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104-547: Cryo- is from the Ancient Greek κρύος (krúos, “ ice , icy cold, chill, frost”). Uses of the prefix Cryo- include: [REDACTED] The dictionary definition of cryo- at Wiktionary Ice Ice is water that is frozen into a solid state, typically forming at or below temperatures of 0 ° C , 32 ° F , or 273.15 K . It occurs naturally on Earth , on other planets, in Oort cloud objects, and as interstellar ice . As

208-619: A density between a quarter and two thirds that of pure ice, due to a high proportion of trapped air, which also makes soft rime appear white. Hard rime is denser, more transparent, and more likely to appear on ships and aircraft. Cold wind specifically causes what is known as advection frost when it collides with objects. When it occurs on plants, it often causes damage to them. Various methods exist to protect agricultural crops from frost - from simply covering them to using wind machines. In recent decades, irrigation sprinklers have been calibrated to spray just enough water to preemptively create

312-695: A donor, particularly when the carbon or one of its neighbors is electronegative (e.g., in chloroform, aldehydes and terminal acetylenes). Gradually, it was recognized that there are many examples of weaker hydrogen bonding involving donor other than N, O, or F and/or acceptor Ac with electronegativity approaching that of hydrogen (rather than being much more electronegative). Although weak (≈1 kcal/mol), "non-traditional" hydrogen bonding interactions are ubiquitous and influence structures of many kinds of materials. The definition of hydrogen bonding has gradually broadened over time to include these weaker attractive interactions. In 2011, an IUPAC Task Group recommended

416-587: A feat that would only be possible if the hydrogen bond contained some covalent character. The concept of hydrogen bonding once was challenging. Linus Pauling credits T. S. Moore and T. F. Winmill with the first mention of the hydrogen bond, in 1912. Moore and Winmill used the hydrogen bond to account for the fact that trimethylammonium hydroxide is a weaker base than tetramethylammonium hydroxide . The description of hydrogen bonding in its better-known setting, water, came some years later, in 1920, from Latimer and Rodebush. In that paper, Latimer and Rodebush cited

520-410: A few molecules in the droplet need to get together by chance to form an arrangement similar to that in an ice lattice; then the droplet freezes around this "nucleus". Experiments show that this "homogeneous" nucleation of cloud droplets only occurs at temperatures lower than −35 °C (238 K; −31 °F). In warmer clouds an aerosol particle or "ice nucleus" must be present in (or in contact with)

624-689: A form of precipitation consisting of small, translucent balls of ice, which are usually smaller than hailstones. This form of precipitation is also referred to as "sleet" by the United States National Weather Service . (In British English "sleet" refers to a mixture of rain and snow .) Ice pellets typically form alongside freezing rain, when a wet warm front ends up between colder and drier atmospheric layers. There, raindrops would both freeze and shrink in size due to evaporative cooling. So-called snow pellets, or graupel , form when multiple water droplets freeze onto snowflakes until

728-555: A function of temperature and sliding speed. 2014 research suggests that frictional heating is the most important process under most typical conditions. The term that collectively describes all of the parts of the Earth's surface where water is in frozen form is the cryosphere . Ice is an important component of the global climate, particularly in regard to the water cycle. Glaciers and snowpacks are an important storage mechanism for fresh water; over time, they may sublimate or melt. Snowmelt

832-432: A hailstone becomes too heavy to be supported by the storm's updraft, it falls from the cloud. Hail forms in strong thunderstorm clouds, particularly those with intense updrafts, high liquid water content, great vertical extent, large water droplets, and where a good portion of the cloud layer is below freezing 0 °C (32 °F). Hail-producing clouds are often identifiable by their green coloration. The growth rate

936-577: A key role in Earth's water cycle and climate . In the recent decades, ice volume on Earth has been decreasing due to climate change . The largest declines have occurred in the Arctic and in the mountains located outside of the polar regions. The loss of grounded ice (as opposed to floating sea ice ) is the primary contributor to sea level rise . Humans have been using ice for various purposes for thousands of years. Some historic structures designed to hold ice to provide cooling are over 2,000 years old. Before

1040-419: A layer of ice that would form slowly and so avoid a sudden temperature shock to the plant, and not be so thick as to cause damage with its weight. Ablation of ice refers to both its melting and its dissolution . The melting of ice entails the breaking of hydrogen bonds between the water molecules. The ordering of the molecules in the solid breaks down to a less ordered state and the solid melts to become

1144-456: A liquid. This is achieved by increasing the internal energy of the ice beyond the melting point . When ice melts it absorbs as much energy as would be required to heat an equivalent amount of water by 80 °C. While melting, the temperature of the ice surface remains constant at 0 °C. The rate of the melting process depends on the efficiency of the energy exchange process. An ice surface in fresh water melts solely by free convection with

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1248-436: A low speed. Ice forms on calm water from the shores, a thin layer spreading across the surface, and then downward. Ice on lakes is generally four types: primary, secondary, superimposed and agglomerate. Primary ice forms first. Secondary ice forms below the primary ice in a direction parallel to the direction of the heat flow. Superimposed ice forms on top of the ice surface from rain or water which seeps up through cracks in

1352-447: A modern evidence-based definition of hydrogen bonding, which was published in the IUPAC journal Pure and Applied Chemistry . This definition specifies: The hydrogen bond is an attractive interaction between a hydrogen atom from a molecule or a molecular fragment X−H in which X is more electronegative than H, and an atom or a group of atoms in the same or another molecule, in which there

1456-581: A naturally occurring crystalline inorganic solid with an ordered structure, ice is considered to be a mineral . Depending on the presence of impurities such as particles of soil or bubbles of air , it can appear transparent or a more or less opaque bluish-white color. Virtually all of the ice on Earth is of a hexagonal crystalline structure denoted as ice I h (spoken as "ice one h"). Depending on temperature and pressure, at least nineteen phases ( packing geometries ) can exist. The most common phase transition to ice I h occurs when liquid water

1560-505: A rate that depends linearly on the water temperature, T ∞ , when T ∞ is less than 3.98 °C, and superlinearly when T ∞ is equal to or greater than 3.98 °C, with the rate being proportional to (T ∞  − 3.98 °C) , with α  =  ⁠ 5 / 3 ⁠ for T ∞ much greater than 8 °C, and α =  ⁠ 4 / 3 ⁠ for in between temperatures T ∞ . In salty ambient conditions, dissolution rather than melting often causes

1664-487: A single oxygen atom covalently bonded to two hydrogen atoms , or H–O–H. However, many of the physical properties of water and ice are controlled by the formation of hydrogen bonds between adjacent oxygen and hydrogen atoms; while it is a weak bond, it is nonetheless critical in controlling the structure of both water and ice. An unusual property of water is that its solid form—ice frozen at atmospheric pressure —is approximately 8.3% less dense than its liquid form; this

1768-746: A soft ball-like shape is formed. So-called " diamond dust ", (METAR code IC ) also known as ice needles or ice crystals, forms at temperatures approaching −40 °C (−40 °F) due to air with slightly higher moisture from aloft mixing with colder, surface-based air. As water drips and re-freezes, it can form hanging icicles , or stalagmite -like structures on the ground. On sloped roofs, buildup of ice can produce an ice dam , which stops melt water from draining properly and potentially leads to damaging leaks. More generally, water vapor depositing onto surfaces due to high relative humidity and then freezing results in various forms of atmospheric icing , or frost . Inside buildings, this can be seen as ice on

1872-471: A temperature of −78.5 °C (−109.3 °F), the vaporization point of solid carbon dioxide (dry ice). Most liquids under increased pressure freeze at higher temperatures because the pressure helps to hold the molecules together. However, the strong hydrogen bonds in water make it different: for some pressures higher than 1 atm (0.10 MPa), water freezes at a temperature below 0 °C (32 °F). Ice, water, and water vapour can coexist at

1976-574: A thin surface layer, which makes it particularly hazardous to walk across it. Another dangerous form of rotten ice to traverse on foot is candle ice, which develops in columns perpendicular to the surface of a lake. Because it lacks a firm horizontal structure, a person who has fallen through has nothing to hold onto to pull themselves out. Snow crystals form when tiny supercooled cloud droplets (about 10  μm in diameter) freeze . These droplets are able to remain liquid at temperatures lower than −18 °C (255 K; 0 °F), because to freeze,

2080-414: A water molecule is up to four. The number of hydrogen bonds formed by a molecule of liquid water fluctuates with time and temperature. From TIP4P liquid water simulations at 25 °C, it was estimated that each water molecule participates in an average of 3.59 hydrogen bonds. At 100 °C, this number decreases to 3.24 due to the increased molecular motion and decreased density, while at 0 °C,

2184-530: A weakening of the X−H bond. Certain hydrogen bonds - improper hydrogen bonds - show a blue shift of the X−H stretching frequency and a decrease in the bond length. H-bonds can also be measured by IR vibrational mode shifts of the acceptor. The amide I mode of backbone carbonyls in α-helices shifts to lower frequencies when they form H-bonds with side-chain hydroxyl groups. The dynamics of hydrogen bond structures in water can be probed by this OH stretching vibration. In

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2288-455: Is H-bonded with up to four other molecules, as shown in the figure (two through its two lone pairs, and two through its two hydrogen atoms). Hydrogen bonding strongly affects the crystal structure of ice , helping to create an open hexagonal lattice. The density of ice is less than the density of water at the same temperature; thus, the solid phase of water floats on the liquid, unlike most other substances. Liquid water's high boiling point

2392-442: Is a basic cause of freeze-thaw weathering of rock in nature and damage to building foundations and roadways from frost heaving . It is also a common cause of the flooding of houses when water pipes burst due to the pressure of expanding water when it freezes. Because ice is less dense than liquid water, it floats, and this prevents bottom-up freezing of the bodies of water. Instead, a sheltered environment for animal and plant life

2496-427: Is a lone pair of electrons in nonmetallic atoms (most notably in the nitrogen , and chalcogen groups). In some cases, these proton acceptors may be pi-bonds or metal complexes . In the dihydrogen bond, however, a metal hydride serves as a proton acceptor, thus forming a hydrogen-hydrogen interaction. Neutron diffraction has shown that the molecular geometry of these complexes is similar to hydrogen bonds, in that

2600-432: Is a pair of water molecules with one hydrogen bond between them, which is called the water dimer and is often used as a model system. When more molecules are present, as is the case with liquid water, more bonds are possible because the oxygen of one water molecule has two lone pairs of electrons, each of which can form a hydrogen bond with a hydrogen on another water molecule. This can repeat such that every water molecule

2704-422: Is a strong type of hydrogen bond. It is characterized by the π-delocalization that involves the hydrogen and cannot be properly described by the electrostatic model alone. This description of the hydrogen bond has been proposed to describe unusually short distances generally observed between O=C−OH··· or ···O=C−C=C−OH . The X−H distance is typically ≈110  pm , whereas

2808-427: Is abundant on the Earth's surface, particularly in the polar regions and above the snow line , where it can aggregate from snow to form glaciers and ice sheets . As snowflakes and hail , ice is a common form of precipitation , and it may also be deposited directly by water vapor as frost . The transition from ice to water is melting and from ice directly to water vapor is sublimation . These processes plays

2912-407: Is also responsible for many of the physical and chemical properties of compounds of N, O, and F that seem unusual compared with other similar structures. In particular, intermolecular hydrogen bonding is responsible for the high boiling point of water (100 °C) compared to the other group-16 hydrides that have much weaker hydrogen bonds. Intramolecular hydrogen bonding is partly responsible for

3016-418: Is also seen in the bifluoride ion [F···H···F] . Due to severe steric constraint, the protonated form of Proton Sponge (1,8-bis(dimethylamino)naphthalene) and its derivatives also have symmetric hydrogen bonds ( [N···H···N] ), although in the case of protonated Proton Sponge, the assembly is bent. The hydrogen bond can be compared with

3120-410: Is an essential step in water reorientation. Acceptor-type hydrogen bonds (terminating on an oxygen's lone pairs) are more likely to form bifurcation (it is called overcoordinated oxygen, OCO) than are donor-type hydrogen bonds, beginning on the same oxygen's hydrogens. For example, hydrogen fluoride —which has three lone pairs on the F atom but only one H atom—can form only two bonds; ( ammonia has

3224-424: Is an important source of seasonal fresh water. The World Meteorological Organization defines several kinds of ice depending on origin, size, shape, influence and so on. Clathrate hydrates are forms of ice that contain gas molecules trapped within its crystal lattice. Ice that is found at sea may be in the form of drift ice floating in the water, fast ice fixed to a shoreline or anchor ice if attached to

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3328-498: Is cooled below 0  °C ( 273.15  K , 32  °F ) at standard atmospheric pressure . When water is cooled rapidly ( quenching ), up to three types of amorphous ice can form. Interstellar ice is overwhelmingly low-density amorphous ice (LDA), which likely makes LDA ice the most abundant type in the universe. When cooled slowly, correlated proton tunneling occurs below −253.15  °C ( 20  K , −423.67  °F ) giving rise to macroscopic quantum phenomena . Ice

3432-490: Is divided into four categories: pore ice, vein ice (also known as ice wedges), buried surface ice and intrasedimental ice (from the freezing of underground waters). One example of ice formation in permafrost areas is aufeis - layered ice that forms in Arctic and subarctic stream valleys. Ice, frozen in the stream bed, blocks normal groundwater discharge, and causes the local water table to rise, resulting in water discharge on top of

3536-416: Is due to the high number of hydrogen bonds each molecule can form, relative to its low molecular mass . Owing to the difficulty of breaking these bonds, water has a very high boiling point, melting point, and viscosity compared to otherwise similar liquids not conjoined by hydrogen bonds. Water is unique because its oxygen atom has two lone pairs and two hydrogen atoms, meaning that the total number of bonds of

3640-435: Is equivalent to a volumetric expansion of 9%. The density of ice is 0.9167 –0.9168  g/cm at 0 °C and standard atmospheric pressure (101,325 Pa), whereas water has a density of 0.9998 –0.999863  g/cm at the same temperature and pressure. Liquid water is densest, essentially 1.00 g/cm , at 4 °C and begins to lose its density as the water molecules begin to form the hexagonal crystals of ice as

3744-556: Is evidence of bond formation. Hydrogen bonds can vary in strength from weak (1–2 kJ/mol) to strong (161.5 kJ/mol in the bifluoride ion, HF − 2 ). Typical enthalpies in vapor include: The strength of intermolecular hydrogen bonds is most often evaluated by measurements of equilibria between molecules containing donor and/or acceptor units, most often in solution. The strength of intramolecular hydrogen bonds can be studied with equilibria between conformers with and without hydrogen bonds. The most important method for

3848-484: Is extremely rare otherwise. Even icy moons like Ganymede are expected to mainly consist of other crystalline forms of ice. Water in the interstellar medium is dominated by amorphous ice, making it likely the most common form of water in the universe. Low-density ASW (LDA), also known as hyperquenched glassy water, may be responsible for noctilucent clouds on Earth and is usually formed by deposition of water vapor in cold or vacuum conditions. High-density ASW (HDA)

3952-484: Is formed beneath the floating ice, which protects the underside from short-term weather extremes such as wind chill . Sufficiently thin floating ice allows light to pass through, supporting the photosynthesis of bacterial and algal colonies. When sea water freezes, the ice is riddled with brine-filled channels which sustain sympagic organisms such as bacteria, algae, copepods and annelids . In turn, they provide food for animals such as krill and specialized fish like

4056-452: Is formed by compression of ordinary ice I h or LDA at GPa pressures. Very-high-density ASW (VHDA) is HDA slightly warmed to 160 K under 1–2 GPa pressures. Ice from a theorized superionic water may possess two crystalline structures. At pressures in excess of 500,000 bars (7,300,000 psi) such superionic ice would take on a body-centered cubic structure. However, at pressures in excess of 1,000,000 bars (15,000,000 psi)

4160-473: Is formed. When the spacing is less, between positions i and i + 3 , then a 3 10 helix is formed. When two strands are joined by hydrogen bonds involving alternating residues on each participating strand, a beta sheet is formed. Hydrogen bonds also play a part in forming the tertiary structure of protein through interaction of R-groups. (See also protein folding ). Bifurcated H-bond systems are common in alpha-helical transmembrane proteins between

4264-448: Is maximized at about −13 °C (9 °F), and becomes vanishingly small much below −30 °C (−22 °F) as supercooled water droplets become rare. For this reason, hail is most common within continental interiors of the mid-latitudes, as hail formation is considerably more likely when the freezing level is below the altitude of 11,000 feet (3,400 m). Entrainment of dry air into strong thunderstorms over continents can increase

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4368-464: Is over 70% ice on its surface is said to be covered by pack ice. Fully formed sea ice can be forced together by currents and winds to form pressure ridges up to 12 metres (39 ft) tall. On the other hand, active wave activity can reduce sea ice to small, regularly shaped pieces, known as pancake ice . Sometimes, wind and wave activity "polishes" sea ice to perfectly spherical pieces known as ice eggs . The largest ice formations on Earth are

4472-409: Is shifted toward slightly lower energies. Thus, ice appears blue, with a slightly greener tint than liquid water. Since absorption is cumulative, the color effect intensifies with increasing thickness or if internal reflections cause the light to take a longer path through the ice. Other colors can appear in the presence of light absorbing impurities, where the impurity is dictating the color rather than

4576-468: Is still not well established, though several mechanisms have been proposed. Computer molecular dynamics simulations suggest that osmolytes stabilize proteins by modifying the hydrogen bonds in the protein hydration layer. Several studies have shown that hydrogen bonds play an important role for the stability between subunits in multimeric proteins. For example, a study of sorbitol dehydrogenase displayed an important hydrogen bonding network which stabilizes

4680-611: Is the Lewis base. Hydrogen bonds are represented as H···Y system, where the dots represent the hydrogen bond. Liquids that display hydrogen bonding (such as water) are called associated liquids . Hydrogen bonds arise from a combination of electrostatics (multipole-multipole and multipole-induced multipole interactions), covalency (charge transfer by orbital overlap), and dispersion ( London forces ). In weaker hydrogen bonds, hydrogen atoms tend to bond to elements such as sulfur (S) or chlorine (Cl); even carbon (C) can serve as

4784-531: Is therefore slower than melting. Ice has long been valued as a means of cooling. In 400 BC Iran, Persian engineers had already developed techniques for ice storage in the desert through the summer months. During the winter, ice was transported from harvesting pools and nearby mountains in large quantities to be stored in specially designed, naturally cooled refrigerators , called yakhchal (meaning ice storage ). Yakhchals were large underground spaces (up to 5000 m ) that had thick walls (at least two meters at

4888-466: The H·;··Y distance is ≈160 to 200 pm. The typical length of a hydrogen bond in water is 197 pm. The ideal bond angle depends on the nature of the hydrogen bond donor. The following hydrogen bond angles between a hydrofluoric acid donor and various acceptors have been determined experimentally: Strong hydrogen bonds are revealed by downfield shifts in the H NMR spectrum . For example,

4992-446: The bald notothen , fed upon in turn by larger animals such as emperor penguins and minke whales . When ice melts, it absorbs as much energy as it would take to heat an equivalent mass of water by 80 °C (176 °F). During the melting process, the temperature remains constant at 0 °C (32 °F). While melting, any energy added breaks the hydrogen bonds between ice (water) molecules. Energy becomes available to increase

5096-473: The intramolecular bound states of, for example, covalent or ionic bonds . However, hydrogen bonding is generally still a bound state phenomenon, since the interaction energy has a net negative sum. The initial theory of hydrogen bonding proposed by Linus Pauling suggested that the hydrogen bonds had a partial covalent nature. This interpretation remained controversial until NMR techniques demonstrated information transfer between hydrogen-bonded nuclei,

5200-408: The secondary and tertiary structures of proteins and nucleic acids . In a hydrogen bond, the electronegative atom not covalently attached to the hydrogen is named the proton acceptor, whereas the one covalently bound to the hydrogen is named the proton donor. This nomenclature is recommended by the IUPAC. The hydrogen of the donor is protic and therefore can act as a Lewis acid and the acceptor

5304-752: The triple point , which is exactly 273.16 K (0.01 °C) at a pressure of 611.657  Pa . The kelvin was defined as ⁠ 1 / 273.16 ⁠ of the difference between this triple point and absolute zero , though this definition changed in May 2019. Unlike most other solids, ice is difficult to superheat . In an experiment, ice at −3 °C was superheated to about 17 °C for about 250 picoseconds . Subjected to higher pressures and varying temperatures, ice can form in nineteen separate known crystalline phases at various densities, along with hypothetical proposed phases of ice that have not been observed. With care, at least fifteen of these phases (one of

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5408-473: The "Ice King", worked on developing better insulation products for long distance shipments of ice, especially to the tropics; this became known as the ice trade. Between 1812 and 1822, under Lloyd Hesketh Bamford Hesketh 's instruction, Gwrych Castle was built with 18 large towers, one of those towers is called the 'Ice Tower'. Its sole purpose was to store Ice. Trieste sent ice to Egypt , Corfu , and Zante ; Switzerland, to France; and Germany sometimes

5512-722: The United States, with a combined value of shipments of $ 595,487,000. Home refrigerators can also make ice with a built in icemaker , which will typically make ice cubes or crushed ice. The first such device was presented in 1965 by Frigidaire . Ice forming on roads is a common winter hazard, and black ice particularly dangerous because it is very difficult to see. It is both very transparent, and often forms specifically in shaded (and therefore cooler and darker) areas, i.e. beneath overpasses . Hydrogen bond Hydrogen bonds can be intermolecular (occurring between separate molecules) or intramolecular (occurring among parts of

5616-469: The ablation of ice. For example, the temperature of the Arctic Ocean is generally below the melting point of ablating sea ice. The phase transition from solid to liquid is achieved by mixing salt and water molecules, similar to the dissolution of sugar in water, even though the water temperature is far below the melting point of the sugar. However, the dissolution rate is limited by salt concentration and

5720-446: The acidic proton in the enol tautomer of acetylacetone appears at ⁠ δ H {\displaystyle \delta _{\text{H}}} ⁠  15.5, which is about 10 ppm downfield of a conventional alcohol. In the IR spectrum, hydrogen bonding shifts the X−H stretching frequency to lower energy (i.e. the vibration frequency decreases). This shift reflects

5824-553: The average number of hydrogen bonds increases to 3.69. Another study found a much smaller number of hydrogen bonds: 2.357 at 25 °C. Defining and counting the hydrogen bonds is not straightforward however. Because water may form hydrogen bonds with solute proton donors and acceptors, it may competitively inhibit the formation of solute intermolecular or intramolecular hydrogen bonds. Consequently, hydrogen bonds between or within solute molecules dissolved in water are almost always unfavorable relative to hydrogen bonds between water and

5928-510: The backbone amide C=O of residue i as the H-bond acceptor and two H-bond donors from residue i + 4 : the backbone amide N−H and a side-chain hydroxyl or thiol H . The energy preference of the bifurcated H-bond hydroxyl or thiol system is -3.4 kcal/mol or -2.6 kcal/mol, respectively. This type of bifurcated H-bond provides an intrahelical H-bonding partner for polar side-chains, such as serine , threonine , and cysteine within

6032-419: The base) made of a specific type of mortar called sarooj made from sand, clay, egg whites, lime, goat hair, and ash. The mortar was resistant to heat transfer, helping to keep the ice cool enough not to melt; it was also impenetrable by water. Yakhchals often included a qanat and a system of windcatchers that could lower internal temperatures to frigid levels, even during the heat of the summer. One use for

6136-420: The basic structure of the polymer backbone. This hierarchy of bond strengths (covalent bonds being stronger than hydrogen-bonds being stronger than van der Waals forces) is relevant in the properties of many materials. In these macromolecules, bonding between parts of the same macromolecule cause it to fold into a specific shape, which helps determine the molecule's physiological or biochemical role. For example,

6240-416: The chains. Prominent examples include cellulose and its derived fibers, such as cotton and flax . In nylon , hydrogen bonds between carbonyl and the amide N H effectively link adjacent chains, which gives the material mechanical strength. Hydrogen bonds also affect the aramid fibre , where hydrogen bonds stabilize the linear chains laterally. The chain axes are aligned along the fibre axis, making

6344-418: The closely related dihydrogen bond , which is also an intermolecular bonding interaction involving hydrogen atoms. These structures have been known for some time, and well characterized by crystallography ; however, an understanding of their relationship to the conventional hydrogen bond, ionic bond , and covalent bond remains unclear. Generally, the hydrogen bond is characterized by a proton acceptor that

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6448-449: The dehydration stabilizes the hydrogen bond by destabilizing the nonbonded state consisting of dehydrated isolated charges . Wool , being a protein fibre, is held together by hydrogen bonds, causing wool to recoil when stretched. However, washing at high temperatures can permanently break the hydrogen bonds and a garment may permanently lose its shape. The properties of many polymers are affected by hydrogen bonds within and/or between

6552-415: The donors and acceptors for hydrogen bonds on those solutes. Hydrogen bonds between water molecules have an average lifetime of 10 seconds, or 10 picoseconds. A single hydrogen atom can participate in two hydrogen bonds. This type of bonding is called "bifurcated" (split in two or "two-forked"). It can exist, for instance, in complex organic molecules. It has been suggested that a bifurcated hydrogen atom

6656-479: The double helical structure of DNA is due largely to hydrogen bonding between its base pairs (as well as pi stacking interactions), which link one complementary strand to the other and enable replication . In the secondary structure of proteins , hydrogen bonds form between the backbone oxygens and amide hydrogens. When the spacing of the amino acid residues participating in a hydrogen bond occurs regularly between positions i and i + 4 , an alpha helix

6760-427: The droplet to act as a nucleus. Our understanding of what particles make efficient ice nuclei is poor – what we do know is they are very rare compared to that cloud condensation nuclei on which liquid droplets form. Clays, desert dust and biological particles may be effective, although to what extent is unclear. Artificial nuclei are used in cloud seeding . The droplet then grows by condensation of water vapor onto

6864-471: The electron density of the system. Interpretations of the anisotropies in the Compton profile of ordinary ice claim that the hydrogen bond is partly covalent. However, this interpretation was challenged and subsequently clarified. Most generally, the hydrogen bond can be viewed as a metric -dependent electrostatic scalar field between two or more intermolecular bonds. This is slightly different from

6968-423: The fibres extremely stiff and strong. Hydrogen-bond networks make both polymers sensitive to humidity levels in the atmosphere because water molecules can diffuse into the surface and disrupt the network. Some polymers are more sensitive than others. Thus nylons are more sensitive than aramids , and nylon 6 more sensitive than nylon-11 . A symmetric hydrogen bond is a special type of hydrogen bond in which

7072-449: The freezing point is reached. This is due to hydrogen bonding dominating the intermolecular forces, which results in a packing of molecules less compact in the solid. The density of ice increases slightly with decreasing temperature and has a value of 0.9340 g/cm at −180 °C (93 K). When water freezes, it increases in volume (about 9% for fresh water). The effect of expansion during freezing can be dramatic, and ice expansion

7176-465: The frequency of hail by promoting evaporative cooling which lowers the freezing level of thunderstorm clouds giving hail a larger volume to grow in. Accordingly, hail is actually less common in the tropics despite a much higher frequency of thunderstorms than in the mid-latitudes because the atmosphere over the tropics tends to be warmer over a much greater depth. Hail in the tropics occurs mainly at higher elevations. Ice pellets ( METAR code PL ) are

7280-534: The frozen layer. This water then freezes, causing the water table to rise further and repeat the cycle. The result is a stratified ice deposit, often several meters thick. Snow line and snow fields are two related concepts, in that snow fields accumulate on top of and ablate away to the equilibrium point (the snow line) in an ice deposit. Ice which forms on moving water tends to be less uniform and stable than ice which forms on calm water. Ice jams (sometimes called "ice dams"), when broken chunks of ice pile up, are

7384-636: The greatest ice hazard on rivers. Ice jams can cause flooding, damage structures in or near the river, and damage vessels on the river. Ice jams can cause some hydropower industrial facilities to completely shut down. An ice dam is a blockage from the movement of a glacier which may produce a proglacial lake . Heavy ice flows in rivers can also damage vessels and require the use of an icebreaker vessel to keep navigation possible. Ice discs are circular formations of ice floating on river water. They form within eddy currents , and their position results in asymmetric melting, which makes them continuously rotate at

7488-499: The hailstones to the upper part of the cloud. The updraft dissipates and the hailstones fall down, back into the updraft, and are lifted up again. Hail has a diameter of 5 millimetres (0.20 in) or more. Within METAR code, GR is used to indicate larger hail, of a diameter of at least 6.4 millimetres (0.25 in) and GS for smaller. Stones of 19 millimetres (0.75 in), 25 millimetres (1.0 in) and 44 millimetres (1.75 in) are

7592-439: The hydrogen bonding network in protic organic ionic plastic crystals (POIPCs), which are a type of phase change material exhibiting solid-solid phase transitions prior to melting, variable-temperature infrared spectroscopy can reveal the temperature dependence of hydrogen bonds and the dynamics of both the anions and the cations. The sudden weakening of hydrogen bonds during the solid-solid phase transition seems to be coupled with

7696-583: The hydrophobic membrane environments. The role of hydrogen bonds in protein folding has also been linked to osmolyte-induced protein stabilization. Protective osmolytes, such as trehalose and sorbitol , shift the protein folding equilibrium toward the folded state, in a concentration dependent manner. While the prevalent explanation for osmolyte action relies on excluded volume effects that are entropic in nature, circular dichroism (CD) experiments have shown osmolyte to act through an enthalpic effect. The molecular mechanism for their role in protein stabilization

7800-464: The ice exerted by any object. However, the significance of this hypothesis is disputed by experiments showing a high coefficient of friction for ice using atomic force microscopy . Thus, the mechanism controlling the frictional properties of ice is still an active area of scientific study. A comprehensive theory of ice friction must take into account all of the aforementioned mechanisms to estimate friction coefficient of ice against various materials as

7904-429: The ice itself. For instance, icebergs containing impurities (e.g., sediments, algae, air bubbles) can appear brown, grey or green. Because ice in natural environments is usually close to its melting temperature, its hardness shows pronounced temperature variations. At its melting point, ice has a Mohs hardness of 2 or less, but the hardness increases to about 4 at a temperature of −44 °C (−47 °F) and to 6 at

8008-456: The ice layer is caused by friction. However, this theory does not sufficiently explain why ice is slippery when standing still even at below-zero temperatures. Subsequent research suggested that ice molecules at the interface cannot properly bond with the molecules of the mass of ice beneath (and thus are free to move like molecules of liquid water). These molecules remain in a semi-liquid state, providing lubrication regardless of pressure against

8112-471: The ice surfaces. Ice storm is a type of winter storm characterized by freezing rain , which produces a glaze of ice on surfaces, including roads and power lines . In the United States, a quarter of winter weather events produce glaze ice, and utilities need to be prepared to minimize damages. Hail forms in storm clouds when supercooled water droplets freeze on contact with condensation nuclei , such as dust or dirt . The storm's updraft blows

8216-474: The ice was to create chilled treats for royalty. There were thriving industries in 16th–17th century England whereby low-lying areas along the Thames Estuary were flooded during the winter, and ice harvested in carts and stored inter-seasonally in insulated wooden houses as a provision to an icehouse often located in large country houses, and widely used to keep fish fresh when caught in distant waters. This

8320-416: The ice which often settles when loaded with snow. An ice shove occurs when ice movement, caused by ice expansion and/or wind action, occurs to the extent that ice pushes onto the shores of lakes, often displacing sediment that makes up the shoreline. Shelf ice is formed when floating pieces of ice are driven by the wind piling up on the windward shore. This kind of ice may contain large air pockets under

8424-603: The ice, would melt a thin layer, providing sufficient lubrication for the blade to glide across the ice. Yet, 1939 research by Frank P. Bowden and T. P. Hughes found that skaters would experience a lot more friction than they actually do if it were the only explanation. Further, the optimum temperature for figure skating is −5.5 °C (22 °F; 268 K) and −9 °C (16 °F; 264 K) for hockey; yet, according to pressure melting theory, skating below −4 °C (25 °F; 269 K) would be outright impossible. Instead, Bowden and Hughes argued that heating and melting of

8528-662: The identification of hydrogen bonds also in complicated molecules is crystallography , sometimes also NMR-spectroscopy. Structural details, in particular distances between donor and acceptor which are smaller than the sum of the van der Waals radii can be taken as indication of the hydrogen bond strength. One scheme gives the following somewhat arbitrary classification: those that are 15 to 40 kcal/mol, 5 to 15 kcal/mol, and >0 to 5 kcal/mol are considered strong, moderate, and weak, respectively. Hydrogen bonds involving C-H bonds are both very rare and weak. The resonance assisted hydrogen bond (commonly abbreviated as RAHB)

8632-427: The invention of refrigeration technology, the only way to safely store food without modifying it through preservatives was to use ice. Sufficiently solid surface ice makes waterways accessible to land transport during winter, and dedicated ice roads may be maintained. Ice also plays a major role in winter sports . Ice possesses a regular crystalline structure based on the molecule of water, which consists of

8736-515: The known exceptions being ice X) can be recovered at ambient pressure and low temperature in metastable form. The types are differentiated by their crystalline structure, proton ordering, and density. There are also two metastable phases of ice under pressure, both fully hydrogen-disordered; these are Ice IV and Ice XII. Ice XII was discovered in 1996. In 2006, Ice XIII and Ice XIV were discovered. Ices XI, XIII, and XIV are hydrogen-ordered forms of ices I h , V, and XII respectively. In 2009, ice XV

8840-495: The large number of glaciers it contains. They cover an area of around 80,000 km (31,000 sq mi), and have a combined volume of between 3,000-4,700 km . These glaciers are nicknamed "Asian water towers", because their meltwater run-off feeds into rivers which provide water for an estimated two billion people. Permafrost refers to soil or underwater sediment which continuously remains below 0 °C (32 °F) for two years or more. The ice within permafrost

8944-517: The most frequently reported hail sizes in North America. Hailstones can grow to 15 centimetres (6 in) and weigh more than 0.5 kilograms (1.1 lb). In large hailstones, latent heat released by further freezing may melt the outer shell of the hailstone. The hailstone then may undergo 'wet growth', where the liquid outer shell collects other smaller hailstones. The hailstone gains an ice layer and grows increasingly larger with each ascent. Once

9048-487: The onset of orientational or rotational disorder of the ions. Hydrogen bonding is of persistent theoretical interest. According to a modern description O:H−O integrates both the intermolecular O:H lone pair ":" nonbond and the intramolecular H−O polar-covalent bond associated with O−O repulsive coupling. Quantum chemical calculations of the relevant interresidue potential constants ( compliance constants ) revealed large differences between individual H bonds of

9152-453: The opposite problem: three hydrogen atoms but only one lone pair). Hydrogen bonding plays an important role in determining the three-dimensional structures and the properties adopted by many proteins. Compared to the C−C , C−O , and C−N bonds that comprise most polymers, hydrogen bonds are far weaker, perhaps 5%. Thus, hydrogen bonds can be broken by chemical or mechanical means while retaining

9256-514: The process to an even older author, Ibn Bakhtawayhi, of whom nothing is known. Ice is now produced on an industrial scale, for uses including food storage and processing, chemical manufacturing, concrete mixing and curing, and consumer or packaged ice. Most commercial icemakers produce three basic types of fragmentary ice: flake, tubular and plate, using a variety of techniques. Large batch ice makers can produce up to 75 tons of ice per day. In 2002, there were 426 commercial ice-making companies in

9360-484: The proton is spaced exactly halfway between two identical atoms. The strength of the bond to each of those atoms is equal. It is an example of a three-center four-electron bond . This type of bond is much stronger than a "normal" hydrogen bond. The effective bond order is 0.5, so its strength is comparable to a covalent bond. It is seen in ice at high pressure, and also in the solid phase of many anhydrous acids such as hydrofluoric acid and formic acid at high pressure. It

9464-653: The same molecule). The energy of a hydrogen bond depends on the geometry, the environment, and the nature of the specific donor and acceptor atoms and can vary between 1 and 40 kcal/mol. This makes them somewhat stronger than a van der Waals interaction , and weaker than fully covalent or ionic bonds . This type of bond can occur in inorganic molecules such as water and in organic molecules like DNA and proteins. Hydrogen bonds are responsible for holding materials such as paper and felted wool together, and for causing separate sheets of paper to stick together after becoming wet and subsequently drying. The hydrogen bond

9568-496: The same type. For example, the central interresidue N−H···N hydrogen bond between guanine and cytosine is much stronger in comparison to the N−H·;··N bond between the adenine-thymine pair. Theoretically, the bond strength of the hydrogen bonds can be assessed using NCI index, non-covalent interactions index , which allows a visualization of these non-covalent interactions , as its name indicates, using

9672-425: The seafloor. Ice which calves (breaks off) from an ice shelf or a coastal glacier may become an iceberg. The aftermath of calving events produces a loose mixture of snow and ice known as Ice mélange . Sea ice forms in several stages. At first, small, millimeter-scale crystals accumulate on the water surface in what is known as frazil ice . As they become somewhat larger and more consistent in shape and cover,

9776-440: The structure may shift to a more stable face-centered cubic lattice. It is speculated that superionic ice could compose the interior of ice giants such as Uranus and Neptune. Ice is " slippery " because it has a low coefficient of friction. This subject was first scientifically investigated in the 19th century. The preferred explanation at the time was " pressure melting " -i.e. the blade of an ice skate, upon exerting pressure on

9880-688: The summer. The advent of artificial refrigeration technology made the delivery of ice obsolete. Ice is still harvested for ice and snow sculpture events . For example, a swing saw is used to get ice for the Harbin International Ice and Snow Sculpture Festival each year from the frozen surface of the Songhua River . The earliest known written process to artificially make ice is by the 13th-century writings of Arab historian Ibn Abu Usaybia in his book Kitab Uyun al-anba fi tabaqat-al-atibba concerning medicine in which Ibn Abu Usaybia attributes

9984-443: The surface of un-insulated windows. Hoar frost is common in the environment, particularly in the low-lying areas such as valleys . In Antarctica, the temperatures can be so low that electrostatic attraction is increased to the point hoarfrost on snow sticks together when blown by wind into tumbleweed -like balls known as yukimarimo . Sometimes, drops of water crystallize on cold objects as rime instead of glaze. Soft rime has

10088-428: The tetrameric quaternary structure within the mammalian sorbitol dehydrogenase protein family. A protein backbone hydrogen bond incompletely shielded from water attack is a dehydron . Dehydrons promote the removal of water through proteins or ligand binding . The exogenous dehydration enhances the electrostatic interaction between the amide and carbonyl groups by de-shielding their partial charges . Furthermore,

10192-441: The thermal energy (temperature) only after enough hydrogen bonds are broken that the ice can be considered liquid water. The amount of energy consumed in breaking hydrogen bonds in the transition from ice to water is known as the heat of fusion . As with water, ice absorbs light at the red end of the spectrum preferentially as the result of an overtone of an oxygen–hydrogen (O–H) bond stretch. Compared with water, this absorption

10296-480: The two ice sheets which almost completely cover the world's largest island, Greenland , and the continent of Antarctica . These ice sheets have an average thickness of over 1 km (0.6 mi) and have existed for millions of years. Other major ice formations on land include ice caps , ice fields , ice streams and glaciers . In particular, the Hindu Kush region is known as the Earth's "Third Pole" due to

10400-433: The water surface begins to look "oily" from above, so this stage is called grease ice . Then, ice continues to clump together, and solidify into flat cohesive pieces known as ice floes . Ice floes are the basic building blocks of sea ice cover, and their horizontal size (defined as half of their diameter ) varies dramatically, with the smallest measured in centimeters and the largest in hundreds of kilometers. An area which

10504-442: The work of a fellow scientist at their laboratory, Maurice Loyal Huggins , saying, "Mr. Huggins of this laboratory in some work as yet unpublished, has used the idea of a hydrogen kernel held between two atoms as a theory in regard to certain organic compounds." An ubiquitous example of a hydrogen bond is found between water molecules. In a discrete water molecule, there are two hydrogen atoms and one oxygen atom. The simplest case

10608-452: Was allegedly copied by an Englishman who had seen the same activity in China. Ice was imported into England from Norway on a considerable scale as early as 1823. In the United States, the first cargo of ice was sent from New York City to Charleston, South Carolina , in 1799, and by the first half of the 19th century, ice harvesting had become a big business. Frederic Tudor , who became known as

10712-411: Was found at extremely high pressures and −143 °C. At even higher pressures, ice is predicted to become a metal ; this has been variously estimated to occur at 1.55 TPa or 5.62 TPa. As well as crystalline forms, solid water can exist in amorphous states as amorphous solid water (ASW) of varying densities. In outer space, hexagonal crystalline ice is present in the ice volcanoes , but

10816-500: Was supplied from Bavarian lakes. From 1930s and up until 1994, the Hungarian Parliament building used ice harvested in the winter from Lake Balaton for air conditioning. Ice houses were used to store ice formed in the winter, to make ice available all year long, and an early type of refrigerator known as an icebox was cooled using a block of ice placed inside it. Many cities had a regular ice delivery service during

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