The Batéké Plateau is located around the border between the Republic of Congo and Gabon . In both countries it gave name to departments:
114-611: The reaches between 550 and 830 metres, and is rich in manganese . The Bateke Plateau is an ancient volcanic area. Several rivers rise in that area, including the Niari River , which flows in Congo, the Ogooue , Mpassa , Ndjoumou , Lekabi and Lekey Rivers which flow in Gabon. This Gabon location article is a stub . You can help Misplaced Pages by expanding it . Manganese Manganese
228-467: A half-life of 3.7 million years, Mn with a half-life of 312.2 days, and Mn with a half-life of 5.591 days. All of the remaining radioactive isotopes have half-lives of less than three hours, and the majority of less than one minute. The primary decay mode in isotopes lighter than the most abundant stable isotope, Mn, is electron capture and the primary mode in heavier isotopes is beta decay . Manganese also has three meta states . Manganese
342-409: A magnesia nigra (the black ore) from magnesia alba (a white ore, also from Magnesia, also useful in glassmaking). Michele Mercati called magnesia nigra manganesa , and finally the metal isolated from it became known as manganese ( German : Mangan ). The name magnesia eventually was then used to refer only to the white magnesia alba (magnesium oxide), which provided the name magnesium for
456-517: A planetary nebula , returning some of the material that formed the Sun—but now enriched with heavier elements like carbon—to the interstellar medium . Astronomers sometimes divide the Solar System structure into separate regions. The inner Solar System includes Mercury, Venus, Earth, Mars, and the bodies in the asteroid belt . The outer Solar System includes Jupiter, Saturn, Uranus, Neptune, and
570-654: A definite surface, as they are mainly composed of gases and liquids. Over 99.86% of the Solar System's mass is in the Sun and nearly 90% of the remaining mass is in Jupiter and Saturn. There is a strong consensus among astronomers that the Solar System has at least nine dwarf planets : Ceres , Orcus , Pluto , Haumea , Quaoar , Makemake , Gonggong , Eris , and Sedna . There are a vast number of small Solar System bodies , such as asteroids , comets , centaurs , meteoroids , and interplanetary dust clouds . Some of these bodies are in
684-408: A diameter of about 250 km (160 mi) and is one of the few minor planets possessing a ring system. Beyond the orbit of Neptune lies the area of the " trans-Neptunian region ", with the doughnut-shaped Kuiper belt, home of Pluto and several other dwarf planets, and an overlapping disc of scattered objects, which is tilted toward the plane of the Solar System and reaches much further out than
798-415: A few meters to hundreds of kilometers in size. Many asteroids are divided into asteroid groups and families based on their orbital characteristics. Some asteroids have natural satellites that orbit them , that is, asteroids that orbit larger asteroids. The asteroid belt occupies a torus-shaped region between 2.3 and 3.3 AU from the Sun, which lies between the orbits of Mars and Jupiter. It
912-596: A lesser extent as rhodochrosite ( MnCO 3 ). The most important manganese ore is pyrolusite ( MnO 2 ). Other economically important manganese ores usually show a close spatial relation to the iron ores, such as sphalerite . Land-based resources are large but irregularly distributed. About 80% of the known world manganese resources are in South Africa; other important manganese deposits are in Ukraine, Australia, India, China, Gabon and Brazil. According to 1978 estimate,
1026-442: A primitive cubic structure with 20 atoms per unit cell at two types of sites, which is as complex as that of any other elemental metal. It is easily obtained as a metastable phase at room temperature by rapid quenching. It does not show magnetic ordering , remaining paramagnetic down to the lowest temperature measured (1.1 K). Gamma manganese (γ-Mn) forms when heated above 1,370 K (1,100 °C; 2,010 °F). It has
1140-565: A relationship between these orbital distances, like the Titius–Bode law and Johannes Kepler's model based on the Platonic solids , but ongoing discoveries have invalidated these hypotheses. Some Solar System models attempt to convey the relative scales involved in the Solar System in human terms. Some are small in scale (and may be mechanical—called orreries )—whereas others extend across cities or regional areas. The largest such scale model,
1254-399: A rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In
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#17328735111211368-532: A shell surrounding the inert helium, and the energy output will be greater than at present. The outer layers of the Sun will expand to roughly 260 times its current diameter, and the Sun will become a red giant . Because of its increased surface area, the surface of the Sun will be cooler (2,600 K (4,220 °F) at its coolest) than it is on the main sequence. The expanding Sun is expected to vaporize Mercury as well as Venus, and render Earth and Mars uninhabitable (possibly destroying Earth as well). Eventually,
1482-447: A simple face-centered cubic structure (four atoms per unit cell). When quenched to room temperature it converts to β-Mn, but it can be stabilized at room temperature by alloying it with at least 5 percent of other elements (such as C, Fe, Ni, Cu, Pd or Au), and these solute-stabilized alloys distort into a face-centered tetragonal structure. Delta manganese (δ-Mn) forms when heated above 1,406 K (1,130 °C; 2,070 °F) and
1596-413: A small fraction of the solar nebula, the terrestrial planets could not grow very large. The giant planets (Jupiter, Saturn, Uranus, and Neptune) formed further out, beyond the frost line, the point between the orbits of Mars and Jupiter where material is cool enough for volatile icy compounds to remain solid. The ices that formed these planets were more plentiful than the metals and silicates that formed
1710-417: Is 30 AU from the Sun. With a few exceptions, the farther a planet or belt is from the Sun, the larger the distance between its orbit and the orbit of the next nearest object to the Sun. For example, Venus is approximately 0.33 AU farther out from the Sun than Mercury, whereas Saturn is 4.3 AU out from Jupiter, and Neptune lies 10.5 AU out from Uranus. Attempts have been made to determine
1824-436: Is MnO 2 . It is the dark brown pigment of many cave drawings but is also a common ingredient in dry cell batteries. Complexes of Mn(IV) are well known, but they require elaborate ligands . Mn(IV)-OH complexes are an intermediate in some enzymes , including the oxygen evolving center (OEC) in plants. Simple derivatives Mn are rarely encountered but can be stabilized by suitably basic ligands. Manganese(III) acetate
1938-430: Is a chemical element ; it has symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron . Manganese was first isolated in the 1770s. It is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels . It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as
2052-466: Is a brown pigment for paint and is a constituent of natural umber . Tetravalent manganese is used as an activator in red-emitting phosphors . While many compounds are known which show luminescence , the majority are not used in commercial application due to low efficiency or deep red emission. However, several Mn activated fluorides were reported as potential red-emitting phosphors for warm-white LEDs. But to this day, only K 2 SiF 6 :Mn
2166-552: Is a commonly used laboratory reagent because of its oxidizing properties; it is used as a topical medicine (for example, in the treatment of fish diseases). Solutions of potassium permanganate were among the first stains and fixatives to be used in the preparation of biological cells and tissues for electron microscopy. Aside from various permanganate salts, Mn(VII) is represented by the unstable, volatile derivative Mn 2 O 7 . Oxyhalides (MnO 3 F and MnO 3 Cl) are powerful oxidizing agents . The most prominent example of Mn in
2280-409: Is a great ring of debris similar to the asteroid belt, but consisting mainly of objects composed primarily of ice. It extends between 30 and 50 AU from the Sun. It is composed mainly of small Solar System bodies, although the largest few are probably large enough to be dwarf planets. There are estimated to be over 100,000 Kuiper belt objects with a diameter greater than 50 km (30 mi), but
2394-494: Is a silvery-gray metal that resembles iron. It is hard and very brittle, difficult to fuse, but easy to oxidize. Manganese and its common ions are paramagnetic . Manganese tarnishes slowly in air and oxidizes ("rusts") like iron in water containing dissolved oxygen. Naturally occurring manganese is composed of one stable isotope , Mn. Several radioisotopes have been isolated and described, ranging in atomic weight from 46 u ( Mn) to 72 u ( Mn). The most stable are Mn with
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#17328735111212508-428: Is a small chance that another star will pass through the Solar System in the next few billion years. Although this could destabilize the system and eventually lead millions of years later to expulsion of planets, collisions of planets, or planets hitting the Sun, it would most likely leave the Solar System much as it is today. The Sun's main-sequence phase, from beginning to end, will last about 10 billion years for
2622-549: Is also seen in the mineral rhodochrosite ( manganese(II) carbonate ). Manganese(II) commonly exists with a high spin, S = 5/2 ground state because of the high pairing energy for manganese(II). There are no spin-allowed d–d transitions in manganese(II), which explain its faint color. Manganese forms a large variety of organometallic derivatives, i.e., compounds with Mn-C bonds. The organometallic derivatives include numerous examples of Mn in its lower oxidation states, i.e. Mn(−III) up through Mn(I). This area of organometallic chemistry
2736-568: Is an oxidant useful in organic synthesis . Solid compounds of manganese(III) are characterized by its strong purple-red color and a preference for distorted octahedral coordination resulting from the Jahn-Teller effect . A particularly common oxidation state for manganese in aqueous solution is +2, which has a pale pink color. Many manganese(II) compounds are known, such as the aquo complexes derived from manganese(II) sulfate (MnSO 4 ) and manganese(II) chloride (MnCl 2 ). This oxidation state
2850-464: Is attractive because Mn is inexpensive and of relatively low toxicity. Of greatest commercial interest is "MMT", methylcyclopentadienyl manganese tricarbonyl , which is used as an anti-knock compound added to gasoline (petrol) in some countries. It features Mn(I). Consistent with other aspects of Mn(II) chemistry, manganocene ( Mn(C 5 H 5 ) 2 ) is high-spin. In contrast, its neighboring metal iron forms an air-stable, low-spin derivative in
2964-446: Is commercially available for use in warm-white LEDs . Solar System The Solar System is the gravitationally bound system of the Sun and the objects that orbit it. It formed about 4.6 billion years ago when a dense region of a molecular cloud collapsed, forming the Sun and a protoplanetary disc . The Sun is a typical star that maintains a balanced equilibrium by
3078-421: Is dominant in a given soil. At pH values less than 6 or under anaerobic conditions, Mn(II) dominates, while under more alkaline and aerobic conditions, Mn(III,IV) oxides and hydroxides predominate. These effects of soil acidity and aeration state on the form of Mn can be modified or controlled by microbial activity. Microbial respiration can cause both the oxidation of Mn to the oxides, and it can cause reduction of
3192-545: Is found throughout the world's oceans, 90% of which originates from hydrothermal vents. Particulate Mn develops in buoyant plumes over an active vent source, while the dMn behaves conservatively. Mn concentrations vary between the water columns of the ocean. At the surface, dMn is elevated due to input from external sources such as rivers, dust, and shelf sediments. Coastal sediments normally have lower Mn concentrations, but can increase due to anthropogenic discharges from industries such as mining and steel manufacturing, which enter
3306-458: Is low spin, which contrasts with the high spin character of its precursor, MnBr 2 (dmpe) 2 ( dmpe = (CH 3 ) 2 PCH 2 CH 2 P(CH 3 ) 2 ). Polyalkyl and polyaryl derivatives of manganese often exist in higher oxidation states, reflecting the electron-releasing properties of alkyl and aryl ligands. One example is [Mn(CH 3 ) 6 ] . The origin of the name manganese is complex. In ancient times, two black minerals were identified from
3420-408: Is mainly mined in South Africa, Australia, China, Gabon, Brazil, India, Kazakhstan, Ghana, Ukraine and Malaysia. For the production of ferromanganese , the manganese ore is mixed with iron ore and carbon, and then reduced either in a blast furnace or in an electric arc furnace. The resulting ferromanganese has a manganese content of 30–80%. Pure manganese used for the production of iron-free alloys
3534-412: Is no "gap" as seen between the size of Earth and of Neptune (with a radius 3.8 times as large). As many of these super-Earths are closer to their respective stars than Mercury is to the Sun, a hypothesis has arisen that all planetary systems start with many close-in planets, and that typically a sequence of their collisions causes consolidation of mass into few larger planets, but in case of the Solar System
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3648-501: Is part of the iron group of elements, which are thought to be synthesized in large stars shortly before the supernova explosion. Mn decays to Cr with a half-life of 3.7 million years. Because of its relatively short half-life, Mn is relatively rare, produced by cosmic rays impact on iron . Manganese isotopic contents are typically combined with chromium isotopic contents and have found application in isotope geology and radiometric dating . Mn–Cr isotopic ratios reinforce
3762-424: Is produced by leaching manganese ore with sulfuric acid and a subsequent electrowinning process. A more progressive extraction process involves directly reducing (a low grade) manganese ore by heap leaching . This is done by percolating natural gas through the bottom of the heap; the natural gas provides the heat (needs to be at least 850 °C) and the reducing agent (carbon monoxide). This reduces all of
3876-442: Is stable up to the manganese melting point of 1,519 K (1,250 °C; 2,270 °F). It has a body-centered cubic structure (two atoms per cubic unit cell). Common oxidation states of manganese are +2, +3, +4, +6, and +7, although all oxidation states from −3 to +7 have been observed. Manganese in oxidation state +7 is represented by salts of the intensely purple permanganate anion MnO − 4 . Potassium permanganate
3990-464: Is strong consensus among astronomers that five members of the Kuiper belt are dwarf planets . Many dwarf planet candidates are being considered, pending further data for verification. The scattered disc, which overlaps the Kuiper belt but extends out to near 500 AU, is thought to be the source of short-period comets. Scattered-disc objects are believed to have been perturbed into erratic orbits by
4104-430: Is the Solar System's star and by far its most massive component. Its large mass (332,900 Earth masses ), which comprises 99.86% of all the mass in the Solar System, produces temperatures and densities in its core high enough to sustain nuclear fusion of hydrogen into helium. This releases an enormous amount of energy , mostly radiated into space as electromagnetic radiation peaking in visible light . Because
4218-468: Is thought to be remnants from the Solar System's formation that failed to coalesce because of the gravitational interference of Jupiter. The asteroid belt contains tens of thousands, possibly millions, of objects over one kilometer in diameter. Despite this, the total mass of the asteroid belt is unlikely to be more than a thousandth of that of Earth. The asteroid belt is very sparsely populated; spacecraft routinely pass through without incident. Below are
4332-405: Is unusual among elemental metals in having a very complex unit cell, with 58 atoms per cell (29 atoms per primitive unit cell) in four different types of site. It is paramagnetic at room temperature and antiferromagnetic at temperatures below 95 K (−178 °C). Beta manganese (β-Mn) forms when heated above the transition temperature of 973 K (700 °C; 1,290 °F). It has
4446-412: Is used as a reagent in organic chemistry for the oxidation of benzylic alcohols (where the hydroxyl group is adjacent to an aromatic ring ). Manganese dioxide has been used since antiquity to oxidize and neutralize the greenish tinge in glass from trace amounts of iron contamination. MnO 2 is also used in the manufacture of oxygen and chlorine and in drying black paints. In some preparations, it
4560-490: The Middle Ages until modern times and is evident in 14th-century glass from Venice . Because it was used in glassmaking, manganese dioxide was available for experiments by alchemists, the first chemists. Ignatius Gottfried Kaim (1770) and Johann Glauber (17th century) discovered that manganese dioxide could be converted to permanganate , a useful laboratory reagent. Kaim also may have reduced manganese dioxide to isolate
4674-489: The Milky Way galaxy. The Solar System formed at least 4.568 billion years ago from the gravitational collapse of a region within a large molecular cloud . This initial cloud was likely several light-years across and probably birthed several stars. As is typical of molecular clouds, this one consisted mostly of hydrogen, with some helium, and small amounts of heavier elements fused by previous generations of stars. As
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4788-597: The Spartan steel exceptionally hard. Around the beginning of the 19th century, manganese was used in steelmaking and several patents were granted. In 1816, it was documented that iron alloyed with manganese was harder but not more brittle. In 1837, British academic James Couper noted an association between miners' heavy exposure to manganese and a form of Parkinson's disease . In 1912, United States patents were granted for protecting firearms against rust and corrosion with manganese phosphate electrochemical conversion coatings, and
4902-608: The Sweden Solar System , uses the 110-meter (361-foot) Avicii Arena in Stockholm as its substitute Sun, and, following the scale, Jupiter is a 7.5-meter (25-foot) sphere at Stockholm Arlanda Airport , 40 km (25 mi) away, whereas the farthest current object, Sedna , is a 10 cm (4 in) sphere in Luleå , 912 km (567 mi) away. At that scale, the distance to Proxima Centauri would be roughly 8 times further than
5016-449: The asteroid belt (between Mars's and Jupiter's orbit) and the Kuiper belt (just outside Neptune's orbit). Six planets, seven dwarf planets, and other bodies have orbiting natural satellites , which are commonly called 'moons'. The Solar System is constantly flooded by the Sun's charged particles , the solar wind , forming the heliosphere . Around 75–90 astronomical units from the Sun,
5130-494: The frost line , and it lies at roughly five times the Earth's distance from the Sun. The planets and other large objects in orbit around the Sun lie near the plane of Earth's orbit, known as the ecliptic . Smaller icy objects such as comets frequently orbit at significantly greater angles to this plane. Most of the planets in the Solar System have secondary systems of their own, being orbited by natural satellites called moons. All of
5244-508: The fusion of hydrogen into helium at its core , releasing this energy from its outer photosphere . Astronomers classify it as a G-type main-sequence star . The largest objects that orbit the Sun are the eight planets . In order from the Sun, they are four terrestrial planets ( Mercury , Venus , Earth and Mars ); two gas giants ( Jupiter and Saturn ); and two ice giants ( Uranus and Neptune ). All terrestrial planets have solid surfaces. Inversely, all giant planets do not have
5358-419: The fusor stars in the Milky Way . The Sun is a population I star , having formed in the spiral arms of the Milky Way galaxy. It has a higher abundance of elements heavier than hydrogen and helium (" metals " in astronomical parlance) than the older population II stars in the galactic bulge and halo . Elements heavier than hydrogen and helium were formed in the cores of ancient and exploding stars, so
5472-528: The grand tack hypothesis suggests that a final inward migration of Jupiter dispersed much of the asteroid belt, leading to the Late Heavy Bombardment of the inner planets. The Solar System remains in a relatively stable, slowly evolving state by following isolated, gravitationally bound orbits around the Sun. Although the Solar System has been fairly stable for billions of years, it is technically chaotic , and may eventually be disrupted . There
5586-427: The heliosphere , which spans much of the Solar System. Along with light , the Sun radiates a continuous stream of charged particles (a plasma ) called the solar wind . This stream spreads outwards at speeds from 900,000 kilometres per hour (560,000 mph) to 2,880,000 kilometres per hour (1,790,000 mph), filling the vacuum between the bodies of the Solar System. The result is a thin , dusty atmosphere, called
5700-554: The interplanetary medium , which extends to at least 100 AU . Activity on the Sun's surface, such as solar flares and coronal mass ejections , disturbs the heliosphere, creating space weather and causing geomagnetic storms . Coronal mass ejections and similar events blow a magnetic field and huge quantities of material from the surface of the Sun. The interaction of this magnetic field and material with Earth's magnetic field funnels charged particles into Earth's upper atmosphere, where its interactions create aurorae seen near
5814-421: The magnetic poles . The largest stable structure within the heliosphere is the heliospheric current sheet , a spiral form created by the actions of the Sun's rotating magnetic field on the interplanetary medium. The inner Solar System is the region comprising the terrestrial planets and the asteroids . Composed mainly of silicates and metals, the objects of the inner Solar System are relatively close to
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#17328735111215928-513: The ocean floor has 500 billion tons of manganese nodules . Attempts to find economically viable methods of harvesting manganese nodules were abandoned in the 1970s. In South Africa, most identified deposits are located near Hotazel in the Northern Cape Province , ( Kalahari manganese fields ), with a 2011 estimate of 15 billion tons. In 2011 South Africa produced 3.4 million tons, topping all other nations. Manganese
6042-566: The pre-solar nebula collapsed, conservation of angular momentum caused it to rotate faster. The center, where most of the mass collected, became increasingly hotter than the surroundings. As the contracting nebula spun faster, it began to flatten into a protoplanetary disc with a diameter of roughly 200 AU and a hot, dense protostar at the center. The planets formed by accretion from this disc, in which dust and gas gravitationally attracted each other, coalescing to form ever larger bodies. Hundreds of protoplanets may have existed in
6156-476: The +6 oxidation state is the green anion manganate , [MnO 4 ] . Manganate salts are intermediates in the extraction of manganese from its ores. Compounds with oxidation states +5 are somewhat elusive, and often found associated to an oxide (O ) or nitride (N ) ligand. One example is the blue anion hypomanganate [MnO 4 ] . Mn(IV) is somewhat enigmatic because it is common in nature but far rarer in synthetic chemistry. The most common Mn ore, pyrolusite ,
6270-487: The 2020s. The real mission of Hughes Glomar Explorer was to raise a sunken Soviet submarine, the K-129 , with the goal of retrieving Soviet code books. An abundant resource of manganese in the form of manganese nodules found on the ocean floor. These nodules, which are composed of 29% manganese, are located along the ocean floor . The environmental impacts of nodule collection are of interest. Dissolved manganese (dMn)
6384-474: The 20th century, manganese dioxide was widely used as the cathodic for commercial disposable dry batteries of both the standard (zinc–carbon) and alkaline types. Manganese is essential to iron and steel production by virtue of its sulfur -fixing, deoxidizing , and alloying properties. This application was first recognized by the British metallurgist Robert Forester Mushet (1811–1891) who, in 1856, introduced
6498-470: The Kuiper belt. The entire region is still largely unexplored . It appears to consist overwhelmingly of many thousands of small worlds—the largest having a diameter only a fifth that of Earth and a mass far smaller than that of the Moon—composed mainly of rock and ice. This region is sometimes described as the "third zone of the Solar System", enclosing the inner and the outer Solar System. The Kuiper belt
6612-557: The Moon is from Earth. If the Sun–Neptune distance is scaled to 100 metres (330 ft), then the Sun would be about 3 cm (1.2 in) in diameter (roughly two-thirds the diameter of a golf ball), the giant planets would be all smaller than about 3 mm (0.12 in), and Earth's diameter along with that of the other terrestrial planets would be smaller than a flea (0.3 mm or 0.012 in) at this scale. Besides solar energy,
6726-462: The Solar System is a measure of the total amount of orbital and rotational momentum possessed by all its moving components. Although the Sun dominates the system by mass, it accounts for only about 2% of the angular momentum. The planets, dominated by Jupiter, account for most of the rest of the angular momentum due to the combination of their mass, orbit, and distance from the Sun, with a possibly significant contribution from comets. The radius of
6840-545: The Solar System is home to the giant planets and their large moons. The centaurs and many short-period comets orbit in this region. Due to their greater distance from the Sun, the solid objects in the outer Solar System contain a higher proportion of volatiles such as water, ammonia, and methane, than planets of the inner Solar System because their lower temperatures allow these compounds to remain solid, without significant sublimation . The four outer planets, called giant planets or Jovian planets, collectively make up 99% of
6954-457: The Solar System stands out in lacking planets interior to the orbit of Mercury. The known Solar System lacks super-Earths , planets between one and ten times as massive as the Earth, although the hypothetical Planet Nine , if it does exist, could be a super-Earth orbiting in the edge of the Solar System. Uncommonly, it has only small terrestrial and large gas giants; elsewhere planets of intermediate size are typical—both rocky and gas—so there
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#17328735111217068-400: The Solar System, created by heat and light pressure from the early Sun; those objects closer to the Sun, which are more affected by heat and light pressure, are composed of elements with high melting points. Objects farther from the Sun are composed largely of materials with lower melting points. The boundary in the Solar System beyond which those volatile substances could coalesce is known as
7182-410: The Solar System. Four allotropes (structural forms) of solid manganese are known, labeled α, β, γ and δ, and occurring at successively higher temperatures. All are metallic, stable at standard pressure, and have a cubic crystal lattice, but they vary widely in their atomic structures. Alpha manganese (α-Mn) is the equilibrium phase at room temperature. It has a body-centered cubic lattice and
7296-406: The Sun by the outer planets, and are expected to become comets or be ejected out of the Solar System. While most centaurs are inactive and asteroid-like, some exhibit cometary activity, such as the first centaur discovered, 2060 Chiron , which has been classified as a comet (95P) because it develops a coma just as comets do when they approach the Sun. The largest known centaur, 10199 Chariklo , has
7410-455: The Sun compared to around two billion years for all other subsequent phases of the Sun's pre- remnant life combined. The Solar System will remain roughly as it is known today until the hydrogen in the core of the Sun has been entirely converted to helium, which will occur roughly 5 billion years from now. This will mark the end of the Sun's main-sequence life. At that time, the core of the Sun will contract with hydrogen fusion occurring along
7524-495: The Sun fuses hydrogen at its core, it is a main-sequence star. More specifically, it is a G2-type main-sequence star , where the type designation refers to its effective temperature . Hotter main-sequence stars are more luminous but shorter lived. The Sun's temperature is intermediate between that of the hottest stars and that of the coolest stars. Stars brighter and hotter than the Sun are rare, whereas substantially dimmer and cooler stars, known as red dwarfs , make up about 75% of
7638-422: The Sun is 0.0047 AU (700,000 km; 400,000 mi). Thus, the Sun occupies 0.00001% (1 part in 10 ) of the volume of a sphere with a radius the size of Earth's orbit, whereas Earth's volume is roughly 1 millionth (10 ) that of the Sun. Jupiter, the largest planet, is 5.2 AU from the Sun and has a radius of 71,000 km (0.00047 AU; 44,000 mi), whereas the most distant planet, Neptune,
7752-403: The Sun is growing brighter; early in its main-sequence life its brightness was 70% that of what it is today. The temperature, reaction rate , pressure, and density increased until hydrostatic equilibrium was achieved: the thermal pressure counterbalancing the force of gravity. At this point, the Sun became a main-sequence star. Solar wind from the Sun created the heliosphere and swept away
7866-472: The Sun twice for every three times that Neptune does, or once for every two. The classical belt consists of objects having no resonance with Neptune, and extends from roughly 39.4 to 47.7 AU. Members of the classical Kuiper belt are sometimes called "cubewanos", after the first of their kind to be discovered, originally designated 1992 QB 1 , (and has since been named Albion); they are still in near primordial, low-eccentricity orbits. Currently, there
7980-499: The Sun; the radius of this entire region is less than the distance between the orbits of Jupiter and Saturn. This region is within the frost line , which is a little less than 5 AU from the Sun. The four terrestrial or inner planets have dense, rocky compositions, few or no moons , and no ring systems . They are composed largely of refractory minerals such as silicates —which form their crusts and mantles —and metals such as iron and nickel which form their cores . Three of
8094-564: The alloys particularly useful in harsh automotive and industrial environments. Manganese oxide and sulfate are components of fertilizers. In the year 2000, an estimated 20,000 tons of these compounds were used in fertilizers in the US alone. A comparable amount of Mn compounds was also used in animal feeds. Methylcyclopentadienyl manganese tricarbonyl is an additive in some unleaded gasoline to boost octane rating and reduce engine knocking . Manganese(IV) oxide (manganese dioxide, MnO 2 )
8208-565: The astronomical sense (chemical compounds with melting points of up to a few hundred kelvins such as water, methane, ammonia, hydrogen sulfide , and carbon dioxide . ) Icy substances comprise the majority of the satellites of the giant planets and small objects that lie beyond Neptune's orbit. The centaurs are icy, comet-like bodies whose semi-major axes are longer than Jupiter's and shorter than Neptune's (between 5.5 and 30 AU). These are former Kuiper belt and scattered disc objects (SDOs) that were gravitationally perturbed closer to
8322-402: The bodies in the Kuiper belt . Since the discovery of the Kuiper belt, the outermost parts of the Solar System are considered a distinct region consisting of the objects beyond Neptune . The principal component of the Solar System is the Sun, a G-type main-sequence star that contains 99.86% of the system's known mass and dominates it gravitationally. The Sun's four largest orbiting bodies,
8436-410: The collisions caused their destruction and ejection. The orbits of Solar System planets are nearly circular. Compared to many other systems, they have smaller orbital eccentricity . Although there are attempts to explain it partly with a bias in the radial-velocity detection method and partly with long interactions of a quite high number of planets, the exact causes remain undetermined. The Sun
8550-432: The core will be hot enough for helium fusion; the Sun will burn helium for a fraction of the time it burned hydrogen in the core. The Sun is not massive enough to commence the fusion of heavier elements, and nuclear reactions in the core will dwindle. Its outer layers will be ejected into space, leaving behind a dense white dwarf , half the original mass of the Sun but only the size of Earth. The ejected outer layers may form
8664-413: The descriptions of the three largest bodies in the asteroid belt. They are all considered to be relatively intact protoplanets , a precursor stage before becoming a fully-formed planet (see List of exceptional asteroids ): Hilda asteroids are in a 3:2 resonance with Jupiter; that is, they go around the Sun three times for every two Jovian orbits. They lie in three linked clusters between Jupiter and
8778-441: The early Solar System, but they either merged or were destroyed or ejected, leaving the planets, dwarf planets, and leftover minor bodies . Due to their higher boiling points, only metals and silicates could exist in solid form in the warm inner Solar System close to the Sun (within the frost line ). They would eventually form the rocky planets of Mercury, Venus, Earth, and Mars. Because these refractory materials only comprised
8892-477: The element, in the form of Spiegeleisen . Manganese comprises about 1000 ppm (0.1%) of the Earth's crust and is the 12th most abundant element. Soil contains 7–9000 ppm of manganese with an average of 440 ppm. The atmosphere contains 0.01 μg/m . Manganese occurs principally as pyrolusite ( MnO 2 ), braunite (Mn Mn 6 )SiO 12 ), psilomelane (Ba,H 2 O) 2 Mn 5 O 10 , and to
9006-508: The evidence from Al and Pd for the early history of the Solar System . Variations in Cr/ Cr and Mn/Cr ratios from several meteorites suggest an initial Mn/ Mn ratio, which indicate that Mn–Cr isotopic composition must result from in situ decay of Mn in differentiated planetary bodies. Hence, Mn provides additional evidence for nucleosynthetic processes immediately before coalescence of
9120-449: The first generation of stars had to die before the universe could be enriched with these atoms. The oldest stars contain few metals, whereas stars born later have more. This higher metallicity is thought to have been crucial to the Sun's development of a planetary system because the planets formed from the accretion of "metals". The region of space dominated by the Solar magnetosphere is
9234-491: The form of ferrocene ( Fe(C 5 H 5 ) 2 ). When conducted under an atmosphere of carbon monoxide , reduction of Mn(II) salts gives dimanganese decacarbonyl Mn 2 (CO) 10 , an orange and volatile solid. The air-stability of this Mn(0) compound (and its many derivatives) reflects the powerful electron-acceptor properties of carbon monoxide. Many alkene complexes and alkyne complexes are derived from Mn 2 (CO) 10 . In Mn(CH 3 ) 2 (dmpe) 2 , Mn(II)
9348-407: The four inner planets (Venus, Earth, and Mars) have atmospheres substantial enough to generate weather; all have impact craters and tectonic surface features, such as rift valleys and volcanoes. Asteroids except for the largest, Ceres, are classified as small Solar System bodies and are composed mainly of carbonaceous , refractory rocky and metallic minerals, with some ice. They range from
9462-461: The free element when it was isolated much later. Manganese dioxide, which is abundant in nature, has long been used as a pigment. The cave paintings in Gargas that are 30,000 to 24,000 years old are made from the mineral form of MnO 2 pigments. Manganese compounds were used by Egyptian and Roman glassmakers, either to add to, or remove, color from glass. Use as "glassmakers soap" continued through
9576-441: The giant planets, account for 99% of the remaining mass, with Jupiter and Saturn together comprising more than 90%. The remaining objects of the Solar System (including the four terrestrial planets, the dwarf planets, moons, asteroids , and comets) together comprise less than 0.002% of the Solar System's total mass. The Sun is composed of roughly 98% hydrogen and helium, as are Jupiter and Saturn. A composition gradient exists in
9690-566: The gravitational influence of Neptune's early outward migration . Most scattered disc objects have perihelia within the Kuiper belt but aphelia far beyond it (some more than 150 AU from the Sun). SDOs' orbits can be inclined up to 46.8° from the ecliptic plane. Some astronomers consider the scattered disc to be merely another region of the Kuiper belt and describe scattered-disc objects as "scattered Kuiper belt objects". Some astronomers classify centaurs as inward-scattered Kuiper belt objects along with
9804-410: The human brain, the manganese is bound to manganese metalloproteins , most notably glutamine synthetase in astrocytes . It is familiar in the laboratory in the form of the deep violet salt potassium permanganate . It occurs at the active sites in some enzymes . Of particular interest is the use of a Mn-O cluster , the oxygen-evolving complex , in the production of oxygen by plants. Manganese
9918-415: The larger moons orbit their planets in prograde direction, matching the direction of planetary rotation; Neptune's moon Triton is the largest to orbit in the opposite, retrograde manner. Most larger objects rotate around their own axes in the prograde direction relative to their orbit, though the rotation of Venus is retrograde. To a good first approximation, Kepler's laws of planetary motion describe
10032-491: The largest natural satellites are in synchronous rotation , with one face permanently turned toward their parent. The four giant planets have planetary rings, thin discs of tiny particles that orbit them in unison. As a result of the formation of the Solar System , planets and most other objects orbit the Sun in the same direction that the Sun is rotating. That is, counter-clockwise, as viewed from above Earth's north pole. There are exceptions, such as Halley's Comet . Most of
10146-422: The level of cosmic-ray penetration in the Solar System varies, though by how much is unknown. The zone of habitability of the Solar System is conventionally located in the inner Solar System, where planetary surface or atmospheric temperatures admit the possibility of liquid water . Habitability might be possible in subsurface oceans of various outer Solar System moons. Compared to many extrasolar systems,
10260-443: The main asteroid belt. Trojans are bodies located within another body's gravitationally stable Lagrange points : L 4 , 60° ahead in its orbit, or L 5 , 60° behind in its orbit. Every planet except Mercury and Saturn is known to possess at least 1 trojan. The Jupiter trojan population is roughly equal to that of the asteroid belt. After Jupiter, Neptune possesses the most confirmed trojans, at 28. The outer region of
10374-412: The manganese content reaches 4%, the embrittlement of the steel becomes a dominant feature. The embrittlement decreases at higher manganese concentrations and reaches an acceptable level at 8%. Steel containing 8 to 15% of manganese has a high tensile strength of up to 863 MPa. Steel with 12% manganese was discovered in 1882 by Robert Hadfield and is still known as Hadfield steel (mangalloy) . It
10488-503: The manganese ore to manganese oxide (MnO), which is a leachable form. The ore then travels through a grinding circuit to reduce the particle size of the ore to between 150 and 250 μm, increasing the surface area to aid leaching. The ore is then added to a leach tank of sulfuric acid and ferrous iron (Fe ) in a 1.6:1 ratio. The iron reacts with the manganese dioxide (MnO 2 ) to form iron hydroxide (FeO(OH)) and elemental manganese (Mn). This process yields approximately 92% recovery of
10602-457: The manganese. For further purification, the manganese can then be sent to an electrowinning facility. In 1972, the CIA 's Project Azorian , through billionaire Howard Hughes , commissioned the ship Hughes Glomar Explorer with the cover story of harvesting manganese nodules from the sea floor. That triggered a rush of activity to collect manganese nodules, which was not actually practical until
10716-400: The mass orbiting the Sun. All four giant planets have multiple moons and a ring system, although only Saturn's rings are easily observed from Earth. Jupiter and Saturn are composed mainly of gases with extremely low melting points, such as hydrogen, helium, and neon , hence their designation as gas giants . Uranus and Neptune are ice giants , meaning they are largely composed of 'ice' in
10830-619: The metal, but that is uncertain. By the mid-18th century, the Swedish chemist Carl Wilhelm Scheele used manganese dioxide to produce chlorine . First, hydrochloric acid , or a mixture of dilute sulfuric acid and sodium chloride was made to react with manganese dioxide, and later hydrochloric acid from the Leblanc process was used and the manganese dioxide was recycled by the Weldon process . The production of chlorine and hypochlorite bleaching agents
10944-569: The metals and organic compounds can then cause them to be oxidized while the Mn(III,IV) oxides are reduced to Mn (e.g., Cr to Cr(VI) and colorless hydroquinone to tea-colored quinone polymers). Manganese is essential to iron and steel production by virtue of its sulfur -fixing, deoxidizing , and alloying properties. Manganese has no satisfactory substitute in these applications in metallurgy. Steelmaking , including its ironmaking component, has accounted for most manganese demand, presently in
11058-524: The ocean from river inputs. Surface dMn concentrations can also be elevated biologically through photosynthesis and physically from coastal upwelling and wind-driven surface currents. Internal cycling such as photo-reduction from UV radiation can also elevate levels by speeding up the dissolution of Mn-oxides and oxidative scavenging, preventing Mn from sinking to deeper waters. Elevated levels at mid-depths can occur near mid-ocean ridges and hydrothermal vents. The hydrothermal vents release dMn enriched fluid into
11172-402: The orbits of objects around the Sun. These laws stipulate that each object travels along an ellipse with the Sun at one focus , which causes the body's distance from the Sun to vary over the course of its year. A body's closest approach to the Sun is called its perihelion , whereas its most distant point from the Sun is called its aphelion . With the exception of Mercury, the orbits of
11286-441: The oxides to the divalent cation. The Mn(III,IV) oxides exist as brownish-black stains and small nodules on sand, silt, and clay particles. These surface coatings on other soil particles have high surface area and carry negative charge. The charged sites can adsorb and retain various cations, especially heavy metals (e.g., Cr , Cu , Zn , and Pb ). In addition, the oxides can adsorb organic acids and other compounds. The adsorption of
11400-464: The planets are nearly circular, but many comets, asteroids, and Kuiper belt objects follow highly elliptical orbits. Kepler's laws only account for the influence of the Sun's gravity upon an orbiting body, not the gravitational pulls of different bodies upon each other. On a human time scale, these perturbations can be accounted for using numerical models , but the planetary system can change chaotically over billions of years. The angular momentum of
11514-415: The primary characteristic of the Solar System enabling the presence of life is the heliosphere and planetary magnetic fields (for those planets that have them). These magnetic fields partially shield the Solar System from high-energy interstellar particles called cosmic rays . The density of cosmic rays in the interstellar medium and the strength of the Sun's magnetic field change on very long timescales, so
11628-571: The process has seen widespread use ever since. The invention of the Leclanché cell in 1866 and the subsequent improvement of batteries containing manganese dioxide as cathodic depolarizer increased the demand for manganese dioxide. Until the development of batteries with nickel–cadmium and lithium, most batteries contained manganese. The zinc–carbon battery and the alkaline battery normally use industrially produced manganese dioxide because naturally occurring manganese dioxide contains impurities. In
11742-400: The range of 85% to 90% of the total demand. Manganese is a key component of low-cost stainless steel . Often ferromanganese (usually about 80% manganese) is the intermediate in modern processes. Small amounts of manganese improve the workability of steel at high temperatures by forming a high-melting sulfide and preventing the formation of a liquid iron sulfide at the grain boundaries. If
11856-476: The regions of the Magnetes (either Magnesia , located within modern Greece, or Magnesia ad Sipylum , located within modern Turkey). They were both called magnes from their place of origin, but were considered to differ in sex. The male magnes attracted iron, and was the iron ore now known as lodestone or magnetite , and which probably gave us the term magnet . The female magnes ore did not attract iron, but
11970-507: The remaining gas and dust from the protoplanetary disc into interstellar space. Following the dissipation of the protoplanetary disk , the Nice model proposes that gravitational encounters between planetisimals and the gas giants caused each to migrate into different orbits. This led to dynamical instability of the entire system, which scattered the planetisimals and ultimately placed the gas giants in their current positions. During this period,
12084-415: The same basic reaction, but a different electrolyte mixture. In 2002, more than 230,000 tons of manganese dioxide was used for this purpose. Copper alloys of manganese, such as Manganin , are commonly found in metal element shunt resistors used for measuring relatively large amounts of current. These alloys have very low temperature coefficient of resistance and are resistant to sulfur. This makes
12198-404: The solar wind is halted, resulting in the heliopause . This is the boundary of the Solar System to interstellar space . The outermost region of the Solar System is the theorized Oort cloud , the source for long-period comets , extending to a radius of 2,000–200,000 AU . The closest star to the Solar System, Proxima Centauri , is 4.25 light-years (269,000 AU) away. Both stars belong to
12312-480: The terrestrial inner planets, allowing them to grow massive enough to capture large atmospheres of hydrogen and helium, the lightest and most abundant elements. Leftover debris that never became planets congregated in regions such as the asteroid belt, Kuiper belt, and Oort cloud. Within 50 million years, the pressure and density of hydrogen in the center of the protostar became great enough for it to begin thermonuclear fusion . As helium accumulates at its core,
12426-456: The total mass of the Kuiper belt is thought to be only a tenth or even a hundredth the mass of Earth. Many Kuiper belt objects have satellites, and most have orbits that are substantially inclined (~10°) to the plane of the ecliptic. The Kuiper belt can be roughly divided into the " classical " belt and the resonant trans-Neptunian objects . The latter have orbits whose periods are in a simple ratio to that of Neptune: for example, going around
12540-589: The water. The dMn can then travel up to 4,000 km due to the microbial capsules present, preventing exchange with particles, lowing the sinking rates. Dissolved Mn concentrations are even higher when oxygen levels are low. Overall, dMn concentrations are normally higher in coastal regions and decrease when moving offshore. Manganese occurs in soils in three oxidation states: the divalent cation, Mn and as brownish-black oxides and hydroxides containing Mn (III,IV), such as MnOOH and MnO 2 . Soil pH and oxidation-reduction conditions affect which of these three forms of Mn
12654-478: Was a large consumer of manganese ores. Scheele and others were aware that pyrolusite (mineral form of manganese dioxide) contained a new element. Johan Gottlieb Gahn isolated an impure sample of manganese metal in 1774, which he did by reducing the dioxide with carbon . The manganese content of some iron ores used in Greece led to speculations that steel produced from that ore contains additional manganese, making
12768-572: Was used for British military steel helmets and later by the U.S. military. Manganese is used in production of alloys with aluminium. Aluminium with roughly 1.5% manganese has increased resistance to corrosion through grains that absorb impurities which would lead to galvanic corrosion . The corrosion-resistant aluminium alloys 3004 and 3104 (0.8 to 1.5% manganese) are used for most beverage cans . Before 2000, more than 1.6 million tonnes of those alloys were used; at 1% manganese, this consumed 16,000 tonnes of manganese. Manganese(IV) oxide
12882-414: Was used in the original type of dry cell battery as an electron acceptor from zinc, and is the blackish material in carbon–zinc type flashlight cells. The manganese dioxide is reduced to the manganese oxide-hydroxide MnO(OH) during discharging, preventing the formation of hydrogen at the anode of the battery. The same material also functions in newer alkaline batteries (usually battery cells), which use
12996-438: Was used to decolorize glass. This female magnes was later called magnesia , known now in modern times as pyrolusite or manganese dioxide . Neither this mineral nor elemental manganese is magnetic. In the 16th century, manganese dioxide was called manganesum (note the two Ns instead of one) by glassmakers, possibly as a corruption and concatenation of two words, since alchemists and glassmakers eventually had to differentiate
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