons of the ring. It is important to note that in the cases above, each of the bonds to carbon contain less than two formal electron pairs. Thus,
644-550: A carbon-metal covalent bond (e.g., metal carboxylates) are termed metalorganic compounds. While carbon is understood to strongly prefer formation of four covalent bonds, other exotic bonding schemes are also known. Carboranes are highly stable dodecahedral derivatives of the [B 12 H 12 ] unit, with one BH replaced with a CH . Thus, the carbon is bonded to five boron atoms and one hydrogen atom. The cation [(Ph 3 PAu) 6 C] contains an octahedral carbon bound to six phosphine-gold fragments. This phenomenon has been attributed to
736-462: A density of about 2 kg/m . Similarly, glassy carbon contains a high proportion of closed porosity , but contrary to normal graphite, the graphitic layers are not stacked like pages in a book, but have a more random arrangement. Linear acetylenic carbon has the chemical structure −(C≡C) n − . Carbon in this modification is linear with sp orbital hybridization , and is a polymer with alternating single and triple bonds. This carbyne
828-515: A hardness superior to diamonds. In the vapor phase, some of the carbon is in the form of highly reactive diatomic carbon dicarbon ( C 2 ). When excited, this gas glows green. Carbon is the fourth most abundant chemical element in the observable universe by mass after hydrogen, helium, and oxygen. Carbon is abundant in the Sun, stars, comets, and in the atmospheres of most planets. Some meteorites contain microscopic diamonds that were formed when
920-413: A high activation energy barrier, the transition into graphite is so slow at normal temperature that it is unnoticeable. However, at very high temperatures diamond will turn into graphite, and diamonds can burn up in a house fire. The bottom left corner of the phase diagram for carbon has not been scrutinized experimentally. Although a computational study employing density functional theory methods reached
1012-425: A hydrogen based engine in cars. The amorphous form is an assortment of carbon atoms in a non-crystalline, irregular, glassy state, not held in a crystalline macrostructure. It is present as a powder, and is the main constituent of substances such as charcoal, lampblack (soot), and activated carbon . At normal pressures, carbon takes the form of graphite, in which each atom is bonded trigonally to three others in
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#17328692691991104-435: A lower binding affinity. Cyanide (CN ), has a similar structure, but behaves much like a halide ion ( pseudohalogen ). For example, it can form the nitride cyanogen molecule ((CN) 2 ), similar to diatomic halides. Likewise, the heavier analog of cyanide, cyaphide (CP ), is also considered inorganic, though most simple derivatives are highly unstable. Other uncommon oxides are carbon suboxide ( C 3 O 2 ),
1196-414: A plane composed of fused hexagonal rings, just like those in aromatic hydrocarbons . The resulting network is 2-dimensional, and the resulting flat sheets are stacked and loosely bonded through weak van der Waals forces . This gives graphite its softness and its cleaving properties (the sheets slip easily past one another). Because of the delocalization of one of the outer electrons of each atom to form
1288-526: A small number of stabilized carbocations (three bonds, positive charge), radicals (three bonds, neutral), carbanions (three bonds, negative charge) and carbenes (two bonds, neutral), although these species are much more likely to be encountered as unstable, reactive intermediates. Carbon occurs in all known organic life and is the basis of organic chemistry . When united with hydrogen, it forms various hydrocarbons that are important to industry as refrigerants, lubricants, solvents, as chemical feedstock for
1380-430: A telluric mineral , and the presence of nickel together with a certain crystalline structure are consequently not sufficient to give the character of meteorites to loose iron blocks. Steenstrup's findings were later confirmed by meteorite expert J. Lawrence Smith in 1879, and then by Joh Lorenzen in 1882. The extremely rare telluric iron found in western Greenland has been under study ever since. In addition to
1472-432: A vast number of compounds , with about two hundred million having been described and indexed; and yet that number is but a fraction of the number of theoretically possible compounds under standard conditions. The allotropes of carbon include graphite , one of the softest known substances, and diamond , the hardest naturally occurring substance. It bonds readily with other small atoms, including other carbon atoms, and
1564-600: Is iron that originated on Earth , and is found in a metallic form rather than as an ore . Telluric iron is extremely rare, with only one known major deposit in the world, located in Greenland . With the exception of its molten core, nearly all elemental iron on Earth is found as iron ores . All metallic iron was thought to have been transformed into iron oxides during the Great Oxidation Event , beginning roughly 2 billion years ago, among other theories. Until
1656-403: Is a chemical element ; it has symbol C and atomic number 6. It is nonmetallic and tetravalent —meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 electrons. It belongs to group 14 of the periodic table . Carbon makes up about 0.025 percent of Earth's crust. Three isotopes occur naturally, C and C being stable, while C
1748-461: Is a radionuclide , decaying with a half-life of 5,700 years. Carbon is one of the few elements known since antiquity . Carbon is the 15th most abundant element in the Earth's crust , and the fourth most abundant element in the universe by mass after hydrogen , helium , and oxygen . Carbon's abundance, its unique diversity of organic compounds , and its unusual ability to form polymers at
1840-437: Is a cast-iron typically containing over 2.0% carbon, while type 2 ranges somewhere between wrought iron and a eutectoid steel. Both types tend to handle weathering in the elements very well, but tend to decompose and crumble very quickly in the dry, controlled atmosphere of a museum, although type 2 is far more prone to this kind of damage. Type 1 telluric iron contains a significant amount of carbon. Type 1
1932-457: Is a limited source of iron. Historically, most British iron originated from ironstone, but it is now rarely used for this purpose because it is far too limited in quantity to be an economic source of iron ore. Ironstone's oxide impurities render it useless as a component in ceramics : the " ironstone china " of Staffordshire and American manufacture, a fine, white, high-fired vitreous semi-porcelain , commonly used for heavy-duty dinner services in
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#17328692691992024-441: Is a two-dimensional sheet of carbon with the atoms arranged in a hexagonal lattice. As of 2009, graphene appears to be the strongest material ever tested. The process of separating it from graphite will require some further technological development before it is economical for industrial processes. If successful, graphene could be used in the construction of a space elevator . It could also be used to safely store hydrogen for use in
2116-426: Is a white nickel cast-iron, containing 1.7 to 4% carbon and 0.05 to 4% nickel, which is very hard and brittle and does not respond well to cold working . The structure of type 1 consists mainly of pearlite and cementite or cohenite , with inclusions of troilite and silicate . The individual ferrite grains are typically about a millimeter in size. Although the composition of the grains may vary, even within
2208-439: Is almost constant, but decreases predictably in their bodies after death. This principle is used in radiocarbon dating , invented in 1949, which has been used extensively to determine the age of carbonaceous materials with ages up to about 40,000 years. There are 15 known isotopes of carbon and the shortest-lived of these is C which decays through proton emission and has a half-life of 3.5 × 10 s. The exotic C exhibits
2300-407: Is also found in methane hydrates in polar regions and under the seas. Various estimates put this carbon between 500, 2500, or 3,000 Gt. According to one source, in the period from 1751 to 2008 about 347 gigatonnes of carbon were released as carbon dioxide to the atmosphere from burning of fossil fuels. Another source puts the amount added to the atmosphere for the period since 1750 at 879 Gt, and
2392-415: Is at 10.8 ± 0.2 megapascals (106.6 ± 2.0 atm; 1,566 ± 29 psi) and 4,600 ± 300 K (4,330 ± 300 °C; 7,820 ± 540 °F), so it sublimes at about 3,900 K (3,630 °C; 6,560 °F). Graphite is much more reactive than diamond at standard conditions, despite being more thermodynamically stable, as its delocalised pi system
2484-594: Is bonded tetrahedrally to four others, forming a 3-dimensional network of puckered six-membered rings of atoms. Diamond has the same cubic structure as silicon and germanium , and because of the strength of the carbon-carbon bonds , it is the hardest naturally occurring substance measured by resistance to scratching . Contrary to the popular belief that "diamonds are forever" , they are thermodynamically unstable ( Δ f G ° (diamond, 298 K) = 2.9 kJ/mol ) under normal conditions (298 K, 10 Pa) and should theoretically transform into graphite. But due to
2576-406: Is capable of forming multiple stable covalent bonds with suitable multivalent atoms. Carbon is a component element in the large majority of all chemical compounds , with about two hundred million examples having been described in the published chemical literature. Carbon also has the highest sublimation point of all elements. At atmospheric pressure it has no melting point, as its triple point
2668-549: Is carbon dioxide (CO 2 ). This was once the principal constituent of the paleoatmosphere , but is a minor component of the Earth's atmosphere today. Dissolved in water, it forms carbonic acid ( H 2 CO 3 ), but as most compounds with multiple single-bonded oxygens on a single carbon it is unstable. Through this intermediate, though, resonance-stabilized carbonate ions are produced. Some important minerals are carbonates, notably calcite . Carbon disulfide ( CS 2 )
2760-663: Is dissolved in the oceans; if bacteria do not consume it, dead plant or animal matter may become petroleum or coal, which releases carbon when burned. Carbon can form very long chains of interconnecting carbon–carbon bonds , a property that is called catenation . Carbon-carbon bonds are strong and stable. Through catenation, carbon forms a countless number of compounds. A tally of unique compounds shows that more contain carbon than do not. A similar claim can be made for hydrogen because most organic compounds contain hydrogen chemically bonded to carbon or another common element like oxygen or nitrogen. The simplest form of an organic molecule
2852-765: Is found in large quantities in the United States (mostly in New York and Texas ), Russia, Mexico, Greenland, and India. Natural diamonds occur in the rock kimberlite , found in ancient volcanic "necks", or "pipes". Most diamond deposits are in Africa, notably in South Africa, Namibia, Botswana, the Republic of the Congo, and Sierra Leone. Diamond deposits have also been found in Arkansas , Canada,
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2944-422: Is found in trace amounts on Earth of 1 part per trillion (0.0000000001%) or more, mostly confined to the atmosphere and superficial deposits, particularly of peat and other organic materials. This isotope decays by 0.158 MeV β emission . Because of its relatively short half-life of 5700 ± 30 years, C is virtually absent in ancient rocks. The amount of C in the atmosphere and in living organisms
3036-412: Is found mixed with basalt as very small grains with sharp corners and irregular shapes, whereas in others the small, grain-sized droplets in the molten magma were able to coalesce into larger, pea-sized droplets that crystallized with a mostly spherical or oblong shape. Still in others the dike or extrusion may be made almost entirely out of very high-carbon cast-iron, which could more easily coalesce within
3128-462: Is much more vulnerable to attack. For example, graphite can be oxidised by hot concentrated nitric acid at standard conditions to mellitic acid , C 6 (CO 2 H) 6 , which preserves the hexagonal units of graphite while breaking up the larger structure. Carbon sublimes in a carbon arc, which has a temperature of about 5800 K (5,530 °C or 9,980 °F). Thus, irrespective of its allotropic form, carbon remains solid at higher temperatures than
3220-493: Is of considerable interest to nanotechnology as its Young's modulus is 40 times that of the hardest known material – diamond. In 2015, a team at the North Carolina State University announced the development of another allotrope they have dubbed Q-carbon , created by a high-energy low-duration laser pulse on amorphous carbon dust. Q-carbon is reported to exhibit ferromagnetism, fluorescence , and
3312-566: Is one such star system with an abundance of carbon, enabling the existence of life as we know it. It is the opinion of most scholars that all the carbon in the Solar System and the Milky Way comes from dying stars. The CNO cycle is an additional hydrogen fusion mechanism that powers stars, wherein carbon operates as a catalyst. Rotational transitions of various isotopic forms of carbon monoxide (for example, CO, CO, and CO) are detectable in
3404-471: Is possibly best accomplished with a carborundum wheel and water cooling. However type 1 was possibly used as hammer and anvil stones by the Inuit. When sawed in half, boulders of type 1 tend to have a thick shell of cast-iron on the outside that can barely be broken with pneumatic jackhammers , but inside a much more brittle construction of iron grains in an almost powdery form, sintered together to form
3496-453: Is similar. Nevertheless, due to its physical properties and its association with organic synthesis, carbon disulfide is sometimes classified as an organic solvent. The other common oxide is carbon monoxide (CO). It is formed by incomplete combustion, and is a colorless, odorless gas. The molecules each contain a triple bond and are fairly polar , resulting in a tendency to bind permanently to hemoglobin molecules, displacing oxygen, which has
3588-566: Is stabilized in various multi-atomic structures with diverse molecular configurations called allotropes . The three relatively well-known allotropes of carbon are amorphous carbon , graphite , and diamond. Once considered exotic, fullerenes are nowadays commonly synthesized and used in research; they include buckyballs , carbon nanotubes , carbon nanobuds and nanofibers . Several other exotic allotropes have also been discovered, such as lonsdaleite , glassy carbon , carbon nanofoam and linear acetylenic carbon (carbyne). Graphene
3680-681: Is the hydrocarbon—a large family of organic molecules that are composed of hydrogen atoms bonded to a chain of carbon atoms. A hydrocarbon backbone can be substituted by other atoms, known as heteroatoms . Common heteroatoms that appear in organic compounds include oxygen, nitrogen, sulfur, phosphorus, and the nonradioactive halogens, as well as the metals lithium and magnesium. Organic compounds containing bonds to metal are known as organometallic compounds ( see below ). Certain groupings of atoms, often including heteroatoms, recur in large numbers of organic compounds. These collections, known as functional groups , confer common reactivity patterns and allow for
3772-521: Is usually grey. The brown external appearance is due to oxidation of its surface. Ironstone, being a sedimentary rock is not always homogeneous , and can be found in a red-and-black banded form called tiger iron , sometimes used for jewelry purposes. Sometimes ironstone hosts concretions or opal gems. Ironstone occurs in a variety of forms. The various forms of ironstone include siderite nodules; deeply weathered saprolite , i.e. ( laterite ); and ooidal ironstone. Ironstone, although widespread,
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3864-484: Is very soft and can be hammered into very thin plates. These flat discs were usually inserted into long slits carved into bone handles, in rows so that they slightly overlapped each other, forming an edge that resembled a combination of a knife and a saw (an inverted scalloped edge ). Aside from a very small deposit of telluric iron in Kassel, Germany , which has now been depleted, and a few other minor deposits from around
3956-484: The International Union of Pure and Applied Chemistry (IUPAC) adopted the isotope carbon-12 as the basis for atomic weights . Identification of carbon in nuclear magnetic resonance (NMR) experiments is done with the isotope C. Carbon-14 ( C) is a naturally occurring radioisotope , created in the upper atmosphere (lower stratosphere and upper troposphere ) by interaction of nitrogen with cosmic rays. It
4048-504: The PAH world hypothesis where they are hypothesized to have a role in abiogenesis and formation of life. PAHs seem to have been formed "a couple of billion years" after the Big Bang , are widespread throughout the universe, and are associated with new stars and exoplanets . It has been estimated that the solid earth as a whole contains 730 ppm of carbon, with 2000 ppm in the core and 120 ppm in
4140-425: The aurophilicity of the gold ligands, which provide additional stabilization of an otherwise labile species. In nature, the iron-molybdenum cofactor ( FeMoco ) responsible for microbial nitrogen fixation likewise has an octahedral carbon center (formally a carbide, C(-IV)) bonded to six iron atoms. In 2016, it was confirmed that, in line with earlier theoretical predictions, the hexamethylbenzene dication contains
4232-695: The biosphere has been estimated at 550 gigatonnes but with a large uncertainty, due mostly to a huge uncertainty in the amount of terrestrial deep subsurface bacteria . Hydrocarbons (such as coal, petroleum, and natural gas) contain carbon as well. Coal "reserves" (not "resources") amount to around 900 gigatonnes with perhaps 18,000 Gt of resources. Oil reserves are around 150 gigatonnes. Proven sources of natural gas are about 175 × 10 cubic metres (containing about 105 gigatonnes of carbon), but studies estimate another 900 × 10 cubic metres of "unconventional" deposits such as shale gas , representing about 540 gigatonnes of carbon. Carbon
4324-451: The carbon cycle . For example, photosynthetic plants draw carbon dioxide from the atmosphere (or seawater) and build it into biomass, as in the Calvin cycle , a process of carbon fixation . Some of this biomass is eaten by animals, while some carbon is exhaled by animals as carbon dioxide. The carbon cycle is considerably more complicated than this short loop; for example, some carbon dioxide
4416-399: The submillimeter wavelength range, and are used in the study of newly forming stars in molecular clouds . Under terrestrial conditions, conversion of one element to another is very rare. Therefore, the amount of carbon on Earth is effectively constant. Thus, processes that use carbon must obtain it from somewhere and dispose of it somewhere else. The paths of carbon in the environment form
4508-584: The 19th century, includes no ironstone in its production. Its "iron" quality is in its resistance to chipping. The stone can be used as a building material. Examples include the parish churches at Kirby Bellars and South Croxton in Leicestershire , and Eydon Hall in Northamptonshire . Sculptures carved out of ironstone are rare. One example is Henry Moore 's Head created in 1930. Telluric iron Telluric iron , also called native iron ,
4600-534: The Disko Bay area of Greenland. Knowing that the Inuit had made tools from the Cape York meteorite , mainly due to Sir John Ross ' discovery that the natives of Greenland used iron knives, Nordenskiöld landed at Fortune Bay on Disko Island to search for the material. The Inuit had told Ross that they got the iron from high on a mountain, at a site where two large boulders lay. One was very hard and could not be broken, but
4692-471: The Disko Island deposit native iron has been reported from Fortune Bay, Mellemfjord, Asuk, and other locations along Greenland's west coast. Other locations include: Native nickel-iron alloys with Ni 3 Fe to Ni 2 Fe occur as placer deposits derived from ultramafic rocks . Awaruite was described in 1885 from New Zealand . Carbon Carbon (from Latin carbo 'coal')
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#17328692691994784-762: The Riksmuseum in Stockholm, a 6.6 ton block outside the Geological Museum in Copenhagen, and a 3-ton block can be found in the Museum of Natural History in Kumpula, Helsinki. Accompanying Nauckhoff in 1871 was K. J. V. Steenstrup . Due to circumstances like the shape of the boulders, which often had sharp corners or jagged edges that are not characteristic of meteorites (which ablate considerably during atmospheric entry ), or
4876-629: The Russian Arctic, Brazil, and in Northern and Western Australia. Diamonds are now also being recovered from the ocean floor off the Cape of Good Hope . Diamonds are found naturally, but about 30% of all industrial diamonds used in the U.S. are now manufactured. Carbon-14 is formed in upper layers of the troposphere and the stratosphere at altitudes of 9–15 km by a reaction that is precipitated by cosmic rays . Thermal neutrons are produced that collide with
4968-459: The Solar System was still a protoplanetary disk . Microscopic diamonds may also be formed by the intense pressure and high temperature at the sites of meteorite impacts. In 2014 NASA announced a greatly upgraded database for tracking polycyclic aromatic hydrocarbons (PAHs) in the universe. More than 20% of the carbon in the universe may be associated with PAHs, complex compounds of carbon and hydrogen without oxygen. These compounds figure in
5060-498: The addition of phosphorus to these other elements, it forms DNA and RNA , the chemical-code carriers of life, and adenosine triphosphate (ATP), the most important energy-transfer molecule in all living cells. Norman Horowitz , head of the Mariner and Viking missions to Mars (1965–1976), considered that the unique characteristics of carbon made it unlikely that any other element could replace carbon, even on another planet, to generate
5152-506: The allotropic form. For example, graphite is opaque and black, while diamond is highly transparent . Graphite is soft enough to form a streak on paper (hence its name, from the Greek verb "γράφειν" which means "to write"), while diamond is the hardest naturally occurring material known. Graphite is a good electrical conductor while diamond has a low electrical conductivity . Under normal conditions, diamond, carbon nanotubes , and graphene have
5244-450: The basalt, although they are sometimes sintered together to form larger aggregates. The larger pieces also contain small amounts of cohenite, ilmenite , pearlite, and troilite. Type 2 was used by the Inuit to make items such as knives and ulus . The basalt was usually crushed in order to release the pea-sized grains, which were then hammered into discs about the size of coins. The metal
5336-451: The biochemistry necessary for life. Commonly carbon-containing compounds which are associated with minerals or which do not contain bonds to the other carbon atoms, halogens, or hydrogen, are treated separately from classical organic compounds; the definition is not rigid, and the classification of some compounds can vary from author to author (see reference articles above). Among these are the simple oxides of carbon. The most prominent oxide
5428-529: The carbon is bonded to. In general, covalent radius decreases with lower coordination number and higher bond order. Carbon-based compounds form the basis of all known life on Earth, and the carbon-nitrogen-oxygen cycle provides a small portion of the energy produced by the Sun, and most of the energy in larger stars (e.g. Sirius ). Although it forms an extraordinary variety of compounds, most forms of carbon are comparatively unreactive under normal conditions. At standard temperature and pressure, it resists all but
5520-406: The coal-gas reaction used in coal gasification : Carbon combines with some metals at high temperatures to form metallic carbides, such as the iron carbide cementite in steel and tungsten carbide , widely used as an abrasive and for making hard tips for cutting tools. The system of carbon allotropes spans a range of extremes: Atomic carbon is a very short-lived species and, therefore, carbon
5612-489: The combined mantle and crust. Since the mass of the earth is 5.972 × 10 kg , this would imply 4360 million gigatonnes of carbon. This is much more than the amount of carbon in the oceans or atmosphere (below). In combination with oxygen in carbon dioxide, carbon is found in the Earth's atmosphere (approximately 900 gigatonnes of carbon — each ppm corresponds to 2.13 Gt) and dissolved in all water bodies (approximately 36,000 gigatonnes of carbon). Carbon in
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#17328692691995704-453: The conclusion that as T → 0 K and p → 0 Pa , diamond becomes more stable than graphite by approximately 1.1 kJ/mol, more recent and definitive experimental and computational studies show that graphite is more stable than diamond for T < 400 K , without applied pressure, by 2.7 kJ/mol at T = 0 K and 3.2 kJ/mol at T = 298.15 K. Under some conditions, carbon crystallizes as lonsdaleite ,
5796-670: The fact that many had areas that were encrusted with basalt , Steenstrup disagreed with Nordenskiöld about the origin of the boulders, and set out on an expedition of his own in 1878. In 1879, Steenstrup first identified the type 2 iron , showing that it also contained Widmanstätten structures . Steenstrup later reported what he found: In the autumn of 1879, I made a discovery in connection with this matter, for in an old grave at Ekaluit ... I found 9 pieces of basalt containing round balls and irregular pieces of metallic iron. These pieces were lying together with bone knives, similar to those brought home by Ross, as well as with
5888-503: The formal electron count of these species does not exceed an octet. This makes them hypercoordinate but not hypervalent. Even in cases of alleged 10-C-5 species (that is, a carbon with five ligands and a formal electron count of ten), as reported by Akiba and co-workers, electronic structure calculations conclude that the electron population around carbon is still less than eight, as is true for other compounds featuring four-electron three-center bonding . The English name carbon comes from
5980-484: The future, but is currently technologically impossible. Isotopes of carbon are atomic nuclei that contain six protons plus a number of neutrons (varying from 2 to 16). Carbon has two stable, naturally occurring isotopes. The isotope carbon-12 ( C) forms 98.93% of the carbon on Earth, while carbon-13 ( C) forms the remaining 1.07%. The concentration of C is further increased in biological materials because biochemical reactions discriminate against C. In 1961,
6072-423: The heavier group-14 elements. The electronegativity of carbon is 2.5, significantly higher than the heavier group-14 elements (1.8–1.9), but close to most of the nearby nonmetals, as well as some of the second- and third-row transition metals . Carbon's covalent radii are normally taken as 77.2 pm (C−C), 66.7 pm (C=C) and 60.3 pm (C≡C), although these may vary depending on coordination number and what
6164-580: The high carbon-content and low oxide presence in the metal, although it is unknown if the metal managed to escape being oxidized with the rest of Earth's iron, or if it began as beds of ore and coal that subducted and then were naturally smelted in the lava due to the reducing environment provided by the carbon-rich, graphitic feldspar . Telluric iron in Greenland is unique, in that it can be found in nearly all phases of iron-carbon alloys , and with drastically varying crystalline structures. In some rock it
6256-675: The highest thermal conductivities of all known materials. All carbon allotropes are solids under normal conditions, with graphite being the most thermodynamically stable form at standard temperature and pressure. They are chemically resistant and require high temperature to react even with oxygen. The most common oxidation state of carbon in inorganic compounds is +4, while +2 is found in carbon monoxide and transition metal carbonyl complexes. The largest sources of inorganic carbon are limestones , dolomites and carbon dioxide , but significant quantities occur in organic deposits of coal , peat , oil , and methane clathrates . Carbon forms
6348-509: The highest-melting-point metals such as tungsten or rhenium . Although thermodynamically prone to oxidation, carbon resists oxidation more effectively than elements such as iron and copper, which are weaker reducing agents at room temperature. Carbon is the sixth element, with a ground-state electron configuration of 1s 2s 2p , of which the four outer electrons are valence electrons . Its first four ionisation energies, 1086.5, 2352.6, 4620.5 and 6222.7 kJ/mol, are much higher than those of
6440-453: The late 1800s, iron as a native metal was only a matter of speculation, outside of isolated Greenland. The only known, terrestrial iron in metallic form were found as meteorites , which were deposited onto the Earth from outer space. Telluric iron is so named after the Latin word Tellus , meaning "Earth" (the planet, as opposed to terra meaning "earth": the land, ground or soil), combined with
6532-410: The magma and flow into cracks due to its lower viscosity and melting point. This cast iron is often crusted with or contains inclusions of basalt, as it extruded out of the ground as very large, globular masses within the lava, out of which large boulders formed due to natural erosion of the surrounding basalt. Telluric iron is largely divided into two groups, depending on the carbon content. Type 1
6624-414: The manufacture of plastics and petrochemicals, and as fossil fuels. When combined with oxygen and hydrogen, carbon can form many groups of important biological compounds including sugars, lignans , chitins , alcohols, fats, aromatic esters , carotenoids and terpenes . With nitrogen, it forms alkaloids , and with the addition of sulfur also it forms antibiotics, amino acids , and rubber products. With
6716-455: The material out of which the Esquimaux made artificial knives , and secondly, because it showed that they have used telluric iron for that purpose . After the discovery in the grave at Ekaluit , Steenstrup found many large outcrops of basalt containing the type 2 iron . Since the type 2 grains are embedded within volcanic basalt that matches the underlying bedrock, Steenstrup
6808-1053: The most polar and salt-like of carbides are not completely ionic compounds. Organometallic compounds by definition contain at least one carbon-metal covalent bond. A wide range of such compounds exist; major classes include simple alkyl-metal compounds (for example, tetraethyllead ), η -alkene compounds (for example, Zeise's salt ), and η -allyl compounds (for example, allylpalladium chloride dimer ); metallocenes containing cyclopentadienyl ligands (for example, ferrocene ); and transition metal carbene complexes . Many metal carbonyls and metal cyanides exist (for example, tetracarbonylnickel and potassium ferricyanide ); some workers consider metal carbonyl and cyanide complexes without other carbon ligands to be purely inorganic, and not organometallic. However, most organometallic chemists consider metal complexes with any carbon ligand, even 'inorganic carbon' (e.g., carbonyls, cyanides, and certain types of carbides and acetylides) to be organometallic in nature. Metal complexes containing organic ligands without
6900-408: The nuclei of nitrogen-14, forming carbon-14 and a proton. As such, 1.5% × 10 of atmospheric carbon dioxide contains carbon-14. Carbon-rich asteroids are relatively preponderant in the outer parts of the asteroid belt in the Solar System. These asteroids have not yet been directly sampled by scientists. The asteroids can be used in hypothetical space-based carbon mining , which may be possible in
6992-473: The other was chipped into smaller pieces from which balls of iron were extracted and hammered into flat discs for the knives. Nordenskiöld searched unsuccessfully for the site, until being led by some of the local Inuit to a place called Uivfaq , where large masses of metallic iron were strewn about the area. He assumed that the metal was of meteoric origin , since both contain significant amounts of nickel and both had Widmanstätten patterns . Most scientists at
7084-423: The outer wall of a nanotube) that combine the properties of both in a single structure. Of the other discovered allotropes, carbon nanofoam is a ferromagnetic allotrope discovered in 1997. It consists of a low-density cluster-assembly of carbon atoms strung together in a loose three-dimensional web, in which the atoms are bonded trigonally in six- and seven-membered rings. It is among the lightest known solids, with
7176-521: The rapid expansion and cooling of the early universe prohibited, and therefore no significant carbon was created during the Big Bang. According to current physical cosmology theory, carbon is formed in the interiors of stars on the horizontal branch . When massive stars die as supernova, the carbon is scattered into space as dust. This dust becomes component material for the formation of the next-generation star systems with accreted planets. The Solar System
7268-503: The same grain, they are mostly composed of fairly pure nickel-ferrite. The ferrite grains are connected with cementite laminations; typically 5–25 micrometers thick; forming the pearlite. Type 1 is found as massive extrusions or very large boulders, typically ranging from a few tons to tens of tons. The metal could not be cold worked by the ancient Inuit , (the local inhabitants of Greenland), and proves extremely difficult to machine even with modern tools. Machining of type 1
7360-433: The same region, as well as drastic variations between different regions such as Uivfaq, Asuk, Blaafjeld, and Mellemfjord. The common factor is that all Greenlandic deposits tend to be found in dikes (lava-filled fractures in the bedrock) or extrusions where molten rock was able to flow out onto the surface. Another commonality is that all deposits are found in association with graphite -rich feldspar , likely contributing to
7452-470: The strongest oxidizers. It does not react with sulfuric acid , hydrochloric acid , chlorine or any alkalis . At elevated temperatures, carbon reacts with oxygen to form carbon oxides and will rob oxygen from metal oxides to leave the elemental metal. This exothermic reaction is used in the iron and steel industry to smelt iron and to control the carbon content of steel : Carbon reacts with sulfur to form carbon disulfide , and it reacts with steam in
7544-509: The structure of fullerenes. The buckyballs are fairly large molecules formed completely of carbon bonded trigonally, forming spheroids (the best-known and simplest is the soccerball-shaped C 60 buckminsterfullerene ). Carbon nanotubes (buckytubes) are structurally similar to buckyballs, except that each atom is bonded trigonally in a curved sheet that forms a hollow cylinder . Nanobuds were first reported in 2007 and are hybrid buckytube/buckyball materials (buckyballs are covalently bonded to
7636-524: The suffix -ic meaning "of" or "born from", differentiating it from meteorites . Telluric iron resembles meteoric iron , in that it contains both a significant amount of nickel and Widmanstatten structures . However, telluric iron typically contains only around 3% nickel, which is too low for meteorites, of which none have been found with less than 5%. There are two types of telluric iron: Both type 1 and type 2 contain comparable amounts of nickel and other impurities. The main difference between
7728-414: The systematic study and categorization of organic compounds. Chain length, shape and functional groups all affect the properties of organic molecules. In most stable compounds of carbon (and nearly all stable organic compounds), carbon obeys the octet rule and is tetravalent , meaning that a carbon atom forms a total of four covalent bonds (which may include double and triple bonds). Exceptions include
7820-460: The temperatures commonly encountered on Earth, enables this element to serve as a common element of all known life . It is the second most abundant element in the human body by mass (about 18.5%) after oxygen. The atoms of carbon can bond together in diverse ways, resulting in various allotropes of carbon . Well-known allotropes include graphite , diamond , amorphous carbon , and fullerenes . The physical properties of carbon vary widely with
7912-558: The time believed that no un- oxidized telluric iron existed, and few questioned Nordenskiöld's finding. Gustav Nauckhoff made an expedition to Greenland in 1871. Armed with dynamite and lifting equipment , his expedition collected three large samples of telluric iron, also believing them to be meteoric, per Nordenskiöld's examination, and brought them back to Europe for further study. These samples can be found currently in Sweden , Finland , and Denmark . A 25-ton block now rests outside of
8004-458: The total going to the atmosphere, sea, and land (such as peat bogs ) at almost 2,000 Gt. Carbon is a constituent (about 12% by mass) of the very large masses of carbonate rock ( limestone , dolomite , marble , and others). Coal is very rich in carbon ( anthracite contains 92–98%) and is the largest commercial source of mineral carbon, accounting for 4,000 gigatonnes or 80% of fossil fuel . As for individual carbon allotropes, graphite
8096-414: The two is the carbon content, which greatly affects the hardness, workability, and melting point of the metal. Telluric iron is metallic iron that formed within the Earth's mantle and crust. Although minor deposits of telluric iron have been found around the world, the west shores of Greenland hold the only known major deposits. However, these deposits may vary drastically in shape and composition, even in
8188-775: The unstable dicarbon monoxide (C 2 O), carbon trioxide (CO 3 ), cyclopentanepentone (C 5 O 5 ), cyclohexanehexone (C 6 O 6 ), and mellitic anhydride (C 12 O 9 ). However, mellitic anhydride is the triple acyl anhydride of mellitic acid; moreover, it contains a benzene ring. Thus, many chemists consider it to be organic. With reactive metals, such as tungsten , carbon forms either carbides (C ) or acetylides ( C 2 ) to form alloys with high melting points. These anions are also associated with methane and acetylene , both very weak acids. With an electronegativity of 2.5, carbon prefers to form covalent bonds . A few carbides are covalent lattices, like carborundum (SiC), which resembles diamond. Nevertheless, even
8280-419: The usual stone tools ... whereas the 9 pieces of basalt with the iron balls were evidently the material for the bone knives. This iron is soft and keeps well in the air, from which reason it is fit for use in the manner described by Ross. The rock in which the iron appears is a typical, large-grained felspar - basalt . The discovery has a double significance, firstly, because it is the first time we have seen
8372-402: The world, the only known major deposits exist in and nearby the area of Disko Bay , in Greenland . The material was found in the volcanic plains of basalt rock, and used by the local Inuit to make cutting edges for tools like knives and ulus . The Inuit were the only people to make practical use of telluric iron. In 1870, Adolf Erik Nordenskiöld discovered large boulders of iron near
8464-485: Was able to show that the iron was from terrestrial, or telluric, sources. In his report, Steenstrup added, This peculiar layer of basalt is filled from top to bottom with iron-grains of all sizes from a fraction of a millimeter to a length of 18 mm with a breadth of 14 mm, which is the greatest I have found. ... When polished, this iron shows beautiful Widmannstätten figures . ... Metallic nickel-iron with Widmannstätten figures has now been proved to be also
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