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Vermiculite

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Vermiculite is a hydrous phyllosilicate mineral which undergoes significant expansion when heated. Exfoliation occurs when the mineral is heated sufficiently; commercial furnaces can routinely produce this effect. Vermiculite forms by the weathering or hydrothermal alteration of biotite or phlogopite . Large commercial vermiculite mines exist in the United States , Russia , South Africa , China , and Brazil .

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85-697: Vermiculite was first described in 1824 for an occurrence in Millbury, Massachusetts . Its name is from the Latin vermiculare , "to breed worms", for the manner in which it exfoliates when heated. It typically occurs as an alteration product at the contact between felsic and mafic or ultramafic rocks such as pyroxenites and dunites . It also occurs in carbonatites and metamorphosed magnesium -rich limestone . Associated mineral phases include: corundum , apatite , serpentine , and talc . It occurs interlayered with chlorite , biotite and phlogopite. Vermiculite

170-437: A soil conditioner —up to one-half the volume of the soil—is recommended. This creates air channels and allows the soil mix to breathe. Mixing vermiculite in flower and vegetable gardens or in potted plants will provide the necessary air to maintain vigorous plant growth. Where soils are sandy, mixing of vermiculite into the soil will allow the soil to hold the water and air needed for growth. Exfoliated vermiculite treated with

255-676: A boom in using nitrogen fertilizers. In the latter half of the 20th century, increased use of nitrogen fertilizers (800% increase between 1961 and 2019) has been a crucial component of the increased productivity of conventional food systems (more than 30% per capita) as part of the so-called " Green Revolution ". The use of artificial and industrially-applied fertilizers has caused environmental consequences such as water pollution and eutrophication due to nutritional runoff; carbon and other emissions from fertilizer production and mining; and contamination and pollution of soil . Various sustainable agriculture practices can be implemented to reduce

340-406: A critical advantage over their neighbors, leading them to become dominant cultures in their respective regions (P Bellwood - 2023 ) . Egyptians, Romans, Babylonians, and early Germans are all recorded as using minerals or manure to enhance the productivity of their farms. The scientific research of plant nutrition started well before the work of German chemist Justus von Liebig although his name

425-471: A female householder with no husband present, and 30.1% were non-families. Of all households, 24.6% were made up of individuals, and 10.3% had someone living alone who was 65 years of age or older. The average household size was 2.53 and the average family size was 3.03. In the town, the population was spread out, with 23.1% under the age of 18, 6.3% from 18 to 24, 31.2% from 25 to 44, 23.4% from 45 to 64, and 16.0% who were 65 years of age or older. The median age

510-436: A few hours in the sun and then place in cartons or bushel baskets and cover with vermiculite. The absorptive power of vermiculite acts as a regulator that prevents mildew and moisture fluctuation during the storage period. It will not absorb moisture from the inside of stored tubers, but it does take up free water from the outside, preventing storage rot. Where the native soil is heavy or sticky, gentle mixing of vermiculite as

595-757: A fourth number for sulfur, and uses elemental values for all values including P and K. Micronutrients are consumed in smaller quantities and are present in plant tissue on the order of parts-per-million (ppm), ranging from 0.15 to 400 ppm or less than 0.04% dry matter. These elements are often required for enzymes essential to the plant's metabolism. Because these elements enable catalysts (enzymes), their impact far exceeds their weight%age. Typical micronutrients are boron , zinc , molybdenum , iron , and manganese . These elements are provided as water-soluble salts. Iron presents special problems because it converts to insoluble (bio-unavailable) compounds at moderate soil pH and phosphate concentrations. For this reason, iron

680-432: A homogeneous mix, and its shape and surface characteristics. Exfoliated vermiculite (typically the finer grades) can be added at site to Portland cement and other aggregates, rheological aids, and water to produce roof and floor concrete screeds which are lightweight and insulating. In many cases, vermiculite-based roof screeds are used in conjunction with other insulation materials, such as polystyrene board, to form

765-428: A mixture of phosphoric acid (H 3 PO 4 ) and calcium nitrate (Ca(NO 3 ) 2 ). This mixture can be combined with a potassium fertilizer to produce a compound fertilizer with the three macronutrients N, P and K in easily dissolved form. Potash is a mixture of potassium minerals used to make potassium (chemical symbol: K) fertilizers. Potash is soluble in water, so the main effort in producing this nutrient from

850-562: A piece of smooth, low surface-energy plastic, and allowing to dry. The resulting sheet can then be peeled off the plastic. Typical end-uses for vermiculite dispersions include inclusion in high temperature coatings or binders for construction materials, gaskets, specialty papers/textiles, oxidation-resistant coating on carbon based composites, and as barrier coatings for films. The cation exchange capacity (up to 1,000 milliequivalents per kg) of vermiculite allows it to be used in fluid purification processes for waste water, chemical processing, and

935-554: A reverse effect on nutrients – fresh sawdust can consume soil nutrients as it breaks down and may lower soil pH – but these same organic texturizers (as well as compost, etc.) may increase the availability of nutrients through improved cation exchange, or through increased growth of microorganisms that in turn increase availability of certain plant nutrients. Organic fertilizers such as composts and manures may be distributed locally without going into industry production, making actual consumption more difficult to quantify. China has become

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1020-409: A total roofing system. A bituminous binder can also be used with exfoliated vermiculite to produce a dry, lightweight roof screed which has the advantages of low thermal conductivity, low moisture content, and ease of placement (by pouring from the bag and then tamping). Exfoliated vermiculite is combined with other materials such as peat or composted pine bark to produce soilless growing medium for

1105-420: A variety of ways: through dry or pelletized or liquid application processes, using large agricultural equipment, or hand-tool methods. Historically, fertilization came from natural or organic sources: compost , animal manure , human manure , harvested minerals, crop rotations , and byproducts of human-nature industries (e.g. fish processing waste , or bloodmeal from animal slaughter ). However, starting in

1190-653: A water repellent is used to fill the pores and cavities of masonry construction and hollow blockwork to enhance fire ratings (e.g. Underwriters Laboratories Wall and Partition designs), thermal insulation , and acoustic performance. Expanded vermiculite has also been used as thermal insulation in the attics and walls of houses and in water heaters, fire safes, stoves, furnaces, and refrigerators. Exfoliated vermiculite can be combined with high alumina (also known as calcium aluminate ) cements and other aggregates such as expanded shale , clay , and slate or sodium silicate to produce refractory/insulation concretes and mortars. In

1275-401: Is ammonia (NH 3 ) ammonium (NH 4 ) or its solutions, including: The main straight phosphate fertilizers are the superphosphates : A mixture of single superphosphate and triple superphosphate is called double superphosphate. More than 90% of a typical superphosphate fertilizer is water-soluble. The main potassium-based straight fertilizer is muriate of potash (MOP, 95–99% KCl). It

1360-632: Is a 2:1 clay , meaning it has two tetrahedral sheets for every one octahedral sheet. It is a limited-expansion clay with a medium shrink–swell capacity . Vermiculite has a high cation-exchange capacity (CEC) at 100–150 meq /100 g. Vermiculite clays are weathered micas in which the potassium ions between the molecular sheets are replaced by magnesium and iron ions. This process involves mixing exfoliated vermiculite with inorganic bonding agents such as sodium silicate , cement (specific quantities), and other compounds, such as those containing potassium, to produce an 'earth damp' mixture. This material

1445-419: Is a rating system describing the amount of nitrogen, phosphorus, and potassium in a fertilizer. NPK ratings consist of three numbers separated by dashes (e.g., 10-10-10 or 16-4-8) describing the chemical content of fertilizers. The first number represents the percentage of nitrogen in the product; the second number, P 2 O 5 ; the third, K 2 O. Fertilizers do not actually contain P 2 O 5 or K 2 O, but

1530-605: Is added to a calcium silicate slurry. This is then dewatered by pressing or by using one of the Fourdriner/Magnani/Hatschek processes to form a flat board which is then heat cured under pressure (typically 10–15 bar) for periods of up to 24 hours. Finer grades of exfoliated vermiculite are being used in brake linings primarily for the automotive market. The properties of vermiculite that make it an appropriate choice for use in brake linings include its thermal resistance, ease of addition to other raw materials to achieve

1615-441: Is an advantage for mechanical application. Urea is usually spread at rates of between 40 and 300 kg/ha (35 to 270 lbs/acre) but rates vary. Smaller applications incur lower losses due to leaching. During summer, urea is often spread just before or during rain to minimize losses from volatilization (a process wherein nitrogen is lost to the atmosphere as ammonia gas). Because of the high nitrogen concentration in urea, it

1700-420: Is called " fertigation ". Granulated fertilizers are more economical to ship and store, not to mention easier to apply. Urea is highly soluble in water and is therefore also very suitable for use in fertilizer solutions (in combination with ammonium nitrate: UAN), e.g., in 'foliar feed' fertilizers. For fertilizer use, granules are preferred over prills because of their narrower particle size distribution, which

1785-454: Is decreasing, while Brazil's is significantly increasing. While some end processors and exfoliators of vermiculite specialize, with proprietary products sold in a wide variety of industries, some have more varied end products, with less stringent technical requirements. Some vermiculite exfoliators blend with lower-cost perlite also. Vermiculite exfoliators have an international trade association called The Vermiculite Association to represent

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1870-438: Is expected, urea can be side- or top-dressed during the growing season. Top-dressing is also popular on pasture and forage crops. In cultivating sugarcane, urea is side dressed after planting and applied to each ratoon crop. Because it absorbs moisture from the atmosphere, urea is often stored in closed containers. Overdose or placing urea near seed is harmful. Foliar fertilizers are applied directly to leaves. This method

1955-832: Is extremely soluble and mobile and is a major cause of eutrophication and algal bloom . Fertilizers are classified in several ways. They are classified according to whether they provide a single nutrient (e.g., K, P, or N), in which case they are classified as "straight fertilizers". "Multinutrient fertilizers" (or "complex fertilizers") provide two or more nutrients, for example, N and P. Fertilizers are also sometimes classified as inorganic (the topic of most of this article) versus organic. Inorganic fertilizers exclude carbon-containing materials except ureas . Organic fertilizers are usually (recycled) plant- or animal-derived matter. Inorganic are sometimes called synthetic fertilizers since various chemical treatments are required for their manufacture. The main nitrogen-based straight fertilizer

2040-546: Is important to remove the calcium nitrate because calcium nitrate is extremely hygroscopic . " Organic fertilizers " can describe those fertilizers with a biologic origin—derived from living or formerly living materials. Organic fertilizers can also describe commercially available and frequently packaged products that strive to follow the expectations and restrictions adopted by " organic agriculture " and " environmentally friendly " gardening – related systems of food and plant production that significantly limit or strictly avoid

2125-468: Is most mentioned as the "father of the fertilizer industry". Nicolas Théodore de Saussure and scientific colleagues at the time were quick to disprove the simplifications of von Liebig. Prominent scientists whom von Liebig drew were Carl Ludwig Sprenger and Hermann Hellriegel . In this field, a 'knowledge erosion' took place, partly driven by an intermingling of economics and research. John Bennet Lawes , an English entrepreneur , began experimenting on

2210-508: Is often administered as a chelate complex , e.g., the EDTA or EDDHA derivatives. The micronutrient needs depend on the plant and the environment. For example, sugar beets appear to require boron , and legumes require cobalt , while environmental conditions such as heat or drought make boron less available for plants. The production of synthetic, or inorganic, fertilizers require prepared chemicals, whereas organic fertilizers are derived from

2295-450: Is required for the production of DNA ( genetic code ) and ATP , the main energy carrier in cells , as well as certain lipids ( phospholipids , the main components of the lipidic double layer of the cell membranes ). Two sets of enzymatic reactions are highly relevant to the efficiency of nitrogen-based fertilizers. The first is the hydrolysis (reaction with water) of urea ( CO(NH 2 ) 2 ). Many soil bacteria possess

2380-487: Is then hydraulically pressed into shape in a mold and then heat cured at temperatures up to 180 °C for up to 24 hours, depending upon the thickness of the moulded part. Such parts can withstand service temperatures of up to 1150 °C and are often used in the aluminium smelting industry as back-up insulation behind the carbon cathode in the pot cells which contain the molten mixture of cryolite and alumina. The moulded shapes and boards are used in: Exfoliated vermiculite

2465-709: Is typically available as 0-0-60 or 0-0-62 fertilizer. These fertilizers are common. They consist of two or more nutrient components. Major two-component fertilizers provide both nitrogen and phosphorus to the plants. These are called NP fertilizers. The main NP fertilizers are About 85% of MAP and DAP fertilizers are soluble in water. NPK fertilizers are three-component fertilizers providing nitrogen, phosphorus, and potassium. There exist two types of NPK fertilizers: compound and blends. Compound NPK fertilizers contain chemically bound ingredients, while blended NPK fertilizers are physical mixtures of single nutrient components. NPK rating

2550-457: Is typically granulated or powdered. Often solids are available as prills , a solid globule. Liquid fertilizers comprise anhydrous ammonia, aqueous solutions of ammonia, aqueous solutions of ammonium nitrate or urea. These concentrated products may be diluted with water to form a concentrated liquid fertilizer (e.g., UAN ). Advantages of liquid fertilizer are its more rapid effect and easier coverage. The addition of fertilizer to irrigation water

2635-443: Is used to germinate seeds ; very little watering is required. When vermiculite is used alone, seedlings should be fed with a weak fertilizer solution when the first true leaves appear, e.g. with one teaspoon of 5-10-5 soluble fertilizer per US gallon of water (1:768 ratio), gradually increased to one tablespoon (1:256 ratio) when transplanting. Pour vermiculite around bulbs placed in container. If clumps are dug, allow to dry for

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2720-450: Is very important to achieve an even spread. Drilling must not occur on contact with or close to seed, due to the risk of germination damage. Urea dissolves in water for application as a spray or through irrigation systems. In grain and cotton crops, urea is often applied at the time of the last cultivation before planting. In high rainfall areas and on sandy soils (where nitrogen can be lost through leaching) and where good in-season rainfall

2805-651: Is water. The town is within the Blackstone Valley and is drained by the Blackstone River . Millbury has three sites on the National Register of Historic Places : As of the census of 2020, there were 13,831 people, 4,927 households, and 3,443 families residing in the town. The population density was 812.5 inhabitants per square mile (313.7/km ). There were 5,109 housing units at an average density of 324.7 per square mile (125.4/km ). The racial makeup of

2890-634: The Atacama Desert in Chile and was one of the original (1830) nitrogen-rich fertilizers used. It is still mined for fertilizer. Nitrates are also produced from ammonia by the Ostwald process . Phosphate fertilizers are obtained by extraction from phosphate rock , which contains two principal phosphorus-containing minerals, fluorapatite Ca 5 (PO 4 ) 3 F (CFA) and hydroxyapatite Ca 5 (PO 4 ) 3 OH. Billions of kg of phosphate rock are mined annually, but

2975-479: The Institute of Arable Crops Research . The Birkeland–Eyde process was one of the competing industrial processes at the beginning of nitrogen-based fertilizer production. This process was used to fix atmospheric nitrogen (N 2 ) into nitric acid (HNO 3 ), one of several chemical processes called nitrogen fixation . The resultant nitric acid was then used as a source of nitrate (NO 3 ). A factory based on

3060-494: The Ostwald process . It is estimated that a third of annual global food production uses ammonia from the Haber–Bosch process and that this supports nearly half the world's population. After World War II, nitrogen production plants that had ramped up for wartime bomb manufacturing were pivoted towards agricultural uses. The use of synthetic nitrogen fertilizers has increased steadily over the last 50 years, rising almost 20-fold to

3145-630: The Town of Millbury , is a town in Worcester County , Massachusetts , United States. Located within Blackstone Valley , the population in Millbury was 13,831 at the 2020 United States Census . Millbury was first settled by Europeans in 1716. It was originally known as the Second or North Parish of Sutton . Because traveling from one part of the town to the other for meetings was time-consuming, inhabitants of

3230-554: The atmosphere , it is in a form that is unavailable to plants. Nitrogen is the most important fertilizer since nitrogen is present in proteins ( amide bonds between amino acids ), DNA ( puric and pyrimidic bases), and other components (e.g., tetrapyrrolic heme in chlorophyll ). To be nutritious to plants, nitrogen must be made available in a "fixed" form. Only some bacteria and their host plants (notably legumes ) can fix atmospheric nitrogen ( N 2 ) by converting it to ammonia ( NH 3 ). Phosphate ( PO 3− 4 )

3315-587: The poverty line , including 8.2% of those under age 18 and 8.4% of those age 65 or over In 1826, the first formal lyceum school was founded by Josiah Holbrook in Millbury. Public schools in Millbury fall under the jurisdiction of Millbury Public Schools school district . Approximately 2,000 students are educated in three schools: Elmwood Street School, (grades Pre-K through 2); Raymond E. Shaw Elementary School (grades 3 through 6); and Millbury Memorial Junior/Senior High School (grades 7 through 12). Millbury Public Library opened in 1864. In fiscal year 2008,

3400-492: The 1960s. Phosphate and potash have increased in price since the 1960s, which is larger than the consumer price index. Potash is produced in Canada, Russia and Belarus, together making up over half of the world production. Potash production in Canada rose in 2017 and 2018 by 18.6%. Conservative estimates report 30 to 50% of crop yields are attributed to natural or synthetic commercial fertilizers. Fertilizer consumption has surpassed

3485-533: The 19th century, after innovations in plant nutrition , an agricultural industry developed around synthetically created agrochemical fertilizers . This transition was important in transforming the global food system , allowing for larger-scale industrial agriculture with large crop yields. Nitrogen-fixing chemical processes, such as the Haber process invented at the beginning of the 20th century, and amplified by production capacity created during World War II, led to

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3570-609: The EU countries. [REDACTED] Fertilizers are commonly used for growing all crops, with application rates depending on the soil fertility, usually as measured by a soil test and according to the particular crop. Legumes, for example, fix nitrogen from the atmosphere and generally do not require nitrogen fertilizer. Fertilizers are applied to crops both as solids and as liquid. About 90% of fertilizers are applied as solids. The most widely used solid inorganic fertilizers are urea , diammonium phosphate and potassium chloride. Solid fertilizer

3655-508: The Libby area had been identified as suffering from some kind of asbestos-related abnormality. The case ended in acquittals on May 8, 2009. On June 17, 2009, the EPA issued a public health emergency in and near Libby, thereby allowing federal agencies to provide funding for health care, and for removal of contaminated insulation from affected homes. Millbury, Massachusetts Millbury , officially

3740-674: The North Parish petitioned the Massachusetts General Court to split Sutton. North Parish became Millbury on June 11, 1813, by way of an act of incorporation. Its name derived from its long history as a mill town . The Blackstone River flows through the town, and during the Industrial Revolution , provided water power to its many textile mills and factories . During this time, the inventor William Crompton worked in Millbury. Millbury's industrial history begins in

3825-622: The adverse environmental effects of fertilizer and pesticide use and environmental damage caused by industrial agriculture . Management of soil fertility has preoccupied farmers since the beginning of agriculture. Middle Eastern, Chinese, Mesoamerican, and Cultures of the Central Andes were all early adopters of agriculture. This is thought to have led to their cultures growing faster in population which allowed an exportation of culture to neighboring hunter-gatherer groups. Fertilizer use along with agriculture allowed some of these early societies

3910-663: The amount of farmland in the United States. Data on the fertilizer consumption per hectare arable land in 2012 are published by The World Bank . The diagram below shows fertilizer consumption by the European Union (EU) countries as kilograms per hectare (pounds per acre). The total consumption of fertilizer in the EU is 15.9 million tons for 105 million hectare arable land area (or 107 million hectare arable land according to another estimate ). This figure equates to 151 kg of fertilizers consumed per ha arable land on average by

3995-479: The celebration. Later that year, a proposal for a casino was made, but the related development company pulled out when it became clear that a large majority of inhabitants were against the proposal. According to the United States Census Bureau , Millbury has a total area of 16.3 square miles (42 km ), of which 15.7 square miles (41 km ) is land and 0.5 square miles (1.3 km ), or 3.20%,

4080-523: The current rate of 100 million tonnes of nitrogen per year. The development of synthetic nitrogen fertilizers has significantly supported global population growth. It has been estimated that almost half the people on the Earth are currently fed due to synthetic nitrogen fertilizer use. The use of phosphate fertilizers has also increased from 9 million tonnes per year in 1960 to 40 million tonnes per year in 2000. Agricultural use of inorganic fertilizers in 2021

4165-457: The early 1970s, Millbury experienced a number of large fires . The town hall burned down, followed by the Union School. A propane plant near Route 146 exploded, causing considerable damage and making nationwide news. In 2004, Millbury was designated as a Preserve America community. Millbury celebrated its bicentennial in 2013. The local Vaillancourt Folk Art designed chalkware for

4250-427: The early days of their use, these products were batched at or very close to the place of installation. This continues to be the case in some limited circumstances; however, more and more use is being made of pre-batched, proprietary mixes. Mixes containing vermiculite are used in areas where strength and corrosion/abrasion resistance are of secondary importance, the most important factor being the insulation performance of

4335-511: The early eighteenth century, not long after the area's settlement. In 1735, John Singletary began operating a mill on Singletary Brook, a stream flowing out of Singletary Lake. Around 1753, Singletary built the S & D Spinning Mill, which is still in operation, making it one of the oldest continuously operated mills in the United States . The mill is featured on the Town Seal. The mill also makes

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4420-441: The effects of various manures on plants growing in pots in 1837, and a year or two later the experiments were extended to crops in the field. One immediate consequence was that in 1842 he patented a manure formed by treating phosphates with sulfuric acid, and thus was the first to create the artificial manure industry. In the succeeding year, he enlisted the services of Joseph Henry Gilbert ; together they performed crop experiments at

4505-516: The elements, but the elements are not used as fertilizers. Instead, compounds containing these elements are the basis of fertilizers. The macro-nutrients are consumed in larger quantities and are present in plant tissue in quantities from 0.15% to 6.0% on a dry matter (DM) (0% moisture) basis. Plants are made up of four main elements: hydrogen, oxygen, carbon, and nitrogen. Carbon, hydrogen, and oxygen are widely available respectively in carbon dioxide and in water. Although nitrogen makes up most of

4590-457: The enzyme urease , which catalyzes the conversion of urea to ammonium ion ( NH + 4 ) and bicarbonate ion ( HCO − 3 ). Ammonia-oxidizing bacteria (AOB), such as species of Nitrosomonas , oxidize ammonia ( NH 3 ) to nitrite ( NO − 2 ), a process termed nitrification . Nitrite-oxidizing bacteria , especially Nitrobacter , oxidize nitrite ( NO − 2 ) to nitrate ( NO − 3 ), which

4675-481: The fines ($ 54.5 million) levied on them from the EPA, but the Supreme Court rejected the appeal. The United States government pursued criminal charges against several former executives and managers of the mine for allegedly disregarding and covering up health risks to employees. They were also accused of wire fraud, and of obstructing the government's cleanup efforts. As of the indictment date, about 1,200 residents of

4760-565: The health risks associated with vermiculite and that several sites in the Salt Lake Valley had been remediated by the EPA when they were shown to be contaminated with asbestos. W. R. Grace and Company has vigorously denied these charges. The vermiculite deposit at the mine in Libby, Montana, was (and is) heavily contaminated with asbestos. Numerous people were knowingly exposed to the harmful dust of vermiculite that contained asbestos. Unfortunately,

4845-402: The in-place refractory lining . These mixes are used in industries including iron/steel, cement, and hydrocarbon processing. Vermiculite is used as an additive to fireproof wallboard . Vermiculite dispersions are typically either chemically or physically very finely delaminated vermiculite in a fluid medium. These dispersions can be used to make vermiculite 'paper' sheets by pouring them onto

4930-529: The industry's interests and to exchange information. Although not all vermiculite contains asbestos , some products were made with vermiculite that contained asbestos until the early 1990s. Vermiculite mines throughout the world are now regularly tested for it and are supposed to sell products that contain no asbestos. The former vermiculite mine in Libby, Montana , did have tremolite asbestos as well as winchite and richterite (both fibrous amphiboles )—in fact, it

5015-583: The inner parts of the Rawlings baseballs for use in Major League Baseball . In the late eighteenth and early nineteenth centuries, after learning the trade of firearms production from their father, Asa Waters and his brother, Elijah, purchased land along the Blackstone River and built mills producing goods such as guns , scythes , and sawmill equipment. In 1808, they erected an armory , which

5100-407: The largest producer and consumer of nitrogen fertilizers while Africa has little reliance on nitrogen fertilizers. Agricultural and chemical minerals are very important in industrial use of fertilizers, which is valued at approximately $ 200 billion. Nitrogen has a significant impact in the global mineral use, followed by potash and phosphate. The production of nitrogen has drastically increased since

5185-409: The largest user of each nutrient. A maize crop yielding 6–9 tonnes of grain per hectare (2.5 acres) requires 31–50 kilograms (68–110 lb) of phosphate fertilizer to be applied; soybean crops require about half, 20–25 kg per hectare. Yara International is the world's largest producer of nitrogen-based fertilizers. Fertilizers enhance the growth of plants. This goal is met in two ways,

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5270-439: The materials have consumer appeal. No matter the definition nor composition, most of these products contain less-concentrated nutrients, and the nutrients are not as easily quantified. They can offer soil-building advantages as well as be appealing to those who are trying to farm / garden more "naturally". In terms of volume, peat is the most widely used packaged organic soil amendment. It is an immature form of coal and improves

5355-513: The mid-1990s—and especially those known to contain the "Zonolite" brand—may contain asbestos, and therefore may be a health concern. An article published in The Salt Lake Tribune on December 3, 2006, reported that vermiculite and Zonolite had been found to contain asbestos, which had led to cancers such as those found in asbestos-related cases. The article stated that there had been a cover-up by W. R. Grace and Company and others regarding

5440-425: The mine had been operating since the 1920s, and environmental and industrial controls were virtually non-existent until the mine was purchased by the W. R. Grace and Company in 1963. Yet, knowing the human health risks, the mining company still continued to operate there until 1990. Consequently, many of the former miners and residents of Libby have been affected and continue to suffer health problems. Over 400 people in

5525-537: The ore involves some purification steps, e.g., to remove sodium chloride (NaCl) (common salt ). Sometimes potash is referred to as K 2 O, as a matter of convenience to those describing the potassium content. In fact, potash fertilizers are usually potassium chloride , potassium sulfate , potassium carbonate , or potassium nitrate . There are three major routes for manufacturing NPK fertilizers (named for their main ingredients: nitrogen (N), phosphorus (P), and potassium (K)): Step 2. Removal of Calcium Nitrate. It

5610-629: The organic processes of plants and animals in biological processes using biochemicals. Nitrogen fertilizers are made from ammonia (NH 3 ) produced by the Haber–Bosch process . In this energy-intensive process, natural gas (CH 4 ) usually supplies the hydrogen , and the nitrogen (N 2 ) is derived from the air . This ammonia is used as a feedstock for all other nitrogen fertilizers, such as anhydrous ammonium nitrate (NH 4 NO 3 ) and urea (CO(NH 2 ) 2 ). Deposits of sodium nitrate (NaNO 3 ) ( Chilean saltpeter ) are also found in

5695-489: The pollution-control of air in mines and gases in industrial processes. In addition to its ion exchange properties, exfoliated vermiculite can retain liquids within the inter-laminar voids of the individual particles, as well as between the particles themselves. In 2014, South Africa, Brazil, the US, and China were the top producers of mined, concentrated and unexfoliated vermiculite, with about 90% world share. South Africa's production

5780-582: The process was built in Rjukan and Notodden in Norway and large hydroelectric power facilities were built. The 1910s and 1920s witnessed the rise of the Haber process and the Ostwald process . The Haber process produces ammonia (NH 3 ) from methane (CH 4 ) ( natural gas ) gas and molecular nitrogen (N 2 ) from the air. The ammonia from the Haber process is then partially converted into nitric acid (HNO 3 ) in

5865-416: The professional horticulturalist and for the home gardener. These mixes promote faster root growth and give quick anchorage to young roots. The mixture helps retain air, fertilizer, and moisture, releasing them as the plant requires them. These mixes were pioneered by Boodley and Sheldrake. Exfoliated vermiculite is also used as a growing medium for hydroponics . Vermiculite, alone or mixed with soil or peat,

5950-410: The size and quality of the remaining ore is decreasing. These minerals are converted into water-soluble phosphate salts by treatment with acids . The large production of sulfuric acid is primarily motivated by this application. In the nitrophosphate process or Odda process (invented in 1927), phosphate rock with up to a 20% phosphorus (P) content is dissolved with nitric acid (HNO 3 ) to produce

6035-442: The slaughter of animals – bloodmeal , bone meal , feather meal , hides, hoofs, and horns all are typical components. Organically derived materials available to industry such as sewage sludge may not be acceptable components of organic farming and gardening, because of factors ranging from residual contaminants to public perception. On the other hand, marketed "organic fertilizers" may include, and promote, processed organics because

6120-456: The soil by aeration and absorbing water but confers no nutritional value to the plants. It is therefore not a fertilizer as defined in the beginning of the article, but rather an amendment. Coir , (derived from coconut husks), bark, and sawdust when added to soil all act similarly (but not identically) to peat and are also considered organic soil amendments – or texturizers – because of their limited nutritive inputs. Some organic additives can have

6205-499: The system is a conventional shorthand for the amount of the phosphorus (P) or potassium (K) in a fertilizer. A 50-pound (23 kg) bag of fertilizer labeled 16-4-8 contains 8 lb (3.6 kg) of nitrogen (16% of the 50 pounds), an amount of phosphorus equivalent to that in 2 pounds of P 2 O 5 (4% of 50 pounds), and 4 pounds of K 2 O (8% of 50 pounds). Most fertilizers are labeled according to this N-P-K convention, although Australian convention, following an N-P-K-S system, adds

6290-633: The town during his youth. He visited his aunt, Delia C. Torrey, during his presidency to celebrate Millbury's centennial . The Torrey House, where President Taft stayed, is now commonly called the Taft House. In 1824, the mineral called Vermiculite was first found in Millbury. Due to the Flood Control Act of 1944 , the Worcester Flood Diversion Channel was constructed in that year within Millbury, as well as nearby Auburn . In

6375-417: The town have died from asbestos-related disease due to contamination from vermiculite mining from nearby Zonolite Mountain, where soil samples were found to be loaded with fibrous tremolite (known to be a very hazardous form of asbestos), and countless others there who insulated their homes with Zonolite have succumbed to asbestos-related diseases, most of whom never were employed in environments where asbestos

6460-708: The town spent 1.15% ($ 358,097) of its budget on the library. Fertilizer A fertilizer ( American English ) or fertiliser ( British English ) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients . Fertilizers may be distinct from liming materials or other non-nutrient soil amendments . Many sources of fertilizer exist, both natural and industrially produced. For most modern agricultural practices, fertilization focuses on three main macro nutrients: nitrogen (N), phosphorus (P), and potassium (K) with occasional addition of supplements like rock flour for micronutrients. Farmers apply these fertilizers in

6545-402: The town was 97.19% White , 0.53% African American , 0.15% Native American , 1.02% Asian , 0.03% Pacific Islander , 0.23% from other races , and 0.84% from two or more races. Hispanic or Latino of any race were 1.02% of the population. There were 4,927 households, out of which 30.2% had children under the age of 18 living with them, 55.7% were married couples living together, 10.9% had

6630-407: The traditional one being additives that provide nutrients. The second mode by which some fertilizers act is to enhance the effectiveness of the soil by modifying its water retention and aeration. This article, like many on fertilizers, emphasizes the nutritional aspect. Fertilizers typically provide, in varying proportions : The nutrients required for healthy plant life are classified according to

6715-568: The use of synthetic fertilizers and pesticides. The "organic fertilizer" products typically contain both some organic materials as well as acceptable additives such as nutritive rock powders, ground seashells (crab, oyster, etc.), other prepared products such as seed meal or kelp, and cultivated microorganisms and derivatives. Fertilizers of an organic origin (the first definition) include animal wastes , plant wastes from agriculture, seaweed , compost , and treated sewage sludge ( biosolids ). Beyond manures, animal sources can include products from

6800-570: The vermiculite was sold under the commercial name Zonolite. The Zonolite brand and the mine were acquired by the W. R. Grace and Company in 1963. Mining operations at the Libby site stopped in 1990 in response to asbestos contamination. While in operation, the Libby mine may have produced 80% of the world's supply of vermiculite. The United States government estimates that vermiculite was used in more than 35 million homes, but does not recommend its removal. Nevertheless, homes or structures containing vermiculite or vermiculite insulation dating from before

6885-491: Was 195 million tonnes of nutrients, of which 56% was nitrogen. Asia represented 53% of the world's total agricultural use of inorganic fertilizers in 2021, followed by the Americas (29%), Europe (12%), Africa (4%) and Oceania (2%). This ranking of the regions is the same for all nutrients. The main users of inorganic fertilizers are, in descending order, China, India, Brazil, and the United States of America (see Table 15), with China

6970-406: Was 39 years. For every 100 females, there were 93.3 males. For every 100 females age 18 and over, there were 88.4 males. The median income for a household in the town was $ 51,415, and the median income for a family was $ 62,564. Males had a median income of $ 41,912 versus $ 28,973 for females. The per capita income for the town was $ 23,531. About 4.1% of families and 6.3% of the population were below

7055-476: Was an issue. After a 1999 Seattle Post-Intelligencer story claimed that asbestos-related disease was common in the town, the EPA, in response to political pressure, made cleanup of the site a priority and called Libby the worst case of community-wide exposure to a toxic substance in U.S. history. The EPA has spent $ 120 million in Superfund money on cleanup. In October 2006, W. R. Grace and Company tried to appeal

7140-408: Was formed underground through essentially the same geologic processes as the contaminants. Pure vermiculite does not contain asbestos and is non-toxic. Impure vermiculite may contain, apart from asbestos, also minor diopside or remnants of the precursor minerals biotite or phlogopite . The largest and oldest vermiculite mine in the United States was started in the 1920s, at Libby, Montana , and

7225-582: Was successful until forced to close suddenly in 1841. It reopened at the start of the American Civil War in 1861. With the wealth received from the industry, Asa began construction of the Asa Waters Mansion in 1826. Designed by local architect Asher Benjamin , it was completed six years later. Louise Taft , mother of United States President William Howard Taft , resided in Millbury for many years, and President Taft spent many summer vacations in

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