Ems-Chemie is a Swiss corporate group based in Domat/Ems , in the canton of Graubünden , whose companies are grouped under "Ems-Chemie Holding". This is the only listed company belonging to the scope of consolidation and is listed on the SIX Swiss Exchange . On 31 December 2013, the stock market capitalization reached CHF 7.4 billion. The main shareholders are "Emesta Holding AG" with 60.82% and Miriam Blocher with 8.89%.
148-642: Ems-Chemie is represented in 22 countries and produces at 26 production sites in 16 countries, with the main location in Domat/Ems. In 2013, the Group's production focus was in Europe (Switzerland 46.2%, Germany 12.2%), followed by the USA (9.2%) and Asia ( China 7.3%, Japan 6.6%). The largest sales markets of the Group are Germany (21.9%), China (14.0%) and the USA (11.9%). The Ems Group
296-459: A catalyst . Laboratory synthesis of biopolymers, especially of proteins , is an area of intensive research. There are three main classes of biopolymers: polysaccharides , polypeptides , and polynucleotides . In living cells, they may be synthesized by enzyme-mediated processes, such as the formation of DNA catalyzed by DNA polymerase . The synthesis of proteins involves multiple enzyme-mediated processes to transcribe genetic information from
444-728: A general armistice ended the fighting. In the German Revolution (November 1918), Wilhelm II and the ruling princes abdicated their positions, and Germany was declared a federal republic . Germany's new leadership signed the Treaty of Versailles in 1919, accepting defeat by the Allies . Germans perceived the treaty as humiliating, which was seen by historians as influential in the rise of Adolf Hitler . Germany lost around 13% of its European territory and ceded all of its colonial possessions in Africa and
592-441: A lower critical solution temperature phase transition (LCST), at which phase separation occurs with heating. In dilute solutions, the properties of the polymer are characterized by the interaction between the solvent and the polymer. In a good solvent, the polymer appears swollen and occupies a large volume. In this scenario, intermolecular forces between the solvent and monomer subunits dominate over intramolecular interactions. In
740-456: A sustainable energy supply, the debt brake for balanced budgets, measures to increase the fertility rate ( pronatalism ), and high-tech strategies for the transition of the German economy, summarised as Industry 4.0 . During the 2015 European migrant crisis , the country took in over a million refugees and migrants. Germany is the seventh-largest country in Europe . It borders Denmark to
888-555: A temperate climate, ranging from oceanic in the north and west to continental in the east and southeast. Winters range from the cold in the Southern Alps to cool and are generally overcast with limited precipitation, while summers can vary from hot and dry to cool and rainy. The northern regions have prevailing westerly winds that bring in moist air from the North Sea, moderating the temperature and increasing precipitation. Conversely,
1036-455: A NATO effort to provide security in that country after the ousting of the Taliban . In the 2005 elections , Angela Merkel became the first female chancellor. In 2009, the German government approved a €50 billion stimulus plan. Among the major German political projects of the early 21st century are the advancement of European integration , the energy transition ( Energiewende ) for
1184-498: A bad solvent or poor solvent, intramolecular forces dominate and the chain contracts. In the theta solvent , or the state of the polymer solution where the value of the second virial coefficient becomes 0, the intermolecular polymer-solvent repulsion balances exactly the intramolecular monomer-monomer attraction. Under the theta condition (also called the Flory condition), the polymer behaves like an ideal random coil . The transition between
1332-638: A centralised totalitarian state , withdrew from the League of Nations , and dramatically increased the country's rearmament . A government-sponsored programme for economic renewal focused on public works, the most famous of which was the Autobahn . In 1935, the regime withdrew from the Treaty of Versailles and introduced the Nuremberg Laws which targeted Jews and other minorities. Germany also reacquired control of
1480-520: A contract with delivery and pick up obligation of more than 98200 tons of fuel was made, with an end date of the 31. In march 1955, including production costs, (including provisions and repayment of state employment contributions). Through this, until the end of the Second World War 30% of the fuel requirements were covered in Switzerland. In addition, on 25 June 1942, a further contract was created for
1628-408: A degree of crystallinity approaching zero or one will tend to be transparent, while polymers with intermediate degrees of crystallinity will tend to be opaque due to light scattering by crystalline or glassy regions. For many polymers, crystallinity may also be associated with decreased transparency. The space occupied by a polymer molecule is generally expressed in terms of radius of gyration , which
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#17328845400571776-587: A deviation from a simple linear chain. A branched polymer molecule is composed of a main chain with one or more substituent side chains or branches. Types of branched polymers include star polymers , comb polymers , polymer brushes , dendronized polymers , ladder polymers , and dendrimers . There exist also two-dimensional polymers (2DP) which are composed of topologically planar repeat units. A polymer's architecture affects many of its physical properties including solution viscosity, melt viscosity, solubility in various solvents, glass-transition temperature and
1924-464: A flexible quality. Plasticizers are also put in some types of cling film to make the polymer more flexible. The attractive forces between polymer chains play a large part in determining the polymer's properties. Because polymer chains are so long, they have many such interchain interactions per molecule, amplifying the effect of these interactions on the polymer properties in comparison to attractions between conventional molecules. Different side groups on
2072-599: A framework laid out in the 1949 constitution known as the Grundgesetz (Basic Law). Amendments generally require a two-thirds majority of both the Bundestag and the Bundesrat ; the fundamental principles of the constitution, as expressed in the articles guaranteeing human dignity, the separation of powers, the federal structure, and the rule of law , are valid in perpetuity. The president , currently Frank-Walter Steinmeier ,
2220-647: A fuel additive for motor vehicles made from wood ethyl alcohol using the Scholler method in Domat. On 23 August 1940, the Swiss Federal Council approved the production of 20,000 hl of fuel and the company secured funds needed for production. This produced was added to gasoline and the high costs were subsidized by federal funding. Due to scarcity of raw materials as a result of the Second World War , on 24 March 1941,
2368-479: A given application, the properties of a polymer can be tuned or enhanced by combination with other materials, as in composites . Their application allows to save energy (lighter cars and planes, thermally insulated buildings), protect food and drinking water (packaging), save land and lower use of fertilizers (synthetic fibres), preserve other materials (coatings), protect and save lives (hygiene, medical applications). A representative, non-exhaustive list of applications
2516-529: A global power in industrial, scientific and technological sectors, it is both the world's third-largest exporter and importer . As a developed country , it offers social security , a universal health care system , and tuition-free university education . Germany is a member of the United Nations , Council of Europe , NATO and OECD , and a founding member of the European Union, G7 and G20 . It has
2664-402: A high surface quality and are also highly transparent so that the laser properties are dominated by the laser dye used to dope the polymer matrix. These type of lasers, that also belong to the class of organic lasers , are known to yield very narrow linewidths which is useful for spectroscopy and analytical applications. An important optical parameter in the polymer used in laser applications
2812-658: A joint responsibility of the international community. It was the world's second-biggest aid donor in 2019 after the United States. Germany's military, the Bundeswehr (Federal Defence), is organised into the Heer (Army and special forces KSK ), Marine (Navy), Luftwaffe (Air Force) and Cyber- und Informationsraum (Cyber and Information Domain Service) branches. In absolute terms, German military spending in 2023
2960-401: A polymer behaves as a continuous macroscopic material. They are classified as bulk properties, or intensive properties according to thermodynamics . The bulk properties of a polymer are those most often of end-use interest. These are the properties that dictate how the polymer actually behaves on a macroscopic scale. The tensile strength of a material quantifies how much elongating stress
3108-421: A polymer is its first and most important attribute. Polymer nomenclature is generally based upon the type of monomer residues comprising the polymer. A polymer which contains only a single type of repeat unit is known as a homopolymer , while a polymer containing two or more types of repeat units is known as a copolymer . A terpolymer is a copolymer which contains three types of repeat units. Polystyrene
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#17328845400573256-433: A polymeric material can be described at different length scales, from the sub-nm length scale up to the macroscopic one. There is in fact a hierarchy of structures, in which each stage provides the foundations for the next one. The starting point for the description of the structure of a polymer is the identity of its constituent monomers. Next, the microstructure essentially describes the arrangement of these monomers within
3404-536: A process called reptation in which each chain molecule is constrained by entanglements with neighboring chains to move within a virtual tube. The theory of reptation can explain polymer molecule dynamics and viscoelasticity . Depending on their chemical structures, polymers may be either semi-crystalline or amorphous. Semi-crystalline polymers can undergo crystallization and melting transitions , whereas amorphous polymers do not. In polymers, crystallization and melting do not suggest solid-liquid phase transitions, as in
3552-537: A provisional capital, to emphasise its stance that the two-state solution was temporary. West Germany was established as a federal parliamentary republic with a " social market economy ". Starting in 1948 West Germany became a major recipient of reconstruction aid under the American Marshall Plan . Konrad Adenauer was elected the first federal chancellor of Germany in 1949. The country enjoyed prolonged economic growth ( Wirtschaftswunder ) beginning in
3700-427: A result, they typically have lower melting temperatures than other polymers. When a polymer is dispersed or dissolved in a liquid, such as in commercial products like paints and glues, the chemical properties and molecular interactions influence how the solution flows and can even lead to self-assembly of the polymer into complex structures. When a polymer is applied as a coating, the chemical properties will influence
3848-615: A state, the East German authorities eased border restrictions, but this actually led to an acceleration of the Wende reform process culminating in the Two Plus Four Treaty under which Germany regained full sovereignty. This permitted German reunification on 3 October 1990, with the accession of the five re-established states of the former GDR. The fall of the Wall in 1989 became a symbol of
3996-456: A statistical distribution of chain lengths, the molecular weight is expressed in terms of weighted averages. The number-average molecular weight ( M n ) and weight-average molecular weight ( M w ) are most commonly reported. The ratio of these two values ( M w / M n ) is the dispersity ( Đ ), which is commonly used to express the width of the molecular weight distribution. The physical properties of polymer strongly depend on
4144-692: A symbol of the Cold War . Tensions between East and West Germany were reduced in the late 1960s by Chancellor Willy Brandt 's Ostpolitik . In 1989, Hungary decided to dismantle the Iron Curtain and open its border with Austria , causing the emigration of thousands of East Germans to West Germany via Hungary and Austria. This had devastating effects on the GDR, where regular mass demonstrations received increasing support. In an effort to help retain East Germany as
4292-537: A tendency to form amorphous and semicrystalline structures rather than crystals . Polymers are studied in the fields of polymer science (which includes polymer chemistry and polymer physics ), biophysics and materials science and engineering . Historically, products arising from the linkage of repeating units by covalent chemical bonds have been the primary focus of polymer science. An emerging important area now focuses on supramolecular polymers formed by non-covalent links. Polyisoprene of latex rubber
4440-432: A variety of different but structurally related monomer residues; for example, polynucleotides such as DNA are composed of four types of nucleotide subunits. A polymer containing ionizable subunits (e.g., pendant carboxylic groups ) is known as a polyelectrolyte or ionomer , when the fraction of ionizable units is large or small respectively. The microstructure of a polymer (sometimes called configuration) relates to
4588-405: A wide-meshed cross-linking between the "main chains". Close-meshed crosslinking, on the other hand, leads to thermosets . Cross-links and branches are shown as red dots in the figures. Highly branched polymers are amorphous and the molecules in the solid interact randomly. An important microstructural feature of a polymer is its architecture and shape, which relates to the way branch points lead to
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4736-814: Is a substance or material that consists of very large molecules, or macromolecules , that are constituted by many repeating subunits derived from one or more species of monomers . Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers . Their consequently large molecular mass , relative to small molecule compounds , produces unique physical properties including toughness , high elasticity , viscoelasticity , and
4884-479: Is a crucial physical parameter for polymer manufacturing, processing, and use. Below T g , molecular motions are frozen and polymers are brittle and glassy. Above T g , molecular motions are activated and polymers are rubbery and viscous. The glass-transition temperature may be engineered by altering the degree of branching or crosslinking in the polymer or by the addition of plasticizers . Whereas crystallization and melting are first-order phase transitions ,
5032-410: Is a long-chain n -alkane. There are also branched macromolecules with a main chain and side chains, in the case of polyethylene the side chains would be alkyl groups . In particular unbranched macromolecules can be in the solid state semi-crystalline, crystalline chain sections highlighted red in the figure below. While branched and unbranched polymers are usually thermoplastics, many elastomers have
5180-400: Is also commonly present in polymer backbones, such as those of polyethylene glycol , polysaccharides (in glycosidic bonds ), and DNA (in phosphodiester bonds ). Polymerization is the process of combining many small molecules known as monomers into a covalently bonded chain or network. During the polymerization process, some chemical groups may be lost from each monomer. This happens in
5328-512: Is an average distance from the center of mass of the chain to the chain itself. Alternatively, it may be expressed in terms of pervaded volume , which is the volume spanned by the polymer chain and scales with the cube of the radius of gyration. The simplest theoretical models for polymers in the molten, amorphous state are ideal chains . Polymer properties depend of their structure and they are divided into classes according to their physical bases. Many physical and chemical properties describe how
5476-481: Is an example of a natural polymer, and the polystyrene of styrofoam is an example of a synthetic polymer. In biological contexts, essentially all biological macromolecules —i.e., proteins (polyamides), nucleic acids (polynucleotides), and polysaccharides —are purely polymeric, or are composed in large part of polymeric components. The term "polymer" derives from Greek πολύς (polus) 'many, much' and μέρος (meros) 'part'. The term
5624-428: Is composed only of styrene -based repeat units, and is classified as a homopolymer. Polyethylene terephthalate , even though produced from two different monomers ( ethylene glycol and terephthalic acid ), is usually regarded as a homopolymer because only one type of repeat unit is formed. Ethylene-vinyl acetate contains more than one variety of repeat unit and is a copolymer. Some biological polymers are composed of
5772-409: Is defined, for small strains , as the ratio of rate of change of stress to strain. Like tensile strength, this is highly relevant in polymer applications involving the physical properties of polymers, such as rubber bands. The modulus is strongly dependent on temperature. Viscoelasticity describes a complex time-dependent elastic response, which will exhibit hysteresis in the stress-strain curve when
5920-637: Is devoted to agriculture, while 30% is forested and 14% is covered by settlements or infrastructure. Plants and animals include those generally common to Central Europe. According to the National Forest Inventory, beeches , oaks , and other deciduous trees constitute just over 40% of the forests; roughly 60% are conifers , particularly spruce and pine . There are many species of ferns , flowers , fungi , and mosses . Wild animals include roe deer , wild boar , mouflon (a subspecies of wild sheep), fox , badger , hare , and small numbers of
6068-599: Is largely autonomous in regard to its internal organisation. As of 2017 , Germany is divided into 401 districts ( Kreise ) at a municipal level; these consist of 294 rural districts and 107 urban districts . Germany has a civil law system based on Roman law with some references to Germanic law . The Bundesverfassungsgericht (Federal Constitutional Court) is the German Supreme Court responsible for constitutional matters, with power of judicial review . Germany's specialized supreme court system includes
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6216-409: Is structured in branches for high-performance Polymere (Ems-Grivory and Ems-Eftec), with sales of CHF 1.6 billion, and specialty chemicals (Ems-Griltec and Ems-Patvag), with sales of CHF 0.3 billion. Ems-Eftec offers equipment and materials for the automobile industry in the fields of gluing (body parts), densities (welding seams), vapors (vibration of the sheet metal) and protection ( plastisols for
6364-627: Is the head of state and invested primarily with representative responsibilities and powers. He is elected by the Bundesversammlung (federal convention), an institution consisting of the members of the Bundestag and an equal number of state delegates. The second-highest official in the German order of precedence is the Bundestagspräsident ( President of the Bundestag ), who is elected by
6512-435: Is the change in refractive index with temperature also known as dn/dT. For the polymers mentioned here the (dn/dT) ~ −1.4 × 10 in units of K in the 297 ≤ T ≤ 337 K range. Most conventional polymers such as polyethylene are electrical insulators , but the development of polymers containing π-conjugated bonds has led to a wealth of polymer-based semiconductors , such as polythiophenes . This has led to many applications in
6660-563: Is the main constituent of wood and paper. Hemoglycin (previously termed hemolithin ) is a space polymer that is the first polymer of amino acids found in meteorites . The list of synthetic polymers , roughly in order of worldwide demand, includes polyethylene , polypropylene , polystyrene , polyvinyl chloride , synthetic rubber , phenol formaldehyde resin (or Bakelite ), neoprene , nylon , polyacrylonitrile , PVB , silicone , and many more. More than 330 million tons of these polymers are made every year (2015). Most commonly,
6808-483: Is vested in the parliament consisting of the Bundestag (Federal Diet) and Bundesrat (Federal Council), which together form the legislative body. The Bundestag is elected through direct elections using the mixed-member proportional representation system. The members of the Bundesrat represent and are appointed by the governments of the sixteen federated states. The German political system operates under
6956-457: The Gründerzeit period following the unification of Germany, Bismarck's foreign policy as chancellor of Germany secured Germany's position as a great nation by forging alliances and avoiding war. However, under Wilhelm II , Germany took an imperialistic course, leading to friction with neighbouring countries. A dual alliance was created with the multinational realm of Austria-Hungary ;
7104-484: The Bundestag and responsible for overseeing the daily sessions of the body. The third-highest official and the head of government is the chancellor, who is appointed by the Bundespräsident after being elected by the party or coalition with the most seats in the Bundestag . The chancellor, currently Olaf Scholz , is the head of government and exercises executive power through his Cabinet . Since 1949,
7252-916: The Allies de jure abolished the German state and partitioned Berlin and Germany's remaining territory into four occupation zones. The western sectors, controlled by France, the United Kingdom , and the United States , were merged on 23 May 1949 to form the Federal Republic of Germany ( German : Bundesrepublik Deutschland ); on 7 October 1949, the Soviet Zone became the German Democratic Republic (GDR) ( German : Deutsche Demokratische Republik ; DDR). They were informally known as West Germany and East Germany. East Germany selected East Berlin as its capital, while West Germany chose Bonn as
7400-607: The Battle of Britain in the same year. In 1941, German troops invaded Yugoslavia , Greece and the Soviet Union . By 1942, Germany and its allies controlled most of continental Europe and North Africa , but following the Soviet victory at the Battle of Stalingrad , the Allied reconquest of North Africa and invasion of Italy in 1943, German forces suffered repeated military defeats. In 1944,
7548-765: The Battle of the Teutoburg Forest . The outcome of this battle dissuaded the Romans from their ambition of conquering Germania and is thus considered one of the most important events in European history . By 100 AD, when Tacitus wrote Germania , Germanic tribes had settled along the Rhine and the Danube (the Limes Germanicus ), occupying most of modern Germany. However, Baden-Württemberg , southern Bavaria , southern Hesse and
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#17328845400577696-578: The Berchtesgaden National Park . In addition, there are 17 Biosphere Reserves , and 105 nature parks . More than 400 zoos and animal parks operate in Germany. The Berlin Zoo , which opened in 1844, is the oldest in Germany, and claims the most comprehensive collection of species in the world. Germany is a federal , parliamentary , representative democratic republic. Federal legislative power
7844-678: The Black Death of 1348–1350. The Golden Bull issued in 1356 provided the constitutional structure of the Empire and codified the election of the emperor by seven prince-electors . Johannes Gutenberg introduced moveable-type printing to Europe, laying the basis for the democratization of knowledge . In 1517, Martin Luther incited the Protestant Reformation and his translation of the Bible began
7992-802: The Carolingian Empire in 800; it was divided in 843 . The eastern successor kingdom of East Francia stretched from the Rhine in the west to the Elbe river in the east and from the North Sea to the Alps. Subsequently, the Holy Roman Empire emerged from it. The Ottonian rulers (919–1024) consolidated several major duchies . In 996, Gregory V became the first German Pope, appointed by his cousin Otto III , whom he shortly after crowned Holy Roman Emperor. The Holy Roman Empire absorbed northern Italy and Burgundy under
8140-624: The Celtic , Iranian , Baltic , and Slavic tribes. Southern Germany was inhabited by Celtic-speaking peoples, who belonged to the wider La Tène culture . They were later assimilated by the Germanic conquerors. Under Augustus , the Roman Empire began to invade lands inhabited by the Germanic tribes, creating a short-lived Roman province of Germania between the Rhine and Elbe rivers. In 9 AD, three Roman legions were defeated by Arminius in
8288-1085: The Eurasian beaver . The blue cornflower was once a German national symbol . The 16 national parks in Germany include the Jasmund National Park , the Vorpommern Lagoon Area National Park , the Müritz National Park , the Wadden Sea National Parks , the Harz National Park , the Hainich National Park , the Black Forest National Park , the Saxon Switzerland National Park , the Bavarian Forest National Park and
8436-643: The Fall of Communism , the dissolution of the Soviet Union , German reunification and Die Wende ("the turning point"). United Germany was considered the enlarged continuation of West Germany so it retained its memberships in international organisations. Based on the Berlin/Bonn Act (1994), Berlin again became the capital of Germany, while Bonn obtained the unique status of a Bundesstadt (federal city) retaining some federal ministries. The relocation of
8584-678: The Imperial Estates . The legal system initiated by a series of Imperial Reforms (approximately 1495–1555) provided for considerable local autonomy and a stronger Imperial Diet . The House of Habsburg held the imperial crown from 1438 until the death of Charles VI in 1740. Following the War of the Austrian Succession and the Treaty of Aix-la-Chapelle , Charles VI's daughter Maria Theresa ruled as empress consort when her husband, Francis I , became emperor. From 1740, dualism between
8732-635: The Molotov–Ribbentrop Pact that divided Eastern Europe into German and Soviet spheres of influence. On 1 September 1939, Germany invaded Poland , beginning World War II in Europe ; Britain and France declared war on Germany on 3 September. In the spring of 1940, Germany conquered Denmark and Norway , the Netherlands , Belgium , Luxembourg , and France , forcing the French government to sign an armistice . The British repelled German air attacks in
8880-474: The Netherlands to the west. The nation's capital and most populous city is Berlin and its main financial centre is Frankfurt ; the largest urban area is the Ruhr . Settlement in the territory of modern Germany began in the Lower Paleolithic , with various tribes inhabiting it from the Neolithic onward, chiefly the Celts . Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity . A region named Germania
9028-399: The North German Confederation Treaty establishing the Prussia -led North German Confederation , which became the German Empire in 1871. After World War I and the German Revolution of 1918–1919 , the Empire was replaced by the Weimar Republic . The Nazi rise to power in 1933 led to the establishment of a totalitarian dictatorship , World War II , and the Holocaust . In 1949, after
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#17328845400579176-430: The Saarland in 1935, remilitarised the Rhineland in 1936, annexed Austria in 1938, annexed the Sudetenland in 1938 with the Munich Agreement , and in violation of the agreement occupied Czechoslovakia in March 1939. Kristallnacht (Night of Broken Glass) saw the burning of synagogues, the destruction of Jewish businesses, and mass arrests of Jewish people. In August 1939, Hitler's government negotiated
9324-423: The Salian emperors (1024–1125), although the emperors lost power through the Investiture controversy . Under the Hohenstaufen emperors (1138–1254), German princes encouraged German settlement to the south and east ( Ostsiedlung ). Members of the Hanseatic League , mostly north German towns, prospered in the expansion of trade. The population declined starting with the Great Famine in 1315, followed by
9472-543: The Swabian Jura , including 42,000-year-old flutes which are the oldest musical instruments ever found, the 40,000-year-old Lion Man , and the 41,000-year-old Venus of Hohle Fels . The Nebra sky disk , created during the European Bronze Age , has been attributed to a German site. The Germanic peoples are thought to have emerged from the Jastorf culture during the Nordic Bronze Age or early Iron Age . From southern Scandinavia and northern Germany , they expanded south, east, and west, coming into contact with
9620-450: The Triple Alliance of 1882 included Italy. Britain, France and Russia also concluded alliances to protect against Habsburg interference with Russian interests in the Balkans or German interference against France. At the Berlin Conference in 1884, Germany claimed several colonies including German East Africa , German South West Africa , Togoland , and Kamerun . Later, Germany further expanded its colonial empire to include holdings in
9768-417: The inquisitorial Federal Court of Justice for civil and criminal cases, along with the Federal Labour Court , Federal Social Court , Federal Fiscal Court , and Federal Administrative Court for other matters. Criminal and private laws are codified on the national level in the Strafgesetzbuch and the Bürgerliches Gesetzbuch respectively. The German penal system seeks the rehabilitation of
9916-428: The revolutions of 1848 in the German states , raising the German question. King Frederick William IV of Prussia was offered the title of emperor, but with a loss of power; he rejected the crown and the proposed constitution, a temporary setback for the movement. King William I appointed Otto von Bismarck as the Minister President of Prussia in 1862. Bismarck successfully concluded the war with Denmark in 1864 ;
10064-438: The third-highest number of UNESCO World Heritage Sites , 54 , of which 51 are cultural. The English word Germany derives from the Latin Germania , which came into use after Julius Caesar adopted it for the peoples east of the Rhine . The German term Deutschland , originally diutisciu land ('the German lands'), is derived from deutsch ( cf. Dutch ), descended from Old High German diutisc 'of
10212-411: The Austrian Habsburg monarchy and the Kingdom of Prussia dominated German history. In 1772, 1793, and 1795, Prussia and Austria, along with the Russian Empire , agreed to the Partitions of Poland . During the period of the French Revolutionary Wars , the Napoleonic era and the subsequent final meeting of the Imperial Diet , most of the Free Imperial Cities were annexed by dynastic territories;
10360-496: The DNA to RNA and subsequently translate that information to synthesize the specified protein from amino acids . The protein may be modified further following translation in order to provide appropriate structure and functioning. There are other biopolymers such as rubber , suberin , melanin , and lignin . Naturally occurring polymers such as cotton , starch , and rubber were familiar materials for years before synthetic polymers such as polyethene and perspex appeared on
10508-437: The German Bundestag , though they have never been part of the federal government. In the 2017 German federal election , the right-wing populist Alternative for Germany gained enough votes to attain representation in the parliament for the first time. Germany is a federation and comprises sixteen constituent states which are collectively referred to as Länder . Each state ( Land ) has its own constitution, and
10656-597: The German Democratic Republic was a communist Eastern Bloc state and member of the Warsaw Pact . After the fall of the communist led-government in East Germany, German reunification saw the former East German states join the Federal Republic of Germany on 3 October 1990 . Germany has been described as a great power with a strong economy ; it has the largest economy in Europe by nominal GDP . As
10804-538: The Holocaust , the German government persecuted minorities , including interning them in concentration and death camps across Europe. The regime systematically murdered 6 million Jews, at least 130,000 Romani , 275,000 disabled , thousands of Jehovah's Witnesses , thousands of homosexuals , and hundreds of thousands of political and religious opponents . Nazi policies in German-occupied countries resulted in
10952-617: The Pacific and China. The colonial government in South West Africa (present-day Namibia ), from 1904 to 1907, carried out the annihilation of the local Herero and Namaqua peoples as punishment for an uprising; this was the 20th century's first genocide . The assassination of Austria's crown prince on 28 June 1914 provided the pretext for Austria-Hungary to attack Serbia and trigger World War I . After four years of warfare, in which approximately two million German soldiers were killed,
11100-664: The Pacific. On 11 August 1919, President Friedrich Ebert signed the democratic Weimar Constitution . In the subsequent struggle for power, communists seized power in Bavaria , but conservative elements elsewhere attempted to overthrow the Republic in the Kapp Putsch . Street fighting in the major industrial centres, the occupation of the Ruhr by Belgian and French troops, and a period of hyperinflation followed. A debt restructuring plan and
11248-583: The Reichstag after a special election in 1932 and Hindenburg appointed Hitler as chancellor of Germany on 30 January 1933. After the Reichstag fire , a decree abrogated basic civil rights and the first Nazi concentration camp opened. On 23 March 1933, the Enabling Act gave Hitler unrestricted legislative power, overriding the constitution, and marked the beginning of Nazi Germany. His government established
11396-653: The Soviets pushed into Eastern Europe ; the Western allies landed in France and entered Germany despite a final German counteroffensive . Following Hitler's suicide during the Battle of Berlin , Germany signed the surrender document on 8 May 1945, ending World War II in Europe and Nazi Germany. Following the end of the war, surviving Nazi officials were tried for war crimes at the Nuremberg trials . In what later became known as
11544-441: The adhesion of the coating and how it interacts with external materials, such as superhydrophobic polymer coatings leading to water resistance. Overall the chemical properties of a polymer are important elements for designing new polymeric material products. Polymers such as PMMA and HEMA:MMA are used as matrices in the gain medium of solid-state dye lasers , also known as solid-state dye-doped polymer lasers. These polymers have
11692-434: The backbone in a variety of ways. A copolymer containing a controlled arrangement of monomers is called a sequence-controlled polymer . Alternating, periodic and block copolymers are simple examples of sequence-controlled polymers . Tacticity describes the relative stereochemistry of chiral centers in neighboring structural units within a macromolecule. There are three types of tacticity: isotactic (all substituents on
11840-437: The body). Ems-Grivory produces high-performance polymers that are delivered to customers as granules. From these high-performance polymers, the customers manufacture plastic parts, for automobile engineering, mobile phones, display windows, LEDs, packaging, baby bottles, eyeglasses, etc. Ems-Griltech produces hot-melt adhesives (for clothing, automobile electronics, packaging, composites) as well as separating and adhesive yarns for
11988-595: The canton of Graubünden. [9] When, on 13 May 1956, a national referendum decided against the further subsidization of «Hovag» for the years 1956 to 1960 in the amount of CHF 28.3 million, it stopped the production of ethyl alcohol. In 1947, "Inventa AG" was founded for research and patent utilization (later, process engineering and plant engineering were combined). In the mid-1950s "Inventa" built more than 300 plants (117 in China) for caprolactam, plastics and synthetic fibers. Before its acquisition by Christoph Blocher , Ems-Chemie
12136-421: The case of water or other molecular fluids. Instead, crystallization and melting refer to the phase transitions between two solid states ( i.e. , semi-crystalline and amorphous). Crystallization occurs above the glass-transition temperature ( T g ) and below the melting temperature ( T m ). All polymers (amorphous or semi-crystalline) go through glass transitions . The glass-transition temperature ( T g )
12284-522: The communist-controlled Socialist Unity Party of Germany , supported by the Stasi , an immense secret service. While East German propaganda was based on the benefits of the GDR's social programmes and the alleged threat of a West German invasion, many of its citizens looked to the West for freedom and prosperity. The Berlin Wall , built in 1961, prevented East German citizens from escaping to West Germany, becoming
12432-529: The company, he began to focus on engineering plastics and changed the name to "Ems Chemie Holding AG" and "Ems Chemie AG" in 1981. In 1983, he was commissioned, by the founding Oswald family, to find a buyer for the shares of Ems Chemie Holding AG. Blocher decided to take over the Oswald family's share package himself and therefore had the majority voting power at the company. In the following years Ems expanded and took over several other companies. In 1988 Ems focused on
12580-624: The company. At the beginning of 2003, the Blocher family decided that the "Ems" should remain a publicly traded shares company and introduced the unit names shares. On 10 December 2003, Christoph Blocher was elected to the Federal Council. Since a Federal Council member is not allowed to have any economic connections, he gave up all his positions at the "Ems" group and sold his majority stake in "Ems Chemie-Holding AG" to his four children on 30 December. On 1 January 2004, his daughter, Magdalena, took over
12728-469: The continuously linked backbone of a polymer used for the preparation of plastics consists mainly of carbon atoms. A simple example is polyethylene ('polythene' in British English), whose repeat unit or monomer is ethylene . Many other structures do exist; for example, elements such as silicon form familiar materials such as silicones, examples being Silly Putty and waterproof plumbing sealant. Oxygen
12876-547: The country's GDP, well below the NATO target of 2%. In 2024, Germany reported $ 97.7 billion to NATO, exceeding the NATO target of 2% at 2.12% of GDP. Polymer A polymer is a substance composed of macromolecules. A macromolecule is a molecule of high relative molecular mass, the structure of which essentially comprises the multiple repetition of units derived, actually or conceptually, from molecules of low relative molecular mass. A polymer ( / ˈ p ɒ l ɪ m ər / )
13024-462: The creation of a new currency in 1924 ushered in the Golden Twenties , an era of artistic innovation and liberal cultural life. The worldwide Great Depression hit Germany in 1929. Chancellor Heinrich Brüning 's government pursued a policy of fiscal austerity and deflation which caused unemployment of nearly 30% by 1932. The Nazi Party led by Adolf Hitler became the largest party in
13172-466: The creation of a more unified European political, economic and security apparatus. The governments of Germany and the United States are close political allies . Cultural ties and economic interests have crafted a bond between the two countries resulting in Atlanticism . After 1990, Germany and Russia worked together to establish a "strategic partnership" in which energy development became one of
13320-536: The criminal and the protection of the public. With the exceptions of petty crimes, tried by a single professional judge, and of serious political crimes, all charges are adjudicated by mixed tribunals where lay judges ( Schöffen ) and professional judges preside together. As of 2016, Germany's murder rate stood at a low of 1.18 murders per 100,000. In 2018, the overall crime rate fell to its lowest since 1992. Same-sex marriage has been legal in Germany since 2017, and LGBT rights are generally protected in
13468-461: The deaths of an estimated 2.7 million Poles , 1.3 million Ukrainians , 1 million Belarusians and 3.5 million Soviet prisoners of war . German military casualties have been estimated at 5.3 million, and around 900,000 German civilians died. Around 12 million ethnic Germans were expelled from across Eastern Europe, and Germany lost roughly one-quarter of its pre-war territory. After Nazi Germany surrendered,
13616-536: The degree of crystallinity may be expressed in terms of a weight fraction or volume fraction of crystalline material. Few synthetic polymers are entirely crystalline. The crystallinity of polymers is characterized by their degree of crystallinity, ranging from zero for a completely non-crystalline polymer to one for a theoretical completely crystalline polymer. Polymers with microcrystalline regions are generally tougher (can be bent more without breaking) and more impact-resistant than totally amorphous polymers. Polymers with
13764-400: The driving force for mixing is usually entropy , not interaction energy. In other words, miscible materials usually form a solution not because their interaction with each other is more favorable than their self-interaction, but because of an increase in entropy and hence free energy associated with increasing the amount of volume available to each component. This increase in entropy scales with
13912-566: The early 1950s. West Germany joined NATO in 1955 and was a founding member of the European Economic Community . On 1 January 1957, the Saarland joined West Germany. East Germany was an Eastern Bloc state under political and military control by the Soviet Union via occupation forces and the Warsaw Pact . Although East Germany claimed to be a democracy, political power was exercised solely by leading members ( Politbüro ) of
14060-681: The ecclesiastical territories were secularised and annexed. In 1806 the Imperium was dissolved; France, Russia, Prussia, and the Habsburgs (Austria) competed for hegemony in the German states during the Napoleonic Wars . Following the fall of Napoleon , the Congress of Vienna founded the German Confederation, a loose league of 39 sovereign states . The appointment of the emperor of Austria as
14208-614: The entire track system would have to be extended in three tracks to Ems factory. There is no proposed funding for this project. Germany – in Europe (light green & dark grey) – in the European Union (light green) Germany , officially the Federal Republic of Germany , is a country in Central Europe . It lies between the Baltic and North Sea to
14356-537: The factories was halted. Between Chur and Domat/Ems runs the narrow-gauge railway line Chur-Domat/Ems of the Rhaetian Railway , which has three tracks since December 1959. Through this, standard gauge freight trains can reach the Ems-Chemie. The RhB stop, Ems factory, serves the factory site directly. There are ideas to introduce normal passenger services to Ems factory in the future. For this purpose, however,
14504-417: The field of organic electronics . Nowadays, synthetic polymers are used in almost all walks of life. Modern society would look very different without them. The spreading of polymer use is connected to their unique properties: low density, low cost, good thermal/electrical insulation properties, high resistance to corrosion, low-energy demanding polymer manufacture and facile processing into final products. For
14652-527: The free energy of mixing for polymer solutions and thereby making solvation less favorable, and thereby making the availability of concentrated solutions of polymers far rarer than those of small molecules. Furthermore, the phase behavior of polymer solutions and mixtures is more complex than that of small molecule mixtures. Whereas most small molecule solutions exhibit only an upper critical solution temperature phase transition (UCST), at which phase separation occurs with cooling, polymer mixtures commonly exhibit
14800-401: The glass transition is not. The glass transition shares features of second-order phase transitions (such as discontinuity in the heat capacity, as shown in the figure), but it is generally not considered a thermodynamic transition between equilibrium states. In general, polymeric mixtures are far less miscible than mixtures of small molecule materials. This effect results from the fact that
14948-597: The government was completed in 1999, and modernisation of the East German economy was scheduled to last until 2019. Since reunification, Germany has taken a more active role in the European Union , signing the Maastricht Treaty in 1992 and the Lisbon Treaty in 2007, and co-founding the eurozone . Germany sent a peacekeeping force to secure stability in the Balkans and sent German troops to Afghanistan as part of
15096-436: The group management as vice-president and Delegate of the board of directors. In the same year "Ems Grivory" was divided into the independent areas "Ems GrivoryEuropa", "Ems Grivory America" and "Ems Grivory Asia". In 2005, Blocher's son Markus's, «Ems Dottikon», was split up as an independent company. The three sisters surrendered their shares to their brother and in return received shares in "Emesta Holding AG". This meant that
15244-508: The highest fully automated high-bay warehouse in Switzerland was put into operation and EMS is selected by General Motors and Bosch as supplier of the year. Foxconn described EMS as the strategic supplier of the year. Ems Chemie lets their apprentices learn in branches abroad. Ems Chemie has two factories in Russia that have 30 employees each. Due to the Russo-Ukrainian war , the production in
15392-415: The individual chains more strongly in position and resist deformations and matrix breakup, both at higher stresses and higher temperatures. Copolymers are classified either as statistical copolymers, alternating copolymers, block copolymers, graft copolymers or gradient copolymers. In the schematic figure below, Ⓐ and Ⓑ symbolize the two repeat units . Monomers within a copolymer may be organized along
15540-691: The joint venture shares of H.B. Fuller and changed the name to «Ems Eftec». In the same year, the special polymers of «Ems Grivory» received the drinking water permit, which allowed new applications in the sanitary sector to be realized. In the following years, "Ems" launched a series of new products and opened new production sites worldwide. In 2010 "Ems Eftec" sold the Aftermarket segment and focused on direct delivery. In 2011, EMS celebrated its 75-year company anniversary; on this occasion Karl Lüönd's released his company biography "Success as an order. «Ems-Chemie»: The History of an Impossible Company". At Domat / EMS,
15688-451: The latter case, increasing the polymer chain length 10-fold would increase the viscosity over 1000 times. Increasing chain length furthermore tends to decrease chain mobility, increase strength and toughness, and increase the glass-transition temperature (T g ). This is a result of the increase in chain interactions such as van der Waals attractions and entanglements that come with increased chain length. These interactions tend to fix
15836-436: The length (or equivalently, the molecular weight) of the polymer chain. One important example of the physical consequences of the molecular weight is the scaling of the viscosity (resistance to flow) in the melt. The influence of the weight-average molecular weight ( M w {\displaystyle M_{w}} ) on the melt viscosity ( η {\displaystyle \eta } ) depends on whether
15984-417: The load is removed. Dynamic mechanical analysis or DMA measures this complex modulus by oscillating the load and measuring the resulting strain as a function of time. Transport properties such as diffusivity describe how rapidly molecules move through the polymer matrix. These are very important in many applications of polymers for films and membranes. The movement of individual macromolecules occurs by
16132-436: The market. Many commercially important polymers are synthesized by chemical modification of naturally occurring polymers. Prominent examples include the reaction of nitric acid and cellulose to form nitrocellulose and the formation of vulcanized rubber by heating natural rubber in the presence of sulfur . Ways in which polymers can be modified include oxidation , cross-linking , and end-capping . The structure of
16280-413: The material will endure before failure. This is very important in applications that rely upon a polymer's physical strength or durability. For example, a rubber band with a higher tensile strength will hold a greater weight before snapping. In general, tensile strength increases with polymer chain length and crosslinking of polymer chains. Young's modulus quantifies the elasticity of the polymer. It
16428-469: The most important factors. As a result of the cooperation, Germany imported most of its natural gas and crude oil from Russia. Germany's development policy functions as a distinct sector within its foreign policy framework. It is formulated by the Federal Ministry for Economic Cooperation and Development and carried out by the implementing organisations. The German government sees development policy as
16576-641: The nation. Germany has a network of 227 diplomatic missions abroad and maintains relations with more than 190 countries. Germany is a member of NATO , the OECD , the G7 , the G20 , the World Bank and the IMF . It has played an influential role in the European Union since its inception and has maintained a strong alliance with France and all neighbouring countries since 1990. Germany promotes
16724-507: The north and the Alps to the south. Its sixteen constituent states have a total population of over 82 million in an area of 357,596 km (138,069 sq mi), making it the most populous member state of the European Union . It borders Denmark to the north, Poland and the Czech Republic to the east, Austria and Switzerland to the south, and France , Luxembourg , Belgium , and
16872-592: The north, Poland and Czechia to the east, Austria and Switzerland to the south, and France , Luxembourg , Belgium , and the Netherlands to the west. Germany is also bordered by the North Sea and, at the north-northeast, by the Baltic Sea. German territory covers 357,596 km (138,069 sq mi). Elevation ranges from the mountains of the Alps (highest point: the Zugspitze at 2,963 metres or 9,721 feet) in
17020-444: The number of particles (or moles) being mixed. Since polymeric molecules are much larger and hence generally have much higher specific volumes than small molecules, the number of molecules involved in a polymeric mixture is far smaller than the number in a small molecule mixture of equal volume. The energetics of mixing, on the other hand, is comparable on a per volume basis for polymeric and small molecule mixtures. This tends to increase
17168-713: The partially negatively charged oxygen atoms in C=O groups on another. These strong hydrogen bonds, for example, result in the high tensile strength and melting point of polymers containing urethane or urea linkages. Polyesters have dipole-dipole bonding between the oxygen atoms in C=O groups and the hydrogen atoms in H-C groups. Dipole bonding is not as strong as hydrogen bonding, so a polyester's melting point and strength are lower than Kevlar 's ( Twaron ), but polyesters have greater flexibility. Polymers with non-polar units such as polyethylene interact only through weak Van der Waals forces . As
17316-587: The party system has been dominated by the Christian Democratic Union and the Social Democratic Party of Germany . So far every chancellor has been a member of one of these parties. However, the smaller liberal Free Democratic Party and the Alliance 90/The Greens have also been junior partners in coalition governments . Since 2007, the democratic socialist party The Left has been a staple in
17464-455: The people' (from diot or diota 'people'), originally used to distinguish the language of the common people from Latin and its Romance descendants . This in turn descends from Proto-Germanic * þiudiskaz 'of the people' (see also the Latinised form Theodiscus ), derived from * þeudō , descended from Proto-Indo-European * tewtéh₂- 'people', from which
17612-472: The permanent president reflected the Congress's rejection of Prussia 's rising influence. Disagreement within restoration politics partly led to the rise of liberal movements, followed by new measures of repression by Austrian statesman Klemens von Metternich . The Zollverein , a tariff union, furthered economic unity. In light of revolutionary movements in Europe , intellectuals and commoners started
17760-422: The physical arrangement of monomer residues along the backbone of the chain. These are the elements of polymer structure that require the breaking of a covalent bond in order to change. Various polymer structures can be produced depending on the monomers and reaction conditions: A polymer may consist of linear macromolecules containing each only one unbranched chain. In the case of unbranched polyethylene, this chain
17908-399: The polymer and create gaps between polymer chains for greater mobility and fewer interchain interactions. A good example of the action of plasticizers is related to polyvinylchlorides or PVCs. A uPVC, or unplasticized polyvinylchloride, is used for things such as pipes. A pipe has no plasticizers in it, because it needs to remain strong and heat-resistant. Plasticized PVC is used in clothing for
18056-426: The polymer at the scale of a single chain. The microstructure determines the possibility for the polymer to form phases with different arrangements, for example through crystallization , the glass transition or microphase separation . These features play a major role in determining the physical and chemical properties of a polymer. The identity of the repeat units (monomer residues, also known as "mers") comprising
18204-540: The polymer can lend the polymer to ionic bonding or hydrogen bonding between its own chains. These stronger forces typically result in higher tensile strength and higher crystalline melting points. The intermolecular forces in polymers can be affected by dipoles in the monomer units. Polymers containing amide or carbonyl groups can form hydrogen bonds between adjacent chains; the partially positively charged hydrogen atoms in N-H groups of one chain are strongly attracted to
18352-403: The polymer is above or below the onset of entanglements . Below the entanglement molecular weight , η ∼ M w 1 {\displaystyle \eta \sim {M_{w}}^{1}} , whereas above the entanglement molecular weight, η ∼ M w 3.4 {\displaystyle \eta \sim {M_{w}}^{3.4}} . In
18500-583: The polymerization of PET polyester . The monomers are terephthalic acid (HOOC—C 6 H 4 —COOH) and ethylene glycol (HO—CH 2 —CH 2 —OH) but the repeating unit is —OC—C 6 H 4 —COO—CH 2 —CH 2 —O—, which corresponds to the combination of the two monomers with the loss of two water molecules. The distinct piece of each monomer that is incorporated into the polymer is known as a repeat unit or monomer residue. Synthetic methods are generally divided into two categories, step-growth polymerization and chain polymerization . The essential difference between
18648-458: The production of caprolactam from which polyamide plastics and, from the subsidiary company, Fibron S.A., polyamide fibers (brand names Grilon) were made. Shortly afterwards, the first foreign sales company was founded, GRILON & Plastics Machinery Ltd. based in Dover ( UK ). In 1954 the "Hovag" was one of the largest employers with 1015 employees and consumed about half of the electrical energy of
18796-437: The same side), atactic (random placement of substituents), and syndiotactic (alternating placement of substituents). Polymer morphology generally describes the arrangement and microscale ordering of polymer chains in space. The macroscopic physical properties of a polymer are related to the interactions between the polymer chains. When applied to polymers, the term crystalline has a somewhat ambiguous usage. In some cases,
18944-512: The size of individual polymer coils in solution. A variety of techniques may be employed for the synthesis of a polymeric material with a range of architectures, for example living polymerization . A common means of expressing the length of a chain is the degree of polymerization , which quantifies the number of monomers incorporated into the chain. As with other molecules, a polymer's size may also be expressed in terms of molecular weight . Since synthetic polymerization techniques typically yield
19092-601: The south to the shores of the North Sea ( Nordsee ) in the northwest and the Baltic Sea ( Ostsee ) in the northeast. The forested uplands of central Germany and the lowlands of northern Germany (lowest point: in the municipality Neuendorf-Sachsenbande , Wilstermarsch at 3.54 metres or 11.6 feet below sea level ) are traversed by such major rivers as the Rhine, Danube and Elbe. Significant natural resources include iron ore, coal, potash , timber, lignite , uranium , copper, natural gas, salt, and nickel. Most of Germany has
19240-955: The southeast regions have more extreme temperatures. From February 2019 – 2020, average monthly temperatures in Germany ranged from a low of 3.3 °C (37.9 °F) in January 2020 to a high of 19.8 °C (67.6 °F) in June 2019. Average monthly precipitation ranged from 30 litres per square metre in February and April 2019 to 125 litres per square metre in February 2020. Average monthly hours of sunshine ranged from 45 in November 2019 to 300 in June 2019. The territory of Germany can be divided into five terrestrial ecoregions : Atlantic mixed forests , Baltic mixed forests , Central European mixed forests , Western European broadleaf forests , and Alps conifer and mixed forests . As of 2016 , 51% of Germany's land area
19388-556: The standardization of the language; the 1555 Peace of Augsburg tolerated the "Evangelical" faith ( Lutheranism ), but also decreed that the faith of the prince was to be the faith of his subjects ( cuius regio, eius religio ). From the Cologne War through the Thirty Years' Wars (1618–1648), religious conflict devastated German lands and significantly reduced the population. The Peace of Westphalia ended religious warfare among
19536-448: The states is known as a coil–globule transition . Inclusion of plasticizers tends to lower T g and increase polymer flexibility. Addition of the plasticizer will also modify dependence of the glass-transition temperature T g on the cooling rate. The mobility of the chain can further change if the molecules of plasticizer give rise to hydrogen bonding formation. Plasticizers are generally small molecules that are chemically similar to
19684-722: The subsequent decisive Prussian victory in the Austro-Prussian War of 1866 enabled him to create the North German Confederation which excluded Austria . After the defeat of France in the Franco-Prussian War , the German princes proclaimed the founding of the German Empire in 1871. Prussia was the dominant constituent state of the new empire; the King of Prussia ruled as its Kaiser, and Berlin became its capital. In
19832-412: The supply of 2000 tons of feed yeast per year, of which only a total of 2639 tons were delivered due to supply shortages. From 1944 to 1947, the company invested in patents and administrations AG ("Patvag AG"), a sister company of "Hovag", focused on hydropower plants, in order to secure their energy supplies. In 1948, Hovag began producing ammonia, in 1949 urea synthesis, and in the 1950s Hovag began with
19980-686: The term crystalline finds identical usage to that used in conventional crystallography . For example, the structure of a crystalline protein or polynucleotide, such as a sample prepared for x-ray crystallography , may be defined in terms of a conventional unit cell composed of one or more polymer molecules with cell dimensions of hundreds of angstroms or more. A synthetic polymer may be loosely described as crystalline if it contains regions of three-dimensional ordering on atomic (rather than macromolecular) length scales, usually arising from intramolecular folding or stacking of adjacent chains. Synthetic polymers may consist of both crystalline and amorphous regions;
20128-478: The textile industry, fibers for press felts (i.e. paper machine felts), powder coatings (i.e. glass and aluminum faucets, machines, appliances, radiators) which are heat, UV and cold resistant. Ems-Patvag develops and produces igniters (ei. airbags, belt tensioners) for safety systems in the automobile sector. In 1936 Werner Oswald founded "Holzverzuckerungs AG" ("Hovag") based in Zürich , to produce, among other things,
20276-430: The three business areas polymeric materials, fine chemicals (EMS Dottikon) and engineering. Amongst the new products, which were developed continuously, was a highly rigid polyamide in 1991. A year later the «Ems» celebrated its 50th birthday of production. In 1997, the "Ems Togo" business unit entered into a joint venture with H.B. Fuller Automotive USA, which appeared under the name of "Eftec". Three years later there
20424-401: The three sisters held the majority of shares of Ems-Chemie Holding. In the following year, the "Tegra" biomass power plant (wood-chip power plant) was put into operation, reducing CO 2 emissions at the Domat / Ems plant by 80%. In 2007, Miriam Blocher reduced her stake in "Ems-Chemie Holding", the majority was now owned by Magdalena Martullo-Blocher and Rahel Blocher. "Ems Togo" took over all
20572-555: The two is that in chain polymerization, monomers are added to the chain one at a time only, such as in polystyrene , whereas in step-growth polymerization chains of monomers may combine with one another directly, such as in polyester . Step-growth polymerization can be divided into polycondensation , in which low-molar-mass by-product is formed in every reaction step, and polyaddition . Newer methods, such as plasma polymerization do not fit neatly into either category. Synthetic polymerization reactions may be carried out with or without
20720-406: The war and a period of Allied occupation , Germany was organized into two separate polities with limited sovereignty: the Federal Republic of Germany, or West Germany , and the German Democratic Republic, or East Germany . Berlin continued its de jure Four Power status . The Federal Republic of Germany was a founding member of the European Economic Community and the European Union , while
20868-621: The western Rhineland had been incorporated into Roman provinces . Around 260, Germanic peoples broke into Roman-controlled lands. After the invasion of the Huns in 375, and with the decline of Rome from 395, Germanic tribes moved farther southwest: the Franks established the Frankish Kingdom and pushed east to subjugate Saxony and Bavaria . Areas of what is today eastern Germany were inhabited by Western Slavic tribes. Charlemagne founded
21016-597: The word Teutons also originates. Pre-human ancestors, the Danuvius guggenmosi , who were present in Germany over 11 million years ago, are theorized to be among the earliest ones to walk on two legs. Ancient humans were present in Germany at least 600,000 years ago. The first non-modern human fossil (the Neanderthal ) was discovered in the Neander Valley . Similarly dated evidence of modern humans has been found in
21164-531: Was a joint venture between «Eftec» and the Czech company D-Plast to open up the Central and Eastern European market. In 2000, the group was made up of four main self-employed companies "Ems Grivory" (technical thermoplastics), "Ems Griltec" (technical fibers and adhesives), "Ems Primid" (thermosets), "Ems Services" (central services workshop Domat / Ems). The following year Blochers eldest daughter Magdalena Martullo joined
21312-605: Was coined in 1833 by Jöns Jacob Berzelius , though with a definition distinct from the modern IUPAC definition. The modern concept of polymers as covalently bonded macromolecular structures was proposed in 1920 by Hermann Staudinger , who spent the next decade finding experimental evidence for this hypothesis. Polymers are of two types: naturally occurring and synthetic or man made . Natural polymeric materials such as hemp , shellac , amber , wool , silk , and natural rubber have been used for centuries. A variety of other natural polymers exist, such as cellulose , which
21460-514: Was developing a kind of napalm weapon in the 1950s that was used in Indonesia and Yemen. In 1960, "Hovag" was renamed "Emser Werke AG". The founding in 1962 of Chemie Holding Ems AG was listed for the first time on the Vorbörse Zurich on 17 December 1962. In the 1960s, "Emser Werke AG" expanded its product portfolio on an ongoing basis and established independent subsidiaries. In 1963, EMS Patvag
21608-673: Was documented before AD 100. In 962, the Kingdom of Germany formed the bulk of the Holy Roman Empire . During the 16th century, northern German regions became the centre of the Protestant Reformation . Following the Napoleonic Wars and the dissolution of the Holy Roman Empire in 1806, the German Confederation was formed in 1815. Formal unification of Germany into the modern nation-state commenced on 18 August 1866 with
21756-488: Was founded for ignition systems. In 1972, Christoph Blocher , who had entered the legal department as a student in 1969, was elected chairman of the board of directors and delegate of the board of directors. In 1978, the various Ems companies were merged under the umbrella of the Chemie Holding Ems AG. On 23 February 1979, the founder Werner Oswald died in the middle of a meeting. As Christoph Blocher continued to lead
21904-444: Was the seventh-highest in the world . In response to the 2022 Russian invasion of Ukraine , Chancellor Olaf Scholz announced that German military expenditure would be increased past the NATO target of 2%, along with a one-time 2022 infusion of 100 billion euros, representing almost double the 53 billion euro military budget for 2021. In 2023, military spending according to NATO criteria amounted to $ 73.1 billion, or 1.64% of
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