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123-464: When a chemical reaction is driven by an electrical potential difference , as in electrolysis , or if a potential difference results from a chemical reaction as in an electric battery or fuel cell , it is called an electrochemical reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via the aforementioned electronically conducting circuit. This phenomenon

246-733: A bridge circuit . The cathode-ray oscilloscope works by amplifying the voltage and using it to deflect an electron beam from a straight path, so that the deflection of the beam is proportional to the voltage. A common voltage for flashlight batteries is 1.5 volts (DC). A common voltage for automobile batteries is 12 volts (DC). Common voltages supplied by power companies to consumers are 110 to 120 volts (AC) and 220 to 240 volts (AC). The voltage in electric power transmission lines used to distribute electricity from power stations can be several hundred times greater than consumer voltages, typically 110 to 1200 kV (AC). The voltage used in overhead lines to power railway locomotives

369-430: A capacitor ), and from an electromotive force (e.g., electromagnetic induction in a generator ). On a macroscopic scale, a potential difference can be caused by electrochemical processes (e.g., cells and batteries), the pressure-induced piezoelectric effect , and the thermoelectric effect . Since it is the difference in electric potential, it is a physical scalar quantity . A voltmeter can be used to measure

492-572: A cascade method, Swiss chemist and physicist Raoul Pierre Pictet evaporated liquid sulfur dioxide in order to liquefy carbon dioxide, which in turn was evaporated to cool oxygen gas enough to liquefy it. He sent a telegram on December 22, 1877, to the French Academy of Sciences in Paris announcing his discovery of liquid oxygen . Just two days later, French physicist Louis Paul Cailletet announced his own method of liquefying molecular oxygen. Only

615-645: A bridge between chemical reactions and electricity on his essay "De Viribus Electricitatis in Motu Musculari Commentarius" (Latin for Commentary on the Effect of Electricity on Muscular Motion) in 1791 where he proposed a "nerveo-electrical substance" on biological life forms. In his essay Galvani concluded that animal tissue contained a here-to-fore neglected innate, vital force, which he termed "animal electricity," which activated nerves and muscles spanned by metal probes. He believed that this new force

738-477: A chemical element. The name oxygen was coined in 1777 by Antoine Lavoisier , who first recognized oxygen as a chemical element and correctly characterized the role it plays in combustion. Common industrial uses of oxygen include production of steel , plastics and textiles , brazing, welding and cutting of steels and other metals , rocket propellant , oxygen therapy , and life support systems in aircraft , submarines , spaceflight and diving . One of

861-434: A few drops of the liquid were produced in each case and no meaningful analysis could be conducted. Oxygen was liquefied in a stable state for the first time on March 29, 1883, by Polish scientists from Jagiellonian University , Zygmunt Wróblewski and Karol Olszewski . In 1891 Scottish chemist James Dewar was able to produce enough liquid oxygen for study. The first commercially viable process for producing liquid oxygen

984-481: A light sky-blue color caused by absorption in the red (in contrast with the blue color of the sky, which is due to Rayleigh scattering of blue light). High-purity liquid O 2 is usually obtained by the fractional distillation of liquefied air. Liquid oxygen may also be condensed from air using liquid nitrogen as a coolant. Liquid oxygen is a highly reactive substance and must be segregated from combustible materials. The spectroscopy of molecular oxygen

1107-560: A major role in absorbing energy from singlet oxygen and converting it to the unexcited ground state before it can cause harm to tissues. The common allotrope of elemental oxygen on Earth is called dioxygen , O 2 , the major part of the Earth's atmospheric oxygen (see Occurrence ). O 2 has a bond length of 121  pm and a bond energy of 498  kJ/mol . O 2 is used by complex forms of life, such as animals, in cellular respiration . Other aspects of O 2 are covered in

1230-418: A motor or power a light. A galvanic cell whose electrodes are zinc and copper submerged in zinc sulfate and copper sulfate , respectively, is known as a Daniell cell . The half reactions in a Daniell cell are as follows: In this example, the anode is the zinc metal which is oxidized (loses electrons) to form zinc ions in solution, and copper ions accept electrons from the copper metal electrode and

1353-438: A part of air that he called spiritus nitroaereus . In one experiment, he found that placing either a mouse or a lit candle in a closed container over water caused the water to rise and replace one-fourteenth of the air's volume before extinguishing the subjects. From this, he surmised that nitroaereus is consumed in both respiration and combustion. Mayow observed that antimony increased in weight when heated, and inferred that

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1476-414: A primary cell which solved the problem of polarization by introducing copper ions into the solution near the positive electrode and thus eliminating hydrogen gas generation. Later results revealed that at the other electrode, amalgamated zinc (i.e., zinc alloyed with mercury ) would produce a higher voltage. William Grove produced the first fuel cell in 1839. In 1846, Wilhelm Weber developed

1599-404: A process called eutrophication and the decay of these organisms and other biomaterials may reduce the O 2 content in eutrophic water bodies. Scientists assess this aspect of water quality by measuring the water's biochemical oxygen demand , or the amount of O 2 needed to restore it to a normal concentration. Paleoclimatologists measure the ratio of oxygen-18 and oxygen-16 in

1722-535: A series of experiments (see oil drop experiment ) to determine the electric charge carried by a single electron . In 1911, Harvey Fletcher, working with Millikan, was successful in measuring the charge on the electron, by replacing the water droplets used by Millikan, which quickly evaporated, with oil droplets. Within one day Fletcher measured the charge of an electron within several decimal places. In 1923, Johannes Nicolaus Brønsted and Martin Lowry published essentially

1845-458: A small proportion of manganese dioxide. Oxygen levels in the atmosphere are trending slightly downward globally, possibly because of fossil-fuel burning. At standard temperature and pressure , oxygen is a colorless, odorless, and tasteless gas with the molecular formula O 2 , referred to as dioxygen. As dioxygen , two oxygen atoms are chemically bound to each other. The bond can be variously described based on level of theory, but

1968-449: A triplet electronic ground state . An electron configuration with two unpaired electrons, as is found in dioxygen orbitals (see the filled π* orbitals in the diagram) that are of equal energy—i.e., degenerate —is a configuration termed a spin triplet state. Hence, the ground state of the O 2 molecule is referred to as triplet oxygen . The highest-energy, partially filled orbitals are antibonding , and so their filling weakens

2091-423: A well-defined voltage between nodes in the circuit, since the electric force is not a conservative force in those cases. However, at lower frequencies when the electric and magnetic fields are not rapidly changing, this can be neglected (see electrostatic approximation ). The electric potential can be generalized to electrodynamics, so that differences in electric potential between points are well-defined even in

2214-576: Is the most abundant element in Earth's crust , and the third-most abundant element in the universe after hydrogen and helium . At standard temperature and pressure , two oxygen atoms will bind covalently to form dioxygen , a colorless and odorless diatomic gas with the chemical formula O 2 . Dioxygen gas currently constitutes 20.95% molar fraction of the Earth's atmosphere , though this has changed considerably over long periods of time in Earth's history . Oxygen makes up almost half of

2337-570: Is a corrosive byproduct of smog and thus an air pollutant . Oxygen was isolated by Michael Sendivogius before 1604, but it is commonly believed that the element was discovered independently by Carl Wilhelm Scheele , in Uppsala , in 1773 or earlier, and Joseph Priestley in Wiltshire , in 1774. Priority is often given for Priestley because his work was published first. Priestley, however, called oxygen "dephlogisticated air", and did not recognize it as

2460-419: Is a common oxidizing agent, but not the only one. Despite the name, an oxidation reaction does not necessarily need to involve oxygen. In fact, a fire can be fed by an oxidant other than oxygen; fluorine fires are often unquenchable, as fluorine is an even stronger oxidant (it has a weaker bond and higher electronegativity , and thus accepts electrons even better) than oxygen. For reactions involving oxygen,

2583-462: Is a temperature difference between the joints. In 1827, the German scientist Georg Ohm expressed his law in this famous book "Die galvanische Kette, mathematisch bearbeitet" (The Galvanic Circuit Investigated Mathematically) in which he gave his complete theory of electricity. In 1832, Michael Faraday 's experiments led him to state his two laws of electrochemistry. In 1836, John Daniell invented

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2706-463: Is a well-defined voltage across the inductor's terminals. This is the reason that measurements with a voltmeter across an inductor are often reasonably independent of the placement of the test leads. The volt (symbol: V ) is the derived unit for electric potential , voltage, and electromotive force . The volt is named in honour of the Italian physicist Alessandro Volta (1745–1827), who invented

2829-477: Is absorbed by specialized respiratory organs called gills , through the skin or via the gut ; in terrestrial animals such as tetrapods , oxygen in air is actively taken into the body via specialized organs known as lungs , where gas exchange takes place to diffuse oxygen into the blood and carbon dioxide out, and the body's circulatory system then transports the oxygen to other tissues where cellular respiration takes place. However in insects ,

2952-548: Is affected by thermodynamics. The quantity measured by a voltmeter is the negative of the difference of the electrochemical potential of electrons ( Fermi level ) divided by the electron charge and commonly referred to as the voltage difference, while the pure unadjusted electrostatic potential (not measurable with a voltmeter) is sometimes called Galvani potential . The terms "voltage" and "electric potential" are ambiguous in that, in practice, they can refer to either of these in different contexts. The term electromotive force

3075-508: Is associated with the atmospheric processes of aurora and airglow . The absorption in the Herzberg continuum and Schumann–Runge bands in the ultraviolet produces atomic oxygen that is important in the chemistry of the middle atmosphere. Excited-state singlet molecular oxygen is responsible for red chemiluminescence in solution. Table of thermal and physical properties of oxygen (O 2 ) at atmospheric pressure: Naturally occurring oxygen

3198-427: Is between 12 kV and 50 kV (AC) or between 0.75 kV and 3 kV (DC). Inside a conductive material, the energy of an electron is affected not only by the average electric potential but also by the specific thermal and atomic environment that it is in. When a voltmeter is connected between two different types of metal, it measures not the electrostatic potential difference, but instead something else that

3321-469: Is composed of three stable isotopes , O , O , and O , with O being the most abundant (99.762% natural abundance ). Most O is synthesized at the end of the helium fusion process in massive stars but some is made in the neon burning process . O is primarily made by the burning of hydrogen into helium during the CNO cycle , making it a common isotope in the hydrogen burning zones of stars. Most O

3444-417: Is defined so that negatively charged objects are pulled towards higher voltages, while positively charged objects are pulled towards lower voltages. Therefore, the conventional current in a wire or resistor always flows from higher voltage to lower voltage. Historically, voltage has been referred to using terms like "tension" and "pressure". Even today, the term "tension" is still used, for example within

3567-476: Is lost. Conversely, loss of oxygen or gain of hydrogen implies reduction. Electrochemical reactions in water are better analyzed by using the ion-electron method , where H , OH ion, H 2 O and electrons (to compensate the oxidation changes) are added to the cell's half-reactions for oxidation and reduction. In acidic medium, H ions and water are added to balance each half-reaction . For example, when manganese reacts with sodium bismuthate . Finally,

3690-447: Is oxygen as a component of water, the major constituent of lifeforms. Oxygen in Earth's atmosphere is produced by biotic photosynthesis , in which photon energy in sunlight is captured by chlorophyll to split water molecules and then react with carbon dioxide to produce carbohydrates and oxygen is released as a byproduct . Oxygen is too chemically reactive to remain a free element in air without being continuously replenished by

3813-441: Is produced when N (made abundant from CNO burning) captures a He nucleus, making O common in the helium-rich zones of evolved, massive stars . Fifteen radioisotopes have been characterized, ranging from O to O. The most stable are O with a half-life of 122.24 seconds and O with a half-life of 70.606 seconds. All of the remaining radioactive isotopes have half-lives that are less than 27 seconds and

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3936-408: Is reasonably and simply described as a covalent double bond that results from the filling of molecular orbitals formed from the atomic orbitals of the individual oxygen atoms, the filling of which results in a bond order of two. More specifically, the double bond is the result of sequential, low-to-high energy, or Aufbau , filling of orbitals, and the resulting cancellation of contributions from

4059-712: Is temperature-dependent, and about twice as much ( 14.6  mg/L ) dissolves at 0 °C than at 20 °C ( 7.6  mg/L ). At 25 °C and 1 standard atmosphere (101.3  kPa ) of air, freshwater can dissolve about 6.04  milliliters  (mL) of oxygen per liter , and seawater contains about 4.95 mL per liter. At 5 °C the solubility increases to 9.0 mL (50% more than at 25 °C) per liter for freshwater and 7.2 mL (45% more) per liter for sea water. Oxygen condenses at 90.20  K (−182.95 °C, −297.31 °F) and freezes at 54.36 K (−218.79 °C, −361.82 °F). Both liquid and solid O 2 are clear substances with

4182-547: Is the joule per coulomb , where 1 volt = 1 joule (of work) per 1 coulomb of charge. The old SI definition for volt used power and current ; starting in 1990, the quantum Hall and Josephson effect were used, and in 2019 physical constants were given defined values for the definition of all SI units. Voltage is denoted symbolically by Δ V {\displaystyle \Delta V} , simplified V , especially in English -speaking countries. Internationally,

4305-530: Is the intensity of the electric field. In this case, the voltage increase from point A to point B is equal to the work done per unit charge, against the electric field, to move the charge from A to B without causing any acceleration. Mathematically, this is expressed as the line integral of the electric field along that path. In electrostatics, this line integral is independent of the path taken. Under this definition, any circuit where there are time-varying magnetic fields, such as AC circuits , will not have

4428-435: Is the result of the oxygen cycle . This biogeochemical cycle describes the movement of oxygen within and between its three main reservoirs on Earth: the atmosphere, the biosphere, and the lithosphere . The main driving factor of the oxygen cycle is photosynthesis , which is responsible for modern Earth's atmosphere. Photosynthesis releases oxygen into the atmosphere, while respiration , decay , and combustion remove it from

4551-450: Is the sum of the voltage between A and B and the voltage between B and C . The various voltages in a circuit can be computed using Kirchhoff's circuit laws . When talking about alternating current (AC) there is a difference between instantaneous voltage and average voltage. Instantaneous voltages can be added for direct current (DC) and AC, but average voltages can be meaningfully added only when they apply to signals that all have

4674-457: Is unusual among the planets of the Solar System in having such a high concentration of oxygen gas in its atmosphere: Mars (with 0.1% O 2 by volume) and Venus have much less. The O 2 surrounding those planets is produced solely by the action of ultraviolet radiation on oxygen-containing molecules such as carbon dioxide. The unusually high concentration of oxygen gas on Earth

4797-517: Is usually given priority in the discovery. The French chemist Antoine Laurent Lavoisier later claimed to have discovered the new substance independently. Priestley visited Lavoisier in October 1774 and told him about his experiment and how he liberated the new gas. Scheele had also dispatched a letter to Lavoisier on September 30, 1774, which described his discovery of the previously unknown substance, but Lavoisier never acknowledged receiving it (a copy of

4920-513: Is what distinguishes an electrochemical reaction from a conventional chemical reaction. Understanding of electrical matters began in the sixteenth century. During this century, the English scientist William Gilbert spent 17 years experimenting with magnetism and, to a lesser extent, electricity. For his work on magnets, Gilbert became known as the "Father of Magnetism." He discovered various methods for producing and strengthening magnets. In 1663,

5043-608: The Earth , the Moon , Mars , and meteorites , but were long unable to obtain reference values for the isotope ratios in the Sun , believed to be the same as those of the primordial solar nebula . Analysis of a silicon wafer exposed to the solar wind in space and returned by the crashed Genesis spacecraft has shown that the Sun has a higher proportion of oxygen-16 than does the Earth. The measurement implies that an unknown process depleted oxygen-16 from

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5166-463: The Earth's crust in the form of various oxides such as water , carbon dioxide , iron oxides and silicates . All eukaryotic organisms , including plants , animals , fungi , algae and most protists , need oxygen for cellular respiration , which extracts chemical energy by the reaction of oxygen with organic molecules derived from food and releases carbon dioxide as a waste product. In aquatic animals , dissolved oxygen in water

5289-516: The German physicist Otto von Guericke created the first electric generator, which produced static electricity by applying friction in the machine. The generator was made of a large sulfur ball cast inside a glass globe, mounted on a shaft. The ball was rotated by means of a crank and an electric spark was produced when a pad was rubbed against the ball as it rotated. The globe could be removed and used as source for experiments with electricity. By

5412-506: The Greek roots ὀξύς (oxys) ( acid , literally 'sharp', from the taste of acids) and -γενής (-genēs) (producer, literally begetter), because he mistakenly believed that oxygen was a constituent of all acids. Chemists (such as Sir Humphry Davy in 1812) eventually determined that Lavoisier was wrong in this regard, but by then the name was too well established. Oxygen entered the English language despite opposition by English scientists and

5535-411: The conductivity and electrolytic dissociation of organic acids . Walther Hermann Nernst developed the theory of the electromotive force of the voltaic cell in 1888. In 1889, he showed how the characteristics of the voltage produced could be used to calculate the free energy change in the chemical reaction producing the voltage. He constructed an equation, known as Nernst equation , which related

5658-827: The electrodynamometer . In 1868, Georges Leclanché patented a new cell which eventually became the forerunner to the world's first widely used battery, the zinc–carbon cell . Svante Arrhenius published his thesis in 1884 on Recherches sur la conductibilité galvanique des électrolytes (Investigations on the galvanic conductivity of electrolytes). From his results the author concluded that electrolytes , when dissolved in water, become to varying degrees split or dissociated into electrically opposite positive and negative ions. In 1886, Paul Héroult and Charles M. Hall developed an efficient method (the Hall–Héroult process ) to obtain aluminium using electrolysis of molten alumina. In 1894, Friedrich Ostwald concluded important studies of

5781-470: The shells and skeletons of marine organisms to determine the climate millions of years ago (see oxygen isotope ratio cycle ). Seawater molecules that contain the lighter isotope , oxygen-16, evaporate at a slightly faster rate than water molecules containing the 12% heavier oxygen-18, and this disparity increases at lower temperatures. During periods of lower global temperatures, snow and rain from that evaporated water tends to be higher in oxygen-16, and

5904-430: The thermal decomposition of potassium nitrate . In Bugaj's view, the isolation of oxygen and the proper association of the substance to that part of air which is required for life, provides sufficient evidence for the discovery of oxygen by Sendivogius. This discovery of Sendivogius was however frequently denied by the generations of scientists and chemists which succeeded him. It is also commonly claimed that oxygen

6027-430: The voltaic pile , possibly the first chemical battery . A simple analogy for an electric circuit is water flowing in a closed circuit of pipework , driven by a mechanical pump . This can be called a "water circuit". The potential difference between two points corresponds to the pressure difference between two points. If the pump creates a pressure difference between two points, then water flowing from one point to

6150-504: The 17th and the 18th century but none of them recognized it as a chemical element . This may have been in part due to the prevalence of the philosophy of combustion and corrosion called the phlogiston theory , which was then the favored explanation of those processes. Established in 1667 by the German alchemist J. J. Becher , and modified by the chemist Georg Ernst Stahl by 1731, phlogiston theory stated that all combustible materials were made of two parts. One part, called phlogiston,

6273-531: The 2s electrons, after sequential filling of the low σ and σ orbitals; σ overlap of the two atomic 2p orbitals that lie along the O–O molecular axis and π overlap of two pairs of atomic 2p orbitals perpendicular to the O–O molecular axis, and then cancellation of contributions from the remaining two 2p electrons after their partial filling of the π orbitals. This combination of cancellations and σ and π overlaps results in dioxygen's double-bond character and reactivity, and

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6396-527: The American scientist Robert H. Goddard became the first person to develop a rocket engine that burned liquid fuel; the engine used gasoline for fuel and liquid oxygen as the oxidizer . Goddard successfully flew a small liquid-fueled rocket 56 m at 97 km/h on March 16, 1926, in Auburn, Massachusetts , US. In academic laboratories, oxygen can be prepared by heating together potassium chlorate mixed with

6519-478: The Philosopher's Stone drawn from the source of nature and manual experience"] (1604) described a substance contained in air, referring to it as 'cibus vitae' (food of life, ) and according to Polish historian Roman Bugaj, this substance is identical with oxygen. Sendivogius, during his experiments performed between 1598 and 1604, properly recognized that the substance is equivalent to the gaseous byproduct released by

6642-438: The Sun's disk of protoplanetary material prior to the coalescence of dust grains that formed the Earth. Oxygen presents two spectrophotometric absorption bands peaking at the wavelengths 687 and 760  nm . Some remote sensing scientists have proposed using the measurement of the radiance coming from vegetation canopies in those bands to characterize plant health status from a satellite platform. This approach exploits

6765-458: The anode and cathode electrolytes in addition to the electron conduction path. The simplest ionic conduction path is to provide a liquid junction. To avoid mixing between the two electrolytes, the liquid junction can be provided through a porous plug that allows ion flow while minimizing electrolyte mixing. To further minimize mixing of the electrolytes, a salt bridge can be used which consists of an electrolyte saturated gel in an inverted U-tube. As

6888-493: The atmosphere. In the present equilibrium, production and consumption occur at the same rate. Free oxygen also occurs in solution in the world's water bodies. The increased solubility of O 2 at lower temperatures (see Physical properties ) has important implications for ocean life, as polar oceans support a much higher density of life due to their higher oxygen content. Water polluted with plant nutrients such as nitrates or phosphates may stimulate growth of algae by

7011-546: The atoms, ions or molecules involved in an electrochemical reaction. Formally, oxidation state is the hypothetical charge that an atom would have if all bonds to atoms of different elements were 100% ionic . An atom or ion that gives up an electron to another atom or ion has its oxidation state increase, and the recipient of the negatively charged electron has its oxidation state decrease. For example, when atomic sodium reacts with atomic chlorine , sodium donates one electron and attains an oxidation state of +1. Chlorine accepts

7134-513: The balanced equation is obtained: An electrochemical cell is a device that produces an electric current from energy released by a spontaneous redox reaction. This kind of cell includes the Galvanic cell or Voltaic cell, named after Luigi Galvani and Alessandro Volta , both scientists who conducted experiments on chemical reactions and electric current during the late 18th century. Electrochemical cells have two conductive electrodes (the anode and

7257-412: The bond order from three to two. Because of its unpaired electrons, triplet oxygen reacts only slowly with most organic molecules, which have paired electron spins; this prevents spontaneous combustion. In the triplet form, O 2 molecules are paramagnetic . That is, they impart magnetic character to oxygen when it is in the presence of a magnetic field, because of the spin magnetic moments of

7380-463: The cathode). The anode is defined as the electrode where oxidation occurs and the cathode is the electrode where the reduction takes place. Electrodes can be made from any sufficiently conductive materials, such as metals, semiconductors, graphite, and even conductive polymers . In between these electrodes is the electrolyte , which contains ions that can freely move. The galvanic cell uses two different metal electrodes, each in an electrolyte where

7503-413: The circuit are not negligible, then their effects can be modelled by adding mutual inductance elements. In the case of a physical inductor though, the ideal lumped representation is often accurate. This is because the external fields of inductors are generally negligible, especially if the inductor has a closed magnetic path . If external fields are negligible, we find that is path-independent, and there

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7626-402: The conclusion that the production of electricity in simple electrolytic cells resulted from chemical action and that chemical combination occurred between substances of opposite charge. This work led directly to the isolation of metallic sodium and potassium by electrolysis of their molten salts, and of the alkaline earth metals from theirs, in 1808. Hans Christian Ørsted 's discovery of

7749-431: The device with respect to a common reference point (or ground ). The voltage drop is the difference between the two readings. Two points in an electric circuit that are connected by an ideal conductor without resistance and not within a changing magnetic field have a voltage of zero. Any two points with the same potential may be connected by a conductor and no current will flow between them. The voltage between A and C

7872-444: The diatomic elemental molecules in those gases. The first commercial method of producing oxygen was chemical, the so-called Brin process involving a reversible reaction of barium oxide . It was invented in 1852 and commercialized in 1884, but was displaced by newer methods in early 20th century. By the late 19th century scientists realized that air could be liquefied and its components isolated by compressing and cooling it. Using

7995-472: The difference in electric potential between two points. In a static electric field , it corresponds to the work needed per unit of charge to move a positive test charge from the first point to the second point. In the International System of Units (SI), the derived unit for voltage is the volt (V) . The voltage between points can be caused by the build-up of electric charge (e.g.,

8118-446: The electric field in the region exterior to each component is conservative, and voltages between nodes in the circuit are well-defined, where as long as the path of integration does not pass through the inside of any component. The above is the same formula used in electrostatics. This integral, with the path of integration being along the test leads, is what a voltmeter will actually measure. If uncontained magnetic fields throughout

8241-428: The electric field, rather than to differences in electric potential. In this case, the voltage rise along some path P {\displaystyle {\mathcal {P}}} from r A {\displaystyle \mathbf {r} _{A}} to r B {\displaystyle \mathbf {r} _{B}} is given by: However, in this case the "voltage" between two points depends on

8364-434: The electron and its oxidation state is reduced to −1. The sign of the oxidation state (positive/negative) actually corresponds to the value of each ion's electronic charge. The attraction of the differently charged sodium and chlorine ions is the reason they then form an ionic bond . The loss of electrons from an atom or molecule is called oxidation, and the gain of electrons is reduction. This can be easily remembered through

8487-416: The electron is assigned to the atom with the largest electronegativity in determining the oxidation state. The atom or molecule which loses electrons is known as the reducing agent , or reductant , and the substance which accepts the electrons is called the oxidizing agent , or oxidant . Thus, the oxidizing agent is always being reduced in a reaction; the reducing agent is always being oxidized. Oxygen

8610-466: The electron spins are paired. It is much more reactive with common organic molecules than is normal (triplet) molecular oxygen. In nature, singlet oxygen is commonly formed from water during photosynthesis, using the energy of sunlight. It is also produced in the troposphere by the photolysis of ozone by light of short wavelength and by the immune system as a source of active oxygen. Carotenoids in photosynthetic organisms (and possibly animals) play

8733-563: The fact that the Englishman Priestley had first isolated the gas and written about it. This is partly due to a poem praising the gas titled "Oxygen" in the popular book The Botanic Garden (1791) by Erasmus Darwin , grandfather of Charles Darwin . John Dalton 's original atomic hypothesis presumed that all elements were monatomic and that the atoms in compounds would normally have the simplest atomic ratios with respect to one another. For example, Dalton assumed that water's formula

8856-399: The first known experiments on the relationship between combustion and air was conducted by the 2nd century BCE Greek writer on mechanics, Philo of Byzantium . In his work Pneumatica , Philo observed that inverting a vessel over a burning candle and surrounding the vessel's neck with water resulted in some water rising into the neck. Philo incorrectly surmised that parts of the air in

8979-412: The gain of oxygen implies the oxidation of the atom or molecule to which the oxygen is added (and the oxygen is reduced). In organic compounds, such as butane or ethanol , the loss of hydrogen implies oxidation of the molecule from which it is lost (and the hydrogen is reduced). This follows because the hydrogen donates its electron in covalent bonds with non-metals but it takes the electron along when it

9102-400: The half-reactions. By multiplying the stoichiometric coefficients so the numbers of electrons in both half reaction match: the balanced overall reaction is obtained: The same procedure as used in acidic medium can be applied, for example, to balance the complete combustion of propane : By multiplying the stoichiometric coefficients so the numbers of electrons in both half reaction match:

9225-399: The idea; instead, it was based on observations of what happens when something burns, that most common objects appear to become lighter and seem to lose something in the process. Polish alchemist , philosopher , and physician Michael Sendivogius (Michał Sędziwój) in his work De Lapide Philosophorum Tractatus duodecim e naturae fonte et manuali experientia depromti ["Twelve Treatises on

9348-402: The ion's oxidation state is reduced to 0. This forms a solid metal that electrodeposits on the cathode. The two electrodes must be electrically connected to each other, allowing for a flow of electrons that leave the metal of the anode and flow through this connection to the ions at the surface of the cathode. This flow of electrons is an electric current that can be used to do work, such as turn

9471-473: The ions deposit at the copper cathode as an electrodeposit. This cell forms a simple battery as it will spontaneously generate a flow of electric current from the anode to the cathode through the external connection. This reaction can be driven in reverse by applying a voltage, resulting in the deposition of zinc metal at the anode and formation of copper ions at the cathode. To provide a complete electric circuit, there must also be an ionic conduction path between

9594-499: The letter was found in Scheele's belongings after his death). Lavoisier conducted the first adequate quantitative experiments on oxidation and gave the first correct explanation of how combustion works. He used these and similar experiments, all started in 1774, to discredit the phlogiston theory and to prove that the substance discovered by Priestley and Scheele was a chemical element . In one experiment, Lavoisier observed that there

9717-426: The magnetic effect of electric currents in 1820 was immediately recognized as an epoch-making advance, although he left further work on electromagnetism to others. André-Marie Ampère quickly repeated Ørsted's experiment, and formulated them mathematically. In 1821, Estonian-German physicist Thomas Johann Seebeck demonstrated the electrical potential between the juncture points of two dissimilar metals when there

9840-428: The majority of these have half-lives that are less than 83 milliseconds. The most common decay mode of the isotopes lighter than O is β decay to yield nitrogen, and the most common mode for the isotopes heavier than O is beta decay to yield fluorine . Oxygen is the most abundant chemical element by mass in the Earth's biosphere , air, sea and land. Oxygen is the third most abundant chemical element in

9963-527: The mid-18th century the French chemist Charles François de Cisternay du Fay had discovered two types of static electricity, and that like charges repel each other whilst unlike charges attract. Du Fay announced that electricity consisted of two fluids: "vitreous" (from the Latin for "glass" ), or positive, electricity; and "resinous," or negative, electricity. This was the two-fluid theory of electricity , which

10086-418: The most successful and biodiverse terrestrial clade , oxygen is directly conducted to the internal tissues via a deep network of airways . Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins , nucleic acids , carbohydrates and fats , as do the major constituent inorganic compounds of animal shells, teeth, and bone. Most of the mass of living organisms

10209-400: The negatively charged electrons flow in one direction around this circuit, the positively charged metal ions flow in the opposite direction in the electrolyte. A voltmeter is capable of measuring the change of electrical potential between the anode and the cathode. Voltage Voltage , also known as (electrical) potential difference , electric pressure , or electric tension is

10332-494: The nitroaereus must have combined with it. He also thought that the lungs separate nitroaereus from air and pass it into the blood and that animal heat and muscle movement result from the reaction of nitroaereus with certain substances in the body. Accounts of these and other experiments and ideas were published in 1668 in his work Tractatus duo in the tract "De respiratione". Robert Hooke , Ole Borch , Mikhail Lomonosov , and Pierre Bayen all produced oxygen in experiments in

10455-495: The observed potential difference at the terminals of an electrochemical cell when it was open circuit must exactly balance the emf of the cell so that no current flowed. Oxygen Oxygen is a chemical element with the symbol   O and atomic number 8. It is a member of the chalcogen group in the periodic table , a highly reactive nonmetal , and a potent oxidizing agent that readily forms oxides with most elements as well as with other compounds . Oxygen

10578-407: The other will be able to do work, such as driving a turbine . Similarly, work can be done by an electric current driven by the potential difference provided by a battery . For example, the voltage provided by a sufficiently-charged automobile battery can "push" a large current through the windings of an automobile's starter motor . If the pump is not working, it produces no pressure difference, and

10701-424: The path taken. In circuit analysis and electrical engineering , lumped element models are used to represent and analyze circuits. These elements are idealized and self-contained circuit elements used to model physical components. When using a lumped element model, it is assumed that the effects of changing magnetic fields produced by the circuit are suitably contained to each element. Under these assumptions,

10824-451: The photosynthetic activities of autotrophs such as cyanobacteria , chloroplast -bearing algae and plants. A much rarer triatomic allotrope of oxygen , ozone ( O 3 ), strongly absorbs the UVB and UVC wavelengths and forms a protective ozone layer at the lower stratosphere , which shields the biosphere from ionizing ultraviolet radiation . However, ozone present at the surface

10947-697: The phrase " high tension " (HT) which is commonly used in thermionic valve ( vacuum tube ) based and automotive electronics. In electrostatics , the voltage increase from point r A {\displaystyle \mathbf {r} _{A}} to some point r B {\displaystyle \mathbf {r} _{B}} is given by the change in electrostatic potential V {\textstyle V} from r A {\displaystyle \mathbf {r} _{A}} to r B {\displaystyle \mathbf {r} _{B}} . By definition, this is: where E {\displaystyle \mathbf {E} }

11070-430: The points across which the voltage is measured. When using a voltmeter to measure voltage, one electrical lead of the voltmeter must be connected to the first point, one to the second point. A common use of the term "voltage" is in describing the voltage dropped across an electrical device (such as a resistor). The voltage drop across the device can be understood as the difference between measurements at each terminal of

11193-412: The positively charged ions are the oxidized form of the electrode metal. One electrode will undergo oxidation (the anode) and the other will undergo reduction (the cathode). The metal of the anode will oxidize, going from an oxidation state of 0 (in the solid form) to a positive oxidation state and become an ion. At the cathode, the metal ion in solution will accept one or more electrons from the cathode and

11316-414: The presence of time-varying fields. However, unlike in electrostatics, the electric field can no longer be expressed only in terms of the electric potential. Furthermore, the potential is no longer uniquely determined up to a constant, and can take significantly different forms depending on the choice of gauge . In this general case, some authors use the word "voltage" to refer to the line integral of

11439-464: The process of electroplating . He also observed that the amount of metal deposited and the amount of oxygen produced during an electrolytic process depended on the distance between the electrodes . By 1801, Ritter observed thermoelectric currents and anticipated the discovery of thermoelectricity by Thomas Johann Seebeck . By the 1810s, William Hyde Wollaston made improvements to the galvanic cell . Sir Humphry Davy 's work with electrolysis led to

11562-416: The reaction is balanced by multiplying the stoichiometric coefficients so the numbers of electrons in both half reactions match and adding the resulting half reactions to give the balanced reaction: In basic medium, OH ions and water are added to balance each half-reaction. For example, in a reaction between potassium permanganate and sodium sulfite : Here, 'spectator ions' (K, Na) were omitted from

11685-455: The remainder of this article. Trioxygen ( O 3 ) is usually known as ozone and is a very reactive allotrope of oxygen that is damaging to lung tissue. Ozone is produced in the upper atmosphere when O 2 combines with atomic oxygen made by the splitting of O 2 by ultraviolet (UV) radiation. Since ozone absorbs strongly in the UV region of the spectrum , the ozone layer of

11808-415: The same frequency and phase. Instruments for measuring voltages include the voltmeter , the potentiometer , and the oscilloscope . Analog voltmeters , such as moving-coil instruments, work by measuring the current through a fixed resistor, which, according to Ohm's law , is proportional to the voltage across the resistor. The potentiometer works by balancing the unknown voltage against a known voltage in

11931-471: The same material. Nevertheless, Volta's experimentation led him to develop the first practical battery , which took advantage of the relatively high energy (weak bonding) of zinc and could deliver an electrical current for much longer than any other device known at the time. In 1800, William Nicholson and Johann Wilhelm Ritter succeeded in decomposing water into hydrogen and oxygen by electrolysis using Volta's battery. Soon thereafter Ritter discovered

12054-473: The same theory about how acids and bases behave, using an electrochemical basis. In 1937, Arne Tiselius developed the first sophisticated electrophoretic apparatus. Some years later, he was awarded the 1948 Nobel Prize for his work in protein electrophoresis . A year later, in 1949, the International Society of Electrochemistry (ISE) was founded. By the 1960s–1970s quantum electrochemistry

12177-414: The seawater left behind tends to be higher in oxygen-18. Marine organisms then incorporate more oxygen-18 into their skeletons and shells than they would in a warmer climate. Paleoclimatologists also directly measure this ratio in the water molecules of ice core samples as old as hundreds of thousands of years. Planetary geologists have measured the relative quantities of oxygen isotopes in samples from

12300-465: The symbol U is standardized. It is used, for instance, in the context of Ohm's or Kirchhoff's circuit laws . The electrochemical potential is the voltage that can be directly measured with a voltmeter. The Galvani potential that exists in structures with junctions of dissimilar materials is also work per charge but cannot be measured with a voltmeter in the external circuit (see § Galvani potential vs. electrochemical potential ). Voltage

12423-401: The turbine will not rotate. Likewise, if the automobile's battery is very weak or "dead" (or "flat"), then it will not turn the starter motor. The hydraulic analogy is a useful way of understanding many electrical concepts. In such a system, the work done to move water is equal to the " pressure drop" (compare p.d.) multiplied by the volume of water moved. Similarly, in an electrical circuit,

12546-486: The universe, after hydrogen and helium. About 0.9% of the Sun 's mass is oxygen. Oxygen constitutes 49.2% of the Earth's crust by mass as part of oxide compounds such as silicon dioxide and is the most abundant element by mass in the Earth's crust . It is also the major component of the world's oceans (88.8% by mass). Oxygen gas is the second most common component of the Earth's atmosphere , taking up 20.8% of its volume and 23.1% of its mass (some 10 tonnes). Earth

12669-401: The unpaired electrons in the molecule, and the negative exchange energy between neighboring O 2 molecules. Liquid oxygen is so magnetic that, in laboratory demonstrations, a bridge of liquid oxygen may be supported against its own weight between the poles of a powerful magnet. Singlet oxygen is a name given to several higher-energy species of molecular O 2 in which all

12792-435: The upper atmosphere functions as a protective radiation shield for the planet. Near the Earth's surface, it is a pollutant formed as a by-product of automobile exhaust . At low earth orbit altitudes, sufficient atomic oxygen is present to cause corrosion of spacecraft . The metastable molecule tetraoxygen ( O 4 ) was discovered in 2001, and was assumed to exist in one of the six phases of solid oxygen . It

12915-494: The use of mnemonic devices. Two of the most popular are "OIL RIG" (Oxidation Is Loss, Reduction Is Gain) and "LEO" the lion says "GER" (Lose Electrons: Oxidation, Gain Electrons: Reduction). Oxidation and reduction always occur in a paired fashion such that one species is oxidized when another is reduced. For cases where electrons are shared (covalent bonds) between atoms with large differences in electronegativity ,

13038-451: The vessel were converted into the classical element fire and thus were able to escape through pores in the glass. Many centuries later Leonardo da Vinci built on Philo's work by observing that a portion of air is consumed during combustion and respiration . In the late 17th century, Robert Boyle proved that air is necessary for combustion. English chemist John Mayow (1641–1679) refined this work by showing that fire requires only

13161-400: The voltage between two points in a system. Often a common reference potential such as the ground of the system is used as one of the points. In this case, voltage is often mentioned at a point without completely mentioning the other measurement point. A voltage can be associated with either a source of energy or the loss, dissipation, or storage of energy. The SI unit of work per unit charge

13284-443: The voltage of a cell to its properties. In 1898, Fritz Haber showed that definite reduction products can result from electrolytic processes if the potential at the cathode is kept constant. In 1898, he explained the reduction of nitrobenzene in stages at the cathode and this became the model for other similar reduction processes. In 1902, The Electrochemical Society (ECS) was founded. In 1909, Robert Andrews Millikan began

13407-465: The work done to move electrons or other charge carriers is equal to "electrical pressure difference" multiplied by the quantity of electrical charges moved. In relation to "flow", the larger the "pressure difference" between two points (potential difference or water pressure difference), the greater the flow between them (electric current or water flow). (See " electric power ".) Specifying a voltage measurement requires explicit or implicit specification of

13530-428: Was HO, leading to the conclusion that the atomic mass of oxygen was 8 times that of hydrogen, instead of the modern value of about 16. In 1805, Joseph Louis Gay-Lussac and Alexander von Humboldt showed that water is formed of two volumes of hydrogen and one volume of oxygen; and by 1811 Amedeo Avogadro had arrived at the correct interpretation of water's composition, based on what is now called Avogadro's law and

13653-518: Was a form of electricity in addition to the "natural" form produced by lightning or by the electric eel and torpedo ray as well as the "artificial" form produced by friction (i.e., static electricity). Galvani's scientific colleagues generally accepted his views, but Alessandro Volta rejected the idea of an "animal electric fluid," replying that the frog's legs responded to differences in metal temper , composition, and bulk. Galvani refuted this by obtaining muscular action with two pieces of

13776-441: Was developed by Revaz Dogonadze and his students. The term " redox " stands for reduction-oxidation . It refers to electrochemical processes involving electron transfer to or from a molecule or ion , changing its oxidation state . This reaction can occur through the application of an external voltage or through the release of chemical energy. Oxidation and reduction describe the change of oxidation state that takes place in

13899-408: Was first discovered by Swedish pharmacist Carl Wilhelm Scheele . He had produced oxygen gas by heating mercuric oxide (HgO) and various nitrates in 1771–72. Scheele called the gas "fire air" because it was then the only known agent to support combustion. He wrote an account of this discovery in a manuscript titled Treatise on Air and Fire , which he sent to his publisher in 1775. That document

14022-612: Was first used by Volta in a letter to Giovanni Aldini in 1798, and first appeared in a published paper in 1801 in Annales de chimie et de physique . Volta meant by this a force that was not an electrostatic force, specifically, an electrochemical force. The term was taken up by Michael Faraday in connection with electromagnetic induction in the 1820s. However, a clear definition of voltage and method of measuring it had not been developed at this time. Volta distinguished electromotive force (emf) from tension (potential difference):

14145-451: Was given off when the substance containing it was burned, while the dephlogisticated part was thought to be its true form, or calx . Highly combustible materials that leave little residue , such as wood or coal, were thought to be made mostly of phlogiston; non-combustible substances that corrode, such as iron, contained very little. Air did not play a role in phlogiston theory, nor were any initial quantitative experiments conducted to test

14268-491: Was independently developed in 1895 by German engineer Carl von Linde and British engineer William Hampson . Both men lowered the temperature of air until it liquefied and then distilled the component gases by boiling them off one at a time and capturing them separately. Later, in 1901, oxyacetylene welding was demonstrated for the first time by burning a mixture of acetylene and compressed O 2 . This method of welding and cutting metal later became common. In 1923,

14391-445: Was no overall increase in weight when tin and air were heated in a closed container. He noted that air rushed in when he opened the container, which indicated that part of the trapped air had been consumed. He also noted that the tin had increased in weight and that increase was the same as the weight of the air that rushed back in. This and other experiments on combustion were documented in his book Sur la combustion en général , which

14514-462: Was not sensibly different from that of common air , but I fancied that my breast felt peculiarly light and easy for some time afterwards." Priestley published his findings in 1775 in a paper titled "An Account of Further Discoveries in Air", which was included in the second volume of his book titled Experiments and Observations on Different Kinds of Air . Because he published his findings first, Priestley

14637-408: Was proven in 2006 that this phase, created by pressurizing O 2 to 20  GPa , is in fact a rhombohedral O 8 cluster . This cluster has the potential to be a much more powerful oxidizer than either O 2 or O 3 and may therefore be used in rocket fuel . A metallic phase was discovered in 1990 when solid oxygen is subjected to a pressure of above 96 GPa and it

14760-499: Was published in 1777. In the meantime, on August 1, 1774, an experiment conducted by the British clergyman Joseph Priestley focused sunlight on mercuric oxide contained in a glass tube, which liberated a gas he named "dephlogisticated air". He noted that candles burned brighter in the gas and that a mouse was more active and lived longer while breathing it. After breathing the gas himself, Priestley wrote: "The feeling of it to my lungs

14883-458: Was published in 1777. In that work, he proved that air is a mixture of two gases; 'vital air', which is essential to combustion and respiration, and azote (Gk. ἄζωτον "lifeless"), which did not support either. Azote later became nitrogen in English, although it has kept the earlier name in French and several other European languages. Lavoisier renamed 'vital air' to oxygène in 1777 from

15006-420: Was shown in 1998 that at very low temperatures, this phase becomes superconducting . Oxygen dissolves more readily in water than nitrogen, and in freshwater more readily than in seawater. Water in equilibrium with air contains approximately 1 molecule of dissolved O 2 for every 2 molecules of N 2 (1:2), compared with an atmospheric ratio of approximately 1:4. The solubility of oxygen in water

15129-582: Was to be opposed by Benjamin Franklin 's one-fluid theory later in the century. In 1785, Charles-Augustin de Coulomb developed the law of electrostatic attraction as an outgrowth of his attempt to investigate the law of electrical repulsions as stated by Joseph Priestley in England. In the late 18th century the Italian physician and anatomist Luigi Galvani marked the birth of electrochemistry by establishing

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