108-628: The Cloudbreak mine is an iron ore mine located in the Pilbara region of Western Australia , 89 kilometres west-south-west of Nullagine , in the Chichester Range . The mine is fully owned and operated by the Fortescue Metals Group (FMG) and is one of four iron ore mines the company operates in the Pilbara, the others being Christmas Creek mine (located 50 kilometres east of Cloudbreak) and
216-434: A body-centered cubic (bcc) crystal structure . As it cools further to 1394 °C, it changes to its γ-iron allotrope, a face-centered cubic (fcc) crystal structure, or austenite . At 912 °C and below, the crystal structure again becomes the bcc α-iron allotrope. The physical properties of iron at very high pressures and temperatures have also been studied extensively, because of their relevance to theories about
324-466: A fatality as a sign of respect and to ensure the safety of the workers. Approximately 1,500 workers at the mine had to be evacuated in October 2013 after a large bushfire threatened the accommodation village near the mine. The workers were taken to Christmas Creek mine until the danger had passed. No injuries or damage was caused to the minesite by the fire which was eventually contained. The approval of
432-430: A nuclear spin (− 1 ⁄ 2 ). The nuclide Fe theoretically can undergo double electron capture to Cr, but the process has never been observed and only a lower limit on the half-life of 4.4×10 years has been established. Fe is an extinct radionuclide of long half-life (2.6 million years). It is not found on Earth, but its ultimate decay product is its granddaughter, the stable nuclide Ni . Much of
540-499: A supernova for their formation, involving rapid neutron capture by starting Fe nuclei. In the far future of the universe, assuming that proton decay does not occur, cold fusion occurring via quantum tunnelling would cause the light nuclei in ordinary matter to fuse into Fe nuclei. Fission and alpha-particle emission would then make heavy nuclei decay into iron, converting all stellar-mass objects to cold spheres of pure iron. Iron's abundance in rocky planets like Earth
648-455: A $ 3.2 billion capital raising in August 2006 to finance its projects. Construction on the mine itself began in October 2006. Fortescue began mining at Cloudbreak in October 2007. Iron ore production at the mine began in 2008 and, in its first full year of operation, the mine produced 28 million tonnes of iron ore. The ore from the mine is processed on site before being loaded onto rail. The product
756-516: A 33% to 40% recovery of magnetite by weight, to produce a concentrate grading in excess of 64% iron by weight. The typical magnetite iron ore concentrate has less than 0.1% phosphorus , 3–7% silica , and less than 3% aluminium . As of 2019, magnetite iron ore is mined in Minnesota and Michigan in the United States , eastern Canada , and northern Sweden . Magnetite-bearing banded iron formation
864-684: A benchmark to be followed by the rest of the industry. Singapore Mercantile Exchange (SMX) has launched the world's first global iron ore futures contract, based on the Metal Bulletin Iron Ore Index (MBIOI) which uses daily price data from a broad spectrum of industry participants and independent Chinese steel consultancy and data provider Shanghai Steelhome's widespread contact base of steel producers and iron ore traders across China. The futures contract has seen monthly volumes over 1,500,000 t (1,500,000 long tons; 1,700,000 short tons) after eight months of trading. This move follows
972-458: A blast furnace more efficient. Others are added because they make the iron more fluid, harder, or give it some other desirable quality. The choice of ore, fuel, and flux determines how the slag behaves and the operational characteristics of the iron produced. Ideally, iron ore contains only iron and oxygen. In reality, this is rarely the case. Typically, iron ore contains a host of elements which are often unwanted in modern steel. Iron Iron
1080-428: A cost of US$ 360 million, by building a mine and process plant there and linking it to its existing rail network. Christmas Creek is scheduled to produce 16 million tonnes of iron ore in its first year of operation. Fortescue plans to reach an annual production of 95 million tonnes of iron ore by 2012, downgraded from an earlier target of 120 million. Mining at Cloudbreak was temporarily suspended on 24 December 2010 after
1188-454: A distorted sodium chloride structure. The binary ferrous and ferric halides are well-known. The ferrous halides typically arise from treating iron metal with the corresponding hydrohalic acid to give the corresponding hydrated salts. Iron reacts with fluorine, chlorine, and bromine to give the corresponding ferric halides, ferric chloride being the most common. Ferric iodide is an exception, being thermodynamically unstable due to
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#17328871364291296-553: A macroscopic piece of iron will have a nearly zero overall magnetic field. Application of an external magnetic field causes the domains that are magnetized in the same general direction to grow at the expense of adjacent ones that point in other directions, reinforcing the external field. This effect is exploited in devices that need to channel magnetic fields to fulfill design function, such as electrical transformers , magnetic recording heads, and electric motors . Impurities, lattice defects , or grain and particle boundaries can "pin"
1404-475: A mixture of O 2 /Ar. Iron(IV) is a common intermediate in many biochemical oxidation reactions. Numerous organoiron compounds contain formal oxidation states of +1, 0, −1, or even −2. The oxidation states and other bonding properties are often assessed using the technique of Mössbauer spectroscopy . Many mixed valence compounds contain both iron(II) and iron(III) centers, such as magnetite and Prussian blue ( Fe 4 (Fe[CN] 6 ) 3 ). The latter
1512-632: A negative effect on the species survival in the area. The occurrence of the night parrot in the future mining area was discovered during a 2005 survey, at Minga Well on 12 April 2005, commissioned by FMG, which was carried out by two contract biologists who sighted a small group of the birds. Unconfirmed sightings of the bird had been made previously in a nearby area in 2004. Iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron
1620-424: A premium price. Due to the high density of hematite relative to associated silicate gangue, hematite beneficiation usually involves a combination of beneficiation techniques. One method relies on passing the finely-crushed ore over a slurry containing magnetite or other agent such as ferrosilicon which increases its density. When the density of the slurry is properly calibrated, the hematite will sink and
1728-453: A relatively low-grade ore, they are also inexpensive to collect, as they do not have to be mined. Because of this, companies such as Magnetation have started reclamation projects where they use iron ore tailings as a source of metallic iron. The two main methods of recycling iron from iron ore tailings are magnetizing roasting and direct reduction. Magnetizing roasting uses temperatures between 700 and 900 °C (1,292 and 1,652 °F) for
1836-471: A result, mercury is traded in standardized 76 pound flasks (34 kg) made of iron. Iron is by far the most reactive element in its group; it is pyrophoric when finely divided and dissolves easily in dilute acids, giving Fe . However, it does not react with concentrated nitric acid and other oxidizing acids due to the formation of an impervious oxide layer, which can nevertheless react with hydrochloric acid . High-purity iron, called electrolytic iron ,
1944-600: A source of iron ore. Prior to the industrial revolution, most iron was obtained from widely-available goethite or bog ore , for example, during the American Revolution and the Napoleonic Wars . Historically, much of the iron ore utilized by industrialized societies has been mined from predominantly hematite deposits with grades of around 70% Fe. These deposits are commonly referred to as "direct shipping ores" or "natural ores". Increasing iron ore demand, coupled with
2052-597: A switch to index-based quarterly pricing by the world's three largest iron ore miners— Vale , Rio Tinto , and BHP —in early 2010, breaking a 40-year tradition of benchmark annual pricing. Iron is the most abundant element on earth but not in the crust. The extent of the accessible iron ore reserves is not known, though Lester Brown of the Worldwatch Institute suggested in 2006 that iron ore could run out within 64 years (that is, by 2070), based on 2% growth in demand per year. Geoscience Australia calculates that
2160-418: A time of under 1 hour to produce an iron concentrate (Fe 3 O 4 ) to be used for iron smelting. For magnetizing roasting, it is important to have a reducing atmosphere to prevent oxidization and the formation of Fe 2 O 3 because it is harder to separate as it is less magnetic. Direct reduction uses hotter temperatures of over 1,000 °C (1,830 °F) and longer times of 2–5 hours. Direct reduction
2268-455: A type of rock consisting of repeated thin layers of iron oxides alternating with bands of iron-poor shale and chert . The banded iron formations were laid down in the time between 3,700 million years ago and 1,800 million years ago . Materials containing finely ground iron(III) oxides or oxide-hydroxides, such as ochre , have been used as yellow, red, and brown pigments since pre-historical times. They contribute as well to
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#17328871364292376-655: A typically titanium -bearing magnetite, often with vanadium . These ores form a niche market, with specialty smelters used to recover the iron, titanium, and vanadium. These ores are beneficiated essentially similarly to banded iron formation ores, but usually are more easily upgraded via crushing and screening . The typical titanomagnetite concentrate grades 57% Fe, 12% Ti, and 0.5% V 2 O 5 . For every one ton of iron ore concentrate produced, approximately 2.5–3.0 tons of iron ore tailings will be discharged. Statistics show that there are 130 million tons of iron ore tailings discharged every year. If, for example,
2484-632: A value of $ 2.3 billion. 46% of Canada's iron ore comes from the Iron Ore Company of Canada mine, in Labrador City , Newfoundland , with secondary sources including the Mary River Mine in Nunavut . According to the U.S. Geological Survey's 2021 Report on iron ore, India is estimated to produce 59,000,000 t (58,000,000 long tons; 65,000,000 short tons) of iron ore in 2020, placing it as
2592-435: A very large coordination and organometallic chemistry : indeed, it was the discovery of an iron compound, ferrocene , that revolutionalized the latter field in the 1950s. Iron is sometimes considered as a prototype for the entire block of transition metals, due to its abundance and the immense role it has played in the technological progress of humanity. Its 26 electrons are arranged in the configuration [Ar]3d 4s , of which
2700-814: Is a chemical element ; it has the symbol Fe (from Latin ferrum 'iron') and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table . It is, by mass, the most common element on Earth , forming much of Earth's outer and inner core . It is the fourth most abundant element in the Earth's crust , being mainly deposited by meteorites in its metallic state. Extracting usable metal from iron ores requires kilns or furnaces capable of reaching 1,500 °C (2,730 °F), about 500 °C (932 °F) higher than that required to smelt copper . Humans started to master that process in Eurasia during
2808-511: Is a high-volume, low-margin business, as the value of iron is significantly lower than base metals. It is highly capital intensive, and requires significant investment in infrastructure such as rail in order to transport the ore from the mine to a freight ship. For these reasons, iron ore production is concentrated in the hands of a few major players. World production averages 2,000,000,000 t (2.0 × 10 long tons; 2.2 × 10 short tons) of raw ore annually. The world's largest producer of iron ore
2916-630: Is also rarely found in basalts that have formed from magmas that have come into contact with carbon-rich sedimentary rocks, which have reduced the oxygen fugacity sufficiently for iron to crystallize. This is known as telluric iron and is described from a few localities, such as Disko Island in West Greenland, Yakutia in Russia and Bühl in Germany. Ferropericlase (Mg,Fe)O , a solid solution of periclase (MgO) and wüstite (FeO), makes up about 20% of
3024-407: Is considered to be resistant to rust, due to its oxide layer. Iron forms various oxide and hydroxide compounds ; the most common are iron(II,III) oxide (Fe 3 O 4 ), and iron(III) oxide (Fe 2 O 3 ). Iron(II) oxide also exists, though it is unstable at room temperature. Despite their names, they are actually all non-stoichiometric compounds whose compositions may vary. These oxides are
3132-495: Is due to its abundant production during the runaway fusion and explosion of type Ia supernovae , which scatters the iron into space. Metallic or native iron is rarely found on the surface of the Earth because it tends to oxidize. However, both the Earth's inner and outer core , which together account for 35% of the mass of the whole Earth, are believed to consist largely of an iron alloy, possibly with nickel . Electric currents in
3240-428: Is expected to rise by a CAGR of 2% between 2023 and 2027, and industry analyst Fitch Solutions forecasted in 2021 that Brazil's annual production will reach 592,000,000 t (583,000,000 long tons; 653,000,000 short tons) by 2030. In 2017, Canadian iron ore mines produced 49,000,000 t (48,000,000 long tons; 54,000,000 short tons) of iron ore in concentrate pellets and 13.6 million tons of crude steel. Of
3348-474: Is experimentally well defined for pressures less than 50 GPa. For greater pressures, published data (as of 2007) still varies by tens of gigapascals and over a thousand kelvin. Below its Curie point of 770 °C (1,420 °F; 1,040 K), α-iron changes from paramagnetic to ferromagnetic : the spins of the two unpaired electrons in each atom generally align with the spins of its neighbors, creating an overall magnetic field . This happens because
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3456-510: Is followed by Japan and Korea, which consume a significant amount of raw iron ore and metallurgical coal . In 2006, China produced 588,000,000 t (579,000,000 long tons; 648,000,000 short tons) of iron ore, with an annual growth of 38%. Over the last 40 years, iron ore prices have been decided in closed-door negotiations between the small handful of miners and steelmakers which dominate both spot and contract markets. Until 2006, prices were determined in annual benchmark negotiations between
3564-443: Is in Earth's crust only amounts to about 5% of the overall mass of the crust and is thus only the fourth most abundant element in that layer (after oxygen , silicon , and aluminium ). Most of the iron in the crust is combined with various other elements to form many iron minerals . An important class is the iron oxide minerals such as hematite (Fe 2 O 3 ), magnetite (Fe 3 O 4 ), and siderite (FeCO 3 ), which are
3672-586: Is in the iron ranges around Lake Superior . These iron ranges occur in Minnesota and Michigan, which combined accounted for 93% of the usable iron ore produced in the United States in 2014. Seven of the nine operational open pit mines in the United States are located in Minnesota as well as two of the three tailings reclamation operations. The other two active open pit mines were located in Michigan . In 2016, one of
3780-693: Is mined extensively in Brazil as of 2019, which exports significant quantities to Asia , and there is a nascent and large magnetite iron ore industry in Australia . Direct-shipping iron ore (DSO) deposits (typically composed of hematite ) are currently exploited on all continents except Antarctica , with the largest intensity in South America , Australia, and Asia. Most large hematite iron ore deposits are sourced from altered banded iron formations and (rarely) igneous accumulations. DSO deposits are typically rarer than
3888-401: Is not like that of Mn with its weak, spin-forbidden d–d bands, because Fe has higher positive charge and is more polarizing, lowering the energy of its ligand-to-metal charge transfer absorptions. Thus, all the above complexes are rather strongly colored, with the single exception of the hexaquo ion – and even that has a spectrum dominated by charge transfer in the near ultraviolet region. On
3996-407: Is possible, but nonetheless the sequence does effectively end at Ni because conditions in stellar interiors cause the competition between photodisintegration and the alpha process to favor photodisintegration around Ni. This Ni, which has a half-life of about 6 days, is created in quantity in these stars, but soon decays by two successive positron emissions within supernova decay products in
4104-548: Is somewhat different). Pieces of magnetite with natural permanent magnetization ( lodestones ) provided the earliest compasses for navigation. Particles of magnetite were extensively used in magnetic recording media such as core memories , magnetic tapes , floppies , and disks , until they were replaced by cobalt -based materials. Iron has four stable isotopes : Fe (5.845% of natural iron), Fe (91.754%), Fe (2.119%) and Fe (0.282%). Twenty-four artificial isotopes have also been created. Of these stable isotopes, only Fe has
4212-442: Is such a strong oxidizing agent that it oxidizes ammonia to nitrogen (N 2 ) and water to oxygen: The pale-violet hex aquo complex [Fe(H 2 O) 6 ] is an acid such that above pH 0 it is fully hydrolyzed: As pH rises above 0 the above yellow hydrolyzed species form and as it rises above 2–3, reddish-brown hydrous iron(III) oxide precipitates out of solution. Although Fe has a d configuration, its absorption spectrum
4320-502: Is supposed to have an orthorhombic or a double hcp structure. (Confusingly, the term "β-iron" is sometimes also used to refer to α-iron above its Curie point, when it changes from being ferromagnetic to paramagnetic, even though its crystal structure has not changed. ) The inner core of the Earth is generally presumed to consist of an iron- nickel alloy with ε (or β) structure. The melting and boiling points of iron, along with its enthalpy of atomization , are lower than those of
4428-456: Is the raw material used to make pig iron , which is one of the main raw materials to make steel —98% of the mined iron ore is used to make steel. In 2011 the Financial Times quoted Christopher LaFemina, mining analyst at Barclays Capital, saying that iron ore is "more integral to the global economy than any other commodity, except perhaps oil ". Metallic iron is virtually unknown on
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4536-476: Is the Brazilian mining corporation Vale , followed by Australian companies Rio Tinto Group and BHP . A further Australian supplier, Fortescue Metals Group Ltd, has helped bring Australia's production to first in the world. The seaborne trade in iron ore—that is, iron ore to be shipped to other countries—was 849,000,000 t (836,000,000 long tons; 936,000,000 short tons) in 2004. Australia and Brazil dominate
4644-611: Is then transported to the coast at Port Hedland via the Fortescue railway , where it is loaded onto ships. Construction on the 280 kilometre long line from Cloudbreak to the Herb Elliott Port at Port Hedland was begun in November 2006. The line was scheduled to be fully operational within 18 months. A cyclone in March 2007 killed two workers at the project and lead to delays. The first train from
4752-418: Is thus very important economically, and iron is the cheapest metal, with a price of a few dollars per kilogram or pound. Pristine and smooth pure iron surfaces are a mirror-like silvery-gray. Iron reacts readily with oxygen and water to produce brown-to-black hydrated iron oxides , commonly known as rust . Unlike the oxides of some other metals that form passivating layers, rust occupies more volume than
4860-451: Is used as the traditional "blue" in blueprints . Iron is the first of the transition metals that cannot reach its group oxidation state of +8, although its heavier congeners ruthenium and osmium can, with ruthenium having more difficulty than osmium. Ruthenium exhibits an aqueous cationic chemistry in its low oxidation states similar to that of iron, but osmium does not, favoring high oxidation states in which it forms anionic complexes. In
4968-437: Is used in chemical actinometry and along with its sodium salt undergoes photoreduction applied in old-style photographic processes. The dihydrate of iron(II) oxalate has a polymeric structure with co-planar oxalate ions bridging between iron centres with the water of crystallisation located forming the caps of each octahedron, as illustrated below. Iron(III) complexes are quite similar to those of chromium (III) with
5076-425: Is used to produce sponge iron (Fe) to be used for steel-making. Direct reduction requires more energy, as the temperatures are higher and the time is longer and it requires more reducing agent than magnetizing roasting. Lower-grade sources of iron ore generally require beneficiation , using techniques like crushing, milling , gravity or heavy media separation , screening, and silica froth flotation to improve
5184-467: Is usually found in the form of magnetite ( Fe 3 O 4 , 72.4% Fe), hematite ( Fe 2 O 3 , 69.9% Fe), goethite ( FeO(OH) , 62.9% Fe), limonite ( FeO(OH)·n(H 2 O) , 55% Fe), or siderite ( FeCO 3 , 48.2% Fe). Ores containing very high quantities of hematite or magnetite, typically greater than about 60% iron, are known as natural ore or direct shipping ore , and can be fed directly into iron-making blast furnaces . Iron ore
5292-557: The 2nd millennium BC and the use of iron tools and weapons began to displace copper alloys – in some regions, only around 1200 BC. That event is considered the transition from the Bronze Age to the Iron Age . In the modern world , iron alloys, such as steel , stainless steel , cast iron and special steels , are by far the most common industrial metals, due to their mechanical properties and low cost. The iron and steel industry
5400-820: The Chichester Range , the Hamersley Range and Koolyanobbing , Western Australia . Other types of ore are coming to the fore recently, such as oxidised ferruginous hardcaps, for instance laterite iron ore deposits near Lake Argyle in Western Australia. The total recoverable reserves of iron ore in India are about 9,602,000,000 t (9.450 × 10 long tons; 1.0584 × 10 short tons) of hematite and 3,408,000,000 t (3.354 × 10 long tons; 3.757 × 10 short tons) of magnetite . Chhattisgarh , Madhya Pradesh , Karnataka , Jharkhand , Odisha , Goa , Maharashtra , Andhra Pradesh , Kerala , Rajasthan , and Tamil Nadu are
5508-551: The Earth 's surface except as iron-nickel alloys from meteorites and very rare forms of deep mantle xenoliths . Although iron is the fourth-most abundant element in the Earth's crust , composing about 5%, the vast majority is bound in silicate or, more rarely, carbonate minerals, and smelting pure iron from these minerals would require a prohibitive amount of energy. Therefore, all sources of iron used by human industry exploit comparatively rarer iron oxide minerals, primarily hematite . Prehistoric societies used laterite as
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#17328871364295616-663: The Kings Valley mine and Firetail mine at the Solomon Project. FMG is the third-largest iron ore mining company in the Pilbara, behind Rio Tinto and BHP . The mine is situated within the boundaries of Mulga Downs Station which is currently owned by Gina Rinehart . FMG acquired the Cloudbreak and Christmas Creek tenements during 2003. The company begun constructing port facilities at Port Hedland in February 2006, followed by
5724-506: The Pilbara region of Western Australia is approximately 844,000,000 t (831,000,000 long tons; 930,000,000 short tons) per year and rising. Gavin Mudd ( RMIT University ) and Jonathon Law ( CSIRO ) expect it to be gone within 30–50 years and 56 years, respectively. These 2010 estimates require ongoing review to take into account shifting demand for lower-grade iron ore and improving mining and recovery techniques (allowing deeper mining below
5832-407: The silicate mineral fragments will float and can be removed. Iron is the world's most commonly used metal—steel, of which iron ore is the key ingredient, represents almost 95% of all metal used per year. It is used primarily in structures, ships, automobiles, and machinery. Iron-rich rocks are common worldwide, but ore-grade commercial mining operations are dominated by the countries listed in
5940-432: The supernova remnant gas cloud, first to radioactive Co, and then to stable Fe. As such, iron is the most abundant element in the core of red giants , and is the most abundant metal in iron meteorites and in the dense metal cores of planets such as Earth . It is also very common in the universe, relative to other stable metals of approximately the same atomic weight . Iron is the sixth most abundant element in
6048-488: The trans - chlorohydridobis(bis-1,2-(diphenylphosphino)ethane)iron(II) complex is used as a starting material for compounds with the Fe( dppe ) 2 moiety . The ferrioxalate ion with three oxalate ligands displays helical chirality with its two non-superposable geometries labelled Λ (lambda) for the left-handed screw axis and Δ (delta) for the right-handed screw axis, in line with IUPAC conventions. Potassium ferrioxalate
6156-466: The universe , and the most common refractory element. Although a further tiny energy gain could be extracted by synthesizing Ni , which has a marginally higher binding energy than Fe, conditions in stars are unsuitable for this process. Element production in supernovas greatly favor iron over nickel, and in any case, Fe still has a lower mass per nucleon than Ni due to its higher fraction of lighter protons. Hence, elements heavier than iron require
6264-420: The 13,600,000 t (13,400,000 long tons; 15,000,000 short tons) of steel 7,000,000 t (6,900,000 long tons; 7,700,000 short tons) was exported, and 43,100,000 t (42,400,000 long tons; 47,500,000 short tons) of iron ore was exported at a value of $ 4.6 billion. Of the iron ore exported, 38.5% of the volume was iron ore pellets with a value of $ 2.3 billion, and 61.5% was iron ore concentrates with
6372-570: The 3d and 4s electrons are relatively close in energy, and thus a number of electrons can be ionized. Iron forms compounds mainly in the oxidation states +2 ( iron(II) , "ferrous") and +3 ( iron(III) , "ferric"). Iron also occurs in higher oxidation states , e.g., the purple potassium ferrate (K 2 FeO 4 ), which contains iron in its +6 oxidation state. The anion [FeO 4 ] with iron in its +7 oxidation state, along with an iron(V)-peroxo isomer, has been detected by infrared spectroscopy at 4 K after cocondensation of laser-ablated Fe atoms with
6480-680: The 62–64% Fe range. Granite and ultrapotassic igneous rocks were sometimes used to segregate magnetite crystals and form masses of magnetite suitable for economic concentration. A few iron ore deposits, notably in Chile , are formed from volcanic flows containing significant accumulations of magnetite phenocrysts . Chilean magnetite iron ore deposits within the Atacama Desert have also formed alluvial accumulations of magnetite in streams leading from these volcanic formations. Some magnetite skarn and hydrothermal deposits have been worked in
6588-548: The A$ 2 billion project through the then- Minister for the Environment , Ian Campbell , was criticised because of a number of endangered species in the area of the future mine, among them the incredibly rare night parrot . Continuation of the mining project was endangered and, in order to gain EPA approval, the mine had to implement a management plan to ensure that mining activities would not have
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#17328871364296696-589: The Earth's surface. Items made of cold-worked meteoritic iron have been found in various archaeological sites dating from a time when iron smelting had not yet been developed; and the Inuit in Greenland have been reported to use iron from the Cape York meteorite for tools and hunting weapons. About 1 in 20 meteorites consist of the unique iron-nickel minerals taenite (35–80% iron) and kamacite (90–95% iron). Native iron
6804-429: The United States is estimated to have accounted for 2% of the world's iron ore output. In the United States there are twelve iron ore mines, with nine being open pit mines and three being reclamation operations. There were also ten pelletizing plants, nine concentration plants, two direct-reduced iron (DRI) plants, and one iron nugget plant that were operating in 2014. In the United States the majority of iron ore mining
6912-450: The brown deposits present in a sizeable number of streams. Due to its electronic structure, iron has a very large coordination and organometallic chemistry. Many coordination compounds of iron are known. A typical six-coordinate anion is hexachloroferrate(III), [FeCl 6 ] , found in the mixed salt tetrakis(methylammonium) hexachloroferrate(III) chloride . Complexes with multiple bidentate ligands have geometric isomers . For example,
7020-683: The color of various rocks and clays , including entire geological formations like the Painted Hills in Oregon and the Buntsandstein ("colored sandstone", British Bunter ). Through Eisensandstein (a jurassic 'iron sandstone', e.g. from Donzdorf in Germany) and Bath stone in the UK, iron compounds are responsible for the yellowish color of many historical buildings and sculptures. The proverbial red color of
7128-411: The concentration of the ore and remove impurities. The results, high-quality fine ore powders, are known as fines. Magnetite is magnetic , and hence easily separated from the gangue minerals and capable of producing a high-grade concentrate with very low levels of impurities. The grain size of the magnetite and its degree of commingling with the silica groundmass determine the grind size to which
7236-464: The cores of the Earth and other planets. Above approximately 10 GPa and temperatures of a few hundred kelvin or less, α-iron changes into another hexagonal close-packed (hcp) structure, which is also known as ε-iron . The higher-temperature γ-phase also changes into ε-iron, but does so at higher pressure. Some controversial experimental evidence exists for a stable β phase at pressures above 50 GPa and temperatures of at least 1500 K. It
7344-533: The country's " economic demonstrated resources " of iron currently amount to 24 gigatonnes , or 24,000,000,000 t (2.4 × 10 long tons; 2.6 × 10 short tons). Another estimate places Australia's reserves of iron ore at 52,000,000,000 t (5.1 × 10 long tons; 5.7 × 10 short tons), or 30% of the world's estimated 170,000,000,000 t (1.7 × 10 long tons; 1.9 × 10 short tons), of which Western Australia accounts for 28,000,000,000 t (2.8 × 10 long tons; 3.1 × 10 short tons). The current production rate from
7452-584: The depletion of high-grade hematite ores in the United States, led after World War II to the development of lower-grade iron ore sources, principally the use of magnetite and taconite . Iron ore mining methods vary by the type of ore being mined. There are four main types of iron ore deposits worked currently, depending on the mineralogy and geology of the ore deposits. These are magnetite, titanomagnetite , massive hematite, and pisolitic ironstone deposits. The origin of iron can be ultimately traced to its formation through nuclear fusion in stars, and most of
7560-401: The domains in the new positions, so that the effect persists even after the external field is removed – thus turning the iron object into a (permanent) magnet . Similar behavior is exhibited by some iron compounds, such as the ferrites including the mineral magnetite , a crystalline form of the mixed iron(II,III) oxide Fe 3 O 4 (although the atomic-scale mechanism, ferrimagnetism ,
7668-479: The earlier 3d elements from scandium to chromium , showing the lessened contribution of the 3d electrons to metallic bonding as they are attracted more and more into the inert core by the nucleus; however, they are higher than the values for the previous element manganese because that element has a half-filled 3d sub-shell and consequently its d-electrons are not easily delocalized. This same trend appears for ruthenium but not osmium . The melting point of iron
7776-406: The exception of iron(III)'s preference for O -donor instead of N -donor ligands. The latter tend to be rather more unstable than iron(II) complexes and often dissociate in water. Many Fe–O complexes show intense colors and are used as tests for phenols or enols . For example, in the ferric chloride test , used to determine the presence of phenols, iron(III) chloride reacts with a phenol to form
7884-442: The gangue is separated during the beneficiation process and is removed as tailings . Taconite tailings are mostly the mineral quartz , which is chemically inert. This material is stored in large, regulated water settling ponds. The key parameters for magnetite ore being economic are the crystallinity of the magnetite, the grade of the iron within the banded iron formation host rock, and the contaminant elements which exist within
7992-462: The global stock of iron in use in society is 2,200 kg per capita. More-developed countries differ in this respect from less-developed countries (7,000–14,000 vs 2,000 kg per capita). Ocean science demonstrated the role of the iron in the ancient seas in both marine biota and climate. Iron shows the characteristic chemical properties of the transition metals , namely the ability to form variable oxidation states differing by steps of one and
8100-789: The groundwater table). Brazil is the second-largest producer of iron ore after Australia, accounting for 16% of the world's iron ore production. After a somewhat sluggish production volume 2010-2020, partly due to the Mariana dam disaster in 2015 and the Brumadinho dam disaster in 2019, which halted the production at the two involved mines, production has increased steadily since 2021, when Brazil produced 431,000,000 t (424,000,000 long tons; 475,000,000 short tons). In 2022 it increased to 435,000,000 t (428,000,000 long tons; 480,000,000 short tons) and in 2023 to 440,000,000 t (430,000,000 long tons; 490,000,000 short tons). The Brazilian production
8208-450: The iron and carbon smelting must be kept in an oxygen-deficient (reducing) state to promote the burning of carbon to produce CO and not CO 2 . The inclusion of even small amounts of some elements can have profound effects on the behavioral characteristics of a batch of iron or the operation of a smelter. These effects can be both good and bad, some catastrophically bad. Some chemicals are deliberately added, such as flux, which makes
8316-413: The iron from the oxygen, a stronger elemental bond must be presented to attach to the oxygen. Carbon is used because the strength of a carbon-oxygen bond is greater than that of the iron-oxygen bond at high temperatures. Thus, the iron ore must be powdered and mixed with coke , to be burnt in the smelting process. Carbon monoxide is the primary ingredient of chemically stripping oxygen from iron. Thus,
8424-889: The iron is thought to have originated in dying stars that are large enough to explode as supernovae . The Earth's core is thought to consist mainly of iron, but this is inaccessible from the surface. Some iron meteorites are thought to have originated from asteroids 1,000 km (620 mi) in diameter or larger. Banded iron formations (BIFs) are sedimentary rocks containing more than 15% iron composed predominantly of thinly-bedded iron minerals and silica (as quartz ). Banded iron formations occur exclusively in Precambrian rocks, and are commonly weakly-to-intensely metamorphosed . Banded iron formations may contain iron in carbonates ( siderite or ankerite ) or silicates ( minnesotaite , greenalite , or grunerite ), but in those mined as iron ores, oxides ( magnetite or hematite ) are
8532-449: The liquid outer core are believed to be the origin of the Earth's magnetic field . The other terrestrial planets ( Mercury , Venus , and Mars ) as well as the Moon are believed to have a metallic core consisting mostly of iron. The M-type asteroids are also believed to be partly or mostly made of metallic iron alloy. The rare iron meteorites are the main form of natural metallic iron on
8640-446: The literature, this mineral phase of the lower mantle is also often called magnesiowüstite. Silicate perovskite may form up to 93% of the lower mantle, and the magnesium iron form, (Mg,Fe)SiO 3 , is considered to be the most abundant mineral in the Earth, making up 38% of its volume. While iron is the most abundant element on Earth, most of this iron is concentrated in the inner and outer cores. The fraction of iron that
8748-423: The magnetite concentrate. The size and strip ratio of most magnetite resources is irrelevant, as a banded iron formation can be hundreds of meters thick, extend hundreds of kilometers along strike , and can easily come to more than three billion or more tonnes of contained ore. The typical grade of iron at which a magnetite-bearing banded iron formation becomes economic is roughly 25% iron, which can generally yield
8856-476: The magnetite-bearing BIF or other rocks which form its main source, or protolith rock, but are considerably cheaper to mine and process as they require less beneficiation due to the higher iron content. However, DSO ores can contain significantly higher concentrations of penalty elements, typically being higher in phosphorus, water content (especially pisolite sedimentary accumulations), and aluminium ( clays within pisolites). Export-grade DSO ores are generally in
8964-399: The main iron ore producers ( BHP Billiton , Rio Tinto , and Vale S.A. ) and Japanese importers. In 2006, Chinese company Baosteel began handling negotiations for the importer side. The Chinese government replaced Baosteel with China Iron and Steel Association as lead negotiator in 2009. Traditionally, the first deal reached between these the major producers and the major importers sets
9072-407: The major ores of iron . Many igneous rocks also contain the sulfide minerals pyrrhotite and pentlandite . During weathering , iron tends to leach from sulfide deposits as the sulfate and from silicate deposits as the bicarbonate. Both of these are oxidized in aqueous solution and precipitate in even mildly elevated pH as iron(III) oxide . Large deposits of iron are banded iron formations ,
9180-775: The metal and thus flakes off, exposing more fresh surfaces for corrosion. Chemically, the most common oxidation states of iron are iron(II) and iron(III) . Iron shares many properties of other transition metals, including the other group 8 elements , ruthenium and osmium . Iron forms compounds in a wide range of oxidation states , −4 to +7. Iron also forms many coordination compounds ; some of them, such as ferrocene , ferrioxalate , and Prussian blue have substantial industrial, medical, or research applications. The body of an adult human contains about 4 grams (0.005% body weight) of iron, mostly in hemoglobin and myoglobin . These two proteins play essential roles in oxygen transport by blood and oxygen storage in muscles . To maintain
9288-606: The meteorites Semarkona and Chervony Kut, a correlation between the concentration of Ni, the granddaughter of Fe, and the abundance of the stable iron isotopes provided evidence for the existence of Fe at the time of formation of the Solar System . Possibly the energy released by the decay of Fe, along with that released by Al , contributed to the remelting and differentiation of asteroids after their formation 4.6 billion years ago. The abundance of Ni present in extraterrestrial material may bring further insight into
9396-410: The mine tailings contain an average of approximately 11% iron, there would be approximately 1.41 million tons of iron wasted annually. These tailings are also high in other useful metals such as copper , nickel , and cobalt , and they can be used for road-building materials like pavement and filler and building materials such as cement, low-grade glass, and wall materials. While tailings are
9504-422: The mine to the port travelled on 5 April 2008. The mine's workforce is on a fly-in fly-out roster. FIFO arrivals and departures take place at Fortescue Dave Forrest Airport , which is approximately five kilometres away. The hubs' (Cloudbreak and Chichester combined) annual production rate, as of January 2013, is 90 million tonnes of iron ore. Instead, Fortescue decided to develop its Christmas Creek deposit, at
9612-559: The necessary levels, human iron metabolism requires a minimum of iron in the diet. Iron is also the metal at the active site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants and animals. At least four allotropes of iron (differing atom arrangements in the solid) are known, conventionally denoted α , γ , δ , and ε . The first three forms are observed at ordinary pressures. As molten iron cools past its freezing point of 1538 °C, it crystallizes into its δ allotrope, which has
9720-436: The orbitals of those two electrons (d z and d x − y ) do not point toward neighboring atoms in the lattice, and therefore are not involved in metallic bonding. In the absence of an external source of magnetic field, the atoms get spontaneously partitioned into magnetic domains , about 10 micrometers across, such that the atoms in each domain have parallel spins, but some domains have other orientations. Thus
9828-533: The origin and early history of the Solar System . The most abundant iron isotope Fe is of particular interest to nuclear scientists because it represents the most common endpoint of nucleosynthesis . Since Ni (14 alpha particles ) is easily produced from lighter nuclei in the alpha process in nuclear reactions in supernovae (see silicon burning process ), it is the endpoint of fusion chains inside extremely massive stars . Although adding more alpha particles
9936-444: The other hand, the pale green iron(II) hexaquo ion [Fe(H 2 O) 6 ] does not undergo appreciable hydrolysis. Carbon dioxide is not evolved when carbonate anions are added, which instead results in white iron(II) carbonate being precipitated out. In excess carbon dioxide this forms the slightly soluble bicarbonate, which occurs commonly in groundwater, but it oxidises quickly in air to form iron(III) oxide that accounts for
10044-581: The oxidizing power of Fe and the high reducing power of I : Ferric iodide, a black solid, is not stable in ordinary conditions, but can be prepared through the reaction of iron pentacarbonyl with iodine and carbon monoxide in the presence of hexane and light at the temperature of −20 °C, with oxygen and water excluded. Complexes of ferric iodide with some soft bases are known to be stable compounds. The standard reduction potentials in acidic aqueous solution for some common iron ions are given below: The red-purple tetrahedral ferrate (VI) anion
10152-504: The past as high-grade iron ore deposits requiring little beneficiation . There are several granite-associated deposits of this nature in Malaysia and Indonesia . Other sources of magnetite iron ore include metamorphic accumulations of massive magnetite ore such as at Savage River , Tasmania , formed by shearing of ophiolite ultramafics . Another, minor, source of iron ores are magmatic accumulations in layered intrusions which contain
10260-497: The past work on isotopic composition of iron has focused on the nucleosynthesis of Fe through studies of meteorites and ore formation. In the last decade, advances in mass spectrometry have allowed the detection and quantification of minute, naturally occurring variations in the ratios of the stable isotopes of iron. Much of this work is driven by the Earth and planetary science communities, although applications to biological and industrial systems are emerging. In phases of
10368-473: The principal Indian producers of iron ore. World consumption of iron ore grows 10% per year on average with the main consumers being China, Japan, Korea, the United States, and the European Union. China is currently the largest consumer of iron ore, which translates to be the world's largest steel producing country. It is also the largest importer, buying 52% of the seaborne trade in iron ore in 2004. China
10476-474: The principal iron mineral. Banded iron formations are known as taconite within North America. The mining involves moving tremendous amounts of ore and waste. The waste comes in two forms: non-ore bedrock in the mine ( overburden or interburden locally known as mullock), and unwanted minerals, which are an intrinsic part of the ore rock itself ( gangue ). The mullock is mined and piled in waste dumps , and
10584-414: The principal ores for the production of iron (see bloomery and blast furnace). They are also used in the production of ferrites , useful magnetic storage media in computers, and pigments. The best known sulfide is iron pyrite (FeS 2 ), also known as fool's gold owing to its golden luster. It is not an iron(IV) compound, but is actually an iron(II) polysulfide containing Fe and S 2 ions in
10692-429: The quartz is left behind when the resultant powder is passed under a magnetic separator. Generally, most magnetite banded iron formation deposits must be ground to between 32 and 45 μm (0.0013 and 0.0018 in) in order to produce a low-silica magnetite concentrate. Magnetite concentrate grades are generally in excess of 70% iron by weight and usually are low in phosphorus, aluminium, titanium, and silica and demand
10800-407: The rock must be comminuted to enable efficient magnetic separation to provide a high-purity magnetite concentrate. This determines the energy inputs required to run a milling operation. Mining of banded iron formations involves coarse crushing and screening, followed by rough crushing and fine grinding to comminute the ore to the point where the crystallized magnetite and quartz are fine enough that
10908-446: The seaborne trade, with 72% of the market. BHP, Rio and Vale control 66% of this market between them. In Australia , iron ore is won from three main sources: pisolite " channel iron deposit " ore derived by mechanical erosion of primary banded-iron formations and accumulated in alluvial channels such as at Pannawonica, Western Australia ; and the dominant metasomatically altered banded iron formation -related ores such as at Newman ,
11016-437: The second half of the 3d transition series, vertical similarities down the groups compete with the horizontal similarities of iron with its neighbors cobalt and nickel in the periodic table, which are also ferromagnetic at room temperature and share similar chemistry. As such, iron, cobalt, and nickel are sometimes grouped together as the iron triad . Unlike many other metals, iron does not form amalgams with mercury . As
11124-459: The seventh largest global center of iron ore production, behind Australia, Brazil, China, India, Russia, and South Africa. Producers of iron ore in Ukraine include Ferrexpo , Metinvest , and ArcelorMittal Kryvyi Rih . In 2014, mines in the United States produced 57,500,000 t (56,600,000 long tons; 63,400,000 short tons) of iron ore with an estimated value of $ 5.1 billion. Iron mining in
11232-451: The seventh-largest global center of iron ore production, behind Australia, Brazil, China, Russia, South Africa, and Ukraine. India's iron ore production in 2023 was 285,000,000 metric tonnes and was the fourth largest producer in the world. According to the U.S. Geological Survey's 2021 Report on iron ore, Ukraine is estimated to have produced 62,000,000 t (61,000,000 long tons; 68,000,000 short tons) of iron ore in 2020, placing it as
11340-547: The surface of Mars is derived from an iron oxide-rich regolith . Significant amounts of iron occur in the iron sulfide mineral pyrite (FeS 2 ), but it is difficult to extract iron from it and it is therefore not exploited. In fact, iron is so common that production generally focuses only on ores with very high quantities of it. According to the International Resource Panel 's Metal Stocks in Society report ,
11448-401: The table aside. The major constraint to economics for iron ore deposits is not necessarily the grade or size of the deposits, because it is not particularly hard to geologically prove enough tonnage of the rocks exist. The main constraint is the position of the iron ore relative to market, the cost of rail infrastructure to get it to market, and the energy cost required to do so. Mining iron ore
11556-589: The two mines shut down. There have also been iron ore mines in Utah and Alabama ; however, the last iron ore mine in Utah shut down in 2014 and the last iron ore mine in Alabama shut down in 1975. Iron ores consist of oxygen and iron atoms bonded together into molecules. To convert it to metallic iron, it must be smelted or sent through a direct reduction process to remove the oxygen. Oxygen-iron bonds are strong, and to remove
11664-455: The volume of the lower mantle of the Earth, which makes it the second most abundant mineral phase in that region after silicate perovskite (Mg,Fe)SiO 3 ; it also is the major host for iron in the lower mantle. At the bottom of the transition zone of the mantle, the reaction γ- (Mg,Fe) 2 [SiO 4 ] ↔ (Mg,Fe)[SiO 3 ] + (Mg,Fe)O transforms γ-olivine into a mixture of silicate perovskite and ferropericlase and vice versa. In
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