A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen ) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied.
149-467: A breathalyzer or breathalyser (a portmanteau of breath and analyzer/analyser ), also called an alcohol meter , is a device for measuring breath alcohol content (BrAC). It is commonly utilized by law enforcement officers whenever they initiate traffic stops . The name is a genericized trademark of the Breathalyzer brand name of instruments developed by inventor Robert Frank Borkenstein in
298-403: A cathode , and an electrolyte that allows ions, often positively charged hydrogen ions (protons), to move between the two sides of the fuel cell. At the anode, a catalyst causes the fuel to undergo oxidation reactions that generate ions (often positively charged hydrogen ions) and electrons. The ions move from the anode to the cathode through the electrolyte. At the same time, electrons flow from
447-490: A cogeneration power plant in hospitals, universities and large office buildings. In recognition of the fuel cell industry and America's role in fuel cell development, the United States Senate recognized October 8, 2015 as National Hydrogen and Fuel Cell Day , passing S. RES 217. The date was chosen in recognition of the atomic weight of hydrogen (1.008). Fuel cells come in many varieties; however, they all work in
596-442: A " stish " or a " starsh ", it would be a blend. Furthermore, when blends are formed by shortening established compounds or phrases, they can be considered clipped compounds , such as romcom for romantic comedy . Blends of two or more words may be classified from each of three viewpoints: morphotactic, morphonological, and morphosemantic. Blends may be classified morphotactically into two kinds: total and partial . In
745-507: A "slope" parameter. This parameter detects any decrease in alcohol concentration of 0.006 g per 210 L of breath in 0.6 second, a condition indicative of residual mouth alcohol, and will result in an "invalid sample" warning to the operator, notifying the operator of the presence of the residual mouth alcohol. Other instruments require that the individual be tested twice at least two minutes apart. Mouthwash or other mouth alcohol will have somewhat dissipated after two minutes and cause
894-467: A Conforming Products List of breath alcohol devices approved for preliminary screening use. In the United States, the main use of the preliminary breath test (PBT) is to establish probable cause for arrest. All states have implied consent laws , which means that by applying for a driver's license, drivers are agreeing to take an evidentiary chemical test (blood, breath, or urine) after being arrested for
1043-664: A DUI. But in US law, the arrest and subsequent test may be invalidated if it is found that the arrest lacked probable cause. The PBT establishes a baseline alcohol level that the police officer may use to justify the arrest. The result of the PBT is not generally admissible in court, except to establish probable cause, although some states, such as Idaho, permit data or "readings" from hand-held preliminary breath testers or preliminary alcohol screeners to be presented as evidence in court. In states such as Florida and Colorado, there are no penalties for refusing
1192-409: A PBT. Police are not obliged to advise the suspect that participation in a FST, PBT, or other pre-arrest procedures is voluntary. In contrast, formal evidentiary tests given under implied consent requirements are considered mandatory. Portmanteau In linguistics , a blend —also known as a blend word , lexical blend , or portmanteau —is a word formed by combining the meanings, and parts of
1341-723: A SOFC system are less than those from a fossil fuel combustion plant. The chemical reactions for the SOFC system can be expressed as follows: SOFC systems can run on fuels other than pure hydrogen gas. However, since hydrogen is necessary for the reactions listed above, the fuel selected must contain hydrogen atoms. For the fuel cell to operate, the fuel must be converted into pure hydrogen gas. SOFCs are capable of internally reforming light hydrocarbons such as methane (natural gas), propane, and butane. These fuel cells are at an early stage of development. Challenges exist in SOFC systems due to their high operating temperatures. One such challenge
1490-471: A battery, except as hydrogen, but in some applications, such as stand-alone power plants based on discontinuous sources such as solar or wind power , they are combined with electrolyzers and storage systems to form an energy storage system. As of 2019, 90% of hydrogen was used for oil refining, chemicals and fertilizer production (where hydrogen is required for the Haber–Bosch process ), and 98% of hydrogen
1639-679: A blood-alcohol concentration of 0.07%, for example, a person could have a partition ratio of 1500:1 and a breath test reading of 0.10 g/2100 mL, over the legal limit in some jurisdictions. However, low partition ratios are generally observed during the absorption phase. Post-absorption, the ratio is relatively fixed, 2382 ± 119 [2125–2765], although this ratio was measured in a laboratory environment and variation may be larger in real-world scenarios. Other false positives of high BrAC and also blood reading are related to patients with proteinuria and hematuria, due to kidney metabolization and failure. The metabolization rate of related patients with kidney damage
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#17328845558791788-452: A breath analyzer test. The methods tested included breath mints , onions , denture cream, mouthwash , pennies and batteries; all of these methods proved ineffective. The show noted that using these items to cover the smell of alcohol may fool a person, but, since they will not actually reduce a person's BrAC, there will be no effect on a breath analyzer test regardless of the quantity used, if any, it appeared that using mouthwash only raised
1937-578: A certain level of alcohol in the breath, was approved for police use. Lion Laboratories won the Queen's Award for Technological Achievement for the product in 1980, and it began to be marketed worldwide. The Alcolyser was superseded by the Lion Intoximeter 3000 in 1983, and later by the Lion Alcolmeter and Lion Intoxilyser. These later models used a fuel cell alcohol sensor rather than crystals, providing
2086-622: A common gasoline additive, has been alleged anecdotally to cause false positives in persons exposed to it. Tests have shown this to be true for older machines; however, newer machines detect this interference and compensate for it. Any number of other products found in the environment or workplace can also cause erroneous BAC results. These include compounds found in lacquer , paint remover, celluloid , gasoline , and cleaning fluids, especially ethers , alcohols , and other volatile compounds. Absorption of alcohol continues for anywhere from 20 minutes (on an empty stomach) to two-and-one-half hours (on
2235-651: A complete, closed-loop system: Solar panels power an electrolyzer, which makes hydrogen. The hydrogen is stored in a 500-U.S.-gallon (1,900 L) tank at 200 pounds per square inch (1,400 kPa), and runs a ReliOn fuel cell to provide full electric back-up to the off-the-grid residence. Another closed system loop was unveiled in late 2011 in Hempstead, NY. Fuel cells can be used with low-quality gas from landfills or waste-water treatment plants to generate power and lower methane emissions . A 2.8 MW fuel cell plant in California
2384-449: A concentrated solution of KOH or NaOH which serves as an electrolyte. H 2 gas and O 2 gas are bubbled into the electrolyte through the porous carbon electrodes. Thus the overall reaction involves the combination of hydrogen gas and oxygen gas to form water. The cell runs continuously until the reactant's supply is exhausted. This type of cell operates efficiently in the temperature range 343–413 K (70 -140 °C) and provides
2533-523: A form suitable for carrying on horseback; (now esp.) one in the form of a stiff leather case hinged at the back to open into two equal parts". According to The American Heritage Dictionary of the English Language ( AHD ), the etymology of the word is the French porte-manteau , from porter , "to carry", and manteau , "cloak" (from Old French mantel , from Latin mantellum ). According to
2682-476: A fuel cell type detector, or an organic interferent to fool an infrared absorption detector. The infrared absorption detector is more vulnerable to interference than a laboratory instrument measuring a continuous absorption spectrum since it only makes measurements at particular discrete wavelengths. However, due to the fact that any interference can only cause higher absorption, not lower, the estimated blood alcohol content will be overestimated. Additionally, Cl 2
2831-597: A fuel-to-electricity efficiency of 50%, considerably higher than the 37–42% efficiency of a phosphoric acid fuel cell plant. Efficiencies can be as high as 65% when the fuel cell is paired with a turbine, and 85% if heat is captured and used in a combined heat and power (CHP) system. FuelCell Energy, a Connecticut-based fuel cell manufacturer, develops and sells MCFC fuel cells. The company says that their MCFC products range from 300 kW to 2.8 MW systems that achieve 47% electrical efficiency and can utilize CHP technology to obtain higher overall efficiencies. One product,
2980-581: A full stomach) after the last consumption, generally taking around 40-50 minutes. During the absorptive phase, the concentration of alcohol throughout the body changes unpredictably, as it is affected by gastrointestinal physiology such as irregular contraction patterns. After absorption, the concentrations in the body settle down and follow predictable patterns. During absorption, the BAC in arterial blood will generally be higher than in venous blood, but post-absorption, venous BAC will be higher than arterial BAC. This
3129-458: A high operating temperature provides an advantage by removing the need for a precious metal catalyst like platinum, thereby reducing cost. Additionally, waste heat from SOFC systems may be captured and reused, increasing the theoretical overall efficiency to as high as 80–85%. The high operating temperature is largely due to the physical properties of the YSZ electrolyte. As temperature decreases, so does
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#17328845558793278-403: A higher current to be supplied. Such a design is called a fuel cell stack . The cell surface area can also be increased, to allow higher current from each cell. In the archetypical hydrogen–oxide proton-exchange membrane fuel cell (PEMFC) design, a proton-conducting polymer membrane (typically nafion ) contains the electrolyte solution that separates the anode and cathode sides. This
3427-432: A hot water storage tank to smooth out the thermal heat production was a serious disadvantage in the domestic market place where space in domestic properties is at a great premium. Delta-ee consultants stated in 2013 that with 64% of global sales the fuel cell micro-combined heat and power passed the conventional systems in sales in 2012. The Japanese ENE FARM project stated that 34.213 PEMFC and 2.224 SOFC were installed in
3576-568: A hydrogen source would create less than one ounce of pollution (other than CO 2 ) for every 1,000 kW·h produced, compared to 25 pounds of pollutants generated by conventional combustion systems. Fuel Cells also produce 97% less nitrogen oxide emissions than conventional coal-fired power plants. One such pilot program is operating on Stuart Island in Washington State. There the Stuart Island Energy Initiative has built
3725-455: A hydrogen-rich gas in the anode, eliminating the need to produce hydrogen externally. The reforming process creates CO 2 emissions. MCFC-compatible fuels include natural gas, biogas and gas produced from coal. The hydrogen in the gas reacts with carbonate ions from the electrolyte to produce water, carbon dioxide, electrons and small amounts of other chemicals. The electrons travel through an external circuit, creating electricity, and return to
3874-527: A jury finds it unreliable or if other evidence establishes a reasonable doubt as to whether the person actually drove with a breath or blood alcohol level of 0.08% or greater. Another issue is that the BrAC is typically tested several hours after the time of driving. Some jurisdictions, such as the State of Washington, allow the use of breath analyzer test results without regard as to how much time passed between operation of
4023-427: A kind of bath), the attributive blends of English are mostly head-final and mostly endocentric . As an example of an exocentric attributive blend, Fruitopia may metaphorically take the buyer to a fruity utopia (and not a utopian fruit); however, it is not a utopia but a drink. Coordinate blends (also called associative or portmanteau blends) combine two words having equal status, and have two heads. Thus brunch
4172-545: A more reliable curbside test and removing the need for blood or urine samples to be taken at a police station . In 1991, Lion Laboratories was sold to the American company MPD, Inc. Breath analyzers do not directly measure blood alcohol concentration (BAC), which requires the analysis of a blood sample. Instead, they measure the amount of alcohol in one's breath, BrAC, generally reported in milligrams of alcohol per liter of breathed air. The relationship between BrAC and BAC
4321-573: A person produce a breathalyzer sample an officer must have "reasonable suspicion" that the person drove with more than 80 mg alcohol per 100 mL of blood. The demand must be within three hours of driving. Any driver that refuses can be charged under s.254 of the Criminal Code. With the legalization of cannabis , updates to the criminal code are proposed that will allow a breathalyzer test to be administered without suspicion of impairment. The US National Highway Traffic Safety Administration maintains
4470-459: A potential of about 0.9 V. Alkaline anion exchange membrane fuel cell (AAEMFC) is a type of AFC which employs a solid polymer electrolyte instead of aqueous potassium hydroxide (KOH) and it is superior to aqueous AFC. Solid oxide fuel cells (SOFCs) use a solid material, most commonly a ceramic material called yttria-stabilized zirconia (YSZ), as the electrolyte . Because SOFCs are made entirely of solid materials, they are not limited to
4619-770: A power-plant-to-wheel efficiency of 22% if the hydrogen is stored as high-pressure gas, and 17% if it is stored as liquid hydrogen . Stationary fuel cells are used for commercial, industrial and residential primary and backup power generation. Fuel cells are very useful as power sources in remote locations, such as spacecraft, remote weather stations, large parks, communications centers, rural locations including research stations, and in certain military applications. A fuel cell system running on hydrogen can be compact and lightweight, and have no major moving parts. Because fuel cells have no moving parts and do not involve combustion, in ideal conditions they can achieve up to 99.9999% reliability. This equates to less than one minute of downtime in
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4768-425: A requirement, as in enclosed spaces such as warehouses, and where hydrogen is considered an acceptable reactant, a [PEM fuel cell] is becoming an increasingly attractive choice [if exchanging batteries is inconvenient]". In 2013 military organizations were evaluating fuel cells to determine if they could significantly reduce the battery weight carried by soldiers. In a fuel cell vehicle the tank-to-wheel efficiency
4917-401: A six-year period. Since fuel cell electrolyzer systems do not store fuel in themselves, but rather rely on external storage units, they can be successfully applied in large-scale energy storage, rural areas being one example. There are many different types of stationary fuel cells so efficiencies vary, but most are between 40% and 60% energy efficient. However, when the fuel cell's waste heat
5066-413: A suspect to inflate a football bladder with his breath. Since the 2 liters of the man's breath contained 1.5 mg of ethanol, Gorsky testified before the court that the defendant was "50% drunk". The use of drunkenness as the standard, as opposed to BAC, perhaps invalidated the analysis, as tolerance to alcohol varies. However, the story illustrates the general principles of breath analysis. In 1931
5215-401: A sustained equilibrium BAC where absorption and elimination are proportional. Across all phases, BrAC correlates closely with arterial BAC. Arterial blood distributes oxygen throughout the body. Breath alcohol is a representation of the equilibrium of alcohol concentration as the blood gases (alcohol) pass from the arterial blood into the lungs to be expired in the breath. The ratio of ABAC:BrAC
5364-411: A system or device that converts energy is measured by the ratio of the amount of useful energy put out by the system ("output energy") to the total amount of energy that is put in ("input energy") or by useful output energy as a percentage of the total input energy. In the case of fuel cells, useful output energy is measured in electrical energy produced by the system. Input energy is the energy stored in
5513-481: A total blend, each of the words creating the blend is reduced to a mere splinter. Some linguists limit blends to these (perhaps with additional conditions): for example, Ingo Plag considers "proper blends" to be total blends that semantically are coordinate, the remainder being "shortened compounds". Commonly for English blends, the beginning of one word is followed by the end of another: Much less commonly in English,
5662-437: A welding machine. In the 1960s, Pratt & Whitney licensed Bacon's U.S. patents for use in the U.S. space program to supply electricity and drinking water (hydrogen and oxygen being readily available from the spacecraft tanks). In 1991, the first hydrogen fuel cell automobile was developed by Roger E. Billings. UTC Power was the first company to manufacture and commercialize a large, stationary fuel cell system for use as
5811-413: A year. There are two ways of calibrating a precision fuel cell breath analyzer, the wet-bath and the dry-gas methods. Each method requires specialized equipment and factory-trained technicians. It is not a procedure that can be conducted by untrained users or without the proper equipment. Some semiconductor models are designed specifically to allow the sensor module to be replaced without the need to send
5960-572: Is flow batteries , in which the fuel can be regenerated by recharging. Individual fuel cells produce relatively small electrical potentials, about 0.7 volts, so cells are "stacked", or placed in series, to create sufficient voltage to meet an application's requirements. In addition to electricity, fuel cells produce water vapor, heat and, depending on the fuel source, very small amounts of nitrogen dioxide and other emissions. PEMFC cells generally produce fewer nitrogen oxides than SOFC cells: they operate at lower temperatures, use hydrogen as fuel, and limit
6109-407: Is frankenword , an autological word exemplifying the phenomenon it describes, blending " Frankenstein " and "word". Fuel cell The first fuel cells were invented by Sir William Grove in 1838. The first commercial use of fuel cells came almost a century later following the invention of the hydrogen–oxygen fuel cell by Francis Thomas Bacon in 1932. The alkaline fuel cell , also known as
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6258-446: Is 2294 ± 56 across all phases and 2251 ± 46 [2141-2307] in the post-absorption phase. For example, a breathalyzer measurement of 0.10 mg/L of breath alcohol characterises approximately 0.0001×2251 g/L, or 0.2251 g/L of arterial blood alcohol concentration (equivalent to 0.2251 permille or 0.02251% BAC). The ratio of venous blood alcohol content to breath alcohol content may vary significantly, from 1300:1 to 3100:1. Assuming
6407-477: Is a Japanese blend that has entered the English language. The Vietnamese language also encourages blend words formed from Sino-Vietnamese vocabulary . For example, the term Việt Cộng is derived from the first syllables of "Việt Nam" (Vietnam) and "Cộng sản" (communist). Many corporate brand names , trademarks, and initiatives, as well as names of corporations and organizations themselves, are blends. For example, Wiktionary , one of Misplaced Pages 's sister projects,
6556-489: Is a blend of wiki and dictionary . The word portmanteau was introduced in this sense by Lewis Carroll in the book Through the Looking-Glass (1871), where Humpty Dumpty explains to Alice the coinage of unusual words used in " Jabberwocky ". Slithy means "slimy and lithe" and mimsy means "miserable and flimsy". Humpty Dumpty explains to Alice the practice of combining words in various ways, comparing it to
6705-500: Is abnormal in relation to percent in alcohol in the breath. However, since potassium dichromate is a strong oxidizer, numerous alcohol groups can be oxidized by kidney and blood filtration, producing false positives. It is sometimes said that the exhaled air analyzed by the breathalyzer is "alveolar air", coming from the alveoli in close proximity to the blood in pulmonary circulation and containing ethanol in concentrations proportional to that blood approximated by Henry's law . However,
6854-440: Is both phonological and orthographic, but with no other shortening: The overlap may be both phonological and orthographic, and with some additional shortening to at least one of the ingredients: Such an overlap may be discontinuous: These are also termed imperfect blends. It can occur with three components: The phonological overlap need not also be orthographic: If the phonological but non-orthographic overlap encompasses
7003-432: Is complex, and is affected by many factors. Calibration is the process of checking and adjusting the internal settings of a breath analyzer by comparing and adjting its test results to a known alcohol standard. Breath analyzer sensors drift over time and require periodic calibration to ensure accuracy. Many handheld breath analyzers sold to consumers use a silicon oxide sensor (also called a semiconductor sensor) to determine
7152-406: Is especially clear with bolus dosing, chugging a single large drink. With additional doses of alcohol, the definitions of absorption and post-absorption are less clear. However, once absorption of the last drink has finished, the concentrations will follow standard post-absorption curves. It is also not always clear from a BAC graph when the absorption phase finishes - for example, the body can reach
7301-417: Is exhaled during breathing. But the relationship of the alcohol concentration of this air to the concentration of alcohol in the blood is somewhat suspect and can be affected by many variables. As air is exhaled, the alcohol concentration of the exhaled air increases over time, rising significantly in the first few seconds and then slowing down after, but not leveling out until the subject stops exhaling. This
7450-639: Is greater than 45% at low loads and shows average values of about 36% when a driving cycle like the NEDC ( New European Driving Cycle ) is used as test procedure. The comparable NEDC value for a Diesel vehicle is 22%. In 2008 Honda released a demonstration fuel cell electric vehicle (the Honda FCX Clarity ) with fuel stack claiming a 60% tank-to-wheel efficiency. It is also important to take losses due to fuel production, transportation, and storage into account. Fuel cell vehicles running on compressed hydrogen may have
7599-557: Is making the assumption that the alcohol in the breath sample came from the lungs. However, alcohol may have come from the mouth, throat or stomach for a number of reasons. A very tiny amount of alcohol from the mouth, throat or stomach can have a significant impact on the breath-alcohol reading. Recent use of mouthwash or breath fresheners can also skew results upward, as they can contain fairly high levels of alcohol. Listerine mouthwash , for example, contains 26.9% alcohol, and can skew results for between 5 and 10 minutes. A scientist tested
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#17328845558797748-692: Is neither a breakfasty lunch nor a lunchtime breakfast but instead some hybrid of breakfast and lunch; Oxbridge is equally Oxford and Cambridge universities. This too parallels (conventional, non-blend) compounds: an actor–director is equally an actor and a director. Two kinds of coordinate blends are particularly conspicuous: those that combine (near‑) synonyms: and those that combine (near‑) opposites: Blending can also apply to roots rather than words, for instance in Israeli Hebrew : "There are two possible etymological analyses for Israeli Hebrew כספר kaspár 'bank clerk, teller'. The first
7897-446: Is not because there is a "dead space" of non-alcoholic air in the airways - the alcohol concentration is nearly identical in all regions of the lung. Rather, it is because, during exhalation, water and alcohol are being redeposited on the airways, primarily the trachea and generations 6 though 12 of the airways. As more fluid is deposited on the mucous surfaces, the remaining fluid travels further, resulting in more alcohol being recorded by
8046-482: Is produced by steam methane reforming , which emits carbon dioxide. The overall efficiency (electricity to hydrogen and back to electricity) of such plants (known as round-trip efficiency ), using pure hydrogen and pure oxygen can be "from 35 up to 50 percent", depending on gas density and other conditions. The electrolyzer/fuel cell system can store indefinite quantities of hydrogen, and is therefore suited for long-term storage. Solid-oxide fuel cells produce heat from
8195-585: Is referred to as the heart of the PEMFC and is usually made of a proton-exchange membrane sandwiched between two catalyst -coated carbon papers . Platinum and/or similar types of noble metals are usually used as the catalyst for PEMFC, and these can be contaminated by carbon monoxide , necessitating a relatively pure hydrogen fuel. The electrolyte could be a polymer membrane . Phosphoric acid fuel cells (PAFCs) were first designed and introduced in 1961 by G. V. Elmore and H. A. Tanner . In these cells, phosphoric acid
8344-433: Is represented by various shorter substitutes – ‑otel ... – which I shall call splinters. Words containing splinters I shall call blends". Thus, at least one of the parts of a blend, strictly speaking, is not a complete morpheme , but instead a mere splinter or leftover word fragment. For instance, starfish is a compound, not a blend, of star and fish , as it includes both words in full. However, if it were called
8493-438: Is said to be the largest of the type. Small-scale (sub-5kWhr) fuel cells are being developed for use in residential off-grid deployment. Combined heat and power (CHP) fuel cell systems, including micro combined heat and power (MicroCHP) systems are used to generate both electricity and heat for homes (see home fuel cell ), office building and factories. The system generates constant electric power (selling excess power back to
8642-405: Is that it consists of (Hebrew>) Israeli כסף késef 'money' and the ( International /Hebrew>) Israeli agentive suffix ר- -ár . The second is that it is a quasi- portmanteau word which blends כסף késef 'money' and (Hebrew>) Israeli ספר √spr 'count'. Israeli Hebrew כספר kaspár started as a brand name but soon entered the common language. Even if the second analysis is the correct one,
8791-452: Is the O-H bond, which gives a strong absorbance at a short wavelength. The more light is absorbed by compounds containing the alcohol group, the less reaches the detector on the other side—and the higher the reading. Other groups, most notably aromatic rings and carboxylic acids can give similar absorbance readings. Some natural and volatile interfering compounds do exist, however. For example,
8940-594: Is the cells' short life span. The high-temperature and carbonate electrolyte lead to corrosion of the anode and cathode. These factors accelerate the degradation of MCFC components, decreasing the durability and cell life. Researchers are addressing this problem by exploring corrosion-resistant materials for components as well as fuel cell designs that may increase cell life without decreasing performance. MCFCs hold several advantages over other fuel cell technologies, including their resistance to impurities. They are not prone to "carbon coking", which refers to carbon build-up on
9089-528: Is the potential for carbon dust to build up on the anode, which slows down the internal reforming process. Research to address this "carbon coking" issue at the University of Pennsylvania has shown that the use of copper-based cermet (heat-resistant materials made of ceramic and metal) can reduce coking and the loss of performance. Another disadvantage of SOFC systems is the long start-up, making SOFCs less useful for mobile applications. Despite these disadvantages,
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#17328845558799238-670: Is toxic and corrosive. A 2007 episode of the Spike network's show Manswers showed some of the more common and not-so-common ways of attempts to beat the breath analyzer, none of which work. Test 1 was to suck on a copper-coated coin such as a penny. Test 2 was to hold a battery on the tongue. Test 3 was to chew gum. None of these tests showed a "pass" reading if the subject had consumed alcohol. In general, two types of breathalyzer are used. Small hand-held breathalyzers are not reliable enough to provide evidence in court but reliable enough to justify an arrest. These devices may be used by officers in
9387-506: Is used as a non-conductive electrolyte to pass protons from the anode to the cathode and to force electrons to travel from anode to cathode through an external electrical circuit. These cells commonly work in temperatures of 150 to 200 °C. This high temperature will cause heat and energy loss if the heat is not removed and used properly. This heat can be used to produce steam for air conditioning systems or any other thermal energy-consuming system. Using this heat in cogeneration can enhance
9536-436: Is used to heat a building in a cogeneration system this efficiency can increase to 85%. This is significantly more efficient than traditional coal power plants, which are only about one third energy efficient. Assuming production at scale, fuel cells could save 20–40% on energy costs when used in cogeneration systems. Fuel cells are also much cleaner than traditional power generation; a fuel cell power plant using natural gas as
9685-690: Is used, the CO 2 is released when methane from natural gas is combined with steam, in a process called steam methane reforming , to produce the hydrogen. This can take place in a different location to the fuel cell, potentially allowing the hydrogen fuel cell to be used indoors—for example, in forklifts. The different components of a PEMFC are The materials used for different parts of the fuel cells differ by type. The bipolar plates may be made of different types of materials, such as, metal, coated metal, graphite , flexible graphite, C–C composite , carbon – polymer composites etc. The membrane electrode assembly (MEA)
9834-613: The Electrochemical Society journal Interface in 2008, wrote, "While fuel cells are efficient relative to combustion engines, they are not as efficient as batteries, primarily due to the inefficiency of the oxygen reduction reaction (and ... the oxygen evolution reaction, should the hydrogen be formed by electrolysis of water). ... [T]hey make the most sense for operation disconnected from the grid, or when fuel can be provided continuously. For applications that require frequent and relatively rapid start-ups ... where zero emissions are
9983-570: The National Highway Traffic Safety Administration has found that dieters and diabetics may have acetone levels hundreds or even thousands of times higher than those in others. Acetone is one of the many substances that can be falsely identified as ethyl alcohol by some breath machines. However, fuel cell based systems are non-responsive to substances like acetone. Substances in the environment can also lead to false BAC readings. For example, methyl tert-butyl ether ,
10132-520: The OED Online , the etymology of the word is the "officer who carries the mantle of a person in a high position (1507 in Middle French), case or bag for carrying clothing (1547), clothes rack (1640)". In modern French, a porte-manteau is a clothes valet , a coat-tree or similar article of furniture for hanging up jackets, hats, umbrellas and the like. An occasional synonym for "portmanteau word"
10281-511: The ionic conductivity of YSZ. Therefore, to obtain the optimum performance of the fuel cell, a high operating temperature is required. According to their website, Ceres Power , a UK SOFC fuel cell manufacturer, has developed a method of reducing the operating temperature of their SOFC system to 500–600 degrees Celsius. They replaced the commonly used YSZ electrolyte with a CGO (cerium gadolinium oxide) electrolyte. The lower operating temperature allows them to use stainless steel instead of ceramic as
10430-428: The waste heat produced by the primary power cycle - whether fuel cell, nuclear fission or combustion - is captured and put to use, increasing the efficiency of the system to up to 85–90%. The theoretical maximum efficiency of any type of power generation system is never reached in practice, and it does not consider other steps in power generation, such as production, transportation and storage of fuel and conversion of
10579-442: The 1950s. Research into the possibilities of using breath to test for alcohol in a person's body dates as far back as 1874, when Francis E. Anstie made the observation that small amounts of alcohol were excreted in breath. In 1927, Emil Bogen produced a paper on breath analysis. He collected air in a football bladder and then tested this air for traces of alcohol, discovering that the alcohol content of 2 litres of expired air
10728-664: The Bacon fuel cell after its inventor, has been used in NASA space programs since the mid-1960s to generate power for satellites and space capsules . Since then, fuel cells have been used in many other applications. Fuel cells are used for primary and backup power for commercial, industrial and residential buildings and in remote or inaccessible areas. They are also used to power fuel cell vehicles , including forklifts, automobiles, buses, trains, boats, motorcycles, and submarines. There are many types of fuel cells, but they all consist of an anode ,
10877-515: The BrAC level itself became the direct predicate evidence for conviction, with no need to estimate BAC. In per se jurisdictions such as the UK, it is automatically illegal to drive a vehicle with a sufficiently high breath alcohol concentration (BrAC). The breath analyzer reading of the operator will be offered as evidence of that crime, and challenges can only be offered on the basis of an inaccurate reading. In other states, such as California and New Jersey,
11026-422: The BrAC. Pennies supposedly produce a chemical reaction, while batteries supposedly create an electrical charge, yet neither of these methods affected the breath analyzer results. The MythBusters episode also pointed out another complication: it would be necessary to insert the item into one's mouth (for example, eat an onion, rinse with mouthwash, conceal a battery), take the breath test, and then possibly remove
11175-552: The Breathalyzer provided law enforcement with a quick and portable test to determine an individual's intoxication level via breath analysis. Subsequent breath analyzers have converted primarily to infrared spectroscopy . In 1967 in Britain, Bill Ducie and Tom Parry Jones developed and marketed the first electronic breathalyser. They established Lion Laboratories in Cardiff . Ducie was a chartered electrical engineer , and Tom Parry Jones
11324-489: The DFC-ERG, is combined with a gas turbine and, according to the company, it achieves an electrical efficiency of 65%. The electric storage fuel cell is a conventional battery chargeable by electric power input, using the conventional electro-chemical effect. However, the battery further includes hydrogen (and oxygen) inputs for alternatively charging the battery chemically. Glossary of terms in table: The energy efficiency of
11473-431: The US initially prohibited driving with a high level of BAC, and did not have any laws regarding BrAC. A BrAC test result was merely presented as indirect evidence of BAC. Where the defendant had refused to take a subsequent blood test, the only way the state could prove BAC was by presenting scientific evidence of how alcohol in the breath gets there from alcohol in the blood, along with evidence of how to convert from one to
11622-465: The US, the ratio of 2100:1 was determined based on studies done in 1930-1950, with a 1952 report of the National Safety Council establishing the 2100:1 figure. The NSC has acknowledged that more recent research shows the actual relationship is most probably higher than 2100:1 and closer to 2300:1, but opines that this difference is of minimal practical significance in law enforcement. The use of
11771-435: The air reaches the alveoli, it is already near equilibrium - this is why inhaling dry air does not dry out the lungs significantly. With exhalation, water and alcohol are rapidly lost to the airways, primarily within the fifth to fifteenth generations of branching. Nonetheless, as may be evidenced by seeing one's breath in the cold, some water vapor does not get re-absorbed by the airways and is exhaled, and similarly some alcohol
11920-403: The alcohol concentration. These sensors are prone to contamination and interference from substances other than breath alcohol, and require recalibration or replacement every six months. Higher-end personal breath analyzers and professional-use breath alcohol testers use platinum fuel cell sensors. These too require recalibration but at less frequent intervals than semiconductor devices, usually once
12069-454: The alcohol for longer periods. Also known to produce false results due to residual alcohol in the mouth is passionate kissing with an intoxicated person. To help guard against mouth-alcohol contamination, certified breath-test operators and police officers are trained to observe a test subject carefully for at least 15–20 minutes before administering the breath test. Some instruments also feature built-in safeguards. The Intoxilyzer 5000 features
12218-467: The alcohol in the exhaled air comes essentially from the airways of the lung, and not from the alveoli. The alcohol acts similarly to water vapor, so it is instructive to study the humidity of lung air. During breathing, the inspired air picks up water and alcohol from the airways. Almost all uptake occurs in the upper airways; thus, the BrAC is most affected by the alcohol concentration in the bronchial circulation , which supplies blood to these airways. When
12367-493: The anode that results in reduced performance by slowing down the internal fuel reforming process. Therefore, carbon-rich fuels like gases made from coal are compatible with the system. The United States Department of Energy claims that coal, itself, might even be a fuel option in the future, assuming the system can be made resistant to impurities such as sulfur and particulates that result from converting coal into hydrogen. MCFCs also have relatively high efficiencies. They can reach
12516-478: The anode to the cathode through an external circuit, producing direct current electricity. At the cathode, another catalyst causes ions, electrons, and oxygen to react, forming water and possibly other products. Fuel cells are classified by the type of electrolyte they use and by the difference in start-up time ranging from 1 second for proton-exchange membrane fuel cells (PEM fuel cells, or PEMFC) to 10 minutes for solid oxide fuel cells (SOFC). A related technology
12665-423: The anode to the cathode), as is the case in all other types of fuel cells. Oxygen gas is fed through the cathode, where it absorbs electrons to create oxygen ions. The oxygen ions then travel through the electrolyte to react with hydrogen gas at the anode. The reaction at the anode produces electricity and water as by-products. Carbon dioxide may also be a by-product depending on the fuel, but the carbon emissions from
12814-502: The beginning of one word may be followed by the beginning of another: Some linguists do not regard beginning+beginning concatenations as blends, instead calling them complex clippings, clipping compounds or clipped compounds . Unusually in English, the end of one word may be followed by the end of another: A splinter of one word may replace part of another, as in three coined by Lewis Carroll in " Jabberwocky ": They are sometimes termed intercalative blends; these words are among
12963-420: The breath alcohol results." Acid reflux, or gastroesophageal reflux disease , can greatly exacerbate the mouth-alcohol problem. The stomach is normally separated from the throat by a valve, but when this valve becomes incompetent or herniated, there is nothing to stop the liquid contents in the stomach from rising and permeating the esophagus and mouth. The contents—including any alcohol—are then later exhaled into
13112-400: The breath sample is accepted. This raises concerns for subject with smaller lung volumes - they must exhale a greater fraction of their available lung volume compared with a larger subject. A mathematical model suggests that a 2L-lung-capacity subject's end-exhaled BrAC may read 35% higher than a 6L subject for the same minimum 1.5L exhalation and alveolar alcohol concentration. For exhalation to
13261-435: The breath test is more forgiving for some subjects than others. Nonetheless, the overall variance due to how much one breathes out is usually low, and some breathalyzers compensate for the volume of air. Jones tested several breathing patterns immediately before and during breathalyzer use and found the following changes (in order of effect): Overall, the results show an increase in measured BrAC with increased contact between
13410-406: The breathalyzer. One study of 10 individuals suffering from this condition did not find any actual increase in breath ethanol. Mouth alcohol can also be created in other ways. Dentures, some have theorized, will trap alcohol, although experiments have shown no difference if the normal 15 minute observation period is observed. Periodontal disease can also create pockets in the gums which will contain
13559-496: The breathalyzer. The recorded alcohol concentrations never reach the alveolar alcohol concentration, even if the subject exhales as deeply as possible. According to Henry's law, alveolar air alcohol concentration would be pulmonary BAC divided by 1756, compared to the BrAC which is arterial blood concentration divided by 2251. When the subject stops exhaling, the alcohol concentration levels off - this does not indicate that alveolar air has been obtained, as it will level off regardless of
13708-413: The captured breath in the sample chamber and detect the absorbance of the compound as a function of the wavelength of the beam, producing an absorbance spectrum that can be used to identify the compound, as the absorbance is due to the harmonic vibration and stretching of specific bonds in the molecule at specific wavelengths (see infrared spectroscopy ). The characteristic bond of alcohols in infrared
13857-548: The cathode. There, oxygen from the air and carbon dioxide recycled from the anode react with the electrons to form carbonate ions that replenish the electrolyte, completing the circuit. The chemical reactions for an MCFC system can be expressed as follows: As with SOFCs, MCFC disadvantages include slow start-up times because of their high operating temperature. This makes MCFC systems not suitable for mobile applications, and this technology will most likely be used for stationary fuel cell purposes. The main challenge of MCFC technology
14006-462: The cell substrate, which reduces cost and start-up time of the system. Molten carbonate fuel cells (MCFCs) require a high operating temperature, 650 °C (1,200 °F), similar to SOFCs . MCFCs use lithium potassium carbonate salt as an electrolyte, and this salt liquefies at high temperatures, allowing for the movement of charge within the cell – in this case, negative carbonate ions. Like SOFCs, MCFCs are capable of converting fossil fuel to
14155-501: The color change, the more alcohol there was present in the breath. The drunkometer was manufactured and sold by Stephenson Corporation of Red Bank, New Jersey . In 1954 Robert Frank Borkenstein (1912–2002) was a captain with the Indiana State Police and later a professor at Indiana University Bloomington . His trademarked Breathalyzer used chemical oxidation and photometry to determine alcohol concentrations. The invention of
14304-597: The development of his first crude fuel cells. He used a combination of sheet iron, copper, and porcelain plates, and a solution of sulphate of copper and dilute acid. In a letter to the same publication written in December 1838 but published in June 1839, German physicist Christian Friedrich Schönbein discussed the first crude fuel cell that he had invented. His letter discussed the current generated from hydrogen and oxygen dissolved in water. Grove later sketched his design, in 1842, in
14453-549: The diffusion of nitrogen into the anode via the proton exchange membrane, which forms NOx. The energy efficiency of a fuel cell is generally between 40 and 60%; however, if waste heat is captured in a cogeneration scheme, efficiencies of up to 85% can be obtained. The first references to hydrogen fuel cells appeared in 1838. In a letter dated October 1838 but published in the December 1838 edition of The London and Edinburgh Philosophical Magazine and Journal of Science , Welsh physicist and barrister Sir William Grove wrote about
14602-404: The effects of Binaca breath spray on an Intoxilyzer 5000. He performed 23 tests with subjects who sprayed their throats and obtained readings as high as 0.81—far beyond legal levels. The scientist also noted that the effects of the spray did not fall below detectable levels until after 18 minutes. Other than those, the most common source of mouth alcohol is from belching or burping . This causes
14751-404: The efficiency of phosphoric acid fuel cells from 40 to 50% to about 80%. Since the proton production rate on the anode is small, platinum is used as a catalyst to increase this ionization rate. A key disadvantage of these cells is the use of an acidic electrolyte. This increases the corrosion or oxidation of components exposed to phosphoric acid. Solid acid fuel cells (SAFCs) are characterized by
14900-447: The electricity into mechanical power. However, this calculation allows the comparison of different types of power generation. The theoretical maximum efficiency of a fuel cell approaches 100%, while the theoretical maximum efficiency of internal combustion engines is approximately 58%. Values are given from 40% for acidic, 50% for molten carbonate, to 60% for alkaline, solid oxide and PEM fuel cells. Fuel cells cannot store energy like
15049-427: The exhalation, which corresponds to the BrAC measured at about the 5-second mark. The Supreme Court of California determined that the BrAC is defined as the alcohol concentration of the last part of the subject’s expired breath. End-exhaled BrAC varies depending on several factors. Most alcohol breath testers require a minimum exhalation volume (normally between 1.1 and 1.5 L) or minimum six-second exhalation time before
15198-632: The federal government ensuring that the legal drinking age be the age of 21 across the 50 states. Police in Victoria , Australia , use breathalyzers that give a recognized 20% tolerance on readings. Noel Ashby, former Victoria Police Assistant Commissioner (Traffic & Transport), claims that this tolerance is to allow for different body types. The preliminary breath test or preliminary alcohol screening test uses small hand-held breath analyzers (hand-held breathalyzers). (The terms "preliminary breath test" ("PBT") and "preliminary alcohol screening test" reference
15347-408: The field as a form of "field sobriety test" commonly called "preliminary breath test" or "preliminary alcohol screening", or as evidential devices in point of arrest testing. Larger breathalyzer devices found in police stations can be used to produce court evidence, These desktop analyzers generally use infrared spectrophotometer technology, electrochemical fuel cell technology, or a combination of
15496-586: The final syllable ר- -ár apparently facilitated nativization since it was regarded as the Hebrew suffix ר- -år (probably of Persian pedigree), which usually refers to craftsmen and professionals, for instance as in Mendele Mocher Sforim 's coinage סמרטוטר smartutár 'rag-dealer'." Blending may occur with an error in lexical selection , the process by which a speaker uses his semantic knowledge to choose words. Lewis Carroll's explanation, which gave rise to
15645-488: The first practical roadside breath-testing device was the drunkometer developed by Rolla Neil Harger of the Indiana University School of Medicine . The drunkometer collected a motorist's breath sample directly into a balloon inside the machine. The breath sample was then pumped through an acidified potassium permanganate solution. If there was alcohol in the breath sample, the solution changed color. The greater
15794-442: The flat plane configuration of other types of fuel cells and are often designed as rolled tubes. They require high operating temperatures (800–1000 °C) and can be run on a variety of fuels including natural gas. SOFCs are unique because negatively charged oxygen ions travel from the cathode (positive side of the fuel cell) to the anode (negative side of the fuel cell) instead of protons travelling vice versa (i.e., from
15943-463: The fuel. According to the U.S. Department of Energy, fuel cells are generally between 40 and 60% energy efficient. This is higher than some other systems for energy generation. For example, the internal combustion engine of a car can be about 43% energy efficient. Steam power plants usually achieve efficiencies of 30-40% while combined cycle gas turbine and steam plants can achieve efficiencies above 60%. In combined heat and power (CHP) systems,
16092-461: The gradual drifting together of words over time due to them commonly appearing together in sequence, such as do not naturally becoming don't (phonologically, / d uː n ɒ t / becoming / d oʊ n t / ). A blend also differs from a compound , which fully preserves the stems of the original words. The British lecturer Valerie Adams's 1973 Introduction to Modern English Word-Formation explains that "In words such as motel ..., hotel
16241-506: The grid when it is not consumed), and at the same time produces hot air and water from the waste heat . As the result CHP systems have the potential to save primary energy as they can make use of waste heat which is generally rejected by thermal energy conversion systems. A typical capacity range of home fuel cell is 1–3 kW el , 4–8 kW th . CHP systems linked to absorption chillers use their waste heat for refrigeration . The waste heat from fuel cells can be diverted during
16390-403: The ingredients is the head and the other is attributive. A porta-light is a portable light, not a 'light-emitting' or light portability; light is the head. A snobject is a snobbery-satisfying object and not an objective or other kind of snob; object is the head. As is also true for (conventional, non-blend) attributive compounds (among which bathroom , for example, is a kind of room, not
16539-462: The ions are reunited with the electrons and the two react with a third chemical, usually oxygen, to create water or carbon dioxide. Design features in a fuel cell include: A typical fuel cell produces a voltage from 0.6 to 0.7 V at a full-rated load. Voltage decreases as current increases, due to several factors: To deliver the desired amount of energy, the fuel cells can be combined in series to yield higher voltage , and in parallel to allow
16688-411: The item — all of which would have to be accomplished discreetly enough to avoid alerting the police officers administering the test (who would obviously become very suspicious if they noticed that a person was inserting items into their mouth prior to taking a breath test). It would likely be very difficult, especially for someone in an intoxicated state, to be able to accomplish such a feat. In addition,
16837-429: The liquids and/or gases from the stomach—including any alcohol—to rise up into the soft tissue of the esophagus and oral cavity, where it will stay until it has dissipated. The American Medical Association concludes in its Manual for Chemical Tests for Intoxication (1959): "True reactions with alcohol in expired breath from sources other than the alveolar air (eructation, regurgitation, vomiting) will, of course, vitiate
16986-400: The load. At the anode a catalyst ionizes the fuel, turning the fuel into a positively charged ion and a negatively charged electron. The electrolyte is a substance specifically designed so ions can pass through it, but the electrons cannot. The freed electrons travel through a wire creating an electric current. The ions travel through the electrolyte to the cathode. Once reaching the cathode,
17135-454: The lower 2100:1 factor errs on the side of conservativism and can only favor the driver. In early years, the range of the BrAC threshold in the US varied considerably between States. States have since adopted a uniform 0.08% BrAC level, due to federal guidelines. It is said that the federal government ensures the passage of the federal guidelines by tying traffic safety highway funds to compliance with federal guidelines on certain issues, such as
17284-425: The lungs and the measured air. Exercising immediately before the test, such as running up and down a flight of stairs, can also reduce measured BrAC by 13% or more, with the combined effect of exercise and hyperventilation reaching 20%. One of the most common causes of falsely high breath analyzer readings is the existence of mouth alcohol. In analyzing a subject's breath sample, the breath analyzer's internal computer
17433-400: The maximum extent, such as under typical laboratory conditions, measured BrAC is unaffected by lung size. The subject's body temperature and breath temperature also influence results, with an increase in temperature corresponding to an increase in measured BrAC. Furthermore, the humidity and temperature of the ambient air can decrease results by as much as 10%. The result of these factors is that
17582-609: The membrane to the cathode, but the electrons are forced to travel in an external circuit (supplying power) because the membrane is electrically insulating. On the cathode catalyst, oxygen molecules react with the electrons (which have traveled through the external circuit) and protons to form water. In addition to this pure hydrogen type, there are hydrocarbon fuels for fuel cells, including diesel , methanol ( see: direct-methanol fuel cells and indirect methanol fuel cells ) and chemical hydrides. The waste products with these types of fuel are carbon dioxide and water. When hydrogen
17731-490: The morphemes or phonemes stay in the same position within the syllable. Some languages, like Japanese , encourage the shortening and merging of borrowed foreign words (as in gairaigo ), because they are long or difficult to pronounce in the target language. For example, karaoke , a combination of the Japanese word kara (meaning empty ) and the clipped form oke of the English loanword "orchestra" (J. ōkesutora , オーケストラ ),
17880-495: The original "portmanteaus" for which this meaning of the word was created. In a partial blend, one entire word is concatenated with a splinter from another. Some linguists do not recognize these as blends. An entire word may be followed by a splinter: A splinter may be followed by an entire word: An entire word may replace part of another: These have also been called sandwich words, and classed among intercalative blends. (When two words are combined in their entirety,
18029-490: The original fuel cell design by using a sulphonated polystyrene ion-exchange membrane as the electrolyte. Three years later another GE chemist, Leonard Niedrach, devised a way of depositing platinum onto the membrane, which served as a catalyst for the necessary hydrogen oxidation and oxygen reduction reactions. This became known as the "Grubb-Niedrach fuel cell". GE went on to develop this technology with NASA and McDonnell Aircraft, leading to its use during Project Gemini . This
18178-414: The other. DUI defense attorneys frequently contested the scientific reliability of such evidence. Before September 2011, South Dakota relied solely on blood tests to ensure accuracy. States responded in different ways to the inability to rely on breathalyzer evidence. Many states such as California modified their statutes so to make a certain level of alcohol in the breath illegal per se . In other words,
18327-756: The period 2012–2014, 30,000 units on LNG and 6,000 on LPG . Four fuel cell electric vehicles have been introduced for commercial lease and sale: the Honda Clarity , Toyota Mirai , Hyundai ix35 FCEV , and the Hyundai Nexo . By year-end 2019, about 18,000 FCEVs had been leased or sold worldwide. Fuel cell electric vehicles feature an average range of 505 km (314 mi) between refuelings and can be refueled in about 5 minutes. The U.S. Department of Energy's Fuel Cell Technology Program states that, as of 2011, fuel cells achieved 53–59% efficiency at one-quarter power and 42–53% vehicle efficiency at full power, and
18476-404: The point at which the subject stops exhaling. But it does mean that end-exhaled BrAC is readily obtained. This brings up the question of what is meant by reporting BrAC as a single number; is it the "deep-lung air", the highest possible reading obtainable by the subject's full exhalation? Or is it the zero concentration at the initial part of the curve? Hlastala suggests using the average BrAC during
18625-537: The process. A monochromatic light beam is passed through this sample, and a detector records the change in intensity and, hence, the change in color, which is used to calculate the percent alcohol in the breath. However, since potassium dichromate is a strong oxidizer, numerous alcohol groups can be oxidized by it, producing false positives . This source of false positives is unlikely as very few other substances found in exhaled air are oxidizable. Infrared-based breath analyzers project an infrared beam of radiation through
18774-493: The recombination of the oxygen and hydrogen. The ceramic can run as hot as 800 °C (1,470 °F). This heat can be captured and used to heat water in a micro combined heat and power (m-CHP) application. When the heat is captured, total efficiency can reach 80–90% at the unit, but does not consider production and distribution losses. CHP units are being developed today for the European home market. Professor Jeremy P. Meyers, in
18923-453: The result is considered a compound word rather than a blend. For example, bagpipe is a compound, not a blend, of bag and pipe. ) Morphologically, blends fall into two kinds: overlapping and non-overlapping . Overlapping blends are those for which the ingredients' consonants, vowels or even syllables overlap to some extent. The overlap can be of different kinds. These are also called haplologic blends. There may be an overlap that
19072-630: The same devices and functions.) They are generally based on electrochemical platinum fuel cell analysis. These units are similar to some evidentiary breathalyzers, but typically are not calibrated frequently enough for evidentiary purposes. The test device typically provides numerical blood alcohol content (BAC) readings, but its primary use is for screening. In some cases, the device even has "pass/fail" indicia. For example, in Canada, PST devices, called "alcohol screening devices" are set so that, from 0 to 49 mg% it shows digits, from 50 to 99 mg% it shows
19221-405: The same general manner. They are made up of three adjacent segments: the anode , the electrolyte , and the cathode . Two chemical reactions occur at the interfaces of the three different segments. The net result of the two reactions is that fuel is consumed, water or carbon dioxide is created, and an electric current is created, which can be used to power electrical devices, normally referred to as
19370-504: The same journal. The fuel cell he made used similar materials to today's phosphoric acid fuel cell . In 1932, English engineer Francis Thomas Bacon successfully developed a 5 kW stationary fuel cell. NASA used the alkaline fuel cell (AFC), also known as the Bacon fuel cell after its inventor, from the mid-1960s. In 1955, W. Thomas Grubb, a chemist working for the General Electric Company (GE), further modified
19519-410: The second reading to disagree with the first, requiring a retest. Many preliminary breath testers, however, feature no such safeguards. There are a number of substances or techniques that can supposedly "fool" a breath analyzer (i.e., generate a lower blood alcohol content ). A 2003 episode of the science television show MythBusters tested a number of methods that supposedly allow a person to fool
19668-435: The show noted that breath tests are often verified with blood tests (BAC, which are more accurate) and that even if a person somehow managed to fool a breath test, a blood test would certainly confirm a person's guilt. Other substances that might reduce the BrAC reading include a bag of activated charcoal concealed in the mouth (to absorb alcohol vapor), an oxidizing gas (such as N 2 O, Cl 2 , O 3 , etc.) that would fool
19817-399: The sounds, of two or more words together. English examples include smog , coined by blending smoke and fog , as well as motel , from motor ( motorist ) and hotel . A blend is similar to a contraction . On the one hand, mainstream blends tend to be formed at a particular historical moment followed by a rapid rise in popularity. Contractions, on the other hand, are formed by
19966-440: The statute remains tied to BAC, but the BrAC results of certain machines have been judicially deemed presumptively accurate substitutes for blood testing when used as directed. While BrAC tests are not necessary to prove a defendant was under the influence, laws in these states create a rebuttable presumption , which means it is presumed that the driver was intoxicated given a high BrAC reading, but that presumption can be rebutted if
20115-764: The summer directly into the ground providing further cooling while the waste heat during winter can be pumped directly into the building. The University of Minnesota owns the patent rights to this type of system. Co-generation systems can reach 85% efficiency (40–60% electric and the remainder as thermal). Phosphoric-acid fuel cells (PAFC) comprise the largest segment of existing CHP products worldwide and can provide combined efficiencies close to 90%. Molten carbonate (MCFC) and solid-oxide fuel cells (SOFC) are also used for combined heat and power generation and have electrical energy efficiencies around 60%. Disadvantages of co-generation systems include slow ramping up and down rates, high cost and short lifetime. Also their need to have
20264-480: The then-common type of luggage , which opens into two equal parts: You see it's like a portmanteau—there are two meanings packed up into one word. In his introduction to his 1876 poem The Hunting of the Snark , Carroll again uses portmanteau when discussing lexical selection: Humpty Dumpty's theory, of two meanings packed into one word like a portmanteau, seems to me the right explanation for all. For instance, take
20413-459: The thousands of hours. The alkaline fuel cell (AFC) or hydrogen-oxygen fuel cell was designed and first demonstrated publicly by Francis Thomas Bacon in 1959. It was used as a primary source of electrical energy in the Apollo space program. The cell consists of two porous carbon electrodes impregnated with a suitable catalyst such as Pt, Ag, CoO, etc. The space between the two electrodes is filled with
20562-462: The two words "fuming" and "furious". Make up your mind that you will say both words, but leave it unsettled which you will say first … if you have the rarest of gifts, a perfectly balanced mind, you will say "frumious". In then-contemporary English, a portmanteau was a suitcase that opened into two equal sections. According to the OED Online , a portmanteau is a "case or bag for carrying clothing and other belongings when travelling; (originally) one of
20711-480: The two. All breath alcohol testers used by law enforcement in the United States of America must be approved by the Department of Transportation's National Highway Traffic Safety Administration . The breath alcohol content reading may be used in prosecutions of the crime of driving under the influence of alcohol (sometimes referred to as driving or operating while intoxicated) in several ways. Historically, states in
20860-445: The unit to a calibration lab. One major problem with older breath analyzers is non-specificity: the machines identify not only the ethyl alcohol (or ethanol ) found in alcoholic beverages but also other substances similar in molecular structure or reactivity, "interfering compounds". The oldest breath analyzer models pass breath through a solution of potassium dichromate , which oxidizes ethanol into acetic acid , changing color in
21009-406: The use of 'portmanteau' for such combinations, was: Humpty Dumpty's theory, of two meanings packed into one word like a portmanteau, seems to me the right explanation for all. For instance, take the two words "fuming" and "furious." Make up your mind that you will say both words ... you will say "frumious." The errors are based on similarity of meanings, rather than phonological similarities, and
21158-579: The use of a solid acid material as the electrolyte. At low temperatures, solid acids have an ordered molecular structure like most salts. At warmer temperatures (between 140 and 150 °C for CsHSO 4 ), some solid acids undergo a phase transition to become highly disordered "superprotonic" structures, which increases conductivity by several orders of magnitude. The first proof-of-concept SAFCs were developed in 2000 using cesium hydrogen sulfate (CsHSO 4 ). Current SAFC systems use cesium dihydrogen phosphate (CsH 2 PO 4 ) and have demonstrated lifetimes in
21307-508: The vehicle and the time the test was administered, or within a certain number of hours of testing. Other jurisdictions use retrograde extrapolation to estimate the BAC or BrAC at the time of driving. One exception to criminal prosecution is the state of Wisconsin, where a first time drunk driving offense is normally a civil ordinance violation. There is no international consensus on the statutory ratio of blood to breath levels, ranging from 2000:1 (most of Europe) to 2100:1 (US) to 2300:1 (UK). In
21456-542: The whole of the shorter ingredient, as in then the effect depends on orthography alone. (They are also called orthographic blends. ) An orthographic overlap need not also be phonological: For some linguists, an overlap is a condition for a blend. Non-overlapping blends (also called substitution blends) have no overlap, whether phonological or orthographic: Morphosemantically, blends fall into two kinds: attributive and coordinate . Attributive blends (also called syntactic or telescope blends) are those in which one of
21605-460: The word "warn" and 100 mg% and above it shows "fail". These preliminary breath tests are sometimes categorised as part of field sobriety testing , although it is not part of the series of performance tests generally associated with field sobriety tests ( FSTs ) or standard field sobriety tests ( SFSTs ). In Canada, a preliminary non-evidentiary screening device can be approved by Parliament as an approved screening device . In order to demand
21754-508: Was a lecturer at UWIST . The Road Safety Act 1967 introduced the first legally enforceable maximum blood alcohol level for drivers in the UK, above which it became an offence to be in charge of a motor vehicle; and introduced the roadside breathalyser, made available to police forces across the country. In 1979, Lion Laboratories' version of the breathalyser, known as the Alcolyser and incorporating crystal-filled tubes that changed colour above
21903-460: Was a little greater than that of 1 cc of urine. Also in 1927, a Chicago chemist, William Duncan McNally , invented a breathalyzer in which the breath moving through chemicals in water would change color. One suggested use for his invention was for housewives to test whether their husbands had been drinking. In December 1927, in a case in Marlborough , England, Dr. Gorsky, a police surgeon, asked
22052-540: Was called a solid polymer electrolyte fuel cell ( SPEFC ) in the early 1970s, before the proton-exchange mechanism was well understood. (Notice that the synonyms polymer electrolyte membrane and proton-exchange mechanism result in the same acronym .) On the anode side, hydrogen diffuses to the anode catalyst where it later dissociates into protons and electrons. These protons often react with oxidants causing them to become what are commonly referred to as multi-facilitated proton membranes. The protons are conducted through
22201-408: Was the first commercial use of a fuel cell. In 1959, a team led by Harry Ihrig built a 15 kW fuel cell tractor for Allis-Chalmers , which was demonstrated across the U.S. at state fairs. This system used potassium hydroxide as the electrolyte and compressed hydrogen and oxygen as the reactants. Later in 1959, Bacon and his colleagues demonstrated a practical five-kilowatt unit capable of powering
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