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120-433: The HP-75 had a single-line liquid crystal display , 48 KiB system ROM and 16 KiB RAM, a comparatively large keyboard (albeit without a separate numeric pad), a manually operated magnetic card reader (2×650 bytes per card), 4 ports for memory expansion (1 for RAM and 3 for ROM modules), and an HP-IL interface that could be used to connect printers, storage and electronic test equipment. The BASIC interpreter also acted as

240-440: A plane , e.g. graphene ; or three-dimensionally e.g. diamond , quartz , sodium chloride . The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding . Thus solid metals are not made of molecules. In glasses , which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of

360-454: A refresh operation. Active-matrix addressed displays look brighter and sharper than passive-matrix addressed displays of the same size, and generally have quicker response times, producing much better images. Sharp produces bistable reflective LCDs with a 1-bit SRAM cell per pixel that only requires small amounts of power to maintain an image. Segment LCDs can also have color by using Field Sequential Color (FSC LCD). This kind of displays have

480-626: A 14-inch, active-matrix, full-color, full-motion TFT-LCD. This led to Japan launching an LCD industry, which developed large-size LCDs, including TFT computer monitors and LCD televisions. Epson developed the 3LCD projection technology in the 1980s, and licensed it for use in projectors in 1988. Epson's VPJ-700, released in January 1989, was the world's first compact , full-color LCD projector . In 1990, under different titles, inventors conceived electro optical effects as alternatives to twisted nematic field effect LCDs (TN- and STN- LCDs). One approach

600-493: A Gen 8.5 mother glass, significantly reducing waste. The thickness of the mother glass also increases with each generation, so larger mother glass sizes are better suited for larger displays. An LCD module (LCM) is a ready-to-use LCD with a backlight. Thus, a factory that makes LCD modules does not necessarily make LCDs, it may only assemble them into the modules. LCD glass substrates are made by companies such as AGC Inc. , Corning Inc. , and Nippon Electric Glass . The origin and

720-572: A TN device in the voltage-on state is far less dependent on variations in the device thickness than that in the voltage-off state. Because of this, TN displays with low information content and no backlighting are usually operated between crossed polarizers such that they appear bright with no voltage (the eye is much more sensitive to variations in the dark state than the bright state). As most of 2010-era LCDs are used in television sets, monitors and smartphones, they have high-resolution matrix arrays of pixels to display arbitrary images using backlighting with

840-455: A blue polarizer, or birefringence which gives them their distinctive appearance. STN LCDs have to be continuously refreshed by alternating pulsed voltages of one polarity during one frame and pulses of opposite polarity during the next frame. Individual pixels are addressed by the corresponding row and column circuits. This type of display is called passive-matrix addressed , because the pixel must retain its state between refreshes without

960-545: A brighter backlight and consuming more power, making this type of display less desirable for notebook computers. Panasonic Himeji G8.5 was using an enhanced version of IPS, also LGD in Korea, then currently the world biggest LCD panel manufacture BOE in China is also IPS/FFS mode TV panel. Super-IPS was later introduced after in-plane switching with even better response times and color reproduction. Molecule A molecule

1080-565: A certain number of these atoms united by attraction to form a single molecule . In coordination with these concepts, in 1833 the French chemist Marc Antoine Auguste Gaudin presented a clear account of Avogadro's hypothesis, regarding atomic weights, by making use of "volume diagrams", which clearly show both semi-correct molecular geometries, such as a linear water molecule, and correct molecular formulas, such as H 2 O: In 1917, an unknown American undergraduate chemical engineer named Linus Pauling

1200-419: A dark background. When no image is displayed, different arrangements are used. For this purpose, TN LCDs are operated between parallel polarizers, whereas IPS LCDs feature crossed polarizers. In many applications IPS LCDs have replaced TN LCDs, particularly in smartphones . Both the liquid crystal material and the alignment layer material contain ionic compounds . If an electric field of one particular polarity

1320-414: A digital clock) are all examples of devices with these displays. They use the same basic technology, except that arbitrary images are made from a matrix of small pixels , while other displays have larger elements. LCDs can either be normally on (positive) or off (negative), depending on the polarizer arrangement. For example, a character positive LCD with a backlight has black lettering on a background that

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1440-399: A dimension of a few angstroms (Å) to several dozen Å, or around one billionth of a meter. Single molecules cannot usually be observed by light (as noted above), but small molecules and even the outlines of individual atoms may be traced in some circumstances by use of an atomic force microscope . Some of the largest molecules are macromolecules or supermolecules . The smallest molecule

1560-646: A few used plasma displays ) and the original Nintendo Game Boy until the mid-1990s, when color active-matrix became standard on all laptops. The commercially unsuccessful Macintosh Portable (released in 1989) was one of the first to use an active-matrix display (though still monochrome). Passive-matrix LCDs are still used in the 2010s for applications less demanding than laptop computers and TVs, such as inexpensive calculators. In particular, these are used on portable devices where less information content needs to be displayed, lowest power consumption (no backlight ) and low cost are desired or readability in direct sunlight

1680-460: A finely ground powdered pigment, with particles being just 40 nanometers across. The black resist is the first to be applied; this will create a black grid (known in the industry as a black matrix) that will separate red, green and blue subpixels from one another, increasing contrast ratios and preventing light from leaking from one subpixel onto other surrounding subpixels. After the black resist has been dried in an oven and exposed to UV light through

1800-415: A glass substrate to form the cell circuitry to operate the panel. It is usually not possible to use soldering techniques to directly connect the panel to a separate copper-etched circuit board. Instead, interfacing is accomplished using anisotropic conductive film or, for lower densities, elastomeric connectors . Monochrome and later color passive-matrix LCDs were standard in most early laptops (although

1920-435: A graphical type of formula called a structural formula may be needed. Structural formulas may in turn be represented with a one-dimensional chemical name, but such chemical nomenclature requires many words and terms which are not part of chemical formulas. Molecules have fixed equilibrium geometries—bond lengths and angles— about which they continuously oscillate through vibrational and rotational motions. A pure substance

2040-514: A grid with vertical wires across the whole screen on one side of the screen and horizontal wires across the whole screen on the other side of the screen. To this grid each pixel has a positive connection on one side and a negative connection on the other side. So the total amount of wires needed for a 1080p display is 3 x 1920 going vertically and 1080 going horizontally for a total of 6840 wires horizontally and vertically. That's three for red, green and blue and 1920 columns of pixels for each color for

2160-412: A high speed passive segment LCD panel with an RGB backlight. The backlight quickly changes color, making it appear white to the naked eye. The LCD panel is synchronized with the backlight. For example, to make a segment appear red, the segment is only turned ON when the backlight is red, and to make a segment appear magenta, the segment is turned ON when the backlight is blue, and it continues to be ON while

2280-449: A layer of molecules aligned between two transparent electrodes , often made of indium tin oxide (ITO) and two polarizing filters (parallel and perpendicular polarizers), the axes of transmission of which are (in most of the cases) perpendicular to each other. Without the liquid crystal between the polarizing filters, light passing through the first filter would be blocked by the second (crossed) polarizer. Before an electric field

2400-616: A leading position in the wristwatch market, like Seiko and its first 6-digit TN-LCD quartz wristwatch, and Casio 's 'Casiotron'. Color LCDs based on Guest-Host interaction were invented by a team at RCA in 1968. A particular type of such a color LCD was developed by Japan's Sharp Corporation in the 1970s, receiving patents for their inventions, such as a patent by Shinji Kato and Takaaki Miyazaki in May 1975, and then improved by Fumiaki Funada and Masataka Matsuura in December 1975. TFT LCDs similar to

2520-465: A matrix consisting of electrically connected rows on one side of the LC layer and columns on the other side, which makes it possible to address each pixel at the intersections. The general method of matrix addressing consists of sequentially addressing one side of the matrix, for example by selecting the rows one-by-one and applying the picture information on the other side at the columns row-by-row. For details on

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2640-409: A mini-LED backlight and quantum dot sheets. LCDs with quantum dot enhancement film or quantum dot color filters were introduced from 2015 to 2018. Quantum dots receive blue light from a backlight and convert it to light that allows LCD panels to offer better color reproduction. Quantum dot color filters are manufactured using photoresists containing quantum dots instead of colored pigments, and

2760-473: A photomask, the unexposed areas are washed away, creating a black grid. Then the same process is repeated with the remaining resists. This fills the holes in the black grid with their corresponding colored resists. Black matrices made in the 1980s and 1990s when most color LCD production was for laptop computers, are made of Chromium due to its high opacity, but due to environmental concerns, manufacturers shifted to black colored photoresist with carbon pigment as

2880-449: A plane parallel to the glass substrates. In this method, the electrical field is applied through opposite electrodes on the same glass substrate, so that the liquid crystals can be reoriented (switched) essentially in the same plane, although fringe fields inhibit a homogeneous reorientation. This requires two transistors for each pixel instead of the single transistor needed for a standard thin-film transistor (TFT) display. The IPS technology

3000-454: A primitive operating system, providing file handling capabilities for program storage using RAM , cards, or cassettes/diskettes (via HP-IL). Other features included a text editor as well as an appointment reminder with alarms, similar to functions of modern PDAs . The HP-75D (1984–1986) added a port for a bar code wand, often used for inventory control tasks. The HP-75 was comparatively expensive with an MSRP of $ 995 ($ 2,014 in 2005) for

3120-464: A reflective display. The common implementations of LCD backlight technology are: Today, most LCD screens are being designed with an LED backlight instead of the traditional CCFL backlight, while that backlight is dynamically controlled with the video information (dynamic backlight control). The combination with the dynamic backlight control, invented by Philips researchers Douglas Stanton, Martinus Stroomer and Adrianus de Vaan, simultaneously increases

3240-401: A regular arrangement of molecules (as in a crystal). Microwave spectroscopy commonly measures changes in the rotation of molecules, and can be used to identify molecules in outer space. Infrared spectroscopy measures the vibration of molecules, including stretching, bending or twisting motions. It is commonly used to identify the kinds of bonds or functional groups in molecules. Changes in

3360-523: A sharper threshold of the contrast-vs-voltage characteristic than the original TN LCDs. This is important, because pixels are subjected to partial voltages even while not selected. Crosstalk between activated and non-activated pixels has to be handled properly by keeping the RMS voltage of non-activated pixels below the threshold voltage as discovered by Peter J. Wild in 1972, while activated pixels are subjected to voltages above threshold (the voltages according to

3480-480: A significant role in this growth, including as a result of their investments in LCD manufacturers via state-owned investment companies. China had previously imported significant amounts of LCDs, and the growth of its LCD industry decreased prices for other consumer products that use LCDs and led to growth in other sectors like mobile phones. LCDs do not produce light on their own, so they require external light to produce

3600-401: A single mother glass size and as a result, different manufacturers would use slightly different glass sizes for the same generation. Some manufacturers have adopted Gen 8.6 mother glass sheets which are only slightly larger than Gen 8.5, allowing for more 50- and 58-inch LCDs to be made per mother glass, specially 58-inch LCDs, in which case 6 can be produced on a Gen 8.6 mother glass vs only 3 on

3720-641: A total of 5760 wires going vertically and 1080 rows of wires going horizontally. For a panel that is 28.8 inches (73 centimeters) wide, that means a wire density of 200 wires per inch along the horizontal edge. The LCD panel is powered by LCD drivers that are carefully matched up with the edge of the LCD panel at the factory level. The drivers may be installed using several methods, the most common of which are COG (Chip-On-Glass) and TAB ( Tape-automated bonding ) These same principles apply also for smartphone screens that are much smaller than TV screens. LCD panels typically use thinly-coated metallic conductive pathways on

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3840-531: A video speed-drive scheme that solved the slow response time of STN-LCDs, enabling high-resolution, high-quality, and smooth-moving video images on STN-LCDs. In 1985, Philips inventors Theodorus Welzen and Adrianus de Vaan solved the problem of driving high-resolution STN-LCDs using low-voltage (CMOS-based) drive electronics, allowing the application of high-quality (high resolution and video speed) LCD panels in battery-operated portable products like notebook computers and mobile phones. In 1985, Philips acquired 100% of

3960-416: A visible image. In a transmissive type of LCD, the light source is provided at the back of the glass stack and is called a backlight . Active-matrix LCDs are almost always backlit. Passive LCDs may be backlit but many are reflective as they use a reflective surface or film at the back of the glass stack to utilize ambient light. Transflective LCDs combine the features of a backlit transmissive display and

4080-486: A voltage to a DSM display switches the initially clear transparent liquid crystal layer into a milky turbid state. DSM displays could be operated in transmissive and in reflective mode but they required a considerable current to flow for their operation. George H. Heilmeier was inducted in the National Inventors Hall of Fame and credited with the invention of LCDs. Heilmeier's work is an IEEE Milestone . In

4200-402: Is a chemical bond that involves the sharing of electron pairs between atoms. These electron pairs are termed shared pairs or bonding pairs , and the stable balance of attractive and repulsive forces between atoms, when they share electrons, is termed covalent bonding . Ionic bonding is a type of chemical bond that involves the electrostatic attraction between oppositely charged ions, and

4320-477: Is a group of two or more atoms that are held together by attractive forces known as chemical bonds ; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics , organic chemistry , and biochemistry , the distinction from ions is dropped and molecule is often used when referring to polyatomic ions . A molecule may be homonuclear , that is, it consists of atoms of one chemical element , e.g. two atoms in

4440-455: Is a very simple type of chemical formula. It is the simplest integer ratio of the chemical elements that constitute it. For example, water is always composed of a 2:1 ratio of hydrogen to oxygen atoms, and ethanol (ethyl alcohol) is always composed of carbon, hydrogen, and oxygen in a 2:6:1 ratio. However, this does not determine the kind of molecule uniquely – dimethyl ether has the same ratios as ethanol, for instance. Molecules with

4560-663: Is applied for a long period of time, this ionic material is attracted to the surfaces and degrades the device performance. This is avoided either by applying an alternating current or by reversing the polarity of the electric field as the device is addressed (the response of the liquid crystal layer is identical, regardless of the polarity of the applied field). Displays for a small number of individual digits or fixed symbols (as in digital watches and pocket calculators ) can be implemented with independent electrodes for each segment. In contrast, full alphanumeric or variable graphics displays are usually implemented with pixels arranged as

4680-407: Is applied to a TN liquid crystal cell, polarized light passes through the 90-degrees twisted LC layer. In proportion to the voltage applied, the liquid crystals untwist changing the polarization and blocking the light's path. By properly adjusting the level of the voltage almost any gray level or transmission can be achieved. In-plane switching is an LCD technology that aligns the liquid crystals in

4800-422: Is applied, the orientation of the liquid-crystal molecules is determined by the alignment at the surfaces of electrodes. In a twisted nematic (TN) device, the surface alignment directions at the two electrodes are perpendicular to each other, and so the molecules arrange themselves in a helical structure, or twist. This induces the rotation of the polarization of the incident light, and the device appears gray. If

4920-472: Is based on an electro-hydrodynamic instability forming what are now called "Williams domains" inside the liquid crystal. Building on early MOSFETs , Paul K. Weimer at RCA developed the thin-film transistor (TFT) in 1962. It was a type of MOSFET distinct from the standard bulk MOSFET. In 1964, George H. Heilmeier , who was working at the RCA laboratories on the effect discovered by Richard Williams, achieved

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5040-435: Is composed of molecules with the same average geometrical structure. The chemical formula and the structure of a molecule are the two important factors that determine its properties, particularly its reactivity . Isomers share a chemical formula but normally have very different properties because of their different structures. Stereoisomers , a particular type of isomer, may have very similar physico-chemical properties and at

5160-479: Is derived from French molécule (1678), from Neo-Latin molecula , diminutive of Latin moles "mass, barrier". The word, which until the late 18th century was used only in Latin form, became popular after being used in works of philosophy by Descartes . The definition of the molecule has evolved as knowledge of the structure of molecules has increased. Earlier definitions were less precise, defining molecules as

5280-480: Is essential for the understanding of the chemical bond. The simplest of molecules is the hydrogen molecule-ion , H 2 , and the simplest of all the chemical bonds is the one-electron bond . H 2 is composed of two positively charged protons and one negatively charged electron , which means that the Schrödinger equation for the system can be solved more easily due to the lack of electron–electron repulsion. With

5400-463: Is needed. Displays having a passive-matrix structure use super-twisted nematic STN (invented by Brown Boveri Research Center, Baden, Switzerland, in 1983; scientific details were published ) or double-layer STN (DSTN) technology (the latter of which addresses a color-shifting problem with the former), and color-STN (CSTN), in which color is added by using an internal color filter. STN LCDs have been optimized for passive-matrix addressing. They exhibit

5520-556: Is the diatomic hydrogen (H 2 ), with a bond length of 0.74 Å. Effective molecular radius is the size a molecule displays in solution. The table of permselectivity for different substances contains examples. The chemical formula for a molecule uses one line of chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, and plus (+) and minus (−) signs. These are limited to one typographic line of symbols, which may include subscripts and superscripts. A compound's empirical formula

5640-842: Is the color of the backlight, and a character negative LCD has a black background with the letters being of the same color as the backlight. LCDs are used in a wide range of applications, including LCD televisions , computer monitors , instrument panels , aircraft cockpit displays , and indoor and outdoor signage. Small LCD screens are common in LCD projectors and portable consumer devices such as digital cameras , watches , calculators , and mobile telephones , including smartphones . LCD screens have replaced heavy, bulky and less energy-efficient cathode-ray tube (CRT) displays in nearly all applications. LCDs are not subject to screen burn-in like on CRTs. However, LCDs are still susceptible to image persistence . Each pixel of an LCD typically consists of

5760-617: Is the primary interaction occurring in ionic compounds . The ions are atoms that have lost one or more electrons (termed cations ) and atoms that have gained one or more electrons (termed anions ). This transfer of electrons is termed electrovalence in contrast to covalence . In the simplest case, the cation is a metal atom and the anion is a nonmetal atom, but these ions can be of a more complicated nature, e.g. molecular ions like NH 4 or SO 4 . At normal temperatures and pressures, ionic bonding mostly creates solids (or occasionally liquids) without separate identifiable molecules, but

5880-461: Is used in everything from televisions, computer monitors, and even wearable devices, especially almost all LCD smartphone panels are IPS/FFS mode. IPS displays belong to the LCD panel family screen types. The other two types are VA and TN. Before LG Enhanced IPS was introduced in 2001 by Hitachi as 17" monitor in Market, the additional transistors resulted in blocking more transmission area, thus requiring

6000-423: Is written to the display, the display may be cut from the power while retaining readable images. This has the advantage that such ebooks may be operated for long periods of time powered by only a small battery. High- resolution color displays, such as modern LCD computer monitors and televisions, use an active-matrix structure. A matrix of thin-film transistors (TFTs) is added to the electrodes in contact with

6120-514: The super-twisted nematic (STN) structure for passive matrix -addressed LCDs. H. Amstutz et al. were listed as inventors in the corresponding patent applications filed in Switzerland on July 7, 1983, and October 28, 1983. Patents were granted in Switzerland CH 665491, Europe EP 0131216, U.S. patent 4,634,229 and many more countries. In 1980, Brown Boveri started a 50/50 joint venture with

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6240-529: The Avogadro constant using three different methods, all involving liquid phase systems. First, he used a gamboge soap-like emulsion, second by doing experimental work on Brownian motion , and third by confirming Einstein's theory of particle rotation in the liquid phase. In 1927, the physicists Fritz London and Walter Heitler applied the new quantum mechanics to the deal with the saturable, nondynamic forces of attraction and repulsion, i.e., exchange forces, of

6360-540: The Engineering and Technology History Wiki . In 1888, Friedrich Reinitzer (1858–1927) discovered the liquid crystalline nature of cholesterol extracted from carrots (that is, two melting points and generation of colors) and published his findings. In 1904, Otto Lehmann published his work "Flüssige Kristalle" (Liquid Crystals). In 1911, Charles Mauguin first experimented with liquid crystals confined between plates in thin layers. In 1922, Georges Friedel described

6480-682: The Wayback Machine ) with Wolfgang Helfrich and Martin Schadt (then working for the Central Research Laboratories) listed as inventors. Hoffmann-La Roche licensed the invention to Swiss manufacturer Brown, Boveri & Cie , its joint venture partner at that time, which produced TN displays for wristwatches and other applications during the 1970s for the international markets including the Japanese electronics industry, which soon produced

6600-684: The oxygen molecule (O 2 ); or it may be heteronuclear , a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H 2 O). In the kinetic theory of gases , the term molecule is often used for any gaseous particle regardless of its composition. This relaxes the requirement that a molecule contains two or more atoms, since the noble gases are individual atoms. Atoms and complexes connected by non-covalent interactions , such as hydrogen bonds or ionic bonds , are typically not considered single molecules. Concepts similar to molecules have been discussed since ancient times, but modern investigation into

6720-496: The "Alt & Pleshko" drive scheme). Driving such STN displays according to the Alt & Pleshko drive scheme require very high line addressing voltages. Welzen and de Vaan invented an alternative drive scheme (a non "Alt & Pleshko" drive scheme) requiring much lower voltages, such that the STN display could be driven using low voltage CMOS technologies. White-on-blue LCDs are STN and can use

6840-494: The 75C or $ 1095 ($ 2,058 in 2005) for the 75D, making it less popular than the cheaper successor model, the HP-71B . The HP-75C has a KANGAROO printed on its PCB , as its codename (see link for picture). HP-75D codename's is MERLIN. BYTE praised the flexibility of the appointment scheduler, which the review noted could comprise part of a real-time control system because of its ability to execute BASIC programs. It concluded that

6960-480: The CRT-based sets, leading to a worldwide energy saving of 600 TWh (2017), equal to 10% of the electricity consumption of all households worldwide or equal to 2 times the energy production of all solar cells in the world. A standard television receiver screen, a modern LCD panel, has over six million pixels, and they are all individually powered by a wire network embedded in the screen. The fine wires, or pathways, form

7080-469: The Chemical Bond" in which he used quantum mechanics to calculate properties and structures of molecules, such as angles between bonds and rotation about bonds. On these concepts, Pauling developed hybridization theory to account for bonds in molecules such as CH 4 , in which four sp³ hybridised orbitals are overlapped by hydrogen 's 1s orbital, yielding four sigma (σ) bonds . The four bonds are of

7200-456: The Dutch Philips company, called Videlec. Philips had the required know-how to design and build integrated circuits for the control of large LCD panels. In addition, Philips had better access to markets for electronic components and intended to use LCDs in new product generations of hi-fi, video equipment and telephones. In 1984, Philips researchers Theodorus Welzen and Adrianus de Vaan invented

7320-409: The LC layer. Each pixel has its own dedicated transistor , allowing each column line to access one pixel. When a row line is selected, all of the column lines are connected to a row of pixels and voltages corresponding to the picture information are driven onto all of the column lines. The row line is then deactivated and the next row line is selected. All of the row lines are selected in sequence during

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7440-525: The LCD industry. These six companies were fined 1.3 billion dollars by the United States, 650 million Euro by the European Union, and 350 million RMB by China's National Development and Reform Commission . In 2007 the image quality of LCD televisions surpassed the image quality of cathode-ray-tube-based (CRT) TVs. In the fourth quarter of 2007, LCD televisions surpassed CRT TVs in worldwide sales for

7560-732: The Videlec AG company based in Switzerland. Afterwards, Philips moved the Videlec production lines to the Netherlands. Years later, Philips successfully produced and marketed complete modules (consisting of the LCD screen, microphone, speakers etc.) in high-volume production for the booming mobile phone industry. The first color LCD televisions were developed as handheld televisions in Japan. In 1980, Hattori Seiko 's R&D group began development on color LCD pocket televisions. In 1982, Seiko Epson released

7680-401: The addressing method of these bistable displays is rather complex, a reason why these displays did not make it to the market. That changed when in the 2010 "zero-power" (bistable) LCDs became available. Potentially, passive-matrix addressing can be used with devices if their write/erase characteristics are suitable, which was the case for ebooks which need to show still pictures only. After a page

7800-407: The applied voltage is large enough, the liquid crystal molecules in the center of the layer are almost completely untwisted and the polarization of the incident light is not rotated as it passes through the liquid crystal layer. This light will then be mainly polarized perpendicular to the second filter, and thus be blocked and the pixel will appear black. By controlling the voltage applied across

7920-441: The arrangements of electrons yield absorption or emission lines in ultraviolet, visible or near infrared light, and result in colour. Nuclear resonance spectroscopy measures the environment of particular nuclei in the molecule, and can be used to characterise the numbers of atoms in different positions in a molecule. The study of molecules by molecular physics and theoretical chemistry is largely based on quantum mechanics and

8040-410: The backlight becomes red, and it turns OFF when the backlight becomes green. To make a segment appear black, the segment is always turned ON. An FSC LCD divides a color image into 3 images (one Red, one Green and one Blue) and it displays them in order. Due to persistence of vision , the 3 monochromatic images appear as one color image. An FSC LCD needs an LCD panel with a refresh rate of 180 Hz, and

8160-622: The benefit of a steady electrical charge. As the number of pixels (and, correspondingly, columns and rows) increases, this type of display becomes less feasible. Slow response times and poor contrast are typical of passive-matrix addressed LCDs with too many pixels and driven according to the "Alt & Pleshko" drive scheme. Welzen and de Vaan also invented a non RMS drive scheme enabling to drive STN displays with video rates and enabling to show smooth moving video images on an STN display. Citizen, among others, licensed these patents and successfully introduced several STN based LCD pocket televisions on

8280-408: The black matrix material. Another color-generation method used in early color PDAs and some calculators was done by varying the voltage in a Super-twisted nematic LCD, where the variable twist between tighter-spaced plates causes a varying double refraction birefringence , thus changing the hue. They were typically restricted to 3 colors per pixel: orange, green, and blue. The optical effect of

8400-679: The complex history of liquid-crystal displays from the perspective of an insider during the early days were described by Joseph A. Castellano in Liquid Gold: The Story of Liquid Crystal Displays and the Creation of an Industry . Another report on the origins and history of LCD from a different perspective until 1991 has been published by Hiroshi Kawamoto, available at the IEEE History Center. A description of Swiss contributions to LCD developments, written by Peter J. Wild , can be found at

8520-505: The computer "is a well-integrated and powerful machine ... if you are interested in ... a very portable computer with powerful real-time scheduling capabilities, you should look closely at the HP-75". This computer hardware article is a stub . You can help Misplaced Pages by expanding it . Liquid crystal display A liquid-crystal display ( LCD ) is a flat-panel display or other electronically modulated optical device that uses

8640-484: The development of fast digital computers, approximate solutions for more complicated molecules became possible and are one of the main aspects of computational chemistry . When trying to define rigorously whether an arrangement of atoms is sufficiently stable to be considered a molecule, IUPAC suggests that it "must correspond to a depression on the potential energy surface that is deep enough to confine at least one vibrational state". This definition does not depend on

8760-453: The dominant LCD designs through 2006. In the late 1990s, the LCD industry began shifting away from Japan, towards South Korea and Taiwan , and later on towards China. In this period, Taiwanese, Japanese, and Korean manufacturers were the dominant firms in LCD manufacturing. From 2001 to 2006, Samsung and five other major companies held 53 meetings in Taiwan and South Korea to fix prices in

8880-412: The driving circuitry from the borders of the display to in between the pixels, allowing for narrow bezels. In 2016, Panasonic developed IPS LCDs with a contrast ratio of 1,000,000:1, rivaling OLEDs. This technology was later put into mass production as dual layer, dual panel or LMCL (Light Modulating Cell Layer) LCDs. The technology uses 2 liquid crystal layers instead of one, and may be used along with

9000-413: The dynamic range of the display system (also marketed as HDR , high dynamic range television or FLAD , full-area local area dimming ). The LCD backlight systems are made highly efficient by applying optical films such as prismatic structure (prism sheet) to gain the light into the desired viewer directions and reflective polarizing films that recycle the polarized light that was formerly absorbed by

9120-577: The first LCD television, the Epson TV Watch, a wristwatch equipped with a small active-matrix LCD television. Sharp Corporation introduced dot matrix TN-LCD in 1983. In 1984, Epson released the ET-10, the first full-color, pocket LCD television. The same year, Citizen Watch , introduced the Citizen Pocket TV, a 2.7-inch color LCD TV, with the first commercial TFT LCD . In 1988, Sharp demonstrated

9240-454: The first digital quartz wristwatches with TN-LCDs and numerous other products. James Fergason , while working with Sardari Arora and Alfred Saupe at Kent State University Liquid Crystal Institute , filed an identical patent in the United States on April 22, 1971. In 1971, the company of Fergason, ILIXCO (now LXD Incorporated ), produced LCDs based on the TN-effect, which soon superseded

9360-511: The first flat active-matrix liquid-crystal display (AM LCD) in 1974, and then Brody coined the term "active matrix" in 1975. In 1972 North American Rockwell Microelectronics Corp introduced the use of DSM LCDs for calculators for marketing by Lloyds Electronics Inc, though these required an internal light source for illumination. Sharp Corporation followed with DSM LCDs for pocket-sized calculators in 1973 and then mass-produced TN LCDs for watches in 1975. Other Japanese companies soon took

9480-413: The first major English language publication Molecular Structure and Properties of Liquid Crystals was published by Dr. George W. Gray . In 1962, Richard Williams of RCA found that liquid crystals had some interesting electro-optic characteristics and he realized an electro-optical effect by generating stripe patterns in a thin layer of liquid crystal material by the application of a voltage. This effect

9600-409: The first polarizer of the LCD (invented by Philips researchers Adrianus de Vaan and Paulus Schaareman), generally achieved using so called DBEF films manufactured and supplied by 3M. Improved versions of the prism sheet have a wavy rather than a prismatic structure, and introduce waves laterally into the structure of the sheet while also varying the height of the waves, directing even more light towards

9720-472: The first time. LCD TVs were projected to account 50% of the 200 million TVs to be shipped globally in 2006, according to Displaybank . In October 2011, Toshiba announced 2560 × 1600 pixels on a 6.1-inch (155 mm) LCD panel, suitable for use in a tablet computer , especially for Chinese character display. The 2010s also saw the wide adoption of TGP (Tracking Gate-line in Pixel), which moves

9840-464: The heavenly bodies. The viewpoint of Leucippus and Empedocles, along with the aether, was accepted by Aristotle and passed to medieval and renaissance Europe. In a more concrete manner, however, the concept of aggregates or units of bonded atoms, i.e. "molecules", traces its origins to Robert Boyle 's 1661 hypothesis, in his famous treatise The Sceptical Chymist , that matter is composed of clusters of particles and that chemical change results from

9960-581: The hydrogen molecule. Their valence bond treatment of this problem, in their joint paper, was a landmark in that it brought chemistry under quantum mechanics. Their work was an influence on Pauling, who had just received his doctorate and visited Heitler and London in Zürich on a Guggenheim Fellowship . Subsequently, in 1931, building on the work of Heitler and London and on theories found in Lewis' famous article, Pauling published his ground-breaking article "The Nature of

10080-475: The inventors worked, assigns these patents to Merck KGaA, Darmstadt, a supplier of LC substances. In 1992, shortly thereafter, engineers at Hitachi work out various practical details of the IPS technology to interconnect the thin-film transistor array as a matrix and to avoid undesirable stray fields in between pixels. The first wall-mountable LCD TV was introduced by Sharp Corporation in 1992. Hitachi also improved

10200-574: The late 1960s, pioneering work on liquid crystals was undertaken by the UK's Royal Radar Establishment at Malvern , England. The team at RRE supported ongoing work by George William Gray and his team at the University of Hull who ultimately discovered the cyanobiphenyl liquid crystals, which had correct stability and temperature properties for application in LCDs. The idea of a TFT -based liquid-crystal display (LCD)

10320-735: The laws governing their structure and properties. In practice, however, this distinction is vague. In molecular sciences, a molecule consists of a stable system ( bound state ) composed of two or more atoms. Polyatomic ions may sometimes be usefully thought of as electrically charged molecules. The term unstable molecule is used for very reactive species, i.e., short-lived assemblies ( resonances ) of electrons and nuclei , such as radicals , molecular ions , Rydberg molecules , transition states , van der Waals complexes , or systems of colliding atoms as in Bose–Einstein condensate . Molecules as components of matter are common. They also make up most of

10440-705: The light of the backlight uniformly, while a mirror is placed behind the light guide plate to direct all light forwards. The prism sheet with its diffuser sheets are placed on top of the light guide plate. The DBEF polarizers consist of a large stack of uniaxial oriented birefringent films that reflect the former absorbed polarization mode of the light. DBEF polarizers using uniaxial oriented polymerized liquid crystals (birefringent polymers or birefringent glue) were invented in 1989 by Philips researchers Dirk Broer, Adrianus de Vaan and Joerg Brambring. The combination of such reflective polarizers, and LED dynamic backlight control make today's LCD televisions far more efficient than

10560-467: The light-modulating properties of liquid crystals combined with polarizers to display information. Liquid crystals do not emit light directly but instead use a backlight or reflector to produce images in color or monochrome . LCDs are available to display arbitrary images (as in a general-purpose computer display) or fixed images with low information content, which can be displayed or hidden: preset words, digits, and seven-segment displays (as in

10680-451: The liquid crystal layer in each pixel, light can be allowed to pass through in varying amounts thus constituting different levels of gray. The chemical formula of the liquid crystals used in LCDs may vary. Formulas may be patented. An example is a mixture of 2-(4-alkoxyphenyl)-5-alkylpyrimidine with cyanobiphenyl, patented by Merck and Sharp Corporation . The patent that covered that specific mixture has expired. Most color LCD systems use

10800-468: The market. Bistable LCDs do not require continuous refreshing. Rewriting is only required for picture information changes. In 1984 HA van Sprang and AJSM de Vaan invented an STN type display that could be operated in a bistable mode, enabling extremely high resolution images up to 4000 lines or more using only low voltages. Since a pixel may be either in an on-state or in an off state at the moment new information needs to be written to that particular pixel,

10920-404: The mass of a neutral carbon-12 ( C isotope ) atom. For network solids , the term formula unit is used in stoichiometric calculations. For molecules with a complicated 3-dimensional structure, especially involving atoms bonded to four different substituents, a simple molecular formula or even semi-structural chemical formula may not be enough to completely specify the molecule. In this case,

11040-448: The minerals that make up the substance of the Earth, sand, clay, pebbles, rocks, boulders, bedrock , the molten interior , and the core of the Earth . All of these contain many chemical bonds, but are not made of identifiable molecules. No typical molecule can be defined for salts nor for covalent crystals , although these are often composed of repeating unit cells that extend either in

11160-537: The nature of molecules and their bonds began in the 17th century. Refined over time by scientists such as Robert Boyle , Amedeo Avogadro , Jean Perrin , and Linus Pauling , the study of molecules is today known as molecular physics or molecular chemistry. According to Merriam-Webster and the Online Etymology Dictionary , the word "molecule" derives from the Latin " moles " or small unit of mass. The word

11280-440: The nature of the interaction between the atoms, but only on the strength of the interaction. In fact, it includes weakly bound species that would not traditionally be considered molecules, such as the helium dimer , He 2 , which has one vibrational bound state and is so loosely bound that it is only likely to be observed at very low temperatures. Whether or not an arrangement of atoms is sufficiently stable to be considered

11400-517: The oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids of which they are composed, the nucleic acids (DNA and RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals are generally ionic compounds, thus they are not molecules, e.g. iron sulfate. However, the majority of familiar solid substances on Earth are made partly or completely of crystals or ionic compounds, which are not made of molecules. These include all of

11520-476: The poor-quality DSM types due to improvements of lower operating voltages and lower power consumption. Tetsuro Hama and Izuhiko Nishimura of Seiko received a US patent dated February 1971, for an electronic wristwatch incorporating a TN-LCD. In 1972, the first wristwatch with TN-LCD was launched on the market: The Gruen Teletime which was a four digit display watch. In 1972, the concept of the active-matrix thin-film transistor (TFT) liquid-crystal display panel

11640-557: The prototypes developed by a Westinghouse team in 1972 were patented in 1976 by a team at Sharp consisting of Fumiaki Funada, Masataka Matsuura, and Tomio Wada, then improved in 1977 by a Sharp team consisting of Kohei Kishi, Hirosaku Nonomura, Keiichiro Shimizu, and Tomio Wada. However, these TFT-LCDs were not yet ready for use in products, as problems with the materials for the TFTs were not yet solved. In 1983, researchers at Brown, Boveri & Cie (BBC) Research Center, Switzerland , invented

11760-456: The quantum dots can have a special structure to improve their application onto the color filter. Quantum dot color filters offer superior light transmission over quantum dot enhancement films. In the 2020s, China became the largest manufacturer of LCDs and Chinese firms had a 40% share of the global market. Chinese firms that developed into world industry leaders included BOE Technology , TCL-CSOT, TIANMA, and Visionox. Local governments had

11880-411: The rearrangement of the clusters. Boyle argued that matter's basic elements consisted of various sorts and sizes of particles, called "corpuscles", which were capable of arranging themselves into groups. In 1789, William Higgins published views on what he called combinations of "ultimate" particles, which foreshadowed the concept of valency bonds . If, for example, according to Higgins, the force between

12000-546: The regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals. Molecules are generally held together by covalent bonding . Several non-metallic elements exist only as molecules in the environment either in compounds or as homonuclear molecules, not as free atoms: for example, hydrogen. While some people say a metallic crystal can be considered a single giant molecule held together by metallic bonding , others point out that metals behave very differently than molecules. A covalent bond

12120-535: The response time is reduced to just 5 milliseconds when compared with normal STN LCD panels which have a response time of 16 milliseconds. FSC LCDs contain a Chip-On-Glass driver IC can also be used with a capacitive touchscreen. This technique can also be applied in displays meant to show images, as it can offer higher light transmission and thus potential for reduced power consumption in the backlight due to omission of color filters in LCDs. Samsung introduced UFB (Ultra Fine & Bright) displays back in 2002, utilized

12240-405: The same atoms in different arrangements are called isomers . Also carbohydrates, for example, have the same ratio (carbon:hydrogen:oxygen= 1:2:1) (and thus the same empirical formula) but different total numbers of atoms in the molecule. The molecular formula reflects the exact number of atoms that compose the molecule and so characterizes different molecules. However different isomers can have

12360-404: The same atomic composition while being different molecules. The empirical formula is often the same as the molecular formula but not always. For example, the molecule acetylene has molecular formula C 2 H 2 , but the simplest integer ratio of elements is CH. The molecular mass can be calculated from the chemical formula and is expressed in conventional atomic mass units equal to 1/12 of

12480-405: The same length and strength, which yields a molecular structure as shown below: The science of molecules is called molecular chemistry or molecular physics , depending on whether the focus is on chemistry or physics. Molecular chemistry deals with the laws governing the interaction between molecules that results in the formation and breakage of chemical bonds, while molecular physics deals with

12600-508: The same technique, with color filters used to generate red, green, and blue subpixels. The LCD color filters are made with a photolithography process on large glass sheets that are later glued with other glass sheets containing a thin-film transistor (TFT) array, spacers and liquid crystal, creating several color LCDs that are then cut from one another and laminated with polarizer sheets. Red, green, blue and black colored photoresists (resists) are used to create color filters. All resists contain

12720-568: The same time different biochemical activities. Molecular spectroscopy deals with the response ( spectrum ) of molecules interacting with probing signals of known energy (or frequency , according to the Planck relation ). Molecules have quantized energy levels that can be analyzed by detecting the molecule's energy exchange through absorbance or emission . Spectroscopy does not generally refer to diffraction studies where particles such as neutrons , electrons, or high energy X-rays interact with

12840-413: The screen and reducing aliasing or moiré between the structure of the prism sheet and the subpixels of the LCD. A wavy structure is easier to mass-produce than a prismatic one using conventional diamond machine tools, which are used to make the rollers used to imprint the wavy structure into plastic sheets, thus producing prism sheets. A diffuser sheet is placed on both sides of the prism sheet to distribute

12960-517: The smallest particles of pure chemical substances that still retain their composition and chemical properties. This definition often breaks down since many substances in ordinary experience, such as rocks , salts , and metals , are composed of large crystalline networks of chemically bonded atoms or ions , but are not made of discrete molecules. The modern concept of molecules can be traced back towards pre-scientific and Greek philosophers such as Leucippus and Democritus who argued that all

13080-557: The structure and properties of liquid crystals and classified them in three types (nematics, smectics and cholesterics). In 1927, Vsevolod Frederiks devised the electrically switched light valve, called the Fréedericksz transition , the essential effect of all LCD technology. In 1936, the Marconi Wireless Telegraph company patented the first practical application of the technology, "The Liquid Crystal Light Valve" . In 1962,

13200-524: The super-birefringent effect. It has the luminance, color gamut, and most of the contrast of a TFT-LCD, but only consumes as much power as an STN display, according to Samsung. It was being used in a variety of Samsung cellular-telephone models produced until late 2006, when Samsung stopped producing UFB displays. UFB displays were also used in certain models of LG mobile phones. Twisted nematic displays contain liquid crystals that twist and untwist at varying degrees to allow light to pass through. When no voltage

13320-400: The switching of colors by field-induced realignment of dichroic dyes in a homeotropically oriented liquid crystal. Practical problems with this new electro-optical effect made Heilmeier continue to work on scattering effects in liquid crystals and finally the achievement of the first operational liquid-crystal display based on what he called the dynamic scattering mode (DSM). Application of

13440-652: The ultimate particle of oxygen and the ultimate particle of nitrogen were 6, then the strength of the force would be divided accordingly, and similarly for the other combinations of ultimate particles. Amedeo Avogadro created the word "molecule". His 1811 paper "Essay on Determining the Relative Masses of the Elementary Molecules of Bodies", he essentially states, i.e. according to Partington 's A Short History of Chemistry , that: The smallest particles of gases are not necessarily simple atoms, but are made up of

13560-409: The universe is composed of atoms and voids . Circa 450 BC Empedocles imagined fundamental elements ( fire ( [REDACTED] ), earth ( [REDACTED] ), air ( [REDACTED] ), and water ( [REDACTED] )) and "forces" of attraction and repulsion allowing the elements to interact. A fifth element, the incorruptible quintessence aether , was considered to be the fundamental building block of

13680-432: The vaporization/sublimation of such materials does produce separate molecules where electrons are still transferred fully enough for the bonds to be considered ionic rather than covalent. Most molecules are far too small to be seen with the naked eye, although molecules of many polymers can reach macroscopic sizes, including biopolymers such as DNA . Molecules commonly used as building blocks for organic synthesis have

13800-625: The various matrix addressing schemes see passive-matrix and active-matrix addressed LCDs . LCDs are manufactured in cleanrooms borrowing techniques from semiconductor manufacturing and using large sheets of glass whose size has increased over time. Several displays are manufactured at the same time, and then cut from the sheet of glass, also known as the mother glass or LCD glass substrate. The increase in size allows more displays or larger displays to be made, just like with increasing wafer sizes in semiconductor manufacturing. The glass sizes are as follows: Until Gen 8, manufacturers would not agree on

13920-499: The viewing angle dependence further by optimizing the shape of the electrodes ( Super IPS ). NEC and Hitachi become early manufacturers of active-matrix addressed LCDs based on the IPS technology. This is a milestone for implementing large-screen LCDs having acceptable visual performance for flat-panel computer monitors and television screens. In 1996, Samsung developed the optical patterning technique that enables multi-domain LCD. Multi-domain and In Plane Switching subsequently remain

14040-441: Was conceived by Bernard Lechner of RCA Laboratories in 1968. Lechner, F.J. Marlowe, E.O. Nester and J. Tults demonstrated the concept in 1968 with an 18x2 matrix dynamic scattering mode (DSM) LCD that used standard discrete MOSFETs . On December 4, 1970, the twisted nematic field effect (TN) in liquid crystals was filed for patent by Hoffmann-LaRoche in Switzerland, ( Swiss patent No. 532 261 Archived March 9, 2021, at

14160-516: Was learning the Dalton hook-and-eye bonding method , which was the mainstream description of bonds between atoms at the time. Pauling, however, was not satisfied with this method and looked to the newly emerging field of quantum physics for a new method. In 1926, French physicist Jean Perrin received the Nobel Prize in physics for proving, conclusively, the existence of molecules. He did this by calculating

14280-504: Was prototyped in the United States by T. Peter Brody 's team at Westinghouse , in Pittsburgh, Pennsylvania . In 1973, Brody, J. A. Asars and G. D. Dixon at Westinghouse Research Laboratories demonstrated the first thin-film-transistor liquid-crystal display (TFT LCD). As of 2013 , all modern high-resolution and high-quality electronic visual display devices use TFT-based active matrix displays. Brody and Fang-Chen Luo demonstrated

14400-547: Was to use interdigital electrodes on one glass substrate only to produce an electric field essentially parallel to the glass substrates. To take full advantage of the properties of this In Plane Switching (IPS) technology further work was needed. After thorough analysis, details of advantageous embodiments are filed in Germany by Guenter Baur et al. and patented in various countries. The Fraunhofer Institute ISE in Freiburg, where

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